EP3097377B1 - Improved tube for a heat exchanger - Google Patents
Improved tube for a heat exchanger Download PDFInfo
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- EP3097377B1 EP3097377B1 EP15704060.1A EP15704060A EP3097377B1 EP 3097377 B1 EP3097377 B1 EP 3097377B1 EP 15704060 A EP15704060 A EP 15704060A EP 3097377 B1 EP3097377 B1 EP 3097377B1
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- European Patent Office
- Prior art keywords
- tubes
- millimetres
- element according
- segment
- tube
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 239000012530 fluid Substances 0.000 description 25
- 239000013256 coordination polymer Substances 0.000 description 11
- 230000005494 condensation Effects 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 238000004891 communication Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/08—Tubular elements crimped or corrugated in longitudinal section
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28B—STEAM OR VAPOUR CONDENSERS
- F28B1/00—Condensers in which the steam or vapour is separate from the cooling medium by walls, e.g. surface condenser
- F28B1/02—Condensers in which the steam or vapour is separate from the cooling medium by walls, e.g. surface condenser using water or other liquid as the cooling medium
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/10—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged one within the other, e.g. concentrically
- F28D7/103—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged one within the other, e.g. concentrically consisting of more than two coaxial conduits or modules of more than two coaxial conduits
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/16—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/42—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being both outside and inside the tubular element
- F28F1/424—Means comprising outside portions integral with inside portions
- F28F1/426—Means comprising outside portions integral with inside portions the outside portions and the inside portions forming parts of complementary shape, e.g. concave and convex
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
- F28D2021/0061—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for phase-change applications
- F28D2021/0063—Condensers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2210/00—Heat exchange conduits
- F28F2210/06—Heat exchange conduits having walls comprising obliquely extending corrugations, e.g. in the form of threads
Definitions
- the invention relates to an element for an industrial type heat exchanger, in particular a condenser, of the type comprising a generally tubular body.
- Condensers comprising such elements, also called “tube condensers", are widely used industrially, in particular for the production of electricity.
- a first fluid typically water in the liquid state
- a second fluid in the gaseous state generally steam
- Industrial type condensers must be able to condense large quantities of steam in a minimum of time.
- the volume of vapor that they are able to condense per unit time at least partly characterizes their performance.
- industrial condensers are generally equipped with hundreds of tubes, or even thousands, of great length, typically up to about twenty meters.
- US2011/174469 which represents the document of the state of the art closest to the subject of claim 1, discloses a heat exchanger element of the type comprising a tubular body whose wall is at least partly delimited by an internal surface and an outer surface, the wall having a twisted shape over at least a segment of said body, and the inner surface having at least one groove in shape correspondence with said wall and extending helically over said segment.
- This particular configuration substantially improves the heat exchanges at the level of the tubes: on the one hand, the twisted shape gives the wall a larger contact surface between the fluids, inside and outside the tubes; on the other hand, it causes turbulence in the fluid flowing inside the tubes, which is generally beneficial for the heat exchanges at the level of the tubes.
- the twisted shape also improves the evacuation of drops that form on the outer surface of the tubes.
- tubes having a configuration of this type are said to be “corrugated”, or, more precisely, “provided with corrugations”.
- the pitch of the twist also called pitch of corrugation, is generally greater than 20 millimeters.
- the invention aims to improve the existing.
- the proposed heat exchanger element includes the features of claim 1.
- FIG. 1 shows, generically, an industrial type heat exchanger in the form of a condenser 1.
- the condenser 1 comprises a plurality of elementary tubes 3 held relative to each other in one or more bundles 5 by plates 7 distributed along the tubes 3. Each plate 7 is thus crossed by each of the tubes 3 of the bundle 5.
- Condenser 1 further comprises a pair of header boxes 9 into which the opposite ends of each of tubes 3 respectively open.
- One of the boxes 9 is in fluid communication with a fluid inlet 11, while the other of these boxes 9 is in fluid communication with a fluid outlet 13.
- Inlet 11 and outlet 13 can be connected to the rest of a circuit in which a first fluid circulates.
- the first fluid enters condenser 1 through inlet 11 in liquid form. It circulates from the corresponding collector box 9 to the other collector box inside the tubes 3, in one or more passes. From there, the first fluid leaves condenser 1 for the rest of the circuit through outlet 13.
- the bundle 5 of tubes 3 is housed in an enclosure 15 formed inside what is called a calender 17 in the art.
- the shell 17 is equipped with a fluid inlet 19 and a fluid outlet 21 which open into the enclosure 15.
- the inlet 19 and the outlet 21 make it possible to connect the condenser 1 to a circuit in which a second fluid circulates.
- the second fluid enters enclosure 15 through inlet 19 in gaseous form.
- the second fluid exchanges heat with the first fluid circulating inside these tubes.
- the first fluid being generally introduced at a temperature lower than that of the second fluid, the latter condenses on the outer surface of the tubes 3.
- the second fluid in liquid form leaves the enclosure 15 through the outlet 21.
- Condenser 1 type condensers are widely used in industrial power generation. This involves in particular condensing water vapor using cold water circulating inside the tubes. To do this, very long tubes are used, up to twenty meters each.
- FIG. 2 shows a TE tube element that can be used in a condenser like condenser 1.
- the tube element TE comprises a body BDY in the general shape of an elongated hollow cylinder, or tubular, of length TL.
- the body BDY has two longitudinal end sections ES1 and ES2 connected to each other by a central section CS of length CL.
- the length TL corresponds to the total length of the tubular element TE, including the central section CS and the end sections ES1 and ES2.
- the ES1 and ES2 end sections are generally cylindrical, with an outside diameter TOD.
- the diameter TOD corresponds to the nominal outside diameter of the TE element, as it is commonly referred to in the art.
- End sections ES1 and ES2 each have a smooth outer surface and inner surface.
- the central section CS has a wall which extends along the body in a twist, or in a helical manner, or even in a helicoid, forming turns LP around the longitudinal axis LA of the tube element TE.
- the LP turns are contiguous.
- This twisted conformation of the wall of the element TE results in an outer surface which, over the length of the central section CS, has a helical relief, made of hollows and bumps.
- This relief is likely to improve the heat exchange capacities of the TE element, because the outer surface of the latter is then larger than that of a smooth tube of the same outer diameter. In addition, it improves the evacuation of drops that form on the outer surface of the TE element.
- the central section CS retains the general appearance of a hollow cylinder, having an outside diameter COD.
- FIGS. 3 and 4 show, in a generic way, a twisted portion CW of the wall and a parameterization of this twisted shape.
- the result of the twisted shape of the wall CW is an internal surface IS having a relief made of ridges and hollows, in shape correspondence with the hollows and bumps, respectively of the external surface OS.
- the internal surface IS is provided with a groove which extends according to a helix with contiguous turns along the section CS.
- the inner surface IS has a helicoid shape.
- This relief is likely to improve the heat exchange capacities of the TE element, due to the generation of vortices in the fluid which flows inside the TE element.
- the twisted wall CW has a thickness TT.
- the thickness TT corresponds to the nominal thickness of the TE element, that is to say the thickness of the wall of the smooth tube at the origin of the TE element.
- the central section CS has an inside diameter CID.
- the CID diameter corresponds to the diameter of a gauge just capable of passing through the TE element internally.
- the twisted section CS has an outside diameter COD which corresponds to the nominal outside diameter of the element TE on the twisted section CS, that is to say the diameter of a cylindrical envelope surface of this section.
- the twist shape has a pitch CP, if necessary considered inside the tabular element.
- the depth CD of the internal groove resulting from the twisted form is considered with respect to an internal envelope surface of the tubular element, or, seen otherwise, as the radial distance between the bottom of the hollows of the internal surface IS and the top of the ridges.
- TID the dimension which corresponds to the nominal internal diameter of the tube, as it is usually designated in the art, that is to say here the nominal internal diameter of the smooth terminal sections ES1 and ES2.
- the tube element TE has, on the twisted section CS, a nominal outside diameter COD of between 18 and 30 millimeters.
- the pitch CP of the twist is less than 3.5 millimeters.
- the depth CD is such that the ratio of the pitch CP raised to a real power R of between 1.5 and 2.5 over the depth CD, which is called aspect ratio FR, remains lower than a ceiling value TV.
- the ceiling value TV is close to 24.
- the power R is close to 1.7.
- Tables 1A and 1B show that the twisted part of the tubes according to the invention has a very small pitch, less than 3.5 millimeters, and preferably less than 3 millimeters, compared to the pitch values conventionally used in tubes with corrugations, typically greater than 20 millimeters. Consequently, the tubes according to the invention differ from conventional tubes in that the twisted section has a shape resembling a spiral.
- Table 2 below brings together the dimensional characteristics relating to a set of tube elements (referenced I, ..., XII) each having a twisted central section.
- the tube elements are distinguished from each other by the profile of their respective twisted section, characterized by values of pitch CP and depth CD different from each other.
- Dimensions missing from Table 2 are common to tubes I to XIV.
- the tube elements all have an outside diameter of 22.22 millimeters and a wall thickness of 0.5 millimeters.
- the tubes are made of grade 2 titanium.
- the CP pitch and CD depth values are expressed in millimeters.
- Table 2 also shows the corresponding values of the aspect ratio FR, calculated for a power value R of 1.7. ⁇ u>Table 2 ⁇ /u>: CP CD FR I 2.0 0.14 23.21 II 2.3 0.19 21.92 III 2.5 0.25 18.84 IV 3.1 0.17 39.44 V 3.2 0.39 18.06 VII 3.3 0.24 31.83 VII 3.3 0.32 24.16 VIII 3.3 0.44 17.57 IX 4.2 0.47 24.42 X 4.3 0.49 23.96 XI 4.8 0.40 36.47 XII 4.9 0.64 23.24 XIII 1.3 0.04 39 XIV 1.5 0.06 33
- the tube elements II, III are in accordance with the embodiment variant 2.
- the tubular element III is moreover in conformity with the example embodiment 2.
- the elements I, II, III, V, and VIII are in accordance with the invention in that they have CP pitch values of less than 3.5 millimeters and additionally verify the conditions COND1, COND2 and COND3.
- Tube elements IV and VI have dimensions in accordance with embodiment variant 2, except that they do not satisfy conditions COND1 to COND3.
- Table 3 below collates the results of heat exchange capacity measurements carried out on the elements in table 2.
- the coefficient K represents a heat exchange capacity measured for the tube element considered.
- the K coefficient is expressed in Watt per square meter and per Kelvin (Wm -2 .K -1 ).
- the HER value expressed as a percentage, corresponds to the improvement in the value of K for the element considered compared to a smooth element having otherwise similar dimensions.
- Table 3 shows that compliance with COND1, COND2 and COND3 conditions is generally associated with a significant increase in heat exchange performance.
- the rows corresponding to tube elements I, II, III, V, VIII, X and XII show coefficient K values at least 45% higher than the reference value for a smooth tube (5272 Wm -2 .K - 1 ).
- the comparison in Table 2 of lines VII and X on the one hand, and lines I and XIII and XIV on the other hand, also shows a slight increase in heat exchange performance as soon as the FR ratio exceeds the ceiling value of 24. When the FR ratio is higher than the ceiling value, the increase in heat exchange performance compared to a smooth tube is generally less than 30%.
- Table 3 proves that the tubular elements in accordance with the invention have greatly improved heat transfer capacities in comparison with smooth elements on the one hand, and elements whose twisted section deviates from the profile provided by the invention.
- Table 4 also collates the values of the so-called Darcy coefficient, or Darcy-Weisbach, for the tubes considered, as well as the DCR increase in the value of this coefficient relative to a smooth reference tube.
- the Darcy coefficient corresponds to a pressure drop coefficient. This dimensionless quantity represents the influence of the type of flow (laminar or turbulent) and the appearance of a pipe (smooth or rough) on the pressure drop.
- the DARCY coefficient is calculated for a flow rate of 2.5 cubic meters per hour.
- An increase in the DARCY value is generally unfavorable to the performance of a tube element within a condenser.
- an increase in the DARCY value implies an increase in the energy consumption necessary for the circulation of the fluid inside the tubes.
- an increase in the DARCY value harms the condensation of water vapor on the exterior of the tubular element with constant energy consumption.
- Table 4 generally shows that the tubes in accordance with the invention exhibit a substantial increase in the DARCY value. However, this increase remains limited (less than 140 and less than for certain tubes not in accordance with the invention, as indicated by a comparison with lines X and XII). On the other hand, the relative increase in the DARCY coefficient is very low (near, or even less, to 100%) for the elements conforming to the second variant embodiment (tubes II and III) and for tube I, in comparison with the other tubes tested. The tubes of the second embodiment variant and tube I show an increase in the DARCY value which is very clearly lower than the others.
- the tubes having a twisted section in accordance with the invention are capable of greatly improved performance as regards their ability to condense a gas circulating externally.
- This improved performance is the result of a twist shape which greatly improves the heat exchange capacities and significantly limits the effects of pressure drop.
- the tubes in accordance with the variant embodiments 1 to 3, and to Examples 1 and 2 are likely to have even greater condensation performance due to heat exchange capacities comparable to the other tubes according to the invention and losses. significantly reduced loads compared to these tubes.
- the outer diameter of the TOD tube is between 19 and 26 millimeters, preferably between 20 and 26 millimeters, and even more preferably between 20 and 23 millimeters.
- the outer diameter TOD is close to 19.05 millimeters, 22.22 millimeters, or 25.4 millimeters.
- the outer diameter COD of the twisted part is between 18 and 26 millimeters, preferably between 20 and 26 millimeters, more preferably still between 20 and 23 millimeters. In particular, the diameter COD is close to 18.90 millimeters, 22.07 or 25.25 millimeters.
- the pitch CP is strictly greater than 2 millimeters. It is less than 3 millimeters.
- the thickness TT of the wall CW of the tube is between 0.4 and 1 millimeter, for example of the order of 0.5 millimeter.
Description
L'invention se rapporte à un élément pour un échangeur thermique de type industriel, en particulier un condenseur, du type comportant un corps généralement tubulaire.The invention relates to an element for an industrial type heat exchanger, in particular a condenser, of the type comprising a generally tubular body.
Les condenseurs comportant de tels éléments, aussi dits "condenseurs à tubes", sont largement utilisés industriellement, notamment pour la production d'électricité. Un premier fluide, typiquement de l'eau à l'état liquide, est mis en circulation à l'intérieur d'une pluralité de tubes, tandis qu'un second fluide à l'état gazeux, généralement de la vapeur d'eau, est amené à proximité des tubes, extérieurement à ceux-ci. Il se produit alors un échange thermique entre les premier et second fluides, au travers de la paroi des tubes, lequel échange provoque la condensation du fluide à l'état gazeux.Condensers comprising such elements, also called "tube condensers", are widely used industrially, in particular for the production of electricity. A first fluid, typically water in the liquid state, is circulated inside a plurality of tubes, while a second fluid in the gaseous state, generally steam, is brought close to the tubes, externally thereto. There is then a heat exchange between the first and second fluids, through the wall of the tubes, which exchange causes the condensation of the fluid in the gaseous state.
Les condenseurs de type industriel doivent pouvoir condenser de grandes quantités de vapeur en un minimum de temps. Le volume de vapeur qu'ils sont capables de condenser par unité de temps caractérise en partie au moins leur performance. Pour ce faire, les condenseurs industriels sont généralement équipés de centaines de tubes, voire de milliers, de grande longueur, typiquement jusqu'à une vingtaine de mètres.Industrial type condensers must be able to condense large quantities of steam in a minimum of time. The volume of vapor that they are able to condense per unit time at least partly characterizes their performance. To do this, industrial condensers are generally equipped with hundreds of tubes, or even thousands, of great length, typically up to about twenty meters.
À l'origine, les condenseurs industriels étaient équipés des tubes lisses. Pour améliorer leurs performances, en particulier en ce qui concerne le débit de vapeur condensée, on a commencé à utiliser des tubes d'un type nouveau, dont le corps conserve sa forme généralement tubulaire, mais dont la paroi présente une forme torsadée s'étendant sur un segment au moins dudit corps. Cette forme torsadée de la paroi résulte en une surface extérieure présentant un relief bombé s'étendant de manière hélicoïdale le long du segment en question, et une rainure de forme correspondante sur la surface intérieure du corps.
Cette configuration particulière améliore sensiblement les échanges thermiques au niveau des tubes : d'une part, la forme torsadée confère à la paroi une surface de contact plus grande entre les fluides, à l'intérieur comme à l'extérieur des tubes ; d'autre part, elle provoque des turbulences dans le fluide qui s'écoule à l'intérieur des tubes, ce qui est globalement bénéfique pour les échanges thermiques au niveau des tubes. La forme torsadée améliore en outre l'évacuation des gouttes qui se forment sur la surface extérieure des tubes.This particular configuration substantially improves the heat exchanges at the level of the tubes: on the one hand, the twisted shape gives the wall a larger contact surface between the fluids, inside and outside the tubes; on the other hand, it causes turbulence in the fluid flowing inside the tubes, which is generally beneficial for the heat exchanges at the level of the tubes. The twisted shape also improves the evacuation of drops that form on the outer surface of the tubes.
Dans la technique, les tubes présentant une configuration de ce type sont dits "corrugués", ou, plus justement, "munis de corrugations". Le pas de la torsade, aussi appelé pas de corrugation, est généralement supérieur à 20 millimètres.In the art, tubes having a configuration of this type are said to be "corrugated", or, more precisely, "provided with corrugations". The pitch of the twist, also called pitch of corrugation, is generally greater than 20 millimeters.
La demanderesse a constaté que, de manière générale, les performances réelles des tubes corrugués, notamment en ce qui concerne leur aptitude à condenser un fluide à leur surface extérieure, sont assez nettement inférieures aux performances attendues.The Applicant has found that, in general, the actual performance of corrugated tubes, in particular with regard to their ability to condense a fluid on their outer surface, is quite markedly lower than the expected performance.
L'invention vise à améliorer l'existant.The invention aims to improve the existing.
L'élément d'échangeur thermique proposé comporte les caractéristiques de la revendication 1.The proposed heat exchanger element includes the features of claim 1.
L'invention sera mieux comprise à la lecture de la description détaillée ci-après, faite en relation avec les dessins annexés, sur lesquels :
- la
figure 1 montre un schéma d'un échangeur thermique générique ; - la
figure 2 est une vue en plan d'un élément de tube pour l'échangeur de lafigure 1 ; - la
figure 3 est une vue en coupe longitudinale d'une portion de paroi d'un l'élément de tube pour l'échangeur de lafigure 1 ; - la
figure 4 représente une portion torsadée d'un élément de tube pour un échangeur thermique, vue en perspective et partiellement coupée.
- the
figure 1 shows a diagram of a generic heat exchanger; - the
figure 2 is a plan view of a tube element for the exchanger of thefigure 1 ; - the
picture 3figure 1 ; - the
figure 4 shows a twisted portion of a tube element for a heat exchanger, seen in perspective and partially cut away.
Les dessins annexés contiennent des éléments de caractère certain. Ils pourront donc non seulement servir à compléter la description de l'invention, mais aussi contribuer à sa définition, le cas échéant.The accompanying drawings contain elements of certain character. They may therefore not only be used to complete the description of the invention, but also contribute to its definition, where applicable.
On fait référence à la
Le condenseur 1 comprend une pluralité de tubes élémentaires 3 maintenus les uns par rapport aux autres en un ou plusieurs faisceaux 5 par des plaques 7 réparties le long des tubes 3. Chaque plaque 7 se trouve ainsi traversée par chacun des tubes 3 du faisceau 5.The condenser 1 comprises a plurality of
Le condenseur 1 comprend en outre une paire de boîtes collectrices 9 dans lesquelles débouchent respectivement les extrémités opposées de chacun des tubes 3.Condenser 1 further comprises a pair of
L'une des boîtes 9 est en communication fluidique avec une arrivée de fluide 11, tandis que l'autre de ces boîtes 9 est communication fluidique avec une sortie de fluide 13.One of the
L'arrivée 11 et la sortie 13 peuvent être raccordées au reste d'un circuit dans lequel circule un premier fluide. Typiquement, le premier fluide pénètre dans le condenseur 1 par l'arrivée 11 sous forme liquide. Il circule de la boîte collectrice 9 correspondante jusqu'à l'autre boîte collectrice à l'intérieur des tubes 3, en une ou plusieurs passes. De là, le premier fluide quitte le condenseur 1 pour le reste du circuit par la sortie 13.
Le faisceau 5 de tubes 3 est logé dans une enceinte 15 ménagée à l'intérieur de ce que l'on appelle une calandre 17 dans la technique. La calandre 17 est équipée d'une entrée de fluide 19 et d'une sortie de fluide 21 qui débouchent dans l'enceinte 15.The
L'entrée 19 et la sortie 21 permettent de raccorder le condenseur 1 à un circuit dans lequel circule un second fluide.The
Le second fluide pénètre dans l'enceinte 15 par l'entrée 19 sous forme gazeuse. Au contact des tubes 3, le second fluide échange de la chaleur avec le premier fluide en circulation à l'intérieur de ces tubes. Le premier fluide étant généralement introduit à une température inférieure à celle du second fluide, ce dernier condense à la surface extérieure des tubes 3. Le second fluide sous forme liquide quitte l'enceinte 15 par la sortie 21.The second fluid enters
Des condenseurs du type du condenseur 1 sont largement utilisés dans la production industrielle d'électricité. Il s'agit en particulier de condenser de la vapeur d'eau au moyen d'eau froide en circulation à l'intérieur des tubes. Pour ce faire, on utilise des tubes de grande longueur, jusqu'à une vingtaine de mètres chacun.Condenser 1 type condensers are widely used in industrial power generation. This involves in particular condensing water vapor using cold water circulating inside the tubes. To do this, very long tubes are used, up to twenty meters each.
On fait référence à la
L'élément de tube TE comprend un corps BDY en forme générale de cylindre creux allongé, ou tubulaire, de longueur TL. Le corps BDY présente deux sections longitudinales d'extrémité ES1 et ES2 raccordées l'une à l'autre par une section centrale CS de longueur CL. La longueur TL correspond à la longueur totale de l'élément tubulaire TE, y compris la section centrale CS et les sections terminales ES1 et ES2.The tube element TE comprises a body BDY in the general shape of an elongated hollow cylinder, or tubular, of length TL. The body BDY has two longitudinal end sections ES1 and ES2 connected to each other by a central section CS of length CL. The length TL corresponds to the total length of the tubular element TE, including the central section CS and the end sections ES1 and ES2.
Les sections d'extrémité ES1 et ES2 sont généralement cylindriques, de diamètre extérieur TOD. Le diamètre TOD correspond au diamètre extérieur nominal de l'élément TE, tel qu'il est habituellement désigné dans la technique. Les sections terminales ES1 et ES2 présentent chacune une surface extérieure et une surface intérieure lisses.The ES1 and ES2 end sections are generally cylindrical, with an outside diameter TOD. The diameter TOD corresponds to the nominal outside diameter of the TE element, as it is commonly referred to in the art. End sections ES1 and ES2 each have a smooth outer surface and inner surface.
La section centrale CS présente une paroi qui s'étend le long du corps en torsade, ou de manière hélicoïdale, ou encore en hélicoïde, en formant des spires LP autour de l'axe longitudinal LA de l'élément de tube TE. Ici, les spires LP sont jointives.The central section CS has a wall which extends along the body in a twist, or in a helical manner, or even in a helicoid, forming turns LP around the longitudinal axis LA of the tube element TE. Here, the LP turns are contiguous.
Il résulte de cette conformation torsadée de la paroi de l'élément TE une surface extérieure qui, sur la longueur de la section centrale CS, présente un relief en hélice, fait de creux et bosses. Ce relief est de nature à améliorer les capacités d'échange thermique de l'élément TE, du fait que la surface extérieure de celui-ci est alors plus étendue que celle d'un tube lisse de même diamètre extérieur. En outre, il améliore l'évacuation des gouttes qui se forment à la surface extérieure de l'élément TE. La section centrale CS conserve une allure générale de cylindre creux, présentant un diamètre extérieur COD.This twisted conformation of the wall of the element TE results in an outer surface which, over the length of the central section CS, has a helical relief, made of hollows and bumps. This relief is likely to improve the heat exchange capacities of the TE element, because the outer surface of the latter is then larger than that of a smooth tube of the same outer diameter. In addition, it improves the evacuation of drops that form on the outer surface of the TE element. The central section CS retains the general appearance of a hollow cylinder, having an outside diameter COD.
On fait référence aux
Ce relief est de nature à améliorer les capacités d'échange thermique de l'élément TE, du fait de la génération de tourbillons dans le fluide qui s'écoule à l'intérieur de l'élément TE.This relief is likely to improve the heat exchange capacities of the TE element, due to the generation of vortices in the fluid which flows inside the TE element.
La paroi torsadée CW présente une épaisseur TT. L'épaisseur TT correspond à l'épaisseur nominale de l'élément TE, c'est-à-dire à l'épaisseur de la paroi du tube lisse à l'origine de l'élément TE. La section centrale CS présente un diamètre intérieur CID. Le diamètre CID correspond au diamètre d'un calibre tout juste capable de traverser intérieurement l'élément TE.The twisted wall CW has a thickness TT. The thickness TT corresponds to the nominal thickness of the TE element, that is to say the thickness of the wall of the smooth tube at the origin of the TE element. The central section CS has an inside diameter CID. The CID diameter corresponds to the diameter of a gauge just capable of passing through the TE element internally.
La section torsadée CS présente un diamètre extérieur COD qui correspond au diamètre extérieur nominal de l'élément TE sur la section torsadée CS, c'est-à-dire au diamètre d'une surface d'enveloppe cylindrique de cette section.The twisted section CS has an outside diameter COD which corresponds to the nominal outside diameter of the element TE on the twisted section CS, that is to say the diameter of a cylindrical envelope surface of this section.
La forme de torsade présente un pas CP, le cas échéant considéré à l'intérieur de l'élément tabulaire. La profondeur CD de la rainure interne issue de la forme torsadée est considérée par rapport à une surface d'enveloppe interne de l'élément tubulaire, ou, vu autrement, comme la distance radiale entre le fond des creux de 1a surface interne IS et le sommet des crêtes.The twist shape has a pitch CP, if necessary considered inside the tabular element. The depth CD of the internal groove resulting from the twisted form is considered with respect to an internal envelope surface of the tubular element, or, seen otherwise, as the radial distance between the bottom of the hollows of the internal surface IS and the top of the ridges.
Bien que non représentée sur les figures, on peut noter TID la dimension qui correspond au diamètre intérieur nominal du tube, tel qu'il est habituellement désigné dans la technique, c'est-à-dire ici le diamètre intérieur nominal des sections terminales lisses ES1 et ES2.Although not represented in the figures, we can note TID the dimension which corresponds to the nominal internal diameter of the tube, as it is usually designated in the art, that is to say here the nominal internal diameter of the smooth terminal sections ES1 and ES2.
Selon un aspect général de l'invention, l'élément de tube TE présente, sur la section torsadée CS, un diamètre extérieur nominal COD compris entre 18 et 30 millimètres. Le pas CP de la torsade est inférieur à 3,5 millimètres. La profondeur CD est telle que le rapport du pas CP élevé à une puissance R réelle comprise entre 1,5 et 2,5 sur la profondeur CD, que l'on appelle rapport de forme FR, demeure inférieur à une valeur plafond TV. En particulier, la valeur plafond TV est voisine de 24. En particulier, la puissance R est voisine de 1,7. Autrement dit, la profondeur CD vérifie les conditions COND1, COND2 et COND3 énoncées ci-dessous :
Les tableaux 1A et 1B ci-dessous rassemblent des données caractéristiques de la section torsadée CS pour des éléments de tube TE selon trois variantes de réalisation de l'invention (tableau 1A), et deux exemples de réalisation (tableau 1B). Les dimensions y sont exprimées en millimètre. À chaque fois, les éléments de tube conformes à ces variantes de réalisation sont tels qu'ils vérifient les conditions COND1, COND2 et COND3, en particulier avec R = 1,7.
Les tableaux 1A et 1B font apparaître que la partie torsadée des tubes selon l'invention présente un pas très réduit, inférieur à 3,5 millimètres, et de préférence inférieur à 3 millimètres, par rapport aux valeurs de pas classiquement utilisées dans les tubes à corrugations, typiquement supérieures à 20 millimètres. Dès lors, les tubes selon l'invention se distinguent des tubes classiques en ce que la section torsadée présente une forme qui ressemble à une spirale.Tables 1A and 1B show that the twisted part of the tubes according to the invention has a very small pitch, less than 3.5 millimeters, and preferably less than 3 millimeters, compared to the pitch values conventionally used in tubes with corrugations, typically greater than 20 millimeters. Consequently, the tubes according to the invention differ from conventional tubes in that the twisted section has a shape resembling a spiral.
Le tableau 2 ci-dessous rassemble des caractéristiques dimensionnelles se rapportant à un jeu d'éléments de tube (référencés I, ..., XII) présentant chacun une section centrale torsadée. Les éléments de tubes se distinguent les uns des autres par le profil de leur section torsadée respective, caractérisé par des valeurs de pas CP et de profondeur CD différentes les unes des autres. Des dimensions absentes du tableau 2 sont communes aux tubes I à XIV. En particulier, les éléments de tube présentent tous un diamètre extérieur de 22,22 millimètres et une épaisseur de paroi de 0,5 millimètre. Les tubes sont réalisés en titane grade 2.Table 2 below brings together the dimensional characteristics relating to a set of tube elements (referenced I, ..., XII) each having a twisted central section. The tube elements are distinguished from each other by the profile of their respective twisted section, characterized by values of pitch CP and depth CD different from each other. Dimensions missing from Table 2 are common to tubes I to XIV. In particular, the tube elements all have an outside diameter of 22.22 millimeters and a wall thickness of 0.5 millimeters. The tubes are made of grade 2 titanium.
Les valeurs de pas CP et de profondeur CD sont exprimées en millimètres.The CP pitch and CD depth values are expressed in millimeters.
On a fait également apparaître, dans le tableau 2, les valeurs correspondantes du rapport de forme FR, calculé pour une valeur de puissance R de 1,7.
Dans ce tableau 2, les éléments de tube II, III, sont conformes à la variante de réalisation 2. L'élément tubulaire III est par ailleurs conforme à l'exemple de réalisation 2. En outre, les éléments I, II, III, V, et VIII sont conformes à l'invention en ce qu'ils présentent des valeurs de pas CP inférieures à 3,5 millimètres et vérifient en outre les conditions COND1, COND2 et COND3.In this table 2, the tube elements II, III, are in accordance with the embodiment variant 2. The tubular element III is moreover in conformity with the example embodiment 2. In addition, the elements I, II, III, V, and VIII are in accordance with the invention in that they have CP pitch values of less than 3.5 millimeters and additionally verify the conditions COND1, COND2 and COND3.
Les éléments de tube IV et VI présentent des dimensions conformes à la variante de réalisation 2, à l'exception qu'ils ne vérifient pas les conditions COND1 à COND3.Tube elements IV and VI have dimensions in accordance with embodiment variant 2, except that they do not satisfy conditions COND1 to COND3.
L'élément de tube X vérifie les conditions COND1, COND2 et COND3 avec R = 1,7.The tube element X satisfies the conditions COND1, COND2 and COND3 with R = 1.7.
Le tableau 3 ci-dessous rassemble les résultats de mesures de capacité d'échange thermique effectuées sur les éléments du tableau 2.Table 3 below collates the results of heat exchange capacity measurements carried out on the elements in table 2.
Dans le tableau 3, le coefficient K représente une capacité d'échange thermique mesurée pour l'élément de tube considéré. Le coefficient K y est exprimé en Watt par mètres carrés et par Kelvin (W.m-2.K-1). La valeur HER, exprimée en pour cent, correspond à l'amélioration de la valeur de K pour l'élément considéré par rapport à un élément lisse présentant des dimensions analogues par ailleurs.
Le tableau 3 fait apparaître que le respect des conditions COND1, COND2 et COND3 est généralement associé à une augmentation sensible des performances d'échange thermique. Les lignes correspondant aux éléments de tube I, II, III, V, VIII, X et XII présentent des valeurs du coefficient K supérieures d'au moins 45 % à la valeur de référence pour un tube lisse (5272 W.m-2.K-1). La comparaison dans le tableau 2 des lignes VII et X d'une part, et des lignes I et XIII et XIV d'autre part, fait également apparaître une augmentation de faible importance des performances d'échange thermique dès que le rapport FR dépasse la valeur plafond de 24. Lorsque le rapport FR est supérieur à la valeur plafond, l'augmentation des performances d'échange thermique par rapport à un tube lisse est généralement inférieure à 30%.Table 3 shows that compliance with COND1, COND2 and COND3 conditions is generally associated with a significant increase in heat exchange performance. The rows corresponding to tube elements I, II, III, V, VIII, X and XII show coefficient K values at least 45% higher than the reference value for a smooth tube (5272 Wm -2 .K - 1 ). The comparison in Table 2 of lines VII and X on the one hand, and lines I and XIII and XIV on the other hand, also shows a slight increase in heat exchange performance as soon as the FR ratio exceeds the ceiling value of 24. When the FR ratio is higher than the ceiling value, the increase in heat exchange performance compared to a smooth tube is generally less than 30%.
Le tableau 3 prouve que les éléments tubulaires conformes à l'invention ont des capacités de transfert thermique grandement améliorées en comparaison des éléments lisses d'une part, et des éléments dont la section torsadée s'écarte du profil prévu par l'invention.Table 3 proves that the tubular elements in accordance with the invention have greatly improved heat transfer capacities in comparison with smooth elements on the one hand, and elements whose twisted section deviates from the profile provided by the invention.
Le tableau 4 ci-dessous rassemble les résultats de mesures réalisées sur les éléments de tube du tableau 2.Table 4 below collates the results of measurements carried out on the tube elements of table 2.
Le tableau 4 rassemble également les valeurs du coefficient dit de Darcy, ou Darcy-Weisbach, pour les tubes considérés, ainsi que l'accroissement DCR de la valeur de ce coefficient par rapport à un tube de référence lisse. Le coefficient Darcy correspond à un coefficient de perte de charge. Cette grandeur sans dimension représente l'influence du type d'écoulement (laminaire ou turbulent) et de l'aspect d'une conduite (lisse ou rugueux) sur la perte de charge. Ici, le coefficient DARCY est calculé pour un débit de 2,5 mètres cube par heure.Table 4 also collates the values of the so-called Darcy coefficient, or Darcy-Weisbach, for the tubes considered, as well as the DCR increase in the value of this coefficient relative to a smooth reference tube. The Darcy coefficient corresponds to a pressure drop coefficient. This dimensionless quantity represents the influence of the type of flow (laminar or turbulent) and the appearance of a pipe (smooth or rough) on the pressure drop. Here, the DARCY coefficient is calculated for a flow rate of 2.5 cubic meters per hour.
Une augmentation de la valeur DARCY est globalement défavorable aux performances d'un élément de tube au sein d'un condenseur. En particulier, une augmentation de la valeur DARCY implique une augmentation de la consommation énergétique nécessaire à la circulation du fluide à l'intérieur des tubes Autrement dit, l'augmentation de la valeur DARCY nuit à la condensation de la vapeur d'eau sur l'extérieur de l'élément tubulaire à consommation énergétique constante.
Le tableau 4 montre de manière générale que les tubes conformes à l'invention présentent une augmentation sensible de la valeur DARCY. Toutefois, cette augmentation reste limitée (inférieure à 140 et moindre que pour certains tubes non conformes à l'invention, comme l'indique une comparaison avec les lignes X et XII). D'autre part, l'augmentation relative du coefficient de DARCY est très faible (voisine, voire inférieure, à 100%) pour les éléments conformes à la seconde variante de réalisation (tubes II et III) et pour le tube I, en comparaison des autres tubes testés. Les tubes de la seconde variante de réalisation et le tube I présentent une augmentation de la valeur DARCY très nettement inférieure aux autres.Table 4 generally shows that the tubes in accordance with the invention exhibit a substantial increase in the DARCY value. However, this increase remains limited (less than 140 and less than for certain tubes not in accordance with the invention, as indicated by a comparison with lines X and XII). On the other hand, the relative increase in the DARCY coefficient is very low (near, or even less, to 100%) for the elements conforming to the second variant embodiment (tubes II and III) and for tube I, in comparison with the other tubes tested. The tubes of the second embodiment variant and tube I show an increase in the DARCY value which is very clearly lower than the others.
Il résulte de ce qui précède que les tubes présentant une section torsadée conforme à l'invention sont susceptibles de performances grandement améliorées en qui concerne leur capacité à faire se condenser un gaz en circulation extérieurement. Ces performances améliorées sont consécutives d'une forme de torsade qui améliore grandement les capacités d'échange thermique et limite de manière sensible les effets de perte de charge.It follows from the foregoing that the tubes having a twisted section in accordance with the invention are capable of greatly improved performance as regards their ability to condense a gas circulating externally. This improved performance is the result of a twist shape which greatly improves the heat exchange capacities and significantly limits the effects of pressure drop.
La comparaison des exemples I à II aux exemples XIII et XIV met en avant que la diminution du pas permet de diminuer la valeur DARCY mais que le respect des conditions COND1, COND2, COND3 permet d'obtenir une performance d'échange thermique améliorée.The comparison of examples I to II with examples XIII and XIV highlights that the reduction in the pitch makes it possible to reduce the DARCY value but that compliance with the conditions COND1, COND2, COND3 makes it possible to obtain an improved heat exchange performance.
En outre, les tubes conformes aux variantes de réalisation 1 à 3, et aux exemples 1 et 2, sont susceptibles de présenter des performances de condensation encore accrues du fait de capacités d'échange thermique comparables aux autres tubes selon l'invention et de pertes de charges sensiblement restreintes par rapport à ces tubes.In addition, the tubes in accordance with the variant embodiments 1 to 3, and to Examples 1 and 2, are likely to have even greater condensation performance due to heat exchange capacities comparable to the other tubes according to the invention and losses. significantly reduced loads compared to these tubes.
À partir du mode de réalisation général de l'invention, et sur la base de tests dont les résultats sont en partie au moins mentionnés dans les tableaux 2 à 3, il est considéré que les caractéristiques ci-dessous, qui sont optionnelles, complémentaires ou de substitution, sont susceptibles d'améliorer encore les performances de condensation d'un tube :
Le diamètre extérieur du tube TOD est compris entre 19 et 26 millimètres, de préférence entre 20 et 26 millimètres, et plus préférentiellement encore entre 20 et 23 millimètres. En particulier, le diamètre extérieur TOD est voisin de 19,05 millimètres, 22,22 millimètres, ou de 25,4 millimètres.From the general embodiment of the invention, and on the basis of tests whose results are at least partly mentioned in Tables 2 to 3, it is considered that the characteristics below, which are optional, complementary or substitution, are likely to further improve the condensation performance of a tube:
The outer diameter of the TOD tube is between 19 and 26 millimeters, preferably between 20 and 26 millimeters, and even more preferably between 20 and 23 millimeters. In particular, the outer diameter TOD is close to 19.05 millimeters, 22.22 millimeters, or 25.4 millimeters.
Le diamètre extérieur COD de la partie torsadée est compris entre 18 et 26 millimètres, de préférence entre 20 et 26 millimètres, plus préférentiellement encore entre 20 et 23 millimètres. En particulier, le diamètre COD est voisin de 18,90 millimètres, de 22,07 ou de 25,25 millimètres.The outer diameter COD of the twisted part is between 18 and 26 millimeters, preferably between 20 and 26 millimeters, more preferably still between 20 and 23 millimeters. In particular, the diameter COD is close to 18.90 millimeters, 22.07 or 25.25 millimeters.
Le pas CP est strictement supérieur à 2 millimètres. Il est inférieur à 3 millimètres.The pitch CP is strictly greater than 2 millimeters. It is less than 3 millimeters.
L'épaisseur TT de la paroi CW du tube est comprise entre 0,4 et 1 millimètre, par exemple de l'ordre de 0,5 millimètre.The thickness TT of the wall CW of the tube is between 0.4 and 1 millimeter, for example of the order of 0.5 millimeter.
L'invention n'est pas limitée aux modes de réalisation décrit ci-avant, mais englobe toutes les variantes que pourra envisager l'homme de l'art.The invention is not limited to the embodiments described above, but encompasses all the variants that a person skilled in the art may consider.
Claims (8)
- Industrial type condenser element (TE) comprising a tubular body (BDY) made from grade 2 titanium, designed for liquid water circulation inside, the wall (CW) of which is at least partly delimited by an inner surface (IS) and an outer surface (OS), the wall (CW) having a twisted shape on at least one segment (CS) of said body (BDY), and the inner surface (IS) having at least one groove with a shape corresponding to said wall (CW) and extending helically over said segment (CS), such that on said segment (CS), the outer surface (OS) has a diameter (COD) comprised between 18 and 30 millimetres, while the groove has a pitch (CP) of less than 3.5 millimetres and a depth (CD) such that the ratio of the pitch (CP) at a real power comprised between 1.5 and 2.5 to the depth (CD) is less than a threshold value close to 24, said depth (CD) being comprised between 0.05 millimetre and 0.6 millimetre, in particular greater than 0.15 millimetre.
- Element according to claim 1, in which the real power is close to 1.7.
- Element according to one of claims 1 and 2, in which the body (BDY) has, on at least said segment (CS), an outside diameter (COD) comprised between 18 and 26 millimetres, preferably between 20 and 26 millimetres, and even more preferentially between 20 and 23 millimetres.
- Element according to claim 3, in which the body (BDY) has, on at least said segment (CS), an outside diameter (COD) close to 18.90, 22.07 or 25.25 millimetres.
- Element according to one of the preceding claims, in which said pitch (CP) is strictly greater than 2 millimetres.
- Element according to one of the preceding claims, in which said pitch (CP) is less than 3 millimetres.
- Element according to one of the preceding claims, in which the wall (CW) has a thickness comprised between 0.4 and 1 millimetre, preferably close to 0.5 millimetre, on at least part of said segment (CS).
- Heat exchanger comprising at least one element according to one of the preceding claims
Applications Claiming Priority (2)
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FR1450439A FR3016689B1 (en) | 2014-01-20 | 2014-01-20 | IMPROVED TUBE FOR THERMAL EXCHANGER |
PCT/FR2015/050126 WO2015107314A1 (en) | 2014-01-20 | 2015-01-19 | Improved tube for a heat exchanger |
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EP3097377A1 EP3097377A1 (en) | 2016-11-30 |
EP3097377B1 true EP3097377B1 (en) | 2022-04-20 |
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EP15704060.1A Active EP3097377B1 (en) | 2014-01-20 | 2015-01-19 | Improved tube for a heat exchanger |
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US (1) | US20160341491A1 (en) |
EP (1) | EP3097377B1 (en) |
JP (1) | JP6648036B2 (en) |
KR (1) | KR20160121537A (en) |
CN (1) | CN106104190A (en) |
FR (1) | FR3016689B1 (en) |
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WO (1) | WO2015107314A1 (en) |
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EP3147619A1 (en) * | 2015-09-28 | 2017-03-29 | Siemens Aktiengesellschaft | Pipes for power plant capacitors |
CN109791023A (en) * | 2016-08-05 | 2019-05-21 | 仁诺特斯实验室有限责任公司 | The heat exchanger tube of shell and tube condenser and shell and tube condenser |
CN106855367B (en) * | 2017-02-28 | 2024-01-26 | 郑州大学 | Shell-and-tube heat exchanger with distributed inlets and outlets |
CN106679467B (en) * | 2017-02-28 | 2019-04-05 | 郑州大学 | Shell-and-tube heat exchanger with external bobbin carriage |
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2015
- 2015-01-19 RU RU2016129630A patent/RU2016129630A/en unknown
- 2015-01-19 US US15/109,239 patent/US20160341491A1/en not_active Abandoned
- 2015-01-19 EP EP15704060.1A patent/EP3097377B1/en active Active
- 2015-01-19 CN CN201580005133.0A patent/CN106104190A/en active Pending
- 2015-01-19 WO PCT/FR2015/050126 patent/WO2015107314A1/en active Application Filing
- 2015-01-19 KR KR1020167022789A patent/KR20160121537A/en not_active Application Discontinuation
- 2015-01-19 JP JP2016564420A patent/JP6648036B2/en active Active
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Also Published As
Publication number | Publication date |
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KR20160121537A (en) | 2016-10-19 |
FR3016689B1 (en) | 2016-01-15 |
JP6648036B2 (en) | 2020-02-14 |
CN106104190A (en) | 2016-11-09 |
FR3016689A1 (en) | 2015-07-24 |
US20160341491A1 (en) | 2016-11-24 |
WO2015107314A1 (en) | 2015-07-23 |
RU2016129630A (en) | 2018-01-25 |
JP2017503146A (en) | 2017-01-26 |
EP3097377A1 (en) | 2016-11-30 |
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