EP3087318A1 - Procédé de traitement de cendres provenant d'installations d'incinération d'ordures par classement par voie humide - Google Patents
Procédé de traitement de cendres provenant d'installations d'incinération d'ordures par classement par voie humideInfo
- Publication number
- EP3087318A1 EP3087318A1 EP14827784.1A EP14827784A EP3087318A1 EP 3087318 A1 EP3087318 A1 EP 3087318A1 EP 14827784 A EP14827784 A EP 14827784A EP 3087318 A1 EP3087318 A1 EP 3087318A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fraction
- residue
- screening device
- pollutants
- screening
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 24
- 238000010333 wet classification Methods 0.000 title claims abstract description 7
- 238000012216 screening Methods 0.000 claims abstract description 36
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 12
- 239000011707 mineral Substances 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- 150000002739 metals Chemical class 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims description 29
- 239000003344 environmental pollutant Substances 0.000 claims description 20
- 231100000719 pollutant Toxicity 0.000 claims description 20
- 239000002562 thickening agent Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 8
- 238000004056 waste incineration Methods 0.000 claims description 8
- 238000011144 upstream manufacturing Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 6
- 238000011085 pressure filtration Methods 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 2
- 238000006297 dehydration reaction Methods 0.000 claims description 2
- 238000005360 mashing Methods 0.000 abstract 1
- 239000002956 ash Substances 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 238000000926 separation method Methods 0.000 description 4
- -1 ferrous metals Chemical class 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000003562 lightweight material Substances 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B9/00—General arrangement of separating plant, e.g. flow sheets
- B03B9/04—General arrangement of separating plant, e.g. flow sheets specially adapted for furnace residues, smeltings, or foundry slags
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J1/00—Removing ash, clinker, or slag from combustion chambers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2900/00—Special arrangements for conducting or purifying combustion fumes; Treatment of fumes or ashes
- F23J2900/01001—Sorting and classifying ashes or fly-ashes from the combustion chamber before further treatment
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2900/00—Special arrangements for conducting or purifying combustion fumes; Treatment of fumes or ashes
- F23J2900/01005—Mixing water to ash
Definitions
- the invention relates to a method for the treatment of ash from waste incineration plants, in particular municipal waste incineration plants, by wet classification.
- Classification is understood as meaning a separation of a starting material consisting of particles with a given particle size distribution into a plurality of fractions of different particle size distribution.
- the classification serves, in particular, to separate the ashes into different proportions of pollutants.
- a method for the treatment of ash from waste incineration plant by wet classification in which the ash is mixed in a mash vessel with liquid and fed by screening a coarse fraction as a feed stream of a classification, the upstream classifier and an upstream hydrocyclone includes.
- the feed stream is separated in the classifying stage into a pollutant-free material fraction and a residual fraction loaded with pollutants, wherein the residual fraction is withdrawn as a suspension at the top of a fluidized bed produced in the upflow classifier and wherein the removed on the underside of the fluidized bed Gutfrtress is drained by a sieve.
- the Gutfr quasi-strength has a grain size between 0.25 mm and 4 mm and can be landfilled without environmental requirements or possibly also economically, z. B. be used as an aggregate in road construction.
- the residue contains particles having a particle size of less than 250 ⁇ and contains pollutants, eg. As heavy metals, organic light materials and metal oxides, which deposit as a coating on the particles.
- pollutants eg. As heavy metals, organic light materials and metal oxides, which deposit as a coating on the particles.
- the residue fraction contains some value
- Substances such as iron and non-ferrous metals.
- the residue is thickened and must be disposed of in compliance with applicable legal regulations at the expense.
- the dry weight fraction of the contaminated residue fraction is between 10% and 30% of the ash feed.
- the object of the invention is to further reduce the amount of residue which can not be utilized economically and to recover valuable substances in a pure form, which enables economic utilization.
- Ash from a waste incineration plant is mixed with liquid in a mash tank and, after screening off a coarse fraction, is fed as a feed stream to a first classification stage, where the feed stream is separated into a pollutant-free material fraction and a residual fraction contaminated with pollutants.
- the material fraction is dewatered by means of a first screening device, wherein a sieve residue with a lower particle size of more than 150 m, preferably obtained with a lower particle size of about 250 ⁇ .
- the loaded with pollutants residual fraction is separated in a second classification stage in a finely divided mineral fraction and a contaminated with pollutants residue, the residue has a grain upper limit between 20 ⁇ and 50 ⁇ .
- the finely divided mineral fraction is dewatered by means of a second screening device.
- metals are separated from the screen residue of the first screening device and / or from the screen residue of the second screening device.
- the metal deposition may relate both to the deposition of non-ferrous metals and of iron constituents which are separated from the sieve residue.
- the dewatered residue of the second screening device forms a finely divided mineral fraction without interfering ingredients that can be recycled economically.
- As valuable products also finely divided metals are obtained, which are separated by means of metal deposition from the screen residue of the first screening device and / or the second screening device.
- An advantageous embodiment of the method according to the invention provides that in the first classification stage at the top of a fluidized bed produced in a Aufstromklassierer contaminated with pollutants fraction is withdrawn as a suspension and that the Gutfr forcing deducted at the bottom of the upflow kl assierers and Entraces means of the first screening device - Sert, wherein the passage of the first sieve device is recycled to a hydrocyclone plant.
- the hydrocyclone plant is upstream of the upstream classifier.
- the hydrocyclone plant is designed so that the cyclone overflow essentially carries only particles with a particle size of less than 100 m.
- the hydrocyclone plant is operated so that the upper grain boundary of the withdrawn in the hydrocyclone overflow suspension is in a range between 60 ⁇ and 70 ⁇ .
- the hydrocyclone overflow of the hydrocyclone plant is fed together with the extracted from the upstream classifier and loaded with pollutants fraction as a residual fraction of the second classification stage.
- the hydrocyclone plant may comprise two parallel-connected hydrocyclones, the feed stream being fed to a first hydrocyclone of the hydrocyclone plant and the sieve throughput of the first screening device to the second hydrocyclone of the hydrocyclone plant.
- the cyclone overflows of the parallel
- Each hydrocyclone contains only particles which are smaller than the separating grain of the first screening device and are fed to the second classification stage.
- the separating grain is understood to mean the grain size which is roughly 50% coarse and 50% fine.
- a further advantageous embodiment of the method according to the invention provides that organic light substances are separated from the fraction loaded with pollutants from the upcurrent fraction. These include in particular fibrous materials. For example, a tumble screen can be used to separate off the organic impurities. In addition, automatic backflush filters can be used.
- the fraction is fed together with the cyclone overflow of the hydrocyclone plant of the second classification stage.
- a hydrocyclone plant which, as a multicyclone, can comprise a plurality of hydrocyclones connected in parallel.
- the mineral fraction is withdrawn as a cyclone underflow.
- the cyclone overflow carries the polluted with pollutants residue. This has a grain spectrum with a grain upper limit between 20 ⁇ and 50 ⁇ on.
- the hydrocyclone plant of the second classification stage is operated so that the residue in the cyclone overflow has a grain upper limit of about 25 ⁇ .
- the cyclone overflow of the hydrocyclone units used in the second classification stage is expediently concentrated in a thickener, which can be designed as a continuously operated sedimentation separator. Clarified liquid is withdrawn from the thickener and returned to the process as process fluid.
- the liquid return may comprise a liquid tank to which a water treatment plant is connected. As part of the water treatment at least a pH adjustment is made. From the thickener, a suspension with high solids content is withdrawn. This is then dewatered, wherein for dehydration of the residue preferably a pressure filtration is used.
- the pressure filtration can be designed, for example, as a chamber filter press or as a drum filter press.
- a significant advantage of the method according to the invention over the prior art from DE 10 201 1 013 030 A1 is that the thickener is a much lower mass flow with finely divided particles having a particle size of less than 50 ⁇ , and as a result, the downstream pressure drainage procedurally easier and can be operated with smaller apparatus.
- the ash 1 comes from a waste incineration plant, in particular a domestic waste incineration plant, and is mixed with liquid 3 in a mash tank 2 and, after screening a coarse fraction 4, is fed to a first classification stage 5.
- the coarse fraction 4 comprises a grain spectrum between 4 mm and 60 mm and can optionally be divided into two or more coarse fractions.
- the sieve devices used for this purpose can
- the classifying stage 5 comprises an upflow classifier 6 and an upstream hydrocyclone plant 7.
- the feed stream is separated in the classification stage 5 into a pollutant-free material fraction 8 and a polluted with pollutants residual fraction 9, wherein the residual fraction 9 at the top of a fluidized bed produced in the upflow classifier 6 as a suspension is withdrawn and wherein the deducted at the bottom of the fluidized bed Gutfr disorders 8 is drained by a first screening device 10.
- the Siebschreibstand 1 1 of the first screening device 10 advantageously has a lower particle size of more than 150 ⁇ on.
- the classifying stage 5 is operated so that the screen residue 1 1 of the screening device 10 has a particle size range between 250 m and 4 mm. From the sieve residue metals 12 are deposited, which can be recycled as recyclables.
- the Siebschreibstand 1 1 with a particle size range between 0.25 mm to 4 mm is pollutant-free and can be recycled economically.
- the screen passage 13 of the screening device 10 is returned to the hydrocyclone unit 7, which in the exemplary embodiment has two parallel hydrocyclones 14, 14 '.
- the feed stream is fed to a first hydrocyclone 14 of the hydrocyclone unit 7.
- the sieve passage 13 of the sieve device 10 passes as a feed into the second hydrocyclone 14 'of the hydrocyclone plant 7.
- the screen residue 1 1 of the first screening device 10 has a lower particle size of more than 150 m, preferably a lower particle size of about 250 ⁇ m.
- organic lightweight materials in particular also fibrous substances, are separated off, wherein the separation of the light substances can take place, for example, by means of a tumble screen 16.
- the residual fraction 9 is fed together with the cyclone overflows 15, 15 'to a second classification stage 17, in which the material streams are separated into a finely divided mineral fraction 18 and a residue 19 contaminated with pollutants.
- the second classification stage 17 is operated so that the residue 19 has a grain upper limit between 20 ⁇ and 50 ⁇ .
- a grain upper limit of the residue 19 of about 25 ⁇ .
- a hydrocyclone plant 20 is used, wherein the finely divided mineral fraction 18 is withdrawn as a cyclone underflow and the cyclone overflow entrained with pollutants finely divided residue 19.
- the cyclone underflow is dewatered by means of a second screening device 21, wherein metals 23 are expediently separated from the screen residue 22. It falls to a finely divided mineral value product, which has a particle size range between 20 ⁇ and 250 ⁇ .
- metals 23 fall in finely divided form, which can also be recycled as recyclables.
- the hydrocyclone plant 20 has two hydrocyclones 29, 29 'connected in parallel, the feed stream being fed to a first hydrocyclone 29 of the hydrocyclone plant 20 and the sieve passage 30 of the second screening device 21 to the second hydrocyclone 29' of the hydrocyclone plant.
- Runs 31, 31 'of the parallel-connected hydrocyclones 29, 29' are fed to a thickener 24.
- the cyclone overflow of the hydrocyclone plant 20 used in the second classification stage 17 is concentrated in the thickener 24, wherein clarified liquid 25 is withdrawn from the thickener 24 and returned to the process.
- the liquid return comprises a liquid tank 26 to which a water treatment plant is connected.
- a suspension 28 with a high solids content is withdrawn, which is subsequently dewatered by a pressure filtration 27.
- the finely divided residue has a grain spectrum with a grain upper limit between 20 ⁇ and 50 ⁇ , preferably a Kornoberalia of about 25 ⁇ is selected.
- the residue, which consists exclusively of very finely divided particles, has a large surface, at which the pollutants contained in the ash are effectively bound. Metal oxides are also deposited with the finely divided residue.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Separation Of Solids By Using Liquids Or Pneumatic Power (AREA)
- Cyclones (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL14827784T PL3087318T3 (pl) | 2013-12-23 | 2014-12-23 | Sposób obróbki popiołów ze spalarni odpadów z użyciem klasyfikacji na mokro |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102013021790 | 2013-12-23 | ||
DE102014100725.5A DE102014100725B3 (de) | 2013-12-23 | 2014-01-23 | Verfahren zur Aufbereitung von Asche aus Müllverbrennungsanlagen durch Nassklassierung |
PCT/EP2014/079260 WO2015097256A1 (fr) | 2013-12-23 | 2014-12-23 | Procédé de traitement de cendres provenant d'installations d'incinération d'ordures par classement par voie humide |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3087318A1 true EP3087318A1 (fr) | 2016-11-02 |
EP3087318B1 EP3087318B1 (fr) | 2018-12-12 |
Family
ID=52017617
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP14825112.7A Active EP3087317B1 (fr) | 2013-12-23 | 2014-12-09 | Procédé de traitement de cendres provenant d'installations d'incinération d'ordures par classification hydraulique |
EP14827784.1A Active EP3087318B1 (fr) | 2013-12-23 | 2014-12-23 | Procédé de traitement de cendres provenant d'installations d'incinération d'ordures par classement par voie humide |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP14825112.7A Active EP3087317B1 (fr) | 2013-12-23 | 2014-12-09 | Procédé de traitement de cendres provenant d'installations d'incinération d'ordures par classification hydraulique |
Country Status (6)
Country | Link |
---|---|
US (1) | US10213790B2 (fr) |
EP (2) | EP3087317B1 (fr) |
CN (1) | CN105980775B (fr) |
DE (1) | DE102014100725B3 (fr) |
PL (2) | PL3087317T3 (fr) |
WO (2) | WO2015096977A1 (fr) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DK3325167T3 (da) * | 2015-07-25 | 2020-10-12 | Tav Holdings Inc | System og fremgangsmåde til genvinding af ønskede materialer fra finpartikler i aske fra forbrændingsanlæg |
PL414609A1 (pl) * | 2015-10-29 | 2017-05-08 | Henryk Karcz | Sposób odzysku masy palnej z popiołu dennego oraz instalacja do odzysku masy palnej z popiołu |
DE102016106054A1 (de) * | 2016-04-03 | 2017-10-05 | Schauenburg Maschinen- Und Anlagen-Bau Gmbh | Verfahren und Anlage zur Aufbereitung von Asche aus Müllverbrennungsanlagen |
DE102016106053A1 (de) | 2016-04-03 | 2017-10-05 | Schauenburg Maschinen- Und Anlagen-Bau Gmbh | Verfahren und Anlage zur Aufbereitung von Asche aus Müllverbrennungsanlagen |
ES2803239T3 (es) * | 2016-05-30 | 2021-01-25 | Martin Gmbh Fuer Umwelt Und Energietechnik | Método para procesar la escoria de un dispositivo de combustión |
DE102016117741B4 (de) * | 2016-09-20 | 2019-01-24 | Schauenburg Maschinen- Und Anlagen-Bau Gmbh | Verfahren und Anlage zur Aufbereitung von Asche aus Müllverbrennungsanlagen |
CN108918367B (zh) * | 2018-06-15 | 2021-04-09 | 酒泉钢铁(集团)有限责任公司 | 一种快速识别铁矿粉中有害物质来源的检测方法 |
US20220056554A1 (en) * | 2018-12-18 | 2022-02-24 | Sepro Mineral Systems Corp. | Recovery of material from wet incinerator bottom ash |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL78361C (fr) | 1950-03-09 | |||
GB777561A (en) | 1951-12-21 | 1957-06-26 | Siteg Siebtech Gmbh | Process of continuously dehydrating muds containing recoverable minerals |
US5794791A (en) * | 1987-11-30 | 1998-08-18 | Genesis Research Corporation | Coal cleaning process |
FI93753C (fi) * | 1993-07-28 | 1995-05-26 | Ahlstroem Oy | Menetelmä ja laitteisto täyteainepitoisen materiaalin, kuten kierrätyskuidun käsittelyyn |
FI97736C (fi) * | 1995-03-07 | 1997-02-10 | Ahlstrom Machinery Oy | Menetelmä ja laitteisto täyteainepitoisen materiaalin, kuten kierrätyskuidun käsittelyyn |
US20020017224A1 (en) | 2000-05-03 | 2002-02-14 | Robert Horton | Method for the treatment of pozzolanic materials |
EP2052780B1 (fr) | 2007-10-26 | 2013-06-05 | Scherer & Kohl GmbH & Co. KG | Procédé destiné au traitement de scories |
CN101433880B (zh) * | 2008-11-07 | 2012-05-23 | 倪志群 | 一种煤灰渣分选方法 |
DE102011013030A1 (de) * | 2011-03-04 | 2012-09-06 | Alexandra Beckmann | Aufbereiten von Müllverbrennungsasche |
DE102011013033A1 (de) | 2011-03-04 | 2012-09-06 | Alexandra Beckmann | Aufbereiten von Müllverbrennungsasche |
CN102284350B (zh) * | 2011-08-01 | 2013-09-04 | 福建耀中建材实业有限公司 | 炉渣综合利用之分选分离工艺 |
AT512479B1 (de) * | 2012-02-10 | 2013-11-15 | Andritz Energy & Environment Gmbh | Verfahren zur feinstoffreduktion im rea-gips |
-
2014
- 2014-01-23 DE DE102014100725.5A patent/DE102014100725B3/de not_active Expired - Fee Related
- 2014-12-09 CN CN201480073979.3A patent/CN105980775B/zh active Active
- 2014-12-09 US US15/105,488 patent/US10213790B2/en active Active
- 2014-12-09 EP EP14825112.7A patent/EP3087317B1/fr active Active
- 2014-12-09 WO PCT/EP2014/077004 patent/WO2015096977A1/fr active Application Filing
- 2014-12-09 PL PL14825112T patent/PL3087317T3/pl unknown
- 2014-12-23 EP EP14827784.1A patent/EP3087318B1/fr active Active
- 2014-12-23 WO PCT/EP2014/079260 patent/WO2015097256A1/fr active Application Filing
- 2014-12-23 PL PL14827784T patent/PL3087318T3/pl unknown
Also Published As
Publication number | Publication date |
---|---|
PL3087318T3 (pl) | 2019-05-31 |
EP3087317A1 (fr) | 2016-11-02 |
EP3087317B1 (fr) | 2018-12-12 |
DE102014100725B3 (de) | 2014-12-31 |
WO2015096977A1 (fr) | 2015-07-02 |
CN105980775A (zh) | 2016-09-28 |
WO2015097256A1 (fr) | 2015-07-02 |
CN105980775B (zh) | 2018-07-20 |
PL3087317T3 (pl) | 2019-05-31 |
EP3087318B1 (fr) | 2018-12-12 |
US10213790B2 (en) | 2019-02-26 |
US20160310960A1 (en) | 2016-10-27 |
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