EP3081285A1 - Dispositif de mélange statique pour des matières pouvant s'écouler - Google Patents

Dispositif de mélange statique pour des matières pouvant s'écouler Download PDF

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Publication number
EP3081285A1
EP3081285A1 EP15163858.2A EP15163858A EP3081285A1 EP 3081285 A1 EP3081285 A1 EP 3081285A1 EP 15163858 A EP15163858 A EP 15163858A EP 3081285 A1 EP3081285 A1 EP 3081285A1
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EP
European Patent Office
Prior art keywords
webs
flow channel
mixing device
mixing
adjacent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP15163858.2A
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German (de)
English (en)
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EP3081285B1 (fr
Inventor
Adrian Eihozer
Daniel Altenburger
Silvano Andreoli
Alain Georg
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FLUITEC INVEST AG
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FLUITEC INVEST AG
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Priority to EP15163858.2A priority Critical patent/EP3081285B1/fr
Publication of EP3081285A1 publication Critical patent/EP3081285A1/fr
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Publication of EP3081285B1 publication Critical patent/EP3081285B1/fr
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40Mixing liquids with liquids; Emulsifying
    • B01F23/47Mixing liquids with liquids; Emulsifying involving high-viscosity liquids, e.g. asphalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/431Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
    • B01F25/4316Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor the baffles being flat pieces of material, e.g. intermeshing, fixed to the wall or fixed on a central rod
    • B01F25/43161Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor the baffles being flat pieces of material, e.g. intermeshing, fixed to the wall or fixed on a central rod composed of consecutive sections of flat pieces of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F2101/00Mixing characterised by the nature of the mixed materials or by the application field
    • B01F2101/2805Mixing plastics, polymer material ingredients, monomers or oligomers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F2215/00Auxiliary or complementary information in relation with mixing
    • B01F2215/04Technical information in relation with mixing
    • B01F2215/0413Numerical information
    • B01F2215/0418Geometrical information
    • B01F2215/0422Numerical values of angles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F2215/00Auxiliary or complementary information in relation with mixing
    • B01F2215/04Technical information in relation with mixing
    • B01F2215/0413Numerical information
    • B01F2215/0418Geometrical information
    • B01F2215/0431Numerical size values, e.g. diameter of a hole or conduit, area, volume, length, width, or ratios thereof

Definitions

  • the present invention relates to a static mixing device having a tubular, a longitudinal axis and an inner diameter having flow channel having at least one arranged in the flow channel mixing element of a length and a substantially the inner diameter of the flow channel corresponding diameter, each mixing element arranged a plurality of crosswise, with the longitudinal axis of the flow channel having an angle greater than 0 ° including webs, wherein the webs are arranged in two intersecting, a plurality of mutually parallel, mutually separated by an equal distance planes levels and in projection of the two level coulters (A, B) a projection plane lying perpendicular to the longitudinal axis (X) of the flow channel (10) has at least partially an intermediate spacing between adjacent webs.
  • Static mixers are now used in all areas of chemical engineering. A characteristic feature of static mixers is that only the liquids or gases to be mixed are moved. In contrast to dynamic mixing systems, no stirring takes place, but pumps, blowers or compressors continuously convey the media to be mixed to the mixing tube, which with the Equipped mixing elements. Static mixers can be used in many applications such as mixing of pumpable liquids, dispersing and emulsifying intoluble components, mixing reactive liquids, mixing and homogenizing plastic melts, gas-liquid contacting, mixing gases, heat exchange of viscous substances and the use as residence time with narrow residence time behavior are used, to name a few key applications.
  • a spiral mixer is known and has helically curved, sheet-like, alternating left- and right-handed plates or mixing elements that lined up with intersecting front edges divide the flow of substances to be mixed as they enter each element.
  • the flow channel is the same in shape and cross section in each of the elements.
  • the spiral mixer is used in particular for mixing in the turbulent range. In the laminar field, the spiral mixer is only partially usable because of its moderate mixing performance.
  • a special family of static mixers are the so-called X-mixers. These consist of intersecting webs or plates.
  • X-mixer On off AT 330 135 B
  • Known X-mixer has in a tube at least one mixing insert in the form of a web and slots having plate pair. In each case, the webs of a plate extend through the slots of the other plate crossing therethrough.
  • the plates are arranged inclined to one another and to the axis of the tube.
  • the supplied stream of substances to be mixed is split by the webs as a result of the inclination of the plates in terms of time and place offset into partial streams.
  • the web approaches form strong dead zones, which can unnecessarily increase the residence time and damage critical fluids.
  • the plates must be positioned with countless welds, which can lead to increased corrosion.
  • the assembly of the plates is very time consuming and therefore costly.
  • This known device is used in particular for mixing in the laminar range. In the turbulent range, it is only partially usable because of its high pressure loss.
  • CSE-X mixer The geometry known as CSE-X mixer is in CH 693 560 A5 described.
  • This patent shows a device for static mixing, consisting of a tubular housing with at least one mixing insert arranged therein in the form of a webs and slots having plate which is bent.
  • the plates Preferably, the plates have projections at the web edges and have elliptical peripheral shapes.
  • Two curved plates, each with the webs of one plate passing through the slits of the other plate, are attached to the protrusions.
  • the mixing inserts can be positioned one behind the other in the tubular housing, wherein the mixing inserts can touch directly or can also have spacings between the inserts.
  • the device can mix well with this simple geometry in all flow areas.
  • the mixing quality is determined only by the number of mixing inserts and their installation position.
  • the mixed use was known on the market especially as 4-, 6- and 8-bar construction and also has an increasing with increasing number of webs, high pressure loss.
  • EP 2 286 904 B1 shows a particularly innovative mixing device with waisted mixing bars.
  • the edge zones of the mixer are opened significantly, so that an additional reduction of the pressure loss occurs.
  • type V has a very high mixing performance with very low pressure loss.
  • Micromacromixing is the targeted use of static mixers of various geometries and nominal diameters. Basically, first a uniform pre-distribution in the macro mixer must be achieved, then in the micro mixer the best possible fine distribution is achieved.
  • the basics typically used are the CSE-X mixers.
  • static mixers have also been used as heat exchangers.
  • Static mixers are equipped with a double jacket.
  • Static mixers which are used as heat exchangers are referred to today as mixer heat exchangers.
  • a typical design is in the DE 2'808'854 described.
  • Further mixer heat exchangers are in the EP 2'113'732 .
  • Mixer heat exchangers are generally characterized by a high heat transfer capacity and at the same time a narrow residence time behavior. As a result, static mixer heat exchangers are increasingly used in reaction technology.
  • static mixer heat exchangers as reactors is detailed in the journal Chemical Engineer Technology 2005,77 , No. 6 described.
  • Static mixers with a double jacket are preferably used as residence time reactors or as dwellers.
  • the possible slim design of the mixer heat exchanger causes a tight retention time, which has a particularly positive effect on the product quality of the flowing product in the pipe.
  • a tight design also causes shorter residence times or very long mixers.
  • the residence time behavior in static mixers can be described by means of the Bodenstein number.
  • the present invention seeks to provide a static mixing device with good mixing effect and low pressure drop, which additionally has a tighter and more defined residence time behavior as known mixer.
  • the mixing device should preferably be able to be used in the laminar flow region and in the transition region and a substantially complete Ensure thorough mixing.
  • the mixing elements should be simple and inexpensive to manufacture, have a low pressure drop and mechanically stable can be assembled to mixer bars.
  • the mixing elements should be able to be positioned as short as possible as well as long designs in the flow channel.
  • the flow channel should be able to have a round, rectangular or square cross section.
  • the webs between the adjacent intersections are formed at least partially waisted and in the middle between adjacent intersections, the webs their smallest width and adjacent webs have their greatest spacing, and the inner wall of the flow channel adjacent webs between the front edge edges of the sidecut of the webs corresponding recess having the smallest width to form a largest in the middle between the front edge edges wall distance.
  • the measured over the diameter of the mixing element sum of the smallest width of the webs is at least 40% of the diameter of the mixing element.
  • the webs of the inner cross 14A, 14B have no tapered webs, so that a laminar flow profile is largely prevented.
  • the remaining waisted webs lead to the necessary pressure loss reduction.
  • the webs At the end of the webs, where an elliptical contour would form when the pipe wall touched, the webs will now only touch the pipe wall selectively, taking into account tolerances, so that the marginality is reduced to a minimum.
  • the webs are sharpened, for example, on the tube inner wall, so that the mixer rests only at small points.
  • a connection of the mixing elements, for example with a welded connection, must be ensured for stability reasons.
  • a static mixing device has a flow channel with at least one mixing element arranged in the flow channel.
  • Each mixing element has a plurality of crosswise arranged, with the longitudinal axis of the flow channel at an angle greater than 0 ° including webs. The webs between adjacent intersections are formed waisted.
  • the webs, which are adjacent to the inner wall of the flow channel, have, between frontal butt edges, a recess corresponding to the sidecut of the webs, forming a largest wall spacing in the middle between the end-side butt edges.
  • the measured over the diameter of the mixing element sum of the smallest widths of the webs can be at least 40% of the diameter of the mixing element.
  • the mixer according to the invention has a narrower residence time spectrum compared to commercially available static mixers.
  • the residence time spectrum in a static mixer is generally important. In particular, dead zones must be prevented, since the longer residence time can damage the product quality or significantly disrupt the process.
  • flows with Reynolds number> 10,000 are turbulent. This applies to static mixers as well as for the empty pipe.
  • flows with Reynolds numbers ⁇ 20 are called laminar. In between there is a transition area.
  • Fig. 5 schematically shows the turbulent and laminar flow.
  • a parabolic flow 85 is formed in the flow channel 10, which has a very poor residence time spectrum.
  • the residence time spectrum is usually measured with a Dirac impact.
  • the measurement and detection of a residence time spectrum is well known to those skilled in the art and will not be described in detail. It is also known that measuring a Dirac impact in the laminar flow regime is difficult because inlet and outlet perturbations can significantly affect the results.
  • the typical measured residence-time shifts and light tailing in the curve are characteristic of a residence time distribution in a static mixer in the laminar flow regime.
  • Fig. 6 shows in comparison the residence time distribution of a static mixer according to the patent CH 642 564 and CH 693 560 to the 1D dispersion model.
  • the Bodenstein number (also called Bo for short) is a dimensionless characteristic number from the reaction technique and describes the ratio of the convection current to the dispersion current.
  • the Bodenstein number characterizes the backmixing within a system and thus allows statements about whether and how strongly volume elements or substances within the dweller mix by the prevailing currents.
  • the Bodenstein number is usually described with the 1-d dispersion model. This model concept takes the 1-dimensional process in a flow tube (plug flow) as a starting point. In the direction z, a flow velocity u z, which is practically constant at the respective mixers cross section A is carried out.
  • the residence time cumulative curve can be used for comparison of the residence time spectra.
  • Fig. 7 shows a comparison of different mixing elements.
  • the mixer according to CH 693 560 has a relationship with the dashed curve 202, the mixer according to EP 2 286 904 B1 a ratio according to curve 201.
  • the features according to the invention make it possible with such a mixer to achieve a significantly improved residence time behavior.
  • the comparison is based on identical flow conditions, the same diameter and the same mixer lengths.
  • the resistance factor can be used as a power comparison.
  • the resistance factor of the mixer 1 is standardized at 100%.
  • the mixer decreases EP 2 286 904 B1 with 38% the worse residence time behavior than the mixer after the CH 693 560 on. It is therefore all the more surprising that the mixer according to the invention with 60% compared to the mixer after CH 693 560 a considerable one has better residence time behavior.
  • Fig. 1 shows a side view of a portion of a flow channel 10 with two adjoining mixing elements 12 with six webs according to an embodiment of the invention.
  • the following description is also based on the Fig. 2 with a view of the mixing element 12 of Fig. 1 in the flow channel 10 in the direction of the longitudinal axis of the flow channel 10; on the Fig. 3 with a plan view of web plates before welding to a mixing element 12 with webs to be joined, on the Fig. 4 with a plan view of a web plate of a mixing element 12 with six web parts before welding to a mixing element, on the Fig. 9 with a view of a web plate of a mixing element with four web parts before welding to a mixing element and finally to the Fig. 10 with a plan view of the web plates of Fig. 9 before bending to a mixing element with webs to be joined.
  • the Fig. 8 Finally, a perspective view of a mixer follows Fig. 1 ,
  • tubular flow channel 10 having a longitudinal axis x and an inner diameter D has two adjoining, a length L having identical mixing elements 12 with a substantially the inner diameter D of the flow channel 10 corresponding Umhüllungs trimmesser.
  • the two mixing elements 12 are arranged with respect to the longitudinal axis x of the flow channel 10 at an angle of 90 ° to each other rotated.
  • the mixing element 12 consists of a plurality of intersecting webs 14A, 14B.
  • the webs 14A, 14B are arranged in mutually parallel planes separated from each other by an equal distance and forming two intersecting planes A, B.
  • the two level shares A, B close with the longitudinal axis x of the flow channel an angle ⁇ of 45 ° and with each other an angle of 90 °.
  • the mixing element 12 shown by way of example in the drawing has six web layers, each with two webs 14A, 14B which intersect alternately, and thus corresponds to a 6-web mixer.
  • a common other number of bars is four or eight.
  • All webs 14A, 14B extend within the mixing element 12 via their respective maximum length which is limited by the end faces of the mixing element 12 and by the inner wall of the flow channel 10, the contour of the webs 14A, 14B close to the wall being the circular cross-section of the wall Flow channel 10 is only partially adapted so that in the near-wall webs 14A, 14B - as in the other webs - only front end portions 22 adjoin the inner wall of the flow channel 10 with little play.
  • the adjoining the inner wall of the flow channel 10 webs 14A, 14B are provided on the directed against the inner wall side with a recess 24 which extends between the end-side end portions or butt edges 22 with the inner wall of the flow channel 10 and corresponding to the waist of the webs largest Wall distance c have, which in the present case is 50% of the greatest distance between a adjacent bars 14A, 14B.
  • the webs 14A, 14B at each intended intersection point 16 a notch 18 or the notch depth of the notch 18 corresponding, a projection 20 generating cutback on.
  • the assembly of the mixing element 12 is carried out in a simple manner of two in Fig. 10 shown web plates 26 with four arranged alternately, the four in Fig. 9 shown webs 14A, 14B corresponding half webs 14A ', 14B' and the four in Fig. 9 illustrated webs 14A, 14B.
  • two web plates 26 are bent around an axis by an angle of 90 ° and in the in Fig. 1 shown connected by ends 28 of the two middle web halves 14A ', 14B' by welding together.
  • four webs 14A, 14B are placed over the notches 18 and projections 20 at the intersections 16 on the curved and welded together web plates 24 and partially welded at the intersections 16.
  • All embodiments have in common that the areas of the ends 28, which lie in known mixers in the context of the game on the inner wall of the flow tube, are cut out.
  • the cutouts can, as in Fig. 4 to recognize straight cuts 122 at the ends which leave a small end portion which further adjoins the flow tube.
  • the cutout 122 at the longest land portion is steeper than the cutout 122 at a shorter land.
  • the cutouts 122 can be seen with respect to the usual non-cutout end regions 22, the latter being shown in dashed lines. These lines 22 correspond to the inner diameter of the flow tube.
  • some cutouts 122 are concave, others have a polygonal course, for example, two sections meeting at a concave point.
  • the end region 28 may have an edge region adjoining the tube, have only one point or, as at the web 14A 'in FIG Fig. 10 bottom right, be cut from both sides, so that even the top of the convex here polygon no longer touches the wall of the flow tube.
  • Fig. 5 schematically shows the turbulent and laminar flow.
  • a parabolic flow 85 is formed in the flow channel 10, which has a very poor residence time spectrum.
  • there are very slow fluid fractions 86 at the tube edges while there are fast fluid fractions 87 in the middle.
  • a distribution results according to curve 82, while with a mixer according to the invention a distribution according to curve 81 can be achieved, in which both the edge flow and the center flow have comparable speeds.
  • the Fig. 6 shows the residence time distribution of static mixers according to CH 642 564 and CH 693 560 compared to different Bodenstein numbers according to the 1D dispersion model and the Fig. 7 shows dwell sum curves of various Mixers of the prior art and a mixer according to an embodiment of the invention. It is shown that the opening of the edge regions by recesses between the inner tube edge 22 and the web end by cutting 122 of the edge-side end regions accelerates the volume flow in the edge regions by a Mass that a high homogeneous velocity distribution as the flow 81 after Fig. 5 results. In the plan view along the longitudinal axis x, the mixing elements continue to be substantially full-surface, in particular on the main axis along the intersection 16, so that a good mixing takes place.
  • an additional lateral wall clearance is created, which is defined by the angle of the straight cuts, the depth of the concave round recesses or the depth of the polygons with a point.
  • the alternating concerns of edge regions 22 and the removed portions 122 so that there is a mixing in the edge regions.
  • FIG. 11 another embodiment is shown.
  • a mixer according to FIG. 1 an additional elongated, rod-shaped profile element 30 is arranged, which extends parallel to the longitudinal direction of the mixer and passes through it.
  • the mixer can also be penetrated by several such profile elements.
  • the at least one profile element 30 is slidably held in the mixer or firmly connected to the mixer. It is preferably made of metal.
  • the at least profile element 30 is hollow or solid, depending on the embodiment. completed formed. It preferably has a round cross-section. If it is hollow, in particular designed as a tube, it may be empty. Preferably, however, at least one temperature sensor is arranged in the tube. Alternatively or additionally, the tube may include a heat transfer medium, for example a thermal oil or water.
  • the profile element serves as a mechanical reinforcement of the mixer and / or improve the heat transfer.
EP15163858.2A 2015-04-16 2015-04-16 Dispositif de mélange statique pour des matières pouvant s'écouler Active EP3081285B1 (fr)

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EP15163858.2A EP3081285B1 (fr) 2015-04-16 2015-04-16 Dispositif de mélange statique pour des matières pouvant s'écouler

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EP15163858.2A EP3081285B1 (fr) 2015-04-16 2015-04-16 Dispositif de mélange statique pour des matières pouvant s'écouler

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EP3081285A1 true EP3081285A1 (fr) 2016-10-19
EP3081285B1 EP3081285B1 (fr) 2018-02-14

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019126535A1 (de) * 2019-10-01 2021-04-01 Bitzer Kühlmaschinenbau Gmbh Wärmeübertrager, Kälte- oder Wärmeanlage mit einem solchen Wärmeübertrager

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3932531A1 (fr) 2020-07-02 2022-01-05 Fluitec Invest AG Calorimètre à réactions continu

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3286992A (en) 1965-11-29 1966-11-22 Little Inc A Mixing device
AT330135B (de) 1973-06-06 1976-06-10 Bayer Ag Vorrichtung zum statischen mischen von stromenden medien
DE2808854A1 (de) 1977-05-31 1979-01-04 Sulzer Ag Ein mit einbauten versehener stroemungskanal fuer ein an einem indirekten austausch, insbesondere waermeaustausch beteiligtes medium
DE2839564A1 (de) 1978-09-12 1980-03-20 Hoechst Ag Vorrichtung zur waermetauschenden und mischenden behandlung von stroemenden medien
CH642564A5 (de) 1979-10-26 1984-04-30 Sulzer Ag Statische mischvorrichtung.
EP1067352A1 (fr) 1999-07-07 2001-01-10 Fluitec Georg AG Dispositif d'echange de chaleur
CH693560A5 (de) 2001-11-05 2003-10-15 Fluitec Georg Ag Statische Mischvorrichtung für fliessfähige Stoffe.
WO2008141472A1 (fr) 2007-05-24 2008-11-27 Atlas Holding Ag Canal d'écoulement pour un échangeur de chaleur mélangeur
EP2113732A1 (fr) 2008-04-30 2009-11-04 Fluitec Invest AG Mélangeur-échangeur thermique
EP2286904A1 (fr) 2009-08-12 2011-02-23 Fluitec Invest AG Dispositif de mélange statique pour matières pouvant s'écouler

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3286992A (en) 1965-11-29 1966-11-22 Little Inc A Mixing device
AT330135B (de) 1973-06-06 1976-06-10 Bayer Ag Vorrichtung zum statischen mischen von stromenden medien
DE2808854A1 (de) 1977-05-31 1979-01-04 Sulzer Ag Ein mit einbauten versehener stroemungskanal fuer ein an einem indirekten austausch, insbesondere waermeaustausch beteiligtes medium
DE2839564A1 (de) 1978-09-12 1980-03-20 Hoechst Ag Vorrichtung zur waermetauschenden und mischenden behandlung von stroemenden medien
CH642564A5 (de) 1979-10-26 1984-04-30 Sulzer Ag Statische mischvorrichtung.
EP1067352A1 (fr) 1999-07-07 2001-01-10 Fluitec Georg AG Dispositif d'echange de chaleur
CH693560A5 (de) 2001-11-05 2003-10-15 Fluitec Georg Ag Statische Mischvorrichtung für fliessfähige Stoffe.
WO2008141472A1 (fr) 2007-05-24 2008-11-27 Atlas Holding Ag Canal d'écoulement pour un échangeur de chaleur mélangeur
EP2113732A1 (fr) 2008-04-30 2009-11-04 Fluitec Invest AG Mélangeur-échangeur thermique
EP2286904A1 (fr) 2009-08-12 2011-02-23 Fluitec Invest AG Dispositif de mélange statique pour matières pouvant s'écouler
EP2286904B1 (fr) 2009-08-12 2012-04-18 Fluitec Invest AG Dispositif de mélange statique pour matières pouvant s'écouler

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ZEITSCHRIFT CHEMIE INGENIEUR TECHNIK, vol. 77, no. 6, 2005

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019126535A1 (de) * 2019-10-01 2021-04-01 Bitzer Kühlmaschinenbau Gmbh Wärmeübertrager, Kälte- oder Wärmeanlage mit einem solchen Wärmeübertrager
US11421938B2 (en) 2019-10-01 2022-08-23 Bitzer Kühlmaschinenbau Gmbh Heat exchanger, refrigeration or heating system with such a heat exchanger

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