EP2952628B1 - Tintenstrahlpapierbeschichtung - Google Patents
Tintenstrahlpapierbeschichtung Download PDFInfo
- Publication number
- EP2952628B1 EP2952628B1 EP14460083.0A EP14460083A EP2952628B1 EP 2952628 B1 EP2952628 B1 EP 2952628B1 EP 14460083 A EP14460083 A EP 14460083A EP 2952628 B1 EP2952628 B1 EP 2952628B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- paper
- ink
- chloride
- paper coating
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000576 coating method Methods 0.000 title claims description 19
- 239000011248 coating agent Substances 0.000 title claims description 15
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 18
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 12
- 239000011780 sodium chloride Substances 0.000 claims description 9
- 238000007641 inkjet printing Methods 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 229920000768 polyamine Polymers 0.000 claims description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 235000019270 ammonium chloride Nutrition 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 6
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 claims description 4
- 239000000429 sodium aluminium silicate Substances 0.000 claims description 4
- 235000012217 sodium aluminium silicate Nutrition 0.000 claims description 4
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 4
- 235000002639 sodium chloride Nutrition 0.000 claims description 3
- 238000007639 printing Methods 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- -1 vinyl acetal resin Chemical compound 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 239000011354 acetal resin Substances 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 150000003857 carboxamides Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/11—Halides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
- D21H17/56—Polyamines; Polyimines; Polyester-imides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
Definitions
- the present invention relates to a paper coating for ink-jet printing.
- Ink-jet printing a technique pioneered during the second half of twentieth century, has created a need for paper of appropriate quality.
- special coatings designed for ink acceptance during printing were applied to improve print quality.
- the aim was achieved by hydrophilic coatings applied onto paper ground, using silica gel, polyvinyl alcohol and/or carboxymethylcellulose plus low molecular weight cationic polymer (e.g. modified polyethylenimine, polyvinylamine, condensation product of organic amides with formaldehyde, polyacrylamide) [ Handbook of Paper and Board. Ed. H. Holik, WILEY-VCH Verlag GmbH & Co. KgaA, 2006, Weinheim, pp. 98-99 ].
- Patent and specialist literature provide numerous versions of ink-jet paper coatings.
- a paper ground for ink-jet printing with a cationic two-component surface coating is known from patent description US4,554,181 .
- Cationic polymers applied in that invention characterises in that the cationic groups are available for anionic component of ink dye(s).
- the other source of cations are salts of a metal from group II, III or the Transition Metals of the Periodic Table of Elements of solubility greater than 5 g in 100 ml of water at 23°C. Due to tend to colour the paper, salts of Fe 2+ , Fe 3+ and Cu 2+ are scarcely useful. It was revealed that salts of strong acids (including hydrochloric acid) are capable of insolubilising anionic ink components, but the anionic parts of the strong acids accelerate paper degradation.
- a coating for ink-jet paper is known for Japanese patent application description JP 2001315433 , which consists of 2-10 parts by weight of inorganic electrolyte (preferably sodium chloride), 0-100 parts by weight of porous absorbing material (e.g. silica particles), and up to 100 parts by weight hydrophilic or vinyl acetal resin.
- the mixture is to be prepared onto a polyethylene foil and then transferred onto a paper.
- the Polish patent application P405943 discloses a paper coating for ink-jet printing according the invention, comprising of sodium aluminosilicate, sodium chloride, polyvinyl alcohol, aliphatic polyamine and polyaluminum chloride, of hydrophilic properties, which characterises in that weight ratio of sodium chloride and polyaluminum chloride to aliphatic polyamine is 9.6 : 1.
- a paper coating for ink-jet printing according the invention comprising of sodium aluminosilicate, sodium chloride, ammonium chloride, polyvinyl alcohol, aliphatic polyamine and polyaluminum chloride, of hydrophilic properties characterises in that weight ratio of sodium chloride, ammonium chloride and polyaluminum chloride to aliphatic polyamine is 8.55 : 1.
- the coating is applied by a machine on a paper ground on one- or two-sides.
- the invention is illustrated by the following exemplary embodiment.
- Example. Water is to be poured into a mixer with a high-speed stirrer at amounts depending on demanded concentration of the coating mixture, and than the ingredients are added gradually at the indicated amounts:: Ingredient Commercial name Amount of a dry substance in g/100 g of the mixture Weight percentage of all ingredients Sodium aluminosilicate Zeocros PF 2.00 17.45% Sodium chloride evaporated salt 2.50 21.93% Ammonium chloride 3.00 26.32% Polyvinyl alcohol PVOH BP-05 3.00 26.32% Aliphatic polyamine CATIOFAST 160 0.67 5.88% Polyaluminum chloride PAX 18 0.23 2.02% Every ingredient shall be added as soon as a previous is completely dissolved in the mixture.
- a paper sheet is to be covered with the mixture with a papermaking machine or with a covering machine on one or two sides. Paper density of the produced paper is 70 - 160 g/m 2 , and coating density is 2-4 g/m 2 .
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Paper (AREA)
- Ink Jet (AREA)
Claims (2)
- Eine Papierbeschichtung für den Tintenstrahldruck gemäß der Erfindung, bestehend aus Aluminiumnatriumsilicat, Natriumchlorid, Ammoniumchlorid, Polyvinylalkohol, aliphatischen Polyaminen und Polyaluminumchlorid mit hydrophilen Eigenschaften,gekennzeichnet dadurch, dass das Gewichtsverhältnis von NatriumChlorid, Ammoniumchlorid und Polyaluminumchlorid zu den aliphatischen Polyaminen 8,55 beträgt: 1.
- Die Papierbeschichtung gemäß Anspruch 1, gekennzeichnet dadurch, dass die Mischung von einer Maschine auf einen Papieruntergrund auf einer oder beiden Seiten aufgetragen wird.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL14460083T PL2952628T3 (pl) | 2014-06-05 | 2014-11-05 | Powłoka papieru do druku strumieniowego |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL408443A PL236334B1 (pl) | 2014-06-05 | 2014-06-05 | Powłoka do druku strumieniowego nakładana jedno-lub dwustronnie na papier |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2952628A1 EP2952628A1 (de) | 2015-12-09 |
EP2952628B1 true EP2952628B1 (de) | 2017-11-22 |
Family
ID=52021150
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP14460083.0A Active EP2952628B1 (de) | 2014-06-05 | 2014-11-05 | Tintenstrahlpapierbeschichtung |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP2952628B1 (de) |
PL (2) | PL236334B1 (de) |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2756431C2 (de) * | 1977-12-17 | 1985-05-15 | Bayer Ag, 5090 Leverkusen | Amidgruppenhaltige Polyamine |
US4554181A (en) | 1984-05-07 | 1985-11-19 | The Mead Corporation | Ink jet recording sheet having a bicomponent cationic recording surface |
JP2001315433A (ja) | 2000-05-12 | 2001-11-13 | Sekisui Chem Co Ltd | 水性インク受容層用組成物及び水性インクジェットプリンター用記録材料の製造方法 |
US7144946B2 (en) * | 2002-12-19 | 2006-12-05 | Hugh McIntyre Smith | Cationic polyvinyl alcohol-containing compositions |
FR2872736B1 (fr) * | 2004-07-08 | 2006-09-22 | Eastman Kodak Co | Materiau destine a la formation d'images par impression par jet d'encre |
-
2014
- 2014-06-05 PL PL408443A patent/PL236334B1/pl unknown
- 2014-11-05 PL PL14460083T patent/PL2952628T3/pl unknown
- 2014-11-05 EP EP14460083.0A patent/EP2952628B1/de active Active
Non-Patent Citations (1)
Title |
---|
None * |
Also Published As
Publication number | Publication date |
---|---|
PL236334B1 (pl) | 2020-12-28 |
PL2952628T3 (pl) | 2018-05-30 |
EP2952628A1 (de) | 2015-12-09 |
PL408443A3 (pl) | 2015-12-07 |
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