EP2931929B1 - Legierung zur herstellung von juwelen - Google Patents
Legierung zur herstellung von juwelen Download PDFInfo
- Publication number
- EP2931929B1 EP2931929B1 EP13824341.5A EP13824341A EP2931929B1 EP 2931929 B1 EP2931929 B1 EP 2931929B1 EP 13824341 A EP13824341 A EP 13824341A EP 2931929 B1 EP2931929 B1 EP 2931929B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- gold
- alloy
- platinum
- palladium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910045601 alloy Inorganic materials 0.000 title claims description 62
- 239000000956 alloy Substances 0.000 title claims description 62
- 239000010437 gem Substances 0.000 title claims description 14
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 48
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 46
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 39
- 229910052737 gold Inorganic materials 0.000 claims description 39
- 239000010931 gold Substances 0.000 claims description 39
- 229910052697 platinum Inorganic materials 0.000 claims description 24
- 229910052763 palladium Inorganic materials 0.000 claims description 23
- 229910052751 metal Inorganic materials 0.000 claims description 20
- 239000002184 metal Substances 0.000 claims description 20
- 150000002739 metals Chemical class 0.000 claims description 16
- 229910052709 silver Inorganic materials 0.000 claims description 16
- 239000004332 silver Substances 0.000 claims description 16
- 229910052725 zinc Inorganic materials 0.000 claims description 16
- 239000011701 zinc Substances 0.000 claims description 16
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 14
- 239000010949 copper Substances 0.000 claims description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 13
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 11
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 9
- 229910052733 gallium Inorganic materials 0.000 claims description 9
- 229910052738 indium Inorganic materials 0.000 claims description 9
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052732 germanium Inorganic materials 0.000 claims description 8
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 8
- 229910052741 iridium Inorganic materials 0.000 claims description 8
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 7
- 229910052762 osmium Inorganic materials 0.000 claims description 7
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 7
- 229910052718 tin Inorganic materials 0.000 claims description 7
- 239000012535 impurity Substances 0.000 claims description 5
- 229910001751 gemstone Inorganic materials 0.000 claims description 2
- 239000010970 precious metal Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 4
- 229910001020 Au alloy Inorganic materials 0.000 description 3
- 239000003353 gold alloy Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 241000220317 Rosa Species 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- JUWSSMXCCAMYGX-UHFFFAOYSA-N gold platinum Chemical compound [Pt].[Au] JUWSSMXCCAMYGX-UHFFFAOYSA-N 0.000 description 1
- 238000005495 investment casting Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- SWELZOZIOHGSPA-UHFFFAOYSA-N palladium silver Chemical compound [Pd].[Ag] SWELZOZIOHGSPA-UHFFFAOYSA-N 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- COEZWFYORILMOM-UHFFFAOYSA-N sodium 4-[(2,4-dihydroxyphenyl)diazenyl]benzenesulfonic acid Chemical compound [Na+].OC1=CC(O)=CC=C1N=NC1=CC=C(S(O)(=O)=O)C=C1 COEZWFYORILMOM-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000010938 white gold Substances 0.000 description 1
- 229910000832 white gold Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/04—Alloys based on copper with zinc as the next major constituent
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C27/00—Making jewellery or other personal adornments
- A44C27/001—Materials for manufacturing jewellery
- A44C27/002—Metallic materials
- A44C27/003—Metallic alloys
Definitions
- the invention concerns an alloy for the production of jewels, in particular precious jewels or trinkets.
- the invention concerns jewels, produced with this alloy.
- the object of the present invention is to provide an improved alloy that overcomes the drawbacks listed above.
- the object of the present invention is mainly to propose an alloy with a low precious metal carat rating that, in addition to not oxidizing easily and having good workability, imitates the aspect and the brightness of precious metals and their alloys.
- the alloys described herein can always contain other elements, meaning elements that are not listed as components that make up the alloy, in the form of inevitable traces. These traces derive from impurities present in the raw materials or are residues of auxiliary materials used during the production or processing of the alloy. In this case, the remaining percentage needed to reach 100% by weight is constituted by copper and inevitable impurities.
- the traces are present in total quantities not exceeding 0.2% by weight.
- metals such as gallium and/or indium helps lower the melting point of the alloy.
- forming in this case silicon-free alloys are preferably used
- welding in this case indium should be preferably added
- the expert in the art thanks to his/her general knowledge of the matter, changes the percentages of the auxiliary components.
- the low carat rating of gold, platinum and palladium, respectively makes it possible to produce alloys that imitate the colours of the respective precious metals or their alloys while at the same time showing a high degree of brightness.
- the alloy is very elastic, easy to clean, polish and machine and has good lapping values, partly better than those of other alloys with higher carat rating.
- the alloy does not contain iridium, germanium, silicon, osmium, tin, indium and gallium as elements that make up the alloy.
- the alloy in any case, can contain these elements within the group consisting of traces of other elements.
- compositions that in the search for economic alloys with low precious metal carat rating have proved to be particularly suited to be used to make trinkets, because they do not oxidize easily, are easy to machine and shiny, and imitate the shades of alloys with high carat rating.
- a much preferred variant embodiment of the invention concerns an alloy comprising 4.17% by weight of a metal or a combination of metals selected among a) platinum, b) palladium, and c) platinum and palladium.
- Preferred quantities of gold are 0.2% by weight - 3.5% by weight.
- silver is present in quantities included between 8 and 10% by weight and zinc is present in quantities included between 15 and 19% by weight. Even more preferably, the quantity of silver corresponds to 8.8-9.2% by weight, the quantity of zinc to 16.8-17.2% by weight and the quantity of copper to 69.8-70.2% by weight.
- a further preferred embodiment of the alloy according to the invention is constituted by an alloy comprising 4.17% by weight of a combination of gold, palladium and platinum, in which the three metals are present in equal quantities expressed in weight percentages.
- the alloy comprises 4.17% by weight of a combination of gold and palladium or of a combination of gold and platinum, in which the two metals are present in equal quantities expressed in weight percentages.
- a very advantageous variant embodiment of the invention concerns an alloy comprising 0.5% gold by weight and preferably at least 0.1% platinum by weight. Such an alloy is extraordinarily bright.
- the alloy is consisting of 0.5% gold by weight; 12.5% silver and palladium by weight; 17% zinc by weight and 70% copper by weight wherein there is 0.1% platinum by weight which correspondingly partially replaces silver, palladium, zinc and/or copper, in accordance with the scope of the invention.
- the invention furthermore concerns a jewel, produced from an alloy according to the invention.
- Other possible items are, for example, coins, tableware, candle holders or other items of art handicraft.
- the alloy according to the invention is suited to be used in the processing cycles that are typical of the jewellery sector.
- the invention achieves the object to provide an economic alloy with low carat rating of gold, platinum and palladium that, in addition to not oxidizing easily and having good workability, imitates the appearance of gold or its alloys with high carat rating and is considerably bright.
- the production of the alloy follows the methods known in the art for producing alloys containing gold, silver, brass, etc. which are not described herein for the sake of brevity.
- Table 1 gold platinum palladium silver zinc copper [% by wt.] [% by wt.] [% by wt.] [% by wt.] [% by wt.] [% by wt.] [% by wt.] [% by wt.] Ex. 1 0,5 0 12,5 17 70 Ex. 2 0,5 0,1 0 12,4 17 70 Ex. 3 1,39 1,39 1,39 8,83 17 70 Ex. 4 2,09 2,09 0 8,83 17 70 Ex. 5 2,09 0 2,09 8,83 17 70 Ex. 6 4.17 of which 0.2-3.5 gold 8-10 15-19 rest Ex. 7 4.17 of which 0.5-1.0 gold 8-10 15-19 rest Ex. 8 4.17 of which 1.1-2.5 gold 8-10 15-19 rest Ex. 9 4.17 of which 2.6-3.5 gold 8-10 15-19 rest
- the palladium and silver content of Ex. 1 is according to the claims of the invention.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Adornments (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Medicinal Preparation (AREA)
- Saccharide Compounds (AREA)
Claims (10)
- Legierung für die Herstellung von Schmuckstücken, Folgendes umfassend: 7-16% Gewichtsanteil Silber; 15-36% Gewichtsanteil Zink; 4,17% Gewichtsanteil einer aus a) Gold und Platin, b) Gold und Palladium, und c) Gold, Platin und Palladium ausgewählten Metallkombination; 0-0,5% Gewichtsanteil eines oder mehrerer aus Iridium, Germanium, Silicium, Osmium, Zinn, Indium und Gallium ausgewählten Metalle; wobei der Rest aus Kupfer und unvermeidbaren Verunreinigungen besteht und wobei die Legierung 0,2% bis 3,5% Gewichtsanteil Gold umfasst, vorzugsweise 0,5-1% Gewichtsanteil Gold oder 1,1-2,5% Gewichtsanteil Gold oder 2,6-3,5% Gewichtsanteil Gold.
- Legierung für die Herstellung von Schmuckstücken, Folgendes umfassend: 7-16% Gewichtsanteil Silber; 15-36% Gewichtsanteil Zink; 0,1-4,17% Gewichtsanteil eines aus a) Platin, b) Palladium und c) Platin und Palladium ausgewählten Metalls oder einer daraus ausgewählten Metallkombination; 0-0,5% Gewichtsanteil eines oder mehrerer aus Iridium, Germanium, Silicium, Osmium, Zinn, Indium und Gallium ausgewählten Metalle; wobei der Rest aus Kupfer und unvermeidbaren Verunreinigungen besteht.
- Legierung gemäß Patentanspruch 2, dadurch gekennzeichnet, dass sie 4,17% Gewichtsanteil eines aus a) Platin, b) Palladium und c) Platin und Palladium ausgewählten Metalls oder einer daraus ausgewählten Metallkombination umfasst.
- Legierung gemäß Patentanspruch 1 oder 3, dadurch gekennzeichnet, dass sie kein Iridium, Germanium, Silicium, Osmium, Zinn, Indium und Gallium enthält und Silber in Mengen zwischen 8 und 10% Gewichtsanteil enthalten ist, und dadurch, dass Zink in Mengen zwischen 15 und 19% Gewichtsanteil enthalten ist.
- Legierung gemäß eines jeden der Patentansprüche 1 oder 4, dadurch gekennzeichnet, dass sie 4,17% Gewichtsanteil einer Kombination aus Gold, Palladium und Platin umfasst, in der die drei Metalle in gleichen, als Gewichtsanteile ausgedrückten Mengen enthalten sind.
- Legierung gemäß eines jeden der Patentansprüche 1 oder 4, dadurch gekennzeichnet, dass sie 4,17% Gewichtsanteil einer Kombination aus Gold und Palladium oder einer Kombination aus Gold und Platin umfasst, in der die drei Metalle in gleichen, als Gewichtsanteile ausgedrückten Mengen enthalten sind.
- Legierung für die Herstellung von Schmuckstücken, Folgendes umfassend: 7-16% Gewichtsanteil Silber; 15-36% Gewichtsanteil Zink; bis zu 4,17% Gewichtsanteil eines/einer aus a) Gold und Platin, b) Gold und Palladium, und c) Gold, Platin und Palladium ausgewählten Metalls/ Metallkombination; 0-0,5% Gewichtsanteil eines oder mehrerer aus Iridium, Germanium, Silicium, Osmium, Zinn, Indium und Gallium ausgewählten Metalle; wobei der Rest aus Kupfer und unvermeidbaren Verunreinigungen besteht, und wobei die Legierung 0,5% Gewichtsanteil Gold und vorzugsweise wenigstens 0,1% Gewichtsanteil Platin umfasst.
- Legierung gemäß Patentanspruch 7, dadurch gekennzeichnet, dass sie zu 0,5% Gewichtsanteil aus Gold, zu 12,5% Gewichtsanteil aus Silber und Palladium, zu 17% Gewichtsanteil aus Zink und zu 70% Gewichtsanteil aus Kupfer besteht, in dem 0,1% Gewichtsanteil Platin vorhanden ist, das entsprechend teilweise Silber, Palladium, Zink und/oder Kupfer ersetzt.
- Legierung gemäß eines jeden der Patentansprüche 1, 3 oder 5-8, dadurch gekennzeichnet, dass der Gewichtsanteil von 0-0,5% eines oder mehrerer Metalle aus Iridium, Germanium, Silicium und Gallium ausgewählt ist.
- Aus einer Legierung gemäß eines jeden der vorstehenden Patentansprüche hergestelltes Schmuckstück.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL13824341T PL2931929T3 (pl) | 2012-12-17 | 2013-12-16 | Stop do wytwarzania wyrobów jubilerskich |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT000335A ITVI20120335A1 (it) | 2012-12-17 | 2012-12-17 | Lega per la produzione di monili |
PCT/IB2013/002810 WO2014096938A1 (en) | 2012-12-17 | 2013-12-16 | Alloy for the production of jewels |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2931929A1 EP2931929A1 (de) | 2015-10-21 |
EP2931929B1 true EP2931929B1 (de) | 2017-06-14 |
Family
ID=47683984
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13824341.5A Active EP2931929B1 (de) | 2012-12-17 | 2013-12-16 | Legierung zur herstellung von juwelen |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP2931929B1 (de) |
ES (1) | ES2640020T3 (de) |
IT (1) | ITVI20120335A1 (de) |
PL (1) | PL2931929T3 (de) |
WO (1) | WO2014096938A1 (de) |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU523626B2 (en) * | 1979-01-18 | 1982-08-05 | Murao Shoten K.K. | (au + cu) base-ag-zn alloy |
JPS55125246A (en) * | 1979-03-19 | 1980-09-26 | Murao Shoten:Kk | Quaternary gold alloy |
JPS5695491A (en) * | 1979-12-28 | 1981-08-01 | Masatoshi Tsuda | Copper-group brazing alloy |
DE102005045477A1 (de) * | 2005-09-22 | 2007-03-29 | Qvc Handel Gmbh | Goldlegierung |
US20090317292A1 (en) * | 2008-06-20 | 2009-12-24 | Gertge Annette T | Variable karat gold alloys |
US20090317291A1 (en) * | 2008-06-20 | 2009-12-24 | Annette Gertge | Variable karat gold alloys |
KR20120080810A (ko) * | 2011-01-10 | 2012-07-18 | 이용화 | 저순도(低純度) 골드용 합금조성물 및 그것을 이용한 저순도 골드 |
KR20120081724A (ko) * | 2011-01-12 | 2012-07-20 | 이용화 | 저순도(低純度) 골드용 합금조성물 및 그것을 이용한 저순도 골드 |
KR20120083184A (ko) * | 2011-01-17 | 2012-07-25 | 이용화 | 저순도(低純度) 화이트 골드용 합금조성물 및 그것을 이용한 저순도 화이트 골드 |
KR20120085127A (ko) * | 2011-01-21 | 2012-07-31 | 이한동 | 저순도(低純度) 골드용 합금조성물 및 그것을 이용한 저순도 골드 |
-
2012
- 2012-12-17 IT IT000335A patent/ITVI20120335A1/it unknown
-
2013
- 2013-12-16 ES ES13824341.5T patent/ES2640020T3/es active Active
- 2013-12-16 EP EP13824341.5A patent/EP2931929B1/de active Active
- 2013-12-16 WO PCT/IB2013/002810 patent/WO2014096938A1/en active Application Filing
- 2013-12-16 PL PL13824341T patent/PL2931929T3/pl unknown
Also Published As
Publication number | Publication date |
---|---|
EP2931929A1 (de) | 2015-10-21 |
ITVI20120335A1 (it) | 2014-06-18 |
WO2014096938A1 (en) | 2014-06-26 |
PL2931929T3 (pl) | 2017-11-30 |
ES2640020T3 (es) | 2017-10-31 |
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