EP2914385A1 - Procédé de revêtement d'objets - Google Patents

Procédé de revêtement d'objets

Info

Publication number
EP2914385A1
EP2914385A1 EP13829035.8A EP13829035A EP2914385A1 EP 2914385 A1 EP2914385 A1 EP 2914385A1 EP 13829035 A EP13829035 A EP 13829035A EP 2914385 A1 EP2914385 A1 EP 2914385A1
Authority
EP
European Patent Office
Prior art keywords
clearcoat
film coating
film
layer
liquid rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP13829035.8A
Other languages
German (de)
English (en)
Other versions
EP2914385B1 (fr
Inventor
David Zbrodov
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zbrodov David
Original Assignee
Cardip GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cardip GmbH filed Critical Cardip GmbH
Publication of EP2914385A1 publication Critical patent/EP2914385A1/fr
Application granted granted Critical
Publication of EP2914385B1 publication Critical patent/EP2914385B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/56—Three layers or more
    • B05D7/57—Three layers or more the last layer being a clear coat
    • B05D7/574—Three layers or more the last layer being a clear coat at least some layers being let to dry at least partially before applying the next layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/56—Three layers or more
    • B05D7/58—No clear coat specified
    • B05D7/584—No clear coat specified at least some layers being let to dry, at least partially, before applying the next layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/04—Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2530/00—Rubber or the like

Definitions

  • the invention relates to a method for coating objects, in particular of vehicles and vehicle parts, a film coating which can be peeled off or sprayed over by a vehicle after use, and a vehicle provided with a film coating.
  • Non-spray coatings are also known in which coated films are applied to a substrate, for example a motor vehicle body.
  • the films can be provided with one or more coating layers on one side and can have an adhesive layer on the same or the other side, so that the film can be fixed on the substrate.
  • the films can be laminated to the substrate so that they remain fixed to the substrate.
  • CONFIRMATION COPY Composition while avoiding the spray application. It has no separate adhesive layer and no backing layer, such as a film on.
  • the substrate in particular provided with a precoating, is coated with the additional coating layer, which is applied from a thermosetting coating composition and heat-cured.
  • This method has the disadvantage that the film is difficult to peel off again.
  • the color range in this process is limited and the gloss effect often unsatisfactory.
  • lacquer system and method for producing film-like peelable, film-like coatings with uncrosslinked polymers (DE 41 10 135 A1), which proposes a sprayable, linear polymer-containing lacquer system which is intended to provide vehicles with a weatherproof coating. to protect them from corrosion and mechanical effects, but to be removable again after a certain period of time, using polymers which are used to coat films using liquid or grease-like plasticizers of the alkyd resin type applied to the object to be coated, followed by Film-forming liquid film is dried to form a film with uncrosslinked, soluble polymers, resulting in peelable films.
  • the film has little adhesive force, so that it is designed to be suitable only for short-term use as a protective cover.
  • the object of the invention is therefore to provide a method that allows a coating of objects with a greater variety of colors, matte and high gloss or even short-term color change for vehicles or parts. Disclosure of the invention
  • the vehicle is sprayed to produce a film coating.
  • a liquid rubber which is applied in several layers on the vehicle.
  • Layer by layer a "rubber film” builds up, which in the finished state can not be distinguished from a normal finish and is completely removable again without any residue.
  • This method is suitable for application to the basecoat of the vehicle.
  • This coating can be made transparent or combined with color pigments, so that matt or glossy transparent or colored coatings are achieved. The following steps are performed on the vehicle in advance:
  • the processing conditions are an air temperature of + 10 ° C or more and up to 75% relative humidity.
  • Liquid rubber is diluted at least in the ratio 1: 1 with an acrylic thinner.
  • the advantage here is the so-called “short” dilution (a few seconds to a few minutes), "long” dilution also works (several minutes).
  • the dilution fraction can also be increased to achieve an optimized viscosity.
  • the dilution ratio must be adjusted to the air pressure: higher pressure - more dilution.
  • a diluted acrylic paint can be added.
  • the diluted liquid gum is filled in a paint gun with a nozzle (for example, nozzle size of 1, 4-1, 8) or in an electric sprayer through a sieve.
  • a nozzle for example, nozzle size of 1, 4-1, 8
  • an electric sprayer through a sieve.
  • each nozzle size is conceivable, the usual nozzle sizes are between 0.6 - 1, 9 mm.
  • the air pressure should be between at least 2 bar and a maximum of 4 bar. The higher the pressure, the finer the liquid rubber is applied. At higher pressure, more dilution must be added to prevent liquid gum from dripping in the gun or in the air during spraying. This would form spider web-like particles. Excessive dilution may cause the material to run easily when applied
  • the spray-ready material will be applied to the surface.
  • the first layer will be applied relatively dry. All other layers are applied evenly wet. An indication of optimal application is that the wet surface resembles an orange peel
  • the clearcoat is preferably a scratch-resistant 2K HS clearcoat based on reflow technology. This clearcoat has high resistance to micro-scratches and chemicals. He is VOC compliant. Thereafter, the total amount in relation to the clear coat of mostly 2: 1 mixed with hardener. Up to 30% of a thinner, for example an acrylic thinner, may follow this total amount
  • Dilute transparent liquid rubber at least in the ratio 1: 1 with acrylic thinner is advantageously with the so-called “short” dilution, a “long” works as well.
  • the dilution fraction can also be increased to the to achieve optimal viscosity. Here it is important to adjust the air pressure. A higher pressure requires more dilution.
  • 11 ready-to-use colored liquid film contains 700 ml of diluted transparent liquid rubber and 300 ml of diluted acrylic paint
  • the diluted liquid gum is filled in a paint gun (for example, with a nozzle size of 1, 4-1, 8) or in an electric spray device through a sieve
  • the air pressure should be at least 2 bar and a maximum of 4 bar. The higher the pressure, the finer the liquid rubber is applied. At higher pressure, more thinner must be added so that no liquid rubber in the gun or in the air dries when spraying and forms spider web-like particles. Excessive dilution may cause the material to run easily when applied
  • 3rd embodiment a) Here, the process steps for mixing and coating with transparent liquid film and the subsequent dyeing by water-based paint are explained: ⁇ Dilute transparent liquid rubber at least in the ratio 1: 1 with acrylic thinner. It is best a "short” dilution, a “long” works as well. The dilution fraction can also be increased to achieve the optimum viscosity. Here it is important to adjust the air pressure. A higher pressure requires more dilution. • Conventionally dilute water-based paint or use diluted water-based paint
  • the air pressure should be at least 2 bar and a maximum of 4 bar. The higher the
  • the spray-ready water-based or even acrylic-based paint can be applied to the film, as in conventional painting. Once the desired opacity and color is achieved, allow the film to dry. The film can also be blown or baked.
  • the vehicle provided with the film coating according to the invention from the liquid rubber layers can additionally be sprayed with a single-layer paint.
  • a coloring of the underlying film can be achieved. But it can be a glossy or a dull one-coat paint applied.
  • the film is applied in several layers by spraying and dried, after which the single-layer lacquer is applied to the film coating, in particular sprayed on.
  • the single-layer lacquer is applied to the film coating, in particular sprayed on.
  • This embodiment has the Advantage that the seal is completed with the application of the single-coat paint, there is no additional layer (clear coat) necessary.
  • the clearcoat is designed so that it forms a compound with the film without plastic adhesion promoter.
  • the clearcoat is preferably a scratch-resistant 2K-HS-A-cryl clearcoat based on reflow technology. This clearcoat has high resistance to micro-scratches and chemicals. It is VOC compliant.
  • the clearcoat used in particular has a spray viscosity of 20 to 22 s 4 mm DIN. It can be applied with spray nozzles from 1, 2 to 1, 4 mm at pressures between 2 - 3 bar with a nozzle internal pressure of 0.7 bar.
  • the layer thickness of the dry film is 50 to 60 m.
  • the drying time is between 5 min and 24 h.
  • the clearcoats used are acid and base and pollutant resistant.
  • Hardeners in various proportions may be added, e.g. Clearcoat - Hardener Vol. 2: 1 to 3: 1.
  • the hardeners usually contain aliphatic polyisocyanates.
  • colorless additives e.g. Plasticizers
  • the additives are colorless and are used in a mixing ratio of 10 - 50% additions to the stock paint.
  • the drying time using the additives may be increased by up to 100%.
  • the coloring can be done with matt water-based paint or matt acrylic paint. For sealing the clearcoat is applied over it.
  • the coloring can also be done with a single-coat varnish. This single-layer varnish automatically seals the sprayed foil. It can be dull or shiny.
  • the liquid rubber used is a rubber-based rubber, is elastic, resistant and easy to process.
  • the rubber may be natural or synthetically produced rubber and is vulcanized.
  • additives such as vulcanization accelerators or retarders, fillers, organic solvents, antioxidants and / or antiozonants are usually added to improve durability and processability.
  • Silicone rubbers are compounds which can be converted into the rubber-elastic state and contain poly (organo) siloxanes which have groups which are accessible to crosslinking reactions.
  • the method according to the invention has a further positive benefit in addition to the aesthetic aspect: the film seals and protects the underlying basecoat against scratches, weathering, stone chips and other signs of use, whereby the value of the vehicle is maintained. Rims or other vehicle parts treated in accordance with the method are thus also protected from salts in winter.
  • the color scheme can be designed specifically to customer requirements. For example, colors, e.g. Acrylic-based paints or solvent-based paints, mixed with liquid rubber and single-coat paints. Possible are also special color designs, such as phosphorescent
  • the film can easily be removed again and a new color of the vehicle or parts can be applied by means of the method according to the invention.
  • a vehicle or part already provided with a film according to the invention can be provided with another film according to the invention without stripping off the film present.
  • the "new” film can be sprayed directly onto the existing film, for example, you could overspray a car sprayed today in “red” with “black” tomorrow.
  • FIG. 1 shows a schematic sequence of the method.
  • the surface to be treated is previously cleaned and degreased. If necessary, parts that are not to be processed are masked off.
  • liquid rubber which is diluted for better processability.
  • the liquid rubber can be dyed with color additives. At least one layer of the liquid rubber is sprayed on; a coating of four to seven layers of liquid rubber has proven to be suitable for forming a film coating. After each application, a drying phase takes place.
  • the resulting film coating is then sealed.
  • a single-coat varnish can be used to seal the liquid rubber layers.
  • the single-coat lacquer can achieve the desired result by adding colors or its formation (matt / clear).

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

L'invention concerne un procédé de revêtement d'objets, notamment de véhicules et de pièces de véhicules, un film de revêtement qui peut être enlevé du véhicule ou recouvert par projection, après son utilisation, ainsi qu'un véhicule doté de ce film de revêtement. Le film est appliqué sur le véhicule par projection. A cet effet, on utilise un caoutchouc liquide qui est appliqué sur le véhicule en plusieurs couches. Couche après couche, un "film de caoutchouc" est ainsi formé qui, lorsqu'il est terminé, ne se différencie pas d'une peinture normale et qui peut être intégralement enlevé, sans laisser de résidus. Ce "film de caoutchouc" est ensuite scellé par l'application de vernis incolores ou de vernis monocouche.
EP13829035.8A 2012-10-16 2013-10-16 Procédé de revêtement d'objets Active EP2914385B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102012020197 2012-10-16
PCT/DE2013/000603 WO2014059963A1 (fr) 2012-10-16 2013-10-16 Procédé de revêtement d'objets

Publications (2)

Publication Number Publication Date
EP2914385A1 true EP2914385A1 (fr) 2015-09-09
EP2914385B1 EP2914385B1 (fr) 2020-04-15

Family

ID=50097521

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13829035.8A Active EP2914385B1 (fr) 2012-10-16 2013-10-16 Procédé de revêtement d'objets

Country Status (5)

Country Link
EP (1) EP2914385B1 (fr)
DE (2) DE202013011985U1 (fr)
DK (1) DK2914385T3 (fr)
HU (1) HUE052296T2 (fr)
WO (1) WO2014059963A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2022083522A (ja) * 2020-11-25 2022-06-06 トヨタ自動車株式会社 塗装システム

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4110135A1 (de) 1991-03-27 1992-10-01 Windmoeller & Hoelscher Verfahren und vorrichtung zur bestimmung der von einem extruder aus einem aufgabebehaelter ueber die zeit abgezogenen menge
US6126999A (en) * 1998-04-13 2000-10-03 Tomasino; Randolf R. Urethane-acrylic rubber coating and method of forming a vehicle bed liner
US6964989B1 (en) * 1998-07-08 2005-11-15 Ashland Inc. Peelable coating composition
JP2000070839A (ja) * 1998-09-02 2000-03-07 Kansai Paint Co Ltd 一時的塗色変更工法
US7351446B2 (en) 2002-10-17 2008-04-01 E.I. Du Pont De Nemours & Company Process for the production of paint coating layers
EP2115076A2 (fr) * 2007-02-08 2009-11-11 Valspar Sourcing, Inc. Compositions de revêtement pelable

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2014059963A1 *

Also Published As

Publication number Publication date
DE202013011985U1 (de) 2014-12-08
DK2914385T3 (da) 2020-07-27
EP2914385B1 (fr) 2020-04-15
HUE052296T2 (hu) 2021-05-28
WO2014059963A1 (fr) 2014-04-24
DE102013017164A1 (de) 2014-04-17

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