EP2881477A1 - Alliage résistant à la chaleur pour la production de boîtiers d'aérosol - Google Patents
Alliage résistant à la chaleur pour la production de boîtiers d'aérosol Download PDFInfo
- Publication number
- EP2881477A1 EP2881477A1 EP13466032.3A EP13466032A EP2881477A1 EP 2881477 A1 EP2881477 A1 EP 2881477A1 EP 13466032 A EP13466032 A EP 13466032A EP 2881477 A1 EP2881477 A1 EP 2881477A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alloy
- weight
- alloys
- aerosol cans
- remainder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 50
- 239000000956 alloy Substances 0.000 title claims abstract description 50
- 239000000443 aerosol Substances 0.000 title claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 10
- 238000007792 addition Methods 0.000 claims abstract 2
- 238000005275 alloying Methods 0.000 claims abstract 2
- 229910000838 Al alloy Inorganic materials 0.000 claims description 7
- 239000011572 manganese Substances 0.000 description 18
- 241000237858 Gastropoda Species 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 10
- 239000004411 aluminium Substances 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 7
- 238000001953 recrystallisation Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 239000002966 varnish Substances 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 4
- 239000000470 constituent Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000010421 standard material Substances 0.000 description 3
- 229910000967 As alloy Inorganic materials 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 229910018176 Al—(Mn, Fe)—Si Inorganic materials 0.000 description 1
- 229910015136 FeMn Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
Definitions
- aerosol cans are manufactured either from pure aluminium or from aluminium alloys.
- 1000-series aluminium according to the European standard EN 573-3 is mostly used.
- the most common aluminium grades are EN AW 1050A having the minimum Al content of Al 99.5% and EN AW 1070A having the minimum Al content of 99.7%.
- aerosol cans are mostly made of 3000-series aluminium alloys according to the European standard EN 573-3.
- the most common aluminium alloy grades are EN AW 3102 having the Mn content of approximately 0.3% and EN AW 3207 having the Mn content of approximately 0.6%.
- aluminium and its alloys are mostly supplied in the form of slugs.
- Such slugs are manufactured in a continuous two-phase process comprising the following steps.
- the method of manufacturing aerosol cans can be described as follows:
- Aluminium alloys EN AW 3102 and EN AW 3207 offer enhanced mechanical properties (strength) and hence better rigidity and pressure resistance of finished aerosol cans. Nevertheless, the mechanical properties of these materials are changed when the cans pass through a curing oven in which polymerization of the inner varnish layer takes place.
- the curing (polymerization) temperatures of the inner varnish layers range between 210 and 255°C, the respective curing process lasting about 10 minutes. Under such temperatures, partial annealing of the can bodies occurs causing the mechanical strength of the same to decrease.
- Fig. 1 shows the temperature dependences of the strengths of the new alloys in comparison with those of standard alloys by means of a graphical representation.
- the subject matter of the present invention is a new, modified heat resistant aluminium based alloy provided for eliminating the effect of weakening the material of the cans passing through a curing oven.
- the desired enhancement of the mechanical properties of aerosol cans is achieved in comparison with standard (conventionally used) materials, along with the reduction of the wall thickness and increase of the pressure resistance of the same.
- the above favourable effect is achieved by adding an anti-recrystallization admixture formed by Zr (zirconium) for the purpose of modifying the compositions of aluminium and its alloys: EN AW 1050A, EN AW 3102, EN AW 3207.
- the alloys according to the invention have new chemical compositions with added Zr, the proportion of the new constituent ranging between 0.05 and 0.20% by weight.
- the addition of Zr gives rise to completely new alloys which cannot be categorized in the existing classes according to the standard EN 573-3. Therefore, the new alloys will be referred to as MC alloys hereinafter, namely MC1 (EN AW 1050A + Zr), MC3 (EN AW 3102 + Zr) and MC4 (EN AW 3207 + Zr).
- the compositions of the new alloys are as follows:
- the new alloys have the following chemical compositions (in percent by weight) which are optimized for the technology of production aerosol cans:
- the new alloys were compared with the known, commonly used materials.
- the outcome is graphically represented in Fig. 1 where the first standard material according to EN AW 1050A, herein specifically referred to as alloy A5, is compared with the new alloy MC1_A and the second standard material according to EN AW 3102, herein specifically referred to as alloy A3Mn, is compared with the new alloy MC3_A containing the added anti-recrystallization constituent Zr.
- the cans which were made of the above materials under the same technological conditions, had identical wall specifications.
- Table 1 shows the mechanical properties of the cans made of the above materials. During the comparison, the values of the tensile strength (Rm) of the cans measured before and after the curing oven, in which the inner varnish layer was polymerized, were evaluated. Moreover, the hardness (HB) of the input semifinished products (slugs) was measured.
- aluminium alloys A3Mn and MC3_A show that the value of the tensile strength of the latter alloy was by 27.1 MPa higher after the passage through the polymerization oven under the temperature of 255°C.
- the main advantages of the new alloys MC1, MC3 and MC4 particularly include:
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Rigid Containers With Two Or More Constituent Elements (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
HUE13466032A HUE034858T2 (en) | 2013-12-06 | 2013-12-06 | Heat-resistant alloy for aerosol containers |
EP15198382.2A EP3031941B1 (fr) | 2013-12-06 | 2013-12-06 | Alliage résistant à la chaleur pour la production de bombes aérosols |
SI201330705T SI3031941T1 (sl) | 2013-12-06 | 2013-12-06 | Toplotno odporna zlitina za izdelavo pločevink za aerosol |
ES15198381.4T ES2648668T3 (es) | 2013-12-06 | 2013-12-06 | Aleación resistente al calor para la producción de latas de aerosol |
SI201330831T SI3009524T1 (sl) | 2013-12-06 | 2013-12-06 | Toplotno odporna zlitina za izdelavo pločevink za aerosol |
EP13466032.3A EP2881477B1 (fr) | 2013-12-06 | 2013-12-06 | Alliage résistant à la chaleur pour la production de boîtiers d'aérosol |
HUE15198381A HUE035724T2 (en) | 2013-12-06 | 2013-12-06 | Heat-resistant alloy for aerosol containers |
ES13466032.3T ES2630058T3 (es) | 2013-12-06 | 2013-12-06 | Aleación resistente al calor para la producción de latas de aerosol |
EP15198381.4A EP3009524B1 (fr) | 2013-12-06 | 2013-12-06 | Alliage résistant à la chaleur pour la production de bombes aérosols |
SI201330681T SI2881477T1 (sl) | 2013-12-06 | 2013-12-06 | Toplotno odporna zlitina za izdelavo pločevink za aerosol |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13466032.3A EP2881477B1 (fr) | 2013-12-06 | 2013-12-06 | Alliage résistant à la chaleur pour la production de boîtiers d'aérosol |
Related Child Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15198382.2A Division EP3031941B1 (fr) | 2013-12-06 | 2013-12-06 | Alliage résistant à la chaleur pour la production de bombes aérosols |
EP15198382.2A Division-Into EP3031941B1 (fr) | 2013-12-06 | 2013-12-06 | Alliage résistant à la chaleur pour la production de bombes aérosols |
EP15198381.4A Division-Into EP3009524B1 (fr) | 2013-12-06 | 2013-12-06 | Alliage résistant à la chaleur pour la production de bombes aérosols |
EP15198381.4A Division EP3009524B1 (fr) | 2013-12-06 | 2013-12-06 | Alliage résistant à la chaleur pour la production de bombes aérosols |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2881477A1 true EP2881477A1 (fr) | 2015-06-10 |
EP2881477B1 EP2881477B1 (fr) | 2017-03-29 |
Family
ID=49955876
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15198382.2A Active EP3031941B1 (fr) | 2013-12-06 | 2013-12-06 | Alliage résistant à la chaleur pour la production de bombes aérosols |
EP13466032.3A Active EP2881477B1 (fr) | 2013-12-06 | 2013-12-06 | Alliage résistant à la chaleur pour la production de boîtiers d'aérosol |
EP15198381.4A Active EP3009524B1 (fr) | 2013-12-06 | 2013-12-06 | Alliage résistant à la chaleur pour la production de bombes aérosols |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15198382.2A Active EP3031941B1 (fr) | 2013-12-06 | 2013-12-06 | Alliage résistant à la chaleur pour la production de bombes aérosols |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15198381.4A Active EP3009524B1 (fr) | 2013-12-06 | 2013-12-06 | Alliage résistant à la chaleur pour la production de bombes aérosols |
Country Status (4)
Country | Link |
---|---|
EP (3) | EP3031941B1 (fr) |
ES (2) | ES2648668T3 (fr) |
HU (2) | HUE035724T2 (fr) |
SI (3) | SI3031941T1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3075875A1 (fr) * | 2015-04-03 | 2016-10-05 | Talum d.d. Kidricevo | Alliage d'aluminium pour bombes aérosol fabriqué par l'extrusion par percurssion et procédé de préparation de celui-ci |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102018215254A1 (de) * | 2018-09-07 | 2020-03-12 | Neuman Aluminium Austria Gmbh | Aluminiumlegierung, Halbzeug, Dose, Verfahren zur Herstellung eines Butzen, Verfahren zur Herstellung einer Dose sowie Verwendung einer Aluminiumlegierung |
DE102018215243A1 (de) * | 2018-09-07 | 2020-03-12 | Neumann Aluminium Austria Gmbh | Aluminiumlegierung, Halbzeug, Dose, Verfahren zur Herstellung eines Butzen, Verfahren zur Herstellung einer Dose sowie Verwendung einer Aluminiumlegierung |
SG11202102944WA (en) * | 2018-10-12 | 2021-04-29 | Jt Int Sa | Aerosol generation device and heating chamber therefor |
EP3940099A1 (fr) * | 2020-07-16 | 2022-01-19 | Envases Metalúrgicos De Álava, S.A. | Alliages d'aluminium pour la fabrication de boîtes d'aluminium par extrusion par percussion |
EP3940100A1 (fr) | 2020-07-16 | 2022-01-19 | Envases Metalúrgicos De Álava, S.A. | Alliages d'aluminium pour la fabrication de boîtes d'aluminium par extrusion par percussion |
EP3940098A1 (fr) * | 2020-07-16 | 2022-01-19 | Envases Metalúrgicos De Álava, S.A. | Alliages d'aluminium pour la fabrication de canettes d'aluminium par extrusion par percussion |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6543636B1 (en) * | 1998-02-26 | 2003-04-08 | Cebal, S.A. | Method for making an aerosol housing with threaded neck |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2873717B1 (fr) * | 2004-07-27 | 2006-10-06 | Boxal France Soc Par Actions S | Procede de fabrication de boitiers d'aerosols. |
-
2013
- 2013-12-06 EP EP15198382.2A patent/EP3031941B1/fr active Active
- 2013-12-06 ES ES15198381.4T patent/ES2648668T3/es active Active
- 2013-12-06 HU HUE15198381A patent/HUE035724T2/en unknown
- 2013-12-06 SI SI201330705T patent/SI3031941T1/sl unknown
- 2013-12-06 EP EP13466032.3A patent/EP2881477B1/fr active Active
- 2013-12-06 HU HUE13466032A patent/HUE034858T2/en unknown
- 2013-12-06 SI SI201330681T patent/SI2881477T1/sl unknown
- 2013-12-06 EP EP15198381.4A patent/EP3009524B1/fr active Active
- 2013-12-06 SI SI201330831T patent/SI3009524T1/sl unknown
- 2013-12-06 ES ES13466032.3T patent/ES2630058T3/es active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6543636B1 (en) * | 1998-02-26 | 2003-04-08 | Cebal, S.A. | Method for making an aerosol housing with threaded neck |
Non-Patent Citations (1)
Title |
---|
"ASM Speciality Handbook - Aluminium and Aluminium Alloys", 1 December 1993, ASM INTERNATIONAL, USA, ISBN: 0-87170-496-X, pages: 21 - 21, XP002728368 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3075875A1 (fr) * | 2015-04-03 | 2016-10-05 | Talum d.d. Kidricevo | Alliage d'aluminium pour bombes aérosol fabriqué par l'extrusion par percurssion et procédé de préparation de celui-ci |
Also Published As
Publication number | Publication date |
---|---|
EP3031941B1 (fr) | 2017-07-05 |
HUE034858T2 (en) | 2018-03-28 |
HUE035724T2 (en) | 2018-05-28 |
ES2648668T3 (es) | 2018-01-05 |
EP2881477B1 (fr) | 2017-03-29 |
ES2630058T3 (es) | 2017-08-17 |
SI2881477T1 (sl) | 2017-08-31 |
SI3009524T1 (sl) | 2017-12-29 |
EP3009524B1 (fr) | 2017-10-11 |
SI3031941T1 (sl) | 2017-09-29 |
EP3009524A1 (fr) | 2016-04-20 |
EP3031941A1 (fr) | 2016-06-15 |
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