EP2864676A1 - Dispositif d'etancheite a l'arret passif pour systeme de joints d'arbre d'un groupe motopompe primaire - Google Patents
Dispositif d'etancheite a l'arret passif pour systeme de joints d'arbre d'un groupe motopompe primaireInfo
- Publication number
- EP2864676A1 EP2864676A1 EP13744618.3A EP13744618A EP2864676A1 EP 2864676 A1 EP2864676 A1 EP 2864676A1 EP 13744618 A EP13744618 A EP 13744618A EP 2864676 A1 EP2864676 A1 EP 2864676A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- pump unit
- sealing ring
- separator
- primary pump
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D29/00—Details, component parts, or accessories
- F04D29/08—Sealings
- F04D29/10—Shaft sealings
- F04D29/14—Shaft sealings operative only when pump is inoperative
- F04D29/146—Shaft sealings operative only when pump is inoperative especially adapted for liquid pumps
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D27/00—Control, e.g. regulation, of pumps, pumping installations or pumping systems specially adapted for elastic fluids
- F04D27/001—Testing thereof; Determination or simulation of flow characteristics; Stall or surge detection, e.g. condition monitoring
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D27/00—Control, e.g. regulation, of pumps, pumping installations or pumping systems specially adapted for elastic fluids
- F04D27/008—Stop safety or alarm devices, e.g. stop-and-go control; Disposition of check-valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D29/00—Details, component parts, or accessories
- F04D29/08—Sealings
- F04D29/10—Shaft sealings
- F04D29/12—Shaft sealings using sealing-rings
- F04D29/126—Shaft sealings using sealing-rings especially adapted for liquid pumps
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D7/00—Pumps adapted for handling specific fluids, e.g. by selection of specific materials for pumps or pump parts
- F04D7/02—Pumps adapted for handling specific fluids, e.g. by selection of specific materials for pumps or pump parts of centrifugal type
- F04D7/08—Pumps adapted for handling specific fluids, e.g. by selection of specific materials for pumps or pump parts of centrifugal type the fluids being radioactive
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16J—PISTONS; CYLINDERS; SEALINGS
- F16J15/00—Sealings
- F16J15/16—Sealings between relatively-moving surfaces
- F16J15/164—Sealings between relatively-moving surfaces the sealing action depending on movements; pressure difference, temperature or presence of leaking fluid
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16J—PISTONS; CYLINDERS; SEALINGS
- F16J15/00—Sealings
- F16J15/16—Sealings between relatively-moving surfaces
- F16J15/32—Sealings between relatively-moving surfaces with elastic sealings, e.g. O-rings
- F16J15/3204—Sealings between relatively-moving surfaces with elastic sealings, e.g. O-rings with at least one lip
- F16J15/3208—Sealings between relatively-moving surfaces with elastic sealings, e.g. O-rings with at least one lip provided with tension elements, e.g. elastic rings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16J—PISTONS; CYLINDERS; SEALINGS
- F16J15/00—Sealings
- F16J15/16—Sealings between relatively-moving surfaces
- F16J15/32—Sealings between relatively-moving surfaces with elastic sealings, e.g. O-rings
- F16J15/3204—Sealings between relatively-moving surfaces with elastic sealings, e.g. O-rings with at least one lip
- F16J15/3208—Sealings between relatively-moving surfaces with elastic sealings, e.g. O-rings with at least one lip provided with tension elements, e.g. elastic rings
- F16J15/3212—Sealings between relatively-moving surfaces with elastic sealings, e.g. O-rings with at least one lip provided with tension elements, e.g. elastic rings with metal springs
Definitions
- the field of the invention is that of the primary pump units of pressurized water nuclear reactors (PWRs).
- PWRs pressurized water nuclear reactors
- the invention relates to a passive off-line seal (DEA) for controlling a primary coolant leak resulting from the failure of the seal system present on the primary pump unit.
- DEA passive off-line seal
- DEA Shut-off devices
- shut-off devices In this acci- dent situation and after stopping the primary pump, the shut-off devices must be able to control and stop a leakage of the primary coolant resulting from the failure of the seal system. of the primary pump unit.
- this type of device is activated by an auxiliary source (such as for example a pressurized nitrogen circuit) and the triggering is controlled by information delivered by the control command of the reactor, in case of loss of the cooling sources of the reactor.
- auxiliary source such as for example a pressurized nitrogen circuit
- the described sealing device is a bulky device and its mounting in a joint system of a primary pump unit is relatively complex.
- the invention aims to propose an improvement of such a sealing device to reduce its size and thus its mounting on the shaft seal systems of primary pump units in service.
- a passive shutdown seal device for a primary pump unit shaft seal system comprising:
- a split seal ring having an inactivated position and an activated position
- a separator made of a fusible material capable of changing state from a temperature threshold, called a change of state threshold, said separator keeping said sealing ring split in its inactivated position when the temperature of the device is less than the change of state temperature threshold;
- said device being characterized in that said device comprises circular elastic means positioned around the split sealing ring, said resilient means being adapted to bring said sealing ring into its activated position when the temperature is greater than or equal to the threshold value of change of state of said separator.
- change of state is intended to mean a modification of the mechanical characteristics of the fusible material.
- the invention it is possible to stop a leakage of the primary coolant resulting from the failure of the seal system of the primary pump unit without the need for an auxiliary source of activation.
- the design of the device according to the invention allows a simplified implementation on the architectures of the primary pump units already in service.
- the device according to the invention it is also possible to adjust the device to the operating constraints of each type of nuclear reactor by adjusting the self-activation temperature of the device, and more specifically by modifying the composition. of the fuse element.
- first temperature change threshold of the material from which the fuse material separator changes state that is to say that its mechanical characteristics change
- a temperature threshold of activation of the DEA device which may be different and greater than the temperature of the change of state threshold, from which the separator is no longer able to withstand the force exerted by the elastic means, thus bringing the ring of sealing in its activated position.
- said elastic means bring said sealing ring into its activated position when the temperature is greater than or equal to the value of an activation threshold of the device, the temperature of the activation threshold being greater than the temperature of the threshold of change; state;
- said device is adapted to be integrated on a system of joints of a primary pump unit shaft in use;
- split seal ring is made of polymer resistant to temperatures above 300 ° C .
- split seal ring is made of polyetheretherketone, or polyetheretherketone matrix composite loaded with glass or carbon fibers;
- said circular elastic means exert a compressive force on said sealing ring;
- said sealing ring comprises a peripheral annular groove adapted to receive said circular elastic means;
- said separator made of a fusible material is adapted to mechanically withstand the force exerted by the elastic means to a temperature threshold of between 80 ° C and 260 ° C, preferably equal to 150 ° C;
- said separator and the sealing ring are in one piece.
- said separator may be formed by a part independent of the sealing ring and attached at the opening of the ring by fixing means.
- the subject of the invention is also a primary pump unit comprising:
- a seal system adapted to achieve a controlled leak established along a leak path arranged along the shaft of the primary pump unit;
- a passive stopping device adapted to at least partially close said leakage path of said seal system when said seal system fails and when said sealing ring is brought into its activated position by said seal system; circular elastic means, so as to achieve a controlled leak.
- FIG. 1 illustrates a partial view of a joint system of a primary pump unit
- FIG. 2 illustrates a sectional view of a passive stopping device according to the invention in its rest position integrated in a seal system of a primary pump unit, as partially shown in Figure 1;
- - Figure 3 illustrates a sectional view of a passive stop device according to the invention in its activated position, integrated in a joint system of a primary pump unit, as partially shown in Figure 1;
- FIG. 4 illustrates a perspective view of the sealing ring of the stop device according to the invention
- FIG. 5 is a detail view at the slot of the sealing ring of the stop device according to the invention.
- FIG. 6 is a detail view at the slot of the sealing ring of a second embodiment of the stop device according to the invention
- the primary pumps of pressurized water reactors are centrifugal type with vertical axis.
- the dynamic sealing at the shaft outlet 10 (FIG. 1) is ensured by a joint system consisting of three stages.
- the first floor is called seal n ° 1.
- the seal No. 1, referenced J1 is a hydrostatic seal leak controlled. In normal operation, a leakage flow, illustrated by the arrow F1, is established along the shaft 10.
- Figure 1 shows more particularly the leakage path F1 along the shaft 10 between the seal No. 1 J1 and the seal No. 2 (referenced J2) located upstream of the seal No. 1.
- the DEA device 20 according to the invention is positioned on the escape path F1 and more precisely at the zone represented by the reference Z, so as to block the flow of the leakage flow along the shaft 10 during an accidental situation.
- FIG. 2 more particularly illustrates a sectional view of the sealing device 20 according to the invention during normal operating conditions of the primary pump unit, that is to say when the temperature of the leakage flow rate is less than a value. predetermined threshold.
- Figure 3 illustrates a sectional view of the sealing device in its activated position, that is to say during accident situations of operation of the primary pump unit.
- the stationary sealing device 20 according to the invention comprises:
- the stop seal 20 may further comprise a first contact ring 24 arranged between the bushing 15 of the seal No. 1 and the split seal ring 23 and a second contact ring 26. positioned in contact with the split seal ring 23 and adapted to come into contact with the support piece of the floating crew of seal No. 1.
- the first contact ring 24 is made of steel or nickel alloy.
- the second contact ring 26 has a chromed face in contact with the sealing ring 23.
- the chromed coating of the face in contact with the sealing ring 23 makes it possible to reduce the coefficient of friction between the ring 23 and the second ring 26. Indeed, in case of stopping pumps by loss of power (SBO), the stop device 20 can be triggered by increasing the temperature before the pump shaft is completely stopped. Such a chromed coating therefore makes it possible not to damage the second sealing ring 26.
- the sealing ring 23 has a peripheral groove 25 on its outer circumference whose shape and dimensions are adapted to receive the elastic means 22.
- the split sealing ring 23 is maintained in its inactivated position, as shown in FIGS. 1 and 4, by means of the fusible separator 27.
- the fusible separator 27 is made of a polymer material advantageously chosen according to its temperature of 25.degree. degradation and its loss of mechanical characteristics.
- the separator 27 is characterized so as to be able to withstand the force exerted by the elastic means 22 to a temperature threshold of between 80 ° C. and 260 ° C. and advantageously equal to 150 ° C.
- the fusible separator 27 is in the form of a beam capable of keeping the two ends of the split sealing ring 23 (inactivated position) in the separated position during the normal operation of the primary motor pump unit.
- the sealing ring 23 is kept back from the escape path F1.
- the split sealing ring 23 is locked in this position by the fusible separator 27.
- the increase in the temperature of the leakage flow has the effect of increasing the temperature in the vicinity of the device. 20, and in particular the temperature of the fusible separator 27.
- said threshold state change predefined according to the nature of the fusible separator 27, it is degraded instantly or gradually no longer ensuring sufficient strength to withstand the stress circumferential compression generated by the elastic means 22.
- the loss of the mechanical characteristics of the fusible separator, and in particular the fall of the flexural modulus occurs when the temperature is greater than the glass transition temperature of the material in which the fusible separator 27 is realized.
- a first temperature change threshold of the material from which the fusible separator 27 has initiated a change of state that is to say that its mechanical characteristics are modified
- an activation temperature threshold of the device DEA from which the fusible separator 27 collapses because it is no longer able to withstand the force exerted by the elastic means 22, thereby causing the sealing ring 23 in its activated position.
- the triggering of the device 20 corresponding to the exceeding of the state change threshold of the fusible separator 27 and the activation of the device are combined.
- the losses of the mechanical characteristics are almost instantaneous.
- the activation of the device 20 operates in an off-set manner with respect to the triggering of the device by the exceeding of the change of state temperature threshold.
- the losses of the mechanical characteristics are progressive and lead to a collapse of the fusible separator 27 at a different time and / or at a temperature higher than the temperature of the change of state threshold.
- Fusible separator 27 advantageously has notches 28, or zones having a thinning of material, capable of guiding the flaming and deformation of fusible separator 27.
- Such notches 28 allow for example to guide the deformation of the separator in the direction axial or in the radial direction of the sealing ring 23
- the notches 28 are machined at the center and at the ends of the fusible separator 27.
- a free space in the vicinity of the fusible separator so as not to interfere with the deformation of the fusible separator 27. separator. This space may be for example a notch (not shown) in the bushing January 1 seal 1 facing the circumferential position of the fusible separator 27 in the case of a radial deformation of the fusible separator 27.
- the force exerted by the elastic means 22, encircling the sealing ring 23, modifies the diameter of the sealing ring 23 in such a way that that it comes to tighten against the shaft of the rotor 10.
- the sealing ring 23 ensures the blocking of the escape path F1 by virtue of the circumferential force exerted by the elastic means 22 combined with the loss of the mechanical characteristics of the separator no longer ensuring its separation function. .
- the blocking of the leak is ensured in addition by the autoclave effect induced by the increase of the pressure upstream of the sealing device 20 in the activated position.
- the sealing ring 23 of the stop device 20 may be made of a polymer material resistant to high temperatures (ie greater than 300 ° C.), such as, for example, lyetheretherketone (PEEK) or a PEEK composite filled with glass or carbon fibers.
- PEEK lyetheretherketone
- the fusible separator 27 is of the same nature as the body of the sealing ring 23 and is advantageously monobloc.
- the fuse separator 127 is formed by an independent piece (ie not a single piece) of the sealing ring 123 which is attached at the level of the opening of the ring. 123.
- Such a configuration makes it possible to produce the fusible separator 127 in a material of a different nature from the material used by the embodiment of the sealing ring 123 and which also has a loss of mechanical characteristics sufficient to trigger and activate the device from a given temperature threshold.
- the fusible separator 127 may be made of PEEK loaded with carbon fiber and the sealing ring 123 may be made of graphite.
- This second embodiment makes it possible to simplify the design of the sealing ring 123 as well as the achievement of a covering at the level of the opening of the ring 123 in order to reinforce the effectiveness of the seal. chéotti.
- the fusible splitter 127 assembly on the sealing ring 123 can be made by various methods; preferentially, the assembly is of the type mortise and tenon.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
- Sealing Devices (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1256005A FR2992392B1 (fr) | 2012-06-25 | 2012-06-25 | Dispositif d’etancheite a l’arret passif pour systeme de joints d’arbre d’un groupe motopompe primaire |
| PCT/FR2013/051473 WO2014001702A1 (fr) | 2012-06-25 | 2013-06-25 | Dispositif d'etancheite a l'arret passif pour systeme de joints d'arbre d'un groupe motopompe primaire |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2864676A1 true EP2864676A1 (fr) | 2015-04-29 |
Family
ID=46785670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP13744618.3A Withdrawn EP2864676A1 (fr) | 2012-06-25 | 2013-06-25 | Dispositif d'etancheite a l'arret passif pour systeme de joints d'arbre d'un groupe motopompe primaire |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20150192142A1 (fr) |
| EP (1) | EP2864676A1 (fr) |
| JP (1) | JP2015528896A (fr) |
| KR (1) | KR20150032300A (fr) |
| CN (1) | CN104620027A (fr) |
| BR (1) | BR112014032566A2 (fr) |
| CA (1) | CA2877212A1 (fr) |
| FR (1) | FR2992392B1 (fr) |
| IN (1) | IN2014DN11210A (fr) |
| RU (1) | RU2015102015A (fr) |
| WO (1) | WO2014001702A1 (fr) |
| ZA (1) | ZA201409510B (fr) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6021674B2 (ja) * | 2012-09-28 | 2016-11-09 | 三菱重工業株式会社 | 軸シール構造及び一次冷却材循環ポンプ |
| KR101548866B1 (ko) * | 2014-05-14 | 2015-09-01 | 한국수력원자력 주식회사 | 원자로 냉각재 펌프의 피동형 질소주입장치 |
| CN105240309B (zh) * | 2014-11-19 | 2017-11-17 | 中广核工程有限公司 | 核反应堆冷却剂泵及其非能动停车密封组件 |
| DE202015100048U1 (de) * | 2015-01-08 | 2016-04-11 | Krones Ag | Dichtring |
| CN104976150B (zh) * | 2015-07-16 | 2017-11-17 | 中广核工程有限公司 | 核反应堆冷却剂泵及其非能动停车密封装置 |
| CN108368939B (zh) * | 2015-11-30 | 2020-12-04 | 瓦锡兰斯万霍有限公司 | 静态轴密封装置 |
| CN107100882B (zh) * | 2017-05-16 | 2019-04-16 | 中广核工程有限公司 | 核反应堆冷却剂泵及其非能动停车密封装置 |
| JP6764381B2 (ja) * | 2017-08-24 | 2020-09-30 | 三菱重工業株式会社 | 軸シール構造および一次冷却材循環ポンプ |
| JP2019173889A (ja) * | 2018-03-29 | 2019-10-10 | 三菱重工業株式会社 | 多段軸シール装置及び回転機械 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4105040A (en) * | 1977-06-27 | 1978-08-08 | Chester Arnold M | Temperature responsive valve seal |
| US5171024A (en) * | 1988-05-23 | 1992-12-15 | Westinghouse Electric Corp. | Reactor coolant pump shaft seal utilizing shape memory metal |
| DE19653580B4 (de) * | 1996-12-20 | 2006-03-16 | Richard Wolf Gmbh | Dichtung für die Welle eines sterilisierbaren Drehantriebes für medizinische Werkzeuge und Instrumente |
| JP3440777B2 (ja) * | 1997-09-10 | 2003-08-25 | 株式会社日立製作所 | セグメント型軸封装置及びそれを備えた排水ポンプ |
| JPH11280910A (ja) * | 1998-03-30 | 1999-10-15 | Senshin Zairyo Riyo Gas Generator Kenkyusho:Kk | 円筒面シール装置 |
| US20030057655A1 (en) * | 2001-09-24 | 2003-03-27 | Siemens Westinghouse Power Corporation | Environmentally-reactive seal and associated method |
| CA2551014A1 (fr) * | 2003-12-22 | 2005-07-14 | E.I. Du Pont De Nemours And Company | Structure d'etancheite multicouche |
| CN2674209Y (zh) * | 2003-12-24 | 2005-01-26 | 天津渤海化工有限责任公司天津碱厂 | 一种压缩机气缸密封填料装置 |
| GB2417298B (en) * | 2004-08-21 | 2008-12-24 | Alstom Technology Ltd | Sealing arrangement |
| US20070172367A1 (en) * | 2006-01-26 | 2007-07-26 | Janocko David J | Flow restricting devices in pumps |
| US8356972B2 (en) * | 2008-12-10 | 2013-01-22 | Westinghouse Electric Company Llc | Thermally activated shutdown seals for rotatable shafts |
| JP2010265995A (ja) * | 2009-05-15 | 2010-11-25 | Nok Corp | 密封装置 |
| US8690534B1 (en) * | 2009-06-08 | 2014-04-08 | Curtiss-Wright Electro-Mechanical Corporation | Backup seals in rotary pumps |
| FR2986300B1 (fr) * | 2012-02-01 | 2014-03-07 | Jeumont Systemes De Pompes Et De Mecanismes | Dispositif d'etancheite a l'arret passif pour systeme de joints d'arbre d'un groupe motopompe primaire |
| US9217441B2 (en) * | 2013-08-20 | 2015-12-22 | Westinghouse Electric Company Llc | Pump seal with thermal retracting actuator |
| US9206812B2 (en) * | 2013-03-13 | 2015-12-08 | Westinghouse Electric Company Llc | Pump seal with thermal retracting actuator |
| US9206791B2 (en) * | 2013-03-13 | 2015-12-08 | Westinghouse Electric Company Llc | Pump seal with thermal retracting actuator |
-
2012
- 2012-06-25 FR FR1256005A patent/FR2992392B1/fr not_active Expired - Fee Related
-
2013
- 2013-06-25 US US14/409,836 patent/US20150192142A1/en not_active Abandoned
- 2013-06-25 CN CN201380033642.5A patent/CN104620027A/zh active Pending
- 2013-06-25 JP JP2015517834A patent/JP2015528896A/ja active Pending
- 2013-06-25 WO PCT/FR2013/051473 patent/WO2014001702A1/fr not_active Ceased
- 2013-06-25 KR KR20157001350A patent/KR20150032300A/ko not_active Withdrawn
- 2013-06-25 BR BR112014032566A patent/BR112014032566A2/pt not_active IP Right Cessation
- 2013-06-25 EP EP13744618.3A patent/EP2864676A1/fr not_active Withdrawn
- 2013-06-25 CA CA2877212A patent/CA2877212A1/fr not_active Abandoned
- 2013-06-25 RU RU2015102015A patent/RU2015102015A/ru not_active Application Discontinuation
-
2014
- 2014-12-23 ZA ZA2014/09510A patent/ZA201409510B/en unknown
- 2014-12-30 IN IN11210DEN2014 patent/IN2014DN11210A/en unknown
Non-Patent Citations (2)
| Title |
|---|
| None * |
| See also references of WO2014001702A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US20150192142A1 (en) | 2015-07-09 |
| ZA201409510B (en) | 2016-09-28 |
| JP2015528896A (ja) | 2015-10-01 |
| CN104620027A (zh) | 2015-05-13 |
| FR2992392A1 (fr) | 2013-12-27 |
| RU2015102015A (ru) | 2016-08-20 |
| WO2014001702A1 (fr) | 2014-01-03 |
| CA2877212A1 (fr) | 2014-01-03 |
| IN2014DN11210A (fr) | 2015-10-02 |
| FR2992392B1 (fr) | 2014-07-11 |
| KR20150032300A (ko) | 2015-03-25 |
| BR112014032566A2 (pt) | 2017-06-27 |
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