EP2782689B1 - Method and forming tool for hot forming and press hardening work pieces made of sheet steel, in particular galvanized sheet steel - Google Patents
Method and forming tool for hot forming and press hardening work pieces made of sheet steel, in particular galvanized sheet steel Download PDFInfo
- Publication number
- EP2782689B1 EP2782689B1 EP12778287.8A EP12778287A EP2782689B1 EP 2782689 B1 EP2782689 B1 EP 2782689B1 EP 12778287 A EP12778287 A EP 12778287A EP 2782689 B1 EP2782689 B1 EP 2782689B1
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- EP
- European Patent Office
- Prior art keywords
- female mold
- edge region
- drawing edge
- insert part
- workpiece
- Prior art date
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- 229910000831 Steel Inorganic materials 0.000 title claims description 21
- 239000010959 steel Substances 0.000 title claims description 21
- 238000000034 method Methods 0.000 title claims description 17
- 239000000463 material Substances 0.000 claims description 35
- 238000003466 welding Methods 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 9
- 239000012530 fluid Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 230000002093 peripheral effect Effects 0.000 claims description 4
- 239000012809 cooling fluid Substances 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 description 12
- 238000000576 coating method Methods 0.000 description 12
- 229910001335 Galvanized steel Inorganic materials 0.000 description 5
- 239000008397 galvanized steel Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 238000010285 flame spraying Methods 0.000 description 3
- 230000017525 heat dissipation Effects 0.000 description 3
- 229910000734 martensite Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- -1 for example Substances 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910001200 Ferrotitanium Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D37/00—Tools as parts of machines covered by this subclass
- B21D37/16—Heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/02—Stamping using rigid devices or tools
- B21D22/022—Stamping using rigid devices or tools by heating the blank or stamping associated with heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/20—Deep-drawing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/20—Deep-drawing
- B21D22/208—Deep-drawing by heating the blank or deep-drawing associated with heat treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/62—Quenching devices
- C21D1/673—Quenching devices for die quenching
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
- C21D1/22—Martempering
Definitions
- the invention relates to a method for hot forming and press hardening of plate-shaped or preformed workpieces made of sheet steel, in particular galvanized workpieces made of sheet steel, in which the workpiece is heated to a temperature above the Austenitmaschinestemperatur and then in a cooled forming tool having at least one punch and at least one die , reshaped and quenched. Furthermore, the invention relates to a forming tool for hot forming and press hardening of plate-shaped or preformed workpieces made of sheet steel, in particular galvanized workpieces made of sheet steel, with at least one punch and a die associated with the die, wherein the punch and / or die have cooling channels for passing a cooling fluid.
- Such a method and such a forming tool are eg in the JP-A-2007075834 disclosed.
- the present invention has for its object to provide a method or a forming tool of the type mentioned, which improves the flow properties of steel materials during hot forming, so that the risk of occurrence of cracks in the hot forming of workpieces made of sheet steel, especially galvanized steel blanks considerably is reduced.
- the die used for hot forming and press hardening is coated in its defined by a positive drawing radius Ziehkanten Society with material and / or provided with at least one insert which has a thermal conductivity which is lower by at least 10 W / (m * K) than the thermal conductivity the portion of the die adjacent the drawing edge region which contacts the workpiece during hot working and press hardening of the workpiece.
- the applied in the drawing edge region material or arranged there insert part, which according to the invention has a relatively low thermal conductivity, is formed so that its surface facing the workpiece has a extending over the drawing edge transverse dimension which is in the range of 1.6 times to 10 times, preferably in the range of 1.6 times to 6 times the positive drawing radius of the die is.
- the transverse extent (transverse dimension) of the relatively low thermal conductivity having arranged in the drawing edge region material or insert part is thus limited and relatively small.
- the coated steel sheet (workpiece) to be formed is subjected to high plastic deformation.
- the workpiece initially experiences a compressive stress, which changes into tensile stress during the continued closing movement of the forming tool.
- the local flow properties of the workpiece in a conventional forming tool in particular in the drawing radius of the die of a conventional forming tool are adversely affected, which often leads to cracks in the coating, such as zinc coating.
- different crack depths can form, which can extend into the sheet of the coated component.
- the material applied in the drawing edge region for example by coating, having a relatively low thermal conductivity or arranged there, a relatively low thermal conductivity insert is such that it is ensured that the component produced by hot forming and press hardening has a substantially completely martensitic structure
- the part of the press-hardened component influenced by the drawing edge of the die ie the material or insert part having a relatively low thermal conductivity, may have a lower hardness than another part or the remaining part of the component, but this so influenced part of the press-hardened component according to the invention always has a hardness above a required minimum hardness, which corresponds to a martensitic structure. In this way, cracks in the coating, for example in a Zinc layer, as well as in the corresponding coated sheet avoided or significantly reduced at least crack depths in the coating or the coated sheet metal.
- the hot working of the coating e.g. galvanized workpiece (steel sheet) occurring stresses and strains and the solidification occurring in the forming process are reduced by the reduced heat or temperature loss compared to that in a conventional tempered forming. This also reduces or prevents any local material failure.
- the present invention thus improves the flow characteristics of steel sheet workpieces during hot forming, and thus significantly reduces the risk of cracking during hot forming of steel sheet workpieces, preferably galvanized steel blanks.
- the feasibility of components having a complex three-dimensional shape and of coated, e.g. galvanized steel sheet are improved.
- a preferred embodiment of the solution according to the invention provides that the thermal conductivity of the insertion part or material applied in the drawing edge region is less than 40 W / (m * K), preferably less than 30 W / (m * K), particularly preferably less than 20 W / (m * K) is.
- the heat or temperature loss during the hot working of the workpiece is advantageously reduced and the forming behavior of the workpiece is improved accordingly.
- a further advantageous embodiment of the solution according to the invention is characterized in that a heat insulating layer is or is arranged between the insert part and the die.
- a heat insulating layer is or is arranged between the insert part and the die.
- this embodiment makes it possible to use an insert which is made of a particularly wear-resistant material, but which has a relatively high thermal conductivity, wherein the heat insulating, which exposed to the Ziehkanten Scheme insert part not exposed to high mechanical stress, in particular no high Reibbe screwung is, from a heat insulating material, for example, plastic or wood material, with low wear resistance can exist.
- the insert part has a projection protruding from the inner circumference of the die and / or opposite to the edge of the cavity adjacent to the cavity of the die.
- a further advantageous embodiment of the solution according to the invention is characterized in that the material applied in the drawing edge region of the die is applied to the die by build-up welding, preferably laser-deposition welding.
- build-up welding preferably laser-deposition welding.
- the one relatively small Thermal conductivity having material application can be replaced inexpensively by build-up welding, preferably laser deposition welding, if this is required due to a wear-related wear (removal).
- a further advantageous embodiment of the solution according to the invention is characterized in that the drawing edge region of the die is locally selectively heated by means of a heat source integrated in the matrix or a channel carrying a heating fluid.
- FIGS. 1 and 2 are each sections of cooled forming tools for hot forming and press hardening of a plate-shaped or preformed workpiece 1 made of sheet steel, in particular a galvanized workpiece made of sheet steel.
- the reference numeral 2 is a stamp and the reference numeral 3 is a die (die) of the respective forming tool designated.
- Shaping tool shown optionally have a holding-down device (blank holder), which presses the workpiece 1 against the die 3 during the forming process.
- the forming tool according to the invention is designed as a blank holder (low-holder) forming tool.
- Die (die) 3 contains a cavity 4, in which the punch 2 during forming or deep drawing of the workpiece. 1 penetrates.
- the respective forming tool is shown in each case in the closed state with the workpiece 1 formed therein.
- cooling channels for passing a cooling fluid are provided near the forming die surface.
- the workpiece 1 to be formed is first heated to a target temperature, preferably to a temperature above the austenitizing temperature, and then shaped and quenched in the cooled forming tool.
- the temperature of the heated plate-shaped or preformed workpiece 1 is preferably kept as high as possible prior to the forming in order to achieve an improvement in the flow properties of the workpiece 1 or a reduction of the stresses and / or strains during the forming process. This may be, for example, via the selected level of heating temperature and / or by short transfer times, i. short handling times between the heating device (not shown), such as a continuous furnace, and the start of the forming, are influenced.
- the forming tool according to the invention is characterized by an optimized heat transfer coefficient.
- the die 3 is in its defined by a positive drawing radius Ziehkanten Scheme cohesively coated with material and / or there provided with at least one insert part 5, which has a thermal conductivity which is lower by at least 10 W / (m * K) than the thermal conductivity of the drawing edge region adjacent section 3.1 of the die 3, during hot forming and Press hardening of the workpiece with the same comes into contact.
- the means with comparatively low thermal conductivity are dimensioned such that it is furthermore ensured that a completely martensitic microstructure is established in the formed component (workpiece) 1 after completion of the quenching process (press hardening), whereas the workpiece region influenced by the draw edge region designed according to the invention reduces the Hardness, however, must be within the required minimum hardness, may have, whereby cracks in the workpiece 1 can be avoided or crack depths can be reduced.
- the workpiece 1 facing surface of the applied in the drawing edge region material 6 (see. Fig. 3 ) or arranged insert 5 therefore has according to the invention a extending over the drawing edge 7 transverse dimension, which is in the range of 1.6 times to 10 times the positive drawing radius of the die 3.
- the respective die 3 in its positive drawing radius defined pulling edge region at least one insert part 5, whose thermal conductivity is preferably less than 40 W / (m * K), more preferably less than 30 W / (m * K).
- the at least one insert part 5 is annular or strip-shaped and inserted into a formed in the drawing edge region of the die 3 recess 3.2.
- FIGS. 3 to 8 Further embodiments of a forming tool according to the invention, preferably a die 3 are shown schematically.
- a die 3 serving for hot forming and press-hardening is coated, in its drawing edge region defined by a positive drawing radius, with material 6 which has a relatively low thermal conductivity.
- the material (coating) 6 is preferably ceramic, for example alumina or zirconia.
- the selective coating of the drawing edge region can be effected, for example, by flame spraying, in particular powder flame spraying or wire flame spraying, or by arc spraying or plasma spraying.
- the transverse dimension of the coating 6 extending over the drawing edge 7 is, for example, in the range of 1.6 times to 4 times, preferably in the range of 1.6 times to 2 times, the positive drawing radius of the die 3.
- the coating 6 stands or may protrude slightly from the adjacent surface 3.1 of the die 3, for example by about 0.25 mm to 0.5 mm or even more.
- the die 3 serving for hot forming and press hardening in the drawing edge region is provided with a material application 6 'produced by build-up welding, which has a relatively low thermal conductivity.
- a depression 3.3 extending transversely across the drawing edge is produced in the drawing edge region of the die 3, for example by machining.
- this recess (recess) 3.3 is then by deposition welding material 6 'with arranged relatively low thermal conductivity.
- This application material 6 ' may be, for example, chromium steel, titanium or high alloy steel, such as X5CrNi18-10, which has a thermal conductivity of about 30 W / (m * K) or less than 30 W / (m * K ) exhibit.
- the material 6 'applied to the drawing edge region by build-up welding is applied to the extent or subsequently removed by milling or grinding in such a way that it terminates substantially flush in the surface 3.1 of the die 3 or protrudes slightly from the surface 3.1 of the die 3.
- a strip-shaped insert 5 is arranged with relatively low thermal conductivity in the drawing edge region of the die 3.
- the insert 5 consists for example of ceramic, preferably of aluminum oxide (Al 2 O 3 ) or zirconium oxide.
- Al 2 O 3 aluminum oxide
- zirconium oxide zirconium oxide.
- a heat source or a heating fluid leading channel 8 is integrated, by means of which the drawing edge region of the die 3 is locally selectively heated.
- the heat source for example in the form of one or more electrical heating wires, or the channel 8 carrying a heating fluid is integrated in the insertion part 5 forming the drawing edge region.
- FIG. 6 illustrated embodiment differs from those in the FIGS. 1, 2 and 5 shown embodiments in that between the insert part 5 and the die 3, a heat insulating layer 9 is arranged.
- the heat insulating layer 9 is single-layered or multi-layered and consists for example of plastic and / or mineral wool.
- the die 3 used for hot forming and press hardening in the drawing edge region is again provided with a material application 6 'produced by build-up welding, which has a relatively low thermal conductivity.
- the material application 6 ' is designed so that it has a relation to the inner periphery of the die 3 or opposite to the cavity 4 of the die 3 adjacent edge peripheral surface projecting projection 6.1.
- a heat source or a heating fluid-conducting channel 8 can again be integrated in the matrix, by means of which the drawing edge region of the die 3 can be locally selectively heated.
- Fig. 8 illustrated embodiment differs from the embodiment according to Fig. 6 in that the insert part 5 has a projection 5.1 protruding from the inner periphery of the cavity 4 of the die 3 or opposite the edge peripheral surface adjacent to the cavity 4 having.
- the reference numeral 9 again denotes a disposed between the insert part 5 and the die 3 heat insulating layer.
- the embodiment of the present invention is not limited to the embodiments described above and / or illustrated in the drawings. On the contrary, numerous variants or modifications are conceivable which make use of the invention specified in the appended claims, even if the design deviates from the exemplary embodiments.
- the stamp and / or optionally also the sheet holder (hold-down) with means 5, 5.1, 6, 6 ', 6.1 and / or 9 be provided with low thermal conductivity for optimizing the heat transfer coefficient.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Shaping Metal By Deep-Drawing, Or The Like (AREA)
- Mounting, Exchange, And Manufacturing Of Dies (AREA)
- Heat Treatment Of Articles (AREA)
- Extrusion Of Metal (AREA)
Description
Die Erfindung betrifft ein Verfahren zum Warmumformen und Presshärten von plattenförmigen oder vorgeformten Werkstücken aus Stahlblech, insbesondere verzinkten Werkstücken aus Stahlblech, bei dem das Werkstück auf eine Temperatur oberhalb der Austenitisierungstemperatur erhitzt und anschließend in einem gekühlten Umformwerkzeug, das mindestens einen Stempel und mindestens eine Matrize aufweist, umgeformt und abgeschreckt wird. Ferner betrifft die Erfindung ein Umformwerkzeug zum Warmumformen und Presshärten von plattenförmigen oder vorgeformten Werkstücken aus Stahlblech, insbesondere verzinkten Werkstücken aus Stahlblech, mit mindestens einem Stempel und einer dem Stempel zugeordneten Matrize, wobei der Stempel und/oder die Matrize Kühlkanäle zum Durchleiten eines Kühlfluids aufweisen. Solch ein Verfahren und solch ein Umformwerkzeug sind z.B. in der
Hinsichtlich der Warmumformung und Presshärtung von Werkstücken aus Stahlblech sind Vorrichtungen bekannt, die mindestens zwei Werkzeughälften aufweisen, wobei diese bereichsweise derart ausgebildet sind, dass sie unterschiedliche Wärmeleiteigenschaften besitzen, die genutzt werden, um lokal unterschiedliche Festigkeitseigenschaften in dem herzustellenden Bauteil einstellen zu können. Das mit diesen Vorrichtungen ausgeführte Verfahren wird von Fachleuten mit dem Begriff "Tailored-Tempering" bezeichnet. Eine entsprechende Vorrichtung ist beispielsweise aus der
Ferner ist es bekannt, die Maß- und Passgenauigkeit von umgeformten Bauteilen dadurch zu erhöhen, dass die zur Herstellung verwendeten Werkzeughälften im Bereich von Rundungen des Werkstücks positive Radien aufweisen und in den gegenüberliegenden Bereichen Luftspalte bilden, wobei benachbart zu den Luftspalten Vorsprünge derart ausgebildet sind, dass ein verzugsfreies Klemmen ermöglicht wird. Dadurch können auch unterschiedliche Härtegrade im Bauteil eingestellt werden. Eine entsprechende Vorrichtung zum Herstellen von gehärteten Bauteilen aus Stahlblech ist in der
Untersuchungen haben gezeigt, dass bei der Warmumformung von verzinkten Stahlplatinen in konventionellen Umformwerkzeugen mitunter Risse in der Zinkbeschichtung entstehen. Die Risse können sich in die Platine fortsetzen, so dass es zu einem vorzeitigen Bauteilversagen kommen kann.Investigations have shown that during hot forming of galvanized steel blanks in conventional forming tools, cracks sometimes occur in the zinc coating. The cracks can continue into the board, which can lead to premature component failure.
Der vorliegenden Erfindung liegt die Aufgabe zugrunde, ein Verfahren bzw. ein Umformwerkzeug der eingangs genannten Art anzugeben, das die Fließeigenschaften für Stahlwerkstoffe während der Warmumformung verbessert, so dass die Gefahr des Auftretens von Rissen bei der Warmumformung von Werkstücken aus Stahlblech, insbesondere verzinkten Stahlplatinen erheblich verringert wird.The present invention has for its object to provide a method or a forming tool of the type mentioned, which improves the flow properties of steel materials during hot forming, so that the risk of occurrence of cracks in the hot forming of workpieces made of sheet steel, especially galvanized steel blanks considerably is reduced.
Diese Aufgabe wird durch ein Verfahren mit den Merkmalen des Anspruchs 1 bzw. durch ein Umformwerkzeug mit den Merkmalen des Anspruchs 8 gelöst.This object is achieved by a method having the features of claim 1 or by a forming tool having the features of
Bevorzugte und vorteilhafte Ausgestaltungen der Erfindung sind in den Unteransprüchen angegeben.Preferred and advantageous embodiments of the invention are specified in the subclaims.
Erfindungsgemäß wird die zum Warmumformen und Presshärten verwendete Matrize in ihrem durch einen positiven Ziehradius definierten Ziehkantenbereich mit Material beschichtet und/oder mit mindestens einem Einsatzteil versehen, das eine Wärmeleitfähigkeit aufweist, die um mindestens 10 W/(m * K) geringer ist als die Wärmeleitfähigkeit des dem Ziehkantenbereich benachbarten Abschnitts der Matrize, der beim Warmumformen und Presshärten des Werkstückes mit demselben in Kontakt gelangt. Das im Ziehkantenbereich aufgetragene Material oder dort angeordnete Einsatzteil, welches erfindungsgemäß eine relativ geringe Wärmeleitfähigkeit besitzt, wird so ausgebildet, dass sich dessen dem Werkstück zugewandte Oberfläche ein sich über die Ziehkante erstreckendes Quermaß besitzt, das im Bereich des 1,6-fachen bis 10-fachen, vorzugsweise im Bereich des 1,6-fachen bis 6-fachen des positiven Ziehradius der Matrize liegt. Die Quererstreckung (Quermaß) des eine relativ geringe Wärmeleitfähigkeit aufweisenden, im Ziehkantenbereich angeordneten Materials bzw. Einsatzteils ist also beschränkt und vergleichsweise klein.According to the invention, the die used for hot forming and press hardening is coated in its defined by a positive drawing radius Ziehkantenbereich with material and / or provided with at least one insert which has a thermal conductivity which is lower by at least 10 W / (m * K) than the thermal conductivity the portion of the die adjacent the drawing edge region which contacts the workpiece during hot working and press hardening of the workpiece. The applied in the drawing edge region material or arranged there insert part, which according to the invention has a relatively low thermal conductivity, is formed so that its surface facing the workpiece has a extending over the drawing edge transverse dimension which is in the range of 1.6 times to 10 times, preferably in the range of 1.6 times to 6 times the positive drawing radius of the die is. The transverse extent (transverse dimension) of the relatively low thermal conductivity having arranged in the drawing edge region material or insert part is thus limited and relatively small.
Insbesondere in dem durch einen positiven Ziehradius definierten Ziehkantenbereich der Matrize wird das umzuformende beschichtete Stahlblech (Werkstück) hohen plastischen Verformungen unterworfen. Durch das Einwirken des Werkzeugstempels erfährt das Werkstück in diesem Bereich zunächst eine Druckbeanspruchung, die sich während der fortgesetzten Schließbewegung des Umformwerkzeuges in eine Zugbeanspruchung wandelt. Aufgrund des hohen Temperaturunterschiedes zwischen dem Werkstück und dem Umformwerkzeug werden die lokalen Fließeigenschaften des Werkstücks in einem herkömmlichen Umformwerkzeug, insbesondere im Ziehradius des Gesenks eines herkömmlichen Umformwerkzeuges negativ beeinflusst, wobei es häufig zu Rissen in der Beschichtung, beispielsweise Zinkschicht kommt. Mit zunehmender Blechdicke und in Abhängigkeit der Komplexität der Geometrie des herzustellenden Bauteils können sich unterschiedliche Risstiefen ausbilden, die sich bis in das Blech des beschichteten Bauteils erstrecken können.In particular, in the drawing edge region of the die defined by a positive drawing radius, the coated steel sheet (workpiece) to be formed is subjected to high plastic deformation. By the action of the tool punch In this area, the workpiece initially experiences a compressive stress, which changes into tensile stress during the continued closing movement of the forming tool. Due to the high temperature difference between the workpiece and the forming tool, the local flow properties of the workpiece in a conventional forming tool, in particular in the drawing radius of the die of a conventional forming tool are adversely affected, which often leads to cracks in the coating, such as zinc coating. With increasing sheet thickness and depending on the complexity of the geometry of the component to be manufactured, different crack depths can form, which can extend into the sheet of the coated component.
Erfindungsgemäß ist das im Ziehkantenbereich beispielsweise durch Beschichten aufgetragene, eine relativ geringe Wärmeleitfähigkeit aufweisende Material bzw. das dort angeordnete, eine relativ geringe Wärmeleitfähigkeit aufweisende Einsatzteil so bemessen, dass sichergestellt ist, dass das durch Warmumformen und Presshärten hergestellte Bauteil ein im Wesentlichen vollständig martensitisches Gefüge aufweist. Der durch die Ziehkante der Matrize, d.h. das eine relativ geringe Wärmeleitfähigkeit aufweisende Material bzw. Einsatzteil beeinflusste Teil des pressgehärteten Bauteils kann dabei eine geringere Härte aufweisen als ein anderer Teil oder der restliche Teil des Bauteils, wobei jedoch dieser so beeinflusste Teil des pressgehärteten Bauteils erfindungsgemäß stets noch eine oberhalb einer geforderten Mindesthärte liegende Härte aufweist, die einem martensitischen Gefüge entspricht. Auf diese Weise werden Risse in der Beschichtung, beispielsweise in einer Zinkschicht, sowie in dem entsprechend beschichteten Blech vermieden oder zumindest Risstiefen in der Beschichtung bzw. dem beschichteten Blech erheblich reduziert.According to the invention, the material applied in the drawing edge region, for example by coating, having a relatively low thermal conductivity or arranged there, a relatively low thermal conductivity insert is such that it is ensured that the component produced by hot forming and press hardening has a substantially completely martensitic structure , The part of the press-hardened component influenced by the drawing edge of the die, ie the material or insert part having a relatively low thermal conductivity, may have a lower hardness than another part or the remaining part of the component, but this so influenced part of the press-hardened component according to the invention always has a hardness above a required minimum hardness, which corresponds to a martensitic structure. In this way, cracks in the coating, for example in a Zinc layer, as well as in the corresponding coated sheet avoided or significantly reduced at least crack depths in the coating or the coated sheet metal.
Die bei der Warmumformung des beschichten, z.B. verzinkten Werkstückes (Stahlblechs) auftretenden Spannungen und Dehnungen sowie die auftretende Verfestigung im Umformprozess werden durch den reduzierten Wärme- bzw. Temperaturverlust im Vergleich zu demjenigen bei einer konventionellen temperierten Umformung vermindert. Hierdurch wird auch ein eventuelles lokales Materialversagen reduziert oder verhindert.The hot working of the coating, e.g. galvanized workpiece (steel sheet) occurring stresses and strains and the solidification occurring in the forming process are reduced by the reduced heat or temperature loss compared to that in a conventional tempered forming. This also reduces or prevents any local material failure.
Durch die vorliegende Erfindung werden somit die Fließeigenschaften von Werkstücken aus Stahlblech während der Warmumformung verbessert und damit die Gefahr des Auftretens von Rissen bei der Warmumformung von Werkstücken aus Stahlblech, vorzugsweise verzinkten Stahlplatinen erheblich reduziert. Insbesondere wird durch die vorliegende Erfindung die Machbarkeit von Bauteilen, die eine komplexe dreidimensionale Form aufweisen und aus beschichtetem, z.B. verzinktem Stahlblech herzustellen sind, verbessert.The present invention thus improves the flow characteristics of steel sheet workpieces during hot forming, and thus significantly reduces the risk of cracking during hot forming of steel sheet workpieces, preferably galvanized steel blanks. In particular, by the present invention, the feasibility of components having a complex three-dimensional shape and of coated, e.g. galvanized steel sheet are improved.
Eine bevorzugte Ausgestaltung der erfindungsgemäßen Lösung sieht vor, dass die Wärmeleitfähigkeit des im Ziehkantenbereich angeordneten Einsatzteils oder aufgetragenen Materials weniger als 40 W/(m * K), vorzugsweise weniger als 30 W/(m * K), besonders bevorzugt weniger als 20 W/(m * K) beträgt. Hierdurch wird der Wärme- bzw. Temperaturverlust während der Warmumformung des Werkstückes vorteilhaft reduziert und das Umformverhalten des Werkstückes entsprechend verbessert.A preferred embodiment of the solution according to the invention provides that the thermal conductivity of the insertion part or material applied in the drawing edge region is less than 40 W / (m * K), preferably less than 30 W / (m * K), particularly preferably less than 20 W / (m * K) is. As a result, the heat or temperature loss during the hot working of the workpiece is advantageously reduced and the forming behavior of the workpiece is improved accordingly.
Eine weitere vorteilhafte Ausgestaltung der erfindungsgemäßen Lösung ist dadurch gekennzeichnet, dass zwischen dem Einsatzteil und der Matrize eine Wärmeisolierschicht angeordnet wird bzw. ist. Auf diese Weise kann der Wärme- bzw. Temperaturverlust während der Warmumformung des Werkstückes weiter verringert werden. Insbesondere ermöglicht diese Ausgestaltung, ein Einsatzteil zu verwenden, das aus einem besonders verschleißfesten Werkstoff hergestellt ist, der jedoch eine relativ hohe Wärmeleitfähigkeit besitzt, wobei die Wärmeisolierschicht, die im Vergleich zu dem den Ziehkantenbereich bildenden Einsatzteil keiner hohen mechanischen Beanspruchung, insbesondere keiner hohen Reibbeanspruchung ausgesetzt ist, aus einem Wärmeisoliermaterial, zum Beispiel Kunststoff oder Holzwerkstoff, mit geringer Verschleißfestigkeit bestehen kann.A further advantageous embodiment of the solution according to the invention is characterized in that a heat insulating layer is or is arranged between the insert part and the die. In this way, the heat or temperature loss during the hot working of the workpiece can be further reduced. In particular, this embodiment makes it possible to use an insert which is made of a particularly wear-resistant material, but which has a relatively high thermal conductivity, wherein the heat insulating, which exposed to the Ziehkantenbereich insert part not exposed to high mechanical stress, in particular no high Reibbeanspruchung is, from a heat insulating material, for example, plastic or wood material, with low wear resistance can exist.
Nach einer weiteren vorteilhaften Ausgestaltung der erfindungsgemäßen Lösung ist vorgesehen, dass das Einsatzteil einen gegenüber dem Innenumfang der Matrize und/oder gegenüber der an die Kavität der Matrize angrenzenden Randumfangsfläche vorstehenden Vorsprung aufweist. Durch diesen eine lokale Erhöhung darstellenden Vorsprung kann die Wärmeabfuhr aus dem umzuformenden Werkstück vor dem Ziehradius noch wirksamer reduziert werden.According to a further advantageous embodiment of the solution according to the invention, it is provided that the insert part has a projection protruding from the inner circumference of the die and / or opposite to the edge of the cavity adjacent to the cavity of the die. By this projection representing a local increase, the heat dissipation from the workpiece to be reshaped can be more effectively reduced before the drawing radius.
Eine weitere vorteilhafte Ausgestaltung der erfindungsgemäßen Lösung ist dadurch gekennzeichnet, dass das im Ziehkantenbereich der Matrize aufgetragene Material durch Auftragsschweißen, vorzugsweise Laserauftragsschweißen auf die Matrize aufgetragen wird. Auf diese Weise lässt sich relativ einfach die Wärmeleitfähigkeit im Ziehkantenbereich der Matrize zuverlässig verringern. Der eine relativ geringe Wärmeleitfähigkeit aufweisende Materialauftrag kann durch Auftragsschweißen, vorzugsweise Laserauftragsschweißen kostengünstig erneuert werden, wenn dies aufgrund einer verschleißbedingten Abnutzung (Abtragung) erforderlich ist.A further advantageous embodiment of the solution according to the invention is characterized in that the material applied in the drawing edge region of the die is applied to the die by build-up welding, preferably laser-deposition welding. In this way, it is relatively easy to reliably reduce the thermal conductivity in the drawing edge region of the die. The one relatively small Thermal conductivity having material application can be replaced inexpensively by build-up welding, preferably laser deposition welding, if this is required due to a wear-related wear (removal).
Eine weitere vorteilhafte Ausgestaltung der erfindungsgemäßen Lösung ist dadurch gekennzeichnet, dass der Ziehkantenbereich der Matrize mittels einer in der Matrize integrierten Wärmequelle oder eines ein Heizfluid führenden Kanals örtlich selektiv erwärmt wird. Auch hierdurch können die Wärmeabfuhr aus dem umzuformenden Werkstück erheblich verringert und damit die Fließeigenschaften des Stahlwerkstoffs während der Warmumformung verbessert werden.A further advantageous embodiment of the solution according to the invention is characterized in that the drawing edge region of the die is locally selectively heated by means of a heat source integrated in the matrix or a channel carrying a heating fluid. As a result, the heat dissipation from the workpiece to be formed can be significantly reduced and thus the flow properties of the steel material can be improved during hot forming.
Es liegt auch im Rahmen der vorliegenden Erfindung, mehrere der vorgenannten oder alle vorgenannten Ausgestaltungen der erfindungsgemäßen Lösung miteinander zu kombinieren.It is also within the scope of the present invention to combine several of the aforementioned or all the aforementioned embodiments of the solution according to the invention.
Nachfolgend wird die Erfindung anhand einer mehrere Ausführungsbeispiele darstellenden Zeichnung näher erläutert. Es zeigen schematisch:
- Fig. 1
- einen Abschnitt eines erfindungsgemäßen Umformwerkzeuges in Schnittansicht;
- Fig. 2
- einen Abschnitt eines weiteren erfindungsgemäßen Umformwerkzeuges in Schnittansicht;
- Fig. 3
- eine Schnittansicht eines eine Ziehkante umfassenden Abschnitts eines erfindungsgemäßen Umformwerkzeuges mit einer im Ziehkantenbereich angeordneten, eine relativ geringe Wärmeleitfähigkeit aufweisenden Beschichtung;
Figuren 4 und 7- jeweils eine Schnittansicht eines eine Ziehkante umfassenden Abschnitts eines erfindungsgemäßen Umformwerkzeuges mit im Ziehkantenbereich durch Auftragsschweißen aufgebrachtem Material, das jeweils eine relativ geringe Wärmeleitfähigkeit aufweist; und
5, 6 und 8Figuren - jeweils eine Schnittansicht eines eine Ziehkante umfassenden Abschnitts eines erfindungsgemäßen Umformwerkzeuges mit einem im Ziehkantenbereich angeordneten Einsatzteil, das eine relativ geringe Wärmeleitfähigkeit aufweist.
- Fig. 1
- a section of a forming tool according to the invention in sectional view;
- Fig. 2
- a section of another forming tool according to the invention in sectional view;
- Fig. 3
- a sectional view of a pulling edge comprehensive portion of a forming tool according to the invention with a in the drawing edge region arranged, having a relatively low thermal conductivity coating;
- FIGS. 4 and 7
- each a sectional view of a drawing edge comprehensive portion of a forming tool according to the invention with applied in the drawing edge region by build-up welding material, each having a relatively low thermal conductivity; and
- FIGS. 5, 6 and 8
- in each case a sectional view of a pulling edge comprehensive portion of a forming tool according to the invention with a arranged in the drawing edge region insert part, which has a relatively low thermal conductivity.
In den
Die Matrize (Gesenk) 3 enthält eine Kavität 4, in die der Stempel 2 beim Umformen bzw. Tiefziehen des Werkstücks 1 eindringt. In den
In dem Stempel 2 und/oder der Matrize 3 sind nahe der formgebenden Werkzeugoberfläche Kühlkanäle (nicht gezeigt) zum Durchleiten eines Kühlfluids vorhanden. Das umzuformende Werkstück 1 wird vor dem Einlegen in das geöffnete Umformwerkzeug zunächst auf eine Zieltemperatur, vorzugsweise auf eine Temperatur oberhalb der Austenitisierungstemperatur erhitzt und anschließend in dem gekühlten Umformwerkzeug umgeformt und abgeschreckt.In the
Die Temperatur des erhitzen plattenförmigen oder vorgeformten Werkstücks 1 wird vor der Umformung vorzugsweise möglichst hoch gehalten, um eine Verbesserung der bei der Umformung wirkenden Fließeigenschaften des Werkstücks 1 bzw. eine Reduzierung der Spannungen und/oder Dehnungen zu erzielen. Dies kann zum Beispiel über die gewählte Höhe der Erwärmungstemperatur und/oder durch kurze Transferzeiten, d.h. kurzen Handlingzeiten zwischen der Erwärmungsvorrichtung (nicht gezeigt), beispielsweise einem Durchlaufofen, und dem Start der Umformung, beeinflusst werden.The temperature of the heated plate-shaped or preformed workpiece 1 is preferably kept as high as possible prior to the forming in order to achieve an improvement in the flow properties of the workpiece 1 or a reduction of the stresses and / or strains during the forming process. This may be, for example, via the selected level of heating temperature and / or by short transfer times, i. short handling times between the heating device (not shown), such as a continuous furnace, and the start of the forming, are influenced.
Das erfindungsgemäße Umformwerkzeug zeichnet sich durch einen optimierten Wärmeübergangskoeffizienten aus. Hierdurch wird eine zu schnelle lokale Abkühlung des erhitzen Werkstücks 1 (z.B. der verzinkten Stahlplatine) nach dem Positionieren und während der Umformung im Werkzeug verhindert. Erfindungsgemäß ist zumindest die Matrize 3 hinsichtlich des Wärmeübergangskoeffizienten optimiert. Hierzu ist die Matrize 3 in ihrem durch einen positiven Ziehradius definierten Ziehkantenbereich mit Material stoffschlüssig beschichtet und/oder dort mit mindestens einem Einsatzteil 5 versehen, das eine Wärmeleitfähigkeit aufweist, die um mindestens 10 W/(m * K) geringer ist als die Wärmeleitfähigkeit des dem Ziehkantenbereich benachbarten Abschnitts 3.1 der Matrize 3, der beim Warmumformen und Presshärten des Werkstückes mit demselben in Kontakt gelangt. Die Mittel mit vergleichsweise geringer Wärmeleitfähigkeit sind dabei derart bemessen, dass weiterhin gewährleistet ist, dass sich im umgeformten Bauteil (Werkstück) 1 nach Abschluss des Abschreckvorgangs (Presshärtens) ein vollständig martensitisches Gefüge einstellt, wohingegen der durch den erfindungsgemäß ausgeführten Ziehkantenbereich beeinflusste Werkstückbereich eine Reduzierung der Härte, die jedoch im Rahmen der geforderten Mindesthärte liegen muss, aufweisen kann, wodurch Risse im Werkstück 1 vermieden bzw. Risstiefen reduziert werden können. Die dem Werkstück 1 zugewandte Oberfläche des im Ziehkantenbereich aufgetragenen Materials 6 (vgl.
In den in den
In den
Bei dem in
Das Quermaß der sich über die Ziehkante 7 erstreckenden Beschichtung 6 liegt beispielsweise im Bereich des 1,6-fachen bis 4-fachen, vorzugsweise im Bereich des 1,6-fachen bis 2-fachen des positiven Ziehradius der Matrize 3. Die Beschichtung 6 steht bzw. kann gegenüber der benachbarten Oberfläche 3.1 der Matrize 3 geringfügig vorstehen, beispielsweise um ca. 0,25 mm bis 0,5 mm oder auch mehr.The transverse dimension of the
Bei dem in
Die in
In
Das in
Bei dem in
Das in
Die Ausführung der vorliegenden Erfindung ist nicht auf die vorstehend beschriebenen und/oder in der Zeichnung dargestellten Ausführungsbeispiele beschränkt. Vielmehr sind zahlreiche Varianten oder Abwandlungen denkbar, die auch bei einer von den Ausführungsbeispielen abweichenden Gestaltung von der in den beiliegenden Ansprüchen angegebenen Erfindung Gebrauch machen. So können beispielsweise zusätzlich auch der Stempel und/oder gegebenenfalls auch der Blechhalter (Niederhalter) mit Mitteln 5, 5.1, 6, 6', 6.1 und/oder 9 mit geringer Wärmeleitfähigkeit zur Optimierung des Wärmeübergangskoeffizienten versehen sein.The embodiment of the present invention is not limited to the embodiments described above and / or illustrated in the drawings. On the contrary, numerous variants or modifications are conceivable which make use of the invention specified in the appended claims, even if the design deviates from the exemplary embodiments. Thus, for example, in addition, the stamp and / or optionally also the sheet holder (hold-down) with
Claims (14)
- Method for hot forming and press hardening plate-shaped or preformed workpieces (1) of sheet steel, in particular galvanised workpieces (1) of sheet steel, in which the workpiece is heated to a temperature above the austenitisation temperature and is then formed and quenched in a cooled forming tool having at least one punch (2) and at least one female mold (3), characterised in that the female mold (3) used for hot forming and press hardening is coated in its drawing edge region, defined by a positive die radius, with material (6, 6') in a material-uniting manner and/or is provided there with at least one insert part (5) having a thermal conductivity which is at least 10 W/ (m * K) lower than the thermal conductivity of the portion (3.1) of the female mold (3), which portion is adjacent to the drawing edge region and comes into contact with the workpiece (1) when said workpiece is being hot formed and press hardened, the surface, facing the workpiece (1), of the material (6, 6') applied in the drawing edge region, or of the insert part (5) arranged there, having a transverse dimension which extends over the drawing edge (7) and is within the range of 1.6 times to 10 times the positive radius of the female mold (3).
- Method according to claim 1, characterised in that the thermal conductivity of the insert part (5) arranged in the drawing edge region or of the applied material (6, 6') is less than 40 W/ (m * K), preferably less than 30 W/ (m * K).
- Method according to claim 1 or claim 2, characterised in that the at least one insert part (5) is configured in the form of a strip and is inserted into a recess (3.2) formed in the corner region of the female mold (3).
- Method according to any one of claims 1 to 3, characterised in that a heat insulating layer (9) is arranged between the insert part (5) and the female mold (3).
- Method according to any one of claims 1 to 4, characterised in that the insert part (5) has a projection (5.1) which protrudes with respect to the inner periphery of the female mold (3) and/or with respect to the peripheral surface (3.1) adjoining the cavity (4) of the female mold (3).
- Method according to any one of claims 1 to 5, characterised in that the material (6') applied in the drawing edge region of the female mold (3) is applied to the female mold (3) by build-up welding.
- Method according to any one of claims 1 to 6, characterised in that the drawing edge region of the female mold (3) is heated in a locally selective manner by a heat source integrated into the female mold or by a duct (8) conducting a heating fluid.
- Forming tool for hot forming and press hardening plate-shaped or preformed workpieces (1) of sheet steel, in particular galvanised workpieces (1) of sheet steel, having at least one punch (2) and a female mold (3) associated with said punch, the punch (2) and/or the female mold (3) having cooling ducts for conducting a cooling fluid, characterised in that the female mold (3) is coated in its drawing edge region, defined by a positive die radius, with material (6, 6') in a material-uniting manner and/or is provided there with at least one insert part (5) having a thermal conductivity which is at least 10 W/ (m * K) lower than the thermal conductivity of the portion (3.1) of the female mold (3), which portion is adjacent to the drawing edge region and comes into contact with the workpiece (1) when said workpiece is being hot formed and press hardened, the surface, facing the workpiece (1), of the material (6, 6') applied in the drawing edge region or of the insert part (5) arranged there having a transverse dimension which extends over the drawing edge (7) and is within the range of 1.6 times to 10 times the positive radius of the female mold (3).
- Forming tool according to claim 8, characterised in that the thermal conductivity of the insert part (5) arranged in the drawing edge region or of the applied material (6, 6') is less than 40 W/ (m * K), preferably less than 30 W/ (m * K).
- Forming tool according to claim 8 or claim 9, characterised in that the at least one insert part (5) is configured in the form of a strip and is inserted into a recess (3.2) formed in the drawing edge region of the female mold (3).
- Forming tool according to any one of claims 8 to 10, characterised in that a heat insulating layer (9) is arranged between the insert part (5) and the female mold (3).
- Forming tool according to any one of claims 8 to 11, characterised in that the insert part (5) has a projection (5.1) which protrudes with respect to the inner periphery of the female mold (3) and/or with respect to the peripheral surface (3.1) adjoining the cavity (4) of the female mold (3).
- Forming tool according to any one of claims 8 to 12, characterised in that the material (6') applied in the drawing edge region of the female mold (3) is applied to the female mold (3) by build-up welding.
- Forming tool according to any one of claims 8 to 13, characterised in that integrated into the female mold (3) is a heat source or a duct (8) conducting heating fluid, by which the drawing edge region of the female mold (3) can be heated in a locally selective manner.
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DE102011055643A DE102011055643A1 (en) | 2011-11-23 | 2011-11-23 | Method and forming tool for hot forming and press hardening of workpieces made of sheet steel, in particular galvanized workpieces made of sheet steel |
PCT/EP2012/070445 WO2013075888A1 (en) | 2011-11-23 | 2012-10-16 | Method and forming tool for hot forming and press hardening work pieces made of sheet steel, in particular galvanized sheet steel |
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US (1) | US9770750B2 (en) |
EP (1) | EP2782689B1 (en) |
JP (1) | JP5886977B2 (en) |
KR (1) | KR20140094021A (en) |
CN (1) | CN103958087B (en) |
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DE (1) | DE102011055643A1 (en) |
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-
2011
- 2011-11-23 DE DE102011055643A patent/DE102011055643A1/en not_active Ceased
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2012
- 2012-10-16 CA CA2856679A patent/CA2856679C/en not_active Expired - Fee Related
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- 2012-10-16 KR KR1020147017102A patent/KR20140094021A/en not_active Application Discontinuation
- 2012-10-16 EP EP12778287.8A patent/EP2782689B1/en active Active
- 2012-10-16 PL PL12778287.8T patent/PL2782689T3/en unknown
- 2012-10-16 RU RU2014125268A patent/RU2606359C2/en active
- 2012-10-16 ES ES12778287.8T patent/ES2569351T3/en active Active
- 2012-10-16 MX MX2014006178A patent/MX341647B/en active IP Right Grant
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EP2782689A1 (en) | 2014-10-01 |
PL2782689T3 (en) | 2016-12-30 |
MX341647B (en) | 2016-08-26 |
CA2856679C (en) | 2019-10-29 |
WO2013075888A1 (en) | 2013-05-30 |
MX2014006178A (en) | 2014-06-19 |
DE102011055643A1 (en) | 2013-05-23 |
ES2569351T3 (en) | 2016-05-10 |
CN103958087B (en) | 2016-03-02 |
JP2014533608A (en) | 2014-12-15 |
KR20140094021A (en) | 2014-07-29 |
HUE027539T2 (en) | 2016-11-28 |
CN103958087A (en) | 2014-07-30 |
CA2856679A1 (en) | 2013-05-30 |
RU2606359C2 (en) | 2017-01-10 |
US9770750B2 (en) | 2017-09-26 |
US20140311205A1 (en) | 2014-10-23 |
JP5886977B2 (en) | 2016-03-16 |
RU2014125268A (en) | 2015-12-27 |
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