EP2761043A1 - Alliage de métal blanc pour bague de palier de laminoir - Google Patents

Alliage de métal blanc pour bague de palier de laminoir

Info

Publication number
EP2761043A1
EP2761043A1 EP12758948.9A EP12758948A EP2761043A1 EP 2761043 A1 EP2761043 A1 EP 2761043A1 EP 12758948 A EP12758948 A EP 12758948A EP 2761043 A1 EP2761043 A1 EP 2761043A1
Authority
EP
European Patent Office
Prior art keywords
alloy
weight
white metal
cobalt
tin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12758948.9A
Other languages
German (de)
English (en)
Inventor
Karl F. Seelig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens Industry Inc
Original Assignee
Siemens Industry Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens Industry Inc filed Critical Siemens Industry Inc
Publication of EP2761043A1 publication Critical patent/EP2761043A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C13/00—Alloys based on tin
    • C22C13/02—Alloys based on tin with antimony or bismuth as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C13/00—Alloys based on tin
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02—Parts of sliding-contact bearings
    • F16C33/04—Brasses; Bushes; Linings
    • F16C33/06—Sliding surface mainly made of metal
    • F16C33/12—Structural composition; Use of special materials or surface treatments, e.g. for rust-proofing
    • F16C33/121—Use of special materials
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2204/00—Metallic materials; Alloys
    • F16C2204/30—Alloys based on one of tin, lead, antimony, bismuth, indium, e.g. materials for providing sliding surfaces
    • F16C2204/34—Alloys based on tin
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2322/00—Apparatus used in shaping articles
    • F16C2322/12—Rolling apparatus, e.g. rolling stands, rolls

Definitions

  • Embodiments and aspects of the present invention relate to tin based white metal alloys useful in various industrial applications, including the bushings of rolling mill oil film bearings.
  • ASTM #2 The most prominent white metal alloy used in oil film bearings in the rolling mill field is described in ASTM B23 #2, (referred to here as ASTM #2) and is comprised primarily of tin, with antimony and copper, as alloying elements. ASTM #2 is well understood and is readily deposited onto bushing shells via centrifugal casting, spray deposition, or welding. Unfortunately, ASTM #2 has relatively low fatigue resistance, which limits load capacity of bearings made with this material.
  • the alloy of Roeingh is suitable for centrifugal casting applications. But due to the brittleness of the zinc component, this alloy cannot be readily drawn into wire for use in spray and welding applications.
  • U.S. Patent No. 4,140,835 (Goddard) and U.K. Application No. 2146354 A disclose cobalt as a component of tin based white metal alloys that also include cadmium.
  • Cadmium is a known carcinogen that has been banned from most workplaces and thus is undesirable.
  • U.S. Patent No. 4,795,682 discloses a tin/cobalt alloy useful as a sacrificial coating designed to absorb particulates. Such coatings lack the toughness required for heavily loaded oil film bearing applications, and the disclosed use of cobalt at elevated percentage levels would inhibit the flow characteristics necessary in a casting or welding process.
  • aspects of the present invention relate to a tin based white metal alloy that is universally useful in centrifugal casting, spraying, and welding applications. Aspects of the present invention also relate to a tin based white metal alloy having the elevated strength and fatigue resistance required for use in heavily loaded oil film bearings of the type commonly found in the metals industry.
  • aspects of the present invention further relate to a tin based white metal alloy that is low in toxicity and generally free from carcinogenic components, including cadmium and the like.
  • aspects of the present invention may be achieved by replacing zinc and silver components of the alloy disclosed in the above referenced U.S. Patent No. 6,589,372 Bl with cobalt in amounts ranging between about 0.1%-0.7% by weight, with amounts ranging between 0.2% and 0.5% being considered optimal.
  • Embodiments of the present invention are not limited to use in the described systems.
  • a tin based white metal alloy in accordance with the present invention includes as principal components tin, antimony, and copper, to which cobalt has been added. Addition of cobalt in amounts above approximately 0.7% by weight has been found to disadvantageously lower the fluidity of the resulting alloy. Thus, cobalt additions of between about 0.1%-0.7% by weight have been found to be effective in achieving the above-stated objectives, with additions of between about 0.2%-0.5% by weight being optimal.
  • Tin based white metal alloys of the present invention consist essentially of the components listed in the following examples:
  • alloys of the present invention may be centrifugally cast, and may also be drawn into wire for use in spraying or welding applications. Further, alloys of the present invention have the strength and fatigue resistance required for use in heavily loaded bearing applications, including the steel making industry applications, while being free of components that either are banned or otherwise detrimental.
  • Fatigue resistance of white metal alloys can be determined experimentally through the use of tension/compression specimens that are cycled until failure. Laboratory test data comparing the alloy of the present invention with commonly used alloys in the field are illustrated in TABLE 1. Based on test data the fatigue strength of the alloy containing 0.3% to 0.5% cobalt has excellent fatigue resistance, exceeding that of other alloys commonly used in the rolling mill application. Test data shown was determined in accordance with ASTM E 466 with an applied load of 7,500 psi (51.7 MPa) and test frequency of 10 Hz. Axial Fatigue Resistance of Various White Metal Alloys

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Sliding-Contact Bearings (AREA)
  • Contacts (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Cell Electrode Carriers And Collectors (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)

Abstract

L'invention concerne un alliage de métal blanc à base d'étain consistant essentiellement, en poids, en approximativement 5,0 %-9,0 % d'antimoine, approximativement 3,0 %-8,0 % de cuivre, approximativement 0,1 %-0,7 % de cobalt, le complément étant constitué par de l'étain.
EP12758948.9A 2011-09-30 2012-08-30 Alliage de métal blanc pour bague de palier de laminoir Withdrawn EP2761043A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161541395P 2011-09-30 2011-09-30
US13/590,996 US20130084209A1 (en) 2011-09-30 2012-08-21 White Metal Babbitt for Rolling Mill Bushing
PCT/US2012/053004 WO2013048664A1 (fr) 2011-09-30 2012-08-30 Alliage de métal blanc pour bague de palier de laminoir

Publications (1)

Publication Number Publication Date
EP2761043A1 true EP2761043A1 (fr) 2014-08-06

Family

ID=47992760

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12758948.9A Withdrawn EP2761043A1 (fr) 2011-09-30 2012-08-30 Alliage de métal blanc pour bague de palier de laminoir

Country Status (14)

Country Link
US (1) US20130084209A1 (fr)
EP (1) EP2761043A1 (fr)
JP (1) JP2014534335A (fr)
KR (1) KR20140070562A (fr)
CN (1) CN103842532A (fr)
AR (1) AR088179A1 (fr)
BR (1) BR112014007510A2 (fr)
CA (1) CA2850419A1 (fr)
IN (1) IN2014DN01803A (fr)
MX (1) MX2014003658A (fr)
RU (1) RU2014117637A (fr)
TW (1) TW201326414A (fr)
WO (1) WO2013048664A1 (fr)
ZA (1) ZA201402160B (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI543431B (zh) * 2012-09-06 2016-07-21 Kureha Corp Non-aqueous electrolyte secondary battery negative electrode carbonaceous material and its manufacturing method, and the use of the carbonaceous material of the negative and non-aqueous electrolyte secondary battery
AT515099B1 (de) * 2014-01-31 2015-06-15 Miba Gleitlager Gmbh Mehrschichtgleitlager
CN103949614B (zh) * 2014-05-06 2015-12-30 浙江机电职业技术学院 对开式径向轴瓦产品的制作方法
CN110227809B (zh) * 2018-09-07 2022-01-11 襄阳航力机电技术发展有限公司 一种锡基轴承合金的离心铸造工艺
CN114058899A (zh) * 2022-01-17 2022-02-18 中机智能装备创新研究院(宁波)有限公司 一种锡基巴氏合金的制备方法
CN115652137B (zh) * 2022-03-01 2024-03-29 中国机械总院集团宁波智能机床研究院有限公司 一种锡基巴氏合金及其制备方法、轴瓦

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3563732A (en) * 1968-02-09 1971-02-16 Daido Metal Co Ltd Bearing alloys of tin based white metal
US4140835A (en) * 1976-06-23 1979-02-20 The Glacier Metal Company Limited Bearing materials
JPS53131922A (en) 1977-04-22 1978-11-17 Daido Metal Co Ltd Tinnbased white metal bearing alloy
GB8324353D0 (en) 1983-09-12 1983-10-12 Darchem Ltd Materials
GB8617676D0 (en) 1986-07-19 1986-08-28 Ae Plc Bearing alloys
JP2761181B2 (ja) 1993-12-27 1998-06-04 大同メタル工業株式会社 耐熱性及び耐疲労性に優れた錫基ホワイトメタル軸受合金
DE19905213A1 (de) * 1999-02-09 2000-08-31 Sms Demag Ag Gleitlager
AT505664B1 (de) * 2008-03-03 2009-03-15 Miba Gleitlager Gmbh Gleitlagerlegierung aus weissmetall auf zinnbasis
AT509112B1 (de) * 2009-12-10 2011-09-15 Miba Gleitlager Gmbh Gleitschicht

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2013048664A1 *

Also Published As

Publication number Publication date
RU2014117637A (ru) 2015-11-10
KR20140070562A (ko) 2014-06-10
WO2013048664A1 (fr) 2013-04-04
US20130084209A1 (en) 2013-04-04
AR088179A1 (es) 2014-05-14
IN2014DN01803A (fr) 2015-05-15
ZA201402160B (en) 2015-05-27
BR112014007510A2 (pt) 2017-04-04
JP2014534335A (ja) 2014-12-18
CA2850419A1 (fr) 2013-04-04
MX2014003658A (es) 2014-05-21
CN103842532A (zh) 2014-06-04
TW201326414A (zh) 2013-07-01

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