EP2753403B1 - Siloxane-containing fire extinguishing foam - Google Patents
Siloxane-containing fire extinguishing foam Download PDFInfo
- Publication number
- EP2753403B1 EP2753403B1 EP12753148.1A EP12753148A EP2753403B1 EP 2753403 B1 EP2753403 B1 EP 2753403B1 EP 12753148 A EP12753148 A EP 12753148A EP 2753403 B1 EP2753403 B1 EP 2753403B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- carbohydrate
- solution
- acid
- surfactant
- substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000006260 foam Substances 0.000 title claims description 22
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 title description 4
- 239000004094 surface-active agent Substances 0.000 claims description 37
- 150000001720 carbohydrates Chemical class 0.000 claims description 20
- 235000014633 carbohydrates Nutrition 0.000 claims description 17
- 239000012141 concentrate Substances 0.000 claims description 13
- 150000001719 carbohydrate derivatives Chemical class 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 150000003999 cyclitols Chemical class 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- RSNQKPMXXVDJFG-UHFFFAOYSA-N tetrasiloxane Chemical compound [SiH3]O[SiH2]O[SiH2]O[SiH3] RSNQKPMXXVDJFG-UHFFFAOYSA-N 0.000 claims description 3
- 150000004043 trisaccharides Chemical class 0.000 claims description 3
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 150000002337 glycosamines Chemical class 0.000 claims description 2
- 150000007970 thio esters Chemical class 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 35
- 230000007480 spreading Effects 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 17
- 125000000217 alkyl group Chemical group 0.000 description 10
- -1 ethyl siloxanes Chemical class 0.000 description 10
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
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- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 101000939676 Androctonus crassicauda Toxin a Proteins 0.000 description 3
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- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- MSWZFWKMSRAUBD-UHFFFAOYSA-N beta-D-galactosamine Natural products NC1C(O)OC(CO)C(O)C1O MSWZFWKMSRAUBD-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- ATDWJHOSZLOQDJ-UHFFFAOYSA-N ciceritol Natural products OC1C(OC)C(O)C(O)C(O)C1OC1C(O)C(O)C(O)C(COC2C(C(O)C(O)C(CO)O2)O)O1 ATDWJHOSZLOQDJ-UHFFFAOYSA-N 0.000 description 1
- 229940061631 citric acid acetate Drugs 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 150000002016 disaccharides Chemical class 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical class CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- DBTMGCOVALSLOR-AXAHEAMVSA-N galactotriose Natural products OC[C@@H]1O[C@@H](O[C@@H]2[C@@H](O)[C@H](CO)O[C@@H](O[C@H]3[C@@H](O)[C@H](O)O[C@@H](CO)[C@@H]3O)[C@@H]2O)[C@H](O)[C@H](O)[C@H]1O DBTMGCOVALSLOR-AXAHEAMVSA-N 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 229960002442 glucosamine Drugs 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229940097043 glucuronic acid Drugs 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 150000002338 glycosides Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002402 hexoses Chemical class 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 150000004693 imidazolium salts Chemical class 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- DLRVVLDZNNYCBX-RTPHMHGBSA-N isomaltose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)C(O)O1 DLRVVLDZNNYCBX-RTPHMHGBSA-N 0.000 description 1
- FBJQEBRMDXPWNX-FYHZSNTMSA-N isomaltotriose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@@H](OC[C@@H]2[C@H]([C@H](O)[C@@H](O)C(O)O2)O)O1 FBJQEBRMDXPWNX-FYHZSNTMSA-N 0.000 description 1
- IZSRJDGCGRAUAR-WISUUJSJSA-N keto-D-fructuronic acid Chemical compound OCC(=O)[C@@H](O)[C@H](O)[C@H](O)C(O)=O IZSRJDGCGRAUAR-WISUUJSJSA-N 0.000 description 1
- 239000000832 lactitol Substances 0.000 description 1
- 235000010448 lactitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-JVCRWLNRSA-N lactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-JVCRWLNRSA-N 0.000 description 1
- 229960003451 lactitol Drugs 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- FGPATWVHNYVVEE-SKPZHCOCSA-N maltotriulose Chemical compound OC[C@H]1OC(O)(CO)[C@@H](O)[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O[C@@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@@H](CO)O1 FGPATWVHNYVVEE-SKPZHCOCSA-N 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 229960001855 mannitol Drugs 0.000 description 1
- FYGDTMLNYKFZSV-UHFFFAOYSA-N mannotriose Natural products OC1C(O)C(O)C(CO)OC1OC1C(CO)OC(OC2C(OC(O)C(O)C2O)CO)C(O)C1O FYGDTMLNYKFZSV-UHFFFAOYSA-N 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002972 pentoses Chemical class 0.000 description 1
- YFSUTJLHUFNCNZ-UHFFFAOYSA-N perfluorooctane-1-sulfonic acid Chemical compound OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YFSUTJLHUFNCNZ-UHFFFAOYSA-N 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229940057950 sodium laureth sulfate Drugs 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- FYGDTMLNYKFZSV-BYLHFPJWSA-N β-1,4-galactotrioside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@H](CO)O[C@@H](O[C@@H]2[C@@H](O[C@@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-BYLHFPJWSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0071—Foams
Definitions
- the present invention relates to the field of fire-extinguishing foams.
- Fuels are the extinguishing water usually added special foaming agents. These have surface-active properties and, in contrast to conventional extinguishing foams, permit the self-wetting of the surface of the burned material. Therefore, such a so-called AFFF (Aqueous Film Forming Foams) extinguishing foams form as a special feature a film of water on the surface of the burning liquid. The resulting vapor barrier makes it more difficult for the combustible liquid to pass into the gas phase and thus maintain the fire or form ignitable or explosive gas mixtures.
- AFFF Aqueous Film Forming Foams
- the wetting ability characteristic of the AFFF foams also allows the foam to slide on the surface of the burning liquid so as to reach areas where the foam can not be applied directly.
- the foam surface closes after failure (for example, by falling objects) again independently.
- the film also flows and acts in areas that are not directly reached by foam.
- PFOS perfluorooctylsulfonate
- EU Directive 2006/122 / EC of 12.12.2006 limited Extinguishing foams with more than 50 ppm PFOS content must not be used in the EU.
- various other polyfluorinated surfactants are used as substitutes for PFOS in AFFF. These surfactants are heretofore believed to be non-bioactive or at least less bioaccumulating and toxic.
- a final assessment is still pending and the fundamental problem of persistence of polyfluorinated compounds remains intact.
- a fire-extinguishing foam concentrate which comprises a surfactant according to claim 1, containing at least one substituted or unsubstituted carbohydrate or carbohydrate derivative and at least one oligosiloxane.
- the term "containing" in this context means that both the carbohydrate or carbohydrate derivative and the oligosiloxane are subcomponents of a larger molecule and both are linked via covalent bonds to the remainder of the molecule.
- A is a substituted or unsubstituted carbohydrate or carbohydrate derivative having one to four sugar units.
- Preferred are mono-, di- and trisaccharides, i. one, two or three sugar units.
- subcomponent A or parts of subcomponent A may also be derived from carbohydrate derivatives such as e.g. the sugar acids (aldonic acids, uronic acids or aldaric acids), sugar alcohols (alditols), aminosugars or cyclitols, and their ethers, esters, amides or thioesters.
- carbohydrate derivatives such as e.g. the sugar acids (aldonic acids, uronic acids or aldaric acids), sugar alcohols (alditols), aminosugars or cyclitols, and their ethers, esters, amides or thioesters.
- sugar moieties or “carbohydrate” is understood to mean, in particular, hexoses, pentoses or cyclitols, which (in the presence of di- or higher saccharides) are preferably linked to one another in a glycosidic manner.
- the carbohydrates may be substituted or unsubstituted, with unsubstituted carbohydrates being preferred because of the resulting higher water solubility.
- carbohydrates are substituted, ethyleneoxy, oligo (ethyleneoxy), methyl, ethyl, allyl or acetyl substituents are preferred.
- Preferred carbohydrates or carbohydrate derivatives in the context of the present invention are for monosaccharides: glucose, glucosamine, fructose, galactose for disaccharides: maltose, isomaltose, sucrose, cellobiose, lactose, trehalose for trisaccharides: raffinose, maltotriose, isomaltotriose, maltotriulose, ciceritol for cyclitols: inositol, quebrachitol, pinitol in the case of sugar acids: gluconic acid, glucuronic acid, glucaric acid, tartaric acid, galactonic acid, galacturonic acid, maleic acid, mannuronic acid, mannaric acid, fructonic acid, fructuronic acid, fructaric acid, arabinonic acid, arabinuronic acid, arabinaric acid, xylonic acid, xyluronic acid, xylaric acid, rib
- B is an optional linker substructure of at least one atom or chain, preferably of carbon and / or nitrogen and / or oxygen atoms (O-O bonds being excluded).
- This chain may be a pure alkyl chain, i.
- B is an unsubstituted or optionally alkyl-substituted alkylene radical.
- B may also contain ether, ester or amide groups.
- B may contain glycerol, poly- or oligoethylene glycol, poly- or oligopropylene glycol, pentaerythritol, alkylamines or carboxylic acids as a substructure.
- B is preferably linked to residue A glycosidically via an anomeric carbon atom.
- B may also be linked to A via an amide or ester bond.
- residue C (the siloxane)
- B is preferably linked via an Si-C or Si-O bond.
- subcomponent B may also be omitted, i. if necessary, A and C are directly linked.
- radical B-C or C may also be attached to other regiochemical positions of the carbohydrate or carbohydrate derivative A.
- C is an oligosiloxane, preferably a di-, tri- or tetrasiloxane.
- methyl and ethyl siloxanes or mixed siloxanes with methyl and ethyl radicals are preferred.
- C is a tri- or higher siloxane
- C may be linked to B (or optionally A) via one of the terminal siloxanes (forming a kind of "continuous chain")
- C may be combined with B (or optionally A ) may also be linked via one of the medium siloxanes, so that a type of X- or T-shaped or branched structure forms.
- the substructures AB or A joined to C may be the same or different.
- C has one of the following structures: wherein each R, independently of one another, is ethyl or methyl and n is between 0 and 10, preferably between 0 and 5, more preferably 0, 1 or 2.
- the fire-fighting foam concentrate also comprises one or more of the following constituents: foaming agents, film formers, film stabilizers, antifreeze preservatives and corrosion inhibitors, solubilizers and buffers.
- foaming cosurfactants can be added.
- these may be: linear alkylbenzenesulfonates, secondary alkanesulfonates, sodium alkylsulfonates, ⁇ -olefmsulfonates, sulfosuccinic acid esters, ⁇ -methyl ester sulfonates, alcohol ethoxylates, alkylphenol ethoxylates, fatty alcohol ethylene oxide / propylene oxide adducts, Glycoside surfactants (eg, glucopone, this is particularly preferred), lauryl sulfates, laureth sulfates, imidazolium salts, lauriminodipropionate, acrylic copolymers.
- Suitable counterions for the anionic surfactants present in this list are, in particular, Li + , Na + , K + , NH 4 + , N (C 2 H 5 ) 4 +
- the foaming agent concentrate may, inter alia, be admixed with the following constituents: polysaccharides, alginates, xanthan gum, starch derivatives
- the foaming agent concentrate may be admixed with, inter alia, the following components: ethylene glycol, propylene glycol, glycerol, 1-propanol, 2-propanol, urea, inorganic salts
- the foam concentrate may be admixed inter alia with the following components: Formaldehyde solution, alkylcarboxylic acid salts, ascorbic acid, salicylic acid, tolyltriazoles
- the foam concentrate may be admixed with, inter alia, the following constituents: Butyl glycol, butyl diglycol, hexylene glycol
- the present invention also relates to the use of a surfactant containing at least one substituted or unsubstituted carbohydrate or carbohydrate derivative and at least one oligosiloxane as an additive to fire-fighting foams and / or concentrates.
- Example I relates to a surfactant according to the present invention having the structure:
- Example II relates to a surfactant according to the present invention having the structure:
- Example III relates to a surfactant according to the present invention having the structure:
- Example IV relates to a surfactant according to the present invention having the following structure
- Example V relates to a surfactant according to the present invention having the following structure
- Example VI refers to a surfactant according to the present invention having the structure:
- Example VII relates to a surfactant according to the present invention having the structure:
- Example VIII relates to a surfactant according to the present invention having the structure:
- Example IX relates to a surfactant according to the present invention having the structure:
- Example X refers to a surfactant according to the present invention having the structure:
- Example X The spreading behavior of a solution of 2 g / L Example X was investigated; it was found out that this connection is spreading. Similarly, for a solution of 2 g / L, Example X and 0.5 g / L SDS apply.
- Example XI refers to a surfactant according to the present invention having the structure:
- surfactants were selected which contain polyethylene glycol units instead of the carbohydrate residues.
- surfactant I As comparison surfactant I, a surfactant was selected which contains polyethylene glycol units instead of the carbohydrate residues. It has the following structure:
- siloxane glycoside surfactants shown in the examples can be prepared, inter alia, from the carbohydrates as follows: respectively.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing Compositions (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Paints Or Removers (AREA)
Description
Die vorliegende Erfindung betrifft das Gebiet der Feuerlöschschäume bzw. -schaumkonzentrate.The present invention relates to the field of fire-extinguishing foams.
Insbesondere bei Bränden größerer Flüssigkeitsmengen organischer Chemikalien wie z.B. Treibstoffen werden dem Löschwasser üblicherweise spezielle Schaummittel zugesetzt. Diese haben tensidische Eigenschaften und ermöglichen im Gegensatz zu herkömmlichen Löschschaummitteln die selbständige Benetzung der Brandgutoberfläche. Daher bilden solche sogenannten AFFF-Löschschäume (Aqueous Film Forming Foams) als besonderes Merkmal einen Wasserfilm auf der Oberfläche der brennenden Flüssigkeit aus. Die so entstehende Dampfsperre erschwert, dass die brennbare Flüssigkeit in die Gasphase übergeht und so das Feuer unterhält oder zünd- bzw. explosionsfähige Gasgemische bildet. Die für die AFFF-Schäume charakteristische Benetzungsfähigkeit ermöglicht dem Schaum zudem das Gleiten auf der Oberfläche der brennenden Flüssigkeit, so dass auch Stellen erreicht werden, auf denen der Löschschaum nicht direkt aufgetragen werden kann. Zudem schließt sich die Schaumfläche nach Störung (z.B. durch herabstürzende Gegenstände) wieder selbständig. Des Weiteren fließt und wirkt der Film auch in Bereichen, die nicht direkt von Schaum erreicht werden.Especially in fires of larger amounts of liquid organic chemicals such. Fuels are the extinguishing water usually added special foaming agents. These have surface-active properties and, in contrast to conventional extinguishing foams, permit the self-wetting of the surface of the burned material. Therefore, such a so-called AFFF (Aqueous Film Forming Foams) extinguishing foams form as a special feature a film of water on the surface of the burning liquid. The resulting vapor barrier makes it more difficult for the combustible liquid to pass into the gas phase and thus maintain the fire or form ignitable or explosive gas mixtures. The wetting ability characteristic of the AFFF foams also allows the foam to slide on the surface of the burning liquid so as to reach areas where the foam can not be applied directly. In addition, the foam surface closes after failure (for example, by falling objects) again independently. Furthermore, the film also flows and acts in areas that are not directly reached by foam.
Lange Zeit galt Perfluoroktylsulfonat (PFOS) bei derartigen Feuerlöschschäumen als ein Mittel der Wahl. Da es jedoch als toxisch, persistent und bioakkumulativ erkannt wurde, wurde seine Verwendung durch die EU-Richtlinie 2006/122/EG vom 12. 12. 2006 stark eingeschränkt. Löschschäume mit mehr als 50 ppm PFOS-Gehalt dürfen in der EU nicht mehr verwendet werden. Heute werden in AFFF verschiedene andere polyfluorierte Tenside als Ersatzprodukte für PFOS verwendet. Von diesen Tensiden wird bisher angenommen, dass sie nicht oder zumindest weniger bioakkumulativ und toxisch sind. Eine abschließende Bewertung steht diesbezüglich aber noch aus und das grundsätzliche Problem der Persistenz polyfluorierter Verbindungen bleibt in jedem Fall erhalten.For a long time, perfluorooctylsulfonate (PFOS) has been the drug of choice in such fire-fighting foams. However, as it was recognized to be toxic, persistent and bioaccumulating, its use was strengthened by EU Directive 2006/122 / EC of 12.12.2006 limited. Extinguishing foams with more than 50 ppm PFOS content must not be used in the EU. Today, various other polyfluorinated surfactants are used as substitutes for PFOS in AFFF. These surfactants are heretofore believed to be non-bioactive or at least less bioaccumulating and toxic. However, a final assessment is still pending and the fundamental problem of persistence of polyfluorinated compounds remains intact.
Es stellt sich somit die Aufgabe, alternative leistungsfähige AFFF-Feuerlöschschaumkonzentrate zu finden, die möglichst gleichwirkende, aber bevorzugt weniger toxische und bevorzugt halogenfreie Tenside enthalten.It is therefore the task of finding alternative high-performance AFFF fire-extinguishing foam concentrates which contain the most equally effective but preferably less toxic and preferably halogen-free surfactants.
Diese Aufgabe wird durch Anspruch 1 der vorliegenden Erfindung gelöst. Demgemäß wird ein Feuerlöschschaumkonzentrat vorgeschlagen, welches ein Tensid gemäss Anspruch 1 umfasst, enthaltend mindestens ein substituiertes oder unsubstituiertes Kohlenhydrat oder Kohlenhydratderivat sowie mindestens ein Oligosiloxan. Der Term "enthaltend" in diesem Zusammenhang bedeutet, dass sowohl das Kohlenhydrat oder Kohlenhydratderivat wie das Oligosiloxan Unterbestandteile eines größeren Moleküls sind und beide über kovalente Bindungen an den Rest des Moleküls angeknüpft sind.This object is solved by claim 1 of the present invention. Accordingly, a fire-extinguishing foam concentrate is proposed, which comprises a surfactant according to claim 1, containing at least one substituted or unsubstituted carbohydrate or carbohydrate derivative and at least one oligosiloxane. The term "containing" in this context means that both the carbohydrate or carbohydrate derivative and the oligosiloxane are subcomponents of a larger molecule and both are linked via covalent bonds to the remainder of the molecule.
Überraschenderweise hat sich herausgestellt, dass die Tenside nach Anspruch 1 zur Erzeugung von wasserfilmbildenden Feuerlöschschäumen geeignet sind und je nach Anwendung mindestens einer der folgenden Vorteile erreicht werden kann:
- Durch die hohe Wasserlöslichkeit der Kohlenhydrate ist die Gesamtmolekülgröße der erfindungsgemäßen Tenside bei ausreichender Löslichkeit hinreichend klein; kleine Moleküle sind bei den meisten Anwendungen bevorzugt, da ihre Diffusionskoeffizienten höher sind.
- Due to the high water solubility of the carbohydrates, the total molecular size of the surfactants of the invention is sufficiently small with sufficient solubility; Small molecules are preferred in most applications because their diffusion coefficients are higher.
Tenside sind u.a. aus der
- Die Tenside sind halogen-, insbesondere fluorfrei und lassen sich weitestgehend aus nachwachsenden Rohstoffen herstellen.
- Die Tenside ermöglichen die selbständige Bildung eines geschlossenen Wasserfilms auf der Oberfläche des Brandguts (z.B. Treibstoff): Als Dampfsperre behindert dieser Wasserfilm den Übergang der brennbaren Flüssigkeit in die Gasphase und minimiert auf diese Weise, dass das Brandgut das Feuer unterhält oder brand-/explosionsfähige Gasgemische bildet.
- Aufgrund der Wasserfilmbildung ist es besonders für Flüssigkeitsbrände geeignet, ohne poly- oder perfluorierte Verbindungen zu enthalten
- The surfactants are halogen-free, in particular fluorine-free and can be produced as far as possible from renewable raw materials.
- The surfactants enable the self-formation of a closed water film on the surface of the fire (eg fuel): As a vapor barrier, this water film impedes the transition of the flammable liquid into the gas phase and thus minimizes the fire that sustains the fire or flammable gas mixtures forms.
- Due to the formation of water film, it is particularly suitable for liquid fires, without containing poly- or perfluorinated compounds
Gemäß der Erfindung umfasst das Tensid ein Molekül ausgewählt aus der Gruppe enthaltend
- wobei A ein substituiertes oder unsubstituiertes Kohlenhydrat oder Kohlenhydratderivat mit ein bis vier Zuckereinheiten ist,
- B eine optionale Linkersubstruktur aus mindestens einem Atom oder eine Kette darstellt sowie C ein Oligosiloxan ist, bevorzugt ein Di-, Tri- oder Tetrasiloxan
- wherein A is a substituted or unsubstituted carbohydrate or carbohydrate derivative having one to four sugar units,
- B is an optional linker substructure of at least one atom or chain and C is an oligosiloxane, preferably a di-, tri- or tetrasiloxane
A ist ein substituiertes oder unsubstituiertes Kohlenhydrat oder Kohlenhydratderivat mit ein bis vier Zuckereinheiten. Bevorzugt sind Mono-, Di- und Trisaccharide, d.h. ein, zwei oder drei Zuckereinheiten.A is a substituted or unsubstituted carbohydrate or carbohydrate derivative having one to four sugar units. Preferred are mono-, di- and trisaccharides, i. one, two or three sugar units.
Des Weiteren kann Unterbestandteil A oder Teile des Unterbestandteils A auch aus Kohlenhydratderivaten wie z.B. die Zuckersäuren (Aldonsäuren, Uronsäuren oder Aldarsäuren), Zuckeralkoholen (Alditole), Aminozuckern oder Cyclitolen, sowie deren Ethern, Estern, Amiden oder Thioestern bestehen.Further, subcomponent A or parts of subcomponent A may also be derived from carbohydrate derivatives such as e.g. the sugar acids (aldonic acids, uronic acids or aldaric acids), sugar alcohols (alditols), aminosugars or cyclitols, and their ethers, esters, amides or thioesters.
Unter dem Term "Zuckereinheiten" oder "Kohlenhydrat" werden insbesondere Hexosen, Pentosen oder Cyclitole verstanden, die (bei Vorliegen von Di- oder höheren Sacchariden) bevorzugt miteinander glykosidisch verbunden sind.The term "sugar moieties" or "carbohydrate" is understood to mean, in particular, hexoses, pentoses or cyclitols, which (in the presence of di- or higher saccharides) are preferably linked to one another in a glycosidic manner.
Wie beschrieben, können die Kohlenhydrate substituiert oder unsubstituiert sein, wobei unsubstituierte Kohlenhydrate bevorzugt sind aufgrund der resultierenden höheren Wasserlöslichkeit.As described, the carbohydrates may be substituted or unsubstituted, with unsubstituted carbohydrates being preferred because of the resulting higher water solubility.
Sofern die Kohlenhydrate substituiert sind, sind Ethylenoxy-, Oligo(ethylenoxy)-, Methyl-, Ethyl-, Allyl- oder Acetylsubstituenten bevorzugt.If the carbohydrates are substituted, ethyleneoxy, oligo (ethyleneoxy), methyl, ethyl, allyl or acetyl substituents are preferred.
Bevorzugte Kohlenhydrate oder Kohlenhydratderivate im Sinne der vorliegenden Erfindung sind
bei Monosacchariden: Glucose, Glucosamin, Fructose, Galaktose
bei Disacchariden: Maltose, Isomaltose, Saccharose, Cellobiose, Lactose, Trehalose
bei Trisacchariden: Raffinose, Maltotriose, Isomaltotriose, Maltotriulose, Ciceritol
bei Cyclitolen: Inosite, Quebrachitol, Pinitol
bei Zuckersäuren: Gluconsäure, Glucuronsäure, Glucarsäure, Weinsäure, Galactonsäure, Galacturonsäure, Galactarsäure, Mannonsäure, Mannuronsäure, Mannarsäure, Fructonsäure, Fructuronsäure, Fructarsäure, Arabinonsäure, Arabinuronsäure, Arabinarsäure, Xylonsäure, Xyluronsäure, Xylarsäure, Ribonsäure, Riburonsäure, Ribarsäure, Ascorbinsäure
bei Alditolen: Sorbitol, Xylitol, Mannitol, Lactitol, Maltitol, Isomaltitol, Threitol, ErythritolPreferred carbohydrates or carbohydrate derivatives in the context of the present invention are
for monosaccharides: glucose, glucosamine, fructose, galactose
for disaccharides: maltose, isomaltose, sucrose, cellobiose, lactose, trehalose
for trisaccharides: raffinose, maltotriose, isomaltotriose, maltotriulose, ciceritol
for cyclitols: inositol, quebrachitol, pinitol
in the case of sugar acids: gluconic acid, glucuronic acid, glucaric acid, tartaric acid, galactonic acid, galacturonic acid, maleic acid, mannuronic acid, mannaric acid, fructonic acid, fructuronic acid, fructaric acid, arabinonic acid, arabinuronic acid, arabinaric acid, xylonic acid, xyluronic acid, xylaric acid, ribonic acid, riburonic acid, ribaric acid, ascorbic acid
for alditols: sorbitol, xylitol, mannitol, lactitol, maltitol, isomaltitol, threitol, erythritol
B ist eine optionale Linker-Substruktur aus mindestens einem Atom oder einer Kette, bevorzugt aus Kohlenstoff und/oder Stickstoff- und/oder Sauerstoffatomen (wobei O-O-Bindungen ausgeschlossen sein sollen).B is an optional linker substructure of at least one atom or chain, preferably of carbon and / or nitrogen and / or oxygen atoms (O-O bonds being excluded).
Diese Kette kann eine reine Alkylkette sein, d.h. B ist ein unsubstituierter oder ggf. alkylsubstituierter Alkylenrest.This chain may be a pure alkyl chain, i. B is an unsubstituted or optionally alkyl-substituted alkylene radical.
Alternativ kann B auch Ether-,Ester- oder Amidgruppen enthalten. Z.B kann B Glycerin, Poly- bzw. Oligoethylenglykol, Poly- bzw. Oligopropylenglykol, Pentaetythrit, Alkylamine oder Carbonsäuren als Substruktur enthalten.Alternatively, B may also contain ether, ester or amide groups. For example, B may contain glycerol, poly- or oligoethylene glycol, poly- or oligopropylene glycol, pentaerythritol, alkylamines or carboxylic acids as a substructure.
B ist mit Rest A bevorzugt glykosidisch über ein anomeres Kohlenstoffatom verbunden. Im Fall eines Carbonsäurederivates als A kann B auch über eine Amid- oder Esterbindung mit A verknüpft sein.B is preferably linked to residue A glycosidically via an anomeric carbon atom. In the case of a carboxylic acid derivative as A, B may also be linked to A via an amide or ester bond.
Mit Rest C (dem Siloxan) ist B bevorzugt über eine Si-C oder Si-O-Bindung verbunden.With residue C (the siloxane), B is preferably linked via an Si-C or Si-O bond.
Es sei darauf hingewiesen, dass bei einigen Tensiden gemäß der vorliegenden Erfindung Unterbestandteil B auch weggelassen werden kann, d.h. ggf. sind A und C direkt miteinander verknüpft.It should be noted that with some surfactants according to the present invention, subcomponent B may also be omitted, i. if necessary, A and C are directly linked.
Desweiteren kann bei einigen Tensiden gemäß der vorliegenden Erfindung der Rest B-C bzw. C auch an anderen regiochemischen Positionen des Kohlenhydrats oder Kohlenhydratderivats A angebunden sein.Furthermore, with some surfactants according to the present invention, the radical B-C or C may also be attached to other regiochemical positions of the carbohydrate or carbohydrate derivative A.
C ist ein Oligosiloxan, bevorzugt ein Di-, Tri- oder Tetrasiloxan. Dabei sind die Methyl und Ethylsiloxane oder gemischte Siloxane mit Methyl und Ethylresten bevorzugt.C is an oligosiloxane, preferably a di-, tri- or tetrasiloxane. The methyl and ethyl siloxanes or mixed siloxanes with methyl and ethyl radicals are preferred.
Falls C ein Tri- oder höheres Siloxan ist, kann C mit B (oder ggf. A) über eines der endständigen Siloxane verknüpft sein (so dass sich eine Art "durchgehende Kette" bildet), alternativ kann C mit B (oder ggf. A) auch über eines der mittelständigen Siloxane verknüpft sein, so dass sich eine Art X- bzw.T-förmige oder verzweigte Struktur bildet.
Falls C von einem Di- oder Trihydrosiloxan abgeleitet ist, können die mit C verbundenen Substrukturen A-B bzw. A gleichartig oder unterschiedlich sein.If C is a tri- or higher siloxane, C may be linked to B (or optionally A) via one of the terminal siloxanes (forming a kind of "continuous chain"), alternatively C may be combined with B (or optionally A ) may also be linked via one of the medium siloxanes, so that a type of X- or T-shaped or branched structure forms.
If C is derived from a di- or trihydrosiloxane, the substructures AB or A joined to C may be the same or different.
Bevorzugt hat C eine der folgenden Strukturen:
Gemäß einer bevorzugten Ausführungsform der vorliegenden Erfindung umfasst das Feuerlöschschaumkonzentrat noch einen oder mehr der folgenden Bestandteile: Schaumbildner, Filmbildner, Filmstabilisatoren, Frostschutzmittel Konservierungs- und Korrosionsschutzmittel, Lösungsvermittler sowie Puffer.According to a preferred embodiment of the present invention, the fire-fighting foam concentrate also comprises one or more of the following constituents: foaming agents, film formers, film stabilizers, antifreeze preservatives and corrosion inhibitors, solubilizers and buffers.
Im Folgenden werden diese Komponenten näher erläutert, wobei einzelne Merkmale oder Angaben beliebig kombiniert werden können.In the following, these components are explained in more detail, with individual features or specifications can be combined as desired.
Zur Verbesserung der Schaumbildung können Cotenside beigemischt werden. Insbesondere können dies sein: lineare Alkylbenzolsulfonate, sekundäre Alkansulfonate, Natriumalkylsulfonate, α-Olefmsulfonate, Sulfobernsteinsäureester, α-Methylestersulfonate, Alkoholethoxylate, Alkylphenolethoxylate, Fettalkohol-ethylenoxid-/propylenoxid-Addukte, Glycosid-Tenside (z.B. Glucopon, dies ist besonders bevorzugt), Laurylsulfate, Laurethsulfate, Imidazoliumsalze, Lauriminodipropionat, Acrylcopolymere.
Als Gegenionen für die in dieser Liste enthaltenen anionischen Tenside kommen vor allem in Betracht Li+, Na+, K+, NH4 +, N(C2H5)4 + To improve the foaming cosurfactants can be added. In particular, these may be: linear alkylbenzenesulfonates, secondary alkanesulfonates, sodium alkylsulfonates, α-olefmsulfonates, sulfosuccinic acid esters, α-methyl ester sulfonates, alcohol ethoxylates, alkylphenol ethoxylates, fatty alcohol ethylene oxide / propylene oxide adducts, Glycoside surfactants (eg, glucopone, this is particularly preferred), lauryl sulfates, laureth sulfates, imidazolium salts, lauriminodipropionate, acrylic copolymers.
Suitable counterions for the anionic surfactants present in this list are, in particular, Li + , Na + , K + , NH 4 + , N (C 2 H 5 ) 4 +
Zur Verbesserung der Film- und Schaumeigenschaften können dem Schaummittelkonzentrat unter anderem folgende Bestandteile zugemischt werden: Polysaccharide, Alginate, Xanthangummi, StärkederivateTo improve the film and foam properties, the foaming agent concentrate may, inter alia, be admixed with the following constituents: polysaccharides, alginates, xanthan gum, starch derivatives
Zur Verbesserung der Frostbeständigkeit und der Anwendungsfähigkeit bei tiefen Temperaturen können dem Schaummittelkonzentrat unter anderem folgende Bestandteile zugemischt werden: Ethylenglycol, Propylenglycol, Glycerin, 1-Propanol, 2-Propanol, Harnstoff, anorganische SalzeTo improve the frost resistance and the low temperature applicability, the foaming agent concentrate may be admixed with, inter alia, the following components: ethylene glycol, propylene glycol, glycerol, 1-propanol, 2-propanol, urea, inorganic salts
Zur Verbesserung der Lagerungsbeständigkeit und zum Schutz der Aufbewahrungsgefäße und -apparaturen können dem Schaummittelkonzentrat unter anderem folgende Bestandteile zugemischt werden:
Formaldehydlösung, Alkylcarbonsäuresalze, Ascorbinsäure, Salicylsäure, TolyltriazoleIn order to improve the storage stability and to protect the storage vessels and apparatus, the foam concentrate may be admixed inter alia with the following components:
Formaldehyde solution, alkylcarboxylic acid salts, ascorbic acid, salicylic acid, tolyltriazoles
Zur Verbesserung der Löslichkeit der Bestandteile können dem Schaummittelkonzentrat unter anderem folgende Bestandteile zugemischt werden:
Butylglycol, Butyldiglycol, HexylenglycolTo improve the solubility of the constituents, the foam concentrate may be admixed with, inter alia, the following constituents:
Butyl glycol, butyl diglycol, hexylene glycol
Die Siloxantenside sind hinsichtlich der Lagerfähigkeit pH-empfindlich. Eine Pufferung des Konzentrats auf einen pH-Wert von ca. 7 ist daher vorteilhaft. Puffersysteme können zum Beispiel sein:
- Kaliumdihydrogenorthophosphat/N atriumhydroxid,
- Tris(hydroxymethyl)aminomethan/Salzsäure,
- Dinatriumhydrogenphosphat/SalzsäureZitronensäure/Natriumhydroxid, Zitronensäure/Natriumacetat.
- Potassium dihydrogen orthophosphate / sodium hydroxide,
- Tris (hydroxymethyl) aminomethane / hydrochloric acid,
- Disodium hydrogen phosphate / hydrochloric acid citric acid / sodium hydroxide, citric acid / sodium acetate.
Die vorliegende Erfindung bezieht sich ebenfalls auf die Verwendung eines Tensids, enthaltend mindestens ein substituiertes oder unsubstituiertes Kohlenhydrat oder Kohlenhydratderivat sowie mindestens ein Oligosiloxan als Zusatz zu Feuerlöschschäumen und/oder -konzentraten.The present invention also relates to the use of a surfactant containing at least one substituted or unsubstituted carbohydrate or carbohydrate derivative and at least one oligosiloxane as an additive to fire-fighting foams and / or concentrates.
Die vorgenannten sowie die beanspruchten und in den Ausführungsbeispielen beschriebenen erfindungsgemäß zu verwendenden Bauteile unterliegen in ihrer Größe, Formgestaltung, Materialauswahl und technischen Konzeption keinen besonderen Ausnahmebedingungen, so dass die in dem Anwendungsgebiet bekannten Auswahlkriterien uneingeschränkt Anwendung finden können.The above-mentioned and the claimed components to be used according to the invention described in the exemplary embodiments are not subject to special conditions of size, shape, material selection and technical design, so that the selection criteria known in the field of application can be used without restriction.
Weitere Einzelheiten, Merkmale und Vorteile des Gegenstandes der Erfindung ergeben sich aus den Unteransprüchen sowie aus der nachfolgenden Beschreibung der zugehörigen Beispiele, die rein illustrativ und nicht beschränkend zu verstehen sind.Further details, features and advantages of the subject matter of the invention will become apparent from the subclaims and from the following description of the accompanying examples, which are purely illustrative and not restrictive.
Beispiel I bezieht sich auf ein Tensid gemäß der vorliegenden Erfindung mit folgender Struktur:
Das Spreitverhalten einer Lösung von 2 g/Lg/L Beispiel I wurde untersucht; es wurde herausgefunden, dass diese Verbindung spreitet.The spreading behavior of a solution of 2 g / Lg / L Example I was investigated; it was found out that this connection is spreading.
Dasselbe Verhalten zeigte eine Lösung von 2g/L Beispiel I und 0,5g/L SDS.The same behavior was demonstrated by a solution of 2 g / L Example I and 0.5 g / L SDS.
Beispiel II bezieht sich auf ein Tensid gemäß der vorliegenden Erfindung mit folgender Struktur:
Das Spreitverhalten einer Lösung von 2 g/L Beispiel II und 0,24 g/L SDS wurde untersucht; es wurde herausgefunden, dass diese Verbindung sehr schnell spreitet. Ein ähnliches Verhalten (allerdings nicht ganz so schnelles Spreiten) wurde für eine Lösung von 2 g/L Beispiel II und 0,25 g/L Hansanol NS 242 conc. (Natriumlaurethsulfat 2EO) gefunden. Eine Lösung von 500 mg/L Beispiel II und 6 g/L Glucopon 215 CS UP (Alkylpolyglykosid mit C8-C10 Alkylkettenlänge) wurde ebenfalls untersucht und es wurde herausgefunden, dass diese spreitet.The spreading behavior of a solution of 2 g / L Example II and 0.24 g / L SDS was investigated; it was found that this compound spreads very fast. A similar behavior (although not quite as fast spreading) was for a solution of 2 g / L Example II and 0.25 g / L Hansanol NS 242 conc. (Sodium laureth sulfate 2EO) found. A solution of 500 mg / L Example II and 6 g / L Glucopon 215 CS UP (alkyl polyglycoside with C8-C10 alkyl chain length) was also investigated and found to be spreading.
Beispiel III bezieht sich auf ein Tensid gemäß der vorliegenden Erfindung mit folgender Struktur:
Das Spreitverhalten einer Lösung von 2 g/L Beispiel III und 0,5 g/L SDS wurde untersucht; es wurde herausgefunden, dass diese Verbindung sehr schnell spreitet.The spreading behavior of a solution of 2 g / L Example III and 0.5 g / L SDS was investigated; it was found that this compound spreads very fast.
Beispiel IV bezieht sich auf ein Tensid gemäß der vorliegenden Erfindung mit folgender Struktur
Das Spreitverhalten einer Lösung von 2 g/L Beispiel IV wurde untersucht; es wurde herausgefunden, dass diese Verbindung sehr schnell spreitet.The spreading behavior of a solution of 2 g / L Example IV was investigated; it was found that this compound spreads very fast.
Dasselbe Verhalten zeigte eine Lösung von 2g/L Beispiel IV und 0,5g/L SDS.The same behavior was demonstrated by a solution of 2g / L Example IV and 0.5g / L SDS.
Beispiel V bezieht sich auf ein Tensid gemäß der vorliegenden Erfindung mit folgender Struktur
Das Spreitverhalten einer Lösung von 2 g/L Beispiel V und 0,5 g/L SDS wurde untersucht; es wurde herausgefunden, dass diese Verbindung sehr schnell spreitet.The spreading behavior of a solution of 2 g / L Example V and 0.5 g / L SDS was investigated; it was found that this compound spreads very fast.
Beispiel VI bezieht sich auf ein Tensid gemäß der vorliegenden Erfindung mit folgender Struktur:
Das Spreitverhalten einer Lösung von 2 g/L Beispiel VI und 0,5 g/L SDS wurde untersucht; es wurde herausgefunden, dass diese Verbindung sehr schnell spreitet.The spreading behavior of a solution of 2 g / L Example VI and 0.5 g / L SDS was investigated; it was found that this compound spreads very fast.
Beispiel VII bezieht sich auf ein Tensid gemäß der vorliegenden Erfindung mit folgender Struktur:
Das Spreitverhalten einer Lösung von ca. 250 mg/L Beispiel VII wurde untersucht; es wurde herausgefunden, dass diese Verbindung sehr schnell spreitet. Ähnliches gilt für eine Lösung von 500 mg/L Beispiel VII und 6 g/L Glucopon 215 CS UP (Alkylpolyglykosid mit C8-C10 Alkylkettenlänge).The spreading behavior of a solution of about 250 mg / L Example VII was investigated; it was found that this compound spreads very fast. The same applies to a solution of 500 mg / L Example VII and 6 g / L Glucopon 215 CS UP (alkyl polyglycoside with C8-C10 alkyl chain length).
Beispiel VIII bezieht sich auf ein Tensid gemäß der vorliegenden Erfindung mit folgender Struktur:
Das Spreitverhalten einer Lösung von 2 g/L Beispiel VIII und 0,5 g/L SDS wurde untersucht; es wurde herausgefunden, dass diese Verbindung spreitet.The spreading behavior of a solution of 2 g / L Example VIII and 0.5 g / L SDS was investigated; it was found out that this connection is spreading.
Dasselbe Verhalten zeigte eine Lösung von 2g/L Beispiel VIII und 6 g/L Glucopon 215 CS UP (Alkylpolyglykosid mit C8-C10 Alkylkettenlänge).The same behavior was demonstrated by a solution of 2 g / L Example VIII and 6 g / L Glucopon 215 CS UP (alkyl polyglycoside with C 8 -C 10 alkyl chain length).
Beispiel IX bezieht sich auf ein Tensid gemäß der vorliegenden Erfindung mit folgender Struktur:
Das Spreitverhalten einer Lösung von 2 g/L Beispiel IX und 0,5 g/L SDS wurde untersucht; es wurde herausgefunden, dass diese Verbindung spreitet.The spreading behavior of a solution of 2 g / L Example IX and 0.5 g / L SDS was investigated; it was found out that this connection is spreading.
Dasselbe Verhalten zeigte eine Lösung von 2g/L Beispiel IX und 6 g/L Glucopon 215 CS UP (Alkylpolyglykosid mit C8-C10 Alkylkettenlänge).The same behavior was shown by a solution of 2 g / L Example IX and 6 g / L Glucopon 215 CS UP (alkyl polyglycoside with C 8 -C 10 alkyl chain length).
Beispiel X bezieht sich auf ein Tensid gemäß der vorliegenden Erfindung mit folgender Struktur:
Das Spreitverhalten einer Lösung von 2 g/L Beispiel X wurde untersucht; es wurde herausgefunden, dass diese Verbindung spreitet. Desgleichen gilt für eine Lösung von 2 g/L Beispiel X und 0,5 g/L SDS.The spreading behavior of a solution of 2 g / L Example X was investigated; it was found out that this connection is spreading. Similarly, for a solution of 2 g / L, Example X and 0.5 g / L SDS apply.
Dasselbe Verhalten zeigte eine Lösung von 2g/L Beispiel X und 6 g/L Glucopon 215 CS UP (Alkylpolyglykosid mit C8-C10 Alkylkettenlänge).The same behavior was demonstrated by a solution of 2 g / L Example X and 6 g / L Glucopon 215 CS UP (alkyl polyglycoside with C 8 -C 10 alkyl chain length).
Beispiel XI bezieht sich auf ein Tensid gemäß der vorliegenden Erfindung mit folgender Struktur:
Das Spreitverhalten einer Lösung von 2 g/L Beispiel XI und 0,5 g/L SDS wurde untersucht; es wurde herausgefunden, dass diese Verbindung spreitet.The spreading behavior of a solution of 2 g / L Example XI and 0.5 g / L SDS was investigated; it was found out that this connection is spreading.
Dasselbe Verhalten zeigte eine Lösung von 2g/L Beispiel XI und 6 g/L Glucopon 215 CS UP (Alkylpolyglykosid mit C8-C10 Alkylkettenlänge).The same behavior was shown by a solution of 2 g / L Example XI and 6 g / L Glucopon 215 CS UP (alkyl polyglycoside with C8-C10 alkyl chain length).
Als Vergleichsbeispiele wurden Tenside gewählt, welche Polyethylenglykoleeinheiten anstatt der Kohlenhydratreste enthalten.As comparative examples, surfactants were selected which contain polyethylene glycol units instead of the carbohydrate residues.
Als Vergleichstensid I wurde ein Tensid gewählt, welches Polyethylenglykoleinheiten anstatt der Kohlenhydratreste enthält. Es hat folgende Struktur:
Es wurde eine Lösung von 2 g/L Vergleichsbeispiel I sowie 0,5 g/L SDS untersucht. Die Lösung sammelt sich am Boden der Schale, kein Spreiten wurde beobachtet. Dasselbe Verhalten zeigte eine Lösung von Vergleichsbeispiel I ohne SDS.A solution of 2 g / L Comparative Example I and 0.5 g / L SDS was investigated. The solution collects at the bottom of the dish, no spreading was observed. The same behavior was shown by a solution of Comparative Example I without SDS.
Als Vergleichsbeispiel II wurde eine Verbindung mit folgender Struktur gewählt:
Es wurde eine Lösung von 2 g/L Vergleichsbeispiel II sowie 0,5 g/L SDS untersucht. Die Lösung sammelt sich am Boden der Schale, kein Spreiten wurde beobachtet. Dasselbe Verhalten zeigte eine Lösung von Vergleichsbeispiel II ohne SDS.A solution of 2 g / L Comparative Example II and 0.5 g / L SDS was investigated. The solution collects at the bottom of the dish, no spreading was observed. The same behavior was shown by a solution of Comparative Example II without SDS.
Als Vergleichsbeispiel III wurde eine Verbindung mit folgender Struktur gewählt:
Es wurde eine Lösung von 2 g/L Vergleichsbeispiel III sowie 0,5 g/L SDS untersucht. Die Lösung sammelt sich am Boden der Schale, kein Spreiten wurde beobachtet. Dasselbe Verhalten zeigte eine Lösung von Vergleichsbeispiel III ohne SDS.A solution of 2 g / L Comparative Example III and 0.5 g / L SDS was investigated. The solution collects at the bottom of the dish, no spreading was observed. The same behavior was exhibited by a solution of Comparative Example III without SDS.
Als Vergleichsbeispiel IV wurde eine Verbindung mit folgender Struktur gewählt:
Es wurde eine Lösung von 2 g/L Vergleichsbeispiel IV sowie 0,5 g/L SDS untersucht. Die Lösung sammelt sich am Boden der Schale, kein Spreiten wurde beobachtet. Dasselbe Verhalten zeigte eine Lösung von Vergleichsbeispiel IV ohne SDS.A solution of 2 g / L Comparative Example IV and 0.5 g / L SDS was investigated. The solution collects at the bottom of the dish, no spreading was observed. The same behavior was exhibited by a solution of Comparative Example IV without SDS.
Die in den Beispielen gezeigten Siloxan-glycosidtenside können u.a. wie folgt aus den Kohlenhydraten hergestellt werden:
Zur Untersuchung des Spreitverhaltens wurden 5ml Cyclohexan in eine Petrischale mit 9 cm Durchmesser gegeben. Darauf wurde jeweils ein Tropfen der unverschäumten Tensidlösung gegeben und beobachtet, ob und wie sich die Tensidlösung auf der Oberfläche des Cyclohexans ausbreitet.To study the spreading behavior, 5 ml of cyclohexane were placed in a 9 cm diameter Petri dish. One drop each of the unfoamed surfactant solution was then added and observed as to whether and how the surfactant solution spreads on the surface of the cyclohexane.
Die einzelnen Kombinationen der Bestandteile und der Merkmale von den bereits erwähnten Ausführungen sind exemplarisch; der Austausch und die Substitution dieser Lehren mit anderen Lehren, die in dieser Druckschrift enthalten sind mit den zitierten Druckschriften werden ebenfalls ausdrücklich erwogen. Der Fachmann erkennt, dass Variationen, Modifikationen und andere Ausführungen, die hier beschrieben werden, ebenfalls auftreten können ohne von dem Erfindungsgedanken und dem Umfang der Erfindung abzuweichen. Entsprechend ist die obengenannte Beschreibung beispielhaft und nicht als beschränkend anzusehen. Das in den Ansprüchen verwendetet Wort umfassen schließt nicht andere Bestandteile oder Schritte aus. Der unbestimmte Artikel "ein" schließt nicht die Bedeutung eines Plurals aus. Die bloße Tatsache, dass bestimmte Maße in gegenseitig verschiedenen Ansprüchen rezitiert werden, verdeutlicht nicht, dass eine Kombination von diesen Maßen nicht zum Vorteil benutzt werde kann. Der Umfang der Erfindung ist in den folgenden Ansprüchen definiert und den dazugehörigen Äquivalenten.The individual combinations of the components and the features of the already mentioned embodiments are exemplary; the exchange and substitution of these teachings with other teachings contained in this document with the references cited are also expressly contemplated. Those skilled in the art will recognize that variations, modifications and other implementations described herein may also occur without departing from the spirit and scope of the invention. Accordingly, the above description is illustrative and not restrictive. The word used in the claims does not exclude others Components or steps. The indefinite article "a" does not exclude the meaning of a plural. The mere fact that certain measures are recited in mutually different claims does not make it clear that a combination of these dimensions can not be used to advantage. The scope of the invention is defined in the following claims and the associated equivalents.
Claims (4)
- Fire extinguishing foam concentrate comprising a surfactant which includes at least one substituted or unsubstituted carbohydrate or carbohydrate derivative and at least one oligosiloxane, wherein the surfactant comprises a molecule selected from the group includingA is a substituted or unsubstituted carbohydrate or carbohydrate derivative comprising one to four sugar units,B represents an optional linker substructure of at least one atom or a chain, andC is an oligosiloxane.
- Concentrate according to claim 1, wherein C is a di-, tri- or tetra-siloxane.
- Concentrate according to claim 1 or 2, wherein A represents a mono-, di- and trisaccharide, a sugar acid, an amino sugar or a cyclitol, or an ether, ester, amide or thioester of these compounds.
- Use of a surfactant including at least one substituted or unsubstituted carbohydrate or carbohydrate derivative and at least one oligosiloxane as an additive to fire extinguishing foams and/or concentrates, wherein the surfactant comprises a molecule selected from the group includingA is a substituted or unsubstituted carbohydrate or carbohydrate derivative comprising one to four sugar units,B represents an optional linker substructure of at least one atom or a chain, andC is an oligosiloxane.
Applications Claiming Priority (2)
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DE102011053304A DE102011053304A1 (en) | 2011-09-06 | 2011-09-06 | Siloxane-containing fire-extinguishing foam |
PCT/EP2012/067109 WO2013034521A1 (en) | 2011-09-06 | 2012-09-03 | Siloxane-containing fire extinguishing foam |
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EP2753403A1 EP2753403A1 (en) | 2014-07-16 |
EP2753403B1 true EP2753403B1 (en) | 2018-11-14 |
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EP12753148.1A Active EP2753403B1 (en) | 2011-09-06 | 2012-09-03 | Siloxane-containing fire extinguishing foam |
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EP (1) | EP2753403B1 (en) |
JP (1) | JP2014526941A (en) |
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DE102013102239A1 (en) * | 2013-03-06 | 2014-09-11 | Universität Zu Köln | Carbosilane-containing fire-extinguishing foam |
EP3126015B1 (en) | 2014-04-02 | 2020-08-19 | Tyco Fire Products LP | Fire extinguishing compositions |
DE102014112851A1 (en) | 2014-09-05 | 2016-03-10 | Universität Zu Köln | Silicon-containing organic acid derivatives as environmentally friendly AFFF extinguishing agents |
CN104607100B (en) * | 2015-01-23 | 2016-07-06 | 常熟理工学院 | A kind of glycosyl modified fluoro-silicone surfactant and preparation method thereof |
US11173334B2 (en) | 2016-03-18 | 2021-11-16 | Tyco Fire Products Lp | Polyorganosiloxane compounds as active ingredients in fluorine free fire suppression foams |
JP2019528814A (en) | 2016-07-29 | 2019-10-17 | タイコ・フアイヤー・プロダクツ・エルピー | Fire extinguishing foam composition containing deep eutectic solvent |
US11117008B2 (en) | 2018-04-24 | 2021-09-14 | The Government Of The United States Of America, As Represented By The Secretary Of The Navy | Siloxane and glucoside surfactant formulation for fire-fighting foam applications |
US11794048B2 (en) * | 2019-04-23 | 2023-10-24 | Tyco Fire Products Lp | Nonfluorinated agent for liquid vehicle systems |
SG11202012330XA (en) * | 2019-09-06 | 2021-04-29 | Hiow San Choo | Composition and method for extinguishing fire |
JPWO2021230143A1 (en) * | 2020-05-14 | 2021-11-18 | ||
CN111991744A (en) * | 2020-08-19 | 2020-11-27 | 西南石油大学 | Environment-friendly fluorine-free foam extinguishing agent and preparation method thereof |
US11420083B2 (en) | 2021-01-06 | 2022-08-23 | The Government Of The United States Of America, As Represented By The Secretary Of The Navy | Zwitterionic and glucoside surfactant formulations for fire-fighting foam applications |
US11673010B2 (en) | 2021-05-14 | 2023-06-13 | Tyco Fire Products Lp | Fire-fighting foam concentrate |
AU2022274252A1 (en) | 2021-05-14 | 2023-11-30 | Tyco Fire Products Lp | Fire-fighting foam composition with microfibrous cellulose |
US11673011B2 (en) | 2021-05-14 | 2023-06-13 | Tyco Fire Products Lp | Firefighting foam composition |
EP4337343A1 (en) | 2021-05-14 | 2024-03-20 | Tyco Fire Products LP | Fire-fighting foam composition |
US11497952B1 (en) | 2021-05-14 | 2022-11-15 | Tyco Fire Products Lp | Fire-fighting foam concentrate |
US11666791B2 (en) | 2021-05-14 | 2023-06-06 | Tyco Fire Products Lp | Fire-fighting foam composition |
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US9687686B2 (en) | 2017-06-27 |
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