EP2741077A1 - Capteur de gaz - Google Patents

Capteur de gaz Download PDF

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Publication number
EP2741077A1
EP2741077A1 EP14157313.9A EP14157313A EP2741077A1 EP 2741077 A1 EP2741077 A1 EP 2741077A1 EP 14157313 A EP14157313 A EP 14157313A EP 2741077 A1 EP2741077 A1 EP 2741077A1
Authority
EP
European Patent Office
Prior art keywords
protective cover
gas
equal
hole
gas hole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP14157313.9A
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German (de)
English (en)
Other versions
EP2741077B1 (fr
Inventor
Takayuki Sekiya
Mika Murakami
Tomoya Seimori
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NGK Insulators Ltd
Original Assignee
NGK Insulators Ltd
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Publication date
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Publication of EP2741077A1 publication Critical patent/EP2741077A1/fr
Application granted granted Critical
Publication of EP2741077B1 publication Critical patent/EP2741077B1/fr
Active legal-status Critical Current
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Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403—Cells and electrode assemblies
    • G01N27/406—Cells and probes with solid electrolytes
    • G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
    • G01N27/4077—Means for protecting the electrolyte or the electrodes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N11/00—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01M—TESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES; TESTING OF STRUCTURES OR APPARATUS, NOT OTHERWISE PROVIDED FOR
    • G01M15/00—Testing of engines
    • G01M15/04—Testing internal-combustion engines
    • G01M15/10—Testing internal-combustion engines by monitoring exhaust gases or combustion flame

Definitions

  • the present invention relates to a gas sensor.
  • a gas component such as NO x or oxygen
  • gas to be measured such as exhaust gas of an automobile
  • a protective cover is attached to the sensor element so as to cover the sensor element.
  • PTL 1 describes a gas sensor including a sensor element having a protective cover on the outer periphery of the free end portion of the sensor element.
  • the protective cover has a dual structure including a ventilation hole formed therein. The ventilation hole allows exhaust gas to enter the inside of the protective cover.
  • the present inventors discovered that in a gas sensor having a dual structure, adhesion of water to the sensor element can be sufficiently prevented by controlling a ratio A2/A1 defined by a ratio of an opening area A1 per first inner gas hole formed in a portion of the inner protective cover adjacent to the base end of the sensor element and an opening area A2 per second inner gas hole formed in a portion of the inner protective cover adjacent to the free end of the sensor element so that the ratio A2/A1 is in a predetermined range.
  • the goal of the present invention is achieved.
  • a gas sensor of the present invention comprises: a sensor element; an inner protective cover having a bottomed cylindrical shape, the inner protective cover having at least one first inner gas hole and at least one second inner gas hole formed therein and covering a top end of the sensor element; and an outer protective cover having a bottomed cylindrical shape, the outer protective cover having a plurality of outer gas holes formed therein and covering the inner protective cover; wherein the first inner gas hole is located so as to be closer to a base end of the sensor element than the second inner gas hole, and wherein a ratio A2/A1 defined by a ratio of an opening area A1 per first inner gas hole and an opening area A2 per second inner gas holes is higher than or equal to 0.9 and lower than or equal to 3.8.
  • the ratio A2/A1 is higher than or equal to 0.9 and lower than or equal to 3.8, adhesion of water to the sensor element can be sufficiently prevented. It is desirable that the ratio A2/A1 be higher than or equal to 1.5 and lower than or equal to 1.9. The ratio A2/A1 in this range can more effectively prevent adhesion of water to the sensor element.
  • the number of the first inner gas holes may be set to six.
  • the number of the second inner gas holes may be set to a value in the range from 3 to 6.
  • the first inner gas hole may serve as an inlet hole through which the gas to be measured flows into the inner protective cover
  • the second inner gas hole may serve as an outlet hole through which the gas to be measured flows out of the inner protective cover.
  • a ratio B2/B1 defined by a ratio of a total opening area B1 of the first inner gas holes to a total opening area B2 of the second inner gas holes be higher than or equal to 0.85.
  • the ratio B2/B1 in this range can reliably, effectively prevent adhesion of water to the sensor element.
  • adhesion of water to the sensor element can be more effectively prevented.
  • the ratio B2/B1 be higher than or equal to 1.5.
  • the total opening area B2 may be greater than or equal to 1.55 mm 2 or greater than or equal to 2.8 mm 2 .
  • a distance L between the center of the second inner gas hole and a bottom surface of the inner protective cover be less than or equal to 3 mm.
  • the distance L in this range can more reliably, effectively prevent adhesion of water to the sensor element.
  • adhesion of water to the sensor element can be more reliably prevented. It is more desirable that the distance L be less than or equal to 2.2 mm. It is still more desirable that the distance L be less than or equal to 1.1 mm.
  • the outer protective cover be a cover having a side surface and a bottom surface, each of the outer gas holes be formed in a boundary portion between the side surface and the bottom surface of the outer protective cover, and an angle ⁇ 1 formed by an external opening plane of the outer gas hole and the bottom surface of the outer protective cover be in the range from 10° to 80°.
  • the flow velocity dependency of the responsiveness of the sensor element can be reduced.
  • water that entered the outer protective cover can be easily drained to the outside through the outer gas hole, as compared with the case in which the hole is located in the side surface or the case in which an angle formed by the external opening plane of the outer gas hole and the bottom surface of the outer protective cover is outside the range from 10° to 80°.
  • entry of water into the outer protective cover and adhesion of water to the sensor element can be more effectively prevented.
  • the inner protective cover include a guide portion that regulates a flow of a gas to be measured flowing into the inner protective cover through the first inner gas hole, and a ratio R2/R1 defined by a ratio of a radius R1 representing a radius of a circumscribed circle of the sensor element, where the circumscribed circle is coaxial with the inner protective cover, to a radius R2 representing a radius of an inscribed circle of a plane including a regulation surface of the guide portion that regulates the flow of the gas to be measured, where the inscribed circle is coaxial with the inner protective cover, be higher than or equal to 1 and lower than or equal to 2.38.
  • the guide portion can prevent the gas to be measured that has passed through the first inner gas hole from flowing directly toward the sensor element.
  • adhesion of water to the sensor element and cooling of the sensor element due to the flow of the gas to be measured can be more effectively prevented.
  • the ratio R2/R1 to 2.38 or lower, a sufficient opening area of the first inner gas hole can be obtained.
  • the radius R2 may be greater than or equal to the width of the sensor element times 0.55 and less than or equal to the width times 1.30.
  • the gas sensor be fixed to the inside of the pipe such that the center axis of the inner protective cover is tilted from a vertical direction at an angle ⁇ 2 (0° ⁇ ⁇ 2 ⁇ 90°) and, when the second inner gas hole is projected onto a plane perpendicular to the center axis of the inner protective cover, a minimum value ⁇ 3 of an angle formed by a line extending between the center of the second inner gas hole and the center of the inner protective cover and a vertical line obtained by projecting a line extending from the center of the inner protective cover in the vertical downward direction onto the plane be greater than or equal to 0° and less than 45°.
  • the second inner gas hole is located in the inner protective cover closer to the vertically downward direction. Therefore, water is easily drained from the second inner gas hole. In this manner, adhesion of water to the sensor element can be more effectively prevented. It is more desirable that the minimum value ⁇ 3 be greater than or equal to 0° and less than or equal to 15°.
  • the gas sensor may be fixed to the inside of the pipe such that the center axis of the inner protective cover is perpendicular to the flow of the gas to be measured in the pipe and is tilted from the vertical direction at the angle ⁇ 2.
  • the gas sensor in which the minimum value ⁇ 3 is greater than or equal to 0° and less than 45° further include a housing that is fixed to the inside of the pipe using a fixing member and that fixes the inner protective cover.
  • a phase of the inner protective cover relative to the fixing member in the circumferential direction is defined so that the minimum value ⁇ 3 is set to a predetermined value by defining a fixed position of the housing relative to the fixing member using a pair of positioning portions, one formed in the housing and the other formed in the fixing member, and defining a fixed position of the inner protective cover relative to the housing using a pair of positioning portions, one formed in the inner protective cover and the other formed in the housing.
  • the pair of positioning portions may be formed from, for example, a pair consisting of a convex portion and a concave portion. By inserting the convex portion into the concave portion, position adjustment can be performed.
  • the gas sensor be fixed to the inside of the pipe such that the center axis of the inner protective cover is tilted from a vertical direction at an angle ⁇ 2 (0° ⁇ ⁇ 2 ⁇ 90°) and, when each of the outer gas holes is projected onto a plane perpendicular to the center axis of the outer protective cover, a minimum value ⁇ 4 of an angle formed by a line extending between the center of the outer gas hole and the center of the outer protective cover and a vertical line obtained by projecting a line extending from the center of the outer protective cover in the vertical downward direction onto the plane be greater than or equal to 0° and less than or equal to 30°.
  • the outer gas hole is located in the outer protective cover closer to the vertically downward direction. Therefore, water is easily drained from the outer gas hole. In this manner, adhesion of water to the sensor element can be more effectively prevented.
  • the gas sensor may be fixed to the inside of the pipe such that the center axis of the inner protective cover is perpendicular to the flow of the gas to be measured in the pipe and is tilted from a vertical direction at the angle ⁇ 2.
  • the gas sensor in which the minimum value ⁇ 4 is greater than or equal to 0° and less than or equal to 30° further include a housing that is fixed to the inside of the pipe using a fixing member and that fixes the outer protective cover.
  • a phase of the outer protective cover relative to the fixing member in the circumferential direction is defined so that the minimum value ⁇ 4 is set to a predetermined value by defining a fixed position of the housing relative to the fixing member using a pair of positioning portions, one formed in the housing and the other formed in the fixing member, and defining a fixed position of the outer protective cover relative to the housing using a pair of positioning portions, one formed in the outer protective cover and the other formed in the housing.
  • the pair of positioning portions may be formed from, for example, a pair consisting of a convex portion and a concave portion. By inserting the convex portion into the concave portion, position adjustment can be performed.
  • the gas sensor of the present invention further comprises: a first gas chamber; and a second gas chamber; wherein the outer protective cover includes a cylindrical body portion having a plurality of gas passing holes formed therein, a bottomed cylindrical free end portion having a diameter that is smaller than that of the body portion, and a stepped portion that connects the body portion to the free end portion, and wherein each of the outer gas holes is a hole formed in the free end portion, and wherein the first gas chamber is surrounded by the body portion and the stepped portion of the outer protective cover and the inner protective cover, and the first gas chamber communicates with the inside of the inner protective cover through the first inner gas hole, and wherein the second gas chamber is surrounded by the free end portion of the outer protective cover and the inner protective cover, the second gas chamber does not directly communicate with the first gas chamber, and the second gas chamber communicates with the inside of the inner protective cover through the second inner gas hole.
  • the outer protective cover includes a cylindrical body portion having a plurality of gas passing holes formed therein, a bottomed cylindrical
  • the inner protective cover may include a cylindrical first body portion having the first inner gas hole formed therein, a cylindrical second body portion, a bottomed cylindrical free end portion having the second inner gas hole formed therein, a first stepped portion that connects the first body portion to the second body portion, and a second stepped portion that connects the second body portion to the free end portion, and a free end of the sensor element may be located in a space surrounded by the first body portion.
  • the free end of the sensor element is located closer to the first inner gas hole, as compared with, for example, the case in which the free end of the sensor element is located in a space surrounded by the second body portion of the inner protective cover or the free end portion of the inner protective cover.
  • the responsiveness of the sensor element can be improved.
  • the first body portion, the second body portion, and the free end portion of the inner protective cover may be coaxial.
  • the diameter of the second body portion may be smaller than that of the first body portion, and the diameter of the free end portion may be smaller than that of the second body portion.
  • Fig. 1 is a schematic illustration of a gas sensor 100 attached to a pipe 200.
  • Fig. 1(a) is an illustration of the pipe 200 when viewed from the side
  • Fig. 1(b) is a cross-sectional view taken along a line A - A of Fig. 1(a) .
  • Fig. 2 is a cross-sectional view taken along a line B - B of Fig. 1(b)
  • Fig. 3 is a cross-sectional view taken along a line C - C of Fig. 2 .
  • Fig. 2 is an enlarged view of a portion of the cross section taken along the line B - B of Fig. 1(b) .
  • the gas sensor 100 is mounted in the pipe 200 serving as an exhaust path starting from the engine of a vehicle.
  • the gas sensor 100 detects the concentration of at least one of gas components, such as NO x and O 2 , contained in exhaust gas serving as the gas to be measured.
  • the gas sensor 100 is fixed to the inside of the pipe 200 so that the center axis of the gas sensor 100 is perpendicular to the flow of gas to be measured in the pipe 200 and is tilted at an angle of ⁇ 2 with respect to the vertical direction.
  • the angle ⁇ 2 is in the range of 0° ⁇ ⁇ 2 ⁇ 90°. According to the present embodiment, the angle ⁇ 2 is 45°.
  • the gas sensor 100 includes a sensor element 110 having a function of detecting the concentration of a gas component of gas to be measured and a protective cover 120 that protects the sensor element 110.
  • the gas sensor 100 includes a metal housing 102 and a metal nut 103 having a male screw on the outer circumferential surface thereof.
  • the housing 102 is inserted into a fixing member 202 that is welded to the pipe 200 and that has a female screw on the inner circumferential surface thereof.
  • the metal housing 102 is fixed to the fixing member 202. In this manner, the gas sensor 100 is fixed to the inside of the pipe 200.
  • the sensor element 110 has a shape of an elongated plate.
  • the sensor element 110 is made of an oxygen ion conductive solid electrolyte layer, such as a zirconia (ZrO 2 ) layer.
  • the sensor element 110 has a heater therein. The heater controls the temperature of the sensor element 110 by heating the sensor element 110 and maintains the temperature of the sensor element 110.
  • the configuration of the sensor element 110 and the principal for detecting the concentration of a gas component are widely known. For example, the configuration and the principal are described in Japanese Unexamined Patent Application Publication No. 2008-164411 .
  • the protective cover 120 is disposed so as to surround the periphery of the sensor element 110.
  • the protective cover 120 includes a bottomed cylindrical inner protective cover 130 that covers the free end portion of the sensor element 110.
  • the protective cover 120 further includes a bottomed cylindrical outer protective cover 140 that covers the bottomed cylindrical inner protective cover 130.
  • a space formed between the inner protective cover 130 and the outer protective cover 140 serves as a first gas chamber 122 and a second gas chamber 126.
  • a space surrounded by the inner protective cover 130 serves as a sensor element chamber 124. Note that the gas sensor 100, the inner protective cover 130, and the outer protective cover 140 are coaxial.
  • the inner protective cover 130 is formed from a metal member (e.g., a stainless steel member).
  • the inner protective cover 130 includes a large-diameter portion 132 having a cylindrical shape, a first body portion 134 having a cylindrical shape with a diameter that is smaller than that of the large-diameter portion 132, a second body portion 136 having a cylindrical shape with a diameter that is smaller than that of the first body portion 134, and a free end portion 138 having a bottomed cylindrical shape with a diameter that is smaller than that of the second body portion 136.
  • the inner protective cover 130 includes a stepped portion 133 that connects the large-diameter portion 132 to the first body portion 134, a stepped portion 135 that connects the first body portion 134 to the second body portion 136, and a stepped portion 137 that connects the second body portion 136 to the free end portion 138.
  • the large-diameter portion 132, the first body portion 134, the second body portion 136, and the free end portion 138 are coaxial.
  • the inner circumferential surface of the large-diameter portion 132 is in contact with the housing 102.
  • the inner protective cover 130 is fixed to the housing 102.
  • the first body portion 134 and the second body portion 136 are located so as to cover the side surface of the sensor element 110.
  • the first body portion 134 has six first inner gas holes 134a and six plate-like guide portions 134b formed therein (refer to Fig. 3 ).
  • Each of the first inner gas holes 134a allows the first gas chamber 122 to communicate with the sensor element chamber 124.
  • Each of the plate-like guide portions 134b regulates the flow of gas to be measured flowing into the sensor element chamber 124 through one of the first inner gas holes 134a.
  • the first inner gas holes 134a are disposed at equal intervals, and the plate-like guide portions 134b are disposed at equal intervals.
  • the side surface of the free end portion 138 has four second inner gas holes 138a formed at equal intervals. Each of the second inner gas holes 138a allows the sensor element chamber 124 to communicate with the second gas chamber 126.
  • the first inner gas holes 134a have one-to-one correspondence with the guide portions 134b.
  • Each of the guide portions 134b is formed so as to be located between the corresponding first inner gas hole 134a and the sensor element 110.
  • the guide portions 134b are formed so as to be rotationally symmetrical (6-fold rotational symmetry).
  • Fig. 4 illustrates the positional relationship among the sensor element 110 and the guide portions 134b.
  • R1 be the radius of a circumscribed circle of the sensor element 110 (the circle is coaxial with the inner protective cover 130), and let R2 be the radius of an inscribed circle of planes each including the regulation surface of one of the guide portions 134b that regulate the flow of the gas to be measured (the circle is coaxial with the inner protective cover 130).
  • the guide portions 134b are formed so that a ratio R2/R1 is higher than or equal to 1 and lower than or equal to 2.38.
  • the guide portions 134b can prevent the gas to be measured that has passed through the first inner gas holes 134a from directly flowing toward the sensor element 110.
  • the term "opening area of the first inner gas hole 134a" refers to the opening area of the first inner gas hole 134a when viewed in a direction of the flow of the gas to be measured that passes through the first inner gas hole 134a. Accordingly, when the guide portion 134b is present, the opening area of the first inner gas hole 134a represents the opening area of the first inner gas hole 134a when viewed in a direction parallel to the regulation surface of the guide portion 134b.
  • Fig. 5 illustrates the positional relationship among the guide portions 134b and the sensor element 110 when the ratio R2/R1 is a value of 1.
  • Fig. 6 illustrates the positional relationship between the guide portion 134b and the sensor element 110 when the ratio R2/R1 is a value of 2.38.
  • an angle ⁇ 5 formed by the regulation surface of the guide portion 134b and the external opening plane of the first inner gas hole 134a may be greater than or equal to 25° and less than or equal to 67.5°.
  • the radius R2 may be greater than or equal to the width of the sensor element (i.e., the length of the sensor element in the right - left direction in Fig. 4 ) times 0.55 and less than or equal to the width times 1.30.
  • Each of the second inner gas holes 138a is formed so as to have a cross section that is perpendicular to the center axis of the second inner gas hole 138a is a true circle.
  • the second inner gas hole 138a is formed so that a distance L between the center of the second inner gas hole 138a and the bottom surface of the inner protective cover 130 (refer to Fig. 2 ) is 3 mm or less.
  • a distance L can further reliably prevent adhesion of water to the sensor element 110.
  • the distance L decreases, adhesion of water to the sensor element 110 can be more effectively prevented.
  • the distance L is 2.2 mm or less and, more preferably, the distance L is 1.1 mm or less.
  • a ratio A2/A1 defined by a ratio of an opening area A1 per first inner gas hole 134a and an opening area A2 per second inner gas hole 138a is higher than or equal to 0.9 and lower than or equal to 3.8.
  • the ratio A2/A1 is higher than or equal to 1.5 and lower than or equal to 1.9.
  • Such a range can further effectively prevent adhesion of water to the sensor element 110.
  • the term "opening area of the second inner gas hole 138a" refers to an opening area of the second inner gas hole 138a when viewed in a direction of the flow of the gas to be measured that passes through the second inner gas hole 138a.
  • the diameter of the second inner gas hole 138a is in the range including, but not limited to, from 0.6 mm to 1.2 mm.
  • a ratio B2/B1 defined by a ratio of a total opening area B1 of the first inner gas holes 134a (the opening area per hole x the number of holes (i.e., 6)) to a total opening area B2 of the second inner gas holes 138a (the opening area per hole x the number of holes (i.e., 4)) is 0.85 or higher.
  • Such a range can further reliably prevent adhesion of water to the sensor element 110.
  • the ratio B2/B1 increases, adhesion of water to the sensor element 110 can be more effectively prevented.
  • the ratio B2/B1 is 1.5 or higher.
  • the total opening area B2 may be greater than or equal to 1.55 mm 2 or may be greater than or equal to 2.8 mm 2 .
  • the outer protective cover 140 is formed from a metal member (e.g., a stainless steel member).
  • the outer protective cover 140 includes a cylindrical large-diameter portion 142, a cylindrical body portion 144 that is connected to the large-diameter portion 142 and that has a diameter smaller than that of the large-diameter portion 142, and a bottomed cylindrical free end portion 146 having a diameter that is smaller than that of the body portion 144.
  • the outer protective cover 140 includes a stepped portion 145 that connects the body portion 144 to the free end portion 146.
  • the center axes of the large-diameter portion 142, the body portion 144, and the free end portion 146 are the same as the center axis of the inner protective cover 130.
  • the inner circumferential surface of the large-diameter portion 142 is in contact with the housing 102 and the large-diameter portion 132.
  • the outer protective cover 140 is fixed to the housing 102.
  • the body portion 144 is located so as to cover the outer circumferential surfaces of the first body portion 134 and the second body portion 136.
  • the body portion 144 has six gas passing holes 144a formed therein at equal intervals. Each of the gas passing holes 144a allows the outside of the outer protective cover 140 to communicate with the first gas chamber 122.
  • Each of the gas passing holes 144a is a circular hole and is located in a first corner portion 144b which is a boundary portion between the side surface of the body portion 144 and the bottom surface of the stepped portion 145.
  • each of the gas passing holes 144a is formed so that the angle formed by the external opening plane of the gas passing hole 144a and the bottom surface of the stepped portion 145 is 45°, and the angle formed by the inner circumferential surface and the external opening plane of the gas passing hole 144a is 90°.
  • Such a structure can further effectively prevent water from entering the outer protective cover 140 and adhering to the sensor element 110.
  • the structure can reduce the flow velocity dependency of the responsiveness of the sensor element 110. Fig.
  • FIG. 7 is an enlarged partial cross-sectional view of the gas passing hole 144a and its vicinity illustrated in Fig. 2 .
  • the angle formed by the external opening plane of the gas passing hole 144a (a dashed line a) and the bottom surface of the stepped portion 145 (a dashed line b) is 45°.
  • the angle formed by an inner circumferential surface 144c of the gas passing hole 144a and the external opening plane of the gas passing holes 144a (the dashed line a) is 90°.
  • the free end portion 146 is located so as to cover the free end portion 138.
  • the inner circumferential surface of the free end portion 146 is in contact with the outer circumferential surface of the second body portion 136.
  • outer gas holes 146a that allow the outside of the outer protective cover 140 to communicate with the second gas chamber 126 are formed in a second corner portion 146b which is a boundary portion between the side surface and the bottom surface of the free end portion 146 at equal intervals.
  • Each of the outer gas holes 146a is a circular hole.
  • an angle ⁇ 1 formed by the external opening plane of the outer gas hole 146a and the bottom surface of the free end portion 146 is 45°.
  • the angle formed by an inner circumferential surface and the external opening plane of the outer gas hole 146a is 90°.
  • the structure can reduce the flow velocity dependency of the responsiveness of the sensor element 110.
  • the positional relationship between the outer gas hole 146a and the second inner gas hole 138a is determined so that the second inner gas hole 138a is located in a region other than a region in an extension of the outer gas hole 146a.
  • Fig. 8 is an enlarged partial cross-sectional view of the outer gas hole 146a and the second inner gas hole 138a and their vicinity illustrated in Fig. 2 . As illustrated in Fig.
  • a region 146c that receives the light appears in the bottom surface of the free end portion 138 of the inner protective cover 130.
  • the region 146c is referred to as a "region in an extension of the outer gas hole 146a".
  • the second inner gas hole 138a is located in a region other than the region 146c. Note that the areas of the opening portions of the six gas passing holes 144a are the same, and the areas of the opening portions of the six outer gas holes 146a are the same.
  • the area of the opening portion of one of the outer gas holes 146a is larger than the area of the opening portion of one of the gas passing holes 144a. Accordingly, since the number of the gas passing holes 144a is the same as the number of the outer gas holes 146a (i.e., 6), the total area of the outer gas holes 146a (the area per hole x the number of holes) is larger than the total area of the gas passing holes 144a. Note that each of the gas passing holes 144a and the outer gas holes 146a is formed so that the cross section that is perpendicular to the center axis thereof is a true circle.
  • the diameter of the gas passing hole 144a is in the range including, but not limited to, from 0.8 mm to 1.2 mm.
  • the diameter of the outer gas hole 146a is in the range from 0.8 mm to 1.2 mm.
  • the first gas chamber 122 is formed from a space surrounded by the stepped portions 133 and 135, the first body portion 134, the second body portion 136, the large-diameter portion 142, the body portion 144, and the stepped portion 145.
  • the sensor element chamber 124 is formed from a space surrounded by the inner protective cover 130.
  • the second gas chamber 126 is formed from a space surrounded by the stepped portion 137, and the free end portions 138 and 146. Note that since the inner circumferential surface of the free end portion 146 is in contact with the outer circumferential surface of the second body portion 136, the first gas chamber 122 does not directly communicate with the second gas chamber 126.
  • the flow of the gas to be measured when the gas sensor 100 having such a configuration detects a predetermined gas concentration is described next.
  • the gas to be measured flowing in the pipe 200 passes through any one of the gas passing holes 144a and enters the first gas chamber 122. Thereafter, the gas flows into the sensor element chamber 124 through any one of the first inner gas holes 134a. Subsequently, the gas to be measured flows from the sensor element chamber 124 into the second gas chamber 126 through any one of the second inner gas holes 138a and flows from the second gas chamber 126 to the outside through any one of the outer gas holes 146a.
  • Fig. 9 is an enlarged partial cross-sectional view of the free end portion of the gas sensor 100 and its vicinity illustrated in Fig. 1(b) .
  • Fig. 10 is a cross-sectional view taken along a line D - D of Fig. 9 .
  • Fig. 10 is a cross-sectional view of the free end portions 138 and 146 cut by a plane perpendicular to the center axis of the inner protective cover 130.
  • FIG. 10 also illustrates a vertical line obtained by projecting a line extending from the center of the inner protective cover 130 and the outer protective cover 140 in the vertically downward direction (refer to Fig. 9 ).
  • a minimum value ⁇ 3 of the angle formed by a line extending between the center of the second inner gas hole 138a and the center of the inner protective cover 130 and the vertical line obtained by projecting a line extending from the center of the inner protective cover 130 in the vertically downward direction onto the plane is greater than or equal to 0° and is less than 45°.
  • a minimum value ⁇ 3 of the angle formed by a line extending between the center of the second inner gas hole 138a and the center of the inner protective cover 130 and the vertical line obtained by projecting a line extending from the center of the inner protective cover 130 in the vertically downward direction onto the plane is greater than or equal to 0° and is less than 45°.
  • an angle formed by a line extending between the center of the second inner gas hole 138a and the center of the inner protective cover 130 and the vertical line is obtained for each of the four second inner gas holes 138a.
  • one hole having an angle of 0°, two holes having an angle of 90°, and one hole having an angle of 180° are found.
  • the minimum value ⁇ 3 of the angles is 0°.
  • the second inner gas hole 138a is located in the inner protective cover 130 closer to the vertically downward direction (the downward direction in Fig. 9 ). Therefore, water is easily drained from the second inner gas hole 138a. In this manner, adhesion of water to the sensor element 110 can be more effectively prevented.
  • the minimum value ⁇ 3 be greater than or equal to 0° and less than or equal to 15°.
  • a minimum value ⁇ 4 of the angle formed by a line extending between the center of the outer gas hole 146a and the center of the outer protective cover 140 and the vertical line obtained by projecting a line extending from the center of the outer protective cover 140 in the vertically downward direction onto the plane is greater than or equal to 0° and is less than or equal to 30°.
  • an angle formed by a line extending between the center of the outer gas hole 146a and the center of the outer protective cover 140 and the vertical line is obtained for each of the six outer gas holes 146a.
  • two holes having an angle of 30°, two holes having an angle of 90°, and two holes having an angle of 150° are found.
  • the minimum value ⁇ 4 of the angles is 30°.
  • the outer gas hole 146a is located in the outer protective cover 140 so as to be closer to the vertically downward direction (the downward direction in Fig. 9 ). Therefore, water is easily drained from the outer gas hole 146a. In this manner, adhesion of water to the sensor element 110 can be more effectively prevented.
  • Figs. 11 , 12, and 13 correspond to figures illustrating the inner protective cover 130 and the outer protective cover 140 rotated from those of Fig. 10 by 30°, 60°, and 90° in a clockwise circumferential direction, respectively.
  • FIG. 14 is an exploded view illustrating the housing 102 with the inner protective cover 130 and the outer protective cover 140 removed.
  • Fig. 15 illustrates a fracture cross-section of the housing 102 having the inner protective cover 130 and the outer protective cover 140 attached thereto. Note that for convenience of description, in Figs. 14 and 15 , components other than the housing 102, the nut 103, the inner protective cover 130, and the outer protective cover 140 are not illustrated. As illustrated in the drawings, the housing 102 has convex portions 102a, 102b, and 102c formed on the outer circumferential surface thereof.
  • the inner protective cover 130 has a concave portion 130a formed on the inner circumferential surface of the large-diameter portion 132
  • the outer protective cover 140 has a concave portion 140a formed on the inner circumferential surface of the large-diameter portion 142.
  • the convex portion 102a and the concave portion 130a form a pair of positioning portions.
  • the convex portion 102a interferes with the inner protective cover 130 and, therefore, the inner protective cover 130 cannot be attached. In this manner, control is performed so that the phase of the inner protective cover 130 relative to the housing 102 in the circumferential direction is always the same when the inner protective cover 130 is attached.
  • the convex portion 102b and the concave portion 140a form a pair of positioning portions.
  • the convex portion 102b is inserted into the concave portion 140a.
  • the position at which the outer protective cover 140 is fixed to the housing 102 is determined. In this manner, control is performed so that the phase of the outer protective cover 140 relative to the housing 102 in the circumferential direction is always the same when the outer protective cover 140 is attached.
  • FIG. 16 illustrates only the housing 102.
  • Fig. 16(a) is a side view of the housing 102
  • Fig. 16(b) is a view on an arrow E of Fig. 16(a).
  • Fig. 16(c) is a cross-sectional view taken along a line F - F of Fig. 16(b) .
  • Fig. 17 illustrates only the fixing member 202.
  • Fig. 17(a) is a top view of the fixing member 202
  • Fig. 17(b) is a cross-sectional view taken along a line G - G of Fig. 17(a) .
  • Fig. 16(a) is a side view of the housing 102
  • Fig. 16(b) is a view on an arrow E of Fig. 16(a).
  • Fig. 16(c) is a cross-sectional view taken along a line F - F of Fig. 16(b) .
  • Fig. 17 illustrates only the
  • the housing 102 has the convex portion 102c on the outer circumferential surface thereof.
  • the fixing member 202 has a concave portion 202a formed on the inner circumferential surface thereof. The convex portion 102c and the concave portion 202a form a pair of positioning portions.
  • the convex portion 102c is inserted into the concave portion 202a.
  • the position at which the housing 102 is fixed to the fixing member 202 is determined.
  • the housing 102 is inserted into the fixing member 202 so that the concave portion 202a faces the convex portion 102c.
  • the nut 103 is inserted into the fixing member 202 so that the housing 102 is attached. At that time, control is performed so that the phase of the housing 102 relative to the fixing member 202 in the circumferential direction is always the same when the housing 102 is attached.
  • the housing 102 is fixed to the fixing member 202 in place, and the inner protective cover 130 and the outer protective cover 140 are fixed to the housing 102 in place. Accordingly, when the gas sensor 100 is attached to the pipe 200 via the fixing member 202, the positions at which the inner protective cover 130 and the outer protective cover 140 are fixed to the fixing member 202 are always the same.
  • the gas sensor 100 when the gas sensor 100 is attached to the pipe 200, by simply attaching the gas sensor 100 to the pipe 200 so that the convex portion 102a is inserted into the concave portion 130a, the convex portion 102b is inserted into the concave portion 140a, and the convex portion 102c is inserted into the concave portion 202a without measuring the minimum values ⁇ 3 and ⁇ 4 and positioning the second inner gas holes 138a and the outer gas holes 146a, the minimum value ⁇ 3 and the minimum value ⁇ 4 can be easily set to the predetermined values.
  • the ratio A2/A1 is set so as to be higher than or equal to 0.9 and lower than or equal to 3.8 and, more preferably, higher than or equal to 1.5 and lower than or equal to 1.9. Accordingly, adhesion of water to the sensor element 110 can be sufficiently prevented.
  • the ratio B2/B1 is set so as to be higher than or equal to 0.85 and, more preferably, higher than or equal to 1.5. Accordingly, adhesion of water to the sensor element 110 can be more reliably prevented.
  • the distance L is set to shorter than or equal to 3 mm and, more preferably, shorter than or equal to 2.2 mm and, still more preferably, shorter than or equal to 1.1 mm, adhesion of water to the sensor element 110 can be more reliably effectively prevented.
  • the outer gas hole 146a is formed in the boundary portion between the side surface and the bottom surface of the free end portion 146, and the formed angle ⁇ 1 is set to 45°. Accordingly, entry of water into the inner protective cover 130 and adhesion of water to the sensor element 110 can be more effectively prevented. In addition, the flow velocity dependency of the responsiveness of the sensor element 110 can be reduced.
  • the ratio R2/R1 is greater than or equal to 1 and lower than or equal to 2.38, adhesion of water to the sensor element 110 and cooling of the sensor element 110 due to the flow of the gas to be measured can be more effectively prevented.
  • the minimum value ⁇ 3 is greater than or equal to 0° and less than 45°, water can be easily drained from the second inner gas hole 138a. Thus, adhesion of water to the sensor element 110 can be more effectively prevented.
  • the minimum value ⁇ 4 is greater than or equal to 0° and less than or equal to 30°, water can be easily drained from the outer gas hole 146a. Thus, adhesion of water to the sensor element 110 can be more effectively prevented.
  • the minimum value ⁇ 3 and the minimum value ⁇ 4 can be easily set to predetermined values.
  • first inner gas holes 134a and four second inner gas holes 138a the numbers of the holes are not limited thereto. For example, any number of holes greater than or equal to one can be employed.
  • first inner gas holes 134a that are not located at equal intervals can be employed, and the second inner gas holes 138a that are not located at equal intervals can be employed.
  • first inner gas holes 134a can have different opening areas, and the second inner gas holes 138a can have different opening areas.
  • the shapes of the first inner gas hole 134a and the second inner gas hole 138a are not limited to those of the above-described embodiment.
  • the numbers of the gas passing holes 144a and the outer gas holes 146a are not limited thereto.
  • three or more gas passing holes 144a may be formed at equal intervals, and three or more outer gas holes 146a may be formed at equal intervals.
  • two gas passing holes 144a and two outer gas holes 146a may be formed. Note that the gas passing holes 144a and the outer gas holes 146a may be formed at unequal intervals.
  • the angle formed by the external opening plane of the gas passing hole 144a and the bottom surface of the stepped portion 145 is not limited thereto.
  • the angle may be in the range from 10° to 80°. Even in such a case, if the gas passing hole 144a is located in the first corner portion 144b, water is easily drained from the gas passing hole 144a to the outside. Thus, adhesion of water to the sensor element 110 can be prevented. In addition, the flow velocity dependency of the responsiveness of the sensor element 110 can be reduced.
  • the angle ⁇ 1 formed by the external opening plane of the outer gas hole 146a and the bottom surface of the free end portion 146 is set to 45°.
  • the angle ⁇ 1 may be in the range from 10° to 80°. Even in such a case, if the outer gas hole 146a is located in the second corner portion 146b, water is easily drained to the outside through the outer gas hole 146a. Thus, adhesion of water to the sensor element 110 can be prevented. In addition, the flow velocity dependency of the responsiveness of the sensor element 110 can be reduced.
  • Fig. 19 is an enlarged partial cross-sectional view of the second inner gas hole and its vicinity when the second inner gas hole is located in a boundary portion between the side surface and the bottom surface of the inner protective cover. Note that in Fig. 19 , the same numbering is used for the components as in Fig. 8 and, therefore, detailed description of the components is not provided.
  • a second inner gas hole 238a is formed so that the angle formed by the external opening plane of the second inner gas hole 238a and the bottom surface of the free end portion 138 of the inner protective cover 130 is 45°, and the angle formed by the inner circumferential surface and the external opening plane of the second inner gas hole 238a is 90°.
  • the angle formed by the external opening plane of the second inner gas hole 238a and the bottom surface of the free end portion 138 of the inner protective cover 130 is not limited to 45°. The angle may be in the range from 10° to 80°.
  • Fig. 20 is an enlarged partial cross-sectional view of the second inner gas hole and its vicinity when the second inner gas hole is disposed in the side surface of the free end portion 138 at a position close to the bottom surface. Note that in Fig. 20 , the same numbering is used for the components as in Fig. 8 and, therefore, detailed description of the components is not provided.
  • a second inner gas hole 239a is disposed at a position spaced by a minimum distance from a corner portion 138b of the free end portion 138.
  • the lowest surface 239b of the second inner gas hole 239a and an inner bottom surface 138c of the free end portion 138 are coplanar.
  • FIG. 21 is an enlarged partial cross-sectional view of the second inner gas hole and its vicinity when the second inner gas hole is located in the bottom surface of the free end portion 138. Note that in Fig. 21 , the same numbering is used for the components as in Fig. 8 and, therefore, detailed description of the components is not provided.
  • a second inner gas hole 240a is a circular hole located at the center of the bottom surface of the free end portion 138.
  • the second inner gas hole may be disposed at a location other than the center of the bottom surface of the free end portion 138.
  • the second inner gas hole may be disposed in the bottom surface of the free end portion 138 at a location spaced by a minimum distance from the corner of the free end portion 138.
  • the second inner gas hole may be disposed in a region other than the region 146c by offsetting the phase of the position of the second inner gas hole from the phase of the position of the region 146c in an extension of the outer gas holes 146a about the center axis of the free end portion 138 when viewed in the center axis direction of the free end portion 138 (the up - down direction in Fig. 2 ).
  • Fig. 22 illustrates the position of the second inner gas hole in this case.
  • Fig. 22(a) is a partial cross-sectional view of the free end portion 138 and its vicinity.
  • Fig. 22(b) is a cross-sectional view taken along a line H - H of Fig. 22(a) . Note that in Fig.
  • second inner gas holes 241a are formed at equal intervals at locations spaced by minimum distances from the corner portion 138b of the bottom surface of the free end portion 138. Accordingly, when viewed in the center axis direction as illustrated in Fig. 22(b) , the second inner gas hole 241a is located so as to be in contact with the inner circumferential surface of the side portion of the free end portion 138.
  • the second inner gas hole 241a is disposed so that the phase of the position of the second inner gas hole 241a is offset from the phase of the position of the region 146c. In this manner, the second inner gas hole 241a is located so as not to overlap the region 146c. Even when the second inner gas hole 241a is formed in this manner, water negligibly reaches the inside of the sensor element chamber 124 as in the present embodiment, since the second inner gas hole 241a is formed at a location outside the region 146c.
  • the cross-sectional shape is not limited thereto.
  • the cross section perpendicular to the center axis may be elliptical or polygonal (e.g., rectangular).
  • the convex portion 102b and the concave portion 140a need not be formed. Even in such a case, the positional relationship among the fixing member 202, the housing 102, and the inner protective cover 130 can be controlled and, therefore, the minimum value ⁇ 3 can be easily set to a predetermined value. Similarly, the convex portion 102a and the concave portion 130a need not be formed.
  • the concave portion and the convex portion may be exchanged.
  • a positioning portion having any shape that can control the positional relationship among the fixing member 202, the housing 102, the inner protective cover 130, and the outer protective cover 140 can be employed.
  • the structure is not limited thereto.
  • the sensor element 110 extending only up to a space surrounded by the first body portion 134 of the inner protective cover 130 may be employed. That is, the free end of the sensor element 110 may be located in a space surrounded by the first body portion 134. In this manner, the free end of the sensor element 110 is located closer to the first inner gas hole 134a than in the case illustrated in Fig. 2 .
  • the responsiveness of the sensor element 110 can be improved.
  • the sensor element 110 may reach a space surrounded by the free end portion 138 of the inner protective cover 130. That is, the free end of the sensor element 110 may be located in the space surrounded by the free end portion 138.
  • the gas sensor 100 illustrated in Fig. 2 was produced. More specifically, the inner protective cover 130 had a thickness of 0.3 mm and an axis directional length of 17.7 mm.
  • the large-diameter portion 132 had an axis directional length of 1.8 mm.
  • the first body portion 134 had an axis directional length of 5.4 mm.
  • the second body portion 136 had an axis directional length of 5.6 mm.
  • the free end portion 138 had an axis directional length of 4.9 mm.
  • the large-diameter portion 132 had an outer diameter of 14.1 mm.
  • the first body portion 134 had an outer diameter of 11.8 mm.
  • the second body portion 136 had an outer diameter of 8.2 mm.
  • the free end portion 138 had an outer diameter of 5.9 mm.
  • the opening area A1 per first inner gas hole 134a was 0.3053 mm 2 .
  • the number of the first inner gas holes 134a was 6.
  • the value of the ratio R2/R1 was 4.35.
  • the distance between the center of the first inner gas hole 134a and the free end of the inner protective cover 130 was 3.65 mm.
  • Each of the second inner gas holes 138a had an inner diameter of 1.0 mm.
  • the number of the second inner gas holes 138a was 4.
  • the distance L was 1.1 mm.
  • the outer protective cover 140 had a thickness of 0.4 mm and an axis directional length of 24.2 mm.
  • the large-diameter portion 142 had an axis directional length of 6.1 mm.
  • the body portion 144 had an axis directional length of 8.5 mm.
  • the free end portion 146 had an axis directional length of 9.6 mm.
  • the large-diameter portion 142 had an outer diameter of 15.2 mm.
  • the body portion 144 had an outer diameter of 14.6 mm.
  • the free end portion 146 had an outer diameter of 8.7 mm.
  • Each of the gas passing holes 144a had an inner diameter of 1.0 mm.
  • the number of the gas passing holes 144a was 6.
  • the angle formed by the external opening plane of the gas passing hole 144a and the bottom surface of the stepped portion 145 was 45°.
  • Each of the outer gas holes 146a had an inner diameter of 1.2 mm. The number of the outer gas holes 146a was 6.
  • the angle ⁇ 1 formed by the outer gas hole 146a was 45°. Furthermore, the inner protective cover 130 and the outer protective cover 140 were attached to the housing 102 so that in a pipe, the minimum value ⁇ 3 was 0° and the minimum value ⁇ 4 was 30° (as illustrated in Fig. 10 ).
  • the gas sensor 100 produced in this manner was used for the experimental example 1. Note that the first inner gas holes 134a were formed at equal intervals, the second inner gas holes 138a are formed at equal intervals, the gas passing holes 144a were formed at equal intervals, and the outer gas holes 146a were formed at equal intervals. Still furthermore, the sensor element 110 of the produced gas sensor 100 was used for detecting a concentration of oxygen.
  • the inner diameter of the second inner gas hole, the number of the second inner gas holes, the distance L, the minimum value ⁇ 3, and the minimum value ⁇ 4 were changed as indicated by "Experimental Examples 2 to 16" in Table 1.
  • the positional relationship among the second inner gas holes 138a and the outer gas holes 146a in experimental examples 3, 6, and 7 is the same as that illustrated in Fig. 13 .
  • the positional relationships among the second inner gas holes 138a and the outer gas holes 146a in experimental examples 4 and 5 are illustrated in Figs. 24 and 25 , respectively.
  • the positional relationships among the second inner gas holes 138a and the outer gas holes 146a in experimental examples 2, 13 and 14 are illustrated in Fig. 26 .
  • the second inner gas holes 138a were formed at equal intervals.
  • An amount of water remaining in the protective cover and a heater power control value were measured for each of the gas sensors 100.
  • the measured values are illustrated in Table 1 and Figs. 27 and 28 .
  • the amount of water remaining in the protective cover and the heater power control value were measured in the following manner.
  • FIG. 29 illustrates how the water drain tests were conducted. Note that the upper section of Fig. 29 shows the entire configuration for the water drain test, and the lower section of Fig. 29 is a partial cross-sectional view illustrating the inclination of the gas sensor 100 with respect to a pipe 920. This test was conducted in the following manner. The gas sensor was attached to the pipe 920 having a vibration exciter 900 mounted thereon along a direction at an angle of 45° to the vertical direction.
  • a controller 940 that controls the output of a heater and a sensor output monitor 960 that measures the power control value of the heater were connected to the gas sensor 100.
  • water of 0.1 g (0.1 cc) was poured into the inner protective cover 130, and the vibration exciter 900 vibrated the pipe 920 in the center axis direction of the gas sensor 100 with a sine wave by changing the frequency in the range from 10 to 200 Hz.
  • an air blower 980 was operated under a predetermined drive condition. Thus, air was sent from the air blower 980 to the pipe 920. During blasting, control was performed so that the temperature of the heater in the sensor element 110 was 100°C.
  • the power control value of the heater was measured using the sensor output monitor 960. As the amount of water adhering to the sensor element 110 increases, the temperature of the sensor element 110 decreases. Thus, in order to increase the output of the heater, the heater power control value increases. In addition, the vibration was stopped at the same time as the operation of the air blower 980 was completed. Then, a total of water remaining inside the outer protective cover 140 and the inner protective cover 130 was measured as the amount of remaining water.
  • the predetermined drive condition for the air blower 980 was a condition in which an air flow of about 75 m/s was generated by an air blower and was sent to the pipe 920 for 3 seconds. Furthermore, in experimental examples 3 to 7, only the amount of remaining water was measured.
  • Fig. 27 is a graph illustrating a relationship between an area ratio A2/A1 and the amount of remaining water.
  • Fig. 28 is a graph illustrating a relationship between the area ratio A2/A1 and the heater power control value.
  • Table 1 and Fig. 27 in experimental examples 1 to 10 and experimental examples 12 to 15 in which the area ratio A2/A1 is higher than or equal to 0.9 and lower than or equal to 3.8, the amount of remaining water is smaller than that in experimental example 11 in which the area ratio A2/A1 is lower than 0.9.
  • the amount of remaining water is smaller than that in experimental example 16 in which the area ratio A2/A1 is higher than 3.8.
  • the amount of remaining water is generally smaller than those in experimental examples 11 to 16 in which the total area ratio B2/B1 is about 0.8.
  • a comparison of experimental examples 3, 6, and 7 in which only the distances L differ from one another indicates that the amount of remaining water in experimental examples 3 and 6 in which the distance L is less than or equal to 3 mm is smaller than that in experimental example 7 in which the distance L is greater than 3 mm and, in particular, the amount of remaining water in experimental example 3 in which the distance L is less than or equal to 1.1 mm is small.
  • a comparison of experimental examples 6 and 8 in which conditions other than the distances L are relatively close to each other indicates that the amount of remaining water in experimental example 8 in which the distance L is less than or equal to 2.2 mm is smaller than that in experimental example 6.
  • a comparison of experimental examples 13 and 14 in which conditions other than the distances L are the same indicates that the amount of remaining water in experimental example 13 in which the distance L is less than or equal to 1.1 mm is smaller than that in experimental example 14.
  • a comparison of experimental examples 3 to 5 in which the minimum values ⁇ 3 differ from one another indicates that the amount of remaining water in experimental examples 3 and 4 in which the minimum value ⁇ 3 is less than 45° is smaller than that in experimental example 5 in which the minimum value ⁇ 3 is 45°.
  • the amount of remaining water in experimental example 3 in which the minimum value ⁇ 3 is 0° is small.
  • the amount of remaining water in each of experimental examples 1 to 10 and experimental examples 12, 13, and 15 is smaller than those in experimental examples 11 and 16.
  • the heater power control value in each of experimental examples 1 to 10 and experimental examples 12, 13, and 15 is smaller than that in experimental example 16.
  • the increase ratio of the heater power control value in each of experimental examples 1 to 10 and experimental examples 12 to 15 to that in experimental example 11 is relatively smaller than the decrease ratio of the amount of remaining water in each of experimental examples 1 to 10 and experimental examples 12 to 15 to that in experimental example 11.
  • the water drain test of the evaluation test 1 was conducted for each of experimental examples 18, 20, 21, 23, 25, and 26.
  • the results of the water drain test are shown in Table 1 and Fig. 31 in addition to the results of experimental examples 1 and 3.
  • a gas sensor is attached to the pipe 200 first. Thereafter, instead of passing exhaust gas emitted from an engine, reference gas serving as the gas to be measured was passed through the pipe 200 until the sensor output was stabilized.
  • the reference gas was controlled so as to have an NO concentration of 70 ppm and Lambda of 1.05 by burner firing. Subsequently, oxygen was introduced into the reference gas through a gas inlet port. Thus, gas mixture having an NO concentration of 70 ppm and Lambda of 1.35 was passed through the pipe 200 until the sensor output was stabilized.
  • the sensor element 110 functioned as an oxygen concentration cell and, therefore, an electro motive force was generated. Accordingly, the sensor output rose.
  • a time period t10 from when the oxygen was introduced into the reference gas to when the sensor output rose to 10% of the maximum value at the rise time and a time period t90 from when the oxygen was introduced into the reference gas to when the sensor output rose to 90% of the maximum value at the rise time were obtained.
  • the response time decreases, the responsiveness of the gas sensor increases. Note that the test was conducted using the pipe 200 having a diameter of 28 mm for the gas sensors of experimental example 1, experimental examples 17 to 20, experimental example 3, experimental examples 22 to 24, and experimental example 26.
  • Fig. 31 is a graph illustrating a relationship between the rotation angle of the inner protective cover and the amount of remaining water.
  • Fig. 32 is a graph illustrating a relationship between the rotation angle of the inner protective cover and the response time when the diameter of the pipe is 28 mm.
  • Fig. 33 is a graph illustrating a relationship between the rotation angle of the inner protective cover and the response time when the diameter of the pipe is 55 mm.
  • Table 2 and Fig. 31 when the rotation angle of the inner protective cover is 45° (when the minimum value ⁇ 3 is 45°), the value of the amount of remaining water reaches a maximum value (a peak value).
  • the amount of remaining water decreases.
  • the amount of remaining water in experimental examples 3, 21, 23, 25, and 26 in which the minimum value ⁇ 4 is 0° is generally smaller than that in experimental examples 1, 18, and 20 in which the minimum value ⁇ 4 is 30°.
  • a comparison of experimental examples in which the minimum values ⁇ 3 are the same indicates that the amount of remaining water in experimental example in which the minimum value ⁇ 4 is closer to 0° is smaller than that in another experimental example.
  • the response time in experimental examples 1, 17, 18, 19, and 20 in which the minimum value ⁇ 4 is 30° is shorter than that in experimental examples 3, 22, 23, 24, and 26 in which the minimum value ⁇ 4 is 0°.
  • the increase ratio of a response time in experimental examples 3, 22, 23, 24, and 26 to that in experimental examples 1, 17, 18, and 19 is relatively lower than the increase ratio of an amount of remaining water in experimental examples 3, 22, 23, 24, and 26 to that in experimental examples 1, 17, 18, and 19.
  • experimental examples 1 to 10, experimental examples 12 to 15, and experimental examples 17 to 26 correspond to the examples of the present invention, while experimental examples 11 and 16 correspond to comparative examples of the present invention.
  • a plurality of gas sensors 700 illustrated in Fig. 34 were produced.
  • Each of the gas sensors 700 includes an inner protective cover 730 and an outer protective cover 740 those serve as a protective cover 720.
  • the inner protective cover 730 has a structure that is similar to the structure of the inner protective cover 130 illustrated in Fig. 2 with the exception that the shapes of a free end portion 738 and a second inner gas hole 738a differ from those of the free end portion 138 and the second inner gas holes 138a, respectively, and, in addition, the inner protective cover 730 does not have the stepped portion 137. Accordingly, the same numbering is used for the components other than the free end portion 738 and the second inner gas hole 738a as in Fig. 2 and, therefore, detailed description of the components is not provided.
  • the free end portion 738 has a shape of an upside-down truncated triangular pyramid.
  • the inner diameter of a portion connected to the second body portion 136 is 7.4 mm.
  • the diameter of the bottom surface is 2.4 mm.
  • the second inner gas hole 738a is a circular hole located at the central point of the bottom surface of the free end portion 738.
  • the second inner gas hole 738a has an inner diameter of 1 mm.
  • the outer protective cover 740 is similar to the outer protective cover 140 illustrated in Fig. 2 with the exception of a gas passing hole 744a and an outer gas hole 746a. Accordingly, the same numbering is used for the components other than the gas passing hole 744a and the outer gas hole 746a as in Fig.
  • the gas passing hole 744a is located in the side surface of the body portion 144, and the outer gas hole 746a is located in the side surface of the free end portion 146. Note that as in experimental example 1, six gas passing holes 744a and six outer gas holes 746a are formed at equal intervals.
  • a flow velocity dependency test was conducted for experimental example 1 and comparative example 1 in order to study a relationship between the flow velocity of the gas to be measured and the responsiveness of the sensor element. The results are shown in Figs. 35 and 36 .
  • the flow velocity dependency test was conducted in the following manner.
  • a gas sensor of each of experimental example 1 and comparative example 1 was attached to the pipe. Note that the pipe was filled with air. Air flow in the pipe was prevented for 310 seconds. Thereafter, the gas to be measured was passed in the pipe at a predetermined flow velocity. At that time, a time variation of the output of the sensor element was measured. When the output of the sensor element reached the maximum value, it was determined that the air in the protective cover was fully replaced with the gas to be measured. Then, the ratio of the output of the sensor element to the maximum value was computed as a gas replacement ratio in the protective cover. Such a gas replacement ratio was used for the time variation of the gas replacement ratio.
  • the time variation of the gas replacement ratio was obtained for each of the case in which the predetermined flow velocity of the gas to be measured was set to 90 m/s and the case in which the predetermined flow velocity of the gas to be measured was set to 10 m/s.
  • the difference between the time variations of the gas replacement ratio at the flow velocities of 90 m/s and 10 m/s decreases, the flow velocity dependency decreases.
  • the responsiveness tends not to decrease.
  • Fig. 35 is a graph illustrating a time variation of the gas replacement ratio when the flow velocity of the gas to be measured is 90 m/s.
  • Fig. 36 is a graph illustrating a time variation of the gas replacement ratio when the flow velocity of the gas to be measured is 10 m/s.
  • the gas replacement ratio in experimental example 1 more rapidly rises than that in comparative example 1 regardless of the flow velocity.
  • the rise of the gas replacement ratio in the case of a flow velocity of 10 m/s is more slowed down as the time passes than in the case of a flow velocity of 90 m/s.
  • a time variation of the gas replacement ratio is smaller than in comparative example 1 in both cases of the flow velocities of 90 m/s and 10 m/s. That is, since, in experimental example 1, the gas passing hole is formed in the first corner portion 144b and the outer gas hole is formed in the second corner portion 146b, the flow velocity dependency can be more reduced than in comparative example 1 in which the gas passing hole and the outer gas hole are formed in the side surfaces.
  • the present invention can be used as a gas sensor that detects the concentration of a specified gas such as NOx included in a gas to be measured such as an exhaust gas from an automobile.

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EP12192777.6A Active EP2594927B1 (fr) 2011-11-18 2012-11-15 Capteur de gaz
EP14157313.9A Active EP2741077B1 (fr) 2011-11-18 2012-11-15 Capteur de gaz

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Families Citing this family (14)

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Publication number Priority date Publication date Assignee Title
WO2014157279A1 (fr) 2013-03-28 2014-10-02 日本碍子株式会社 Capteur de gaz
DE102013212362A1 (de) * 2013-06-27 2014-12-31 Robert Bosch Gmbh Sensor zur Bestimmung eines Anteils einer Gaskomponente
KR101382056B1 (ko) * 2013-09-26 2014-04-04 주식회사 현대케피코 자동차용 산소센서의 보호튜브
DE102014212862A1 (de) * 2014-07-02 2016-01-07 Robert Bosch Gmbh Sensorvorrichtung zur Erfassung mindestens einer Eigenschaft eines fluiden Mediums und Verfahren zu dessen Bereitstellung
JP6233223B2 (ja) * 2014-07-17 2017-11-22 株式会社デンソー ガスセンサ
JP2016038351A (ja) * 2014-08-11 2016-03-22 ナブテスコ株式会社 センサ
EP3191834B1 (fr) * 2014-09-12 2024-09-04 Sensirion AG Dispositifs d'échantillonnage de souffle et procédés d'échantillonnage de souffle utilisant des capteurs
JP6654416B2 (ja) * 2014-12-02 2020-02-26 日本碍子株式会社 ガスセンサ
JP6454559B2 (ja) * 2015-02-04 2019-01-16 日本特殊陶業株式会社 ガスセンサ
JP6519517B2 (ja) 2016-04-18 2019-05-29 株式会社デンソー ガスセンサ
RU183094U1 (ru) * 2018-03-26 2018-09-11 Общество с ограниченной ответственностью "ЭРИС" Насадка датчика газоанализатора
FR3089632B1 (fr) * 2018-12-11 2020-12-11 Renault Sas Sonde de mesure d’une propriété d’un gaz
JP7261718B2 (ja) * 2019-10-03 2023-04-20 日本碍子株式会社 ガスセンサ
JP7239434B2 (ja) * 2019-10-03 2023-03-14 日本碍子株式会社 ガスセンサ及び保護カバー

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EP1046906A2 (fr) * 1999-04-19 2000-10-25 Ngk Insulators, Ltd. Senseur de gaz
EP1471346A1 (fr) * 2003-03-31 2004-10-27 Ngk Insulators, Ltd. Capteur de gaz
US20080028831A1 (en) * 2006-08-04 2008-02-07 Ngk Spark Plug Co., Ltd. Gas sensor
JP2008164411A (ja) 2006-12-28 2008-07-17 Ngk Insulators Ltd ＮＯｘ分解電極及びＮＯｘセンサの製造方法
EP2287598A1 (fr) * 2009-08-17 2011-02-23 NGK Insulators, Ltd. Capteur de gaz
EP2333534A2 (fr) * 2009-11-27 2011-06-15 NGK Insulators, Ltd. Capteur de détection de concentration de gaz avec un capot de protection
EP2388578A2 (fr) * 2010-05-18 2011-11-23 NGK Insulators, Ltd. Chapeau de protection d'un capteur de gaz

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JPS6058589U (ja) 1983-09-30 1985-04-23 日野自動車株式会社 キヤブロツク用アイボルトの取付構造
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JP4260324B2 (ja) * 1998-08-05 2009-04-30 日本特殊陶業株式会社 ガスセンサ
JP4194648B2 (ja) * 1999-07-23 2008-12-10 日本特殊陶業株式会社 ガスセンサ

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EP1046906A2 (fr) * 1999-04-19 2000-10-25 Ngk Insulators, Ltd. Senseur de gaz
JP2000304719A (ja) 1999-04-19 2000-11-02 Ngk Insulators Ltd ガスセンサ
EP1471346A1 (fr) * 2003-03-31 2004-10-27 Ngk Insulators, Ltd. Capteur de gaz
US20080028831A1 (en) * 2006-08-04 2008-02-07 Ngk Spark Plug Co., Ltd. Gas sensor
JP2008164411A (ja) 2006-12-28 2008-07-17 Ngk Insulators Ltd ＮＯｘ分解電極及びＮＯｘセンサの製造方法
EP2287598A1 (fr) * 2009-08-17 2011-02-23 NGK Insulators, Ltd. Capteur de gaz
EP2333534A2 (fr) * 2009-11-27 2011-06-15 NGK Insulators, Ltd. Capteur de détection de concentration de gaz avec un capot de protection
EP2388578A2 (fr) * 2010-05-18 2011-11-23 NGK Insulators, Ltd. Chapeau de protection d'un capteur de gaz

Also Published As

Publication number Publication date
EP2594927A2 (fr) 2013-05-22
EP2594927A3 (fr) 2013-08-07
EP2741077B1 (fr) 2020-09-16
JP5890765B2 (ja) 2016-03-22
JP2013127454A (ja) 2013-06-27
US9213014B2 (en) 2015-12-15
US20130126352A1 (en) 2013-05-23
EP2594927B1 (fr) 2016-10-19

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