EP2736869A4 - OBTAINING POLYOLS FROM SACCHARIDES - Google Patents

OBTAINING POLYOLS FROM SACCHARIDES

Info

Publication number
EP2736869A4
EP2736869A4 EP12817777.1A EP12817777A EP2736869A4 EP 2736869 A4 EP2736869 A4 EP 2736869A4 EP 12817777 A EP12817777 A EP 12817777A EP 2736869 A4 EP2736869 A4 EP 2736869A4
Authority
EP
European Patent Office
Prior art keywords
saccharides
polyols
generation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12817777.1A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2736869A2 (en
Inventor
John Q Chen
Tom N Kalnes
Joseph A Kocal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell UOP LLC
Original Assignee
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/192,907 external-priority patent/US20110312487A1/en
Priority claimed from US13/192,970 external-priority patent/US8222462B2/en
Application filed by UOP LLC filed Critical UOP LLC
Publication of EP2736869A2 publication Critical patent/EP2736869A2/en
Publication of EP2736869A4 publication Critical patent/EP2736869A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Saccharide Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EP12817777.1A 2011-07-28 2012-07-03 OBTAINING POLYOLS FROM SACCHARIDES Withdrawn EP2736869A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/192,907 US20110312487A1 (en) 2011-07-28 2011-07-28 Catalyst system for generation of polyols from saccharides
US13/192,970 US8222462B2 (en) 2011-07-28 2011-07-28 Process for generation of polyols from saccharides
PCT/US2012/045343 WO2013015955A2 (en) 2011-07-28 2012-07-03 Generation of polyols from saccharides

Publications (2)

Publication Number Publication Date
EP2736869A2 EP2736869A2 (en) 2014-06-04
EP2736869A4 true EP2736869A4 (en) 2015-01-07

Family

ID=47601711

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12817777.1A Withdrawn EP2736869A4 (en) 2011-07-28 2012-07-03 OBTAINING POLYOLS FROM SACCHARIDES

Country Status (6)

Country Link
EP (1) EP2736869A4 (pt)
CN (1) CN103608320A (pt)
BR (1) BR112013026705A2 (pt)
CA (1) CA2832741A1 (pt)
TW (1) TWI539994B (pt)
WO (1) WO2013015955A2 (pt)

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CN105073694B (zh) 2013-04-05 2017-04-26 国际壳牌研究有限公司 制备二醇的方法
US9884798B2 (en) 2013-04-05 2018-02-06 Shell Oil Company Process for the conversion of saccharide-containing feedstock
BR112015019100A2 (pt) 2013-04-26 2017-07-18 Shell Int Research processo para a preparação de monoetileno glicol a partir de sacarose, e, processo para a conversão de sacarose em frutose e/ou derivados de frutose
BR112016003939B1 (pt) * 2013-08-26 2021-02-23 Shell Internationale Research Maatschappij B.V. processo para a preparação de um composto
WO2015028593A1 (en) * 2013-08-30 2015-03-05 Shell Internationale Research Maatschappij B.V. Process for the conversion of saccharide-containing feedstock
CN106573860B (zh) * 2014-04-09 2020-10-27 马来西亚国家石油公司 含糖类的原料选择性转化为乙二醇的方法
CN105523890B (zh) 2014-09-28 2021-04-16 长春美禾科技发展有限公司 一种制备二元醇的方法
WO2016114658A1 (en) * 2015-01-13 2016-07-21 Avantium Knowledge Centre B.V. Process for preparing ethylene glycol from a carbohydrate
CN107438591B (zh) * 2015-01-13 2020-10-16 阿凡田知识中心有限公司 从碳水化合物源制备乙二醇的工艺
AU2016207242B2 (en) 2015-01-13 2018-09-13 Avantium Knowledge Centre B.V. Continuous process for preparing ethylene glycol from a carbohydrate source
CN107406359A (zh) 2015-01-13 2017-11-28 阿凡田知识中心有限公司 从碳水化合物制备乙二醇的工艺
EP3317242B1 (en) * 2015-06-30 2020-07-29 Shell International Research Maatschappij B.V. Process for the preparation of glycols
BR112018004546B1 (pt) * 2015-09-07 2021-10-13 Shell Internationale Research Maatschappij B.V. Processo para preparar glicóis a partir de uma matéria-prima que contém sacarídeo
WO2017085219A1 (en) 2015-11-19 2017-05-26 Shell Internationale Research Maatschappij B.V. Catalyst system and process for the production of glycols
US20180326405A1 (en) * 2015-11-19 2018-11-15 Shell Oil Company Catalyst system and process for the production of glycols
CN108348900B (zh) * 2015-11-19 2021-04-16 国际壳牌研究有限公司 用于产生二醇的催化剂系统和方法
CN108348899B (zh) * 2015-11-19 2021-06-04 国际壳牌研究有限公司 用于制造二醇的催化剂系统和方法
BR112018011713B1 (pt) 2015-12-09 2021-05-18 Shell Internationale Research Maatschappij B.V. processo contínuo para a preparação de etilenoglicol e 1,2-propilenoglicol do material de partida que compreende um ou mais sacarídeos
BR112018016284A2 (pt) 2016-02-09 2018-12-18 Shell Int Research processo para a produção de alquileno glicóis
WO2017153347A1 (en) * 2016-03-07 2017-09-14 Shell Internationale Research Maatschappij B.V. Process for recovering a metallic component
MY193158A (en) * 2016-06-03 2022-09-26 Iowa Corn Promotion Board Continuous processes for the highly selective conversion of aldohexose-yielding carbohydrate to ethylene glycol
CA3031857A1 (en) * 2016-08-04 2018-02-08 Shell Internationale Research Maatschappij B.V. Process for the production of glycols
EP3519379B1 (en) * 2016-09-29 2022-09-07 Shell Internationale Research Maatschappij B.V. Method for acid treatment conditioning of a catalyst in the production of glycols
US10647646B2 (en) * 2016-10-28 2020-05-12 Shell Oil Company Process for the production of glycols
WO2020055831A1 (en) 2018-09-13 2020-03-19 Shell Oil Company Start-up process for the production of glycols
BR112021004750A2 (pt) 2018-09-13 2021-06-01 Shell Internationale Research Maatschappij B.V. processo de desligamento para a produção de glicóis
WO2020212542A1 (en) 2019-04-17 2020-10-22 Shell Internationale Research Maatschappij B.V. Stirred injection mixing process
WO2023083948A1 (en) 2021-11-12 2023-05-19 Shell Internationale Research Maatschappij B.V. Process for separating glycol from diols
WO2023150656A1 (en) 2022-02-04 2023-08-10 Shell Usa, Inc. Process for producing glycol from renewable feedstock

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EP2017250A1 (en) * 2006-05-09 2009-01-21 Kao Corporation Process for producing product of hydrogenolysis of polyhydric alcohol
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US20100256424A1 (en) * 2008-10-24 2010-10-07 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Method of preparing ethylene glycol cellulose
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EP2548858A1 (en) * 2010-03-17 2013-01-23 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Process for preparing ethylene glycol from polyhydric compounds
WO2013015990A2 (en) * 2011-07-28 2013-01-31 Uop Llc Catalytic process for continuously generating polyols

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EP2017250A1 (en) * 2006-05-09 2009-01-21 Kao Corporation Process for producing product of hydrogenolysis of polyhydric alcohol
US20100256424A1 (en) * 2008-10-24 2010-10-07 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Method of preparing ethylene glycol cellulose
WO2011050691A1 (zh) * 2009-10-27 2011-05-05 中国科学院大连化学物理研究所 一种介孔炭担载的碳化钨催化剂及其制备和应用
CN101768050A (zh) * 2009-12-25 2010-07-07 北京大学 一种生产乙二醇和1，2-丙二醇的方法
EP2548858A1 (en) * 2010-03-17 2013-01-23 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Process for preparing ethylene glycol from polyhydric compounds
WO2013015990A2 (en) * 2011-07-28 2013-01-31 Uop Llc Catalytic process for continuously generating polyols

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Also Published As

Publication number Publication date
WO2013015955A3 (en) 2013-03-21
BR112013026705A2 (pt) 2016-12-27
TW201315540A (zh) 2013-04-16
WO2013015955A2 (en) 2013-01-31
CA2832741A1 (en) 2013-01-31
EP2736869A2 (en) 2014-06-04
TWI539994B (zh) 2016-07-01
CN103608320A (zh) 2014-02-26

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