EP2678282B1 - Process for preparing hybrid sol-gel coated glass containers - Google Patents
Process for preparing hybrid sol-gel coated glass containers Download PDFInfo
- Publication number
- EP2678282B1 EP2678282B1 EP12718440.6A EP12718440A EP2678282B1 EP 2678282 B1 EP2678282 B1 EP 2678282B1 EP 12718440 A EP12718440 A EP 12718440A EP 2678282 B1 EP2678282 B1 EP 2678282B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- gel
- degrees celsius
- set forth
- silane
- hybrid sol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011521 glass Substances 0.000 title claims description 135
- 238000004519 manufacturing process Methods 0.000 title description 13
- 238000000576 coating method Methods 0.000 claims description 108
- 239000011248 coating agent Substances 0.000 claims description 89
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 36
- 229910000077 silane Inorganic materials 0.000 claims description 36
- 239000002904 solvent Substances 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- 230000000903 blocking effect Effects 0.000 claims description 10
- 229940075894 denatured ethanol Drugs 0.000 claims description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical class CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- ZZNQQQWFKKTOSD-UHFFFAOYSA-N diethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OCC)(OCC)C1=CC=CC=C1 ZZNQQQWFKKTOSD-UHFFFAOYSA-N 0.000 claims description 7
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 claims description 7
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 6
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 claims description 6
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 5
- -1 cerium alkoxide Chemical class 0.000 claims description 5
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 claims description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 claims description 4
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical class CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 3
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 3
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 claims description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical class C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 3
- 150000004703 alkoxides Chemical class 0.000 claims description 3
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 claims description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 229910002113 barium titanate Inorganic materials 0.000 claims description 2
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 claims description 2
- 229910000416 bismuth oxide Inorganic materials 0.000 claims description 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 2
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- UWNCQPGIQLKINJ-UHFFFAOYSA-N 2,2-dimethoxyethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound C(C1CO1)OCCC[SiH2]OCC(OC)OC UWNCQPGIQLKINJ-UHFFFAOYSA-N 0.000 claims 2
- ZYAASQNKCWTPKI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propan-1-amine Chemical compound CO[Si](C)(OC)CCCN ZYAASQNKCWTPKI-UHFFFAOYSA-N 0.000 claims 2
- 239000000499 gel Substances 0.000 description 94
- 238000000137 annealing Methods 0.000 description 18
- 239000012634 fragment Substances 0.000 description 14
- 238000001000 micrograph Methods 0.000 description 12
- 239000000758 substrate Substances 0.000 description 11
- 238000004132 cross linking Methods 0.000 description 9
- 230000014759 maintenance of location Effects 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 238000005728 strengthening Methods 0.000 description 4
- 238000011144 upstream manufacturing Methods 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000035876 healing Effects 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 150000004756 silanes Chemical class 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- SIWNOIGHWNVCHR-UHFFFAOYSA-N diethoxy(dimethyl)silane;triethoxy(methyl)silane Chemical compound CCO[Si](C)(C)OCC.CCO[Si](C)(OCC)OCC SIWNOIGHWNVCHR-UHFFFAOYSA-N 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 1
- RVHXCFKEGYLMJW-UHFFFAOYSA-N CO.CO[Si](OC)(OC)c1ccccc1.CO[Si](OC)(c1ccccc1)c1ccccc1 Chemical compound CO.CO[Si](OC)(OC)c1ccccc1.CO[Si](OC)(c1ccccc1)c1ccccc1 RVHXCFKEGYLMJW-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- UWONUAJRKDRMBC-UHFFFAOYSA-N diethoxy(diphenyl)silane triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)c1ccccc1.CCO[Si](OCC)(c1ccccc1)c1ccccc1 UWONUAJRKDRMBC-UHFFFAOYSA-N 0.000 description 1
- CIQDYIQMZXESRD-UHFFFAOYSA-N dimethoxy(phenyl)silane Chemical compound CO[SiH](OC)C1=CC=CC=C1 CIQDYIQMZXESRD-UHFFFAOYSA-N 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229940098458 powder spray Drugs 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000012163 sequencing technique Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/001—General methods for coating; Devices therefor
- C03C17/003—General methods for coating; Devices therefor for hollow ware, e.g. containers
- C03C17/005—Coating the outside
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/006—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels to produce glass through wet route
- C03C1/008—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels to produce glass through wet route for the production of films or coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/113—Deposition methods from solutions or suspensions by sol-gel processes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/114—Deposition methods from solutions or suspensions by brushing, pouring or doctorblading
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/131—Glass, ceramic, or sintered, fused, fired, or calcined metal oxide or metal carbide containing [e.g., porcelain, brick, cement, etc.]
- Y10T428/1317—Multilayer [continuous layer]
Definitions
- the present disclosure is directed to coating processes for glass containers including methods and materials for coating glass containers (e.g., glass bottles and jars).
- U.S. Patent 3,522,075 discloses a process for coating a glass container in which the glass container is formed, coated with a layer of metal oxide such as tin oxide, cooled through a lehr, and then coated with an organopolysiloxane resin-based material over the metal oxide layer.
- U.S. Patent 3,522,075 discloses a process for coating a glass container in which the glass container is formed, coated with a layer of metal oxide such as tin oxide, cooled through a lehr, and then coated with an organopolysiloxane resin-based material over the metal oxide layer.
- U.S. Patent 3,522,075 discloses a process for coating a glass container in which the glass container is formed, coated with a layer of metal oxide such as tin oxide, cooled through a lehr, and then coated with an organopolysiloxane resin-based material over the metal oxide layer.
- Patent 3,853,673 discloses a method of strengthening a glass article by, for example, applying to a surface of the article a clear solution of a soluble, further hydrolyzable metallosiloxane, and maintaining the glass article at an elevated temperature sufficiently high to convert the metallosiloxane to a cross-linked polymetallosiloxane gel structure.
- U.S. Patent 3,912,100 discloses a method of making a glass container by heating the glass container and applying a polyurethane powder spray to the glass container.
- JP 2008 273783 A discloses a method for coating an exterior surface of a glass container with a hybrid sol-gel.
- a general object of the present disclosure in accordance with one aspect of the disclosure, is to provide an improved method of increasing strength and/or fragment retention of a glass container.
- the present disclosure embodies a number of aspects that can be implemented separately from or in combination with each other.
- a method of coating an exterior surface of a glass container in accordance with one aspect of the invention includes the steps of
- a glass container that includes an axially closed base at an axial end of the glass container, a body extending axially from the base and being circumferentially closed, an axially open mouth at another end of the glass container opposite of the base, and an exterior glass surface.
- the glass container also includes a hybrid sol-gel cross-linked on at least a portion of the exterior glass surface.
- the glass containers may be hot-end coated in any suitable manner with any suitable hot-end coating materials to produce the hot-end coating 14.
- the silane may be composed of one or more of the following silanes: methyltriethoxysilane, dimethyldiethoxysilane, phenyltriethoxysilane, diphenyldiethoxysilane, phenyltrimethoxysilane, or diphenyldimethoxysilane.
- the silanes may be obtained from Gelest, Inc. of Morrisville, PA, or any other suitable source(s).
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Surface Treatment Of Glass (AREA)
- Details Of Rigid Or Semi-Rigid Containers (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL12718440T PL2678282T3 (pl) | 2011-02-24 | 2012-02-24 | Sposób wytwarzania pojemników szklanych powlekanych hybrydowym zol-żelem |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/034,407 US10450221B2 (en) | 2011-02-24 | 2011-02-24 | Hybrid sol-gel coated glass containers |
PCT/US2012/026562 WO2012166221A1 (en) | 2011-02-24 | 2012-02-24 | Hybrid sol-gel coated glass containers |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2678282A1 EP2678282A1 (en) | 2014-01-01 |
EP2678282B1 true EP2678282B1 (en) | 2020-08-05 |
Family
ID=46025871
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12718440.6A Active EP2678282B1 (en) | 2011-02-24 | 2012-02-24 | Process for preparing hybrid sol-gel coated glass containers |
Country Status (17)
Country | Link |
---|---|
US (1) | US10450221B2 (pt) |
EP (1) | EP2678282B1 (pt) |
CN (1) | CN103380092B (pt) |
AR (1) | AR085388A1 (pt) |
AU (1) | AU2012262941B2 (pt) |
BR (1) | BR112013021428B1 (pt) |
CA (1) | CA2827066C (pt) |
CL (1) | CL2013002432A1 (pt) |
CO (1) | CO6741221A2 (pt) |
ES (1) | ES2826979T3 (pt) |
MX (1) | MX2013009645A (pt) |
PE (1) | PE20140732A1 (pt) |
PL (1) | PL2678282T3 (pt) |
RU (1) | RU2013143148A (pt) |
SG (1) | SG192921A1 (pt) |
TW (1) | TW201236992A (pt) |
WO (1) | WO2012166221A1 (pt) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130126462A1 (en) * | 2011-11-17 | 2013-05-23 | Wisys Technology Foundation, Inc. | Ultraviolet-Blocking Recyclable Plastic Container |
KR102194392B1 (ko) * | 2012-12-21 | 2020-12-23 | 니혼 야마무라가라스 가부시키가이샤 | 유기-무기 하이브리드 프리폴리머, 유기-무기 하이브리드 재료 및 소자 밀봉 구조 |
US9090503B2 (en) * | 2012-12-28 | 2015-07-28 | Owens-Brockway Glass Container Inc. | Coatings for enhancing glass strength |
DE102013103992A1 (de) * | 2013-04-19 | 2014-10-23 | Krones Ag | Testbehältnis zum Testen von Inspektionseinrichtungen |
US8940396B1 (en) * | 2013-10-07 | 2015-01-27 | Owens-Brockway Glass Container Inc. | Graphene coating for glass containers |
JP6655785B2 (ja) * | 2014-04-17 | 2020-02-26 | パナソニックIpマネジメント株式会社 | 樹脂組成物およびその製造方法並びに半導体装置 |
CN108350311A (zh) * | 2015-10-30 | 2018-07-31 | 旭硝子欧洲玻璃公司 | 经涂覆的玻璃板 |
GB201523156D0 (en) | 2015-12-31 | 2016-02-17 | Pilkington Group Ltd | High strength glass containers |
EP3243805A1 (en) * | 2016-05-12 | 2017-11-15 | Anheuser-Busch InBev S.A. | A glass container having an inkjet printed image and a method for the manufacturing thereof |
US11008248B2 (en) * | 2017-05-04 | 2021-05-18 | Agc Glass Europe | Coated substrate |
EP3560897B1 (en) * | 2018-04-26 | 2021-11-24 | Schott AG | Process for making a functionalised hollow body, having a layer of glass, including a superposition of one or more siloxanes and contacting with a plasma |
CN116547248A (zh) | 2020-11-30 | 2023-08-04 | 布莱特普卢斯公司 | 用于玻璃制品的涂层 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3853673A (en) * | 1973-04-30 | 1974-12-10 | Owens Illinois Inc | Strengthened glass articles and methods using glass precursor ion exchange medium |
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- 2012-02-24 MX MX2013009645A patent/MX2013009645A/es active IP Right Grant
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US3853673A (en) * | 1973-04-30 | 1974-12-10 | Owens Illinois Inc | Strengthened glass articles and methods using glass precursor ion exchange medium |
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AR085388A1 (es) | 2013-09-25 |
AU2012262941B2 (en) | 2016-09-15 |
BR112013021428B1 (pt) | 2020-11-03 |
US10450221B2 (en) | 2019-10-22 |
CA2827066A1 (en) | 2012-12-06 |
BR112013021428A2 (pt) | 2016-10-25 |
RU2013143148A (ru) | 2015-03-27 |
CN103380092B (zh) | 2017-03-15 |
CA2827066C (en) | 2018-11-13 |
AU2012262941A1 (en) | 2013-08-15 |
TW201236992A (en) | 2012-09-16 |
CO6741221A2 (es) | 2013-08-30 |
US20120217181A1 (en) | 2012-08-30 |
ES2826979T3 (es) | 2021-05-19 |
EP2678282A1 (en) | 2014-01-01 |
SG192921A1 (en) | 2013-09-30 |
PE20140732A1 (es) | 2014-06-13 |
PL2678282T3 (pl) | 2021-03-08 |
MX2013009645A (es) | 2013-09-26 |
CL2013002432A1 (es) | 2014-06-20 |
CN103380092A (zh) | 2013-10-30 |
WO2012166221A1 (en) | 2012-12-06 |
NZ614041A (en) | 2015-06-26 |
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