EP2639028B1 - Method and plant for making ceramic ware products - Google Patents
Method and plant for making ceramic ware products Download PDFInfo
- Publication number
- EP2639028B1 EP2639028B1 EP13158585.3A EP13158585A EP2639028B1 EP 2639028 B1 EP2639028 B1 EP 2639028B1 EP 13158585 A EP13158585 A EP 13158585A EP 2639028 B1 EP2639028 B1 EP 2639028B1
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- European Patent Office
- Prior art keywords
- applying
- flow
- joining
- zone
- parts
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/26—Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/002—Producing shaped prefabricated articles from the material assembled from preformed elements
Definitions
- the present invention relates to a method and a plant for making ceramic ware products, in particular ceramic sanitary ware products.
- ceramic sanitary ware products are made by pressure casting a liquid mixture, known as slip, consisting of water, clay and very small quantities of other substances, in moulds made of porous resin.
- slip a liquid mixture
- the mould gives the sanitary ware product the required shape and the article is then extracted from the mould in a solid, though plastic, form and further processed according to a well-known sequence of steps until it is completely finished.
- the steps of making the ceramic ware product essentially comprise:
- Some sanitary ware products such as toilet bowls (purely by way of a non-limiting example) comprise at least two parts which can be joined to each other after being demoulded from a single mould or, in some cases, from separate moulds: a first bottom part comprising a pan and a drain siphon (that is, the inner parts of the bowl) and a second top part or "rim".
- the first part consisting of the pan and siphon assembly, is the functional part of the bowl and must have dimensional characteristics such as to allow the collection pan and flushing system of the bowl to work correctly.
- the rim has a portion that is usually annular or ellipsoidal in shape, forming the upper edge of the pan and a rear extension, parallel to the siphon and having a hole through which the flushing water is delivered.
- the operation by which the (two or more) parts are joined is performed with the parts in the state known as the "green" state, that is, while the products still have a high water content of between 14% and 20%, also so as to allow the joined parts to be finished (even using robot units) by smoothing their surfaces to give the finished product a good appearance.
- the sanitary ware product brings about two main changes in the structure/consistency of the article, the first bringing it to an intermediate "leatherhard” state (in which the water content is approximately halved in weight compared to the previous state) and the second, to an almost finished “whitehard” state (in which the water content is further reduced): in these two states, the sanitary ware product is much less subject to plastic deformation than it is when in the green state.
- the most critical situation is that created during the passage of the product from the green state to the leatherhard state, that is to say, the first drying step, which causes contractions in the product due to water loss and, therefore, product shrinkage.
- This invention therefore has for an aim to overcome these drawbacks by providing a method for the manufacture of a ceramic ware product by which the risks of cracking in product parts joined together or bonded using high-density slip can be eliminated rapidly and safely and without excessively affecting traditional operating times.
- This invention also has for an aim to provide a plant which implements the method described above and which is very practical, with structures adapted to reduce the risks of cracking, during the drying process, in the zones along which the product parts are joined, all without adding a large number of components in the stations making up the plant.
- these aims are achieved by a method and a plant for making a ceramic sanitary ware product in accordance with claims 1 and 8 respectively.
- a step of applying through the agency of respective means, a flow of electric charge uniformly distributed at least along the joining zone at a predefined power and for a predetermined length of time so as to increase mechanical strength at least at the joining zone.
- the step of applying the flow of electric charge reduces the moisture content around the joining zone.
- the step of applying the flow of electric charge creates uniformity of moisture content around the joining zone.
- the sanitary ware product denoted in its entirety by the letter M, has at least two parts which can be associated with each other after being demoulded from a single mould or from respective separate moulds (not illustrated here), but without thereby limiting the scope of the solution.
- the method for making a ceramic ware product may basically comprise the following traditional steps:
- the product shown in the drawings is a customary toilet bowl which comprises at least two parts M2 and M3 which can be associated with each other at least after the step of partly opening the mould or moulds.
- the product comprises a first bottom part M2 comprising a pan and a drain siphon (that is, the inner parts of the bowl) and a second top part M3 or "rim".
- the first part M2 consisting of the pan and siphon assembly, is the functional part of the bowl and must have dimensional characteristics such as to allow the collection pan and flushing system of the bowl to work correctly.
- the rim M3 has a portion that is usually annular or ellipsoidal in shape, forming the upper edge of the pan and a rear extension, parallel to the siphon and having a hole through which the flushing water is delivered.
- the two parts M2 and M3 may be cast in the same mould (even if separate from each other).
- the two parts M2 and M3 may be cast in separate moulds.
- the method for making this type of ceramic sanitary ware product further comprises the following steps, in addition to those mentioned above:
- the step of applying a layer S of bonding material is preceded by a step of positioning the first part M2 of the sanitary ware product M in a drying station 1.
- a further positive factor is that the step of applying the flow F of electric charge may create overall uniformity of moisture content around the joining zone.
- the charge is applied all around the joining zone, that is, on both sides of, and above and below a bonding line defined by the two respective joining surfaces 2 and 3 (see Figure 3 ).
- the electric current is applied at a power A of between 5 and 150 Watts.
- the electric current is applied for a length of time T of between 2 and 300 seconds.
- the intensity and time parameters are determined by the type of product M, the joined surface, the predicted obtainable increase in mechanical strength and the predicted obtainable reduction in the moisture content, without affecting the other portions of the product and the subsequent operating time scale.
- the plant denoted in its entirety by the numeral 5, which implements the method for making the sanitary ware product M made up of at least two parts M2 and M3 which can be joined to each other along the two opposable surfaces 2, 3 with the layer S of bonding material interposed between them, comprises at least:
- the means 4 are connected to a control unit 9 which controls the power or intensity A of the flow F and the length of time T for which it is applied.
- the application means 4 may comprise at least one pliable structure 10 shaped to adapt to the shape of the joining zone on at least two sides.
- the structure 10 may be equipped with a plurality of conductive elements 11 or electrodes, for the passage of current and also positioned on two sides of the joining zone and for a stretch covering a zone above and a zone below the bonding line.
- the pliable structure may consist of a metallic mesh 10 equipped with plates 11, also partly pliable, defining the electrodes.
- the mesh 10 may be positioned in such a way as to at least partly surround the joining zone.
- the application means 4 as a whole are connected to a source 12 by which electrical current is generated and which is in turn connected to the control unit 9 which controls the power or intensity of the current and the length of time it is applied to the sanitary ware product M.
- a method and plant as described above fully achieve the preset aims thanks to the inclusion of a step of applying electrical current to zone where the component parts of the sanitary ware product are joined to each other.
- This additional step is performed using simple, inexpensive means which can be quickly adapted to the shape of the product and which need very little application time.
Description
- The present invention relates to a method and a plant for making ceramic ware products, in particular ceramic sanitary ware products.
- As is well known in this trade, ceramic sanitary ware products (such as washbasins, toilet bowls, bidets and the like) are made by pressure casting a liquid mixture, known as slip, consisting of water, clay and very small quantities of other substances, in moulds made of porous resin. The mould gives the sanitary ware product the required shape and the article is then extracted from the mould in a solid, though plastic, form and further processed according to a well-known sequence of steps until it is completely finished.
- More specifically, the steps of making the ceramic ware product essentially comprise:
- filling the mould with slip at an initial pressure;
- forming the product layer at pressure profiles higher than that used for filling;
- emptying excess slip from the mould;
- consolidating the product;
- opening the mould and removing the product, and
- positioning the product in stations for drying and finishing the product.
- Some sanitary ware products, such as toilet bowls (purely by way of a non-limiting example) comprise at least two parts which can be joined to each other after being demoulded from a single mould or, in some cases, from separate moulds: a first bottom part comprising a pan and a drain siphon (that is, the inner parts of the bowl) and a second top part or "rim". The first part, consisting of the pan and siphon assembly, is the functional part of the bowl and must have dimensional characteristics such as to allow the collection pan and flushing system of the bowl to work correctly. The rim has a portion that is usually annular or ellipsoidal in shape, forming the upper edge of the pan and a rear extension, parallel to the siphon and having a hole through which the flushing water is delivered. Essentially, therefore, in a method for making this type of product it is necessary to perform a further set of steps, comprising:
- positioning the first part in the drying and finishing station;
- applying a bonding material (usually consisting of high-viscosity slip) uniformly to the surface to be joined to the rim;
- resting the rim on, and thereby joining it to, the surface of the first part. Obviously, this type of method can be applied to any other type of sanitary ware product whose initially separate parts need to be joined to each other by bonding using high-viscosity slip.
EP-A2-1 273 406 discloses a method and a plant for making a ceramic sanitary ware product in accordance with the preamble ofclaims 1 and 8 respectively. - As may be inferred from the above description, the operation by which the (two or more) parts are joined is performed with the parts in the state known as the "green" state, that is, while the products still have a high water content of between 14% and 20%, also so as to allow the joined parts to be finished (even using robot units) by smoothing their surfaces to give the finished product a good appearance.
- Then, allowing the sanitary ware product to remain in contact with the air (or in a controlled environment) brings about two main changes in the structure/consistency of the article, the first bringing it to an intermediate "leatherhard" state (in which the water content is approximately halved in weight compared to the previous state) and the second, to an almost finished "whitehard" state (in which the water content is further reduced): in these two states, the sanitary ware product is much less subject to plastic deformation than it is when in the green state.
- The most critical situation is that created during the passage of the product from the green state to the leatherhard state, that is to say, the first drying step, which causes contractions in the product due to water loss and, therefore, product shrinkage.
- These contractions during drying can lead to high stresses, particularly in the zone where, basically, the following three separate parts are located: rim - layer of bonding material - first part or pan surface, which is, in practice, a relatively large surface.
- This phenomenon is due essentially to the fact that the three parts which are placed in contact with each other have three different initial states: the two demoulded parts have a percentage water content of between 14% and 20%, whilst the layer of viscous slip used for bonding has a markedly higher water content (up to as much as 33%).
- During the drying process, this difference in the percentage water content and relative moisture causes a different shrinkage behaviour in each of the parts, creating high tensile or traction stresses (especially along the bonding line, for precisely the reasons mentioned above) which, in limit situations, may lead to cracking.
- This invention therefore has for an aim to overcome these drawbacks by providing a method for the manufacture of a ceramic ware product by which the risks of cracking in product parts joined together or bonded using high-density slip can be eliminated rapidly and safely and without excessively affecting traditional operating times.
- This invention also has for an aim to provide a plant which implements the method described above and which is very practical, with structures adapted to reduce the risks of cracking, during the drying process, in the zones along which the product parts are joined, all without adding a large number of components in the stations making up the plant.
- In accordance with the invention, these aims are achieved by a method and a plant for making a ceramic sanitary ware product in accordance with
claims 1 and 8 respectively. According to a preferred embodiment of the invention, after the step of joining the second part to the first part, there is a step of applying, through the agency of respective means, a flow of electric charge uniformly distributed at least along the joining zone at a predefined power and for a predetermined length of time so as to increase mechanical strength at least at the joining zone. Preferably, the step of applying the flow of electric charge reduces the moisture content around the joining zone. - Preferably, the step of applying the flow of electric charge creates uniformity of moisture content around the joining zone.
- These and other features of the invention will become more apparent from the following detailed description of a preferred, non-limiting example embodiment of it, with reference to the accompanying drawings, in which:
-
Figure 1 is a schematic side view, with some parts cut away in order to better illustrate others, of a station of a casting plant for making ceramic sanitary ware products implementing the method of the invention; -
Figure 2 illustrates the station ofFigure 1 in a schematic top plan view and shows means for generating a flow of electric charge forming part of the method and plant of the invention; -
Figure 3 is schematic front cross section of a detail B fromFigure 2 . With reference to the accompanying drawings, in particularFigures 1 and 2 , the method and plant of the invention are used to manufacture ceramic sanitary ware products. - More specifically, in the solution contemplated here, the sanitary ware product, denoted in its entirety by the letter M, has at least two parts which can be associated with each other after being demoulded from a single mould or from respective separate moulds (not illustrated here), but without thereby limiting the scope of the solution.
- Essentially, therefore, the method for making a ceramic ware product may basically comprise the following traditional steps:
- filling the mould with slip at an initial pressure;
- forming the layer which defines the product surfaces at pressure profiles higher than that used for filling;
- emptying excess slip from the mould;
- consolidating the product;
- partly opening the mould to release the product surfaces.
- These basic steps are followed by the further steps of:
- opening the mould completely and removing the product therefrom, and
- positioning the product in stations for drying and finishing the product.
- It should be noted that after the step of partly opening the mould or, in a non-limiting alternative of the invention, when the product is positioned in stations for finishing it (these steps not being illustrated in detail since they are of known type and do not strictly form part of the invention), further steps may follow for certain products which are precisely the products which, after moulding, require at least two parts to be joined.
- In the case of the embodiment described here by way of example only, the product shown in the drawings is a customary toilet bowl which comprises at least two parts M2 and M3 which can be associated with each other at least after the step of partly opening the mould or moulds.
- The product comprises a first bottom part M2 comprising a pan and a drain siphon (that is, the inner parts of the bowl) and a second top part M3 or "rim".
- The first part M2, consisting of the pan and siphon assembly, is the functional part of the bowl and must have dimensional characteristics such as to allow the collection pan and flushing system of the bowl to work correctly.
- The rim M3 has a portion that is usually annular or ellipsoidal in shape, forming the upper edge of the pan and a rear extension, parallel to the siphon and having a hole through which the flushing water is delivered. The two parts M2 and M3 may be cast in the same mould (even if separate from each other).
- Alternatively, the two parts M2 and M3 may be cast in separate moulds. The method for making this type of ceramic sanitary ware product further comprises the following steps, in addition to those mentioned above:
- applying (arrows F1,
Figure 1 ) a uniform layer S of bonding material comprising a high-viscosity fluid mixture or slip to at least onesurface 2 intended to be joined to at least the second part M3 or rim of the sanitary ware product M (this step being performed either manually or with a robot unit UR); - joining the second part M3 or rim to the first part M2 along a joining zone defined by two
respective contact surfaces Figure 1 ); - drying the sanitary ware product M thus obtained.
- After the step of joining the rim M3 to the first part M2, there is a step of applying, through the agency of
respective means 4, a flow F of electric charge uniformly distributed at least along the joining zone of the two parts M2 and M3 at a predefined power or intensity A and for a predetermined length of time T so as to increase mechanical strength at least at the selfsame joining zone. - It should be noted that if the parts M2 and M3 of the sanitary ware product M are removed from the moulds completely, the step of applying a layer S of bonding material is preceded by a step of positioning the first part M2 of the sanitary ware product M in a drying station 1.
- The above mentioned step of passing the flow of electric charge is facilitated also by the fact that both the parts of the sanitary ware product and the bonding material or slip contain electrolytes defined by salts present in the mixture they are made from.
- It has been found that applying an electric charge to this zone considerably increases the mechanical strength of the layer S of bonding material: during the subsequent drying step, this property improves the shrinkage resistance of the joined parts.
- To this must be added that applying a flow F of electric charge causes a relative reduction of the moisture content around the joining zone.
- A further positive factor is that the step of applying the flow F of electric charge may create overall uniformity of moisture content around the joining zone.
- All these factors markedly reduce the risk of cracking at the delicate zone where the parts making up the sanitary ware product M are joined.
- Preferably, in the step of applying a flow F of electric charge, the charge is applied all around the joining zone, that is, on both sides of, and above and below a bonding line defined by the two respective joining
surfaces 2 and 3 (seeFigure 3 ). - Preferably, in the step of applying the flow F of electric charge, the electric current is applied at a power A of between 5 and 150 Watts.
- Again preferably, the electric current is applied for a length of time T of between 2 and 300 seconds.
- The intensity and time parameters are determined by the type of product M, the joined surface, the predicted obtainable increase in mechanical strength and the predicted obtainable reduction in the moisture content, without affecting the other portions of the product and the subsequent operating time scale.
- The plant, denoted in its entirety by the
numeral 5, which implements the method for making the sanitary ware product M made up of at least two parts M2 and M3 which can be joined to each other along the twoopposable surfaces - the station 1 for drying the sanitary ware product M;
- means 7 for spreading the layer S of bonding material (either a human operator or a robot unit), and
- means 8 for joining the two parts M2 and M3 (usually mechanical units for handling the products).
- To these are added the
aforementioned means 4 for applying a flow F of electric charge around the zone where the two parts M2, M3 are joined by the layer S of bonding material. - The
means 4 are connected to acontrol unit 9 which controls the power or intensity A of the flow F and the length of time T for which it is applied. - In an exemplary embodiment, the application means 4 may comprise at least one
pliable structure 10 shaped to adapt to the shape of the joining zone on at least two sides. - The
structure 10 may be equipped with a plurality ofconductive elements 11 or electrodes, for the passage of current and also positioned on two sides of the joining zone and for a stretch covering a zone above and a zone below the bonding line. - The pliable structure may consist of a
metallic mesh 10 equipped withplates 11, also partly pliable, defining the electrodes. - In use, the
mesh 10 may be positioned in such a way as to at least partly surround the joining zone. - The application means 4 as a whole are connected to a
source 12 by which electrical current is generated and which is in turn connected to thecontrol unit 9 which controls the power or intensity of the current and the length of time it is applied to the sanitary ware product M. - A method and plant as described above fully achieve the preset aims thanks to the inclusion of a step of applying electrical current to zone where the component parts of the sanitary ware product are joined to each other.
- This step brings the following important advantages:
- higher mechanical strength of the joining zone thanks to improved interpenetration of the contact surfaces between the product parts and the bonding material;
- rapid reduction of moisture in the joining zone;
- improved uniformity of moisture in the zone where the parts are joined.
- All of this makes it possible to reduce the risk of cracking at that zone thanks to the addition of one simple step which requires very little additional time, that is to say, without affecting the overall time scale of the production cycle.
- This additional step is performed using simple, inexpensive means which can be quickly adapted to the shape of the product and which need very little application time.
Claims (12)
- A method for making a ceramic sanitary ware product (M) comprising at least the following steps:- applying a uniform layer (S) of bonding material comprising a high-viscosity fluid mixture or slip to at least one surface (2) of a first part (M2) intended to be joined to at least a second part (M3) of the sanitary ware product (M);- joining the second part (M3) of the sanitary ware product (M) to the first part (M2) along a joining zone defined by two respective contact surfaces (2, 3) of the selfsame parts (M2, M3) with the layer (S) of bonding material interposed between them;- drying the sanitary ware product (M) thus obtained;
characterized in that it comprises, after the step of joining the second part (M3) to the first part (M2), there is a step of applying, through the agency of respective means (4), a flow (F) of electric charge at least along the joining zone so as to increase mechanical strength at least at the joining zone. - The method according to claim 1, characterized in that the step of applying a flow (F) of electrical charge is uniformly distributed at least along the joining zone.
- The method according to claim 1 or 2, characterized in that the step of applying a flow (F) of electrical charge is applied with a predefined power (A).
- The method according to any of the preceding claims, characterized in that the step of applying a flow (F) of electric charge is applied for a predetermined length of time (T).
- The method according to any of the preceding claims, characterized in that in the step of applying a flow (F) of electric charge, the charge is applied and distributed all around the joining zone, that is, on both sides of, and above and below a bonding line defined by the two respective joining surfaces (2, 3).
- The method according to any of the preceding claims, characterized in that the step of applying a flow (F) of electric charge, comprises applying alternating electric current at a power (A) of between 5 and 150 Watts.
- The method according to any of the preceding claims, characterized in that the step of applying a flow (F) of electric charge comprises applying the electric current for a length of time (T) of between 2 and 300 seconds.
- A plant for making a sanitary ware product (M) made up of at least two parts (M2, M3) which can be joined to each other along two opposable surfaces (2, 3) with a layer (S) of bonding material consisting of a high-viscosity fluid mixture interposed between them, the plant (5) comprising at least:- means (7) for spreading the layer (S) of bonding material, and- means (8) for joining the two parts (M2, M3), characterized in that it further comprises:- means (4) for applying a flow (F) of electric charge around the zone where the two parts (M2, M3) are joined by the layer (S) of bonding material.
- The plant according to claim 8, characterized in that it comprises a control unit (9) connected to the flow (F) application means (4) and configured to control the power (A) of the current and the length of time (T) the flow is applied.
- The plant according to claim 8 or 9, characterized in that the application means (4) comprise at least one pliable structure (10) shaped to adapt to the shape of the joining zone on at least two sides; the structure (10) being equipped with a plurality of conductive elements (11) or electrodes, for the passage of current and also positioned on two sides of the joining zone and for a stretch covering a zone above and a zone below the bonding line.
- The plant according to any of the preceding claims from 8 to 10, characterized in that the application means (4) are connected to a source (12) by which electrical current is generated and which is connected to the control unit (9).
- The plant according to claim 10, characterized in that the pliable structure comprises a metallic mesh (10) equipped with plates (11) defining the electrodes; the mesh (10) being, in use, positioned in such a way as to at least partly surround the joining zone.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL13158585T PL2639028T3 (en) | 2012-03-13 | 2013-03-11 | Method and plant for making ceramic ware products |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT000129A ITBO20120129A1 (en) | 2012-03-13 | 2012-03-13 | METHOD AND PLANT FOR THE PRODUCTION OF CERAMIC MATERIALS. |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2639028A1 EP2639028A1 (en) | 2013-09-18 |
EP2639028B1 true EP2639028B1 (en) | 2014-04-23 |
Family
ID=46018037
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13158585.3A Active EP2639028B1 (en) | 2012-03-13 | 2013-03-11 | Method and plant for making ceramic ware products |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP2639028B1 (en) |
ES (1) | ES2478293T3 (en) |
IT (1) | ITBO20120129A1 (en) |
PL (1) | PL2639028T3 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITUB20152525A1 (en) * | 2015-07-27 | 2017-01-27 | Siti B & T Group Spa | PLANT FOR THE PRODUCTION OF HEALTH ARTICLES, AS WELL AS IT IS METHOD |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1057760A (en) * | 1964-10-15 | 1967-02-08 | Erich Netzsch | Mould for the production of a ceramic article in a casting process and a casting method using the mould |
DD146414A1 (en) * | 1979-11-20 | 1981-02-11 | Reinhard Faustmann | METHOD AND DEVICE FOR GARNING PRE-PRODUCED ITEMS OF CERAMIC MASS |
DE10132790B4 (en) * | 2001-07-06 | 2004-06-24 | Dorst Maschinen- Und Anlagenbau Gmbh & Co. Kg | Die casting system for the manufacture of toilets and manufacturing processes therefor |
-
2012
- 2012-03-13 IT IT000129A patent/ITBO20120129A1/en unknown
-
2013
- 2013-03-11 ES ES13158585.3T patent/ES2478293T3/en active Active
- 2013-03-11 EP EP13158585.3A patent/EP2639028B1/en active Active
- 2013-03-11 PL PL13158585T patent/PL2639028T3/en unknown
Also Published As
Publication number | Publication date |
---|---|
ES2478293T3 (en) | 2014-07-21 |
PL2639028T3 (en) | 2014-09-30 |
ITBO20120129A1 (en) | 2013-09-14 |
EP2639028A1 (en) | 2013-09-18 |
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