EP2561061B1 - Procédé pour la fabrication d'une composition de base de détergent - Google Patents
Procédé pour la fabrication d'une composition de base de détergent Download PDFInfo
- Publication number
- EP2561061B1 EP2561061B1 EP11715377.5A EP11715377A EP2561061B1 EP 2561061 B1 EP2561061 B1 EP 2561061B1 EP 11715377 A EP11715377 A EP 11715377A EP 2561061 B1 EP2561061 B1 EP 2561061B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- detersive surfactant
- detergent
- sulphate
- alkyl
- neutralized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000003599 detergent Substances 0.000 title claims description 75
- 239000000203 mixture Substances 0.000 title claims description 71
- 238000000034 method Methods 0.000 title claims description 33
- 230000008569 process Effects 0.000 title claims description 31
- 239000004094 surface-active agent Substances 0.000 claims description 70
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 42
- -1 alkyl sulphates Chemical class 0.000 claims description 38
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 35
- 239000003795 chemical substances by application Substances 0.000 claims description 24
- 239000007788 liquid Substances 0.000 claims description 24
- 230000003472 neutralizing effect Effects 0.000 claims description 22
- 239000006188 syrup Substances 0.000 claims description 17
- 235000020357 syrup Nutrition 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 14
- 239000003960 organic solvent Substances 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 6
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 17
- 239000000047 product Substances 0.000 description 17
- 239000002904 solvent Substances 0.000 description 16
- 239000000463 material Substances 0.000 description 15
- 239000002736 nonionic surfactant Substances 0.000 description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 11
- 150000008051 alkyl sulfates Chemical class 0.000 description 10
- 238000004140 cleaning Methods 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 10
- 238000007792 addition Methods 0.000 description 9
- 150000001412 amines Chemical class 0.000 description 9
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 9
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 9
- 125000005529 alkyleneoxy group Chemical group 0.000 description 8
- 239000004519 grease Substances 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 238000000518 rheometry Methods 0.000 description 5
- 101001051490 Homo sapiens Neural cell adhesion molecule L1 Proteins 0.000 description 4
- 208000031300 Hydrocephalus with stenosis of the aqueduct of Sylvius Diseases 0.000 description 4
- 102100024964 Neural cell adhesion molecule L1 Human genes 0.000 description 4
- 208000026197 X-linked hydrocephalus with stenosis of the aqueduct of Sylvius Diseases 0.000 description 4
- 150000004996 alkyl benzenes Chemical class 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 4
- 238000007046 ethoxylation reaction Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 150000002191 fatty alcohols Chemical class 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 4
- 238000010412 laundry washing Methods 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 description 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 229920002873 Polyethylenimine Polymers 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 150000003254 radicals Chemical group 0.000 description 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 2
- AFHIIJICYLMCSH-VOTSOKGWSA-N 5-amino-2-[(e)-2-(4-benzamido-2-sulfophenyl)ethenyl]benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC(N)=CC=C1\C=C\C(C(=C1)S(O)(=O)=O)=CC=C1NC(=O)C1=CC=CC=C1 AFHIIJICYLMCSH-VOTSOKGWSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229940092714 benzenesulfonic acid Drugs 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 description 1
- TZJFRKWUJOXRKM-UHFFFAOYSA-N 1-ethoxypentan-1-ol Chemical compound CCCCC(O)OCC TZJFRKWUJOXRKM-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- XXAXVMUWHZHZMJ-UHFFFAOYSA-L 4,5-dihydroxybenzene-1,3-disulfonate Chemical compound OC1=CC(S([O-])(=O)=O)=CC(S([O-])(=O)=O)=C1O XXAXVMUWHZHZMJ-UHFFFAOYSA-L 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229920002214 alkoxylated polymer Polymers 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- CREXVNNSNOKDHW-UHFFFAOYSA-N azaniumylideneazanide Chemical group N[N] CREXVNNSNOKDHW-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 229940044172 calcium formate Drugs 0.000 description 1
- 239000004281 calcium formate Substances 0.000 description 1
- 235000019255 calcium formate Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- YZSJUQIFYHUSKU-UHFFFAOYSA-N ethanol;propane-1,2-diol Chemical compound CCO.CC(O)CO YZSJUQIFYHUSKU-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- VMESOKCXSYNAKD-UHFFFAOYSA-N n,n-dimethylhydroxylamine Chemical compound CN(C)O VMESOKCXSYNAKD-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- LQPLDXQVILYOOL-UHFFFAOYSA-I pentasodium;2-[bis[2-[bis(carboxylatomethyl)amino]ethyl]amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC(=O)[O-])CCN(CC([O-])=O)CC([O-])=O LQPLDXQVILYOOL-UHFFFAOYSA-I 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
- C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
Claims (9)
- Procédé de fabrication d'une composition de base de détergent liquide anhydre comprenant moins de 30 % d'eau en poids et un agent tensioactif détersif, le procédé comprenant les étapes consistant à :a) fournir un sirop d'agent tensioactif détersif à base de sulfate pré-neutralisé, dans lequel au moins 50 % de l'agent tensioactif détersif à base de sulfate est pré-neutralisé avec un agent neutralisant organique ;b) ajouter un agent neutralisant au sirop d'agent tensioactif détersif à base de sulfate ; etc) ajouter un agent tensioactif détersif sulfonique sous forme acide au mélange résultant provenant de l'étape b).
- Procédé selon la revendication 1, dans lequel l'agent neutralisant organique est une alcanolamine, de préférence de la monoéthanolamine.
- Procédé selon la revendication 1 ou 2, dans lequel l'agent tensioactif détersif à base de sulfate est choisi parmi des alkylsulfates alcoxylés, des alkylsulfates primaires ramifiés à mi-chaîne et leurs mélanges.
- Procédé selon la revendication précédente, dans lequel l'agent tensioactif détersif à base de sulfate comprend au moins 50 % d'alkylsulfate alcoxylé.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel le sirop d'agent tensioactif détersif à base de sulfate pré-neutralisé comprend un solvant organique.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel l'agent neutralisant de l'étape b) est choisi parmi des agents neutralisants organiques, des agents neutralisants inorganiques et leurs mélanges.
- Procédé selon l'une quelconque des revendications précédentes, comprenant l'étape consistant à ajouter un solvant organique après l'étape a) et de préférence avant l'étape b).
- Procédé selon l'une quelconque des revendications précédentes, dans lequel l'agent tensioactif détersif à base de sulfate et l'agent tensioactif détersif sulfonique sont dans un rapport pondéral allant d'environ 4:1 à environ 1:1.
- Procédé de fabrication d'un détergent liquide pour le linge comprenant les étapes du procédé selon l'une quelconque des revendications précédentes, suivies par l'étape consistant à ajouter de 5 à 20 % d'eau, en poids du détergent.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL11715377T PL2561061T3 (pl) | 2010-04-19 | 2011-04-14 | Sposób wytwarzania kompozycji bazowej detergentu |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US32540410P | 2010-04-19 | 2010-04-19 | |
PCT/US2011/032419 WO2011133378A1 (fr) | 2010-04-19 | 2011-04-14 | Procédé pour la fabrication d'une composition de base de détergent |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2561061A1 EP2561061A1 (fr) | 2013-02-27 |
EP2561061B1 true EP2561061B1 (fr) | 2014-03-05 |
EP2561061B2 EP2561061B2 (fr) | 2020-07-08 |
Family
ID=44343938
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11715377.5A Active EP2561061B2 (fr) | 2010-04-19 | 2011-04-14 | Procédé pour la fabrication d'une composition de base de détergent |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP2561061B2 (fr) |
JP (1) | JP5774678B2 (fr) |
CN (1) | CN102834501A (fr) |
AR (1) | AR082839A1 (fr) |
BR (1) | BR112012026891A2 (fr) |
CA (1) | CA2795931C (fr) |
ES (1) | ES2460921T3 (fr) |
MX (1) | MX339065B (fr) |
PL (1) | PL2561061T3 (fr) |
WO (1) | WO2011133378A1 (fr) |
ZA (1) | ZA201207402B (fr) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8853142B2 (en) * | 2012-02-27 | 2014-10-07 | The Procter & Gamble Company | Methods for producing liquid detergent products |
EP2992073B1 (fr) * | 2013-04-29 | 2018-12-05 | Unilever PLC, a company registered in England and Wales under company no. 41424 | Procédé pour épaissir une composition de détergent liquide |
JP2017509774A (ja) | 2014-01-20 | 2017-04-06 | ザ プロクター アンド ギャンブル カンパニー | 蛍光増白剤プレミックス |
DE102019129859A1 (de) * | 2019-11-06 | 2021-05-06 | Henkel Ag & Co. Kgaa | Verbessertes lösungsverhalten von tensidsystemen durch adaption der rohstoffzugabe |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
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US2220099A (en) | 1934-01-10 | 1940-11-05 | Gen Aniline & Flim Corp | Sulphonic acids |
US2091704A (en) † | 1934-08-28 | 1937-08-31 | Procter & Gamble | Detergent composition |
US2477383A (en) | 1946-12-26 | 1949-07-26 | California Research Corp | Sulfonated detergent and its method of preparation |
NL128245C (fr) | 1951-05-31 | |||
US2674619A (en) | 1953-10-19 | 1954-04-06 | Wyandotte Chemicals Corp | Polyoxyalkylene compounds |
US3664961A (en) † | 1970-03-31 | 1972-05-23 | Procter & Gamble | Enzyme detergent composition containing coagglomerated perborate bleaching agent |
DE2236727C3 (de) † | 1972-07-26 | 1985-10-24 | Unilever N.V., Rotterdam | Toilettenseife aus synthetischen Tensiden |
GB1430610A (en) * | 1973-09-04 | 1976-03-31 | Procter & Gamble Ltd | Liquid detergent compositions |
DE3725030A1 (de) † | 1987-07-29 | 1989-02-09 | Henkel Kgaa | Oberflaechenaktive hydroxysulfonate |
CA2027518A1 (fr) † | 1990-10-03 | 1992-04-04 | Richard L. Tadsen | Methode de preparation de compositions detergentes a haute densite, contenant des particules tensio-actives sensibles au ph |
NZ240395A (en) † | 1990-11-21 | 1993-10-26 | Colgate Palmolive Co | Process for manufacture of concentrated liquid detergent containing magnesium alkylbenzene sulphonate and alkanolamide suds booster |
FI91278C (fi) * | 1992-05-18 | 1995-04-18 | Ks Chemitra Ltd Oy | Menetelmä tensidiseosten valmistamiseksi |
DE4216629A1 (de) * | 1992-05-20 | 1993-11-25 | Henkel Kgaa | Verfahren zur Herstellung aniontensidhaltiger Wasch- und Reinigungsmittel |
DE69311694T2 (de) † | 1993-02-04 | 1998-01-15 | Procter & Gamble | Hochkonzentrierte Alkylsulfatlösungen |
JP2801829B2 (ja) * | 1993-04-14 | 1998-09-21 | 花王株式会社 | 液体洗浄剤組成物 |
JPH10195488A (ja) * | 1996-12-28 | 1998-07-28 | Lion Corp | 液体洗浄剤組成物 |
JPH10298597A (ja) * | 1997-04-28 | 1998-11-10 | Lion Corp | 液体洗浄剤組成物 |
DE10046363A1 (de) † | 2000-09-20 | 2002-03-28 | Cognis Deutschland Gmbh | Fließfähige wässrige Fettalkoholsulfatpasten |
PL2130897T3 (pl) † | 2008-06-02 | 2012-01-31 | Procter & Gamble | Koncentrat środka powierzchniowo czynnego |
-
2011
- 2011-04-14 CN CN2011800185888A patent/CN102834501A/zh active Pending
- 2011-04-14 BR BR112012026891A patent/BR112012026891A2/pt not_active IP Right Cessation
- 2011-04-14 CA CA2795931A patent/CA2795931C/fr active Active
- 2011-04-14 ES ES11715377.5T patent/ES2460921T3/es active Active
- 2011-04-14 PL PL11715377T patent/PL2561061T3/pl unknown
- 2011-04-14 MX MX2012012239A patent/MX339065B/es active IP Right Grant
- 2011-04-14 WO PCT/US2011/032419 patent/WO2011133378A1/fr active Application Filing
- 2011-04-14 JP JP2013505125A patent/JP5774678B2/ja active Active
- 2011-04-14 EP EP11715377.5A patent/EP2561061B2/fr active Active
- 2011-04-19 AR ARP110101354A patent/AR082839A1/es not_active Application Discontinuation
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- 2012-10-03 ZA ZA2012/07402A patent/ZA201207402B/en unknown
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CA2795931C (fr) | 2015-02-17 |
PL2561061T3 (pl) | 2014-07-31 |
MX339065B (es) | 2016-05-06 |
WO2011133378A1 (fr) | 2011-10-27 |
ES2460921T3 (es) | 2014-05-16 |
MX2012012239A (es) | 2012-11-23 |
EP2561061B2 (fr) | 2020-07-08 |
CA2795931A1 (fr) | 2011-10-27 |
EP2561061A1 (fr) | 2013-02-27 |
JP5774678B2 (ja) | 2015-09-09 |
CN102834501A (zh) | 2012-12-19 |
AR082839A1 (es) | 2013-01-16 |
ZA201207402B (en) | 2014-03-26 |
JP2013525522A (ja) | 2013-06-20 |
BR112012026891A2 (pt) | 2016-07-19 |
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