EP2555867A4 - Catalyseur à zéolithes mixtes fe-bea/fe-mfi et procédé de traitement de nox dans des courants gazeux à l'aide de ce catalyseur - Google Patents

Catalyseur à zéolithes mixtes fe-bea/fe-mfi et procédé de traitement de nox dans des courants gazeux à l'aide de ce catalyseur

Info

Publication number
EP2555867A4
EP2555867A4 EP11765158.8A EP11765158A EP2555867A4 EP 2555867 A4 EP2555867 A4 EP 2555867A4 EP 11765158 A EP11765158 A EP 11765158A EP 2555867 A4 EP2555867 A4 EP 2555867A4
Authority
EP
European Patent Office
Prior art keywords
bea
same
gas streams
zeolite catalyst
mixed zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11765158.8A
Other languages
German (de)
English (en)
Other versions
EP2555867A1 (fr
Inventor
Susanne Stiebels
Claudia Wendt
Torsten Neubauer
Edith Schneider
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP11765158.8A priority Critical patent/EP2555867A4/fr
Publication of EP2555867A1 publication Critical patent/EP2555867A1/fr
Publication of EP2555867A4 publication Critical patent/EP2555867A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/56—Nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/7215—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2067—Urea
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/92—Dimensions
    • B01D2255/9205—Porosity

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Exhaust Gas After Treatment (AREA)
EP11765158.8A 2010-04-08 2011-04-08 Catalyseur à zéolithes mixtes fe-bea/fe-mfi et procédé de traitement de nox dans des courants gazeux à l'aide de ce catalyseur Withdrawn EP2555867A4 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP11765158.8A EP2555867A4 (fr) 2010-04-08 2011-04-08 Catalyseur à zéolithes mixtes fe-bea/fe-mfi et procédé de traitement de nox dans des courants gazeux à l'aide de ce catalyseur

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10159369 2010-04-08
EP11765158.8A EP2555867A4 (fr) 2010-04-08 2011-04-08 Catalyseur à zéolithes mixtes fe-bea/fe-mfi et procédé de traitement de nox dans des courants gazeux à l'aide de ce catalyseur
PCT/IB2011/051526 WO2011125050A1 (fr) 2010-04-08 2011-04-08 Catalyseur à zéolithes mixtes fe-bea/fe-mfi et procédé de traitement de nox dans des courants gazeux à l'aide de ce catalyseur

Publications (2)

Publication Number Publication Date
EP2555867A1 EP2555867A1 (fr) 2013-02-13
EP2555867A4 true EP2555867A4 (fr) 2014-12-10

Family

ID=44762074

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11765158.8A Withdrawn EP2555867A4 (fr) 2010-04-08 2011-04-08 Catalyseur à zéolithes mixtes fe-bea/fe-mfi et procédé de traitement de nox dans des courants gazeux à l'aide de ce catalyseur

Country Status (9)

Country Link
EP (1) EP2555867A4 (fr)
JP (1) JP2013523442A (fr)
KR (1) KR20130091638A (fr)
CN (1) CN102958610A (fr)
BR (1) BR112012025744A2 (fr)
CA (1) CA2795522A1 (fr)
MX (1) MX2012011540A (fr)
WO (1) WO2011125050A1 (fr)
ZA (1) ZA201208258B (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6294127B2 (ja) * 2014-03-31 2018-03-14 株式会社キャタラー Ｓｃｒ用触媒及び排ガス浄化触媒システム
DE102015204012A1 (de) * 2015-03-05 2016-09-08 Clariant International Ltd. SCR-Katalysator mit verbesserter Haftung
WO2019072527A1 (fr) * 2017-10-09 2019-04-18 Umicore Ag & Co. Kg Catalyseur à réduction catalytique sélective
KR20200130845A (ko) * 2018-04-11 2020-11-20 바스프 코포레이션 혼합 제올라이트 함유 scr 촉매
CN109289508B (zh) * 2018-10-24 2021-09-24 昆山工统环保科技有限公司 一种高疏水性沸石材料的制备方法
CN109592687B (zh) * 2018-12-03 2023-06-06 南京理工大学 利用tob制备多孔二氧化硅材料的方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5676912A (en) * 1995-02-22 1997-10-14 Mobil Oil Corporation Process for exhaust gas NOx, CO, and hydrocarbon removal
US20060228283A1 (en) * 2005-02-28 2006-10-12 Catalytic Solutions, Inc. Catalyst and method for reducing nitrogen oxides in exhaust streams with hydrocarbons or alcohols
CN101190866A (zh) * 2006-11-21 2008-06-04 中国石油化工股份有限公司 低乙苯副产物的芳烃烷基转移和脱烷基反应方法
US20080286184A1 (en) * 2007-05-09 2008-11-20 N.E Chemcat Corporation Selective catalytic reduction type catalyst, and exhaust gas purification equipment and purifying process of exhaust gas using the same
WO2009068289A2 (fr) * 2007-11-28 2009-06-04 Süd-Chemie AG Composition de revêtement pour catalyseurs d'oxydation diesel
US20090269265A1 (en) * 2008-04-28 2009-10-29 N.E. Chemcat Corporation Exhaust gas purification method using selective reduction catalyst
US20090325786A1 (en) * 2006-08-31 2009-12-31 China Petroleum & Chemical Corporation Hydrocarbon conversion catalyst

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001087646A (ja) * 1999-08-25 2001-04-03 Praxair Technol Inc 窒素を別のガスから選択的に吸着させるための新規の吸着剤
DE10001539B4 (de) * 2000-01-14 2006-01-19 Uhde Gmbh Verfahren zur Beseitigung von NOx und N2O
CN101607209B (zh) * 2002-11-18 2014-07-02 优美科触媒日本有限公司 废气净化用催化剂的制备方法与废气净化方法
WO2004047960A1 (fr) * 2002-11-25 2004-06-10 Yara International Asa Procede pour la preparation et l'activation de catalyseurs sur zeolites multimetalliques, composition de catalyseurs et application de ce procede pour la reduction du n2o
DE102006020158B4 (de) * 2006-05-02 2009-04-09 Argillon Gmbh Extrudierter Vollkatalysator sowie Verfahren zu seiner Herstellung

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5676912A (en) * 1995-02-22 1997-10-14 Mobil Oil Corporation Process for exhaust gas NOx, CO, and hydrocarbon removal
US20060228283A1 (en) * 2005-02-28 2006-10-12 Catalytic Solutions, Inc. Catalyst and method for reducing nitrogen oxides in exhaust streams with hydrocarbons or alcohols
US20090325786A1 (en) * 2006-08-31 2009-12-31 China Petroleum & Chemical Corporation Hydrocarbon conversion catalyst
CN101190866A (zh) * 2006-11-21 2008-06-04 中国石油化工股份有限公司 低乙苯副产物的芳烃烷基转移和脱烷基反应方法
US20080286184A1 (en) * 2007-05-09 2008-11-20 N.E Chemcat Corporation Selective catalytic reduction type catalyst, and exhaust gas purification equipment and purifying process of exhaust gas using the same
WO2009068289A2 (fr) * 2007-11-28 2009-06-04 Süd-Chemie AG Composition de revêtement pour catalyseurs d'oxydation diesel
US20090269265A1 (en) * 2008-04-28 2009-10-29 N.E. Chemcat Corporation Exhaust gas purification method using selective reduction catalyst

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2011125050A1 *

Also Published As

Publication number Publication date
WO2011125050A1 (fr) 2011-10-13
KR20130091638A (ko) 2013-08-19
CN102958610A (zh) 2013-03-06
CA2795522A1 (fr) 2011-10-13
EP2555867A1 (fr) 2013-02-13
ZA201208258B (en) 2014-01-29
BR112012025744A2 (pt) 2016-06-28
MX2012011540A (es) 2012-11-16
JP2013523442A (ja) 2013-06-17

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Inventor name: STIEBELS, SUSANNE

Inventor name: NEUBAUER, TORSTEN

Inventor name: SCHNEIDER, EDITH

Inventor name: WENDT, CLAUDIA

DAX Request for extension of the european patent (deleted)
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