EP2535401B1 - Detergent composition comprising soil-release polymers of improved storage stability - Google Patents

Detergent composition comprising soil-release polymers of improved storage stability Download PDF

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Publication number
EP2535401B1
EP2535401B1 EP11004982.2A EP11004982A EP2535401B1 EP 2535401 B1 EP2535401 B1 EP 2535401B1 EP 11004982 A EP11004982 A EP 11004982A EP 2535401 B1 EP2535401 B1 EP 2535401B1
Authority
EP
European Patent Office
Prior art keywords
composition
soil
water
lipase
amount
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP11004982.2A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2535401A1 (en
Inventor
Stefan Müller
Jessica Dichter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dalli Werke GmbH and Co KG
Original Assignee
Dalli Werke GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Dalli Werke GmbH and Co KG filed Critical Dalli Werke GmbH and Co KG
Priority to PL11004982T priority Critical patent/PL2535401T3/pl
Priority to ES11004982.2T priority patent/ES2622230T3/es
Priority to EP11004982.2A priority patent/EP2535401B1/en
Publication of EP2535401A1 publication Critical patent/EP2535401A1/en
Application granted granted Critical
Publication of EP2535401B1 publication Critical patent/EP2535401B1/en
Revoked legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3715—Polyesters or polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase

Definitions

  • the present invention relates to a detergent composition, in particular a liquid laundry detergent composition, comprising at least one lipase, at least one soil-release polymer comprising ester moieties and at least one compound which stabilizes said at least one soil-release polymer in the presence of said lipase, to a method for stabilizing such a soil-release polymer in a detergent composition comprising a lipase and to the use of certain compounds for stabilizing soil-release polymers comprising ester moieties in detergent compositions further comprising at least one lipase.
  • the composition of the present invention may comprise of from 20 to 90 wt.-%, more preferably of from 30 to 80 wt.-%, even more preferably of from 40 to 75 wt.-% and most preferably of from 50 to 70 wt.-% of at least one liquid carrier, including the particulary preferred ranges of 52 to 68 wt.-% and 55 to 65 wt.-%, based on the whole composition.
  • mixtures of the afore-mentioned solvents may be employed.
  • a mixture of water and at least one alcohol may be employed as a liquid carrier, wherein the ratio of the amount of water to the amount of alcohol(s) present in the composition preferably may be in the range of from 1:1 to 20:1, more preferably of from 2:1 to 10:1, even more preferably of from 3:1 to 7:1.
  • the alcoholic part of the liquid carrier preferably represents a mixture of at least two different alcohols, preferably of at least one monohydric C 1 -C 4 alcohol and a C 2 -C 6 diol.
  • the liquid carrier may represent a mixture of ethanol and 1,2-propyleneglycol.
  • the ratio of the amount of soil release polymer to the amount of lipase present in the composition preferably may be in the range of from 10:1 to 200:1, more preferably of from 20:1 to 150:1, even more preferably of from 40:1 to 120:1 and most preferably of from 60:1 to 100:1, including the particularly preferred ranges of from 70:1 to 90:1 and of from 75:1 to 85:1.
  • the amount of the boronic acid or water-soluble salts thereof in the composition of the present invention preferably may be in the range of from 0.001 to 1 wt.-%, more preferably in the range of from 0.01 to 0.7 wt.-% and most preferably in the range from 0.02 to 0.5 wt.-%.
  • water-soluble salts of calcium, magnesium or zinc which upon dissolution in the detergent composition of the present invention provide a concentration of calcium, magnesium and/or zinc ions in the range of from 0.01 to 100 mmol, preferably of 0.1 to 10 mmol per liter of the composition may be used.
  • Suitable salts are for example calcium chloride, calcium hydroxide, calcium sulfate, calcium acetate and the like, as well as the corresponding magnesium or zinc salts, without being limited to these.
  • composition of the present invention preferably may comprise at least one further enzyme, which preferably may be selected from the group consisting of proteases, amylases, mannanases, cellulales, peroxidases, pectinases, further esterases or a mixture thereof.
  • Washing tests were carried out in a Linitest which has eight little "beakers” and simulates eight European drum type washing machines.
  • the washing temperature was set to 40 °C, and the heating rate was set to 2 °C per minute.
  • the time for one washing cycle was set to 30 minutes, for both a prewash and the main wash cycle. Rotations were set to 40 rotations per minute. 250 mL of washing liquor were used per beaker and washing cycle. As a soil 50 mL of used synthetic motor oil were applied to each piece of fabric.
  • test fabrics were prewashed using this commercially available product and soiled as described above.
  • Example 3 Stabilization of a soil-release polymer in liquid detergent compositions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
EP11004982.2A 2011-06-17 2011-06-17 Detergent composition comprising soil-release polymers of improved storage stability Revoked EP2535401B1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
PL11004982T PL2535401T3 (pl) 2011-06-17 2011-06-17 Kompozycja detergentowa zawierająca polimery uwalniające zabrudzenia, o lepszej stabilności podczas przechowywania
ES11004982.2T ES2622230T3 (es) 2011-06-17 2011-06-17 Composición de detergente que comprende polímeros de liberación de suciedad con estabilidad en almacenamiento mejorada
EP11004982.2A EP2535401B1 (en) 2011-06-17 2011-06-17 Detergent composition comprising soil-release polymers of improved storage stability

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP11004982.2A EP2535401B1 (en) 2011-06-17 2011-06-17 Detergent composition comprising soil-release polymers of improved storage stability

Publications (2)

Publication Number Publication Date
EP2535401A1 EP2535401A1 (en) 2012-12-19
EP2535401B1 true EP2535401B1 (en) 2017-01-25

Family

ID=44764262

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11004982.2A Revoked EP2535401B1 (en) 2011-06-17 2011-06-17 Detergent composition comprising soil-release polymers of improved storage stability

Country Status (3)

Country Link
EP (1) EP2535401B1 (pl)
ES (1) ES2622230T3 (pl)
PL (1) PL2535401T3 (pl)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013224250A1 (de) * 2013-11-27 2015-05-28 Henkel Ag & Co. Kgaa Lipasestabilisierung in Geschirrspülmitteln
BR112016027081B1 (pt) 2014-05-22 2022-10-11 Unilever Ip Holdings B.V Formulação líquida aquosa para lavagem de roupas
US9828571B2 (en) * 2015-06-05 2017-11-28 Illinois Tool Works, Inc. Heavy duty laundry detergent
CN105154253A (zh) * 2015-10-09 2015-12-16 湖北穆兰同大科技有限公司 生物多酶清洗剂及其制备方法
WO2018028933A1 (en) * 2016-08-08 2018-02-15 Henkel Ag & Co. Kgaa Stable liquid detergent comprising soil release polymer
WO2018028935A1 (en) * 2016-08-08 2018-02-15 Henkel Ag & Co. Kgaa Stable liquid detergent comprising soil release polymer
WO2018028934A1 (en) * 2016-08-08 2018-02-15 Henkel Ag & Co. Kgaa Stable liquid detergent comprising soil release polymer
WO2018028936A1 (en) * 2016-08-08 2018-02-15 Henkel Ag & Co. Kgaa Stable liquid detergent comprising soil release polymer
DE102017104480A1 (de) 2017-03-03 2018-09-06 Nordmark Arzneimittel Gmbh & Co. Kg Wässrige Lösung von Burlulipase umfassend Kalziumionen
WO2019092191A1 (en) * 2017-11-13 2019-05-16 Unilever Plc Method of demonstrating sebum removal from laundered garments
EP3861115A1 (en) * 2018-10-05 2021-08-11 Basf Se Compounds stabilizing hydrolases in liquids
BR112021006317A2 (pt) * 2018-10-05 2021-07-06 Basf Se preparação de enzima, processo para preparar uma preparação de enzima estável, métodos para reduzir perda da atividade amiolítica, de preparação de uma formulação detergente, para remover manchas sensíveis à amilase e para aumentar a estabilidade no armazenamento de uma formulação detergente líquida, usos de um composto e da preparação de enzima, e, formulação detergente
US12084633B2 (en) 2020-12-15 2024-09-10 Henkel Ag & Co. Kgaa Unit dose laundry detergent compositions containing soil release polymers

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4959179A (en) 1989-01-30 1990-09-25 Lever Brothers Company Stabilized enzymes liquid detergent composition containing lipase and protease
WO1995016767A1 (en) 1993-12-14 1995-06-22 The Procter & Gamble Company Liquid laundry detergents containing polyamino acid and polyalkylene glycol
US5496490A (en) 1993-09-07 1996-03-05 Colgate-Palmolive Co. Laundry detergent compositions containing lipase and soil release polymer
WO1996028557A2 (en) 1995-03-09 1996-09-19 The Procter & Gamble Company Subtilisin dy variants having decreased adsorption and increased hydrolysis
WO1997020098A1 (en) 1995-11-27 1997-06-05 The Procter & Gamble Company Cleaning method for textile fabrics
WO1998038276A1 (en) 1997-02-28 1998-09-03 The Procter & Gamble Company Detergent compositions having color care agents
WO2000022079A1 (en) 1998-10-13 2000-04-20 The Procter & Gamble Company Detergent compositions or components
WO2000023548A1 (en) 1998-10-20 2000-04-27 The Procter & Gamble Company Laundry detergents comprising modified alkylbenzene sulfonates
US20020010105A1 (en) 1994-10-20 2002-01-24 The Procter & Gamble Company Detergent compositions containing enduring perfume
WO2007044993A2 (en) 2005-10-12 2007-04-19 Genencor International, Inc. Use and production of storage-stable neutral metalloprotease
WO2011072099A2 (en) 2009-12-09 2011-06-16 Danisco Us Inc. Compositions and methods comprising protease variants

Family Cites Families (3)

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Publication number Priority date Publication date Assignee Title
US4861512A (en) * 1984-12-21 1989-08-29 The Procter & Gamble Company Sulfonated block polyesters useful as soil release agents in detergent compositions
US5447649A (en) * 1990-03-01 1995-09-05 Novo Nordisk A/S Lipase containing liquid pre-spotter and use of such pre-spotter
AR000649A1 (es) * 1995-01-09 1997-07-10 Novo Nordisk As Composiciones líquidas de enzimas procedimientos para preparar una composición detergente y una composición detergente

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4959179A (en) 1989-01-30 1990-09-25 Lever Brothers Company Stabilized enzymes liquid detergent composition containing lipase and protease
US5496490A (en) 1993-09-07 1996-03-05 Colgate-Palmolive Co. Laundry detergent compositions containing lipase and soil release polymer
WO1995016767A1 (en) 1993-12-14 1995-06-22 The Procter & Gamble Company Liquid laundry detergents containing polyamino acid and polyalkylene glycol
US20020010105A1 (en) 1994-10-20 2002-01-24 The Procter & Gamble Company Detergent compositions containing enduring perfume
WO1996028557A2 (en) 1995-03-09 1996-09-19 The Procter & Gamble Company Subtilisin dy variants having decreased adsorption and increased hydrolysis
WO1997020098A1 (en) 1995-11-27 1997-06-05 The Procter & Gamble Company Cleaning method for textile fabrics
WO1998038276A1 (en) 1997-02-28 1998-09-03 The Procter & Gamble Company Detergent compositions having color care agents
WO2000022079A1 (en) 1998-10-13 2000-04-20 The Procter & Gamble Company Detergent compositions or components
WO2000023548A1 (en) 1998-10-20 2000-04-27 The Procter & Gamble Company Laundry detergents comprising modified alkylbenzene sulfonates
WO2007044993A2 (en) 2005-10-12 2007-04-19 Genencor International, Inc. Use and production of storage-stable neutral metalloprotease
WO2011072099A2 (en) 2009-12-09 2011-06-16 Danisco Us Inc. Compositions and methods comprising protease variants

Non-Patent Citations (6)

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Title
BAUER, C-A. ET AL.: "Effect of Boric Acid on the Catalytic Activity of Streptomyces griseus Protease 3", EUROPEAN JOURNAL OF BIOCHEMISTRY, vol. 45, 1974, pages 473 - 477, XP055437716
EBDRUP, S. ET AL.: "Structure-activity relationship for aryl and heteroaryl boronic acid inhibitors of hormone-sensntive lipase", BIOORGANIC & MEDICINAL CHEMISTRY, vol. 13, 2005, pages 2305 - 2312, XP004759027
FERNANDEZ-LAFUENTE, R.: "Lipase from Thermomyces languginosus: Uses and prospects as an industrial biocatalyst", JOURNAL OF MOLECULAR CATALYSIS B: ENZYMATIC, vol. 62, 2010, pages 197 - 212, XP026855415
GUY BROZE: "Handbook of Detergents, Part A: Properties", vol. 82, 1999, MARCEL DEKKER, INC., pages: 639 - 651, XP055437703
LUBERT STRYER: "Biochemistry", 1975, pages: 116, XP055437698
TSUNG MIN KUO ET AL.: "Lipid Biotechnology", 2002, pages: 357 - 358, XP055437710

Also Published As

Publication number Publication date
ES2622230T3 (es) 2017-07-06
PL2535401T3 (pl) 2017-07-31
EP2535401A1 (en) 2012-12-19

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