EP2535401B1 - Composition de détergent comportant des polymères de libération des saletés de stabilité de stockage améliorée - Google Patents

Composition de détergent comportant des polymères de libération des saletés de stabilité de stockage améliorée Download PDF

Info

Publication number
EP2535401B1
EP2535401B1 EP11004982.2A EP11004982A EP2535401B1 EP 2535401 B1 EP2535401 B1 EP 2535401B1 EP 11004982 A EP11004982 A EP 11004982A EP 2535401 B1 EP2535401 B1 EP 2535401B1
Authority
EP
European Patent Office
Prior art keywords
composition
soil
water
lipase
amount
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP11004982.2A
Other languages
German (de)
English (en)
Other versions
EP2535401A1 (fr
Inventor
Stefan Müller
Jessica Dichter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dalli Werke GmbH and Co KG
Original Assignee
Dalli Werke GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=44764262&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP2535401(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dalli Werke GmbH and Co KG filed Critical Dalli Werke GmbH and Co KG
Priority to PL11004982T priority Critical patent/PL2535401T3/pl
Priority to EP11004982.2A priority patent/EP2535401B1/fr
Priority to ES11004982.2T priority patent/ES2622230T3/es
Publication of EP2535401A1 publication Critical patent/EP2535401A1/fr
Application granted granted Critical
Publication of EP2535401B1 publication Critical patent/EP2535401B1/fr
Revoked legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3715—Polyesters or polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase

Definitions

  • the present invention relates to a detergent composition, in particular a liquid laundry detergent composition, comprising at least one lipase, at least one soil-release polymer comprising ester moieties and at least one compound which stabilizes said at least one soil-release polymer in the presence of said lipase, to a method for stabilizing such a soil-release polymer in a detergent composition comprising a lipase and to the use of certain compounds for stabilizing soil-release polymers comprising ester moieties in detergent compositions further comprising at least one lipase.
  • the composition of the present invention may comprise of from 20 to 90 wt.-%, more preferably of from 30 to 80 wt.-%, even more preferably of from 40 to 75 wt.-% and most preferably of from 50 to 70 wt.-% of at least one liquid carrier, including the particulary preferred ranges of 52 to 68 wt.-% and 55 to 65 wt.-%, based on the whole composition.
  • mixtures of the afore-mentioned solvents may be employed.
  • a mixture of water and at least one alcohol may be employed as a liquid carrier, wherein the ratio of the amount of water to the amount of alcohol(s) present in the composition preferably may be in the range of from 1:1 to 20:1, more preferably of from 2:1 to 10:1, even more preferably of from 3:1 to 7:1.
  • the alcoholic part of the liquid carrier preferably represents a mixture of at least two different alcohols, preferably of at least one monohydric C 1 -C 4 alcohol and a C 2 -C 6 diol.
  • the liquid carrier may represent a mixture of ethanol and 1,2-propyleneglycol.
  • the ratio of the amount of soil release polymer to the amount of lipase present in the composition preferably may be in the range of from 10:1 to 200:1, more preferably of from 20:1 to 150:1, even more preferably of from 40:1 to 120:1 and most preferably of from 60:1 to 100:1, including the particularly preferred ranges of from 70:1 to 90:1 and of from 75:1 to 85:1.
  • the amount of the boronic acid or water-soluble salts thereof in the composition of the present invention preferably may be in the range of from 0.001 to 1 wt.-%, more preferably in the range of from 0.01 to 0.7 wt.-% and most preferably in the range from 0.02 to 0.5 wt.-%.
  • water-soluble salts of calcium, magnesium or zinc which upon dissolution in the detergent composition of the present invention provide a concentration of calcium, magnesium and/or zinc ions in the range of from 0.01 to 100 mmol, preferably of 0.1 to 10 mmol per liter of the composition may be used.
  • Suitable salts are for example calcium chloride, calcium hydroxide, calcium sulfate, calcium acetate and the like, as well as the corresponding magnesium or zinc salts, without being limited to these.
  • composition of the present invention preferably may comprise at least one further enzyme, which preferably may be selected from the group consisting of proteases, amylases, mannanases, cellulales, peroxidases, pectinases, further esterases or a mixture thereof.
  • Washing tests were carried out in a Linitest which has eight little "beakers” and simulates eight European drum type washing machines.
  • the washing temperature was set to 40 °C, and the heating rate was set to 2 °C per minute.
  • the time for one washing cycle was set to 30 minutes, for both a prewash and the main wash cycle. Rotations were set to 40 rotations per minute. 250 mL of washing liquor were used per beaker and washing cycle. As a soil 50 mL of used synthetic motor oil were applied to each piece of fabric.
  • test fabrics were prewashed using this commercially available product and soiled as described above.
  • Example 3 Stabilization of a soil-release polymer in liquid detergent compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Claims (15)

  1. Composition de détergent, comprenant au moins une lipase, au moins un polymère détachant les salissures, comprenant des fragments ester, en une quantité d'au moins 0,25 % en poids, par rapport à la composition totale, et au moins un composé qui stabilise ledit au moins un polymère détachant les salissures en présence de ladite lipase pendant le stockage de la composition et est choisi dans l'ensemble constitué par l'aide borique ou des borates hydrosolubles capables d'engendrer de l'aide borique, en une quantité de plus de 1 % en poids à 5,5 % en poids, par rapport à la composition totale et calculée sur la base de l'acide borique; des acides boroniques ou des sels hydrosolubles de ceux-ci en une quantité de 0,001 à 1 % en poids, par rapport à la composition totale; l'acide formique ou des sels hydrosolubles de celui-ci, en une quantité de 0,005 à 0,5 % en poids, par rapport à la composition totale; l'acide lactique en une quantité de 1 à 10 % en poids, par rapport à la composition totale; des sels hydrosolubles de calcium, magnésium ou zinc, en une quantité de 0,01 à 100 mmoles par litre de la composition, ou des mélanges de ceux-ci.
  2. Composition selon la revendication 1, la composition étant une composition de détergent lessiviel liquide, de préférence pour utilisation dans des machines à laver domestiques, qui comprend de préférence de 20 à 90 % en poids, de façon plus particulièrement préférée de 30 à 80 % en poids et de façon encore plus particulièrement préférée de 50 à 70 % en poids d'une substance de support liquide, choisie dans l'ensemble constitué par l'eau, des alcools ou des mélanges de ceux-ci.
  3. Composition selon la revendication 1 ou 2, dans laquelle au moins une lipase est une triacylglycérol lipase et est présente dans la composition de préférence en une quantité de 0,001 à environ 0,05 % en poids, de façon plus particulièrement préférée de 0,002 à 0,02 % en poids, par rapport à la composition totale.
  4. Composition selon l'une quelconque des revendications 1 à 3, dans laquelle ledit au moins un polymère détachant les salissures comprend des fragments ester téréphtalate et représente de préférence un copolymère, de façon plus particulièrement préférée un copolyester comprenant des motifs téréphtaloyle, alkylèneglycol et polyalkylèneglycol en de façon encore plus particulièrement préférée un copolymère comprenant des motifs poly(éthylène-téréphtalate) et poly(oxyéthylène-téréphtalate).
  5. Composition selon l'une quelconque des revendications 1 à 4, dans laquelle la quantité du(des) polymère(s) détachant les salissures dans la composition est d'au moins 0,3 % en poids, de préférence d'au moins 0,35 % en poids, de façon plus particulièrement préférée d'au moins 0,4 % en poids et de façon tout particulièrement préférée d'au moins 0,5 % en poids, par rapport à la composition totale.
  6. Composition selon l'une quelconque des revendications 1 à 5, dans laquelle le rapport de la quantité de polymère détachant les salissures à la quantité de lipase présentes dans la composition (% en poids/% en poids) est dans la plage de 10:1 à 200:1, de préférence de 20:1 à 150:1, de façon plus particulièrement préférée de 40:1 à 120:1 et de façon encore plus particulièrement préférée de 60:1 à 100:1.
  7. Composition selon l'une quelconque des revendications 1 à 6, dans laquelle le rapport de la quantité du composé qui stabilise le polymère détachant les salissures à la quantité de lipase présentes dans la composition (% en poids/% en poids) est (i) dans la plage de 100:1 à 1 000:1, de préférence de 150:1 à 750:1, et de façon tout particulièrement préférée de 200:1 à 600:1, si ledit composé représente l'acide borique ou un borate hydrosoluble capable d'engendrer de l'acide borique, calculé sur la base de l'acide borique, ou (ii) dans la plage de 1:1 à 50:1, de préférence de 1,2:1 à 20:1, et de façon tout particulièrement préférée de 2:1 à 10:1, si ledit composé représente un acide boronique, un sel hydrosoluble de celui-ci, l'acide formique ou un sel hydrosoluble de celui-ci.
  8. Composition selon l'une quelconque des revendications 1 à 7, dans laquelle le pH de la composition est dans l'intervalle de 7,0 à 13, de préférence de 7,0 à 12, de façon plus particulièrement préférée de 7,0 à 11 et de façon tout particulièrement préférée de 7,0 à 9,5.
  9. Composition selon l'une quelconque des revendications 1 à 8, comprenant en outre au moins un tensioactif, choisi de préférence dans l'ensemble constitué par des tensioactifs anioniques et des tensioactifs non ioniques ou un mélange de ceux-ci, de façon plus particulièrement préférée un mélange de tensioactifs anioniques et de tensioactifs non ioniques, en une quantité de 10 à 50 % en poids, par rapport à la composition totale.
  10. Composition selon l'une quelconque des revendications 1 à 9, comprenant en outre une autre enzyme, choisie de préférence dans l'ensemble constitué par des protéases, amylases, mannanases, cellulases, peroxydases, pectinases, d'autres estérases ou un mélanges de celles-ci.
  11. Composition selon l'une quelconque des revendications 1 à 10, comprenant en outre un ou plusieurs composés choisis dans l'ensemble constitué par des alcalis, des agents de blanchiment, des activateurs de blanchiment, des catalyseurs de blanchiment, des adjuvants actifs de détergence, des agents colorants, des agents chélateurs, des colorants, des inhibiteurs de transfert de colorants, des antimousses, des agents hydrotropes, des azurants optiques, des parfums, des pigments, des tampons de pH, des conservateurs ou des savons.
  12. Procédé pour la stabilisation d'un polymère détachant les salissures comprenant des fragments ester, dans une composition qui comprend en outre ne lipase, par association dudit polymère détachant les salissures et de ladite lipase avec un composé pour la stabilisation dudit polymère détachant les salissures, choisi dans l'ensemble constitué par l'acide borique ou des borates hydrosolubles capables d'engendrer de l'acide borique, des acides boroniques ou des sels hydrosolubles de ceux-ci, l'acide formique ou des sels hydrosolubles de celui-ci, les sels hydrosolubles de calcium, magnésium ou zinc ou des mélanges de ceux-ci.
  13. Procédé selon la revendication 12, dans lequel la composition de détergent est une composition de détergent liquide, de préférence une composition de détergent selon l'une quelconque des revendications 1 à 11.
  14. Utilisation d'un composé choisi dans l'ensemble constitué par l'acide borique ou des borates hydrosolubles capables d'engendrer de l'acide borique, des acides boroniques ou des sels hydrosolubles de ceux-ci, l'acide formique ou des sels hydrosolubles de celui-ci, les sels hydrosolubles de calcium, magnésium ou zinc ou des mélanges de ceux-ci, pour la stabilisation d'un polymère détachant les salissures, comprenant des fragments ester, en présence d'une lipase.
  15. Utilisation selon la revendication 14, dans laquelle ledit polymère détachant les salissures ainsi que ladite lipase sont présents l'un et l'autre dans une composition de détergent, de préférence une composition de détergent selon l'une quelconque des revendications 1 à 11.
EP11004982.2A 2011-06-17 2011-06-17 Composition de détergent comportant des polymères de libération des saletés de stabilité de stockage améliorée Revoked EP2535401B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
PL11004982T PL2535401T3 (pl) 2011-06-17 2011-06-17 Kompozycja detergentowa zawierająca polimery uwalniające zabrudzenia, o lepszej stabilności podczas przechowywania
EP11004982.2A EP2535401B1 (fr) 2011-06-17 2011-06-17 Composition de détergent comportant des polymères de libération des saletés de stabilité de stockage améliorée
ES11004982.2T ES2622230T3 (es) 2011-06-17 2011-06-17 Composición de detergente que comprende polímeros de liberación de suciedad con estabilidad en almacenamiento mejorada

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP11004982.2A EP2535401B1 (fr) 2011-06-17 2011-06-17 Composition de détergent comportant des polymères de libération des saletés de stabilité de stockage améliorée

Publications (2)

Publication Number Publication Date
EP2535401A1 EP2535401A1 (fr) 2012-12-19
EP2535401B1 true EP2535401B1 (fr) 2017-01-25

Family

ID=44764262

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11004982.2A Revoked EP2535401B1 (fr) 2011-06-17 2011-06-17 Composition de détergent comportant des polymères de libération des saletés de stabilité de stockage améliorée

Country Status (3)

Country Link
EP (1) EP2535401B1 (fr)
ES (1) ES2622230T3 (fr)
PL (1) PL2535401T3 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013224250A1 (de) * 2013-11-27 2015-05-28 Henkel Ag & Co. Kgaa Lipasestabilisierung in Geschirrspülmitteln
BR112016027081B1 (pt) 2014-05-22 2022-10-11 Unilever Ip Holdings B.V Formulação líquida aquosa para lavagem de roupas
US9828571B2 (en) * 2015-06-05 2017-11-28 Illinois Tool Works, Inc. Heavy duty laundry detergent
CN105154253A (zh) * 2015-10-09 2015-12-16 湖北穆兰同大科技有限公司 生物多酶清洗剂及其制备方法
WO2018028936A1 (fr) * 2016-08-08 2018-02-15 Henkel Ag & Co. Kgaa Détergent liquide stable comprenant un polymère facilitant l'élimination des taches au lavage (« soil release »)
WO2018028934A1 (fr) * 2016-08-08 2018-02-15 Henkel Ag & Co. Kgaa Détergent liquide stable comprenant un polymère facilitant l'élimination des taches au lavage (« soil release »)
WO2018028933A1 (fr) * 2016-08-08 2018-02-15 Henkel Ag & Co. Kgaa Détergent liquide stable comprenant un polymère facilitant l'élimination des taches au lavage (« soil release »)
WO2018028935A1 (fr) * 2016-08-08 2018-02-15 Henkel Ag & Co. Kgaa Détergent liquide stable comprenant un polymère facilitant l'élimination des taches au lavage (« soil release »)
DE102017104480A1 (de) 2017-03-03 2018-09-06 Nordmark Arzneimittel Gmbh & Co. Kg Wässrige Lösung von Burlulipase umfassend Kalziumionen
CN111344566B (zh) * 2017-11-13 2023-07-21 联合利华知识产权控股有限公司 展示从经洗涤的衣物除去皮脂的方法
WO2020069914A1 (fr) * 2018-10-05 2020-04-09 Basf Se Composés stabilisant les amylases dans des liquides
WO2020069915A1 (fr) * 2018-10-05 2020-04-09 Basf Se Composés stabilisant les hydrolases dans des liquides
US12084633B2 (en) 2020-12-15 2024-09-10 Henkel Ag & Co. Kgaa Unit dose laundry detergent compositions containing soil release polymers

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4959179A (en) 1989-01-30 1990-09-25 Lever Brothers Company Stabilized enzymes liquid detergent composition containing lipase and protease
WO1995016767A1 (fr) 1993-12-14 1995-06-22 The Procter & Gamble Company Detergents liquides a lessive contenant de l'acide polyamine et du polyalkyleneglycol
US5496490A (en) 1993-09-07 1996-03-05 Colgate-Palmolive Co. Laundry detergent compositions containing lipase and soil release polymer
WO1996028557A2 (fr) 1995-03-09 1996-09-19 The Procter & Gamble Company Variants de la subtilisine dy dotes d'un pouvoir d'adsorption affaibli et d'une capacite d'hydrolyse accrue
WO1997020098A1 (fr) 1995-11-27 1997-06-05 The Procter & Gamble Company Procede de nettoyage pour textiles
WO1998038276A1 (fr) 1997-02-28 1998-09-03 The Procter & Gamble Company Compositions detergentes comportant des agents protecteurs des couleurs
WO2000022079A1 (fr) 1998-10-13 2000-04-20 The Procter & Gamble Company Compositions ou composants detergents
WO2000023548A1 (fr) 1998-10-20 2000-04-27 The Procter & Gamble Company Detergents a lessive comprenant des alcoylbenzenesulfonates modifies
US20020010105A1 (en) 1994-10-20 2002-01-24 The Procter & Gamble Company Detergent compositions containing enduring perfume
WO2007044993A2 (fr) 2005-10-12 2007-04-19 Genencor International, Inc. Utilisation et production d'une metalloprotease neutre stable au stockage
WO2011072099A2 (fr) 2009-12-09 2011-06-16 Danisco Us Inc. Compositions et procédés comprenant des variants de protéase

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4861512A (en) * 1984-12-21 1989-08-29 The Procter & Gamble Company Sulfonated block polyesters useful as soil release agents in detergent compositions
US5447649A (en) * 1990-03-01 1995-09-05 Novo Nordisk A/S Lipase containing liquid pre-spotter and use of such pre-spotter
AU4328396A (en) * 1995-01-09 1996-07-31 Novo Nordisk A/S Stabilization of liquid enzyme compositions

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4959179A (en) 1989-01-30 1990-09-25 Lever Brothers Company Stabilized enzymes liquid detergent composition containing lipase and protease
US5496490A (en) 1993-09-07 1996-03-05 Colgate-Palmolive Co. Laundry detergent compositions containing lipase and soil release polymer
WO1995016767A1 (fr) 1993-12-14 1995-06-22 The Procter & Gamble Company Detergents liquides a lessive contenant de l'acide polyamine et du polyalkyleneglycol
US20020010105A1 (en) 1994-10-20 2002-01-24 The Procter & Gamble Company Detergent compositions containing enduring perfume
WO1996028557A2 (fr) 1995-03-09 1996-09-19 The Procter & Gamble Company Variants de la subtilisine dy dotes d'un pouvoir d'adsorption affaibli et d'une capacite d'hydrolyse accrue
WO1997020098A1 (fr) 1995-11-27 1997-06-05 The Procter & Gamble Company Procede de nettoyage pour textiles
WO1998038276A1 (fr) 1997-02-28 1998-09-03 The Procter & Gamble Company Compositions detergentes comportant des agents protecteurs des couleurs
WO2000022079A1 (fr) 1998-10-13 2000-04-20 The Procter & Gamble Company Compositions ou composants detergents
WO2000023548A1 (fr) 1998-10-20 2000-04-27 The Procter & Gamble Company Detergents a lessive comprenant des alcoylbenzenesulfonates modifies
WO2007044993A2 (fr) 2005-10-12 2007-04-19 Genencor International, Inc. Utilisation et production d'une metalloprotease neutre stable au stockage
WO2011072099A2 (fr) 2009-12-09 2011-06-16 Danisco Us Inc. Compositions et procédés comprenant des variants de protéase

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
BAUER, C-A. ET AL.: "Effect of Boric Acid on the Catalytic Activity of Streptomyces griseus Protease 3", EUROPEAN JOURNAL OF BIOCHEMISTRY, vol. 45, 1974, pages 473 - 477, XP055437716
EBDRUP, S. ET AL.: "Structure-activity relationship for aryl and heteroaryl boronic acid inhibitors of hormone-sensntive lipase", BIOORGANIC & MEDICINAL CHEMISTRY, vol. 13, 2005, pages 2305 - 2312, XP004759027
FERNANDEZ-LAFUENTE, R.: "Lipase from Thermomyces languginosus: Uses and prospects as an industrial biocatalyst", JOURNAL OF MOLECULAR CATALYSIS B: ENZYMATIC, vol. 62, 2010, pages 197 - 212, XP026855415
GUY BROZE: "Handbook of Detergents, Part A: Properties", vol. 82, 1999, MARCEL DEKKER, INC., pages: 639 - 651, XP055437703
LUBERT STRYER: "Biochemistry", 1975, pages: 116, XP055437698
TSUNG MIN KUO ET AL.: "Lipid Biotechnology", 2002, pages: 357 - 358, XP055437710

Also Published As

Publication number Publication date
ES2622230T3 (es) 2017-07-06
EP2535401A1 (fr) 2012-12-19
PL2535401T3 (pl) 2017-07-31

Similar Documents

Publication Publication Date Title
EP2535401B1 (fr) Composition de détergent comportant des polymères de libération des saletés de stabilité de stockage améliorée
CN109072133B (zh) 具有dna酶活性的多肽用于处理织物的用途
US10323213B2 (en) Detergent containing amine oxide
AU2012238950B2 (en) Method of laundering fabric
EP3655463B1 (fr) Polymères de siloxane fonctionnalisés et compositions comprenant ces polymères
EP4263773B1 (fr) Composition de nettoyage
EP3824057B1 (fr) Utilisation d'un rhamnolipide dans un système tensioactif
CN101617035A (zh) 用于洗衣的酶泡沫处理
EP3655462B1 (fr) Polymères de siloxane fonctionnalisés et compositions comprenant ces polymères
EP3786272A1 (fr) Composition de détergent à lessive liquide à dose unitaire
EP0318279B1 (fr) Compositions pour le lavage en machine de la vaisselle
KR101928587B1 (ko) 리파아제 및 포스포네이트를 함유하는 액체 계면활성제 제제
CA3130450A1 (fr) Compositions de detergent a lessive
EP3668960B1 (fr) Procédé de traitement de tissus
DE102015225465A1 (de) Flüssige Tensidzusammensetzung mit spezieller Kombination aus Enzym und Stabilisator
US20020123447A1 (en) Layered silicate built laundry detergent composition
WO2020229480A1 (fr) Composés stabilisant des hydrolases dans des liquides
EP4414443A1 (fr) Composition de nettoyage comprenant une polyesterase
JP6157970B2 (ja) 衣料用液体洗浄剤組成物
CN117441003A (zh) 机器餐具洗涤剂
JP2001064696A (ja) 予浸洗浄剤組成物

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

17P Request for examination filed

Effective date: 20130419

17Q First examination report despatched

Effective date: 20150817

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20160707

GRAJ Information related to disapproval of communication of intention to grant by the applicant or resumption of examination proceedings by the epo deleted

Free format text: ORIGINAL CODE: EPIDOSDIGR1

INTC Intention to grant announced (deleted)
GRAR Information related to intention to grant a patent recorded

Free format text: ORIGINAL CODE: EPIDOSNIGR71

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

INTG Intention to grant announced

Effective date: 20161215

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 864158

Country of ref document: AT

Kind code of ref document: T

Effective date: 20170215

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602011034585

Country of ref document: DE

REG Reference to a national code

Ref country code: NL

Ref legal event code: FP

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 7

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2622230

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20170706

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170426

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170425

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170525

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170525

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170425

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20170725

Year of fee payment: 10

Ref country code: AT

Payment date: 20170622

Year of fee payment: 7

REG Reference to a national code

Ref country code: DE

Ref legal event code: R026

Ref document number: 602011034585

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

26 Opposition filed

Opponent name: THE PROCTER & GAMBLE COMPANY

Effective date: 20171025

Opponent name: HENKEL AG & CO. KGAA

Effective date: 20171025

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170617

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170630

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170630

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170617

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 864158

Country of ref document: AT

Kind code of ref document: T

Effective date: 20180617

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180617

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180617

APBM Appeal reference recorded

Free format text: ORIGINAL CODE: EPIDOSNREFNO

APBP Date of receipt of notice of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA2O

APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO

APBM Appeal reference recorded

Free format text: ORIGINAL CODE: EPIDOSNREFNO

APBP Date of receipt of notice of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA2O

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20110617

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

R26 Opposition filed (corrected)

Opponent name: THE PROCTER & GAMBLE COMPANY

Effective date: 20171025

APBQ Date of receipt of statement of grounds of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA3O

APBQ Date of receipt of statement of grounds of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA3O

REG Reference to a national code

Ref country code: AT

Ref legal event code: UEP

Ref document number: 864158

Country of ref document: AT

Kind code of ref document: T

Effective date: 20170125

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170125

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170125

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20200604

Year of fee payment: 10

Ref country code: FR

Payment date: 20200619

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20200625

Year of fee payment: 10

Ref country code: BE

Payment date: 20200625

Year of fee payment: 10

Ref country code: PL

Payment date: 20200605

Year of fee payment: 10

Ref country code: GB

Payment date: 20200625

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20200825

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20200625

Year of fee payment: 10

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602011034585

Country of ref document: DE

R26 Opposition filed (corrected)

Opponent name: HENKEL AG & CO. KGAA

Effective date: 20171025

REG Reference to a national code

Ref country code: NL

Ref legal event code: MM

Effective date: 20210701

APBU Appeal procedure closed

Free format text: ORIGINAL CODE: EPIDOSNNOA9O

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20210617

REG Reference to a national code

Ref country code: DE

Ref legal event code: R103

Ref document number: 602011034585

Country of ref document: DE

Ref country code: DE

Ref legal event code: R064

Ref document number: 602011034585

Country of ref document: DE

RDAF Communication despatched that patent is revoked

Free format text: ORIGINAL CODE: EPIDOSNREV1

RDAG Patent revoked

Free format text: ORIGINAL CODE: 0009271

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT REVOKED

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20210630

REG Reference to a national code

Ref country code: FI

Ref legal event code: MGE

27W Patent revoked

Effective date: 20220224

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210617

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20220101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210701

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210630

REG Reference to a national code

Ref country code: AT

Ref legal event code: MA03

Ref document number: 864158

Country of ref document: AT

Kind code of ref document: T

Effective date: 20220224

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210617

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210618

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210618

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210630