EP2477933A2 - Tête de fermeture pour visser des bouchons à vis - Google Patents
Tête de fermeture pour visser des bouchons à visInfo
- Publication number
- EP2477933A2 EP2477933A2 EP10760914A EP10760914A EP2477933A2 EP 2477933 A2 EP2477933 A2 EP 2477933A2 EP 10760914 A EP10760914 A EP 10760914A EP 10760914 A EP10760914 A EP 10760914A EP 2477933 A2 EP2477933 A2 EP 2477933A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- head according
- screw
- closing
- annular surface
- angle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67B—APPLYING CLOSURE MEMBERS TO BOTTLES JARS, OR SIMILAR CONTAINERS; OPENING CLOSED CONTAINERS
- B67B3/00—Closing bottles, jars or similar containers by applying caps
- B67B3/20—Closing bottles, jars or similar containers by applying caps by applying and rotating preformed threaded caps
- B67B3/2066—Details of capping heads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67B—APPLYING CLOSURE MEMBERS TO BOTTLES JARS, OR SIMILAR CONTAINERS; OPENING CLOSED CONTAINERS
- B67B3/00—Closing bottles, jars or similar containers by applying caps
- B67B3/20—Closing bottles, jars or similar containers by applying caps by applying and rotating preformed threaded caps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67B—APPLYING CLOSURE MEMBERS TO BOTTLES JARS, OR SIMILAR CONTAINERS; OPENING CLOSED CONTAINERS
- B67B3/00—Closing bottles, jars or similar containers by applying caps
Definitions
- the invention relates to a capping head for screwing screw caps onto containers, in particular bottles, according to the preamble of claim 1.
- Closing heads of the type mentioned here are known. They serve, when closing containers with screw caps, to screw the screw cap onto the container, in which case in particular a torque is transmitted from the closing head to the screw cap.
- the known Verschwinkexcellent on a central axis, which simultaneously forms an axis of rotation of the capping head, and a closure screw receiving a recess having Verschdorfkonus.
- the design as a closing cone requires that the recess, at least in the region of the closing cone, has a contour which is frusto-conical in cross section. This contour reduces the risk of jamming a screw cap in the recess or in the closing cone.
- the capping cone of such capping heads usually comprises a toothed tooth with teeth pointing substantially in the direction of the center axis of the capping cone.
- Such capping heads are used for screwing - that is to say for screwing tight - screw closures which have corrugations in the form of elevations or teeth on their outer circumferential surface.
- a high torque can be transferred from the capping head to a screw cap.
- the recess of the known Verschwinkée further has an opening through which a
- CONFIRMATION COPY Screw can be introduced into the sealing cone at least partially. It is known that an angled knife of the tooth profile lie on a first imaginary annular surface and a tip circle diameter of the tooth profile on a second imaginary annular surface, wherein the first and second annular surfaces are arranged concentrically to the central axis of the capping head. The second annular surface and the central axis define or close an angle ⁇ between them. Usually ⁇ > 0 ° is chosen to prevent jamming of a screw cap.
- the sealing cone is oriented so that it widens towards the opening. As is known, the first and second annular surfaces are aligned parallel to one another. The known Verschetzköpfe each work together only with a certain screw without problems.
- the closing head is characterized in that the first annular surface and the second annular surface include a second angle ⁇ > 0 °. It is thus provided that an angle greater than zero is located between the first annular surface and the second annular surface, so that the first annular surface and the second annular surface are not aligned parallel to one another. As a result, as seen in the direction of the central axis, the height of the teeth of the tooth profile increases. In an alternative approach, the depth of the tooth base - seen in the axial direction - increases.
- the height of the teeth or depth of the tooth base increases in the direction of the opening of the recess, so that in the region near the opening the teeth have a greater height than in the region far away from the opening, further inside.
- the expansion behavior of the screw when screwing - so when tightening the container - account is taken.
- a screw when viewed in the direction of its central axis seen - ie axially - expands differently.
- the screw caps on their outer surface near their closed end face stretch less far as close to the (threaded) opening, whereby, for example, when screwed on, a previously U-shaped cross section expands, at least in some areas, into a V-shaped cross section.
- the second angle ⁇ > 0 ° between the first and the second annular surface ensures that the screw cap can continue to expand in the region near the opening without it jamming in the capping head.
- the advantageous embodiment of the capping head makes it possible that different screw caps of a so-called SSverBankfamilie with the same capping head on containers, especially bottles, can be screwed.
- the screw caps of a screw cap family differ essentially in the formation of the corrugation and the expansion behavior of the screw cap.
- the choice of the angle ß> 0 allows even the screw cap of the screw cap family with the largest corrugation to be picked up and screwed without jamming by the capping cone.
- angles are selected such that the elongation when screwing does not cause the elevations of the corrugation pressed against the tooth roots or the Marin Vietnamese bemesser the tooth profile of the capping and thereby deformed or damaged. Overall, jamming and / or damaging different screw caps of a screw cap family is prevented by means of the advantageous capping head.
- the angle ⁇ > 0 ° is selected so that the closing cone is not defined or formed not only by the root circle radius of the tooth profile, but also by the tip circle radius or the second ring surface.
- the conicity of the Locking cone is then also formed by the second annular surface and the central axis include a first angle ⁇ > 0 °, and a first diameter of the second annular surface on an opening facing side is greater than a second diameter of the second annular surface facing away from the opening Page.
- the angle 0 ° is selected or will.
- the sealing cone is defined only by the first annular surface of the tooth profile and the angle ß> 0 °.
- the second annular surface, along which the tooth tips extend axially, however, is cylindrical.
- the closing cone overall can be brought particularly close to a screw-type closure which has a cylindrical or at least one cylindrical base surface. Due to the advantageous choice of the angle ß jamming of the screw cap during recording is still prevented in both cases.
- FIG. 1 shows a capping head with a screw cap of a first type
- Figure 2 shows the capping head with a screw cap of a second type of the same screw cap family.
- Figure 1 shows a simplified sectional view of an area or a half of a capping head 1 for screwing - ie for screwing - of screw caps on container.
- the capping head 1 has a central axis 3 about which the capping head 1 can be set into rotation for screwing on a screw cap, wherein the center axis 3 forms an axis of symmetry for the essential elements of the capping head 1.
- the capping head 1 can be arranged on a closing machine, not shown here, which has a drive which is operatively connected, for example, via a drive shaft with the capping head.
- the closing head 1 further comprises a recess 5, which at least partially has a closing cone 7.
- the closing cone 7 is arranged concentrically to the central axis of the closing head 1.
- the closing cone 7 is characterized in that on its inside a tooth profile 9 is provided with a plurality of teeth 11 distributed uniformly over the circumference of the closing cone 7.
- the number of teeth 11 corresponds to the number of elevations or teeth of a corrugation of a screw-on screw closure of a certain screw closure family to be screwed on.
- the corrugation of screw caps of a screw cap family always has the same number of elevations / teeth.
- a tailor-made adaptation of the width of the teeth 11 to the corrugation, however, is not absolutely necessary and ultimately not desired, otherwise the compatibility with different screw caps of a screw cap family would be limited.
- the tooth profile of Verschatekonus 7 generally has a common divider with the corrugation of a screw-on screw closure of a certain SSverBankfamilie screwed.
- the closing cone 7 comprises only 12 teeth, while the corrugations of the screw caps of the screw cap family 24, 60, 72, 120 or 144 have teeth or elevations. It is important that a meshing of tooth profile and corrugation is always possible.
- the teeth 11 of the tooth profile 9 extend parallel to the central axis 3 and expediently have at least substantially in the direction of the central axis 3.
- the dimensioning of the teeth 11 of the tooth profile 9 is determined by a réelle Vietnamese bemesser and a tip circle diameter, the boss Vietnamese silica, the tip diameter is located on a second imaginary annular surface 15.
- the first and the second annular surface 13, 15 are arranged concentrically to the central axis 3 of the closing head 1. It is thus provided that the tooth tips and tooth roots of the teeth 11 each lie on an imaginary annular surface 13, 15, which are arranged concentrically, so seen over the circumference of Verschatekonus 7, the teeth 11 of the tooth profile 9, the same height or tooth roots have the same depth.
- the second annular surface 15 and the central axis 3 enclose a first angle .alpha. Which is selected to be greater than 0 ° (a> 0 °).
- the closing head 1 has at its free end face 17th an opening 19 of the recess 5.
- the sealing cone is designed such that it widens toward the opening 19. For this purpose, a first diameter of the second annular surface 15 at a side facing the opening 19 is greater than a second diameter of the second annular surface 15 at a side facing away from the opening 19.
- the first annular surface 13 and the second annular surface 15 include a second angle ⁇ , which is also selected to be greater than 0 ° ( ⁇ > 0 °).
- ⁇ the angle ß
- the angle ß results for the tooth profile 9
- the height of the teeth 1 seen changed over its longitudinal extent in which case the distance between the first annular surface 13 and the second annular surface 15 on its side facing the opening 9 is greater than the distance between the annular surface 13 and the second annular surface 15 on its side facing away from the opening 19.
- the height of the teeth 11 and the depth of the tooth bottoms of the teeth 11 of the tooth profile 9 in the direction of the opening 19 increases.
- the angles and ⁇ are preferably chosen to be small so that the closest possible contact of the closing cone 7 with a screw closure is ensured.
- the first angle ⁇ lies in a range between 8 ° and 1 °, particularly preferably between 5 ° and 2 ° .in particular, the angle ⁇ is approximately 3.degree ..
- the second angle .beta. Is preferably in a range between 1.degree 5 °. This results in a maximum value of 13 ° and a minimum value of 3 ° for the angle ⁇ .
- the capping head 1 further comprises an alignment device 21, which ensures a defined relative position between the capping cone and a screw cap received by the recess 5.
- the defined relative position is at least the twisting position of the closing head relative to the corresponding screw cap.
- the alignment device 21 is to ensure that when receiving a screw through the recess 5, the teeth 1 1 of the tooth profile 9 are guided in the interdental spaces of a corrugation of a screw cap. This prevents that the corrugation of a screw is already damaged during the recording process, or that the screw in the recess 5 jammed.
- the recording process is also referred to as picking.
- the alignment device 21 preferably comprises at least one alignment surface 23, which can be brought into operative contact with the screw closure for alignment.
- the alignment surface 23 is formed such that it cooperates with the corrugation of the screw cap and is arranged on the inside of the recess 9.
- the alignment surface 23 can be arranged in the region of the sealing cone 7 or also in a region between the sealing cone 7 and the opening 19 of the recess 5.
- the closing cone 7 or the tooth profile 9 connects substantially directly to the alignment surface 23.
- a screw cap is positioned before it comes into operative contact with the tooth profile 9.
- the alignment surface 23 is provided at least on a tooth 11 of the tooth profile 9.
- the alignment surface 23 is in the region of the closing cone 7 or of the tooth profile 9 and on the other hand is formed by the tooth profile 9 itself.
- the alignment surface 23 may in this case be distinguished, for example, by having a wedge-shaped centering tip in the direction of the opening 19 at an end of the corresponding tooth 11 of the tooth profile 9 which faces the opening.
- the alignment surface 23 is provided on a picking element 25.
- the alignment surface 23 can be shaped as described above.
- the picking element 25 is preferably movably mounted in the closing cone 1.
- the closing cone 1 has at least one lateral recess, which opens into the recess 5.
- the recess 5 in its lateral surface on the recess 27, in which the picking element 25 is movably mounted.
- the picking element 25 is at least substantially radially displaceable with respect to the central axis 3.
- the picking element 25 is biased held in the closing cone 1 and in the recesses 27, for which purpose at least one spring element not shown here is provided.
- the spring element exerts on the picking element 25 a force directed in the direction of the recess 5 or in the direction of a screw cap present in the recess 5.
- the biased displaceability of the pimpling element 25 and thus the alignment surface 23 allows on the one hand an alignment of the screw cap to the capping and on the other hand it prevents damage to the Screw closure, if this is received in an unfavorable for aligning rotational position of the recess 5.
- Such a situation may arise, for example, in that the alignment surface 23 meets exactly one tooth of the corrugation of a screw cap.
- the picking element 25 can be pushed back into the closing head 1 and penetrate after a slight rotation of the capping head and / or the screw cap in a tooth space of the corrugation of the screw cap.
- the spring element is preferably an elastically deformable element which is particularly preferably formed by a simple helical spring or also by a ring or band spring or by an O-ring, which respectively extend over the entire circumference of the closure head.
- the band spring can also pretension further picking elements corresponding to the picking elements of the alignment device, which can be distributed over the circumference of the closing head.
- the one or more picking elements can also serve for centering a screw cap in the recess 5 or in the closing cone 7.
- a stop 29 is provided which forms the end of the recess 5 opposite the opening 19. It limits the penetration of a screw cap into the closing cone 7. In particular, it prevents a screw cap from being inserted so far into the closing cone 7 or into the recess 5 that it jams and / or that the tooth profile 9 is pressed against a region of the screw cap. which is no longer compatible with the Rif- is provided, whereby this area, such as a warranty ring of the screw cap, could be damaged.
- the stop 29 also prevents tilting or tumbling of a screw in the Verschierkonus 7.
- the stop 29 may be formed, for example, as a closed bottom surface of the recess 5, in which case the recess 5 has a substantially cup-shaped cross-section.
- the stop 29 is of annular design, so that a screw cap inserted into the recess 5 or into the closing cone 7 only comes into contact with the stop 29 with its closed end side in regions, namely in a ring shape.
- the stop extends annularly over the entire circumference of the recess 9, so that a planar system is created for the screw cap.
- the stop 29 could be formed by a plurality of distributed over the circumference, in particular distributed uniformly over the circumference arranged projections.
- the stopper 29 as (stationary) fixed stop 29 - in relation to the closing head 1 -.
- the stop 29 is mounted axially movable in the direction of the central axis.
- the stopper 29 can not only be adapted to different heights of the screw caps and used to limit the penetration of the screw cap in the Verschonnekonus 7, but also for expelling a screw cap from the Versch pertainkonus 7 and from the recess 5.
- the movable stop works like an ejector or plunger, for which purpose at least one actuator may be provided on the capping head 1, which is operatively connected to the ejection of a screw cap with the movable stop.
- the closing head 1 shown in FIG. 2 corresponds to the closing head 1 shown in FIG. 1, so that already known elements are provided with the same reference numerals, and to that extent reference is made to the above description.
- Figures 1 and 2 each show a screw cap 31 (Figure 1) and 33 ( Figure 2), which belong to a SSverBankfamilie.
- the screw caps 31, 33 of the screw cap family have in common that they have on their outer shell surface 37 a corrugation 39 with the same number of teeth 41 and 43 respectively.
- the teeth 41 of the screw cap 31 have substantially the same height when viewed in their longitudinal extension, the height of the teeth 43 of the screw cap 33 decreases in the direction of the closed end side of the screw cap 33.
- the teeth 43 According to FIG. 2, in the state introduced into the closing cone 7 in the region of the closing cone 7, the teeth 43 have an at least substantially wedge-shaped longitudinal section.
- the neutras of the teeth 43 substantially corresponds to the tip circle radius of the teeth 11 of the tooth profile 9 of the capping head 1.
- the neutr Vietnameseradius the teeth 41 of the screw cap 31 is smaller.
- the tip radius of the teeth 41 and 11 and 43 and 11 overlap. It is important that the maximum root radius of the teeth 11 is greater than the maximum tip radius of the ridges 39, so that the latter is not damaged, at least not visible.
- the maximum tort Vietnamese malmesser is advantageously chosen depending on the material of a screw-on screw of a family to take into account different expansion behavior of the screw when screwing.
- the closing head 1 is inserted into the screw cap 31 or 33 or the screw cap 31 or 33 into the capping head 1. Initially, the rotational position of the respective screw cap 31, 33 with respect to the capping head 1 is ensured by means of the alignment device 21 as described above. Upon further insertion of the respective screw cap 31, 33 in the recess 5, the respective corrugation 39 and the tooth profile 9 come into operative contact. The respective screw cap 31, 33 is inserted up to the stop 29.
- the screw caps 31, 33 are characterized by different sizes.
- the smaller screw cap 31 is the smallest screw cap (Min screw cap) and the larger screw cap 33 is the largest Screw closure (max screw) of SSverBankfamilie, whereby, as seen from Figures 1 and 2, the tooth tips of the teeth 11 abut the raw Vietnameseradius the screw 33, while the tooth tips of the teeth 43 are at a distance to the predominantly Vietnamese Vietnameseradius of the teeth 11.
- the tips of the teeth 39 are thus protected from damage.
- the teeth 41 of the screw cap 31 overlap, however, only over a small area with the teeth 11 of the closing cone 7. About the case tangentially formed contact surfaces, a torque of the capping head 1 on the screw cap 31 and 33 can be securely transmitted.
- the capping head 1 can thus be used for several different screw caps of a fferverBankfamilie. This simplifies the automatic / mechanical screwing of screw caps on containers, especially bottles, significantly. In addition, with the capping head 1, screwing Bolt closures whose visual impression is important, such as screw caps of cosmetic products, since damage to the corrugation is prevented.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Sealing Of Jars (AREA)
- Closures For Containers (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009042147A DE102009042147A1 (de) | 2009-09-14 | 2009-09-14 | Verschließkopf zum Aufschrauben von Schraubverschlüssen |
PCT/EP2010/005590 WO2011029616A2 (fr) | 2009-09-14 | 2010-09-13 | Tête de fermeture pour visser des bouchons à vis |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2477933A2 true EP2477933A2 (fr) | 2012-07-25 |
EP2477933B1 EP2477933B1 (fr) | 2013-09-04 |
Family
ID=43305014
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10760914.1A Not-in-force EP2477933B1 (fr) | 2009-09-14 | 2010-09-13 | Tête de fermeture pour visser des bouchons à vis |
Country Status (11)
Country | Link |
---|---|
US (1) | US9221663B2 (fr) |
EP (1) | EP2477933B1 (fr) |
JP (1) | JP2013504493A (fr) |
KR (1) | KR20120065366A (fr) |
BR (1) | BR112012005728A2 (fr) |
CA (1) | CA2774011A1 (fr) |
DE (1) | DE102009042147A1 (fr) |
ES (1) | ES2437747T3 (fr) |
MX (1) | MX2012003074A (fr) |
RU (1) | RU2538923C2 (fr) |
WO (1) | WO2011029616A2 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102011003074A1 (de) * | 2011-01-24 | 2012-07-26 | Bericap Gmbh & Co. Kg | Vorrichtung und Verfahren zum Verschließen von Behältern mit Schraubkappe |
FR3021964B1 (fr) * | 2014-06-04 | 2016-05-27 | S A Etablissements Andre Zalkin & Cie | Tete de pose de fermetures de flacon a lamelles elastiques |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1208529A (en) * | 1915-01-27 | 1916-12-12 | Automatic Weighing Machine Company | Machine for securing metallic screw-caps to bottles, jars, and the like. |
US1249025A (en) * | 1915-11-27 | 1917-12-04 | Leslie R N Carvalho | Bottle-capping machine. |
US1707201A (en) * | 1924-12-13 | 1929-03-26 | Everedy Company | Bottle-capping tool |
GB946153A (en) * | 1961-07-27 | 1964-01-08 | Wilfred Layland | Appliances for removing closure members from bottles and similar containers |
US3906706A (en) * | 1973-12-13 | 1975-09-23 | Dairy Cap Corp | Cap-tightener |
US3984965A (en) * | 1974-09-19 | 1976-10-12 | Harry Crisci | Device for applying caps to bottles |
JPS521449U (fr) * | 1975-06-21 | 1977-01-07 | ||
US4364218A (en) * | 1979-04-25 | 1982-12-21 | Albert Obrist Ag | Closure apparatus incorporating a magnetic clutch for screwing-on a plastic screw closure |
US5054261A (en) * | 1990-09-26 | 1991-10-08 | Gilbertson Donald J | Cap chucks for use with bottle capping machines |
DE69126782T2 (de) * | 1991-10-08 | 1998-03-12 | Mauro Lenzi | Vorrichtung zum drehmomentbegrenzenden Aufschrauben von mit Aussenkehlungen versehenen Drehverschlusskappen auf Behältnissen |
DE19540545C2 (de) | 1995-10-31 | 1998-05-14 | Kronseder Maschf Krones | Verfahren und Vorrichtung zum optischen Überprüfen des Sitzes von Verschlußkappen auf Gefäßen |
JP3283755B2 (ja) * | 1996-04-12 | 2002-05-20 | ハウス食品株式会社 | キャップ締付装置 |
JPH11124196A (ja) | 1997-10-22 | 1999-05-11 | Kao Corp | ねじの締付方法及び装置 |
US6105343A (en) | 1998-11-06 | 2000-08-22 | Pneumatic Scale Corporation | Apparatus and method for a capping machine |
JP4369567B2 (ja) * | 1999-10-05 | 2009-11-25 | 日本クラウンコルク株式会社 | 蓋締装置のチャック |
JP4232311B2 (ja) | 2000-03-06 | 2009-03-04 | 澁谷工業株式会社 | キャッピング方法とキャッピング装置 |
DE10232846A1 (de) * | 2002-07-19 | 2004-02-12 | Alcoa Deutschland Gmbh Verpackungswerke | Verschliesskonus |
US7882682B2 (en) * | 2006-10-20 | 2011-02-08 | Wendell Martin | Ball grip and friction engaging capping chuck |
JP5002326B2 (ja) * | 2007-05-08 | 2012-08-15 | 株式会社Csiジャパン | キャップ装着装置のキャッピングヘッドセット |
DE102007028429A1 (de) | 2007-06-20 | 2008-12-24 | Krones Ag | Vorrichtung zum Verschließen von Behältern mit Schraubverschlüssen |
WO2009089023A1 (fr) | 2008-01-11 | 2009-07-16 | Parata Systems, Llc | Dispositifs et procédés de vérification du capsulage de flacons dans un système de distribution de prescriptions |
-
2009
- 2009-09-14 DE DE102009042147A patent/DE102009042147A1/de not_active Withdrawn
-
2010
- 2010-09-13 US US13/394,363 patent/US9221663B2/en not_active Expired - Fee Related
- 2010-09-13 WO PCT/EP2010/005590 patent/WO2011029616A2/fr active Application Filing
- 2010-09-13 BR BR112012005728A patent/BR112012005728A2/pt not_active Application Discontinuation
- 2010-09-13 JP JP2012528279A patent/JP2013504493A/ja active Pending
- 2010-09-13 KR KR1020127007383A patent/KR20120065366A/ko not_active Application Discontinuation
- 2010-09-13 ES ES10760914.1T patent/ES2437747T3/es active Active
- 2010-09-13 MX MX2012003074A patent/MX2012003074A/es active IP Right Grant
- 2010-09-13 CA CA2774011A patent/CA2774011A1/fr not_active Abandoned
- 2010-09-13 RU RU2012114880/12A patent/RU2538923C2/ru not_active IP Right Cessation
- 2010-09-13 EP EP10760914.1A patent/EP2477933B1/fr not_active Not-in-force
Non-Patent Citations (1)
Title |
---|
See references of WO2011029616A2 * |
Also Published As
Publication number | Publication date |
---|---|
WO2011029616A2 (fr) | 2011-03-17 |
MX2012003074A (es) | 2012-06-27 |
WO2011029616A3 (fr) | 2012-01-26 |
ES2437747T3 (es) | 2014-01-14 |
DE102009042147A1 (de) | 2011-03-24 |
BR112012005728A2 (pt) | 2016-02-23 |
KR20120065366A (ko) | 2012-06-20 |
EP2477933B1 (fr) | 2013-09-04 |
US9221663B2 (en) | 2015-12-29 |
JP2013504493A (ja) | 2013-02-07 |
RU2012114880A (ru) | 2013-10-27 |
RU2538923C2 (ru) | 2015-01-10 |
US20120159902A1 (en) | 2012-06-28 |
CA2774011A1 (fr) | 2011-03-17 |
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