EP2450118A1 - Procédé destiné à la fabrication d'un tuyau - Google Patents

Procédé destiné à la fabrication d'un tuyau Download PDF

Info

Publication number
EP2450118A1
EP2450118A1 EP10196606A EP10196606A EP2450118A1 EP 2450118 A1 EP2450118 A1 EP 2450118A1 EP 10196606 A EP10196606 A EP 10196606A EP 10196606 A EP10196606 A EP 10196606A EP 2450118 A1 EP2450118 A1 EP 2450118A1
Authority
EP
European Patent Office
Prior art keywords
carrier element
coating material
layer
coating
angle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP10196606A
Other languages
German (de)
English (en)
Other versions
EP2450118B1 (fr
Inventor
Erik Bähr
Peter Heinrich
Helmut Höll
Peter Sen. Richter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Linde GmbH
Original Assignee
Linde GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linde GmbH filed Critical Linde GmbH
Publication of EP2450118A1 publication Critical patent/EP2450118A1/fr
Application granted granted Critical
Publication of EP2450118B1 publication Critical patent/EP2450118B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/06Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D23/00Casting processes not provided for in groups B22D1/00 - B22D21/00
    • B22D23/003Moulding by spraying metal on a surface
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/02Coating starting from inorganic powder by application of pressure only
    • C23C24/04Impact or kinetic deposition of particles

Definitions

  • the present invention relates to a method for producing a tube, wherein a carrier element is coated by means of a thermal spraying method and the material of the later formed tube is selected as coating material, and wherein subsequently the coating forming the tube is released from the carrier element.
  • a block or billet of, for example, steel cylinders is first formed into a billet, a short and thick-walled tube. This billet is then further processed in a subsequent process step by, for example, the pilgering process or the cross rolling to a tube of thinner diameter.
  • seamless tubes have also been produced by various thermal spraying techniques.
  • a powder coating material is introduced into a heated process gas jet.
  • the powder particles melt or on.
  • the process gas is sprayed onto a carrier element, so that a layer is formed on the carrier element.
  • the layer must fulfill two requirements. For one thing, the layer should adhere to the carrier element during the process. Because only in this way can a pipe be made with fixed specifications.
  • the coating material or later the finished tube can be as easily as possible detached from the carrier element in order to avoid subsequent damage to the tube.
  • seamless tubes are produced by means of a cold spraying process and then the finished tube is released from the carrier element by cooling or heating the tube and / or the carrier element or, alternatively, the carrier element is melted, vaporized or broken.
  • the material of the coating material and the carrier element there is a high or low adhesion between the coating material and the carrier element.
  • Low adhesion in turn means that the coating material is minimally or not at all adhered to the carrier element during the injection process, but is very easy to detach from the carrier element after completion. This in turn can cause complications during the application of the layer to the support member.
  • a thermal spraying process is used for producing a pipe, in particular a seamless pipe, by means of which a high adhesive tensile strength is provided.
  • the adhesive tensile strength results from the relationship between adhesion and layer properties. While the layer properties are largely due to the materials of coating material and carrier element as well as to the gas and the temperature used for this purpose, the adhesion properties are adaptable or adjustable according to the invention via the spray angle.
  • the spray angle is selected in the inventive method so that adhesion is sufficient, so that the coating material adheres to the carrier element, and at the same time is so low that the tube after completion without the use of costly process steps can be easily solved by the support element.
  • the process gas is sprayed in the solder onto the carrier element, so that maximum adhesion forms between the coating material and the carrier element.
  • the process gas is sprayed parallel to the carrier element. This creates no contact and thus no adhesion between the coating material and the carrier element.
  • An injection angle, which causes sufficient adhesion between the coating material and the carrier element, is therefore between more than 0 ° and 90 °.
  • the above considerations apply analogously to the angular range of 90 ° to 180 ° (spraying from the "other side"). In the following, for the sake of simplicity, reference will only be made to the acute angle range (0 ° to 90 °).
  • a flange-like layer is applied at an angle of 90 ° to the carrier element, so that, due to a specific layer thickness, an edge of the layer directed towards the carrier element is formed.
  • the jet of the process gas is aligned with the spray device so that the angle to the flank of the layer is about 90 °. In this angular position, the sprayer then remains until the completion of the coating, so that a uniform dense and non-porous layer with low adhesion at the same time.
  • a hollow mandrel is selected as the carrier element, the outer surface of which is coatable with the coating material.
  • the tube gets its shape.
  • the corresponding diameter of the pipe can be selected.
  • the coating material must be released from the carrier element. This is preferably done by introducing a coolant into the hollow mandrel so that the entire inner surface of the mandrel is cooled.
  • the coolant may be carbon dioxide (CO 2 ) or nitrogen (N 2 ), in particular in the liquid state.
  • the introduction of the coolant leads to a shock-like shrinking process of the mandrel, wherein the mandrel changes in size, so that the coating material dissolves from the mandrel, without this being damaged. After the mandrel returns to ambient temperature, it expands to its initial size and can be used for the next manufacturing process.
  • a cold gas spraying process is preferably used.
  • the method is characterized in that the powder particles of the coating material are not heated to the melting temperature, but are sprayed onto the carrier element with high pressure (temperature approx. 600 ° C, particle velocity> 1000m / s). Layers of extreme adhesion strengths can be produced which are extremely dense and nonporous. Due to the relatively low temperature compared to other thermal spray processes, the spray material is thermally influenced little and much less oxidized. Also, the coated substrate shows no material change due to heat. Methods of cold gas spraying are also in the patent WO 2009/109016 described.
  • the cold gas spraying process allows the use of titanium as a coating material.
  • the corrosion- and temperature-resistant titanium is heated only to the extent that it can be applied to the carrier element by means of the cold gas spraying method, without losing its strength properties. At higher temperatures, the titanium would become brittle quickly.
  • support element preferably aluminum is used.
  • Aluminum is a highly corrosion-resistant element that is easy to mold at low temperatures. Upon introduction of coolant into the hollow mandrel, which in the preferred embodiment is aluminum, the mandrel shrinks, thereby releasing the coating material from the mandrel.
  • a preferred embodiment of the spray system is designed so that move during the coating process, the carrier element and the spray device relative to each other, in particular parallel to the surface of the carrier material. There is a movement of Spray device and carrier element with different speeds in the same direction as well conceivable, as an opposite direction of the carrier element and spray device. Likewise, it is provided that either only the carrier element or only the spray device move in one direction.
  • FIG. 1 shows the carrier element 1 in the form of a hollow mandrel, the spray device 2, the flange-like layer 3, the process gas jet 4 and the coating 5 consisting of the coating material.
  • the position A of the spray device 2 serves to apply the flange-like layer 3 to the carrier element 1, wherein the process gas jet 4 strikes the carrier element 1 at an angle of 90 ° 6b.
  • Carrier element 1 and spray device 2 do not move in this case in the axial direction of the mandrel to each other.
  • the process gas jet 4 with the powdery coating material located therein is directed perpendicular to the carrier element 1, so that the flange-like layer 3 with a certain height, preferably 0.5 to 20 mm, is formed.
  • the finished tube is then about as thick as the flange.
  • the position of the spray device 2 changes. This is illustrated by an intermediate position B.
  • the exact position C of the spray device 2 is selected.
  • the process gas jet 4 is aligned by means of the spray device 2 in the solder 6a to the flank 9 of the flange-like layer 3.
  • the angle 6a between propagation direction of the process gas jet 4 and flank 9 of the flange-like layer 3 is substantially 90 °, wherein a possible deviation from the solder should not be more than +/- 10 °.
  • flank angle 7 and the spray angle 8 In addition to the 90 ° angle 6a, there are two more angles that are important.
  • a flank angle 7 is formed between the flank 9 and the carrier element 1. This angle describes the angle at which the flank 9 of the flange-like layer 3 faces the carrier element 1.
  • a uniform layer 5 of the coating material is sprayed onto the carrier element 1, the coating 5 having optimum layer properties with low adhesion.
  • FIG. 2 shows the sequential process steps of the invention
  • the image 1 is only an example of a spray angle 8 of 0 ° show and thus is not to be regarded as a process step.
  • the inventive method begins with Figure 2.
  • Figure 2 first, the flange-like layer 3 is sprayed onto the carrier element 1, wherein the spray device 2 is aligned at 90 ° angle 6b to the support element 1.
  • the spray device 2 is changed in its position so that the process gas jet 4 is at 90 ° angle 6a to the flank 9 of the flange layer 3.
  • the spray device 2 moves in image 3, for example, in the axial direction of the mandrel and parallel to the surface of the support member 1, while the mandrel 1 rotates about its longitudinal axis to form the tube circumference.
  • Figure 4 the approach of a coating 5 of the coating material on the support element 1 can be seen.
  • Figure 8 shows the separation process between tube 10 and mandrel at an advanced stage. After the tube 10 has been completely detached from the carrier element 1 or the mandrel, the finished tube 10 with a predetermined diameter of the selected material, in particular titanium, with the desired layer thickness and the corresponding optimum layer properties.
  • the selected material in particular titanium

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Chemical Vapour Deposition (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
EP10196606.7A 2010-11-04 2010-12-22 Procédé destiné à la fabrication d'un tuyau Not-in-force EP2450118B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102010060362A DE102010060362A1 (de) 2010-11-04 2010-11-04 Verfahren zum Herstellen eines Rohres

Publications (2)

Publication Number Publication Date
EP2450118A1 true EP2450118A1 (fr) 2012-05-09
EP2450118B1 EP2450118B1 (fr) 2013-07-24

Family

ID=43807002

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10196606.7A Not-in-force EP2450118B1 (fr) 2010-11-04 2010-12-22 Procédé destiné à la fabrication d'un tuyau

Country Status (4)

Country Link
US (1) US8316916B2 (fr)
EP (1) EP2450118B1 (fr)
AU (1) AU2011244959B2 (fr)
DE (1) DE102010060362A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2925904A4 (fr) * 2012-12-03 2016-08-17 Future Titanium Technology Pty Ltd Procédé de formation de tuyau sans soudure en titane et/ou alliages de titane

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5365723B2 (ja) * 2012-04-24 2013-12-11 新日鐵住金株式会社 穿孔圧延用プラグの製造方法
DE102013216439A1 (de) 2013-05-22 2014-11-27 Siemens Aktiengesellschaft Verfahren zum Erzeugen eines schalenförmigen Bauteils sowie zur Anwendung dieses Verfahrens geeignete Herstellungsanlage
DE102014206073A1 (de) 2014-03-31 2015-10-01 Siemens Aktiengesellschaft Verfahren zum Herstellen eines Hohlkörpers mittels Kaltgasspritzen und zur Durchführung dieses Verfahrens geeigneter Formkern
DE102018120291B3 (de) 2018-08-21 2020-01-02 Sascha Larch Verfahren zur Herstellung eines einen Leichtbau-Drucktank bildenden Leichtbau-Druckbehälters und Leichtbau-Druckbehälter
EP3841323B1 (fr) 2018-08-21 2023-10-04 LARCH, Sascha Procédé de fabrication d'un récipient léger sous pression formant un réservoir léger sous pression et récipient léger sous pression
US20230278099A1 (en) * 2022-03-04 2023-09-07 Goodrich Corporation Systems and methods for manufacturing landing gear components using titanium

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1599392A (en) * 1978-05-31 1981-09-30 Osprey Metals Ltd Method and apparatus for producing workable spray deposits
DE3617833C1 (de) * 1986-05-27 1987-09-03 Mannesmann Ag Verfahren zum Herstellen von rotationssymmetrischen Hohlkoerpern
US5401539A (en) * 1985-11-12 1995-03-28 Osprey Metals Limited Production of metal spray deposits
WO2008049460A1 (fr) * 2006-10-24 2008-05-02 Siemens Aktiengesellschaft PROCÉDÉ POUR RÉGLER LA RUGOSITÉ de surface LORS D'UNE OPÉRATION DE REVÊTEMENT À BASSE TEMPÉRATURE, ET ÉLÉMENT DE CONSTRUCTION
WO2009109016A1 (fr) 2008-03-06 2009-09-11 Commonwealth Scientific And Industrial Research Organisation Fabrication de tuyaux

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5983495A (en) * 1997-12-29 1999-11-16 Ford Global Technologies, Inc. Method of making spray-formed inserts

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1599392A (en) * 1978-05-31 1981-09-30 Osprey Metals Ltd Method and apparatus for producing workable spray deposits
US5401539A (en) * 1985-11-12 1995-03-28 Osprey Metals Limited Production of metal spray deposits
DE3617833C1 (de) * 1986-05-27 1987-09-03 Mannesmann Ag Verfahren zum Herstellen von rotationssymmetrischen Hohlkoerpern
WO2008049460A1 (fr) * 2006-10-24 2008-05-02 Siemens Aktiengesellschaft PROCÉDÉ POUR RÉGLER LA RUGOSITÉ de surface LORS D'UNE OPÉRATION DE REVÊTEMENT À BASSE TEMPÉRATURE, ET ÉLÉMENT DE CONSTRUCTION
WO2009109016A1 (fr) 2008-03-06 2009-09-11 Commonwealth Scientific And Industrial Research Organisation Fabrication de tuyaux

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2925904A4 (fr) * 2012-12-03 2016-08-17 Future Titanium Technology Pty Ltd Procédé de formation de tuyau sans soudure en titane et/ou alliages de titane
AU2013354884B2 (en) * 2012-12-03 2018-03-08 Commonwealth Scientific And Industrial Research Organisation Method of forming seamless pipe of titanium and/or titanium alloys

Also Published As

Publication number Publication date
EP2450118B1 (fr) 2013-07-24
AU2011244959A1 (en) 2012-05-24
AU2011244959B2 (en) 2013-11-28
US8316916B2 (en) 2012-11-27
US20120273152A1 (en) 2012-11-01
DE102010060362A1 (de) 2012-05-10

Similar Documents

Publication Publication Date Title
EP2450118B1 (fr) Procédé destiné à la fabrication d'un tuyau
DE3247510A1 (de) Verfahren zum ummanteln von stabfoermigen metallischen formkoerpern mit thermoplastischem kunststoff
WO2020038929A1 (fr) Procédé pour produire un corps à enveloppe tubulaire légère et corps à enveloppe tubulaire légère
EP2062997A2 (fr) Procédé destiné à revêtir des composants
EP2602032A1 (fr) Procédé de fabrication d'un tube métallique multicouche et tube métallique multicouche ainsi fabriqué
EP2024654B1 (fr) Procédé de fabrication d'un composant de palier à roulement
EP3381593B1 (fr) Procédé de fusion ou de frittage sélectifs par faisceau
DE102012013750A1 (de) Verfahren zum Verbinden von zwei Bauteilen
DE2519046C3 (de) Verfahren zum Aufbringen einer Schicht aus Polyäthylen auf ein Stahlrohr
EP3259378A1 (fr) Procédé de fabrication d'une barre d'acier fin et barre d'acier fin
EP2714963B1 (fr) Procédé d'injection de gaz froid présentant une meilleure adhérence et une porosité de couche réduite
DE102014222526A1 (de) Verfahren und Vorrichtung zum generativen Herstellen zumindest eines Bauteilbereichs eines Bauteils
EP3110567B1 (fr) Ensemble de gros tuyaux et procédé de production d'un ensemble de gros tuyaux de ce type
DE10202212B4 (de) Verfahren zum Erzeugen von aus metallischem Verbundwerkstoff bestehendem Band oder Blech
EP1506816B1 (fr) Buse de Laval pour la pulvérisation thermique et cinétique
DE4240246C2 (de) Verfahren zur Herstellung eines dickwandigen Rohres geringen Durchmessers
EP2503026A1 (fr) Procédé de réparation d'une couche sur un substrat
DE2338431A1 (de) Ueberzugsverfahren
EP2165778A1 (fr) Procédé de fabrication, extrudeuse et matrice pour un profil creux extrudé et profil creux extrudé et échangeur de chaleur doté d'un profil creux extrudé
EP3025805A2 (fr) Procede de fabrication d'une structure de corps d'un missile et dispositif d'une structure de missile
DE3447557C2 (de) Vorrichtung zur Herstellung eines Hohlzylinders durch Zerstäuben einer Metallschmelze mittels Gaszerstäubung, sowie ein solcher Hohlzylinder
DE102015209660B4 (de) Verfahren zur Herstellung eines Blechumformteils
EP1466674A2 (fr) Procédé et dispositif pour la fabrication d'un tube à partir d'un materiau métallique
DE102015111096B4 (de) Verfahren zur Herstellung eines nahtlosen, mehrlagigen Rohrproduktes
DE102013020587A1 (de) Verfahren zur Herstellung von nachträglich ausgebildeten partiellen Wandstärkenreduzierungen an Halbzeugen mit Hohlraumausbildung

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

17P Request for examination filed

Effective date: 20121023

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RIC1 Information provided on ipc code assigned before grant

Ipc: B22D 23/00 20060101ALI20121214BHEP

Ipc: C23C 24/04 20060101ALI20121214BHEP

Ipc: B21C 37/06 20060101AFI20121214BHEP

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20130527

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 623091

Country of ref document: AT

Kind code of ref document: T

Effective date: 20130815

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502010004116

Country of ref document: DE

Effective date: 20130919

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20130724

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130821

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131024

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131125

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131124

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131025

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

BERE Be: lapsed

Owner name: LINDE A.G.

Effective date: 20131231

26N No opposition filed

Effective date: 20140425

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502010004116

Country of ref document: DE

Effective date: 20140425

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131222

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131231

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131222

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20141212

Year of fee payment: 5

Ref country code: DE

Payment date: 20141216

Year of fee payment: 5

Ref country code: GB

Payment date: 20141217

Year of fee payment: 5

Ref country code: SE

Payment date: 20141211

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20141208

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20141211

Year of fee payment: 5

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20101222

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131024

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 502010004116

Country of ref document: DE

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: SE

Ref legal event code: EUG

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20151222

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151223

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20160831

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160701

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151222

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151231

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151231

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151231

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151222

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 623091

Country of ref document: AT

Kind code of ref document: T

Effective date: 20151222

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151222

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724