EP2388309B2 - Pastilles de détergent dotées de plus de quatre surfaces latérales - Google Patents
Pastilles de détergent dotées de plus de quatre surfaces latérales Download PDFInfo
- Publication number
- EP2388309B2 EP2388309B2 EP10005125.9A EP10005125A EP2388309B2 EP 2388309 B2 EP2388309 B2 EP 2388309B2 EP 10005125 A EP10005125 A EP 10005125A EP 2388309 B2 EP2388309 B2 EP 2388309B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- detergent
- tablet
- tablets
- composition
- side surfaces
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003599 detergent Substances 0.000 title claims description 46
- 239000000203 mixture Substances 0.000 claims description 29
- 238000004851 dishwashing Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 5
- 238000003825 pressing Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000012858 packaging process Methods 0.000 claims description 3
- 238000010412 laundry washing Methods 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 238000005245 sintering Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 238000004061 bleaching Methods 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 239000003826 tablet Substances 0.000 description 94
- 238000004806 packaging method and process Methods 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 230000003247 decreasing effect Effects 0.000 description 5
- 239000000428 dust Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007942 layered tablet Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 235000019263 trisodium citrate Nutrition 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
Definitions
- the present invention refers to detergent tablets in form of pressed bodies having an upper and a lower surface and more than four side surfaces, wherein the tablet has 8 or 10 edges of equal angles and 8 or 10 side surfaces of the same length, wherein the side surfaces have equal length and the edges have equal angles, accordingly, the tablet is in the form of a symmetrical polygon.
- Detergent tablets like e.g. automatic dishwashing detergent tablets or laundry detergent tablets in Europe commonly are provided in form of bars or pressed bodies having an upper and a lower surface, four 90° angles and two longer and two shorter sides. Accordingly, considered in an onview they have a rectangular form wherein dimensions of about 34 mm length and about 25 mm width are usual. Said form fits perfectly in the applied dosing chambers of automatic dishwashing machines or laundry machines in the European market.
- the object of the present invention was to provide stable detergent tablets providing a unit dose of a modern detergent which are easy to handle during preparation, transport and packaging process.
- a detergent tablet having an upper and a lower surface and 8 to 10 edges of equal angles and 8 or 10 side surfaces of the same length, wherein the side surfaces have equal length and the edges have equal angles, accordingly, the tablet is in the form of a symmetrical polygon.
- the contact points or contact areas are meant connecting the side surfaces of the tablets to each other.
- the upper and the lower surface of the tablet are parallel to each other wherein the angels connecting them to the side surfaces are essentially 90° (upper or lower surface to the side surfaces), whereas the side surfaces are connected to each other by equal angels, wherein the side surfaces all have the same length.
- the tablet is in the form of a symmetrical polygon.
- the tablet has 8 or 10 edges of equal angels and 8 or 10 side surfaces of the same length. Most preferred the tablet has 8 edges and 8 side surfaces of the same length resulting in an octagon (onview).
- Rectangular tablets having less width than commonly used up to now result in a lower stability are difficult to steer or arrange during the processing, e.g. on a transport belt and during a wrapping process. Accordingly the speed of preparation, transport, optionally wrapping and packaging has significantly decreased to obtain not too much degraded material. Besides these aspects also the flow wrappers need significant modifications if the width of the tablets is decreased noticeable.
- Tablets having a decreased length without modifying the width show the tendency to turn during the transport to the wrapping angles or packaging station. Accordingly blockages occur and the edges of the tablets can break. This results in a high dust charge. Furthermore it becomes difficult to steer or arrange the tablets for further processing e.g. for the wrapping or packaging process.
- Round tablets having a diameter of about 25 mm have shown to eliminate the problems of breaking edges of the tablets and of steering / arranging the tablets during the transport on the conveyor belts for further processing.
- the round tablets showed the tendency to spin on the conveyor belt, activated by the steering rails on the side of said belts. The spinning causes significant abrasion of the tablets, resulting in an undesired dust formation. This might be overcome e.g. by a protecting coating on the tablets, however, this decreases the production speed and increases the preparation costs.
- the detergent tablets of the present invention can be prepared from any known detergent compositions providing e.g. automatic dishwashing compositions, laundry detergent compositions, beaching compositions, water softening compositions or stain remover compositions.
- composition serving as a basis for the detergent tablets of the present invention is not limiting the invention, since it is not essential which type of detergent composition is representing the tablet. Any detergent composition which can be provided in form of a tablet can be used according to the invention.
- Tablets of the present invention representing automatic dishwashing tablets preferably have a width of about 18 to 34 mm, preferably of about 20 to 32 mm, more preferably of about 22 to 30 mm and most preferred of about 24 to 28 mm. Since all side surfaces have the same length the tablet has a "diameter" (width between two parallel side surfaces) as mentioned before.
- Such automatic dishwashing tablets have a decreased weight compared to the up to now commonly used dishwashing tablets, preferably a weight between 8 and 20 g, more preferred between 9 and 18 g and most preferred between 10 and 16 g.
- Tablets of the present invention representing laundry detergent tablets preferably have a width of about 30 to 70 mm, preferably of about 35 to 55 mm and most preferred of about 40 to 50 mm. In the preferred case where all side surfaces have the same length the tablet has a "diameter" (width between two parallel sides) as mentioned before.
- Laundry detergent tablets preferably have a weight of 15 to 70 g, preferably 20 to 50 g and most preferred of about 25 to 45 g.
- the present form of the tablets results in stable tablets which are easy to process and to handle.
- the present tablets have less tendency to break and can be placed in the dosing chambers of any common dishwashing and laundry machine.
- the tablets, particularly automatic dishwashing tablets, of the present invention can be wrapped by any film, foil or paper, as presently known in the art. Due to their essentially unchanged width and thickness compared to up to now commonly produced tablets the wrapping equipment and wrapping machines don't have to be changed significantly.
- the tablets of the present invention can be coated with any of the known coating compositions for detergent tablets.
- coating compositions are extensively described in the state of the art. Which type of such coatings is used is not limiting the invention.
- Preparation of the tablets can be carried out by pressing a particulate detergent composition e.g. in a mould, by sintering a detergent composition, by melting and solidifying a detergent composition or by a mixture of said methods or by any other process known for preparing detergent tablets.
- the preparation process is not limiting the invention as long as a tablet is obtained having the properties as described above and claimed.
- the tablets can represent a unit dose for automatic dishwashing, for laundry washing of for any other desired use, wherein the tablet can consist of one continuous phase or of several phases like different tablet parts, preferably different layers, an inlay, an additional part attached on at least one of the surfaces or a filled cavity. If the tablet comprises different phases it is preferred that these phases differ in their composition, e.g. providing different detergent ingredients at different time periods during the wash cycles of an automatic dishwashing machine.
- the tablet can comprise one, two, three, four, five or more different phases, preferably one, two or three. Examples for such tablets are multilayer tablets, tablets providing a cavity which is filled with a liquid, particulate or solid additive, tablets with a non-compressed portion on at least one of their upper or lower surfaces and tablets including an inlay.
- the present invention provides a detergent tablet which can be prepared from any known detergent composition using any of the commonly used preparation equipment and machines, which due to the modern raw materials has less weight and accordingly different dimensions compared to rectangular tablets used up to know, showing high stability during preparation process. Accordingly a smaller tablet can be prepared without significant changes in any equipment or machines which due to its form is stable, easy to handle, to process, optionally to wrap and to package.
- the tablets of the present invention are particularly suitable in a process for wrapping, packaging or coating said tablets.
- they are suitable for wrapping on a flow wrapping machine, automatic packaging and/ or automatic coating by suitable machines, since they are easily to process automatically without breakage and without significant abrasion during said automatic processing. Due to their behavior to essentially arrange themselves on a conveyor belt they are particularly suitable in any process including transport on such a belt.
- the figures show one particularly preferred embodiment of the present invention, a tablet having 8 edges of the same angle and 8 sides of the same length.
- the tablet is shown as a two-layered tablet, however, this should not limit the octagonal embodiment in any way.
- Detergent tablets were prepared by pressing 15 g of an automatic dishwashing detergent composition commonly used for tablets in an according mould.
- the detergent powder was dosed in the according mould, the according punch provided a pressure on the powder of 50 ⁇ 10 3 Newton during maximal 1 second.
- the tablets were processed according to commonly used tablets, i.e. transported on a conveyor belt to a flow wrapper and/or to a packaging station.
- Table 1 Example compressability behavior on conveyor belt breakage abrasion/dust charge A good arranged in line high middle B good arranged in line high middle C good turns up to 45° at the edges high D good spins low high E good arranged correctly low low low F good arranged correctly low low low G good arranged correctly low low Table 2
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Claims (8)
- Pastille de détergent présentant une surface supérieure, une surface inférieure et plus de 4 surfaces latérales sur plus de 4 côtés, laquelle pastille présente 8 ou 10 côtés formant des angles égaux et 8 ou 10 surfaces latérales, dans laquelle les surfaces latérales sont de même longueur et les côtés forment des angles égaux, moyennant quoi cette pastille se présente de préférence sous la forme d'un polygone régulier.
- Pastille de détergent selon revendication 1, qui présente 8 côtés et 8 surfaces latérales de même longueur, formant ainsi un octogone.
- Pastille de détergent selon l'une quelconque des revendications 1 à 2, qui est ensachée.
- Pastille de détergent selon l'une quelconque des revendications 1 à 3, dans laquelle la composition détergente fournit une composition de lavage automatique de la vaisselle, une composition de lessive pour le linge, une composition de blanchiment, une composition d'adoucissement de l'eau ou une composition de détachage.
- Pastille de détergent selon l'une quelconque des revendications 1 à 4, dans laquelle la pastille est constituée par des parties différentes, de préférence des couches différentes, une incrustation, une partie supplémentaire attachée à au moins une des surfaces ou une cavité occupée.
- Procédé de préparation d'une pastille de détergent selon l'une quelconque des revendications 1 à 4 par compression d'une composition détergente particulaire dans un moule, par frittage d'une composition détergente, par fusion et solidification d'une composition détergente ou au moyen d'une combinaison desdites procédures.
- Utilisation d'une pastille de détergent selon l'une quelconque des revendications 1 à 4 pour le lavage automatique de la vaisselle, pour le lavage du linge ou pour le nettoyage de surfaces dures.
- Utilisation d'une pastille de détergent selon l'une quelconque des revendications 1 à 4 dans un procédé d'ensachage, d'emballage ou d'enrobage.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES10005125.9T ES2601906T3 (es) | 2010-05-17 | 2010-05-17 | Pastillas de detergente que tienen más de cuatro superficies laterales |
EP10005125.9A EP2388309B2 (fr) | 2010-05-17 | 2010-05-17 | Pastilles de détergent dotées de plus de quatre surfaces latérales |
PL10005125T PL2388309T3 (pl) | 2010-05-17 | 2010-05-17 | Detergentowe tabletki mające więcej niż cztery powierzchnie boczne |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10005125.9A EP2388309B2 (fr) | 2010-05-17 | 2010-05-17 | Pastilles de détergent dotées de plus de quatre surfaces latérales |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2388309A1 EP2388309A1 (fr) | 2011-11-23 |
EP2388309B1 EP2388309B1 (fr) | 2016-10-05 |
EP2388309B2 true EP2388309B2 (fr) | 2023-04-19 |
Family
ID=42262637
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10005125.9A Active EP2388309B2 (fr) | 2010-05-17 | 2010-05-17 | Pastilles de détergent dotées de plus de quatre surfaces latérales |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2388309B2 (fr) |
ES (1) | ES2601906T3 (fr) |
PL (1) | PL2388309T3 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102015218217A1 (de) * | 2015-09-22 | 2017-03-23 | Henkel Ag & Co. Kgaa | Blisterverpackung mit asymmetrischer Tablette sowie asymmetrische Tablette |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10064635A1 (de) † | 2000-12-22 | 2002-07-04 | Henkel Kgaa | Wasch-und Reinigungsmittelformkörper mit Partialcoating |
WO2006021284A1 (fr) † | 2004-08-20 | 2006-03-02 | Henkel Kommanditgesellschaft Auf Aktien | Corps moule detergent ou nettoyant pourvu d'un revetement |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3315950A1 (de) | 1983-05-02 | 1984-11-15 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur herstellung von reinigungsmitteltabletten |
US5316688A (en) * | 1991-05-14 | 1994-05-31 | Ecolab Inc. | Water soluble or dispersible film covered alkaline composition |
US6548473B1 (en) * | 1997-11-26 | 2003-04-15 | The Procter & Gamble Company | Multi-layer detergent tablet having both compressed and non-compressed portions |
GB2333778B (en) | 1998-01-29 | 2000-02-09 | Reckitt & Colman France | A lavatory block |
DE102004010281A1 (de) | 2004-03-03 | 2005-09-22 | Henkel Kgaa | Textilpflegemittelportion |
DE102005022786B4 (de) | 2005-05-12 | 2016-09-15 | Henkel Ag & Co. Kgaa | Wasch- oder Reinigungsmitteldosiereinheit |
-
2010
- 2010-05-17 EP EP10005125.9A patent/EP2388309B2/fr active Active
- 2010-05-17 PL PL10005125T patent/PL2388309T3/pl unknown
- 2010-05-17 ES ES10005125.9T patent/ES2601906T3/es active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10064635A1 (de) † | 2000-12-22 | 2002-07-04 | Henkel Kgaa | Wasch-und Reinigungsmittelformkörper mit Partialcoating |
WO2006021284A1 (fr) † | 2004-08-20 | 2006-03-02 | Henkel Kommanditgesellschaft Auf Aktien | Corps moule detergent ou nettoyant pourvu d'un revetement |
Also Published As
Publication number | Publication date |
---|---|
EP2388309B1 (fr) | 2016-10-05 |
PL2388309T3 (pl) | 2017-07-31 |
ES2601906T3 (es) | 2017-02-16 |
EP2388309A1 (fr) | 2011-11-23 |
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