EP2283527A1 - Strahlung emittierender dünnfilm-halbleiterchip und verfahren zur herstellung eines strahlung emittierenden dünnfilm-halbleiterchips - Google Patents
Strahlung emittierender dünnfilm-halbleiterchip und verfahren zur herstellung eines strahlung emittierenden dünnfilm-halbleiterchipsInfo
- Publication number
- EP2283527A1 EP2283527A1 EP09737722A EP09737722A EP2283527A1 EP 2283527 A1 EP2283527 A1 EP 2283527A1 EP 09737722 A EP09737722 A EP 09737722A EP 09737722 A EP09737722 A EP 09737722A EP 2283527 A1 EP2283527 A1 EP 2283527A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- region
- radiation
- active zone
- semiconductor chip
- active
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/81—Bodies
- H10H20/813—Bodies having a plurality of light-emitting regions, e.g. multi-junction LEDs or light-emitting devices having photoluminescent regions within the bodies
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H29/00—Integrated devices, or assemblies of multiple devices, comprising at least one light-emitting semiconductor element covered by group H10H20/00
- H10H29/10—Integrated devices comprising at least one light-emitting semiconductor component covered by group H10H20/00
- H10H29/14—Integrated devices comprising at least one light-emitting semiconductor component covered by group H10H20/00 comprising multiple light-emitting semiconductor components
Definitions
- a radiation-emitting thin-film semiconductor chip and a method for producing a radiation-emitting thin-film semiconductor chip are specified.
- the publication WO 2005/055379 describes a light-emitting semiconductor component which contains a semiconductor layer sequence with a region of p-doped semiconductor layers and n-doped semiconductor layers, between which a first pn junction is formed.
- the pn junction is divided laterally from an insulating section into a light emitting section and a protective diode section.
- an n-doped layer is applied on the p-doped region, which forms a second pn junction acting as a protective diode with the p-doped region.
- the first pn junction in the protection diode section must have a larger area than the first pn junction in the light emitting section.
- An object to be solved in the present case is to provide a structurally simple thin-film semiconductor chip - O _
- the radiation-emitting thin-film semiconductor chip comprises a first region having a first active zone, a second region laterally separated from the first region by a gap having a second active zone parallel to the first active zone in a different plane extends, and a compensation layer, which is in the second region at the level of the first active zone, wherein the compensation layer contains no semiconductor material.
- Lateral here means a direction that runs parallel to the planes in which the active zones extend.
- the compensation layer By means of the compensation layer, the height difference between the top of the second region and the top of the first region can be adjusted appropriately. In particular, the height difference can be compensated. For this purpose, no complex growth of a semiconductor layer is required. Instead, the compensation layer can be vapor-deposited or split by the use of a material that is different from a semiconductor material, for example. Preferably, the second active zone and the equalization layer directly adjoin one another.
- the two laterally separated regions can advantageously differ from one another with regard to their technical functions, so that advantageously the integration density-more functions on a smaller surface-can be increased in the component. Because in contrast to a conventional device having multiple chips for different functions, in the present case a single chip can be used for multiple functions.
- the thickness of the compensation layer corresponds to the thickness of the first active zone. Due to the compensation layer, the two regions on a first side of the thin-film semiconductor chip are at the same level. This has the advantage that the two areas can be arranged in a simple manner on a common planar support.
- the first region is a radiation-generating region, wherein the first active zone is provided for generating radiation of a first wavelength.
- the first wavelength is within the visible spectrum.
- The. active zone has a pn junction, which is formed in the simplest case of a p-type and an n-type semiconductor layer, which adjoin one another directly.
- the actual radiation-generating layer for instance in form of a doped or undoped quantum layer, is formed between the p-type and the 'n-type Halbleiter. Mrs.
- the quantum layer can be formed as single quantum well structure (SQW, single quantum well) or multiple quantum well structure (MQW, multiple quantum well) or else as quantum wire or quantum dot structure.
- the second region can also be a radiation-generating region, wherein the second active zone can be provided for generating radiation of a second wavelength.
- the second wavelength is also within the visible spectrum.
- the Surface can be illuminated differently colored, if the two areas are operated simultaneously.
- the occurring color contrast can be used, for example, to display symbols.
- the areas can be operated one after the other so that a first luminous color is emitted when the first area is operated and a second luminous color is emitted when the second area is operated.
- a 'semiconductor chip can be used for example in a flashing light display in the interior of a vehicle, so that upon actuation of the flashing light, the first light color and at Operation of the hazard warning lights the second light color is emitted.
- the second area may provide a protection area for protecting the first area
- the second active zone may have a pn junction in which the order of the p-type and n-type semiconductor layers is reversed from the order in the first active zone.
- Another variant provides to form the second region as a radiation-receiving region for the detection of radiation. This makes it possible to monitor the radiation power of the first area and, if necessary, to regulate accordingly.
- the compensation layer arranged at the level of the first active zone preferably contains an electrically conductive material, so that the second active zone can be contacted electrically by means of the compensation layer.
- the compensation layer may contain a metal or a TCO (transparent conductive oxide).
- the TCO is a transparent, conductive material, in particular a metal oxide such as zinc oxide, tin oxide, cadmium oxide, titanium oxide, indium oxide or indium tin oxide (ITO).
- binary metal oxygen compounds such as ZnO, Sn ⁇ 2 or In 2 ⁇ 3 also include ternary metal oxygen compounds , such as Z ⁇ SnO -J , CdSnO3, ZnSn ⁇ 3 , Mgln2 ⁇ 4 , Galn ⁇ 3 , Zn 2 ln 2 ⁇ 5 or Ir ⁇ Si ⁇ O or mixtures of different transparent conductive oxides to the group of TCOs.
- the TCOs do not necessarily correspond to a stoichiometric composition and may also be p- or n-doped.
- Compensation layer can be connected by a contact layer with the first active zone, so that the two areas on one side of the thin-film semiconductor chip can be electrically contacted together.
- the second region may have an etching stop layer on a side of the second active zone facing the compensation layer.
- the etch stop layer prevents structuring of the second active zone from attacking the first active zone.
- Etch stop layer electrically conductive, so that it does not have to be removed after structuring, but may remain in the finished semiconductor chip.
- the gap between the two regions may be provided with a dielectric material such that the first active region is electrically isolated from the second active region.
- a dielectric material such that the first active region is electrically isolated from the second active region.
- Suitable dielectric materials are, for example, silicon nitrides, silicon oxynitrides and silicon oxides.
- first the second active zone is grown on a growth substrate. Then the first active zone is grown on the second active zone. This is followed by removal of the first active zone in the second Area and peeling off the growth substrate. Finally, the second active zone in the first region is removed such that the two regions are laterally separated from one another by a gap.
- the two active zones can be grown on top of each other in a common growth process and then structured so that two separate functional areas each with an active zone arise.
- the second active zone in the first region is selectively removed by etching.
- the first active region in the second region can be selectively removed by etching.
- the etching can be prevented from continuing into layers which are not to be etched.
- a compensation layer is arranged on the second active zone.
- the height difference between the upper side of the second region and the upper side of the first region can be suitably adjusted by means of the compensation layer.
- the height difference can be compensated.
- a carrier is disposed on the growth substrate • an opposite side of the thin-film semiconductor chips prior to separation of the growth substrate.
- FIGS. 1A to 1F show a schematic representation of various method steps of a first variant of a method
- FIG. 2A to 21 is a schematic representation of various method steps of a second variant of a
- FIGS. 3 to 6 are schematic plan views of various embodiments of a thin-film
- FIG. 1A shows a first method step of a preferred variant of a method for producing a radiation-emitting thin-film semiconductor chip.
- a second active zone 2 is epitaxially grown on a growth substrate 3.
- the second active zone 2 has a pn junction, which in the simplest case is formed by a p-conducting and an n-conducting semiconductor layer, which adjoin one another.
- a first active zone 1 is epitaxially grown on the second active zone 2 and, like the second active zone 2, has a pn junction, which in the simplest case is formed by a p-conducting and an n-conducting semiconductor layer which adjoin one another.
- the first active region 1 and the second active zone 2 are made of a based on a phosphide compound semiconductor material, which means in this context that the active zones 1 and 2 is preferably Al n Ga m ini- n - m P include, where O ⁇ n ⁇ l, 0 ⁇ m ⁇ 1 and n + m ⁇ 1.
- this material does not necessarily have to have a mathematically exact composition according to the above formula. Rather, it may have one or more dopants as well as additional ingredients that do not substantially alter the physical properties of the material.
- the above formula includes only the major components of the crystal lattice (Al, Ga, In, P) ", even if these can be replaced in part by small amounts of other substances.
- Beosnders preferred that the first active zone contain 1 and the second active zone 2 InGaAlP.
- the first active zone 1 is structured.
- the first active zone 1 is removed in a second region II, so that only the first region I has the first active zone 1 (FIG. 1B).
- the first active zone 1 in the second region II can be etched away.
- an etching stop layer 4 is advantageously provided between the first active zone 1 and the second active zone 2, which prevents the etching of the first active zone 1, the second active zone 2 is mitgeilort.
- Phosphide compound semiconductor-based material for the two active 'zones 1 and 2 based on an arsenide compound semiconductor material such as AlGaAs is suitable for the etching stop. 4 ,
- the exposed area which is formed by removing the first active zone 1 in the second area II, can be covered by a leveling layer 5 (FIG. 1C).
- the compensation layer 5 is arranged in the second region II at the level of the first active zone 1.
- the thickness of the compensation layer 5 corresponds to the thickness of the first active zone 1, so that the first region I and the second region II are at the same level on a side opposite to the growth substrate 3.
- the compensation layer 5 is electrically conductive, so that the second active zone 2 can be electrically contacted by means of the compensation layer 5.
- the leveling layer 5 may contain a metal such as Au or Al or a metal alloy such as AuZn or AuSn.
- the compensation layer 5 can be vapor-deposited or sputtered onto the second active zone 2.
- the second active zone 2 can be structured, the composite of growth substrate 3, second active zone 2, structured first active zone 1 and 'compensation layer 5 are on the arranged the growth substrate 3 opposite side on a support 7 and the growth substrate 3 is removed ( Figure ID).
- the composite can be bonded to the carrier 7 by means of a contact layer 6.
- the contact layer . 6 may for example contain a metal alloy such as AuZn, which is not only suitable for bonding, but also has advantageous properties in terms of reflectivity and electrical conductivity.
- FIG. IE shows a next method step in which the second active zone 2 is structured.
- the second active zone 2 in the first region I is removed, so that only the second region II has the second ' active zone.
- the second active zone 2 is preferably etched away in the first region I.
- the etch stop layer 4 can prevent this, that the first active zone 1 is mitgeilort.
- etching stop layer 4 An electrically conductive material is advantageously used for the etching stop layer 4, so that the etching stop layer 4 can remain in the finished thin-film semiconductor chip 10 (FIG. 1F).
- a contact metallization 9 is applied to the first active zone 1 and a contact metallization 8 is applied to the second active zone 2, whereby the first area I and the second area II are separately electrically contactable on a side opposite the carrier 7.
- the two areas I and II are laterally separated from each other by a gap 11 so that fault currents between the two areas I and II can be prevented.
- both active zones 1 and 2 can be patterned so that at the end two separate regions I and II with separate active zones 1 and 2.
- a thin-film semiconductor chip 10 emitting radiation as shown in FIG. 1F can be produced, having a first region I with a first active zone 1, a second laterally separated from the first region I by a gap 11 Area II with a second active zone 2, which extends parallel to the first active zone 1 in a different plane, and a compensation layer 5, which is located in the second area II at the level of the first active zone 1, wherein the compensation layer 5 is not a semiconductor material contains.
- the two regions I and II can be formed such that the active zones 1 and 2 emit radiation of different wavelengths within the visible spectrum.
- the thin-film semiconductor chip 10 then emits differently colored light, as a result of which an area can be illuminated in different colors (compare also FIGS. 3 to 5).
- the side opposite the carrier 7 is the radiation outcoupling side.
- the first region I as a radiation-emitting region and the second region II as a protective region for the protection of the first region I from overvoltages or unauthorized voltages are formed (see also FIG.
- the first region I is a radiation-emitting region and the second region II is a radiation-receiving region for detecting radiation.
- FIGS. 2A to 21 show a further variant of a method according to the present application.
- a second active zone 2 is grown on a growth substrate 3, onto which in turn a first active zone 1 is grown (FIG. 2A).
- the first active zone 1 is patterned on the side opposite the growth substrate 3.
- a compensating layer 5 can be applied over the entire surface of the growth substrate 3 so that both the first active zone 1 and the second active zone 2 on this side are covered by the balancing layer 5 ( Figure 2C).
- the compensation layer 5 contains or consists of a TCO.
- the compensation layer 5 can be sputtered on.
- the compensation layer 5 can be structured in a next step (FIG. 2D), so that there is no electrical connection between the first active zone 1 and the second active zone 2 when using a TCO.
- the compensation layer 5 can be used in the first region I with advantage as a current spreading layer.
- the compensating layer 5, which is located in the second region II at the level of the first active zone 1, serve as a current spreading layer.
- the gap 11 between the first region I and the second region II can be provided with a dielectric material 12 such as a silicon nitride, a silicon oxide or a silicon oxynitride.
- the dielectric material 12 can be applied in such a way that the compensation layer 5 in the first region I and in the second region II on the side edges is covered by the dielectric material (12) (FIG. 2E).
- a leveling contact layer 6 is applied on the side opposite the growth substrate. This can also serve as a solder layer for fixing the composite on the carrier 7. Once the composite is mounted on the support 7, the growth substrate 3 can be peeled off ( Figure 2F).
- the second active zone 2 On the side of the detached growth substrate 3, the second active zone 2 is now uncovered and can therefore be easily structured from the side of the original growth substrate (FIG. 2G).
- the second active zone 2 and the first active zone 1 are thus structured on two mutually opposite sides.
- the two active zones 1 and 2 on the side opposite the carrier 7 can also be embedded in the dielectric material 12 on the side flanks, so that they face on the side surfaces and partly on the main surfaces facing the carrier 7 13 are covered by the dielectric material 12.
- current spreading layers 14 can be applied, which ensure homogeneous current distribution over the two active zones 1 and 2.
- the two current spreading layers 14 contain or consist of a TCO.
- contact metallizations 8 and 9 the two current spreading layers 14 and thus the two active zones 1 and 2 are each electrically contactable on a side opposite the carrier (FIG. 21). A common electrical contact is formed on the carrier side by the contact layer 6.
- the radiation-emitting thin-film semiconductor chip 10 produced by the method according to FIGS. 2A to 21 thus comprises a first region I with a first active zone 1, a second region II laterally separated by a gap 11 from the first region I with a second active zone 2, which extends parallel to the first active zone 1 in a different plane, and a compensation layer 5, which in the second region II is at the level of the first active zone 1, wherein the compensation layer 5 contains no semiconductor material.
- the regions I and II are different functional regions and may have the properties explained in connection with FIG. IF. Furthermore, the materials mentioned in connection with FIGS. 1A to IF can also be used in the method according to FIGS. 2A to 21.
- the radiation-emitting thin-film semiconductor chip can also have more than two regions or more than two active zones.
- a corresponding number of active zones are then grown on top of each other and structured in such a way that one area in each case has an active zone which is separated from the other active zones.
- two consecutive active zones are structured starting from two different sides.
- FIG. 3 shows in plan view an advantageous embodiment of a thin-film semiconductor chip 10, which is preferably produced according to one of the methods described above.
- the thin-film semiconductor chip 10 has a first region I and a second region II, which are laterally separated from one another by a gap 11.
- the first region I is in particular intended to emit radiation of a first wavelength within the visible spectrum
- the second region II may be provided to emit radiation of a second wavelength within the visible spectrum.
- two different illuminated areas are produced by the two areas I and II during operation of the thin-film semiconductor chip 10.
- Such a thin-film semiconductor chip 10 can be used, for example, as a flashing light display in the interior of a vehicle.
- Embodiments of a thin film semiconductor chip 10 which may be made according to any of the methods previously described.
- the first regions I are formed as symbols in the form of a circular surface (FIG. 4) or an arrow (FIG. 5).
- the symbols emerge visibly for an observer if they are mapped and can be used, for example, as orientation aids in buildings.
- the first region I is a
- Radiation generating area and the second area II a protection area.
- the two areas I and II do not have separate contact metallizations, but are jointly electrically contactable by means of a contact structure 15 electrically connecting the two areas I and II on a side opposite the support. Since preferably a contact layer (not shown) electrically connects the two regions I and II on the carrier side, the two regions I and II are connected in parallel.
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Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102008021620A DE102008021620A1 (de) | 2008-04-30 | 2008-04-30 | Strahlung emittierender Dünnfilm-Halbleiterchip und Verfahren zur Herstellung eines Strahlung emittierenden Dünnfilm-Halbleiterchips |
| PCT/DE2009/000509 WO2009132614A1 (de) | 2008-04-30 | 2009-04-09 | Strahlung emittierender dünnfilm-halbleiterchip und verfahren zur herstellung eines strahlung emittierenden dünnfilm-halbleiterchips |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2283527A1 true EP2283527A1 (de) | 2011-02-16 |
Family
ID=41016967
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP09737722A Withdrawn EP2283527A1 (de) | 2008-04-30 | 2009-04-09 | Strahlung emittierender dünnfilm-halbleiterchip und verfahren zur herstellung eines strahlung emittierenden dünnfilm-halbleiterchips |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8624269B2 (de) |
| EP (1) | EP2283527A1 (de) |
| JP (1) | JP2011519171A (de) |
| KR (1) | KR101601995B1 (de) |
| CN (1) | CN101971373B (de) |
| DE (1) | DE102008021620A1 (de) |
| WO (1) | WO2009132614A1 (de) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008021620A1 (de) | 2008-04-30 | 2009-11-05 | Osram Opto Semiconductors Gmbh | Strahlung emittierender Dünnfilm-Halbleiterchip und Verfahren zur Herstellung eines Strahlung emittierenden Dünnfilm-Halbleiterchips |
| DE102016112502A1 (de) * | 2016-07-07 | 2018-01-11 | Osram Opto Semiconductors Gmbh | Lumineszenzdiode und Verfahren zu deren Herstellung |
| JP2018026478A (ja) * | 2016-08-10 | 2018-02-15 | 富士ゼロックス株式会社 | 発光素子、発光素子アレイ、及び光伝送装置 |
| DE102016116986B4 (de) * | 2016-09-09 | 2025-07-31 | OSRAM Opto Semiconductors Gesellschaft mit beschränkter Haftung | Bauelement zur Darstellung eines Piktogramms und Verfahren zur Herstellung eines Bauelements |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003158296A (ja) * | 2001-11-22 | 2003-05-30 | Sharp Corp | 窒化物半導体発光デバイスチップとその製造方法 |
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| FR2588701B1 (fr) * | 1985-10-14 | 1988-12-30 | Bouadma Noureddine | Procede de realisation d'une structure integree laser-photodetecteur |
| US5319655A (en) * | 1992-12-21 | 1994-06-07 | Xerox Corporation | Multiwavelength laterally-injecting-type lasers |
| JPH1032223A (ja) * | 1996-07-15 | 1998-02-03 | Mitsubishi Electric Corp | 半導体装置 |
| US5877038A (en) * | 1996-11-27 | 1999-03-02 | The Regents Of The University Of California | Method of making a vertical cavity laser |
| GB2366074A (en) * | 2000-02-15 | 2002-02-27 | Hassan Paddy Abdel Salam | LED light source with two vertically-stacked LEDs of different colours |
| US5999553A (en) * | 1997-11-25 | 1999-12-07 | Xerox Corporation | Monolithic red/ir side by side laser fabricated from a stacked dual laser structure by ion implantation channel |
| TW502458B (en) * | 1999-06-09 | 2002-09-11 | Toshiba Corp | Bonding type semiconductor substrate, semiconductor light emission element and manufacturing method thereof |
| DE10345555A1 (de) | 2003-09-30 | 2005-05-04 | Osram Opto Semiconductors Gmbh | Strahlungsemittierendes und -empfangendes Halbleiterbauelement und Verfahren zu dessen Herstellung |
| KR101060055B1 (ko) | 2003-11-28 | 2011-08-29 | 오스람 옵토 세미컨덕터스 게엠베하 | 보호 다이오드를 포함하는 발광 반도체 소자 |
| DE102004005269B4 (de) * | 2003-11-28 | 2005-09-29 | Osram Opto Semiconductors Gmbh | Lichtemittierendes Halbleiterbauelement mit einer Schutzdiode |
| CN1922733A (zh) | 2004-02-20 | 2007-02-28 | 奥斯兰姆奥普托半导体有限责任公司 | 光电组件、具有多个光电组件的装置和用于制造光电组件的方法 |
| DE102004026125A1 (de) * | 2004-05-28 | 2005-12-22 | Osram Opto Semiconductors Gmbh | Optoelektronisches Bauteil und Verfahren zu dessen Herstellung |
| US7510374B2 (en) | 2005-07-28 | 2009-03-31 | Honeywell International Inc. | Non-concentric rings for reduced turbo-machinery operating clearances |
| US7521727B2 (en) * | 2006-04-26 | 2009-04-21 | Rohm And Haas Company | Light emitting device having improved light extraction efficiency and method of making same |
| DE102006057747B4 (de) * | 2006-09-27 | 2015-10-15 | Osram Opto Semiconductors Gmbh | Halbleiterkörper und Halbleiterchip mit einem Halbleiterkörper |
| DE102006051745B4 (de) * | 2006-09-28 | 2024-02-08 | OSRAM Opto Semiconductors Gesellschaft mit beschränkter Haftung | LED-Halbleiterkörper und Verwendung eines LED-Halbleiterkörpers |
| DE102008021620A1 (de) | 2008-04-30 | 2009-11-05 | Osram Opto Semiconductors Gmbh | Strahlung emittierender Dünnfilm-Halbleiterchip und Verfahren zur Herstellung eines Strahlung emittierenden Dünnfilm-Halbleiterchips |
-
2008
- 2008-04-30 DE DE102008021620A patent/DE102008021620A1/de not_active Withdrawn
-
2009
- 2009-04-09 KR KR1020107020183A patent/KR101601995B1/ko not_active Expired - Fee Related
- 2009-04-09 JP JP2011506567A patent/JP2011519171A/ja active Pending
- 2009-04-09 WO PCT/DE2009/000509 patent/WO2009132614A1/de not_active Ceased
- 2009-04-09 EP EP09737722A patent/EP2283527A1/de not_active Withdrawn
- 2009-04-09 US US12/989,470 patent/US8624269B2/en not_active Expired - Fee Related
- 2009-04-09 CN CN2009801090619A patent/CN101971373B/zh not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003158296A (ja) * | 2001-11-22 | 2003-05-30 | Sharp Corp | 窒化物半導体発光デバイスチップとその製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102008021620A1 (de) | 2009-11-05 |
| KR101601995B1 (ko) | 2016-03-17 |
| KR20110007100A (ko) | 2011-01-21 |
| CN101971373A (zh) | 2011-02-09 |
| US20110121322A1 (en) | 2011-05-26 |
| US8624269B2 (en) | 2014-01-07 |
| JP2011519171A (ja) | 2011-06-30 |
| CN101971373B (zh) | 2012-12-26 |
| WO2009132614A1 (de) | 2009-11-05 |
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