EP2278243B1 - Four tournant pour traitement thermique radiatif de matériaux solides - Google Patents

Four tournant pour traitement thermique radiatif de matériaux solides Download PDF

Info

Publication number
EP2278243B1
EP2278243B1 EP10290339A EP10290339A EP2278243B1 EP 2278243 B1 EP2278243 B1 EP 2278243B1 EP 10290339 A EP10290339 A EP 10290339A EP 10290339 A EP10290339 A EP 10290339A EP 2278243 B1 EP2278243 B1 EP 2278243B1
Authority
EP
European Patent Office
Prior art keywords
heating element
furnace according
rotary furnace
tube
heat treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP10290339A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2278243A1 (fr
Inventor
Elena Sanz
Matthieu Rolland
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to PL10290339T priority Critical patent/PL2278243T3/pl
Publication of EP2278243A1 publication Critical patent/EP2278243A1/fr
Application granted granted Critical
Publication of EP2278243B1 publication Critical patent/EP2278243B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
    • F27B7/20—Details, accessories, or equipment peculiar to rotary-drum furnaces
    • F27B7/34—Arrangements of heating devices
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/28—Other processes
    • C10B47/30—Other processes in rotary ovens or retorts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/40—Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00—Treating solid fuels to improve their combustion
    • C10L9/08—Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
    • C10L9/083—Torrefaction
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/20—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having rotating or oscillating drums
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

  • the present invention relates to the field of heat treatment furnaces of solid materials, and more particularly to pyrolysis (or thermolysis) or roasting furnaces intended to treat solids such as waste of any kind, and for example biomass.
  • the heat is mainly provided by the outside of the heated tube by circulating hot gases around the tube (steam, air, fumes of fuel diluted or cooled) or by radiation (electric or flame).
  • gases around the tube
  • radiation electric or flame
  • the circulation of gases inside the tube is small to avoid pneumatic entrainment of the particles, which limits the possibilities of convective transfer.
  • the heat transfer to the load is mainly by radiation and little by conduction (contact between the load and the heated walls of the oven).
  • the required temperatures make the radiative transfers negligible.
  • Conduction transfers are proportional to the contact area, the temperature difference between the load and the wall, and a heat transfer coefficient from the wall to the load.
  • the transfer coefficient depends on the properties of the load and is not a parameter, it is typically 10-20 W / m 2 / ° C.
  • the charge / wall temperature difference is limited by the nature of the lignocellulosic biomass. Beyond a temperature of 280-300 ° C depending on the species, exothermic reactions begin and are self-sustaining by the effect of thermal acceleration of the kinetics. These reactions lead to pyrolyzed solids having lost a large amount of their mass and energy. The loss of yield is important and it is necessary to place in conditions where the exothermic reactions can not take place.
  • the solution generally adopted to increase the heat transfer is the increase in the length of the rotary kiln to increase the contact area with the biomass. This technique is expensive in terms of investment and energy consumption.
  • Another solution is to increase the residence time in the oven by decreasing the inclination of the oven and decreasing the flow rate to maintain the same bed height, which leads to a decrease in capacity.
  • Licences JP2003307388 and WO 98/54273 describe an oven having a longitudinal heating element of the length of the thermolysis furnace emitting radiation for heating the load.
  • the present invention therefore aims to overcome one or more of the disadvantages of the prior art by providing a rotary kiln for accelerating the heat treatment of solid materials and in particular biomass, to reduce the size of equipment and therefore to reduce the cost of roasting, while respecting the maximum temperatures of the rotating furnace wall and limiting the exothermic reactions.
  • the present invention proposes a rotary kiln for the heat treatment of solid materials comprising at least one rotating tube in which the solid materials are introduced and a means of heating external to the rotating tube making it possible to carry out part of the heat treatment in the absence of oxygen, characterized in that it comprises a second heating means not rotating with the furnace, charge to improve the heat treatment, formed by a heating element positioned to be above the load when the furnace rotates and at least a deflector panel surrounding the heating element at the opposite side of the load disposed within the rotating tube.
  • the heating element is rectilinear, longitudinal and runs the entire length of the rotary furnace.
  • the section of the heating element is polygonal or round or ovoid.
  • the section of the heating element is flat or concave or convex.
  • the width of the heating element is between 1/60 th and 2/3 of the inside diameter of the oven tube and the height is between 1/20 and 4/4 of the width of the heating element.
  • the heating element is fixed by its ends independently of the oven tube and does not turn with the oven.
  • the position of the heating element in the furnace tube is eccentric, with respect to the central longitudinal axis of the furnace tube, in the direction opposite to that where the load is located.
  • the heating element is hollow or solid, waterproof or perforated.
  • the heating element is heated by circulating a very hot gas inside the heating element or by combustion or by an electrical means.
  • the deflector panel is longitudinal and of the same length as the heating element.
  • the deflector panel is constituted by a single part or several parts connected to each other, and forming a central portion disposed above the heating element and two sides arranged on either side from the central part.
  • the deflector panel is in the form of a half-tube or has angles formed by the connection of the various constituent parts.
  • the two sides of the baffle panel have a size that allows them to exceed the heating element.
  • the two sides are oriented so as to form an angle allowing the radiation to cover the entire surface of the bed of the load.
  • the baffle board is fixed at its ends independently of the furnace tube and does not rotate with the furnace.
  • the invention also relates to the use of the rotary kiln to achieve the heat treatment of biomass.
  • the heat treatment is a roasting treatment of solid biomass.
  • the heat treatment is a radiative heat treatment of biomass.
  • the invention relates to a rotary kiln for heat treatment, such as roasting, of solid materials and for example waste household, agricultural, industrial, and solid biomass.
  • the solid biomass treated in the device according to the invention can be for example ligno-cellulose (wood, straw, algae), purified lignin, cellulose or a mixture of these different biomass.
  • the biomass is genal in the form of platelets whose thickness is between 1 mm and 30 mm, the width is between 1 mm and 40 mm and the length is between 1 mm and 100 mm.
  • the roasting carried out in the context of the invention consists of a heat treatment carried out at average temperatures generally between 80 ° C and 400 ° C, and preferably between 150 ° C and 280 ° C and in the absence of oxygen.
  • the rotary kiln is a conventional thermolysis or pyrolysis furnace as already described in the prior art.
  • the rotary furnace is thus formed by at least one main tube in which is sealed at one end of the furnace, the charge to be treated, and which is heated by a first heating means and for example by circulation of hot flue gas or by electric resistors or by burners arranged outside the tube.
  • the tube is thus heated to a temperature not exceeding the maximum temperature permitted by the exothermic reactions, generally between 280 ° C and 400 ° C.
  • the main tube generally rotates about a longitudinal axis thus allowing the mixing of the load and therefore a homogeneous treatment.
  • the furnace tube is usually made of stainless steel or not, with or without coating.
  • the main tube forming the oven (1) rotating according to the invention comprises another source of radiative heat without contact with the particles for improving and / or finalizing the heat treatment started with the first external heating means.
  • the heat treatment is thus achieved by the combination of the two heating means.
  • This heat source is formed by a stationary heating element (4, 4 ', 4 ") incorporated inside the furnace tube, to be heated this element (4, 4', 4") is heated to a temperature to which it radiates, ie above 600 ° C.
  • the infra-red, visible (red-walled) or ultraviolet radiation emitted by this radiating element allows a heat transfer towards the charge (2) proportional to the radiation temperature (in K) power 4, according to Stephan's law.
  • the heating element (4, 4 ', 4 "), also known as the radiating element or the radiant element, is designed so that only the charging bed (2) can receive radiation: the rotating tube thus remains at the maximum permitted temperature. by exothermic reactions.
  • the charge (2) exposed to radiation is the surface charge (3) of the bed. Due to the rotation of the rotating furnace (1), the load (3) exposed to the radiation is constantly renewed and the temperature of the charge remains homogeneous and below the critical threshold.
  • the temperature of the heating element (4, 4 ', 4 ") is thus regulated so that the temperature of the charge remains below the critical threshold
  • the heat transfer at power temperature 4 ensures that the control effects be fast enough to avoid thermal runaway.
  • the heat treatment of the charge inside the oven (1) is carried out in the absence of oxygen.
  • the heating element (4, 4 ', 4 ") is longitudinally and rectilinear lengthwise, and runs the entire length of the oven and is arranged inside the rotating oven tube (1) and in the the length of the furnace Its position in the furnace tube is eccentric, relative to the central longitudinal axis of the furnace tube, in the opposite direction to that in which the load (2) is located. that when the oven (1) rotates, the load (2) is always found down the oven tube (1), the element (4, 4 ', 4 ") heating is arranged so as to be in the upper part of the oven tube (1).
  • the height at which the heating element is arranged is chosen so that the entire load in motion and possibly at rest is "illuminated" by the radiation.
  • the heating element (4, 4 ', 4 ") is thus generally located in the upper half of the tube, at a distance greater than the radius of the tube of the surface (3) of the load bed. placed in the plane of symmetry of the tube (in the middle), or shifted on the side so as to better "illuminate” the load which due to the rotation is inclined and is thus higher on one side than on the other .
  • the heating element (4, 4 ', 4 ") is fixed independently of the oven tube (1), it has no point of contact with the oven tube (1) except perhaps by its ends, it turns not with the oven (1) It is fixed at its ends by techniques, well known to those skilled in the art, to maintain the desired seal and necessary for the heat treatment in the oven (1) rotating.
  • complete heating element is thus generally at least as long as the oven to be fixed, but the heating portion may be shorter or in part to facilitate temperature control.
  • the heating element may comprise several zones at different temperatures. This may allow, for example, drying in a first zone and then roasting in a next zone.
  • the section of the element (4, 4 ', 4 ") heating can be of different shapes: polygonal (square, rectangle ...), round, ovoid ...
  • the section of the element (4, 4 ', 4 ") heating is flat, that is to say wider than high compared to the upper and lower part of the tube of the oven (1) rotating.
  • the width of the heating element is generally between 1/60 th and 2/3 of the inside diameter of the furnace tube and preferably between 1/15 th and 1/2 of the inside diameter of the tube of the rotary furnace.
  • the height is generally between 1/20 and 4/4 of the width of the heating element and preferably between 1/10 and 1/2 of the heating element.
  • the heating element is composed of several heating elements arranged side by side, which makes it possible to have a large width and a low height.
  • the heating element (4, 4 ', 4 ") of flat section can be bent in the direction of the width upwards or downwards, ie convex (4') or concave (4") as illustrated on the figures 2 and 3 .
  • the width of the element can be constant or variable.
  • the element (4, 4 ', 4 ") heating is optionally solid or hollow, depending on the heating mode used to heat it and then allow it to emit radiation.It can be sealed or perforated to let some of the hot gas in the oven.
  • the heating element (4, 4 ', 4 ") is optionally heated over its entire length, that is to say over the entire length of the oven as well, or over only a part of its length. (4, 4 ', 4 ") heating is heated on only part of its length, this is its initial part, corresponding to the beginning of the reaction and at the entrance to the charge in the oven, which is heated and heated. This part also corresponds to the zone of the furnace (1) where the particle temperature is the lowest, in particular where the drying of the residual moisture takes place.
  • the element (4, 4 ', 4 ") heating is associated with at least one panel (5, 5') deflector.
  • the deflector panel (5, 5 ') is placed on the sides and above the heating element (4, 4', 4 "), relative to the load below the element (4, 4). ', 4 "), to ensure that the rotating tube is not heated by the radiative flow
  • This panel (5, 5') surrounds the element (4, 4 ', 4") at the side opposite to the load (2).
  • the heating element (4, 4 ', 4 ") may consist of one or more parts (51, 52, 52', 53, 53 '), and for example three parts connected together, and forming a central portion (51) disposed above the heating element and two sides (52, 53, 52 ', 53') disposed on either side of the central portion (51)
  • the two sides (52, 52 ', 53', 53 ') of this panel have a size which allows them to protrude from the heating element (4, 4', 4 ").
  • it is necessary to provide a space between the panel and the heating element of at least 5 cm, and preferably greater than 10 cm. cm to allow the panels to be cooled by gas flow between the heating element and the panel and avoided overheating.
  • the two sides (52, 52 ', 53', 53 ') are oriented to form an angle allowing the radiation to cover the entire surface (3) of the bed of the load (2).
  • the material used for this panel (5, 5 ') is a reflective material that prevents radii from passing through and resists heat.
  • the material used may be any type of material, and in particular reflective materials to prevent them from heating in turn: aluminum for example, having the properties necessary for use in the device according to the invention, well known to the skilled person. In this way the rays emitted above the heating element (4, 4 ', 4 ") are returned by the panel (5, 5') to the load (3) which is located below the element (4, 5 '). , 4 ', 4 ") heating.
  • this panel (5, 5') is fixed by each of its two ends and does not rotate with the oven (1). no virtually no point of contact with the walls of the furnace tube (1), nor with the element (4, 4 ', 4 ") heating. It is possible, however, to tolerate contact points with the oven and possibly the heating element for mechanical reasons of rigidity.
  • the panel is fixed at its ends by techniques, well known to those skilled in the art, to maintain the desired seal and necessary for the heat treatment in the oven (1) rotating.
  • this panel (5, 5 ') thus forms a cone (6) of spokes directed only towards the load (3).
  • the inner wall of the rotating oven tube (1) is not heated unnecessarily, there is no risk of overheating and all the spokes are directed to the load which allows more efficient heating and thus increases the capacity heat treatment and in particular roasting the oven.
  • the device according to the invention thus makes it possible to carry out the roasting of solid material and in particular of biomass platelets whose thickness is generally between 1 mm and 30 mm, the width is generally between 1 mm and 40 mm and the length is generally between 1 mm and 100 mm, at temperatures generally between 80 ° C and 400 ° C and preferably between 150 ° C and 280 ° C and in the absence of oxygen.
  • the biomass treated in such a device that is to say a heating rotary kiln (1) comprising a second heat source provided by a heating element (4, 4 ') disposed in the oven (1), makes it possible to to obtain a roaster material more friable and therefore easier to grind. The resulting particles of grinding after roasting are thus rounder.
  • the heating element is used as the only means of heating, but it can also be used to heat the walls (at a controlled temperature), so as to simplify the installation. This can be interesting for small installations, or the heating is electric
  • the presence of the element (4, 4 ', 4 ") heating increases the heat treatment capacity of the furnace (1) rotating by 77% compared to a conventional rotary furnace having no additional heating element.
  • One of the advantages of this invention is the increase in amount of heat transferred to the load per unit length. This results in an increase in iso-geometry capacity or a decrease in the size of the iso-capacity reactor.
  • this device can be installed in pre-existing rotary kilns at a lower cost.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Muffle Furnaces And Rotary Kilns (AREA)
  • Processing Of Solid Wastes (AREA)
EP10290339A 2009-07-21 2010-06-23 Four tournant pour traitement thermique radiatif de matériaux solides Active EP2278243B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL10290339T PL2278243T3 (pl) 2009-07-21 2010-06-23 Piec obrotowy do termicznej obróbki radiacyjnej materiałów stałych

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0903587A FR2948448B1 (fr) 2009-07-21 2009-07-21 Four tournant pour traitement thermique radiatif de materiaux solides

Publications (2)

Publication Number Publication Date
EP2278243A1 EP2278243A1 (fr) 2011-01-26
EP2278243B1 true EP2278243B1 (fr) 2012-06-20

Family

ID=41647027

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10290339A Active EP2278243B1 (fr) 2009-07-21 2010-06-23 Four tournant pour traitement thermique radiatif de matériaux solides

Country Status (4)

Country Link
US (1) US9091480B2 (pl)
EP (1) EP2278243B1 (pl)
FR (1) FR2948448B1 (pl)
PL (1) PL2278243T3 (pl)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2948448B1 (fr) 2009-07-21 2014-01-10 Inst Francais Du Petrole Four tournant pour traitement thermique radiatif de materiaux solides
WO2012158118A1 (en) 2011-05-18 2012-11-22 Bioendev Ab Countercurrent oxygen enhanced torrefaction
EP2710099B1 (en) 2011-05-18 2016-08-31 Bioendev AB Method for monitoring and control of torrefaction temperature
US20140166465A1 (en) * 2011-07-07 2014-06-19 Torrefuels Incorporated System and process for conversion of organic matter into torrefied product
JP6225117B2 (ja) * 2012-11-07 2017-11-01 日本碍子株式会社 赤外線加熱装置及び乾燥炉
CN104449791B (zh) * 2014-11-13 2016-07-06 常熟市高压容器制造有限公司 一种蠕动式固相反应器及组合式模块
CN104741042A (zh) * 2015-03-25 2015-07-01 胡振强 太阳能秸秆反应炉
CN113046103B (zh) * 2021-03-17 2021-09-14 湖南耕农富硒农业科技股份有限公司 一种生物质燃料的加工设备及加工方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2432425B2 (de) * 1974-07-04 1976-05-26 In schraeglage gelagerter und an beiden enden luftdicht geschlossener drehrohrofen
DE2656288C3 (de) * 1976-12-11 1981-06-11 Vita Zahnfabrik H. Rauter GmbH & Co KG, 7880 Bad Säckingen Brennofen für dental-keramische Arbeiten
FR2720487B1 (fr) 1994-05-30 1996-07-12 Inst Francais Du Petrole Four tournant de pyrolyse de déchets avec chauffage interne.
AU1862897A (en) * 1996-03-11 1997-10-01 Roasting Technologies Pty Ltd Rotary and tunnel-type kilns with multi-ducted radiant heating
DE69812932T2 (de) 1997-05-30 2003-12-24 Babcock & Wilcox Volund Aps, Esbjerg Verfahren und vorrichtung zur beheizung eines drehrohrofens zur vergasung und zur pyrolyse von organischen substanzen
JP2003307388A (ja) 2002-04-15 2003-10-31 Nippon Furnace Kogyo Kaisha Ltd ロータリーキルン炉
JP2005037044A (ja) * 2003-07-15 2005-02-10 Meidensha Corp 加熱処理装置
US8540794B2 (en) * 2004-09-03 2013-09-24 Jiann-Yang Hwang Method for reducing iron oxide and producing syngas
FR2948448B1 (fr) 2009-07-21 2014-01-10 Inst Francais Du Petrole Four tournant pour traitement thermique radiatif de materiaux solides

Also Published As

Publication number Publication date
US20110019981A1 (en) 2011-01-27
US9091480B2 (en) 2015-07-28
PL2278243T3 (pl) 2012-10-31
FR2948448A1 (fr) 2011-01-28
FR2948448B1 (fr) 2014-01-10
EP2278243A1 (fr) 2011-01-26

Similar Documents

Publication Publication Date Title
EP2278243B1 (fr) Four tournant pour traitement thermique radiatif de matériaux solides
EP3803243B1 (fr) Dispositif de traitement thermique a enveloppe refractaire et son utilisation
EP0520913A1 (fr) Appareil de chauffage avec brûleur catalytique
EP2218300B1 (fr) Dispositif de traitement thermique de solides divises
EP0685551B1 (fr) Four tournant de pyrolyse de déchets avec chauffage interne
EP2281163A1 (fr) Procédé de séchage et/ou de cuisson d'un revêtement: organique sur une bande métallique en défilement continu, et dispositif pour la mise en oeuvre de ce procédé
EP0504355B1 (fr) Ensemble de cuisson pour cuisiniere ou table de cuisson, comportant au moins un bruleur a gaz
WO2010116050A1 (fr) Four tournant pour traitement thermique de matériaux solides
FR3040774A1 (fr) Sechoir solaire pour produits agricoles ou marins.
FR2690736A1 (fr) Ensemble à four à moufle destiné au brasage.
EP1847791A1 (fr) Procédé de séchage des boues et dispositif permettant la mise en oeuvre du procédé
FR2758611A1 (fr) Chambre de combustion d'air charge de particules combustibles
FR2630195A1 (fr) Appareil de chauffage par radiation utilisant du gaz combustible en tant qu'energie de transformation
WO2015067910A1 (fr) Dispositif de traitement a chaud de produits granuleux et procede de regulation de la temperature d'emanations produites par un dispositif de traitement a chaud de produits granuleux
FR2528544A1 (fr) Bruleur electrique pour un four d'oxydation
EP0841519A1 (fr) Procédé et installation de traitement par combustion de déchets, et de récupération de chaleur
EP3178578B1 (fr) Installation d'incineration de dechets et procede associe
WO2022223289A1 (fr) Dispositif de traitement d'un produit
WO2022029373A1 (fr) Four pour chauffe oenologique de bois
FR2505350A1 (fr) Gazeificateurs de combustibles solides a lit fixe et a tirage inverse
FR3030559A1 (fr) Dispositif de traitement gaz/solide par un reacteur a vis comprenant une brosse rapportee sur la vis
FR2664784A1 (fr) Rechauffeur de fluide utilisant des tubes chauffes par effet joule qui transmettent leur energie simultanement par leurs faces interne et externe.
WO2024217888A1 (fr) Four a soles multiples pour mettre en contact un solide et un gaz
CA3153125A1 (fr) Dispositif de traitement thermique d'un produit comprenant au moins un element chauffant et procede correspondant
FR2680226A1 (fr) Dispositif de chauffage a gaz par rayonnement.

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME RS

17P Request for examination filed

Effective date: 20110726

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RIC1 Information provided on ipc code assigned before grant

Ipc: C10L 5/44 20060101ALI20120127BHEP

Ipc: F27B 7/34 20060101AFI20120127BHEP

Ipc: C10B 53/02 20060101ALI20120127BHEP

Ipc: F23G 5/20 20060101ALI20120127BHEP

Ipc: F23G 5/027 20060101ALI20120127BHEP

Ipc: C10B 47/30 20060101ALI20120127BHEP

Ipc: C10L 9/08 20060101ALI20120127BHEP

Ipc: F23G 5/08 20060101ALI20120127BHEP

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 563293

Country of ref document: AT

Kind code of ref document: T

Effective date: 20120715

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: FRENCH

REG Reference to a national code

Ref country code: NL

Ref legal event code: T3

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602010001974

Country of ref document: DE

Effective date: 20120816

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120920

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

REG Reference to a national code

Ref country code: PL

Ref legal event code: T3

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

Effective date: 20120620

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120921

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

BERE Be: lapsed

Owner name: IFP ENERGIES NOUVELLES

Effective date: 20120630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121020

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120630

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121022

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120623

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121001

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120630

26N No opposition filed

Effective date: 20130321

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602010001974

Country of ref document: DE

Effective date: 20130321

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120920

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120620

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120623

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100623

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140630

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140630

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 7

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 8

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 9

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20240618

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20240627

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20240625

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 20240618

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20240625

Year of fee payment: 15

Ref country code: FI

Payment date: 20240624

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PL

Payment date: 20240610

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20240624

Year of fee payment: 15