EP2267732A3 - Rare earth permanent magnet - Google Patents

Rare earth permanent magnet Download PDF

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Publication number
EP2267732A3
EP2267732A3 EP10009421A EP10009421A EP2267732A3 EP 2267732 A3 EP2267732 A3 EP 2267732A3 EP 10009421 A EP10009421 A EP 10009421A EP 10009421 A EP10009421 A EP 10009421A EP 2267732 A3 EP2267732 A3 EP 2267732A3
Authority
EP
European Patent Office
Prior art keywords
rare earth
permanent magnet
earth permanent
concentration
magnet body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP10009421A
Other languages
German (de)
French (fr)
Other versions
EP2267732A2 (en
EP2267732B1 (en
Inventor
Hajime Nakamura
Koichi Hirota
Masanobu Shimao
Takehisa Minowa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shin Etsu Chemical Co Ltd
Original Assignee
Shin Etsu Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shin Etsu Chemical Co Ltd filed Critical Shin Etsu Chemical Co Ltd
Publication of EP2267732A2 publication Critical patent/EP2267732A2/en
Publication of EP2267732A3 publication Critical patent/EP2267732A3/en
Application granted granted Critical
Publication of EP2267732B1 publication Critical patent/EP2267732B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60KARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
    • B60K15/00Arrangement in connection with fuel supply of combustion engines or other fuel consuming energy converters, e.g. fuel cells; Mounting or construction of fuel tanks
    • B60K15/03Fuel tanks
    • B60K15/04Tank inlets
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/005Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/032Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
    • H01F1/04Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
    • H01F1/047Alloys characterised by their composition
    • H01F1/053Alloys characterised by their composition containing rare earth metals
    • H01F1/055Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5
    • H01F1/057Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B
    • H01F1/0571Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B in the form of particles, e.g. rapid quenched powders or ribbon flakes
    • H01F1/0575Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B in the form of particles, e.g. rapid quenched powders or ribbon flakes pressed, sintered or bonded together
    • H01F1/0577Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B in the form of particles, e.g. rapid quenched powders or ribbon flakes pressed, sintered or bonded together sintered
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F41/00Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
    • H01F41/02Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
    • H01F41/0253Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing permanent magnets
    • H01F41/0293Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing permanent magnets diffusion of rare earth elements, e.g. Tb, Dy or Ho, into permanent magnets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60KARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
    • B60K15/00Arrangement in connection with fuel supply of combustion engines or other fuel consuming energy converters, e.g. fuel cells; Mounting or construction of fuel tanks
    • B60K15/03Fuel tanks
    • B60K15/04Tank inlets
    • B60K2015/0458Details of the tank inlet
    • B60K2015/0493Means for checking absence or presence of closure cap
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60KARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
    • B60K15/00Arrangement in connection with fuel supply of combustion engines or other fuel consuming energy converters, e.g. fuel cells; Mounting or construction of fuel tanks
    • B60K15/03Fuel tanks
    • B60K15/04Tank inlets
    • B60K15/05Inlet covers
    • B60K2015/0592Inlet covers with storage means for the cap
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/032Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
    • H01F1/04Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
    • H01F1/047Alloys characterised by their composition
    • H01F1/053Alloys characterised by their composition containing rare earth metals
    • H01F1/055Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5
    • H01F1/058Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IVa elements, e.g. Gd2Fe14C
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F41/00Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
    • H01F41/02Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
    • H01F41/0253Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing permanent magnets
    • H01F41/0266Moulding; Pressing

Abstract

A rare earth permanent magnet is in the form of a sintered magnet body having a composition R1 aR2 bTcAdFeOfMg wherein F and R2 are distributed such that their concentration increases on the average from the center toward the surface of the magnet body, and grain boundaries having a concentration of R2/(R1+R2) which is on the average higher than the concentration of R2/(R1+R2) contained in primary phase grains of (R1,R2)2T14A tetragonal system form a three-dimensional network structure which is continuous from the magnet body surface to a depth of at least 10 µm. The invention provides R-Fe-B sintered magnets which exhibit a high coercive force.
EP10009421.8A 2005-03-23 2006-02-01 Rare earth permanent magnet Active EP2267732B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2005084213 2005-03-23
EP06250543.3A EP1705669B1 (en) 2005-03-23 2006-02-01 Rare earth permanent magnet

Related Parent Applications (3)

Application Number Title Priority Date Filing Date
EP06250543.3A Division-Into EP1705669B1 (en) 2005-03-23 2006-02-01 Rare earth permanent magnet
EP06250543.3A Division EP1705669B1 (en) 2005-03-23 2006-02-01 Rare earth permanent magnet
EP06250543.3 Division 2006-02-01

Publications (3)

Publication Number Publication Date
EP2267732A2 EP2267732A2 (en) 2010-12-29
EP2267732A3 true EP2267732A3 (en) 2011-06-22
EP2267732B1 EP2267732B1 (en) 2014-06-25

Family

ID=36607265

Family Applications (2)

Application Number Title Priority Date Filing Date
EP06250543.3A Active EP1705669B1 (en) 2005-03-23 2006-02-01 Rare earth permanent magnet
EP10009421.8A Active EP2267732B1 (en) 2005-03-23 2006-02-01 Rare earth permanent magnet

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP06250543.3A Active EP1705669B1 (en) 2005-03-23 2006-02-01 Rare earth permanent magnet

Country Status (8)

Country Link
US (1) US7488394B2 (en)
EP (2) EP1705669B1 (en)
KR (1) KR101062229B1 (en)
CN (1) CN100520992C (en)
BR (1) BRPI0601890B1 (en)
MY (1) MY142024A (en)
RU (1) RU2377681C2 (en)
TW (1) TWI364765B (en)

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US8211327B2 (en) 2004-10-19 2012-07-03 Shin-Etsu Chemical Co., Ltd. Preparation of rare earth permanent magnet material
US7559996B2 (en) 2005-07-22 2009-07-14 Shin-Etsu Chemical Co., Ltd. Rare earth permanent magnet, making method, and permanent magnet rotary machine
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US7955443B2 (en) * 2006-04-14 2011-06-07 Shin-Etsu Chemical Co., Ltd. Method for preparing rare earth permanent magnet material
JP4605396B2 (en) * 2006-04-14 2011-01-05 信越化学工業株式会社 Method for producing rare earth permanent magnet material
JP4753030B2 (en) * 2006-04-14 2011-08-17 信越化学工業株式会社 Method for producing rare earth permanent magnet material
JP4737431B2 (en) 2006-08-30 2011-08-03 信越化学工業株式会社 Permanent magnet rotating machine
JP4840606B2 (en) * 2006-11-17 2011-12-21 信越化学工業株式会社 Rare earth permanent magnet manufacturing method
WO2008123251A1 (en) * 2007-03-27 2008-10-16 Hitachi Metals, Ltd. Permanent magnet type rotator and process for producing the same
WO2008139559A1 (en) * 2007-05-02 2008-11-20 Hitachi Metals, Ltd. R-t-b sintered magnet
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JP4672030B2 (en) * 2008-01-31 2011-04-20 日立オートモティブシステムズ株式会社 Sintered magnet and rotating machine using the same
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JP5472444B2 (en) 2010-03-04 2014-04-16 Tdk株式会社 Rare earth sintered magnet and motor
CN102822912B (en) 2010-03-30 2015-07-22 Tdk株式会社 Rare earth sintered magnet, method for producing same, motor and automobile
WO2012099188A1 (en) * 2011-01-19 2012-07-26 日立金属株式会社 R-t-b sintered magnet
KR101243347B1 (en) * 2011-01-25 2013-03-13 한양대학교 산학협력단 R-Fe-B Sintered magnet with enhancing mechanical property and fabrication method thereof
WO2012102497A2 (en) * 2011-01-25 2012-08-02 Industry-University Cooperation Foundation, Hanyang University R-fe-b sintered magnet with enhanced mechanical properties and method for producing the same
JP5868500B2 (en) * 2012-05-30 2016-02-24 株式会社日立製作所 Sintered magnet and manufacturing method thereof
DE102012221448A1 (en) * 2012-11-23 2014-06-12 Hochschule Aalen Magnetic material and process for its production
WO2014148353A1 (en) * 2013-03-18 2014-09-25 インターメタリックス株式会社 RFeB-BASED MAGNET PRODUCTION METHOD, RFeB-BASED MAGNET, AND COATING MATERIAL FOR GRAIN BOUNDARY DIFFUSION PROCESS
CN103258633B (en) * 2013-05-30 2015-10-28 烟台正海磁性材料股份有限公司 A kind of preparation method of R-Fe-B based sintered magnet
CN104715877B (en) * 2013-12-16 2019-08-27 北京中科三环高技术股份有限公司 A kind of rare-earth permanent magnet and its manufacturing method
KR101534717B1 (en) * 2013-12-31 2015-07-24 현대자동차 주식회사 Process for preparing rare earth magnets
GB2540150B (en) 2015-07-06 2020-01-08 Dyson Technology Ltd Rare earth magnet with Dysprosium treatment
GB2540149B (en) * 2015-07-06 2019-10-02 Dyson Technology Ltd Magnet
CN106328367B (en) * 2016-08-31 2017-11-24 烟台正海磁性材料股份有限公司 A kind of preparation method of R Fe B based sintered magnets
CN109256250B (en) * 2017-07-13 2021-07-13 北京中科三环高技术股份有限公司 Ce-containing rare earth permanent magnet and preparation method thereof
JP7196514B2 (en) * 2018-10-04 2022-12-27 信越化学工業株式会社 rare earth sintered magnet
WO2020155113A1 (en) * 2019-02-01 2020-08-06 天津三环乐喜新材料有限公司 Preparation method for rare earth diffused magnet and rare earth diffused magnet
CN112447350B (en) * 2019-08-29 2024-05-07 比亚迪股份有限公司 Rare earth permanent magnet and preparation method thereof
CN111243807B (en) * 2020-02-26 2021-08-27 厦门钨业股份有限公司 Neodymium-iron-boron magnet material, raw material composition, preparation method and application

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Also Published As

Publication number Publication date
CN1838343A (en) 2006-09-27
EP2267732A2 (en) 2010-12-29
KR20060102483A (en) 2006-09-27
EP1705669B1 (en) 2014-04-23
MY142024A (en) 2010-08-16
KR101062229B1 (en) 2011-09-05
BRPI0601890A (en) 2006-12-05
CN100520992C (en) 2009-07-29
RU2377681C2 (en) 2009-12-27
BRPI0601890B1 (en) 2018-01-16
EP1705669A2 (en) 2006-09-27
EP1705669A3 (en) 2008-02-13
US7488394B2 (en) 2009-02-10
RU2006103678A (en) 2007-08-20
EP2267732B1 (en) 2014-06-25
TWI364765B (en) 2012-05-21
US20060213584A1 (en) 2006-09-28
TW200643995A (en) 2006-12-16

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