EP2242657A2 - Security element and method for producing the same - Google Patents
Security element and method for producing the sameInfo
- Publication number
- EP2242657A2 EP2242657A2 EP09711080A EP09711080A EP2242657A2 EP 2242657 A2 EP2242657 A2 EP 2242657A2 EP 09711080 A EP09711080 A EP 09711080A EP 09711080 A EP09711080 A EP 09711080A EP 2242657 A2 EP2242657 A2 EP 2242657A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- laser
- security element
- embossed structure
- metallized
- cover layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 238000004049 embossing Methods 0.000 claims abstract description 49
- 238000001465 metallisation Methods 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 32
- 230000005855 radiation Effects 0.000 claims abstract description 29
- 230000009471 action Effects 0.000 claims abstract description 6
- 239000004922 lacquer Substances 0.000 claims description 50
- 238000005406 washing Methods 0.000 claims description 15
- 239000006096 absorbing agent Substances 0.000 claims description 11
- 239000000049 pigment Substances 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 6
- 239000002966 varnish Substances 0.000 claims description 6
- 230000000007 visual effect Effects 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 4
- 238000011068 loading method Methods 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000012360 testing method Methods 0.000 claims description 3
- 239000000758 substrate Substances 0.000 abstract description 3
- 239000010410 layer Substances 0.000 description 60
- 239000010408 film Substances 0.000 description 16
- 238000010521 absorption reaction Methods 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- 239000003973 paint Substances 0.000 description 11
- 238000000576 coating method Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- 230000002745 absorbent Effects 0.000 description 5
- 239000002250 absorbent Substances 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000003993 interaction Effects 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000005530 etching Methods 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 238000003848 UV Light-Curing Methods 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001227 electron beam curing Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
- B42D25/43—Marking by removal of material
- B42D25/435—Marking by removal of material using electromagnetic radiation, e.g. laser
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/42—Ribbons or strips
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/373—Metallic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
- B42D25/41—Marking using electromagnetic radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
- B42D25/425—Marking by deformation, e.g. embossing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
- B42D25/43—Marking by removal of material
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F3/0291—Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time
- G09F3/0292—Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time tamper indicating labels
-
- B42D2033/10—
-
- B42D2033/24—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/324—Reliefs
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/44—Latent security elements, i.e. detectable or becoming apparent only by use of special verification or tampering devices or methods
- D21H21/48—Elements suited for physical verification, e.g. by irradiation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
Definitions
- the invention relates to a security element with a metallized micro-relief structure and a negative pattern and a method for its preparation.
- Security elements for the purpose of security, which permit verification of the authenticity of the data carrier and at the same time serve as protection against unauthorized reproduction.
- the security elements can be embodied, for example, in the form of a security thread embedded in a banknote, a covering film for a banknote with a hole, an applied security strip or a self-supporting transfer element, which is applied to a document of value after its manufacture.
- the security elements are often provided with negative patterns, such as a so-called negative script. These negative patterns are formed in particular by metal-free regions in an otherwise continuous metallization of the security element.
- WO 99/13157 describes a washing process in which a translucent carrier film is printed with a desired pattern using a high-pigment-content printing ink. Due to the high pigment content, the ink forms a porous, sublime color after drying. A thin cover layer is then formed on the printed carrier film, which in the region of the paint application only partially breaks off the color body due to its large surface and the porous structure. covers. The application of paint and the overlying covering layer can then be removed by washing with a suitable solvent, so that recesses are produced in the covering layer in the originally printed regions of the carrier film.
- By the achievable sharp contours can be introduced by printing a logo, for example, a legible negative writing in the cover layer.
- Metallized holograms, holographic grating images and other hologram-like diffraction patterns can also be provided with a negative pattern by means of such a washing process or by printing a resist mask on the hologram metallization and a subsequent etching step.
- a washing process or by printing a resist mask on the hologram metallization and a subsequent etching step.
- the object of the invention is to avoid the disadvantages of the prior art and, in particular, to specify a method for producing a security element having a metallized microrelief structure and a negative pattern matched thereto and a correspondingly produced security element.
- the desired microrelief structure is introduced into the first regions of the embossed structure
- the second regions of the embossed structure are formed in the form of the desired negative pattern
- the metallized embossing structure is exposed to laser radiation in order to selectively remove the metallization in the second regions of the embossed structure by the action of the laser radiation.
- the microrelief structure of the security element can in particular represent a diffractive structure, such as a hologram, a holographic grating image or a hologram-like diffraction structure, or else an achromatic structure, such as a matt structure with a non-colored, typically silvery-matt appearance, a blaze grating with a sawtooth groove profile or Fresnellinsen- arrangement.
- the dimensions of the structural elements of the diffractive microrelief structures are usually in the order of magnitude of the light wavelength, that is to say generally between 300 nm and 1 ⁇ m.
- Some microrelief structures also have smaller structural elements, such as sub-wavelength gratings or moth eye structures, whose structural elements may also be smaller than 100 nm.
- the microrelief structure is introduced in step P) into first, recessed areas with a low level height, and the negative pattern is formed by second, raised areas with a large level height.
- a cover layer which absorbs laser radiation is preferably applied to the metallized embossed structure, which fills the depressions of the embossed structure.
- the laser-absorbing cover layer is expediently removed from the raised regions of the metallized embossed structure, in particular scraped off or wiped off.
- a technically unavoidable, thin Tonungsfilm the laser beam absorbing cover layer remain on the raised areas of the metallized embossed structure.
- such a tinting film can surprisingly even support and promote the desired demetallization of the raised areas.
- the cover layer material can be applied to suitable embossed coating substrates. Straten predominantly in the wells and a thin Tonungsfilm remains on the raised areas.
- the laser-absorbing cover layer advantageously contains laser-beam-absorbing pigments or dyes.
- laser-beam-absorbing pigments or dyes for laser radiation in the near infrared, for example, carbon black pigments, antimony / tin-based infrared absorbers, or even magnetic pigments, for example based on iron oxides, are suitable.
- the latter in addition to the absorption effect which is important for the production, additionally serve as feature substances for automatic authenticity testing of the finished security element are suitable.
- the concentration of the pigments is between about 1% and about 65%, typically in the range of about 15%, depending on the nature of the pigment.
- the laser beam-absorbing cover layer can also consist of a material which is decomposed by the action of the laser radiation and thereby consumes the incident laser energy.
- cover layers based on polymethyl methacrylates in question which can be thermally depolymerized.
- a concrete facing material may consist of a mixture of 25% Degalan M345 (Degussa), 74% ethyl acetate and 1% of an infrared absorber such as carbon black.
- the laser-absorbing cover layer advantageously contains a binder of high temperature resistance.
- a high-temperature-resistant UV lacquer provided with an absorber can be applied as a laser-beam-absorbing cover layer.
- High-temperature UV coatings often contain novolac-modified epoxy acrylates, such as the Ebecryl 639 and Ebecryl 629 coating raw materials offered by Cytec, or the Craynor CN112C60 coating material offered by CrayValley. It is, however, in particular from the electronics sector, also high-temperature resistant coatings known that do not need this component.
- a high-temperature-resistant, radiation-curing lacquer UV curing or electron beam curing
- other substances such as photoinitiators or reaction diluents for adjusting the viscosity, in addition to the aforementioned or other lacquer raw materials.
- the high-temperature-resistant lacquer for adjusting its absorption characteristics as an absorber may contain suitable dyes and / or pigments.
- the laser-absorbing cover layer has a high thermal conductivity and / or a high heat capacity, since the resulting heat can then be dissipated quickly from the applied points, or at moderate temperature increase, a large amount of heat can be absorbed.
- the laser-absorbing cover layer can be removed after the demetallization step, for example washed out, or it can remain in the security element and be advantageously integrated into the design of the security element.
- the cover layer may in particular also contain a feature substance for the visual and / or mechanical authenticity check of the security element.
- step L) in this variant of the invention expediently takes place from the metallized front side of the embossed structure.
- the loading of the metallized embossed structure with laser radiation in step L) is expediently carried out in this variant of the invention from the rear side of the embossed structure facing away from the metallization.
- the embossed structure can be formed with a laser-beam-embossing embossing lacquer.
- laser-absorbing additives are added to the embossing lacquer prior to application to the carrier.
- Such additives advantageously have a feature substance for the visual and / or mechanical authenticity check of the security element.
- the embossing structure for demetallization can be exposed to an infrared laser in the wavelength range from 0.8 ⁇ m to 3 ⁇ m, in particular with an Nd: Y AG laser.
- the energy density required for demetallization depends on the metal used, the applied layer thickness and the absorption of the cover layer or the embossing lacquer.
- the laser intensity is preferably as uniform as possible over the irradiated area, which can be achieved for example by beam shaping of the laser beam profile, in particular by a so-called top hat profile with a substantially rectangular laser beam profile.
- the coated carrier contains areas in which control marks for the system control are present.
- These tax stamps can also be arranged outside the actual embossed motifs. They can advantageously be demetallised separately with a washing process in which, prior to the metallizing step M), a soluble washing color in the form of the desired recesses in the abovementioned is printed rich, and the washing color after the metallization step M) is washed off in the region of the recesses together with the present there metallization by a solvent. Further details of such a washing process can be found in the publication WO 99/13157, the disclosure of which is incorporated in the present application in this respect. A separate demetallization with such a washing process also lends itself to cleanly and reliably demetallize the area of the weld of the tools used to emboss the embossed structure.
- the invention also includes a security element for security papers, documents of value and the like having a metallized microrelief structure and a matched negative pattern producible in the manner described and having an embossment pattern with embossments and depressions comprising first and second regions having different first and second level heights form, wherein the metallized microrelief structure is present in the first regions of the embossed structure and the negative pattern is present in the second regions of the embossed structure.
- the security element may in particular be a security thread, a security band, a security strip, a patch or a label for application to a security paper, value document or the like.
- the invention further comprises a data carrier, in particular a branded article, a value document or the like, with a security element of the type described.
- FIG. 1 is a schematic representation of a banknote with a hologram security thread according to an embodiment of the invention
- Fig. 2 shows schematically a cross section through the security thread of
- FIG. 4 in (a) to (c) intermediate steps in the manufacture of a security element according to a further embodiment of the invention.
- FIG. 1 shows a schematic representation of a banknote 10 provided with a hologram security thread 12 according to the invention.
- the hologram security thread 12 has a metallized hologram region 14 which is provided with a negative writing 16 which forms the numerical sequence "20" in the exemplary embodiment.
- the negative information 16 is exactly matched with the embossed relief structures of the hologram 14 and with the hologram metallization.
- the invention is not limited to hologram security threads and banknotes, but can be used in all types of security elements, such as labels for goods and packaging or in the security of documents, ID cards, passports, credit cards, health cards and the same.
- transfer elements may be considered in addition to security threads.
- the security thread 12 has a carrier film 20 which is provided on its upper side with a UV-curing embossing layer 22.
- the embossing lacquer layer 22 contains an embossed structure with elevations 24 and depressions 26, the depressions 26 additionally having a microrelief structure 28 in the form of the hologram 14 to be represented and a hologram metallization 30, for example of aluminum.
- the elevations 24 are neither provided with a microrelief embossing nor with a metallization and therefore form a negative pattern 16 within the hologram region 14, which is precisely matched both to the microrelief embossing 28 and to the hologram metallization 30.
- the elevations and depressions of the embossed structure are always shown as rectangular structures with only two height levels for the sake of clarity. It is understood, however, that the elevations and depressions in the general case can also be provided with oblique flanks, with rounded transitions and / or with additional structures. Also, only the embossed structure and the layers necessary for the explanation are always shown and other elements of the structure, such as carrier foils, adhesive and protective layers, either shown only schematically or omitted altogether.
- embossing structure 22 is embossed with embossments 24 and depressions 26 into embossing lacquer layer 22, so that first regions 24 having a high level hi and second regions 26 having a low height h 2 are formed.
- the recessed, second regions 26 of the embossed structure are additionally provided with a microrelief structure 28 in the form of the hologram 14 to be displayed, while the raised first regions 24 are in the form of the desired negative pattern 16.
- the embossed structure 24, 26, 28 is coated over its entire surface with a metallization 30, as shown in Fig. 3 (b).
- a metallization 30 for example, aluminum, chromium, copper or silver can be used.
- a multilayer structure which contains a metal layer, such as a color-shifting thin-film element.
- a thin-film element typically has a metallic reflection layer, for example of aluminum, a dielectric spacer layer, for example of SiO 2, and a thin absorber layer, for example of chromium.
- a thin-layer element which, due to an absorption maximum lying in the region of the laser wavelength of the demetallizing laser used, are easily demagnetized. can be tallinstrument.
- Such thin-film elements are described in detail in WO 97/31774, the disclosure content of which is incorporated into the present application.
- the metallized embossed structure is coated over its entire surface with a laser-beam-absorbing lacquer which fills the depressions 26 of the embossed structure.
- the applied paint is doctored from the surface of the embossed structure, rolled or wiped, with a technically unavoidable, thin Tonungsfilm 34 usually remains on the elevations 24 of the embossed structure.
- this process step results in a metallized embossing structure having a lacquer coating 32 which completely fills the depressions 26 of the embossing structure and which is present on the elevations 24 in a thin toning film 34, as shown in FIG. 3 (c).
- the metallized and lacquer-coated embossing structure is exposed to laser radiation 36 over its entire surface.
- the laser-beam-absorbing lacquer and the laser parameters are matched to one another in such a way that a sufficient interaction between the laser radiation and the lacquer results for the demetallization.
- This interaction consists in particular in the absorption of the laser radiation by pigments or dyes present in the lacquer.
- an infrared laser for example a Nd: YAG laser with a wavelength of 1064 nm, can be used for the laser irradiation.
- the laser intensity is ideally uniform over the irradiated area, for example in the form of a substantially cylindrical so-called top-hat profile.
- the energy density that can be achieved depends on the material and the thickness of the metallization 30 and the absorption of the lacquer layer 32 and can be, for example, 1.5 kJ / m 2 for the demetallization of a 40 nm thick aluminum layer 30.
- a UV varnish of high temperature resistance is used as the laser-beam-absorbing varnish 32, in which an infrared absorber having an absorption maximum in the near infrared is dispersed.
- the laser radiation 36 on the lacquer-coated metallization 30 the raised areas 24 are demetallized, while the metallization in the recessed areas 26 is retained.
- a partially metallized embossed structure is obtained in which the metallized microrelief structures 28, 30 of the indentations 26 are perfectly matched with the negative patterns of the protuberances 24, as shown in FIG. 3 (i.e. ).
- the laser radiation is absorbed there by the metallization without attenuation and leads at suitably selected laser parameters for evaporation, oxidation or other removal of the metallization 30 of the elevations 24.
- a thin Tonungsfilm 34 can even lead to an increased energy input by the higher absorption of the infrared absorber of the paint 32 compared to the bare metal 30 and thereby promote the demetallization of the elevations 24.
- novolac-modified epoxy resin acrylates can contain high-temperature-resistant UV lacquers, even though this constituent does not necessarily have to be present in modern lacquer developments.
- the lacquer 32 also preferably has a high thermal conductivity and / or a high heat capacity in order to be able to dissipate and absorb the heat arising at the metallization of the microrelief structure 28. In the sublime areas 24, where the
- the above-described advantageous effect of the thin toning film can in principle also be achieved by applying a thin metal layer, in particular a thin chromium layer.
- a thin metal layer in particular a thin chromium layer.
- the person skilled in suitable processes for applying a thin metal layer described above are known, so will not be discussed further here.
- the above-described embodiment achieves a similar effect as a thin toning film remaining there by using thin metal layers in the areas to be demetallised. At present, however, the embodiments with demetalization-facilitating thin metal layers, particularly chromium layers, are not preferred.
- infrared absorber various pigments or dyes known per se to those skilled in the art can be used.
- the proportion of pigments in the absorbent paint is generally between 1% and 65%, typically about 10% to 20%.
- the absorbent lacquer layer may be removed after demetallization, such as shown in the embodiment of FIG. However, it is also possible to leave the lacquer layer in the layer structure after demetallization and, if appropriate, to integrate it into the appearance of the security element. This is useful, for example, when the security element is designed to be viewed from the rear side, that is to say the side of the carrier film.
- the binder of the paint layer with regard to its solubility also selected according to whether a subsequent removal of the lacquer layer is provided or not.
- the laser-beam-absorbing lacquer layer 32 may also be selected such that it is decomposed by the absorbed laser radiation and thereby largely consumes the irradiated laser energy in regions of large layer thickness, so that there the demetallization wave for the covered metal layer 30 is not there more is exceeded.
- the varnish 32 in this variant can be constructed from polymethyl methacrylates which can be thermally depolymerized. When the laser is applied, the depolymerization and the evaporation of the lacquer layer endothermic and consume the irradiated laser energy. In the regions of large layer thickness, such as the depressions 26, such a lacquer layer therefore protects the underlying metallization 30, while in the raised regions 24, which have no or only a thin lacquer layer 34, a demetallization takes place.
- the laser wavelength of the demetallization laser and the embossing lacquer used to produce the embossed structure are matched to one another in such a way that an interaction between embossing lacquer and laser radiation arises in the abovementioned sense.
- a laser wavelength can be selected for the demetallization, in which the embossing lacquer used absorbs, or the embossing lacquer can be intentionally mixed with an absorber for a desired laser wavelength.
- an embossing lacquer of high temperature resistance can be selected, which absorbs the heat generated in the embossing lacquer or on the metallization well and can dissipate quickly.
- the embossing lacquer 42 is applied to a carrier foil 20 and embossed in the form of an embossed structure with protrusions 44 and depressions 46, so that first regions 44 with a high level height hi and second regions 46 with a low level height I12 arise.
- the raised, first regions 44 of the embossed structure are provided with a microrelief structure 48 in the form of the hologram 14 to be displayed, while the recessed, second regions 46 are in the form of the desired negative pattern 16.
- the embossing structure 44, 46, 48 is subsequently coated over its entire surface with a metallization 50, and the metallized embossing structure is exposed to laser radiation 52 over its entire surface from the rear side.
- the carrier foil 20 must be transparent to the laser wavelength for this purpose, or that the layer sequence is transferred to another material before the demetallization and the carrier foil 20 is pulled off.
- the embossing lacquer 42 in this process variant itself acts as an exposure mask: In the region of the elevations 44, the embossing lacquer lies in a large layer thickness between the incident laser radiation 52 and metallization 50, so that the laser radiation there, analogous to the above-described case of a lacquer layer present in the depressions 26 , in the embossing lacquer layer 42 to a large extent or even completely absorbed and the resulting heat in the volume of the survey 44 is distributed. A demean Metallization of the present on the elevations 44 metal layer 50 is thereby effectively suppressed.
- the incident laser energy reaches substantially unattenuated or even through the absorption of the embossing lacquer intensifies the metal layer 50 present there and leads to its demetallization. It is important to ensure that the embossment 46 reaches so low, so the level height h2 is chosen small enough that the absorbed laser energy exceeds the demetallization threshold in the recesses 46.
- a metallized hologram 44, 50 is also produced in this variant with a perfectly adjusted negative information 46, wherein the role of the raised or recessed areas compared with the embodiment of Figures 2 and 3 is just the opposite.
- the laser-absorbing lacquer used in the design of FIGS. 2 and 3 may also be provided with additional features and may contain, for example, magnetic, electrically conductive, thermochromic, phosphorescent, fluorescent or other luminescent feature substances.
- the additional feature may also lie only in a desired color of the paint.
- Feature substances can have a function both during demetallization, for example as an absorber, and later as an authenticity feature in the finished security element.
- the mask can be washed out with suitable solvents or even aqueous, which opens up further possible combinations.
- demetallized areas can be generated in a first step, the shape and position of which are predetermined in the manner explained above by the elevations or depressions of the embossed structure.
- other areas For example, be demetallized from the opposite side by laser irradiation, or the soluble paint can be removed, a resist mask printed and then demetallized again.
- a combination of the method described above with further demetallization methods can in particular bring about advantages outside the actual motifs, for example in order to reliably demetallize the regions at the weld of embossing tools or regions of control marks which may also lie outside the embossing region of the motifs.
- the method according to the invention can be combined with all methods known for demetallization, in particular with demetallization by etching. In such etching demetallization, a resist in the form of a desired motif is generally produced on the metallization and those areas of the metallization which are not covered by the resist are removed by a suitable etchant. Further details of demetallization by means of etching are known to the person skilled in the art.
- control marks can be coated with a washing ink already after the embossing even before the lacquer coating of the main surface of the embossed structure and can be washed free after the metallization in order to immediately expose the elements which are important for the system control. Details of a usable washing process can be found in the document WO 99/13157, the disclosure of which is incorporated in the present application in this respect.
- a separate demetallization by a washing process can also be advantageous in the area of the weld of embossing tools since the topography is often determined there by undesired deposits and then a poorly defined layer thickness is produced when coating with laser-absorbing lacquer.
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- Engineering & Computer Science (AREA)
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- Health & Medical Sciences (AREA)
- Electromagnetism (AREA)
- General Health & Medical Sciences (AREA)
- Theoretical Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Business, Economics & Management (AREA)
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Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE102008008685A DE102008008685A1 (en) | 2008-02-12 | 2008-02-12 | Security element and method for its production |
PCT/EP2009/000882 WO2009100869A2 (en) | 2008-02-12 | 2009-02-09 | Security element and method for producing the same |
Publications (2)
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EP2242657A2 true EP2242657A2 (en) | 2010-10-27 |
EP2242657B1 EP2242657B1 (en) | 2011-09-28 |
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EP09711080A Active EP2242657B1 (en) | 2008-02-12 | 2009-02-09 | Security element and method for producing the same |
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US (1) | US8534709B2 (en) |
EP (1) | EP2242657B1 (en) |
AT (1) | ATE526457T1 (en) |
DE (1) | DE102008008685A1 (en) |
WO (1) | WO2009100869A2 (en) |
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2008
- 2008-02-12 DE DE102008008685A patent/DE102008008685A1/en not_active Withdrawn
-
2009
- 2009-02-09 US US12/865,461 patent/US8534709B2/en not_active Expired - Fee Related
- 2009-02-09 WO PCT/EP2009/000882 patent/WO2009100869A2/en active Application Filing
- 2009-02-09 EP EP09711080A patent/EP2242657B1/en active Active
- 2009-02-09 AT AT09711080T patent/ATE526457T1/en active
Non-Patent Citations (1)
Title |
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See references of WO2009100869A2 * |
Also Published As
Publication number | Publication date |
---|---|
WO2009100869A3 (en) | 2009-10-29 |
WO2009100869A2 (en) | 2009-08-20 |
US8534709B2 (en) | 2013-09-17 |
US20100320742A1 (en) | 2010-12-23 |
DE102008008685A1 (en) | 2009-08-13 |
EP2242657B1 (en) | 2011-09-28 |
ATE526457T1 (en) | 2011-10-15 |
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