EP2723578B1 - Security element, method for the manufactur thereof, and use therof - Google Patents
Security element, method for the manufactur thereof, and use therof Download PDFInfo
- Publication number
- EP2723578B1 EP2723578B1 EP12730800.5A EP12730800A EP2723578B1 EP 2723578 B1 EP2723578 B1 EP 2723578B1 EP 12730800 A EP12730800 A EP 12730800A EP 2723578 B1 EP2723578 B1 EP 2723578B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- security element
- absorption
- pigments
- laser
- infrared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
- 238000000034 method Methods 0.000 title claims description 14
- 238000010521 absorption reaction Methods 0.000 claims description 82
- 239000000049 pigment Substances 0.000 claims description 68
- 230000003595 spectral effect Effects 0.000 claims description 53
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 21
- 230000005855 radiation Effects 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 6
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 229910052681 coesite Inorganic materials 0.000 claims 2
- 229910052593 corundum Inorganic materials 0.000 claims 2
- 229910052906 cristobalite Inorganic materials 0.000 claims 2
- 229910052682 stishovite Inorganic materials 0.000 claims 2
- 229910052905 tridymite Inorganic materials 0.000 claims 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 2
- 230000000694 effects Effects 0.000 description 10
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 8
- 229910010413 TiO 2 Inorganic materials 0.000 description 7
- 229910052737 gold Inorganic materials 0.000 description 6
- 239000010931 gold Substances 0.000 description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 238000012795 verification Methods 0.000 description 4
- 239000003086 colorant Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 229910001566 austenite Inorganic materials 0.000 description 2
- 238000005282 brightening Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000004677 hydrates Chemical class 0.000 description 2
- 230000033001 locomotion Effects 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- JZQOJFLIJNRDHK-CMDGGOBGSA-N alpha-irone Chemical compound CC1CC=C(C)C(\C=C\C(C)=O)C1(C)C JZQOJFLIJNRDHK-CMDGGOBGSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000005539 carbonized material Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000010330 laser marking Methods 0.000 description 1
- 238000013532 laser treatment Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- -1 metal oxide hydrates Chemical class 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000001392 ultraviolet--visible--near infrared spectroscopy Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
- B42D25/382—Special inks absorbing or reflecting infrared light
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/24—Ablative recording, e.g. by burning marks; Spark recording
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
- B42D25/41—Marking using electromagnetic radiation
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
- G07D7/06—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using wave or particle radiation
- G07D7/12—Visible light, infrared or ultraviolet radiation
- G07D7/1205—Testing spectral properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
- B41M3/148—Transitory images, i.e. images only visible from certain viewing angles
-
- B42D2033/20—
-
- B42D2035/24—
Definitions
- the document describes WO 2007/110155 A1 a data carrier with markings, which are preferably not visible in the visible spectral range, but can be detected by machine only in the near infrared with corresponding detectors.
- either the visible marking or the machine-readable marking usually stands in the foreground, while the respective other aspect is perceived as disturbing.
- the machine-readable Markers are therefore often laminated or hidden optically, while the visually recognizable markings typically do not have sufficient machine-readable properties for secure detection.
- document DE 10 2010 009 977 A1 discloses a method according to the preamble of claim 1.
- the present invention seeks to provide a security element of the type mentioned above, on the one hand offers an attractive visual appearance and its identification on the other hand not only visually, but also mechanically detected safely.
- a first aspect of the invention relates to a method according to claim 1.
- the magnetic pigments are magnetically aligned after the step of applying the color layer to the substrate in the form of a motif, in particular in the form of patterns, characters or an encoding.
- the laser application is carried out with a pulsed infrared laser in the wavelength range of 0.8 microns to 3 microns, preferably with short pulse durations of 25 ns or less, more preferably from 8 to 18 ns.
- a second aspect of the invention relates to a security element according to claim 6.
- a third aspect of the invention relates to a use of the security element according to the second aspect of the invention for the authenticity verification of valuables by detecting the infrared absorption of the security element in the area of the marking.
- a fourth aspect of the invention relates to a method for authenticity verification of valuables equipped with the security element according to the second aspect of the invention, the method comprising a step of detecting the infrared absorption of the security element in the region of the marking.
- a generic security element has a covering ink layer and an introduced into the ink layer by the action of laser radiation marking in the form of patterns, characters or a coding that is both visually and mechanically detectable.
- the color layer in the background area located outside the marking contains multilayer pigments which, for example, may have a uniform color substantially independent of the viewing angle.
- the multilayered pigments may include an inner layer having a first infrared absorption and at least one inner layer covering outer layer having a second infrared absorption, wherein the first infrared absorption is greater than the second infrared absorption.
- the outer layer of the multilayer pigments is at least partially ablated or removed. The marking is brighter in the visible spectral range than the background range and thereby visually detectable, while the marking in the infrared spectral range has a greater absorption than the background area and is thus mechanically detectable.
- the inner layer may, for example, be magnetic and based on Fe 3 O 4 , gamma iron oxide or maghemite, with alkaline earth oxide, in particular MgO, doped gamma iron oxide, Co-containing gamma iron oxide, Co-containing Fe 3 O 4 or CrO 2 .
- the carrier of the pigments themselves constitutes the inner layer of high infrared absorption, the carrier itself may be magnetic and be formed, for example, on the basis of Fe 2 O 3 .
- the outer layer of the multi-layered pigment consists for example of MgO or TiO 2 , wherein in principle also other materials with high infrared remission come into question, as used for example for solar heat reflection.
- the inner layer can advantageously also be formed on the basis of antimony-doped tin oxide. Also TiO 2 / carbon black mixtures or Rußein gleich füren with high infrared absorption come into consideration for the inner layer.
- the multilayer pigments used according to the invention may alternatively have a carrier with a coating applied above the carrier, wherein the coating has a first constituent with a first infrared absorption and a second component having second infrared absorption ablatable by the action of laser radiation, and the first infrared absorption is greater than the second infrared absorption.
- the first component may be in the form of a matrix in which the second component is embedded, or vice versa.
- first infrared absorption is suitably more than 1.25 times, preferably more than 2 times, more preferably more than 5 times, and most preferably more than 8 times as large as the aforementioned "second infrared absorption".
- infrared absorption suitably refers to a wavelength range of 800 to 1400 nm, preferably 800 to 1200 nm, and more preferably 800 to 1050 nm.
- the magnetic pigments in particular have a support and a layer applied to the support, wherein the support of Al 2 O 3 , Al 2 O 3 with up to 5 wt .-% TiO 2 , SiO 2 , SiO 2 with up to 20 wt. -% silicon hydroxide, glass or borosilicate is selected and the layer gamma-iron oxide, which is doped with at least one alkaline earth metal oxide, preferably MgO, contains.
- the proportion of the alkaline earth metal is for example 0.01 to 2 wt .-%, in particular 0.1 to 1 wt .-%, based on the total pigment.
- the layer applied on the carrier may consist exclusively of the gamma-iron oxide doped with alkaline-earth metal oxide, in particular MgO.
- the gamma iron oxide may also contain other iron compounds, for example Fe 3 O 4 or alpha iron oxide. The last two compounds are in the gamma-iron oxide layer, individually or in combination, preferably in a proportion of at most 25 wt .-% based on the gamma-iron oxide.
- a dielectric layer may be arranged above the gamma-iron oxide-deposited layer on the carrier.
- the dielectric layer may for example be based on metal oxides or metal oxide hydrates or mixtures thereof, in particular oxides or hydrates of Ti, Zr, Zn, Sn, Ce, Si and Al, such as titanium dioxide, zirconium oxide, zinc oxide, tin oxide, cerium oxide, silicon dioxide or hydrates thereof ,
- the magnetic pigments described above may advantageously be oriented magnetically in the form of a motif, in particular in the form of patterns, characters or an encoding.
- a motif resulting from a magnetic alignment may be independent of the laser-generated marking or interact with it.
- the tag may form a static reference point for a dynamic motion effect of the magnetic motif.
- multilayer magnetic pigments can also be used without magnetic alignment of the pigments.
- the multilayer pigments used according to the invention are preferably not optically variable, ie they preferably exhibit a uniform color substantially independent of the viewing angle.
- the pigments can show shiny metallic colors, in particular gold, copper or bronze tones.
- Such pigments are for example in the WO 2010/149266 A1 disclosed.
- the effects according to the invention also occur even when the color layer, in addition to the multilayer pigments and a binder, contains not too large a proportion of optically variable pigments.
- the color layer in addition to the binder, contains 75% to 100% of the described non-optically variable, multi-layered pigments and from 25% to 0% optically variable pigments.
- the laser application is carried out with a pulsed infrared laser in the wavelength range of 0.8 .mu.m to 3 .mu.m, preferably with short pulse durations of 25 ns or less, in particular from 8 to 18 ns.
- FIG. 1 shows a schematic representation of a banknote 10 with a printed directly on the banknote paper security element 12th
- the peculiarity of the security element 12 is particularly evident in the infrared spectral range.
- the label 18 in the infrared spectral region has a significantly higher absorption than the background region 16 and is thereby easily and reliably detectable by machine, for example with an infrared sensor 22 sensitive at a wavelength of 850 nm.
- a first effect typically occurs in the visible and infrared spectral regions relatively strongly absorbing ink layers.
- the absorption 30 of such a color layer in the visible spectral range (VIS) and its absorption 32 in the infrared spectral range (IR) are shown schematically. If such a color layer is irradiated with pulsed laser radiation of sufficient intensity, the color layer is locally destroyed or desorbed by the laser radiation so that the substrate or an underlying printing layer becomes visible.
- the absorption by the color layer in the lasered region generally decreases both in the visible spectral range 34 and in the infrared spectral range 36, resulting in a bright identification with reduced IR absorption, as in the right half of FIG Fig. 3 shown schematically.
- the size of the absorption before the laser application is shown with dashed lines for easier orientation.
- Some colors also show a virtually unchanged absorption in the visible spectral range and a reduced absorption only in the infrared spectral range. Such colors are described, for example, in the document WO 2007/110155 A1 in connection with the local FIG. 3 described. They are well suited for generating machine-readable encodings whose existence is hidden in the visible spectral range.
- the carbonized material absorbs in a broadband manner, the change in absorbance in the visible spectral region 44 and in the infrared spectral region 46 is usually the same and a visually black high infrared absorption label is produced as in the right half of FIG Fig. 4 shown schematically.
- the behavior of the ink layer of the invention 14 In contrast to these two conventional effects is the behavior of the ink layer of the invention 14.
- the absorption 50 of the color layer in the visible spectral range (VIS) and the absorption 52 in the infrared spectral range (IR) is shown.
- VIS visible spectral range
- IR infrared spectral range
- a color layer 14 according to the invention is irradiated with pulsed laser radiation of suitable intensity, a brightening results locally, ie a lower absorption 54 in the visible spectral range, while at the same time a high absorption 56 is produced in the infrared spectral range, as in the right half of FIG Fig. 5 shown.
- the visually visible, bright mark 18 is set in this way a machine-readable mark with very clear and thus easily detectable infrared contrast. In this way, a multi-level authenticity feature is created, on the one hand due to its light color and the partial preservation of the starting color of the ink layer 14 a Visually attractive appearance and on the other hand, both for the layman easy to identify, as well as mechanically proven to prove.
- the ink layer 14 contains multi-layered pigments 60 having a uniform color independent of the viewing angle.
- the pigments 60 are gold-colored and comprise a carrier 62, for example made of Al 2 O 3 , which is coated with an inner layer 64, for example of gamma-iron oxide, and an outer layer 66, for example of MgO.
- the inner layer 64 has a higher, for example by a factor of 4, higher infrared absorption than the outer layer 66.
- the effect used for the invention may be due to the laser radiation partially or even completely ablating or removing the outer MgO layer 66.
- the inner layer 64 is destroyed in addition to the outer layer 66 and there is a reduced absorption both in the visible and in the infrared spectral range, as described above Fig. 3 already described.
- the inner and outer layers 64, 66 need not extend beyond the edge 68 of the pigment, the inner ones and outer layers may instead be deposited separately on the opposite major surfaces of the core 62.
- Fig. 7 The dependence of the absorption A on the exposure intensity I in the visible spectral range and in the infrared spectral range is in Fig. 7 shown schematically. While the absorption 70 decreases in the visible spectral range with increasing exposure intensity, the absorption 72 in the infrared spectral range according to the model described above due to the exposure of the inner layer 64 first increases, and then decrease with increasing destruction of the gamma-iron oxide layer, with a Exposure intensity 74 reaches a reduced absorption in both spectral ranges and thus a situation as in Fig. 3 is generated.
- the intensity range which is preferred according to the invention, in which simultaneously a reduced absorption in the visible spectral range and an increased absorption in the infrared spectral range are obtainable, is indicated in the figure by the reference numeral 76.
- the absolute values of the preferred intensity range depend on the one hand on the pigment 60 used and on the other on the other laser parameters, in particular on the laser wavelength, the pulse duration, the repetition frequency and the speed with which the laser beam is passed over the ink layer during the marking.
- Suitable absolute values for the intensity to be used according to the invention can be determined in the case of the known basic course of the invention Fig. 7 however, can be determined experimentally by a person skilled in the art for a specific parameter set and a specific pigment 60 by a few experiments.
- the multilayer pigments used according to the invention may in particular be magnetic pigments which, in addition to the described effect, may be aligned by an external magnetic field in the form of a desired motif.
- the magnetic pigments are admixed, for example, with a UV-curing lacquer which is screen-printed with the contained magnetic pigments onto the target substrate.
- the target substrate with the still-movable magnetic pigments is placed in a magnetic field of a desired field distribution and the pigments thereby aligned.
- the aligned magnetic pigments are now permanently fixed in their orientation by curing the UV varnish.
- Safety elements with magnetic motifs oriented in the form of a motif show the viewer an effective, three-dimensionally arunutendes appearance with a dynamic movement effect when tilting the security element, which is combined with the static marking described above.
- the resulting ink layer 14 then has a uniform appearance except for the label 18, as in Fig. 2 (a) illustrated.
- FIG. 8 shows for illustration a two-layered pigment 80 with a core 82 of gamma-Fe 2 O 3 and a shell 84 of TiO 2 .
- the core 82 represents an inner layer which has a significantly higher, for example a factor of 3, infrared absorption than the outer TiO 2 shell 84.
- the pigments shown are also the multilayer pigments in question, which in the WO 2010/149266 A1 are disclosed. These include, for example, an Al 2 O 3 support and a MgO-doped layer of gamma-iron oxide applied above the support.
- Fig. 9 shows the measured VIS / IR remissions of three inventive, laser-treated security elements.
- security elements in each case so-called magnetic gold pigments ("magnetic gold", in Fig. 9 also referred to as "M-gold") with an Al 2 O 3 support and a MgO-doped layer of gamma-iron oxide applied above the support.
- M-gold magnetic gold pigments
- the proportion of alkaline earth metal is about 1 wt .-% based on the pigment.
- the three security elements were each treated with a different laser energy.
- Fig. 9 shows the measured VIS / IR remissions of three inventive, laser-treated security elements.
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- Spectroscopy & Molecular Physics (AREA)
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Description
Die Erfindung betrifft ein Sicherheitselement zur Absicherung von Wertgegenständen mit einer deckenden Farbschicht und einer in die Farbschicht durch Einwirkung von Laserstrahlung eingebrachten Kennzeichnung in Form von Mustern, Zeichen oder einer Codierung.The invention relates to a security element for securing valuables with a covering ink layer and an introduced into the ink layer by the action of laser radiation marking in the form of patterns, characters or a coding.
Datenträger, wie Wert- oder Ausweisdokumente, aber auch andere Wertgegenstände, wie etwa Markenartikel, werden zur Absicherung oft mit Sicherheitselementen versehen, die eine Überprüfung der Echtheit des Datenträgers gestatten und die zugleich als Schutz vor unerlaubter Reproduktion dienen. Die Sicherheitselemente werden dabei beispielsweise mit durch Einwirkung von Laserstrahlung erzeugten Kennzeichnungen versehen, die etwa bei personalisierten Karten als Laserbeschriftung bekannt sind. Auch bei Banknoten oder anderen Wertdokumenten ist eine visuell erkennbare Individualisierung durch Laserbeaufschlagung bekannt.Data carriers, such as valuables or identity documents, but also other valuables, such as branded goods, are often provided with security elements for the purpose of security, which permit verification of the authenticity of the data carrier and at the same time serve as protection against unauthorized reproduction. In this case, the security elements are provided, for example, with identifications produced by the action of laser radiation, which are known as laser inscription in personalized cards, for example. Even with banknotes or other value documents a visually recognizable individualization by laser exposure is known.
Es ist auch bekannt, Sicherheitselemente mit maschinenlesbaren Codierungen zu versehen, die eine automatische Echtheitsprüfung und gegebenenfalls eine weitergehende sensorische Erfassung und Bearbeitung der damit ausgestatteten Dokumente ermöglichen. Beispielsweise beschreibt die Druckschrift
Bei den bekannten Gestaltungen steht in der Regel entweder die sichtbare Markierung oder die maschinenlesbare Markierung im Vordergrund, während der jeweils andere Aspekt als störend empfunden wird. Die maschinenlesbaren Markierungen werden daher vielfach optisch kaschiert oder versteckt, während die visuell erkennbaren Markierungen typischerweise keine für eine sichere Erfassung ausreichenden maschinenlesbaren Eigenschaften aufweisen.In the known designs, either the visible marking or the machine-readable marking usually stands in the foreground, while the respective other aspect is perceived as disturbing. The machine-readable Markers are therefore often laminated or hidden optically, while the visually recognizable markings typically do not have sufficient machine-readable properties for secure detection.
Dokument
Ausgehend davon liegt der Erfindung die Aufgabe zugrunde, ein Sicherheitselement der eingangs genannten Art anzugeben, das einerseits ein attraktives visuelles Erscheinungsbild bietet und dessen Kennzeichnung andererseits nicht nur visuell, sondern auch maschinell sicher erfassbar ist.Proceeding from this, the present invention seeks to provide a security element of the type mentioned above, on the one hand offers an attractive visual appearance and its identification on the other hand not only visually, but also mechanically detected safely.
Diese Aufgabe wird durch das Sicherheitselement mit den Merkmalen gemäß dem unabhängigen Anspruch 6 gelöst. Ein Verfahren zur Herstellung eines derartigen Sicherheitselements, eine Verwendung und ein Verfahren zum Echtheitsnachweis von Wertgegenständen sind jeweils in den unabhängigen Ansprüchen 1, 7 und 8 angegeben. Weiterbildungen der Erfindung sind Gegenstand der Unteransprüche.This object is achieved by the security element having the features according to independent claim 6. A method for producing such a security element, a use and a method for the authenticity verification of valuables are given in the
Ein erster Aspekt der Erfindung betrifft ein Verfahren nach Anspruch 1.A first aspect of the invention relates to a method according to
Die mehrschichtigen Pigmente weisen vorzugsweise eine einheitliche, vom Betrachtungswinkel im Wesentlichen unabhängige Farbe auf.The multilayer pigments preferably have a uniform color substantially independent of the viewing angle.
Die mehrschichtigen Pigmente umfassen beispielsweise einen Träger und eine auf dem Träger aufgebrachte Schicht, die einen ersten Bestandteil mit einer ersten Infrarotabsorption und einen zweiten, durch Einwirkung von Laserstrahlung ablatierbaren Bestandteil mit einer zweiten Infrarotabsorption enthält, wobei die erste Infrarotabsorption größer als die zweite Infrarot-absorption ist. Die erste Infrarotabsorption ist bevorzugt mehr als 1,25 mal, weiter bevorzugt mehr als 2 mal und insbesondere bevorzugt mehr als 5 mal so groß wie die zweite Infrarotabsorption.The multilayered pigments include, for example, a support and a support-applied layer containing a first component having a first infrared absorption and a second laser-ablatable component having a second infrared absorption, wherein the first infrared absorption is greater than the second infrared absorption is. The first infrared absorption is preferably more than 1.25 times, more preferably more than 2 times, and most preferably more than 5 times the size of the second infrared absorption.
Die mehrschichtigen Pigmente sind Magnetpigmente, die einen Träger und eine auf dem Träger aufgebrachte Schicht aufweisen, wobei der Träger von Al2O3, Al2O3 mit bis zu 5 Gew.-% TiO2, SiO2, SiO2 mit bis zu 20 Gew.-% Siliziumhydroxid, Glas oder Borosilicat gewählt ist und die Schicht Eisenoxid, insbesondere gamma-Eisenoxid, das mit mindestens einem Erdalkalimetalloxid, bevorzugt MgO, dotiert ist, enthält.The multilayer pigments are magnetic pigments which have a support and a layer applied to the support, wherein the support of Al 2 O 3 , Al 2 O 3 with up to 5 wt .-% TiO 2 , SiO 2 , SiO 2 with up to 20 wt .-% silicon hydroxide, glass or borosilicate is selected and the layer of iron oxide, in particular gamma-iron oxide, which is doped with at least one alkaline earth metal oxide, preferably MgO, contains.
Es wird bevorzugt, dass die Magnetpigmente nach dem Schritt des Aufbringens der Farbschicht auf das Substrat magnetisch in Form eines Motivs, insbesondere in Form von Mustern, Zeichen oder einer Codierung, ausgerichtet werden.It is preferred that the magnetic pigments are magnetically aligned after the step of applying the color layer to the substrate in the form of a motif, in particular in the form of patterns, characters or an encoding.
Die Farbschicht kann vorzugsweise neben einem Bindemittel zu 75% bis 100% die mehrschichtigen Pigmente mit einer einheitlichen, vom Betrachtungswinkel im Wesentlichen unabhängigen Farbe enthalten, und zu 25% bis 0% optisch variable Pigmente.The ink layer may preferably contain 75% to 100% of a multilayer pigment having a uniform color substantially independent of the viewing angle, and 25% to 0% of optically variable pigments besides a binder.
Die Laserbeaufschlagung erfolgt mit einem gepulsten Infrarotlaser im Wellenlängenbereich von 0,8 µm bis 3 µm, bevorzugt mit kurzen Pulsdauern von 25 ns oder weniger, insbesondere bevorzugt von 8 bis 18 ns.The laser application is carried out with a pulsed infrared laser in the wavelength range of 0.8 microns to 3 microns, preferably with short pulse durations of 25 ns or less, more preferably from 8 to 18 ns.
Ein zweiter Aspekt der Erfindung betrifft ein Sicherheitselement nach Anspruch 6.A second aspect of the invention relates to a security element according to claim 6.
Ein dritter Aspekt der Erfindung betrifft eine Verwendung des Sicherheitselements gemäß dem zweiten Aspekt der Erfindung zum Echtheitsnachweis von Wertgegenständen durch Erfassung der Infrarotabsorption des Sicherheitselements im Bereich der Kennzeichnung.A third aspect of the invention relates to a use of the security element according to the second aspect of the invention for the authenticity verification of valuables by detecting the infrared absorption of the security element in the area of the marking.
Ein vierter Aspekt der Erfindung betrifft ein Verfahren zum Echtheitsnachweis von Wertgegenständen, die mit dem Sicherheitselement gemäß dem zweiten Aspekt der Erfindung ausgestattet sind, wobei das Verfahren einen Schritt des Erfassens der Infrarotabsorption des Sicherheitselements im Bereich der Kennzeichnung umfasst.A fourth aspect of the invention relates to a method for authenticity verification of valuables equipped with the security element according to the second aspect of the invention, the method comprising a step of detecting the infrared absorption of the security element in the region of the marking.
Die Erfindung wird nachstehend anhand von bevorzugten Ausführungsformen beschrieben.The invention will be described below with reference to preferred embodiments.
Gemäß der Erfindung weist ein gattungsgemäßes Sicherheitselement eine deckende Farbschicht auf und eine in die Farbschicht durch Einwirkung von Laserstrahlung eingebrachte Kennzeichnung in Form von Mustern, Zeichen oder einer Codierung, die sowohl visuell als auch maschinell erfassbar ist. Dabei enthält die Farbschicht im außerhalb der Kennzeichnung liegenden Hintergrundbereich mehrschichtige Pigmente, die zum Beispiel eine einheitliche, vom Betrachtungswinkel im Wesentlichen unabhängige Farbe aufweisen können. Die mehrschichtigen Pigmente können beispielsweise eine innere Schicht mit einer ersten Infrarotabsorption und zumindest eine die innere Schicht überdeckende äußere Schicht mit einer zweiten Infrarotabsorption aufweisen, wobei die erste Infrarotabsorption größer als die zweite Infrarotabsorption ist. Weiter ist im Bereich der Kennzeichnung durch die Einwirkung der Laserstrahlung die äußere Schicht der mehrschichtigen Pigmente zumindest teilweise ablatiert bzw. abgetragen. Die Kennzeichnung ist im sichtbaren Spektralbereich heller als der Hintergrundbereich und dadurch visuell erfassbar, während die Kennzeichnung im infraroten Spektralbereich eine größere Absorption als der Hintergrundbereich aufweist und dadurch maschinell erfassbar ist.According to the invention, a generic security element has a covering ink layer and an introduced into the ink layer by the action of laser radiation marking in the form of patterns, characters or a coding that is both visually and mechanically detectable. In this case, the color layer in the background area located outside the marking contains multilayer pigments which, for example, may have a uniform color substantially independent of the viewing angle. For example, the multilayered pigments may include an inner layer having a first infrared absorption and at least one inner layer covering outer layer having a second infrared absorption, wherein the first infrared absorption is greater than the second infrared absorption. Furthermore, in the area of the marking by the action of the laser radiation, the outer layer of the multilayer pigments is at least partially ablated or removed. The marking is brighter in the visible spectral range than the background range and thereby visually detectable, while the marking in the infrared spectral range has a greater absorption than the background area and is thus mechanically detectable.
Die im vorangehenden Absatz beschriebenen mehrschichtigen Pigmente weisen einen Träger, insbesondere einen Träger aus Glimmer, Al2O3, Borosilikat oder Siliziumdioxid, auf dem die zumindest eine innere Schicht und die zumindest eine äußere Schicht aufgebracht sind, auf. Alternativ kann auch der Träger selbst die innere Schicht hoher Infrarotabsorption darstellen und von einer äußeren Schicht niedrigerer Infrarotabsorption umgeben sein. Die innere Schicht muss nicht zwangsläufig eine lückenlose Hülle für den Träger darstellen. Die mehrschichtigen Pigmente können beispielsweise auch durch einen Träger gebildet sein, der auf seinen gegenüberliegenden Hauptflächen jeweils mit der inneren Schicht beschichtet ist, ohne dass die inneren Schichten am Rand des Trägers miteinander verbunden sind. In gleicher Weise können die inneren Schichten der gegenüberliegenden Hauptflächen jeweils mit der äußeren Schicht beschichtet sein, ohne dass die gegenüberliegenden äußeren Schichten am Rand des Pigments miteinander verbunden sind.The multilayer pigments described in the preceding paragraph comprise a support, in particular a support of mica, Al 2 O 3 , borosilicate or silicon dioxide, on which the at least one inner layer and the at least one outer layer are applied. Alternatively, the support itself may also constitute the inner layer of high infrared absorption and be surrounded by an outer layer of lower infrared absorption. The inner layer does not necessarily have to represent a complete envelope for the wearer. The multilayered pigments may, for example, also be formed by a carrier which is coated on its opposite major surfaces with the inner layer, respectively, without the inner layers being joined to one another at the edge of the carrier. Likewise, the inner layers of the opposed major surfaces may each be coated with the outer layer without interconnecting the opposing outer layers at the edge of the pigment.
Die innere Schicht kann zum Beispiel magnetisch sein und auf Fe3O4, gamma-Eisenoxid bzw. Maghemit, mit Erdalkalioxid, insbesondere MgO, dotiertem gamma Eisenoxid, Co-enthaltendem gamma-Eisenoxid, Coenthaltendem Fe3O4 oder auf CrO2 basieren. Stellt der Träger der Pigmente selbst die innere Schicht hoher Infrarotabsorption dar, kann der Träger selbst magnetisch sein und z.B. auf Fe2O3-Basis gebildet sein.The inner layer may, for example, be magnetic and based on Fe 3 O 4 , gamma iron oxide or maghemite, with alkaline earth oxide, in particular MgO, doped gamma iron oxide, Co-containing gamma iron oxide, Co-containing Fe 3 O 4 or CrO 2 . If the carrier of the pigments themselves constitutes the inner layer of high infrared absorption, the carrier itself may be magnetic and be formed, for example, on the basis of Fe 2 O 3 .
Die äußere Schicht des mehrschichtigen Pigments besteht zum Beispiel aus MgO oder TiO2, wobei grundsätzlich auch andere Materialien mit hoher Infrarot-Remission in Frage kommen, wie sie beispielsweise für die solare Wärmereflexion eingesetzt werden.The outer layer of the multi-layered pigment consists for example of MgO or TiO 2 , wherein in principle also other materials with high infrared remission come into question, as used for example for solar heat reflection.
Bei nichtmagnetischen mehrschichtigen Pigmenten kann die innere Schicht mit Vorteil auch auf Basis von Antimon-dotiertem Zinnoxid gebildet sein. Auch TiO2/Ruß-Mischungen oder Rußeinschlussschichten mit hoher Infrarotabsorption kommen für die innere Schicht in Betracht.In the case of nonmagnetic multilayer pigments, the inner layer can advantageously also be formed on the basis of antimony-doped tin oxide. Also TiO 2 / carbon black mixtures or Rußeinschlussschichten with high infrared absorption come into consideration for the inner layer.
Die erfindungsgemäß eingesetzten mehrschichtigen Pigmente können alternativ einen Träger mit einer oberhalb des Trägers aufgebrachten Beschichtung aufweisen, wobei die Beschichtung einen ersten Bestandteil mit einer ersten Infrarotabsorption und einen durch Einwirkung von Laserstrahlung ablatierbaren zweiten Bestandteil mit einer zweiten Infrarotabsorption enthält, und die erste Infrarotabsorption größer als die zweite Infrarotabsorption ist. Der erste Bestandteil kann zum Beispiel in Form einer Matrix vorliegen, in die der zweite Bestandteil eingebettet ist, oder umgekehrt.The multilayer pigments used according to the invention may alternatively have a carrier with a coating applied above the carrier, wherein the coating has a first constituent with a first infrared absorption and a second component having second infrared absorption ablatable by the action of laser radiation, and the first infrared absorption is greater than the second infrared absorption. For example, the first component may be in the form of a matrix in which the second component is embedded, or vice versa.
Die vorstehend erwähnte "erste Infrarotabsorption" ist zweckmäßig mehr als 1,25 mal, bevorzugt mehr als 2 mal, besonders bevorzugt mehr als 5 mal und insbesondere bevorzugt mehr als 8 mal so groß wie die vorstehend erwähnte "zweite Infrarotabsorption". Der hierin verwendete Begriff "Infrarotabsorption" bezieht sich zweckmäßig auf einen Wellenlängenbereich von 800 bis 1400 nm, bevorzugt 800 bis 1200 nm und insbesondere bevorzugt 800 bis 1050 nm.The above-mentioned "first infrared absorption" is suitably more than 1.25 times, preferably more than 2 times, more preferably more than 5 times, and most preferably more than 8 times as large as the aforementioned "second infrared absorption". The term "infrared absorption" as used herein suitably refers to a wavelength range of 800 to 1400 nm, preferably 800 to 1200 nm, and more preferably 800 to 1050 nm.
In einer vorteilhaften Erfindungsvariante werden als mehrschichtige Pigmente die in der
Die vorstehend beschriebenen Magnetpigmente können mit Vorteil magnetisch in Form eines Motivs, insbesondere in Form von Mustern, Zeichen oder einer Codierung ausgerichtet sein. Ein solches, durch eine magnetische Ausrichtung entstehendes Motiv kann unabhängig von der lasergenerierten Kennzeichnung sein oder mit dieser in Wechselwirkung stehen. Beispielsweise kann die Kennzeichnung einen statischen Bezugspunkt für einen dynamischen Bewegungseffekt des magnetischen Motivs bilden. Im Rahmen der Erfindung können mehrschichtige Magnetpigmente allerdings auch ohne magnetische Ausrichtung der Pigmente eingesetzt werden.The magnetic pigments described above may advantageously be oriented magnetically in the form of a motif, in particular in the form of patterns, characters or an encoding. Such a motif resulting from a magnetic alignment may be independent of the laser-generated marking or interact with it. For example, the tag may form a static reference point for a dynamic motion effect of the magnetic motif. In the context of the invention, however, multilayer magnetic pigments can also be used without magnetic alignment of the pigments.
Die erfindungsgemäß eingesetzten mehrschichtigen Pigmente sind bevorzugt nicht optisch variabel, d.h. sie zeigen bevorzugt eine einheitliche, vom Betrachtungswinkel im Wesentlichen unabhängige Farbe. Insbesondere können die Pigmente metallisch glänzende Farben, insbesondere Gold-, Kupfer- oder Bronzetöne zeigen. Solche Pigmente sind z.B. in der
Die erfindungsgemäßen Effekte treten auch dann noch auf, wenn die Farbschicht neben den mehrschichtigen Pigmenten und einem Bindemittel einen nicht zu großen Anteil optisch variabler Pigmente enthält. Vorzugsweise enthält die Farbschicht neben dem Bindemittel zu 75% bis 100% die beschriebenen, nicht optisch variablen, mehrschichtigen Pigmente und zu 25% bis 0% optisch variable Pigmente.The effects according to the invention also occur even when the color layer, in addition to the multilayer pigments and a binder, contains not too large a proportion of optically variable pigments. Preferably, in addition to the binder, the color layer contains 75% to 100% of the described non-optically variable, multi-layered pigments and from 25% to 0% optically variable pigments.
Bei dem Verfahren zum Herstellen des Sicherheitselements gemäß dem ersten Aspekt der Erfindung erfolgt die Laserbeaufschlagung mit einem gepulsten Infrarotlaser im Wellenlängenbereich von 0,8 µm bis 3 µm, vorzugsweise mit kurzen Pulsdauern von 25 ns oder weniger, insbesondere von 8 bis 18 ns.In the method for producing the security element according to the first aspect of the invention, the laser application is carried out with a pulsed infrared laser in the wavelength range of 0.8 .mu.m to 3 .mu.m, preferably with short pulse durations of 25 ns or less, in particular from 8 to 18 ns.
Weitere Ausführungsbeispiele sowie Vorteile der Erfindung werden nachfolgend anhand der Figuren erläutert, bei deren Darstellung auf eine maßstabs- und proportionsgetreue Wiedergabe verzichtet wurde, um die Anschaulichkeit zu erhöhen.Further exemplary embodiments and advantages of the invention are explained below with reference to the figures, in the representation of which a representation true to scale and proportion has been dispensed with in order to increase the clarity.
Es zeigen:
- Fig. 1
- eine schematische Darstellung einer Banknote mit einem erfindungsgemäßen Sicherheitselement,
- Fig. 2
- das Erscheinungsbild des Sicherheitselements von
Fig. 1 , in a) im sichtbaren Spektralbereich (VIS) und in b) im infraroten Spektralbereich (IR), - Fig. 3
- in der linken Bildhälfte die Absorption einer relativ stark absorbierenden Farbschicht im sichtbaren Spektralbereich (VIS) und im infraroten Spektralbereich (IR), in der rechten Bildhälfte die Absorption der Farbschicht in den beiden Spektralbereichen nach Laserbeaufschlagung,
- Fig. 4
- in der linken Bildhälfte die Absorption einer schwach bis mäßig absorbierenden Farbschicht im sichtbaren Spektralbereich (VIS) und im infraroten Spektralbereich (IR), in der rechten Bildhälfte die Absorption der Farbschicht in den beiden Spektralbereichen nach Laserbeaufschlagung,
- Fig. 5
- in der linken Bildhälfte die Absorption einer erfindungsgemäßen Farbschicht im sichtbaren Spektralbereich (VIS) und im infraroten Spektralbereich (IR), in der rechten Bildhälfte die Absorption der Farbschicht in den beiden Spektralbereichen nach Laserbeaufschlagung,
- Fig. 6
- ein mehrschichtiges Pigment eines erfindungsgemäßen Sicherheitselements,
- Fig. 7
- schematisch die Abhängigkeit der Absorption A von der Belichtungsintensität I im sichtbaren Spektralbereich und im infraroten Spektralbereich bei der Laserbeaufschlagung der Farbschicht eines erfindungsgemäßen Sicherheitselements,
- Fig. 8
- ein zweischichtiges Pigment eines erfindungsgemäßen Sicherheitselements, und
- Fig. 9
- die gemessenen VIS/IR-Remissionen dreier erfindungsgemäßer Sicherheitselemente.
- Fig. 1
- a schematic representation of a banknote with a security element according to the invention,
- Fig. 2
- the appearance of the security element of
Fig. 1 , in a) in the visible spectral range (VIS) and in b) in the infrared spectral range (IR), - Fig. 3
- in the left half of the picture the absorption of a relatively strongly absorbing color layer in the visible spectral range (VIS) and in the infrared spectral range (IR), in the right half the absorption of the color layer in the two spectral ranges after laser application,
- Fig. 4
- in the left half of the image the absorption of a weakly to moderately absorbing color layer in the visible spectral range (VIS) and in the infrared spectral range (IR), in the right half the absorption of the color layer in the two spectral ranges after laser application,
- Fig. 5
- in the left half of the picture the absorption of a color layer according to the invention in the visible spectral range (VIS) and in the infrared spectral range (IR), in the right half the absorption of the color layer in the two spectral ranges after laser application,
- Fig. 6
- a multi-layered pigment of a security element according to the invention,
- Fig. 7
- schematically the dependence of the absorption A on the exposure intensity I in the visible spectral range and in the infrared spectral range on laser exposure of the color layer of a security element according to the invention,
- Fig. 8
- a two-layered pigment of a security element according to the invention, and
- Fig. 9
- the measured VIS / IR remissions of three inventive security elements.
Die Erfindung wird nun am Beispiel von Sicherheitselementen für Banknoten erläutert.
Die Gestaltung und der visuelle Eindruck des Sicherheitselements 12 für einen Betrachter 20 sind in
Die Besonderheit des Sicherheitselements 12 zeigt sich vor allem im infraroten Spektralbereich. Wie in
Durch die Einwirkung der Laserstrahlung auf die Farbschicht 14 wurde somit die Absorption der Farbschicht 14 im sichtbaren Spektralbereich verringert, während sie im infraroten Spektralbereich erhöht wurde (siehe
Ein erster Effekt tritt typischerweise bei im sichtbaren und infraroten Spektralbereich relativ stark absorbierenden Farbschichten auf. In der linken Bildhälfte von
Manchen Farben zeigen auch im sichtbaren Spektralbereich eine praktisch unveränderte Absorption und nur im infraroten Spektralbereich eine verringerte Absorption 36. Solche Farben sind beispielsweise in der Druckschrift
Der gegenteilige Effekt tritt typischerweise bei Farbschichten auf, die im sichtbaren und infraroten Spektralbereich schwach bis mäßig absorbieren. In der linken Bildhälfte von
Durch die Laserbeaufschlagung solcher Farbschichten können also Kennzeichnungen erzeugt werden, die sowohl visuell als auch maschinell erfassbar sind. Allerdings wird die Schwärzung im sichtbaren Spektralbereich von Betrachtern oft als wenig attraktiv empfunden. Sie gestattet dem Designer auch wenig Spielraum, da unabhängig von der Ausgangsfarbe der Farbschicht stets nur eine schwarze Kennzeichnung erzeugt werden kann.By the laser exposure of such color layers so markings can be generated, which are both visually and mechanically detectable. However, blackening in the visible spectral range is often perceived by viewers as being less attractive. It also allows the designer little leeway, as it can always be produced only a black mark regardless of the initial color of the color layer.
Im Gegensatz zu diesen beiden herkömmlichen Effekten steht das Verhalten der erfindungsgemäßen Farbschicht 14. In der linken Bildhälfte von
Der visuell sichtbaren, hellen Markierung 18 wird auf diese Weise eine maschinenlesbare Markierung mit sehr deutlichem und damit leicht erfassbarem Infrarot-Kontrast zur Seite gestellt. Auf diese Weise wird ein mehrstufiges Echtheitsmerkmal geschaffen, das einerseits aufgrund seiner hellen Färbung und dem teilweisen Erhalt der Ausgangsfarbe der Farbschicht 14 ein visuell attraktives Erscheinungsbild bietet und das andererseits sowohl für den Laien leicht zu identifizieren, als auch maschinell sicher nachzuweisen ist.The visually visible,
Um dieses ungewöhnliche gegenläufige Verhalten der Farbschicht bei der Laserbeaufschlagung zu erreichen, enthält die Farbschicht 14 mehrschichtige Pigmente 60 mit einer einheitlichen, vom Betrachtungswinkel unabhängigen Farbe. Mit Bezug auf
Ohne an eine bestimmte Erklärung gebunden sein zu wollen, kommt der für die Erfindung genutzte Effekt nach gegenwärtigem Verständnis möglicherweise dadurch zustande, dass durch die Laserstrahlung die äußere MgO-Schicht 66 teilweise oder sogar vollständig ablatiert bzw. abgetragen wird. Dadurch wird die stark IR-absorbierende innere Schicht 64 freigelegt, wodurch einerseits die Infrarotabsorption des Pigments 60 insgesamt steigt und andererseits die zum Beispiel einen Goldglanz erzeugenden Interferenzeffekte abgeschwächt werden, was zu einer Aufhellung im sichtbaren Spektralbereich führt.Without wishing to be bound by any specific explanation, the effect used for the invention, as currently understood, may be due to the laser radiation partially or even completely ablating or removing the
Bei sehr hoher Laserintensität wird neben der äußeren Schicht 66 auch die innere Schicht 64 zerstört und es ergibt sich sowohl im sichtbaren, als auch im infraroten Spektralbereich eine verringerte Absorption, wie oben im Zusammenhang mit
Die Abhängigkeit der Absorption A von der Belichtungsintensität I im sichtbaren Spektralbereich und im infraroten Spektralbereich ist in
Der erfindungsgemäß bevorzugte Intensitätsbereich, in dem gleichzeitig eine verringerte Absorption im sichtbaren Spektralbereich und eine erhöhte Absorption im infraroten Spektralbereich erhältlich sind, ist in der Figur mit dem Bezugszeichen 76 eingezeichnet. Die absoluten Werte des bevorzugten Intensitätsbereich hängen natürlich einerseits vom verwendeten Pigment 60 und andererseits von den weiteren Laserparametern, insbesondere von der Laserwellenlänge, der Pulsdauer, der Wiederholfrequenz und der Geschwindigkeit ab, mit der der Laserstrahl bei der Kennzeichnung über die Farbschicht geführt wird. Geeignete absolute Werte für die erfindungsgemäß einzusetzende Intensität können bei dem bekannten prinzipiellen Verlauf der
Es hat sich als vorteilhaft herausgestellt, die Laserkennzeichnung mit einem gepulsten Infrarotlaser im Wellenlängenbereich von 0,8 µm bis 3 µm, insbesondere mit einem Nd:YAG-Laser durchzuführen. Die Pulsdauern liegen vorzugsweise unterhalb von 25 ns, insbesondere im Bereich von 8 bis 18 ns.It has proved to be advantageous laser marking with a pulsed infrared laser in the wavelength range of 0.8 .mu.m to 3 .mu.m, in particular with a Nd: YAG laser. The pulse durations are preferably below 25 ns, in particular in the range from 8 to 18 ns.
Bei den erfindungsgemäß eingesetzten mehrschichtigen Pigmenten kann es sich insbesondere um Magnetpigmente handeln, die zusätzlich zu dem beschriebenen Effekt durch ein externes Magnetfeld in Form eines gewünschten Motivs ausgerichtet werden können. Dazu werden die Magnetpigmente beispielsweise einem UV-härtenden Lack beigemischt, der mit den enthaltenen Magnetpigmenten im Siebdruck auf das Zielsubstrat aufgebracht wird. Dann wird das Zielsubstrat mit den noch beweglichen Magnetpigmenten in ein Magnetfeld einer gewünschten Feldverteilung gebracht und die Pigmente dadurch ausgerichtet. Die ausgerichteten Magnetpigmente werden nun durch Härten des UV-Lacks in ihrer Orientierung dauerhaft fixiert. Sicherheitselemente mit in Form eins Motivs ausgerichteten Magnetpigmenten zeigen dem Betrachter ein effektvolles, dreidimensional arunutendes Erscheinungsbild mit einem dynamischen Bewegungseffekt beim Kippen des Sicherheitselements, das mit der oben beschriebenen statischen Kennzeichnung kombiniert ist.The multilayer pigments used according to the invention may in particular be magnetic pigments which, in addition to the described effect, may be aligned by an external magnetic field in the form of a desired motif. For this purpose, the magnetic pigments are admixed, for example, with a UV-curing lacquer which is screen-printed with the contained magnetic pigments onto the target substrate. Then, the target substrate with the still-movable magnetic pigments is placed in a magnetic field of a desired field distribution and the pigments thereby aligned. The aligned magnetic pigments are now permanently fixed in their orientation by curing the UV varnish. Safety elements with magnetic motifs oriented in the form of a motif show the viewer an effective, three-dimensionally arunutendes appearance with a dynamic movement effect when tilting the security element, which is combined with the static marking described above.
Magnetpigmente können allerdings im Rahmen der Erfindung auch ohne besondere Ausrichtung der Pigmente eingesetzt werden. Die erhaltene Farbschicht 14 weist dann ein bis auf die Kennzeichnung 18 gleichförmiges Erscheinungsbild auf, wie in
Neben den in
Nach dem oben beschriebenen Erklärungsansatz wird durch die Laserstrahlung im Intensitätsbereich 76 (
Neben den in
- 1010
- Banknotebill
- 1212
- Sicherheitselementsecurity element
- 1414
- Farbschichtcoat of paint
- 1616
- HintergrundbereichBackground area
- 1818
- KennzeichnungLabelling
- 2020
- Betrachterobserver
- 2222
- Infrarotsensorinfrared sensor
- 30, 3430, 34
- Absorption VISAbsorption VIS
- 32, 3632, 36
- Absorption IRAbsorption IR
- 40, 4440, 44
- Absorption VISAbsorption VIS
- 42, 4642, 46
- Absorption IRAbsorption IR
- 50, 5450, 54
- Absorption VISAbsorption VIS
- 52, 5652, 56
- Absorption IRAbsorption IR
- 6060
- mehrschichtiges Pigmentmulti-layered pigment
- 6262
- Substratsubstratum
- 6464
- innere Schichtinner layer
- 6666
- äußere Schichtouter layer
- 6868
- Pigmentrandpigment edge
- 7070
- Absorption im sichtbaren SpektralbereichAbsorption in the visible spectral range
- 7272
- Absorption im infraroten SpektralbereichAbsorption in the infrared spectral range
- 7474
- Belichtungsintensitätexposure intensity
- 8080
- zweischichtiges Pigmenttwo-layered pigment
- 8282
- Substratsubstratum
- 8484
- Hülleshell
Claims (8)
- A method for manufacturing a security element (12) for securing value objects (10) with an ink layer (14) having a marking area (18) in the form of patterns, characters or a coding that is incorporated by the action of laser radiation and is both visually and machine-detectable, and having a background area (16), comprising- applying an ink layer containing magnetic pigments to a substrate, and- incorporating a marking in the form of patterns, characters or a coding in the ink layer by the action of laser radiation,characterized in that the ink layer is opaque, and that the nature of the multilayer pigments and the intensity of the laser radiation are chosen such that the marking becomes lighter than the background area in the visible spectral range, thereby becoming visually detectable, and is provided with a greater absorption than the background area in the infrared spectral range, thereby becoming machine-detectable, wherein the multilayer pigments have a carrier and a layer applied to the carrier, wherein the carrier is chosen from Al2O3, Al2O3 with up to 5 weight-% TiO2, SiO2, SiO2 with up to 20 weight-% silicon hydroxide, glass or borosilicate, and the layer contains gamma iron oxide doped with at least one alkaline earth metal oxide, wherein the laser application is carried out with a pulsed infrared laser in the wavelength range of 0.8 µm to 3 µm.
- The method according to claim 1, wherein the multilayer pigments have a uniform color substantially independent of the viewing angle.
- The method according to claim 1 or 2, wherein the magnetic pigments are magnetically aligned in the form of a motif, in particular in the form of patterns, characters or a coding, after the step of applying the ink layer to the substrate.
- The method according to any of the claims 2 or 3, wherein the ink layer contains, besides a binding agent, the multilayer pigments with the uniform color substantially independent of the viewing angle in the amount of 75% to 100%, and optically variable pigments in the amount of 25% to 0%.
- The method according to any of the claims 1 to 4, wherein the laser application is carried out with a pulsed infrared laser with short pulse durations of 25 ns or less, in particular from 8 to 18 ns.
- A security element for securing value objects with an opaque ink layer having a marking area in the form of patterns, characters or a coding that is incorporated by the action of laser radiation and is both visually and machine-detectable, and a background area, wherein the security element can be obtained by the method according to any of the claims 1 to 5.
- The use of the security element according to claim 6 for proving the authenticity of value objects by detecting the infrared absorption of the security element in the area of the marking.
- A method for proving the authenticity of value objects equipped with the security element according to claim 6, wherein the method comprises a step of detecting the infrared absorption of the security element in the area of the marking.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011105399A DE102011105399A1 (en) | 2011-06-22 | 2011-06-22 | Security element and method of making same and use of the security element |
PCT/EP2012/002582 WO2012175191A2 (en) | 2011-06-22 | 2012-06-19 | Security element, method for the production thereof, and use of the security element |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2723578A2 EP2723578A2 (en) | 2014-04-30 |
EP2723578B1 true EP2723578B1 (en) | 2016-04-06 |
Family
ID=46420054
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12730800.5A Not-in-force EP2723578B1 (en) | 2011-06-22 | 2012-06-19 | Security element, method for the manufactur thereof, and use therof |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP2723578B1 (en) |
DE (1) | DE102011105399A1 (en) |
PL (1) | PL2723578T3 (en) |
WO (1) | WO2012175191A2 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107093259B (en) * | 2017-03-09 | 2019-07-26 | 深圳怡化电脑股份有限公司 | A kind of recognition methods of forge or true or paper money and its device |
DE102017004039B4 (en) * | 2017-04-26 | 2019-06-06 | Mühlbauer Gmbh & Co. Kg | Security deposit for a document of identification and method for producing a security deposit for a document of identification |
CN107798770B (en) * | 2017-10-17 | 2019-12-06 | 深圳怡化电脑股份有限公司 | Parameter adjusting method and device for image sensor, ATM and storage medium |
DE102019004229A1 (en) * | 2019-06-13 | 2020-12-17 | Giesecke+Devrient Currency Technology Gmbh | Security element with different printing inks when illuminated with electromagnetic radiation in the infrared wavelength range |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19618569A1 (en) * | 1996-05-09 | 1997-11-13 | Merck Patent Gmbh | Highly transparent multilayer interference pigments for lacquers, inks, cosmetics, laser-markable plastics etc. |
DE102004057918A1 (en) * | 2004-11-30 | 2006-06-01 | Merck Patent Gmbh | Laser marking of value documents |
DE102006014367A1 (en) | 2006-03-27 | 2007-10-04 | Giesecke & Devrient Gmbh | Data medium e.g. bank note, producing method, involves placing markings in form of pattern on marking layer by application of short laser pulse, where markings are detected in infrared spectral region |
DE102008033693A1 (en) * | 2008-07-17 | 2010-01-21 | Giesecke & Devrient Gmbh | Disk with a printed magnetic security feature |
CN102803400B (en) | 2009-06-26 | 2015-05-13 | 默克专利股份有限公司 | Magnetic Pigments Comprising A Flaky Substrate And A Layer Of Maghemite |
-
2011
- 2011-06-22 DE DE102011105399A patent/DE102011105399A1/en not_active Withdrawn
-
2012
- 2012-06-19 WO PCT/EP2012/002582 patent/WO2012175191A2/en active Application Filing
- 2012-06-19 PL PL12730800.5T patent/PL2723578T3/en unknown
- 2012-06-19 EP EP12730800.5A patent/EP2723578B1/en not_active Not-in-force
Also Published As
Publication number | Publication date |
---|---|
WO2012175191A3 (en) | 2013-11-07 |
DE102011105399A1 (en) | 2012-12-27 |
EP2723578A2 (en) | 2014-04-30 |
WO2012175191A2 (en) | 2012-12-27 |
PL2723578T3 (en) | 2016-10-31 |
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