EP2723578B1 - Élément de sécurité, son procédé de fabrication et l' utilisation d'un tel élément de sécurité - Google Patents
Élément de sécurité, son procédé de fabrication et l' utilisation d'un tel élément de sécurité Download PDFInfo
- Publication number
- EP2723578B1 EP2723578B1 EP12730800.5A EP12730800A EP2723578B1 EP 2723578 B1 EP2723578 B1 EP 2723578B1 EP 12730800 A EP12730800 A EP 12730800A EP 2723578 B1 EP2723578 B1 EP 2723578B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- security element
- absorption
- pigments
- laser
- infrared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
- 238000000034 method Methods 0.000 title claims description 14
- 238000010521 absorption reaction Methods 0.000 claims description 82
- 239000000049 pigment Substances 0.000 claims description 68
- 230000003595 spectral effect Effects 0.000 claims description 53
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 21
- 230000005855 radiation Effects 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 6
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 229910052681 coesite Inorganic materials 0.000 claims 2
- 229910052593 corundum Inorganic materials 0.000 claims 2
- 229910052906 cristobalite Inorganic materials 0.000 claims 2
- 229910052682 stishovite Inorganic materials 0.000 claims 2
- 229910052905 tridymite Inorganic materials 0.000 claims 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 2
- 230000000694 effects Effects 0.000 description 10
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 8
- 229910010413 TiO 2 Inorganic materials 0.000 description 7
- 229910052737 gold Inorganic materials 0.000 description 6
- 239000010931 gold Substances 0.000 description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 238000012795 verification Methods 0.000 description 4
- 239000003086 colorant Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 229910001566 austenite Inorganic materials 0.000 description 2
- 238000005282 brightening Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000004677 hydrates Chemical class 0.000 description 2
- 230000033001 locomotion Effects 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- JZQOJFLIJNRDHK-CMDGGOBGSA-N alpha-irone Chemical compound CC1CC=C(C)C(\C=C\C(C)=O)C1(C)C JZQOJFLIJNRDHK-CMDGGOBGSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000005539 carbonized material Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000010330 laser marking Methods 0.000 description 1
- 238000013532 laser treatment Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- -1 metal oxide hydrates Chemical class 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000001392 ultraviolet--visible--near infrared spectroscopy Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
- B42D25/382—Special inks absorbing or reflecting infrared light
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/24—Ablative recording, e.g. by burning marks; Spark recording
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
- B42D25/41—Marking using electromagnetic radiation
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
- G07D7/06—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using wave or particle radiation
- G07D7/12—Visible light, infrared or ultraviolet radiation
- G07D7/1205—Testing spectral properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
- B41M3/148—Transitory images, i.e. images only visible from certain viewing angles
-
- B42D2033/20—
-
- B42D2035/24—
Definitions
- the document describes WO 2007/110155 A1 a data carrier with markings, which are preferably not visible in the visible spectral range, but can be detected by machine only in the near infrared with corresponding detectors.
- either the visible marking or the machine-readable marking usually stands in the foreground, while the respective other aspect is perceived as disturbing.
- the machine-readable Markers are therefore often laminated or hidden optically, while the visually recognizable markings typically do not have sufficient machine-readable properties for secure detection.
- document DE 10 2010 009 977 A1 discloses a method according to the preamble of claim 1.
- the present invention seeks to provide a security element of the type mentioned above, on the one hand offers an attractive visual appearance and its identification on the other hand not only visually, but also mechanically detected safely.
- a first aspect of the invention relates to a method according to claim 1.
- the magnetic pigments are magnetically aligned after the step of applying the color layer to the substrate in the form of a motif, in particular in the form of patterns, characters or an encoding.
- the laser application is carried out with a pulsed infrared laser in the wavelength range of 0.8 microns to 3 microns, preferably with short pulse durations of 25 ns or less, more preferably from 8 to 18 ns.
- a second aspect of the invention relates to a security element according to claim 6.
- a third aspect of the invention relates to a use of the security element according to the second aspect of the invention for the authenticity verification of valuables by detecting the infrared absorption of the security element in the area of the marking.
- a fourth aspect of the invention relates to a method for authenticity verification of valuables equipped with the security element according to the second aspect of the invention, the method comprising a step of detecting the infrared absorption of the security element in the region of the marking.
- a generic security element has a covering ink layer and an introduced into the ink layer by the action of laser radiation marking in the form of patterns, characters or a coding that is both visually and mechanically detectable.
- the color layer in the background area located outside the marking contains multilayer pigments which, for example, may have a uniform color substantially independent of the viewing angle.
- the multilayered pigments may include an inner layer having a first infrared absorption and at least one inner layer covering outer layer having a second infrared absorption, wherein the first infrared absorption is greater than the second infrared absorption.
- the outer layer of the multilayer pigments is at least partially ablated or removed. The marking is brighter in the visible spectral range than the background range and thereby visually detectable, while the marking in the infrared spectral range has a greater absorption than the background area and is thus mechanically detectable.
- the inner layer may, for example, be magnetic and based on Fe 3 O 4 , gamma iron oxide or maghemite, with alkaline earth oxide, in particular MgO, doped gamma iron oxide, Co-containing gamma iron oxide, Co-containing Fe 3 O 4 or CrO 2 .
- the carrier of the pigments themselves constitutes the inner layer of high infrared absorption, the carrier itself may be magnetic and be formed, for example, on the basis of Fe 2 O 3 .
- the outer layer of the multi-layered pigment consists for example of MgO or TiO 2 , wherein in principle also other materials with high infrared remission come into question, as used for example for solar heat reflection.
- the inner layer can advantageously also be formed on the basis of antimony-doped tin oxide. Also TiO 2 / carbon black mixtures or Rußein gleich füren with high infrared absorption come into consideration for the inner layer.
- the multilayer pigments used according to the invention may alternatively have a carrier with a coating applied above the carrier, wherein the coating has a first constituent with a first infrared absorption and a second component having second infrared absorption ablatable by the action of laser radiation, and the first infrared absorption is greater than the second infrared absorption.
- the first component may be in the form of a matrix in which the second component is embedded, or vice versa.
- first infrared absorption is suitably more than 1.25 times, preferably more than 2 times, more preferably more than 5 times, and most preferably more than 8 times as large as the aforementioned "second infrared absorption".
- infrared absorption suitably refers to a wavelength range of 800 to 1400 nm, preferably 800 to 1200 nm, and more preferably 800 to 1050 nm.
- the magnetic pigments in particular have a support and a layer applied to the support, wherein the support of Al 2 O 3 , Al 2 O 3 with up to 5 wt .-% TiO 2 , SiO 2 , SiO 2 with up to 20 wt. -% silicon hydroxide, glass or borosilicate is selected and the layer gamma-iron oxide, which is doped with at least one alkaline earth metal oxide, preferably MgO, contains.
- the proportion of the alkaline earth metal is for example 0.01 to 2 wt .-%, in particular 0.1 to 1 wt .-%, based on the total pigment.
- the layer applied on the carrier may consist exclusively of the gamma-iron oxide doped with alkaline-earth metal oxide, in particular MgO.
- the gamma iron oxide may also contain other iron compounds, for example Fe 3 O 4 or alpha iron oxide. The last two compounds are in the gamma-iron oxide layer, individually or in combination, preferably in a proportion of at most 25 wt .-% based on the gamma-iron oxide.
- a dielectric layer may be arranged above the gamma-iron oxide-deposited layer on the carrier.
- the dielectric layer may for example be based on metal oxides or metal oxide hydrates or mixtures thereof, in particular oxides or hydrates of Ti, Zr, Zn, Sn, Ce, Si and Al, such as titanium dioxide, zirconium oxide, zinc oxide, tin oxide, cerium oxide, silicon dioxide or hydrates thereof ,
- the magnetic pigments described above may advantageously be oriented magnetically in the form of a motif, in particular in the form of patterns, characters or an encoding.
- a motif resulting from a magnetic alignment may be independent of the laser-generated marking or interact with it.
- the tag may form a static reference point for a dynamic motion effect of the magnetic motif.
- multilayer magnetic pigments can also be used without magnetic alignment of the pigments.
- the multilayer pigments used according to the invention are preferably not optically variable, ie they preferably exhibit a uniform color substantially independent of the viewing angle.
- the pigments can show shiny metallic colors, in particular gold, copper or bronze tones.
- Such pigments are for example in the WO 2010/149266 A1 disclosed.
- the effects according to the invention also occur even when the color layer, in addition to the multilayer pigments and a binder, contains not too large a proportion of optically variable pigments.
- the color layer in addition to the binder, contains 75% to 100% of the described non-optically variable, multi-layered pigments and from 25% to 0% optically variable pigments.
- the laser application is carried out with a pulsed infrared laser in the wavelength range of 0.8 .mu.m to 3 .mu.m, preferably with short pulse durations of 25 ns or less, in particular from 8 to 18 ns.
- FIG. 1 shows a schematic representation of a banknote 10 with a printed directly on the banknote paper security element 12th
- the peculiarity of the security element 12 is particularly evident in the infrared spectral range.
- the label 18 in the infrared spectral region has a significantly higher absorption than the background region 16 and is thereby easily and reliably detectable by machine, for example with an infrared sensor 22 sensitive at a wavelength of 850 nm.
- a first effect typically occurs in the visible and infrared spectral regions relatively strongly absorbing ink layers.
- the absorption 30 of such a color layer in the visible spectral range (VIS) and its absorption 32 in the infrared spectral range (IR) are shown schematically. If such a color layer is irradiated with pulsed laser radiation of sufficient intensity, the color layer is locally destroyed or desorbed by the laser radiation so that the substrate or an underlying printing layer becomes visible.
- the absorption by the color layer in the lasered region generally decreases both in the visible spectral range 34 and in the infrared spectral range 36, resulting in a bright identification with reduced IR absorption, as in the right half of FIG Fig. 3 shown schematically.
- the size of the absorption before the laser application is shown with dashed lines for easier orientation.
- Some colors also show a virtually unchanged absorption in the visible spectral range and a reduced absorption only in the infrared spectral range. Such colors are described, for example, in the document WO 2007/110155 A1 in connection with the local FIG. 3 described. They are well suited for generating machine-readable encodings whose existence is hidden in the visible spectral range.
- the carbonized material absorbs in a broadband manner, the change in absorbance in the visible spectral region 44 and in the infrared spectral region 46 is usually the same and a visually black high infrared absorption label is produced as in the right half of FIG Fig. 4 shown schematically.
- the behavior of the ink layer of the invention 14 In contrast to these two conventional effects is the behavior of the ink layer of the invention 14.
- the absorption 50 of the color layer in the visible spectral range (VIS) and the absorption 52 in the infrared spectral range (IR) is shown.
- VIS visible spectral range
- IR infrared spectral range
- a color layer 14 according to the invention is irradiated with pulsed laser radiation of suitable intensity, a brightening results locally, ie a lower absorption 54 in the visible spectral range, while at the same time a high absorption 56 is produced in the infrared spectral range, as in the right half of FIG Fig. 5 shown.
- the visually visible, bright mark 18 is set in this way a machine-readable mark with very clear and thus easily detectable infrared contrast. In this way, a multi-level authenticity feature is created, on the one hand due to its light color and the partial preservation of the starting color of the ink layer 14 a Visually attractive appearance and on the other hand, both for the layman easy to identify, as well as mechanically proven to prove.
- the ink layer 14 contains multi-layered pigments 60 having a uniform color independent of the viewing angle.
- the pigments 60 are gold-colored and comprise a carrier 62, for example made of Al 2 O 3 , which is coated with an inner layer 64, for example of gamma-iron oxide, and an outer layer 66, for example of MgO.
- the inner layer 64 has a higher, for example by a factor of 4, higher infrared absorption than the outer layer 66.
- the effect used for the invention may be due to the laser radiation partially or even completely ablating or removing the outer MgO layer 66.
- the inner layer 64 is destroyed in addition to the outer layer 66 and there is a reduced absorption both in the visible and in the infrared spectral range, as described above Fig. 3 already described.
- the inner and outer layers 64, 66 need not extend beyond the edge 68 of the pigment, the inner ones and outer layers may instead be deposited separately on the opposite major surfaces of the core 62.
- Fig. 7 The dependence of the absorption A on the exposure intensity I in the visible spectral range and in the infrared spectral range is in Fig. 7 shown schematically. While the absorption 70 decreases in the visible spectral range with increasing exposure intensity, the absorption 72 in the infrared spectral range according to the model described above due to the exposure of the inner layer 64 first increases, and then decrease with increasing destruction of the gamma-iron oxide layer, with a Exposure intensity 74 reaches a reduced absorption in both spectral ranges and thus a situation as in Fig. 3 is generated.
- the intensity range which is preferred according to the invention, in which simultaneously a reduced absorption in the visible spectral range and an increased absorption in the infrared spectral range are obtainable, is indicated in the figure by the reference numeral 76.
- the absolute values of the preferred intensity range depend on the one hand on the pigment 60 used and on the other on the other laser parameters, in particular on the laser wavelength, the pulse duration, the repetition frequency and the speed with which the laser beam is passed over the ink layer during the marking.
- Suitable absolute values for the intensity to be used according to the invention can be determined in the case of the known basic course of the invention Fig. 7 however, can be determined experimentally by a person skilled in the art for a specific parameter set and a specific pigment 60 by a few experiments.
- the multilayer pigments used according to the invention may in particular be magnetic pigments which, in addition to the described effect, may be aligned by an external magnetic field in the form of a desired motif.
- the magnetic pigments are admixed, for example, with a UV-curing lacquer which is screen-printed with the contained magnetic pigments onto the target substrate.
- the target substrate with the still-movable magnetic pigments is placed in a magnetic field of a desired field distribution and the pigments thereby aligned.
- the aligned magnetic pigments are now permanently fixed in their orientation by curing the UV varnish.
- Safety elements with magnetic motifs oriented in the form of a motif show the viewer an effective, three-dimensionally arunutendes appearance with a dynamic movement effect when tilting the security element, which is combined with the static marking described above.
- the resulting ink layer 14 then has a uniform appearance except for the label 18, as in Fig. 2 (a) illustrated.
- FIG. 8 shows for illustration a two-layered pigment 80 with a core 82 of gamma-Fe 2 O 3 and a shell 84 of TiO 2 .
- the core 82 represents an inner layer which has a significantly higher, for example a factor of 3, infrared absorption than the outer TiO 2 shell 84.
- the pigments shown are also the multilayer pigments in question, which in the WO 2010/149266 A1 are disclosed. These include, for example, an Al 2 O 3 support and a MgO-doped layer of gamma-iron oxide applied above the support.
- Fig. 9 shows the measured VIS / IR remissions of three inventive, laser-treated security elements.
- security elements in each case so-called magnetic gold pigments ("magnetic gold", in Fig. 9 also referred to as "M-gold") with an Al 2 O 3 support and a MgO-doped layer of gamma-iron oxide applied above the support.
- M-gold magnetic gold pigments
- the proportion of alkaline earth metal is about 1 wt .-% based on the pigment.
- the three security elements were each treated with a different laser energy.
- Fig. 9 shows the measured VIS / IR remissions of three inventive, laser-treated security elements.
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Claims (8)
- Procédé de fabrication d'un élément de sécurité (12) destiné à la sécurisation d'objets de valeur (10), ayant une couche d'encre (14) qui comporte une zone de marque (18) réalisée par action de rayonnement laser et saisissable tant visuellement que par machine, sous forme de motifs, caractères ou d'une codification, et une zone de fond (16), comprenant- l'application d'une couche d'encre contenant des pigments magnétiques sur un substrat, et- la réalisation d'une marque sous forme de motifs, caractères ou d'une codification dans la couche d'encre par action de rayonnement laser, caractérisé en ce quela couche d'encre est couvrante et en ce que la nature des pigments multicouches et l'intensité du rayonnement laser sont choisis de telle façon que la marque devient, dans la plage spectrale visible, plus claire que la zone de fond et ainsi saisissable visuellement, et acquiert dans la plage spectrale infrarouge une plus grande absorption que la zone de fond et devient ainsi saisissable par machine, les pigments multicouches comportant un support et une couche appliquée sur le support, le support étant choisi parmi du Al2O3, du Al2O3 avec jusqu'à 5 pourcent par poids de TiO2, du SiO2, du SiO2 avec jusqu'à 20 pourcent par poids d'hydroxyde de silicium, du verre ou du borosilicate, et la couche contenant de l'oxyde de fer gamma dopé avec au moins un oxyde de métal alcalino-terreux, l'exposition au laser étant effectuée avec un laser infrarouge pulsé dans la plage de longueurs d'ondes située entre 0.8 µm et 3 µm.
- Procédé selon la revendication 1, les pigments multicouches présentant une couleur uniforme essentiellement indépendante de l'angle d'observation.
- Procédé selon la revendication 1 ou 2, les pigments magnétiques étant, après l'étape de l'application de la couche d'encre sur le substrat, alignés magnétiquement sous forme de motifs, caractères ou d'une codification.
- Procédé selon une des revendications 2 ou 3, la couche d'encre contenant, en plus d'un liant, à entre 75% et 100% les pigments multicouches ayant la couleur uniforme essentiellement indépendante de l'angle d'observation, et, à entre 25% et 0%, des pigments optiquement variables.
- Procédé selon une des revendications de 1 à 4, l'exposition au laser étant effectuée avec un laser infrarouge pulsé à courtes durées d'impulsions de 25 ns ou moins, en particulier de 8 à 18 ns.
- Élément de sécurité destiné à la sécurisation d'objets de valeur, ayant une couche d'encre couvrante qui comporte une zone de marque réalisée par action de rayonnement laser et saisissable tant visuellement que par machine, sous forme de motifs, caractères ou d'une codification, et une zone de fond, l'élément de sécurité pouvant être obtenu par le procédé selon une des revendications de 1 à 5.
- Utilisation de l'élément de sécurité selon la revendication 6 pour la vérification de l'authenticité d'objets de valeur par saisie de l'absorption infrarouge de l'élément de sécurité dans la zone de la marque.
- Procédé de vérification de l'authenticité d'objets de valeur équipés de l'élément de sécurité selon la revendication 6, le procédé comprenant une étape de la saisie de l'absorption infrarouge de l'élément de sécurité dans la zone de la marque.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011105399A DE102011105399A1 (de) | 2011-06-22 | 2011-06-22 | Sicherheitselement und Verfahren zum Herstellen desselben sowie Verwendung des Sicherheitselements |
PCT/EP2012/002582 WO2012175191A2 (fr) | 2011-06-22 | 2012-06-19 | Élément de sécurité et procédé de fabrication et utilisation dudit élément de sécurité |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2723578A2 EP2723578A2 (fr) | 2014-04-30 |
EP2723578B1 true EP2723578B1 (fr) | 2016-04-06 |
Family
ID=46420054
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12730800.5A Not-in-force EP2723578B1 (fr) | 2011-06-22 | 2012-06-19 | Élément de sécurité, son procédé de fabrication et l' utilisation d'un tel élément de sécurité |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP2723578B1 (fr) |
DE (1) | DE102011105399A1 (fr) |
PL (1) | PL2723578T3 (fr) |
WO (1) | WO2012175191A2 (fr) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107093259B (zh) * | 2017-03-09 | 2019-07-26 | 深圳怡化电脑股份有限公司 | 一种纸币真伪的识别方法及其装置 |
DE102017004039B4 (de) * | 2017-04-26 | 2019-06-06 | Mühlbauer Gmbh & Co. Kg | Sicherheitseinlage für ein Ausweisdokument und Verfahren zur Herstellung einer Sicherheitseinlage für ein Ausweisdokument |
CN107798770B (zh) * | 2017-10-17 | 2019-12-06 | 深圳怡化电脑股份有限公司 | 图像传感器的参数调整方法、装置、atm及存储介质 |
DE102019004229A1 (de) * | 2019-06-13 | 2020-12-17 | Giesecke+Devrient Currency Technology Gmbh | Sicherheitselement mit bei Beleuchtung mit elektromagnetischer Strahlung im infraroten Wellenlängenbereich unterschiedlichen Druckfarben |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19618569A1 (de) * | 1996-05-09 | 1997-11-13 | Merck Patent Gmbh | Mehrschichtige Interferenzpigmente |
DE102004057918A1 (de) * | 2004-11-30 | 2006-06-01 | Merck Patent Gmbh | Laserkennzeichnung von Wertdokumenten |
DE102006014367A1 (de) | 2006-03-27 | 2007-10-04 | Giesecke & Devrient Gmbh | Datenträger und Verfahren zu seiner Herstellung |
DE102008033693A1 (de) * | 2008-07-17 | 2010-01-21 | Giesecke & Devrient Gmbh | Datenträger mit einem gedruckten magnetischen Sicherheitsmerkmal |
US10174203B2 (en) | 2009-06-26 | 2019-01-08 | Merck Patent Gmbh | Magnetic pigments comprising a flaky substrate and layer of maghemite |
-
2011
- 2011-06-22 DE DE102011105399A patent/DE102011105399A1/de not_active Withdrawn
-
2012
- 2012-06-19 WO PCT/EP2012/002582 patent/WO2012175191A2/fr active Application Filing
- 2012-06-19 EP EP12730800.5A patent/EP2723578B1/fr not_active Not-in-force
- 2012-06-19 PL PL12730800.5T patent/PL2723578T3/pl unknown
Also Published As
Publication number | Publication date |
---|---|
PL2723578T3 (pl) | 2016-10-31 |
EP2723578A2 (fr) | 2014-04-30 |
DE102011105399A1 (de) | 2012-12-27 |
WO2012175191A2 (fr) | 2012-12-27 |
WO2012175191A3 (fr) | 2013-11-07 |
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