EP2220288B1 - Procédé de traitement d'un tissu - Google Patents

Procédé de traitement d'un tissu Download PDF

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Publication number
EP2220288B1
EP2220288B1 EP08861303A EP08861303A EP2220288B1 EP 2220288 B1 EP2220288 B1 EP 2220288B1 EP 08861303 A EP08861303 A EP 08861303A EP 08861303 A EP08861303 A EP 08861303A EP 2220288 B1 EP2220288 B1 EP 2220288B1
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EP
European Patent Office
Prior art keywords
polymer
fabric
polymers
aqueous medium
carboxylic acid
Prior art date
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Not-in-force
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EP08861303A
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German (de)
English (en)
Other versions
EP2220288A1 (fr
Inventor
Sameer Keshav Barne
Ditty Dixon
Aravindakshan Perincheery
Gopa Kumar Velayudhan Nair
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Unilever PLC
Unilever NV
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Unilever PLC
Unilever NV
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Publication of EP2220288A1 publication Critical patent/EP2220288A1/fr
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Publication of EP2220288B1 publication Critical patent/EP2220288B1/fr
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/09—Cellulose ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile

Definitions

  • the present invention relates to a process for treatment of a fabric.
  • the invention will be described hereinafter with reference to this application. However, it will be appreciated that the invention is not limited to this particular field of use.
  • US2006046950A (Penninger and Bastmaschine, 2006 ) teaches a detergent composition for cleaning textile materials comprising a combination of a soil release-capable alkyl or hydroxyalkyl cellulose derivative and a hygroscopic polymer selected from the class consisting of polypeptides, hydrogels, polyvinyl alcohol, the polyalkylene glycols, the homopolymers of acrylic acid, methacrylic acid, and maleic acid, copolymers of acrylic acid, methacrylic acid, and maleic acid and mixtures of the homo and copolymers.
  • the use of the hygroscopic polymers in combination with the cellulose derivatives is said to result in improved cleaning performance.
  • EP025696 (Unilever, 1988 ) teaches that improvement in soil suspension is achieved by adding mixture of vinyl pyrrolidone polymer and a nonionic cellulose ether to a detergent composition.
  • GB994353 (Domestos, 1965 ) teaches that mixtures of certain polymeric materials, when incorporated into unbuilt detergent compositions based on synthetic surface active agents, provide enhanced anti-redeposition as compared to activity of individual polymers alone when added alone to same detergent compositions.
  • the cleaning compositions essentially comprise of a surfactant and the pH of wash liquor is alkaline or neutral.
  • US4007305 (Kakar et al, 1977 ) addresses the problem of providing satisfactory nondurable finishes to textiles which impart optimum soil release and soil repellent properties.
  • the textiles must be treated with an alkaline aqueous medium having pH value of 7.5-11 and containing water soluble hydrophilic soil release polymer having carboxylic acid groups and a dispersed hydrophobic soil repellent fluorochemical.
  • one of the objects of the present invention is to provide a process for reducing soiling of fabrics that can be easily used in the household.
  • Another object of the present invention is to provide a process of treatment of a fabric for reducing soiling of fabrics.
  • Yet another object of the present invention is to provide a process for treatment of a fabric that improves efficacy of subsequent cleaning.
  • Yet another object of the present invention is to provide a process for reducing soiling of fabrics that allows enhanced deposition of benefit agents, such as perfume and fluorescer.
  • Yet another object of the present invention is to provide a process for treatment of a fabric which is effective on various types of fabrics such as cotton, polyester and polycotton.
  • Yet another object of the present invention is to provide a process for treatment of a fabric which is relatively easy to practice in household.
  • the present inventors have surprisingly found that contacting a fabric in an aqueous medium having acidic pH with two different polymers, one comprising a plurality of hydroxyl groups and the other comprising a plurality of carbonyl or ether groups, increases deposition of polymer and provides benefits such as reduction in soiling, ease of subsequent cleaning and enhanced deposition of benefit agents.
  • a process for treatment of a fabric comprising the steps of contacting the fabric with polymers A and B in an aqueous medium, wherein;
  • the fabric that can be treated includes synthetic as well as natural textiles. Fabrics may be made of cotton, polycotton, polyester, silk or nylon. It is envisaged that the method of the present invention can be used to treat garments and other clothing and apparel materials that form typical washload in household laundry.
  • the household materials that can be treated according to the process of the present invention include, but are not limited to, bedspreads, blankets, carpets, curtains and upholstery.
  • the process of the present invention is described primarily for treatment of a fabric, it is envisaged that the process of the present invention can be advantageously used to treat other materials such as jute, leather, denim and canvass. It is envisaged that the process of the present invention can be used to treat articles such as shoes, rain-wear and jackets.
  • polymer A has a plurality of hydroxyl or carboxyl groups.
  • the polymer A has a molecular mass preferably from 300 to 10 9 .
  • the polymer A is selected from the class consisting of homopolymers or copolymers of vinyl alcohol, alkylene glycol, saccharides, and carboxylic acid.
  • polymer A according to the present invention include:
  • Homopolymer or copolymer of vinyl alcohol has a molecular mass of preferably from 10,000 to 1,000,000, more preferably from 50,000 to 500,000 and most preferably from 50,000 to 200,000.
  • Commercially available polyvinyl alcohols that can be used include GOHSENOL® (Nippon Synthetic Chemical Industry), MOWIOL® (Clariant) and POVAL® (Kuraray).
  • Homopolymer or copolymer of alkylene glycol has a molecular mass of preferably from 4,000 to 20,000, more preferably from 5,000 to 15,000 and most preferably from 5,000 to 10,000.
  • Commercially available polyalkylene glycol can be used. Some examples of commercially available polyalkylene glycol include POLYGLYKOL® (Clariant) and CARBOWAX® (Union Carbide).
  • Homopolymer or copolymer of carboxylic acid has a molecular mass of preferably from 2,000 to 10,000,000, more preferably from 50,000 to 1,000,000 and most preferably from 90,000 to 500,000.
  • Homopolymer or copolymer of saccharide has a molecular mass of preferably from 1000 to 10 9 , more preferably from 10000 to 10 3 and most preferably from 100,000 to 10 9 .
  • Polymer A may be synthetic or natural. However, synthetic polymer is preferred over natural polymer.
  • the polymer A is water soluble.
  • the polymer A is selected from a class consisting of homopolymers or copolymers of vinyl alcohol or carboxylic acid.
  • the homopolymer or copolymer of carboxylic acid is preferably a polyacrylic acid or a copolymer thereof.
  • Examples include SOKALAN® PA (BASF) and CARBOPOL® (Lubrizol).
  • the amount of polymer A is preferably from 0.005 to 2, more preferably from 0.02 to 1, and most preferably from 0.05 to 0.5 mg per cm 2 area of the fabric.
  • fabric area refers to surface area of one side of the fabric.
  • polymer B has a monomeric unit comprising ether or carbonyl group.
  • Polymer B has a molecular mass preferably from 1000 to 10 9 .
  • the polymer B is selected from the class consisting of homopolymers or copolymers of vinyl pyrrolidone, alkylene oxide, saccharides and carboxylic acid.
  • Polymers and homopolymers of carboxylic acid and/or sacchharides and/or polyalkylene glycol/ether qualify to be selected both as polymer A or polymer B, as they comprise hydroxyl or carboxyl group and either a carbonyl or an ether group.
  • polymer A and polymer B are not of the same class. It is particularly preferred that the polymers A and B are selected from different classes of polymers. Without wishing to be limited by theory, it is believed that the two polymers A and B, when dissolved in water, form a complex with a solubility lower than each of the polymers A and B, which helps in enhanced deposition and other benefits.
  • Homopolymer or copolymer of vinyl pyrrolidone has a molecular mass of preferably from 1000 to 10000000, more preferably from 10,000 to 1,000,000 and most preferably from 30,000 to 500,000.
  • Commercially available polyvinyl pyrrolidone can be used, one example of which is LUVISKOL® (BASF).
  • Homopolymer or copolymer of poly alkylene oxide has a molecular mass greater than 20,000.
  • the molecular mass is preferably from 20,000 to 1,000,000, more preferably from 30,000 to 500,000 and most preferably from 50,000 to 200,000
  • Homopolymer or copolymer of saccharide has a molecular mass of preferably from 1000 to 10 9 , more preferably from 10,000 to 10 3 and most preferably from 100,000 to 10 9 .
  • Any commercially available poly alkylene oxide for example POLYOX® (Dow Chemical Co) can be used according to the present invention.
  • Polymer B may be synthetic or natural. However, synthetic polymer is preferred over natural polymer.
  • the polymer B is water soluble.
  • the polymer B is selected from a class consisting of homopolymers or copolymers of vinyl pyrrolidone or alkylene oxide.
  • the amount of polymer B is preferably from 0.005 to 2, more preferably from 0.02 to 1, and most preferably from 0.05 to 0.5 mg per cm 2 area of the fabric.
  • Most preferred combinations of the polymers are the ones in the first three rows in the Table 1 above, i.e. PAA-PVP, PAA-PEO and PEG-PAA.
  • the two polymers are contacted with the fabric in an aqueous medium having pH less than 6.
  • the aqueous medium has pH preferably less than 5 and more preferably less than 4.
  • Aqueous medium has pH preferably greater than 1 and more preferably greater than 2.
  • the polymers may be chosen in such a way that when the polymers are added to the aqueous medium, pH of the aqueous medium is less than 6.
  • an acidic ingredient is added to aqueous medium to ensure that the pH of the aqueous medium is less than 6.
  • Acidic ingredients that reduce pH of resulting aqueous medium to less than 6 are well known to a person skilled in the art and any suitable acidic ingredient may be chosen.
  • the aqueous medium may comprise either polymer A, or polymer B, or both the polymers. Alternatively, one or both the polymers may be added to the aqueous medium during the process of the present invention.
  • Polymer A when mixed with the aqueous medium, is from 0.005 to 10%, more preferably from 0.05 to 5%, and most preferably from 0.05 to 2% by weight of the aqueous medium.
  • Polymer B when mixed with the aqueous medium, is from 0.005 to 10%, more preferably from 0.01 to 5%, and most preferably from 0.01 to 2% by weight of the aqueous medium.
  • the aqueous medium preferably comprises an electrolyte.
  • the electrolyte is preferably from 0.001 to 5%, more preferably from 0.01 to 1%, and most preferably from 0.04 to 0.2% by weight of the aqueous medium.
  • Electrolytes that can be used according to the present are selected from chlorides, sulphates or nitrates of sodium, potassium, magnesium or calcium. Calcium salts are particularly preferred.
  • the aqueous medium comprises no more than 200 ppm anionic surfactant.
  • the aqueous medium comprises no more than 100 ppm, more preferably less than 50 ppm anionic surfactant. It is particularly preferred that the aqueous medium is substantially free of anionic surfactant.
  • the aqueous medium preferably comprises of at least one benefit agent.
  • the benefit agent that can be included in the aqueous medium includes, but not limited to ingredients such as perfume, fluorescer, deodorant, antibacterial agent, shading dys and bluing agent.
  • ingredients such as perfume, fluorescer, deodorant, antibacterial agent, shading dys and bluing agent.
  • the fabric is contacted with the polymers A and B either sequentially in any order, or simultaneously. Accordingly the fabric may be contacted with polymer A, followed by contacting with polymer B. Alternatively the fabric may be contacted with polymer B, followed by contacting with polymer A. The fabric may be simultaneously contacted with both the polymers A and B. Although the fabric may be contacted simultaneously with both the polymers, it is preferred that the fabric is contacted with the polymers sequentially, in any order.
  • the step of contacting the fabric with polymers A and B can be carried out in any suitable manner.
  • Polymers A, or polymer B, or both are mixed with the aqueous medium prior to contacting with the fabric.
  • polymer A may also be mixed with a nonaqueous medium including solvents such as alcohol and acetone prior to contacting with the fabric.
  • solvents such as alcohol and acetone
  • the polymer or polymers are mixed with the aqueous medium prior to contacting with the fabric.
  • the fabric may be dipped into the aqueous medium comprising one or more polymers.
  • the aqueous medium comprising one or both the polymers may be sprayed on the fabric.
  • either of the polymers A and B may be used in a form of abradable sticks which may be rubbed against the area of the fabric to be treated, followed by contact with the aqueous medium.
  • compositions for the process of the invention typically comprise 1-99% by weight polymer A, 1-99% by weight polymer B, and 0 to 10% by weight an acidic ingredient wherein;
  • the composition comprises preferably 5-95%, more preferably 10-90% and most preferably 20-80% by weight polymer A.
  • the composition comprises preferably 5-95%, more preferably 10-90% and most preferably 20-80% by weight polymer B.
  • the polymers may be chosen in such a way that pH of 1% aqueous solution of the composition is less than 6.
  • an acidic ingredient is present in the composition at 0.1-10% by weight of the composition to ensure that the pH of 1% aqueous solution of the composition is less than 6.
  • Acidic ingredients that reduce pH of resulting aqueous medium to less than 6 are well known to a person skilled in the art and any suitable acidic ingredient may be chosen.
  • a kit for treatment of a fabric comprising the composition and a set of instructions for use.
  • the polymers A and B are separately packaged, i.e. the polymers A and B are packaged individually in separate packs or in separate compartments of a twin compartment package.
  • Polymer A was polyacrylic acid of molecular mass 450000 in examples 1 and 2 and comparative examples 1-A to 2-B.
  • Polymer B was polyvinyl pyrrolidone of molecular mass 90000, in example 1 and comparative examples A and B.
  • Polymer B in example 2 and comparative examples C, D, and 2A was polyethylene oxide molecular mass 100,000.
  • Fabric was treated with polymer and dried. Dried fabric was dipped in carbon soot dispersion (150 ppm) in water which was stabilized by addition of sodium alkylbenzene sulfonate (50 ppm). The fabric was removed from the carbon soot solution and immediately rinsed in water and dried. Change in reflectance ( ⁇ R), i.e. the difference in reflectance of the fabric before and after soiling, was a measure of soiling of fabric, with negative value of ⁇ R indicating that the fabric was soiled.
  • ⁇ R Change in reflectance
  • PEG 17500 polyethylene glycol, molecular mass 17,500.
  • PAA 8000 polyacrylic acid, molecular mass 8,000.
  • PVA 124000 polyvinyl alcohol, molecular mass 125,000.
  • PVP 90000 polyvinyl pyrrolidone molecular mass 90,000.
  • Fabric was treated with polymer and dried. Dried fabric was dipped in carbon soot dispersion (150 ppm) in water which is stabilized by addition of sodium alkylbenzene sulfonate (50 ppm). The fabric was then dried. The dried fabric was then cleaned with water, sodium carbonate (0.15% by weight) solution in water, and commercially available detergent (SURF EXCEL® 0.3% by weight) in water. Change in reflectance ( ⁇ R) was a measure of cleaning of fabric. Higher values of ⁇ R indicate better cleaning.
  • Polymer A was polyacrylic acid of molecular mass 2000 and polymer B was polyvinyl pyrrolidone of molecular mass 90000.
  • Example 6 both the polymers were used at 0.2 % by weight of the aqueous medium.
  • the pH of aqueous medium was 3.0.
  • comparative examples J and K polymers A and B were used alone, respectively, each at 0.4% by weight of the aqueous medium(pH 2.7 and 7.0, respectively).
  • Comparative example L is for untreated fabrics (pH 7).
  • the cleaning efficacy for example 6 is higher than the cleaning efficacy obtained in the comparative examples J, K and L which are outside the scope of the present invention.
  • the cleaning efficacy is better in case of washing with sodium carbonate or water.
  • the results show that cleaning efficacy is particularly enhanced for polycotton and polyester fabrics, when washing is with commercially available surfactant.
  • Polymer A was polyacrylic acid of molecular mass 450,000 and polymer B was polyvinyl pyrrolidone of molecular mass 1,300,000. In all the examples, both the polymers were used at 0.1 % by weight of the aqueous medium. The effect of electrolyte addition was studied by adding various electrolytes at 0.1% by weight of the total aqueous medium. The pH of aqueous media was in the range 2.7 to 3.0. The fabrics (cotton, polycotton and polyester) were cleaned using sodium carbonate (0.15% by weight) solution in water. The results are tabulated below in terms of cleaning efficacy.
  • Allyl amyl glycollate was taken as a representative perfumery ingredient.
  • Polymer A was polyacrylic acid having molecular mass of 450,000 and polymer B was polyvinyl pyrrolidone having molecular mass of 90000.
  • the perfume was added together with both the polymers A and B each at 0.1% by weight of the aqueous medium (Example 11 - pH 2.8), polymer A and polymer B alone each at 0.2% by weight of the aqueous medium (comparative example M - pH 3 and N - pH 7, respectively), whilst comparative example O (pH 7) was for untreated fabric.
  • the perfume retention was evaluated for various types of fabrics.
  • the process of the present invention is capable of meeting the object of providing a process for treatment of fabric that reduces soiling of fabrics, improves efficacy of subsequent cleaning, allows enhanced deposition of benefit agents and is effective on various types of fabrics including cotton, polycotton and polyester.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Claims (8)

  1. Procédé de traitement d'un tissu, comprenant les étapes de mise en contact du tissu avec des polymères A et B dans un milieu aqueux, dans lequel :
    (a) le polymère A est choisi dans la classe des homopolymères ou des copolymères d'alcool vinylique, d'alkylèneglycol, de saccharides et d'acide carboxylique, et ;
    (b) le polymère B est choisi dans la classe des homopolymères ou des copolymères de vinyl pyrrolidone, d'oxyde d'alkylène, de saccharides et d'acide carboxylique, et ;
    (c) un électrolyte choisi parmi les chlorures, les sulfates ou les nitrates de sodium, de potassium, de magnésium ou de calcium ; et
    les polymères A et B ne sont pas de la même classe et le milieu aqueux possède un pH inférieur à 6.
  2. Procédé selon la revendication 1, dans lequel le milieu aqueux comprend au plus 200 ppm de tensioactif anionique.
  3. Procédé selon l'une quelconque des revendications précédentes, dans lequel ledit polymère A est choisi parmi un homopolymère ou un copolymère d'alcool vinylique ou d'acide carboxylique.
  4. Procédé selon l'une quelconque des revendications précédentes, dans lequel ledit polymère B est choisi parmi un homopolymère ou un copolymère de vinyl pyrrolidone ou d'oxyde d'alkylène.
  5. Procédé selon l'une quelconque des revendications précédentes, dans lequel ledit homopolymère ou copolymère d'acide carboxylique est un poly(acide acrylique) ou l'un de ses copolymères.
  6. Procédé selon l'une quelconque des revendications précédentes, dans lequel ledit électrolyte représente 0,001 % à 5 % en poids dudit milieu.
  7. Procédé selon l'une quelconque des revendications précédentes, dans lequel le pH dudit milieu aqueux va de 1 à moins de 6.
  8. Procédé selon l'une quelconque des revendications précédentes, dans lequel le tissu est mis en contact avec les polymères A et B soit de manière séquentielle dans n'importe quel ordre, soit simultanément.
EP08861303A 2007-12-14 2008-10-31 Procédé de traitement d'un tissu Not-in-force EP2220288B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP08861303A EP2220288B1 (fr) 2007-12-14 2008-10-31 Procédé de traitement d'un tissu

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
IN2459MU2007 2007-12-14
EP08150762 2008-01-29
EP08861303A EP2220288B1 (fr) 2007-12-14 2008-10-31 Procédé de traitement d'un tissu
PCT/EP2008/064764 WO2009077255A1 (fr) 2007-12-14 2008-10-31 Procédé de traitement d'un tissu

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EP2220288A1 EP2220288A1 (fr) 2010-08-25
EP2220288B1 true EP2220288B1 (fr) 2012-02-08

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US (1) US20100297359A1 (fr)
EP (1) EP2220288B1 (fr)
JP (1) JP5080652B2 (fr)
CN (1) CN101889111B (fr)
AT (1) ATE544901T1 (fr)
AU (1) AU2008337741B2 (fr)
BR (1) BRPI0820909B1 (fr)
CA (1) CA2707805C (fr)
MY (1) MY153922A (fr)
RU (1) RU2473724C2 (fr)
WO (1) WO2009077255A1 (fr)
ZA (1) ZA201002991B (fr)

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Publication number Priority date Publication date Assignee Title
CA2771140A1 (fr) * 2009-09-02 2011-03-10 Unilever Plc Composition et procede pour le traitement d'un tissu
WO2013113541A1 (fr) 2012-01-31 2013-08-08 Unilever N.V. Composition et procédé de traitement de substrats
CN111094463A (zh) * 2017-09-21 2020-05-01 捷德货币技术有限责任公司 产生具有预定内部和/或外部轮廓的颜料碎片的方法及颜料碎片
EP4108752A1 (fr) * 2021-06-25 2022-12-28 The Procter & Gamble Company Compositions détergentes

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GB994353A (en) * 1960-06-13 1965-06-02 Domestos Ltd Improvements in detergent compositions
GB1340517A (en) * 1969-12-01 1973-12-12 Burton Parsons Chemicals Inc Ophthalmic solution
US3689435A (en) * 1970-07-27 1972-09-05 Gaf Corp Detergency compositions containing a synergistic mixture of pvp and pva
US4007305A (en) * 1974-12-23 1977-02-08 Basf Wyandotte Corporation Method of imparting nondurable soil release and soil repellency properties to textile materials
JPS5945038B2 (ja) * 1977-07-19 1984-11-02 ライオン株式会社 洗浄剤組成物
SU836262A1 (ru) * 1979-08-01 1981-06-07 Латвийский Научно-Исследовательскийинститут Легкой Промышленности Состав дл гр зеотталкивающей отделкицЕллюлОзНыХ ТЕКСТильНыХ МАТЕРиАлОВ
EP0054325B1 (fr) * 1980-12-17 1984-04-11 Unilever N.V. Composition détergente ayant des propriétés empêchant le redépôt
SU1141127A1 (ru) * 1983-01-06 1985-02-23 Украинский Научно-Исследовательский И Конструкторско-Технологический Институт Бытового Обслуживания Состав дл гр зеотталкивающей отделки текстильных изделий
GB8618635D0 (en) * 1986-07-30 1986-09-10 Unilever Plc Detergent composition
JPS6392700A (ja) * 1986-10-08 1988-04-23 花王株式会社 洗浄剤組成物
JP4638034B2 (ja) * 1998-08-25 2011-02-23 クラリアント ファイナンス （ビーブイアイ） リミティド Ｕｖ活性剤の水性組成物、その製造及び使用
US6785989B2 (en) * 2000-03-31 2004-09-07 The Procter & Gamble Company Methods and apparatus for removal of wrinkles from fabrics
US7026278B2 (en) * 2000-06-22 2006-04-11 The Procter & Gamble Company Rinse-added fabric treatment composition, kit containing such, and method of use therefor
JP3965518B2 (ja) * 2002-04-26 2007-08-29 第一工業製薬株式会社 中性洗浄剤
GB0422026D0 (en) * 2004-10-05 2004-11-03 Unilever Plc Laundry product

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BRPI0820909A2 (pt) 2015-07-28
EP2220288A1 (fr) 2010-08-25
CN101889111B (zh) 2013-01-23
WO2009077255A1 (fr) 2009-06-25
CN101889111A (zh) 2010-11-17
RU2010129064A (ru) 2012-01-20
JP5080652B2 (ja) 2012-11-21
US20100297359A1 (en) 2010-11-25
BRPI0820909B1 (pt) 2018-02-27
MY153922A (en) 2015-04-15
CA2707805C (fr) 2016-10-11
AU2008337741B2 (en) 2011-11-24
ATE544901T1 (de) 2012-02-15
AU2008337741A1 (en) 2009-06-25
JP2011506788A (ja) 2011-03-03
CA2707805A1 (fr) 2009-06-25
RU2473724C2 (ru) 2013-01-27
ZA201002991B (en) 2011-07-27

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