EP2211826A2 - Verfahren zur herstellung einer kosmetikzusammensetzung mit dha, in besagtem verfahren hergestellte kosmetikzusammensetzung und anwendungen davon - Google Patents
Verfahren zur herstellung einer kosmetikzusammensetzung mit dha, in besagtem verfahren hergestellte kosmetikzusammensetzung und anwendungen davonInfo
- Publication number
- EP2211826A2 EP2211826A2 EP08857224A EP08857224A EP2211826A2 EP 2211826 A2 EP2211826 A2 EP 2211826A2 EP 08857224 A EP08857224 A EP 08857224A EP 08857224 A EP08857224 A EP 08857224A EP 2211826 A2 EP2211826 A2 EP 2211826A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- dha
- lipid
- capsules
- phase
- aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/04—Preparations for care of the skin for chemically tanning the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
Definitions
- the invention relates to the field of cosmetic compositions in solid form comprising dihydroxyacetone or 1,3-dihydroxy-2-propanone (hereinafter DHA) as self-tanning active ingredient. It relates more particularly to a process for preparing such a cosmetic composition. It also relates to the use of the compositions obtained according to this process for coloring the skin.
- DHA dihydroxyacetone or 1,3-dihydroxy-2-propanone
- Self-tanning cosmetic compositions comprising DHA are well known and are regularly the subject of further developments.
- DHA is, as those skilled in the art well know, a particularly unstable compound and therefore difficult to use. Indeed, the latter is particularly sensitive to variations in pH and temperature, oxidation, especially by oxygen in the air, the presence of certain compounds such as water, iron oxides, certain amino acids or more generally molecules with primary and / or secondary amino groups.
- compositions must firstly overcome at least a double technical problem which consists on the one hand, to be able to apply the DHA satisfactorily in order to obtain an effective coloration and if possible uniformity of the skin and on the other hand, to maintain the stability of the DHA until its application in order to avoid a loss of self-tanning active agent which generates, as is now well known, problems of odor and browning of the product during storage.
- Document EP-0 513 103 B1 discloses a process for protecting and stabilizing DHA, as well as cosmetic products containing it. This process consists in producing a watertight composition in order to maintain the dimer DHA in crystallized form until it is applied.
- the watertight composition protects the DHA from water and oxidation and constitutes an envelope providing a certain thermal insulation. This watertightness is obtained by using a mixture of water-insoluble polymers as the first protective layer, in particular ethylcellulose.
- WO 93/16683 also discloses stabilized self-tanning compositions in emulsion form.
- the oily phase contains at least one fatty acid or a derivative thereof and the aqueous phase contains at least one alkylhydroxyalkylcellulose or a derivative thereof, both of which are present in a precise ratio as essential compounds.
- EP 0 691 839 also discloses fluid compositions based on DHA in the form of a single or multiple emulsion in which the fatty phase comprises a number of particular emulsifiers to provide stability to the emulsion, in particular preferably using solvents, fatty substances and adjuvants having no primary or secondary amine groups, or oxidizing groups capable of reacting with DHA.
- the self-tanning products comprising as self-tanning active agent of DHA do not allow optimum application while preserving DHA, provided that it is in sufficiently fluid form, in particular as a single or multiple emulsion.
- Such emulsions may also contain DHA encapsulated in a liposome-like lamellar structure to stabilize it as described in US 6,007,796 (Nenzel) and US-2007-0009452 (Golz-Berner).
- Other documents such as documents US 4,772,471, FR 2,492,829 and FR 2,597,367 (LOréal) disclose compositions comprising lipid vesicle dispersions encapsulating various active principles.
- compositions described in this document are limited to 5% of DHA, moreover always used in combination with at least one other self-tanning agent which can be incorporated up to 10% and in particular does not have the disadvantages. already mentioned relating to the stability of DHA.
- the method described for preparing the emulsions suggests, contrary to what is said, that the DHA present in the aqueous or aqueous-alcoholic phase is not stable in the long term because in direct contact with known compounds for their harmful effects, in particular iron oxides (see examples 1 to 3) and the oxygen present.
- the obtaining of a self-tanning composition comprising DHA in the form of compact powder or cream-powder is here essentially due to the systematic use in association of a large quantity of at least one other agent. spray tan.
- EP 1 151 741 (L'Oréal) compositions comprising microcapsules having an aqueous core, with a polymeric and / or waxy envelope, which can contain a large number of active ingredients among which DHA is found.
- the microencapsulation method proposed here comprising an evaporation operation of an organic-type solvent used to produce the primary emulsion involved in the microencapsulation process, does not make it possible to obtain microcapsules at the core. non-aqueous, that is to say in totally dry form, where the DHA is in crystallized form inside the microcapsules.
- the main purpose of the invention is to provide a new method for vectorization of DHA for the preparation of solid formulations, typically in powder form, compacted or otherwise, as opposed to well-known fluid formulations such as creams, gels, and the like.
- the lotions which can satisfactorily solve the double technical problem of providing a composition for topical application, which stabilizes the DHA to keep it in undegraded form until it is applied, while allowing a subsequent effective application of it on the skin.
- This double technical problem is solved for the first time for cosmetic compositions preferably in solid form, by the present invention in a simple, inexpensive way, usable on an industrial and commercial scale, and in particular on the cosmetic scale.
- the invention thus makes it possible to use DHA as an effective self-tanning agent in solid compositions, typically powders.
- This family of cosmetics is very widespread because it covers free powders, cast or compacted.
- the invention provides a novel means for vectorizing dihydroxyacetone (DHA) in solid form, incorporating it into lipid capsules.
- DHA dihydroxyacetone
- the invention relates to a process for preparing a cosmetic composition in solid form, comprising lipid capsules containing DHA.
- the invention relates to cosmetic compositions in solid form, comprising capsules lipids containing DHA. These compositions are in particular likely to be obtained by the preparation process forming the subject of the first aspect of the invention.
- the invention relates to a cosmetic method for coloring the skin by applying to predetermined areas of the skin to be colored with an effective amount of a composition that is the subject of the second aspect of the invention. .
- the present invention relates to a method for preparing a cosmetic composition in solid form comprising lipid capsules containing dihydroxyacetone (DHA), characterized in that it comprises the following steps: a) the hot preparation of a double water-in-oil-in-water emulsion having an aqueous continuous continuous phase and a dispersed phase consisting of a continuous lipid phase, in the molten state, whose composition corresponds to that of said lipid capsules, to the interior of which is dispersed an internal aqueous phase consisting of an aqueous solution of dihydroxyacetone (DHA), b) the cooling of said double emulsion, c) the possible incorporation of at least one solid in powder form, d dehydration of said double emulsion, leading to the production of a lipid capsule powder, and e) the possible incorporation of said powder of lipid capsules in at least one cosmetically acceptable excipient.
- DHA dihydroxyacetone
- lipids or lipid capsule
- lipid means a chemical compound comprising at least one linear, branched or cyclic hydrocarbon-based chain of at least 8 carbon atoms, which is soluble or miscible in organic solvents and insoluble in water in the water. temperature range 0 0 C and 100 0 C.
- a lipid in the sense of the invention is a fatty alcohol, a fatty acid, as well as the esters of these acids and alcohols and the ethers of these alcohols, soluble or miscible in organic solvents and insoluble in water in the water.
- lipid means the products of the esterification reaction between a saturated or unsaturated fatty acid and an alcohol.
- the fatty acids considered are organic acids having at least 8 carbon atoms.
- This family of derivatives comprises, on the one hand, so-called simple lipids consisting solely of carbon, hydrogen and oxygen atoms, and on the other hand so-called complex lipids which furthermore comprise other categories of atoms, in particular nitrogen, sulfur or phosphorus atoms, among which mention will be made of phospholipids, sphingolipids and glycerophospholipids.
- lipids are also included fatty acids having a linear, branched or cyclic, saturated or unsaturated alkyl chain comprising at least 10 carbon atoms, the fatty alcohols having a linear, branched or cyclic alkyl chain, saturated or unsaturated compound comprising at least 14 carbon atoms, as well as the esters of these acids and alcohols and the ethers of these alcohols.
- the alcohols are chosen in particular from glycerol, sterols and fatty alcohols having a linear or branched alkyl chain comprising at least 14 carbon atoms.
- the glycerol esters are chosen from mono-, di- or triglycerides of fatty acids of natural or synthetic origin, preferably those having an alkyl chain. linear or branched comprising from 8 to 24 carbon atoms, in particular glycerol trimyristate, glycerol tripalmitate, glycerol monostearate and glycerol cetylpalmitate.
- the lipid esters of the invention may also be chosen from waxes, which are esters of fatty acids and of fatty alcohols, namely mainly monoesters of carboxylic acids having an alkyl chain comprising 14 to 30 carbon atoms and of alcohols having an alkyl chain, preferably linear and saturated, comprising from 14 to 36 carbon atoms.
- waxes which are esters of fatty acids and of fatty alcohols, namely mainly monoesters of carboxylic acids having an alkyl chain comprising 14 to 30 carbon atoms and of alcohols having an alkyl chain, preferably linear and saturated, comprising from 14 to 36 carbon atoms.
- said lipids are such that said lipid capsules have a melting temperature of between 45 ° C. and 65 ° C.
- the lipids are chosen from fatty acid esters and of alcohols selected from glycerol, sterols or alcohols having a linear or branched alkyl chain comprising at least 14 carbon atoms, natural or synthetic fatty acids comprising at least 10 carbon atoms and their esters, and fatty alcohols comprising at least 14 carbon atoms and their esters and ethers.
- the lipids are advantageously chosen from mono-, di- or triesters of glycerol and of fatty acids having a linear or branched hydrocarbon chain comprising from 8 to 24 carbon atoms, preferably in the group consisting of glycerol trimyristate, glycerol tripalmitate, glycerol monostearate and glycerol cetylpalmitate.
- Such lipids are commercially available and in particular under the following trade names: Suppocire® DM and AM from Gattefossé; Dynasan® 114 and 118 from Sasol Company; and Crodamol GTS from Croda Chemicals.
- a double emulsion of water-in-oil-in-water type having an aqueous external continuous phase and a dispersed phase consisting of a continuous lipid phase is prepared hot. melt, the composition of which corresponds to that of said lipid capsules, inside which is dispersed an internal aqueous phase consisting of an aqueous solution of dihydroxyacetone (DHA).
- DHA dihydroxyacetone
- the concentration of DHA in the solution used to prepare said double emulsion is between 0.5% and 90% by weight, advantageously between 5% and 70% by weight.
- step b) of the process according to the invention said double emulsion is allowed to cool under conventionally appropriate conditions.
- step d) At least one solid in the pulverulent state is optionally incorporated in the said double emulsion.
- This step can also be carried out after step d) described below, but to allow a better homogenization of the composition. it is preferable to implement step c) before step d).
- step c) before step d).
- Well known powder formulations are the isotropic distribution of the active ingredients, here the DHA, within the powder.
- said solid may consist of organic and / or inorganic fillers in variable proportions, for example oxides of titanium, zinc or zirconium, silica, polyamides and polyesters.
- a fourth step d) of the process according to the invention said double emulsion is subjected to a dehydration operation leading to the production of a powder of said lipid capsules.
- the dehydration may be partial, the DHA being found partially or totally incorporated in an aqueous phase internal to said lipid capsules.
- the dehydration can lead to the production of lipid capsules, the internal part of which comprises at least partly or even totally of the DHA solubilized in the internal aqueous phase of said lipid capsules.
- the DHA may also be partly in the crystallized state, since the DHA precipitates in solid form if dehydration is continued once saturation of the internal aqueous phase of said lipid capsules has been reached.
- the dehydration can be complete, the DHA being found crystallized inside said lipid capsules.
- the step of dehydrating said continuous phase of said double water in oil-in-water emulsion is obtained by freeze-drying or flash-type atomization, preferably by lyophilization.
- the dehydration operation is preceded, preferably, by the addition of a cryoprotectant in the aqueous continuous continuous phase of said double emulsion.
- a cryoprotectant it is possible to use at least one polyol, sodium chloride or a solution of at least one salt capable of lowering the melting point of water, and mixtures thereof.
- polyols examples include glycerin, mannitol, sorbitol, polyethylene glycol or sugar such as mannose, glucose, fructose, xylose, trehalose and mixtures thereof.
- salt capable of lowering the melting point of water sodium chloride is preferably used.
- said lipid capsule powder is optionally incorporated into a cosmetically acceptable excipient.
- This cosmetically acceptable excipient may for example consist of at least one solid in the pulverulent state as in optional step c), in particular for free powder formulations, or at least one binder, ie a fatty substance, especially for compact powder type formulations.
- all kinds of self-tanning cosmetic compositions can be prepared in solid form, in particular in the form of a powder.
- the process is conventionally carried out by mixing fillers and pigments that have been ground beforehand with the aid of a coffee grinder, for example with solid lipid capsules and compounds that do not require grinding, such as nacre. It is also possible to add other well-known cosmetically acceptable agents such as fatty substances, preservatives, sunscreens, perfumes. If it is desired to make a compact powder, use a binder, that is to say a fatty substance and sieving the final composition before compacting it in buckets.
- the oils may be chosen from animal, vegetable, mineral or synthetic oils and in particular from liquid petroleum jelly, paraffin oil, silicone oils, volatile or not, isoparaffins, polyolefins, fluorinated oils and the like. perfluorinated.
- the waxes can be chosen from animal, fossil, vegetable, mineral or synthetic waxes known per se.
- waxes that can be used in the context of the present invention, mention may be made, for example, of beeswax, candelilla wax, wax of
- the double emulsion obtained at the end of step a) according to the process of the invention may, if appropriate, also comprise one or more active ingredients that the skilled person will be able to incorporate according to their lipophilic nature. or hydrophilic. Those skilled in the art will choose from among the known surfactants that which is suitable for the emulsion which it wishes to prepare.
- said lipid capsules may additionally contain a pH adjusting agent, in order to maintain the pH of the inner aqueous phase of said capsules between 3 and 6, preferably between 3 and 6. 4, such as a buffer composition comprising a mixture of sodium bisulfite and lactic acid.
- a pH adjusting agent such as a buffer composition comprising a mixture of sodium bisulfite and lactic acid.
- said lipid capsules may further contain at least one antioxidant stabilizing DHA, preferably selected from sodium mono- or bisulfite, ascorbic acid hydroquinone.
- said lipid capsules further contain a DHA stabilizing agent, in particular at a concentration of between 0.1% and 5% by weight relative to the total weight of the aqueous solution.
- an alkylhydroxyalkylcellulose in which the alkyl group comprises from 8 to 30 carbon atoms and the hydroxyalkyl group comprises 1 to 4 carbon atoms, preferably ethylhydroxyethylcellulose, a hydroxyalkylcellulose with alkyl chain comprising 1 to 4 carbon atoms, preferably hydroxyethylcellulose, and methylcellulose, or a mixture thereof.
- the presence of pH adjusting agents, antioxidant, or stabilizing DHA in the internal phase of said lipid capsules results from the addition of said agent or agents during the preparation of the double emulsion in step a) of process according to the invention.
- the method according to the invention comprises the following steps: i) a first water-in-oil emulsion is prepared by incorporating under hot shear, preferably in the presence of a surfactant having an HLB value of less than or equal to 10, a first aqueous phase consisting of an aqueous solution of DHA, which preferably contains at least one pH adjusting agent and / or at least one DHA stabilizing agent, in a melted lipid phase, the composition of which is that of the wall of said lipid capsules, ii) then, is incorporated under shearing heat-treating said first emulsion in a previously heated aqueous second phase, preferably in the presence of a surfactant having an HLB value greater than or equal to 10, to form said double emulsion comprising said second aqueous phase as an aqueous continuous continuous phase, iii ) it is allowed to cool to a temperature below 30 ° C., iv) said double emulsion obtained
- the solid-form composition obtained by the process can be in the form of a free powder or a compacted powder.
- the method of the invention makes it possible to obtain novel cosmetic compositions, in the case where the dehydration carried out in stage d) is total, and where the internal phase of said lipid capsules is completely crystallized, all the water initially present having been evaporated.
- These compositions have the particular advantage of being completely anhydrous and thus of having improved stability.
- the invention also relates to cosmetic compositions, in particular capable of being obtained by the process according to the invention, in solid form and containing lipid capsules containing dihydroxyacetone (DHA) as the active ingredient bronzer, characterized in that:
- DHA dihydroxyacetone
- said lipid capsules comprise, as essential constituent, a lipid having a melting point of greater than or equal to 30 ° C. or a mixture of lipids having a melting temperature greater than or equal to 30 ° C., said lipids optionally containing surfactants and / or or organic and / or inorganic fillers and / or liposoluble compounds and being present in an amount sufficient for said lipid capsules to have a melting point of between 30 ° C. and 75 ° C., and
- the DHA is found crystallized inside said lipid capsules.
- essential constituent means that the lipid capsule may also contain a generally very small amount of surfactant solubilized inherently during the preparation of the emulsions necessary for the manufacture of said lipid capsules (see method exposed upper).
- the person skilled in the art may also, during the preparation of the first oil-in-water emulsion, disperse organic and / or mineral fillers in a variable proportion such that the melting temperature of the capsule remains between 30 and 75 ° C.
- the concentration of DHA is between 0.5 and 90% by weight, advantageously between 5 and 70% by weight, relative to the total weight of the content of said lipid capsules.
- the cosmetic composition according to the invention may comprise from 0.1% to 10%, preferably from 1% to 6% by weight of DHA encapsulated in said capsules relative to the total weight of said cosmetic composition.
- it may be a composition in the form of a free powder or a compacted powder.
- the cosmetic composition may further comprise a moisturizing active agent, preferably chosen from glycerine, trimethylglycine or hyaluronic acid.
- a moisturizing active agent preferably chosen from glycerine, trimethylglycine or hyaluronic acid.
- the size of the lipid capsules according to the invention depends on the average diameter of the dispersed phase in the aqueous continuous phase during the preparation of the double emulsion. Indeed, the average diameter of the dispersed phase, whose composition is that of said lipid capsules, prefigures the size of the future lipid capsules that will solidify during cooling.
- the size of the lipid capsules according to the invention may thus vary between 1 and 100 ⁇ m, preferably between 5 and 25 ⁇ m.
- the present invention also relates to a cosmetic method for coloring the skin, characterized in that, on predetermined areas of the skin to be colored by a person, an effective amount of a composition in the form of solid as defined above, or obtainable by the method as defined above, to obtain the desired coloration.
- An internal aqueous phase and an external fatty phase are prepared in a conventional manner.
- an aqueous solution is used as an internal phase composed of: 49.97% of DHA, 0.05% of sodium disulphite, 0.12% of lactic acid,
- This double water-in-oil emulsion in non-calibrated water containing DHA in the internal phase is then cooled to room temperature, at which temperature the lipid mixture according to the invention, here the wax, is in solid form, thus forming an interface protective lipid surrounding compartments containing the internal aqueous phase containing DHA, dispersed in the external aqueous phase.
- the previously prepared non-calibrated double emulsion is then frozen and placed in a freeze-dryer to be dehydrated.
- a dry powder consisting of lipid capsules is then recovered within which is found 8.54% by weight of DHA in stabilized form relative to the total weight of capsules. Indeed, after 1 month of aging at 45 ° C. in an oven, the DHA content only decreased by 1.75% and after 3 months at 45 ° C. by 6.51% relative to the total weight of capsules . By way of comparison, the level of free DHA decreases by 8% after 1 month of aging at 45 ° C.
- Lb Preparation of lyophilized lipid capsules containing DHA from a double-calibrated emulsion
- a solution serving as an internal phase is prepared from: 55.90% of DHA, 0.06% sodium disulphite, 0.13% lactic acid, 2.68% sodium chloride,
- This double-sized emulsion is then cooled to room temperature, at which temperature the lipid mixture according to the invention, here the wax, is in solid form, thus forming a protective lipid interface surrounding compartments containing the internal aqueous phase containing DHA. dispersed in the external aqueous phase.
- the double-calibrated emulsion thus cooled is then frozen and placed in a lyophilizer to be dehydrated.
- a dry powder is then recovered in the form of solid lipid capsules within which there is 9.13% by weight of stabilized DHA relative to the total weight of the capsules.
- This non-calibrated double emulsion containing the DHA in the internal phase is then cooled to room temperature, at which temperature the lipid mixture according to the invention, here the wax, is in solid form thus forming a protective lipid interface surrounding compartments containing the internal aqueous phase containing DHA, dispersed in the external aqueous phase.
- the previously prepared non-calibrated double emulsion is then frozen and placed in a freeze-dryer to be dehydrated.
- a dry powder consisting of lipid capsules is then recovered inside which there is 5.0% by weight of DHA in stabilized form relative to the total weight of capsules.
- the lipid capsules described above can be directly used in the context of a cosmetic process for coloring the skin. For this purpose, it is applied to the areas of the skin to be colored by a person in need of solid lipid capsules containing DHA directly. It is found that after a few days the skin has a golden tan and uniform.
- Self-tanning cosmetic compositions in the form of powders comprising freeze-dried lipid capsules containing DHA
- EA-209 is a copolymer of ethylene and acrylic acid marketed by KOBO Products, Inc.
- This composition contains 2.52% of DHA by weight relative to the total weight of the composition.
- the DHA level decreased by only 36.43% by weight and after three months by 55.72% by weight relative to the total weight of the composition.
- the level of DHA present in an identical powder but comprising free DHA drops by 96% by weight relative to the total weight of the composition after 1 month of aging at 45 ° C.
- KSP-300 is a copolymer of diphenyl dimethicone / vinyl dimethicone / silsesquioxane sold by Shin-Etsu Chemicals Co.
- the self-tanning cosmetic compositions described above may be used in the context of a cosmetic process for coloring the skin. For this, one applies, on the areas of the skin to be stained by a person in need, a cosmetic composition containing said solid lipid capsules at a rate of once a day for 15 days.
- the lipid capsules according to the invention open more or less rapidly, thus releasing DHA, by contact with the skin and / or by mechanical shear during application. .
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0759429 | 2007-11-29 | ||
PCT/FR2008/052161 WO2009071861A2 (fr) | 2007-11-29 | 2008-11-28 | Procede de preparation d'une composition cosmetique contenant de la dha, compositions obtenues selon ce procede, et leurs utilisations |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2211826A2 true EP2211826A2 (de) | 2010-08-04 |
Family
ID=39587884
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08857224A Withdrawn EP2211826A2 (de) | 2007-11-29 | 2008-11-28 | Verfahren zur herstellung einer kosmetikzusammensetzung mit dha, in besagtem verfahren hergestellte kosmetikzusammensetzung und anwendungen davon |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP2211826A2 (de) |
WO (1) | WO2009071861A2 (de) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2953397B1 (fr) * | 2009-12-07 | 2012-01-13 | Oreal | Procede de traitement cosmetique |
WO2011067707A2 (en) * | 2009-12-02 | 2011-06-09 | L'oreal | A cosmetic treatment method |
FR3102929B1 (fr) * | 2019-11-08 | 2021-10-22 | Lvmh Rech | Composition contenant de la DHA |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2408387A2 (fr) * | 1975-06-30 | 1979-06-08 | Oreal | Compositions a base de dispersions aqueuses de spherules lipidiques |
DE3016170A1 (de) * | 1980-04-26 | 1981-10-29 | Bayer Ag, 5090 Leverkusen | Mikrokapseln mit definierter oeffnungstemperatur, verfahren zu deren herstellung sowie deren verwendung |
FR2492829A1 (fr) * | 1980-10-24 | 1982-04-30 | Oreal | Agents de surface non-ioniques derives du glucose, procede pour les preparer et compositions les contenant |
FR2597367B1 (fr) * | 1986-04-22 | 1988-07-15 | Oreal | Procede pour faciliter la formation de spherules lipidiques en dispersion dans une phase aqueuse et pour ameliorer leur stabilite et leur taux d'encapsulation, et dispersions correspondantes. |
FR2657607B1 (fr) * | 1990-01-30 | 1992-04-30 | Durand Muriel | Procede de protection de la dihydroxyacetone, dihydroxyacetone protegee par ce procede et produit cosmetique contenant une telle dihydroxyacetone protegee. |
EP0818986A1 (de) * | 1995-04-03 | 1998-01-21 | Henkel Kommanditgesellschaft auf Aktien | Selbstbräunungsmittel |
DE10015363B4 (de) * | 2000-03-23 | 2004-08-12 | Coty B.V. | Kosmetischer Kompakt- oder Cremepuder |
CN1189159C (zh) * | 2000-05-05 | 2005-02-16 | 欧莱雅 | 含水溶性美容活性组分水性核的微胶囊及含其的组合物 |
-
2008
- 2008-11-28 EP EP08857224A patent/EP2211826A2/de not_active Withdrawn
- 2008-11-28 WO PCT/FR2008/052161 patent/WO2009071861A2/fr active Application Filing
Non-Patent Citations (1)
Title |
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See references of WO2009071861A3 * |
Also Published As
Publication number | Publication date |
---|---|
WO2009071861A3 (fr) | 2009-12-10 |
WO2009071861A2 (fr) | 2009-06-11 |
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