EP2209773A4 - Novel thiophene-based dye and preparation thereof - Google Patents

Novel thiophene-based dye and preparation thereof

Info

Publication number
EP2209773A4
EP2209773A4 EP08839120A EP08839120A EP2209773A4 EP 2209773 A4 EP2209773 A4 EP 2209773A4 EP 08839120 A EP08839120 A EP 08839120A EP 08839120 A EP08839120 A EP 08839120A EP 2209773 A4 EP2209773 A4 EP 2209773A4
Authority
EP
European Patent Office
Prior art keywords
preparation
based dye
novel thiophene
thiophene
novel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP08839120A
Other languages
German (de)
French (fr)
Other versions
EP2209773A2 (en
Inventor
Ho-Gi Bae
Chong-Chan Lee
Jong-Bok Kim
Hyoung-Don Moon
Tae-Jin Park
Jong-Hyub Baek
Hoe-Taek Yang
Hyun-Cheol An
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongjin Semichem Co Ltd
Original Assignee
Dongjin Semichem Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongjin Semichem Co Ltd filed Critical Dongjin Semichem Co Ltd
Priority to EP12161959.7A priority Critical patent/EP2471785B1/en
Priority to EP12161958.9A priority patent/EP2471784B1/en
Publication of EP2209773A2 publication Critical patent/EP2209773A2/en
Publication of EP2209773A4 publication Critical patent/EP2209773A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
    • C07D333/24—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B49/00—Sulfur dyes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/12—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains three hetero rings
    • C07D495/14—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B11/00—Diaryl- or thriarylmethane dyes
    • C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
    • C09B11/10—Amino derivatives of triarylmethanes
    • C09B11/12—Amino derivatives of triarylmethanes without any OH group bound to an aryl nucleus
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/0008—Methine or polymethine dyes, e.g. cyanine dyes substituted on the polymethine chain
    • C09B23/005—Methine or polymethine dyes, e.g. cyanine dyes substituted on the polymethine chain the substituent being a COOH and/or a functional derivative thereof
    • C09B23/0058—Methine or polymethine dyes, e.g. cyanine dyes substituted on the polymethine chain the substituent being a COOH and/or a functional derivative thereof the substituent being CN
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/10—The polymethine chain containing an even number of >CH- groups
    • C09B23/105—The polymethine chain containing an even number of >CH- groups two >CH- groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B49/00—Sulfur dyes
    • C09B49/06—Sulfur dyes from azines, oxazines, thiazines or thiazoles
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B57/00—Other synthetic dyes of known constitution
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2027—Light-sensitive devices comprising an oxide semiconductor electrode
    • H01G9/2031—Light-sensitive devices comprising an oxide semiconductor electrode comprising titanium oxide, e.g. TiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2059—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/542—Dye sensitized solar cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells
EP08839120A 2007-10-15 2008-10-15 Novel thiophene-based dye and preparation thereof Withdrawn EP2209773A4 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP12161959.7A EP2471785B1 (en) 2007-10-15 2008-10-15 Novel thiophene-based dye and preparation thereof
EP12161958.9A EP2471784B1 (en) 2007-10-15 2008-10-15 Novel thiophene-based dye and preparation thereof

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
KR20070103629 2007-10-15
KR20070137908 2007-12-26
KR20080038731 2008-04-25
KR20080062482 2008-06-30
PCT/KR2008/006056 WO2009051390A2 (en) 2007-10-15 2008-10-15 Novel thiophene-based dye and preparation thereof

Related Child Applications (2)

Application Number Title Priority Date Filing Date
EP12161959.7A Division EP2471785B1 (en) 2007-10-15 2008-10-15 Novel thiophene-based dye and preparation thereof
EP12161958.9A Division EP2471784B1 (en) 2007-10-15 2008-10-15 Novel thiophene-based dye and preparation thereof

Publications (2)

Publication Number Publication Date
EP2209773A2 EP2209773A2 (en) 2010-07-28
EP2209773A4 true EP2209773A4 (en) 2011-06-22

Family

ID=40567944

Family Applications (3)

Application Number Title Priority Date Filing Date
EP08839120A Withdrawn EP2209773A4 (en) 2007-10-15 2008-10-15 Novel thiophene-based dye and preparation thereof
EP12161959.7A Not-in-force EP2471785B1 (en) 2007-10-15 2008-10-15 Novel thiophene-based dye and preparation thereof
EP12161958.9A Not-in-force EP2471784B1 (en) 2007-10-15 2008-10-15 Novel thiophene-based dye and preparation thereof

Family Applications After (2)

Application Number Title Priority Date Filing Date
EP12161959.7A Not-in-force EP2471785B1 (en) 2007-10-15 2008-10-15 Novel thiophene-based dye and preparation thereof
EP12161958.9A Not-in-force EP2471784B1 (en) 2007-10-15 2008-10-15 Novel thiophene-based dye and preparation thereof

Country Status (6)

Country Link
EP (3) EP2209773A4 (en)
JP (2) JP2011500882A (en)
KR (2) KR101330601B1 (en)
CN (3) CN103254659B (en)
TW (2) TWI491677B (en)
WO (1) WO2009051390A2 (en)

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TWI458787B (en) 2009-05-15 2014-11-01 Ind Tech Res Inst Organic dyes and photoelectric conversion devices
WO2010147427A2 (en) * 2009-06-19 2010-12-23 주식회사 동진쎄미켐 Novel organic dye and preparation method thereof
JP5782220B2 (en) * 2009-06-24 2015-09-24 富士フイルム株式会社 Dye compound, photoelectric conversion element using the same, and dye-sensitized solar cell
TWI392775B (en) * 2009-08-26 2013-04-11 Cheng Tung Glass Co Ltd Method of producing single crystal nanorods-poly(3-hexylthiophene-2,5-diyl) (p3ht) complex and uses thereof
WO2011091608A1 (en) * 2010-01-30 2011-08-04 海洋王照明科技股份有限公司 Quinoid thiophene organic photoelectric material, method for its preparation and application thereof
DE102010030500A1 (en) 2010-06-24 2011-12-29 Heliatek Gmbh Evaporatable organic semiconducting material and its use in an optoelectronic device
EP2400575B1 (en) * 2010-06-24 2016-03-23 heliatek GmbH Optoelectronic construction element with organic layers
JP5722579B2 (en) * 2010-09-14 2015-05-20 山本化成株式会社 Ditetraazaporphyrin-based compound and dye-sensitized solar cell using the compound
WO2012049167A1 (en) * 2010-10-11 2012-04-19 Universite De La Mediterranee Aix-Marseille Ii Novel oligothiophene derivatives, their process of preparation and their uses
WO2013084932A1 (en) * 2011-12-09 2013-06-13 Jsr株式会社 Colorant, colored composition, color filter, and display element
JP2013181108A (en) * 2012-03-01 2013-09-12 Kanto Natural Gas Development Co Ltd Highly-active complete organic dye compound for dye-sensitized photoelectric conversion element, and photoelectric conversion element using the same
ITMI20120674A1 (en) * 2012-04-23 2013-10-24 Cnrs Ct Nat De La Rech He Scient ORGANIC COLORING FOR SOLAR CELL SENSITIVE TO DYES
JP5515188B2 (en) * 2012-11-20 2014-06-11 株式会社日本化学工業所 Novel pyrazoline compound and photoelectric conversion device using the same
DE102013101713B4 (en) 2013-02-21 2020-10-01 Heliatek Gmbh Photoactive, organic material for optoelectronic components
DE102013101712B4 (en) 2013-02-21 2020-05-28 Heliatek Gmbh Photoactive organic material for optoelectronic components
JP6056605B2 (en) * 2013-03-28 2017-01-11 富士通株式会社 Organic dye and photosensitive element
CN103450700B (en) * 2013-08-23 2015-12-02 中山大学 A kind of tree-shaped organic dye based on carbazole or triphenylamine derivative and preparing the application in dye sensitization solar battery
DE102013110693B4 (en) 2013-09-27 2024-04-25 Heliatek Gmbh Photoactive organic material for optoelectronic components
CN103834190B (en) * 2013-12-09 2015-07-22 中国科学院长春应用化学研究所 Benzothiadiazole-cyanocinnamic acid receptor-containing organic dye and its use in dye-sensitized solar cell
JP6326140B2 (en) * 2014-08-27 2018-05-16 富士フイルム株式会社 Compound, composition, film, optical instrument
CN104311549B (en) * 2014-09-29 2017-07-07 浙江工业大学 A kind of synthesis and application of carbazoles dye sensitizing agent
DE102015101768A1 (en) 2015-02-06 2016-08-11 Technische Universität Dresden light absorber
DE102015101835A1 (en) 2015-02-09 2016-08-11 Technische Universität Dresden light absorber
JP2018014426A (en) 2016-07-21 2018-01-25 キヤノン株式会社 Organic compound and organic photoelectric conversion element having the same
CN108164546B (en) * 2018-02-27 2021-03-30 华南理工大学 Indoline-dithienoquinoxaline-dibenzo [ a, c ] phenazine dye and application thereof in dye-sensitized solar cell
CN109705612B (en) * 2018-11-27 2020-05-05 西安近代化学研究所 4,4' -di (alkoxybenzene) bithiophene bridged thiourea triphenylamine photosensitive dye and preparation method thereof
CN113200957B (en) * 2021-04-09 2022-02-22 西安工业大学 Acid/alkali dye co-sensitization system and preparation method and application thereof

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Also Published As

Publication number Publication date
TW200927840A (en) 2009-07-01
JP2011500882A (en) 2011-01-06
TWI545160B (en) 2016-08-11
EP2471784A1 (en) 2012-07-04
EP2471785B1 (en) 2017-04-19
CN101821250B (en) 2014-03-26
TWI491677B (en) 2015-07-11
KR101330601B1 (en) 2013-11-18
KR20130082489A (en) 2013-07-19
JP5886812B2 (en) 2016-03-16
EP2471784B1 (en) 2015-07-08
EP2471785A1 (en) 2012-07-04
KR101352024B1 (en) 2014-01-22
CN103254658A (en) 2013-08-21
EP2209773A2 (en) 2010-07-28
CN103254658B (en) 2015-03-11
CN103254659A (en) 2013-08-21
TW201520278A (en) 2015-06-01
JP2014065913A (en) 2014-04-17
WO2009051390A2 (en) 2009-04-23
WO2009051390A3 (en) 2009-07-16
KR20090038377A (en) 2009-04-20
CN101821250A (en) 2010-09-01
CN103254659B (en) 2015-11-18

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