EP2185763B1 - Method for eliminating foam in a drum washing machine and drum washing machine suitable therefor - Google Patents
Method for eliminating foam in a drum washing machine and drum washing machine suitable therefor Download PDFInfo
- Publication number
- EP2185763B1 EP2185763B1 EP08774906A EP08774906A EP2185763B1 EP 2185763 B1 EP2185763 B1 EP 2185763B1 EP 08774906 A EP08774906 A EP 08774906A EP 08774906 A EP08774906 A EP 08774906A EP 2185763 B1 EP2185763 B1 EP 2185763B1
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- European Patent Office
- Prior art keywords
- drum
- foam
- rotational speed
- level
- hydrostatic pressure
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- 239000006260 foam Substances 0.000 title claims description 72
- 238000005406 washing Methods 0.000 title claims description 38
- 238000000034 method Methods 0.000 title claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 49
- 230000002706 hydrostatic effect Effects 0.000 claims description 35
- 239000000203 mixture Substances 0.000 claims description 14
- 238000009987 spinning Methods 0.000 claims description 12
- 238000005086 pumping Methods 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 6
- 230000009467 reduction Effects 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 230000008859 change Effects 0.000 claims description 4
- 230000003287 optical effect Effects 0.000 claims description 2
- 238000012423 maintenance Methods 0.000 claims 2
- 230000001105 regulatory effect Effects 0.000 claims 1
- 208000012886 Vertigo Diseases 0.000 description 12
- 238000001514 detection method Methods 0.000 description 11
- 238000005187 foaming Methods 0.000 description 5
- 230000002123 temporal effect Effects 0.000 description 5
- 101150114468 TUB1 gene Proteins 0.000 description 3
- 239000003599 detergent Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F39/00—Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00
- D06F39/06—Arrangements for preventing or destroying scum
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F2105/00—Systems or parameters controlled or affected by the control systems of washing machines, washer-dryers or laundry dryers
- D06F2105/02—Water supply
Definitions
- the invention relates to a method for removing foam in a drum washing machine and a drum washing machine suitable for this purpose.
- the invention relates to a method for removing existing foam in a tub of a drum washing machine with a program control for controlling a program sequence comprising a sequence of steps comprising adding water and rotating the drum and a drum washing machine suitable therefor.
- the foam is destroyed by switching on a heater.
- the drum In order to destroy the foam in the wider vicinity of the heater, the drum is rotated slowly so that more foam passes to the heater and is destroyed there by supplying heat.
- the DE 102 34 472 A1 describes a method for removing foam in a tub of an electronically controlled drum washing machine as a result of a program step, which is provided for dehydrating the tub, with a arranged at the bottom of the tub lye drain system with a drain pump and with a sensor for determining the height of the liquid in the tub.
- the course of the sensor signal (P) is recorded during the operation of the drain pump, contains a gradient Ap n / .DELTA.t n compared to Ap n-1 / .DELTA.t n-1, indicating the presence of foam, whereupon one of the Gradient-matched foam treatment measure is initiated, for example, supplying a certain amount of water or changing the speed of the laundry drum.
- the EP 1 063 341 A2 describes a washing machine with a tub and a rotatable washing zone, which has a detection device for determining the state of the wash liquor and the output of a signal and a control device for receiving this signal and for issuing predetermined commands for the washing of textiles.
- a detection device for determining the state of the wash liquor and the output of a signal
- a control device for receiving this signal and for issuing predetermined commands for the washing of textiles.
- One such condition is a so-called “suds lock", a foam barrier. This results in a pronounced foaming a large tensile force on the drum, which leads to a significant decrease in the rotational speed of the drum. The operation of the washing machine should then be adjusted.
- the EP 0 268 155 A2 describes a program-controlled washing machine with a drum in a tub, from which the washing and rinsing is discharged by means disposed in a drain line drain pump, wherein the drain line a pipe is connected to a sensor whose output signals an indication of the foaming during the spin process are and constitute control variables for the drive motor of the laundry drum and thus for the control of the spin speed. For example, the spin speed is reduced until the foam limit falls below again.
- the EP 0 724 036 A1 describes a washing and drying machine for clothes equipped with a foam reducing arrangement.
- the machine comprises a tub and a rotatably mounted drum therein a pressure sensor and processing and control means which receive the signal of the pressure sensor as a measure of the pressure in an air chamber and periodically reproduce its mean value.
- a predetermined foaming control washing program is modified.
- the modification may consist in a reduction in the rotational speed of the drum or an addition of a larger amount of water in at least one rinsing phase.
- the foam is usually removed by means of adapted rinsing baths with the greatest possible avoidance of the introduction of mechanical energy (for example due to long downtimes of the drum).
- a disadvantage of the known methods is that they sometimes lead to a considerable lengthening of the overall washing program, greatly increased water consumption and a poor spinning result.
- the object of the invention was therefore the. To provide a method by which the foam produced in a washing machine can be combated more effectively than with conventional methods. In addition, it was an object of the invention to provide a drum washing machine suitable for carrying out this method.
- the present invention is therefore a method for removing detected foam in a drum washing machine with a program control for controlling a program flow, a rotatably mounted in a tub drum, a water inlet system, arranged at the bottom of the tub lye drain system with a drain pump, a drive motor for the Drum and a sensor for determining a foam level h s and / or a negative temporal gradient of the foam level (ie s / dt) of a liquid-air mixture in the tub, wherein detected by the sensor foam during a Centrifugal start-up of the drum, ie a continuous or discontinuous increase in the speed of the drum, continuously or discontinuously switched on a small amount of water is added at continuously or discontinuously switched liquor pump, wherein in a spin the foam level h s monitored by the sensor and depending on the foam level h s a Controlled speed of the drum, so that with an increase in the foam level h s, the speed is reduced, while maintaining the foam level h s,
- the water supply system is generally directed to the laundry located in the drum or into a space between the drum and the tub.
- a small amount of water is generally added after a successful pumping out of washing liquor, continuously or discontinuously.
- a quantity of water can be preset depending on the amount of laundry loaded in a drum.
- a known load detection can be carried out in the drum washing machine. For example, load detection can be performed on the amount of water that has accumulated and, in particular, on a comparison between measured hydrostatic pressures and the amount of water that has been admitted.
- the maximum foam level h smax is preferably adapted to the amount of laundry in the drum.
- the senor may be a single sensor or a system of multiple sensors.
- the term sensor includes besides the actual sensor preferably also a corresponding system for registration and transmission of the data to a program control.
- the senor is an optical measuring system, a conductometric measuring system, a capacitive measuring system or a pressure measuring system.
- a pressure measuring system In the event that a pressure measuring system is used, this is preferably also used for the regulation of a water level during a wash and / or rinse cycle.
- a pressure measuring system As a measure of the foam level h s and / or a negative time gradient of the foam level (ie s / dt) of a liquid-air mixture in the tub, preferably a hydrostatic pressure p and a negative time gradient of the hydrostatic pressure ( dp / dt) of a liquid-air mixture in the tub.
- the continuous amount of water is 0.5 to 1.5 l / min. In a preferred alternative embodiment, the discontinuously tapered amount of water is 0.2 to 2 l in each case.
- the slow rotation of the drum is preferably carried out at a speed in the range of 10 to 40 revolutions per minute, for example, at 35 revolutions per minute.
- the negative temporal gradient of the hydrostatic pressure (-dp / dt) is advantageously measured in step A).
- the presence of a liquid-air mixture (foam) generally manifests itself in a plot of hydrostatic pressure p versus time t during pump down by a more or less pronounced kink which indicates a decrease in the negative time gradient of hydrostatic pressure (-dp / dt).
- the predetermined amount of water .DELTA.V i and / or .DELTA.V j is adapted to a loading of the drum with laundry.
- the predetermined amount of water ⁇ V i and / or ⁇ V j is 0.5 to 2 liters.
- the amounts of water ⁇ V i and ⁇ V j may be the same or different.
- the amounts of water ⁇ V i and ⁇ V j are set so that both are equal.
- the low speed U 1 is preferably in the range of 15 to 45 revolutions per minute.
- the speed U 2 is at least 100 revolutions per minute.
- steps C2) and C3) are preferably carried out simultaneously.
- step F at a pressure p ⁇ p 2, the rotational speed U of the drum is increased until reaching a predetermined maximum rotational speed U max , which is preferably in the range from 900 to 1100 revolutions per minute.
- the increase in speed can be gradual or in one or more stages.
- the time intervals ⁇ t 1 and ⁇ t 2 may be the same or different. Preferably, they are the same.
- a foam detection can be carried out.
- foam liquid-air mixture
- Foam detection can also be carried out by means of a conductivity measurement with two electrodes in the lower region of the tub.
- a foam detection during spinning by means of an evaluation of the target / actual speed difference is possible.
- the foam detection by evaluation of the target / lst speed difference the fact is exploited that the foam can brake a rotating drum, whereby there is a difference between the target and the actual speed.
- the association between a specific foam concentration and the target / difference is generally stored in a data memory of the drum washing machine.
- the invention also relates to a drum washing machine with a program control for controlling a program sequence, a drum rotatably mounted in a tub, a water supply system, a liquor drain system arranged at the bottom of the tub with a drain pump, a drive motor for the drum, a sensor for determining a foam level h s and / or a negative temporal Gradients (ie, s / dt) of a liquid-air mixture in the tub, and switching means for rotating, accelerating, decelerating and / or stopping the drum, wherein the switching means can perform the method of the invention described above.
- the drum washing machine according to the invention preferably also has a heating device.
- the method and drum washing machine of the present invention enable rapid and efficient foam removal. Generally, any foam that has been ejected is not applied to the laundry again. When using reduced amounts of water, the invention makes it possible to avoid residual foam on the laundry and the cuff. In this case, the invention makes possible an automatic adaptation of the foam removal measure to the actual formation of foam.
- FIG. 1 is a schematic representation of the relevant parts of a drum washing machine according to the invention, in which a method according to the invention for the removal of foam can be carried out.
- FIG. 1 is a schematic representation of the relevant parts of a drum washing machine according to the invention, in which a method according to the invention for the removal of foam can be carried out.
- Other embodiments are conceivable.
- the drum washing machine of in FIG. 1 embodiment shown has a tub 1, in which a drum 2 is rotatably mounted and driven by the drive motor 14.
- the rotational axis 3 of the drum 2 is directed from the horizontal by a small angle (eg 13 °) forwardly upwards, so that the user of the drum washing machine has easier access and insight into the interior of the drum 2.
- the drum washing machine also has a liquor inlet system comprising a water connection fitting for the domestic water network 8, an electrically controllable valve 9 and a supply line 10 to the tub 1, which may optionally also be guided via a Waschstoffein Why Surprise ("Ein Hamptonschale") 11, from the Inlet water can transport detergent portions into the tub.
- a heater 13 in the tub 1, a heater 13.
- the valve 9 as well as the heater 13 can be controlled by a control device (“program control”) 12 in response to a program flowchart of a time program and / or the achievement of certain measurements of Parameters such as liquor level, liquor temperature, speed of the drum, etc. may be bound within the drum washing machine.
- 15 means a sensor for measuring the hydrostatic pressure or its negative time gradient in the tub 1.16 means a drain pump for pumping out the wash liquor.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Control Of Washing Machine And Dryer (AREA)
- Detail Structures Of Washing Machines And Dryers (AREA)
Description
Die Erfindung betrifft ein Verfahren zum Beseitigen von Schaum in einer Trommelwaschmaschine und eine hierzu geeignete Trommelwaschmaschine. Insbesondere betrifft die Erfindung ein Verfahren zum Beseitigen von vorhandenem Schaum in einem Laugenbehälter einer Trommelwaschmaschine mit einer Programmsteuerung zur Steuerung eines Programmablaufs mit einer Abfolge von Schritten, die eine Zugabe von Wasser sowie ein Drehen der Trommel umfassen, sowie eine hierzu geeignete Trommelwaschmaschine.The invention relates to a method for removing foam in a drum washing machine and a drum washing machine suitable for this purpose. In particular, the invention relates to a method for removing existing foam in a tub of a drum washing machine with a program control for controlling a program sequence comprising a sequence of steps comprising adding water and rotating the drum and a drum washing machine suitable therefor.
In herkömmlichen Trommelwaschmaschinen wird bereits nach der Hauptwäsche und den Spülgängen hochtourig geschleudert. Wenn viel Schaum vorhanden ist oder beim Schleudern entsteht, fördert die Laugenpumpe das Schaum-Laugengemisch nicht. Das Schleudern wird daher bei Schaumdetektion im Abpumpen nicht ausgeführt oder im Falle einer Schaumdetektion während des Schleuderns abgebrochen. Außerdem kann der Schaum aus den Öffnungen des Laugenbehälters wie der Laugenbehälterbelüftung und dem Einfüllschlauch austreten. Eine frühzeitige Schaumerkennung und effiziente Maßnahmen zur Beseitigung des Schaums sind daher wichtig.In conventional drum washing machines, high speed is thrown after the main wash and the rinse cycles. If a lot of foam is present or is produced during spinning, the lye pump does not promote the foam-lye mixture. The spin is therefore not performed in foam detection in the pumping or stopped in the event of foam detection during spin. In addition, the foam can escape from the openings of the tub as the tub ventilation and the filling hose. Early foam detection and efficient measures to remove the foam are therefore important.
Gemäß der
In der
Außerdem sind Verfahren zum Beseitigen von Schaum in einem Laugenbehälter einer Trommelwaschmaschine aus der
Die
In der
Die
Die
Die
Überdies wird üblicherweise in speziellen Verfahrensabläufen der Schaum durch angepasste Spülbäder unter größtmöglicher Vermeidung des Eintrags von mechanischer Energie (beispielsweise durch lange Stillstandszeiten der Trommel) beseitigt.Moreover, in customary processes, the foam is usually removed by means of adapted rinsing baths with the greatest possible avoidance of the introduction of mechanical energy (for example due to long downtimes of the drum).
Bei den bekannten Verfahren ist nachteilig, dass sie mitunter zu einer erheblichen Verlängerung des gesamten Waschprogramms, stark erhöhtem Wasserverbrauch und einem schlechten Ergebnis beim Schleudern führen.A disadvantage of the known methods is that they sometimes lead to a considerable lengthening of the overall washing program, greatly increased water consumption and a poor spinning result.
Aufgabe der Erfindung war daher die. Bereitstellung eines Verfahrens, mit dem der in einer Waschmaschine entstehende Schaum wirksamer bekämpft werden kann als mit herkömmlichen Verfahren. Außerdem war es Aufgabe der Erfindung, eine zur Durchführung dieses Verfahrens geeignete Trommelwaschmaschine aufzuzeigen.The object of the invention was therefore the. To provide a method by which the foam produced in a washing machine can be combated more effectively than with conventional methods. In addition, it was an object of the invention to provide a drum washing machine suitable for carrying out this method.
Erfindungsgemäß werden diese Aufgaben durch ein Verfahren mit den Merkmalen von Anspruch 1 und durch eine Trommelwaschmaschine mit den Merkmalen von Anspruch 12 gelöst. Vorteilhafte Ausgestaltungen der Erfindung sind in den Unteransprüchen aufgeführt.According to the invention, these objects are achieved by a method having the features of claim 1 and by a drum washing machine having the features of
Gegenstand der vorliegenden Erfindung ist somit ein Verfahren zum Beseitigen von erkanntem Schaum in einer Trommelwaschmaschine mit einer Programmsteuerung zur Steuerung eines Programmablaufs, einer in einem Laugenbehälter drehbar gelagerten Trommel, einem Wasserzulaufsystem, einem am Boden des Laugenbehälters angeordneten Laugenablaufsystem mit einer Laugenpumpe, einem Antriebsmotor für die Trommel und einem Sensor zur Bestimmung eines Schaumniveaus hs und/oder eines negativen zeitlichen Gradienten des Schaumniveaus (dhs/dt) einer im Laugenbehälter befindlichen Flüssigkeit-Luft-Mischung, wobei bei vom Sensor erkanntem Schaum während eines Schleuderhochlaufs der Trommel, d.h. einem kontinuierlichen oder diskontinuierlichen Erhöhen der Drehzahl der Trommel, bei kontinuierlich oder diskontinuierlich eingeschalteter Laugenpumpe kontinuierlich oder diskontinuierlich eine kleine Wassermenge zugegeben wird, wobei bei einem Schleudern das Schaumniveau hs mittels des Sensors überwacht und in Abhängigkeit vom Schaumniveau hs eine Drehzahl der Trommel gesteuertwird, so dass bei einer Erhöhung des Schaumniveaus hs die Drehzahl verringert wird, bei einer Beibehaltung des Schaumniveaus hs die Drehzahl beibehalten wird und/oder bei einer Verringerung des Schaumniveaus hs die Drehzahl erhöht wird, und eine maximal zulaufende Wassermenge während des Schleuderhochlaufs an die Menge der In der Trommel befindlichen Wäsche angepasst ist.The present invention is therefore a method for removing detected foam in a drum washing machine with a program control for controlling a program flow, a rotatably mounted in a tub drum, a water inlet system, arranged at the bottom of the tub lye drain system with a drain pump, a drive motor for the Drum and a sensor for determining a foam level h s and / or a negative temporal gradient of the foam level (ie s / dt) of a liquid-air mixture in the tub, wherein detected by the sensor foam during a Centrifugal start-up of the drum, ie a continuous or discontinuous increase in the speed of the drum, continuously or discontinuously switched on a small amount of water is added at continuously or discontinuously switched liquor pump, wherein in a spin the foam level h s monitored by the sensor and depending on the foam level h s a Controlled speed of the drum, so that with an increase in the foam level h s, the speed is reduced, while maintaining the foam level h s, the speed is maintained and / or with a reduction in the foam level h s, the speed is increased, and a maximum amount of water during the spin-up is adapted to the amount of laundry in the drum.
Das Wasserzulaufsystem ist im Allgemeinen auf die in der Trommel befindliche Wäsche oder in einen Zwischenraum zwischen der Tommel und dem Laugenbehälter gerichtet.The water supply system is generally directed to the laundry located in the drum or into a space between the drum and the tub.
im erfindungsgemäßen Verfahren wird im Allgemeinen nach einem erfolgten Abpumpen von Waschlauge kontinuierlich oder diskontinuierlich eine kleine Menge Wasser zugegeben.In the process according to the invention, a small amount of water is generally added after a successful pumping out of washing liquor, continuously or discontinuously.
Hierzu kann beispielsweise in Abhängigkeit von der in eine Trommel eingefüllten Menge an Wäsche eine Wassermenge vorgegeben werden. Alternativ kann in der Trommelwaschmaschine eine an sich bekannte Beladungserkennung durchgeführt werden. Eine Beladungserkennung kann beispielsweise Ober die zugelaufene Wassermenge und Insbesondere durch einen Vergleich zwischen gemessenen hydrostatischen Drucken und zugelaufener Wassermenge durchgeführt werden.For this purpose, for example, depending on the amount of laundry loaded in a drum, a quantity of water can be preset. Alternatively, a known load detection can be carried out in the drum washing machine. For example, load detection can be performed on the amount of water that has accumulated and, in particular, on a comparison between measured hydrostatic pressures and the amount of water that has been admitted.
Bei Überschreiten eines maximalen Schaumniveaus hsmax wird die Drehzahl im Allgemeinen bis zum Stillstand der Trommel herabgesetzt. Das maximale Schaumniveau hsmax ist vorzugsweise an die Menge der in der Trommel befindlichen Wäsche angepasst.When a maximum foam level h smax is exceeded , the speed is generally reduced until the drum stops. The maximum foam level h smax is preferably adapted to the amount of laundry in the drum.
Bei dem Sensor kann es sich um einen einzelnen Sensor oder um ein System aus mehreren Sensoren handeln. Desgleichen umfasst der Begriff Sensor neben dem eigentlichen Sensor vorzugsweise auch ein entsprechendes System zur Registrierung und Übermittlung der Daten an eine Programmsteuerung.The sensor may be a single sensor or a system of multiple sensors. Likewise, the term sensor includes besides the actual sensor preferably also a corresponding system for registration and transmission of the data to a program control.
In bevorzugten Ausführungsformen der Erfindung ist der Sensor ein optisches Messsystem, ein konduktometrisches Messsystem, ein kapazitives Messsystem oder ein Druckmesssystem.In preferred embodiments of the invention, the sensor is an optical measuring system, a conductometric measuring system, a capacitive measuring system or a pressure measuring system.
Für den Fall, dass ein Druckmesssystem eingesetzt wird, wird dieses vorzugsweise zusätzlich für die Regelung eines Wasserstands während eines Wasch- und/oder Spülgangs genutzt.In the event that a pressure measuring system is used, this is preferably also used for the regulation of a water level during a wash and / or rinse cycle.
Bei Verwendung eines Druckmesssystems wird als Maß für das Schaumniveau hs und/oder eines negativen zeitlichen Gradienten des Schaumniveaus (dhs/dt) einer im Laugenbehälter befindlichen Flüssigkeit-Luft-Mischung vorzugsweise ein hydrostatischer Druck p und ein negativer zeitlicher Gradient des hydrostatischen Drucks (dp/dt) einer im Laugenbehälter befindlichen Flüssigkeit-Luft-Mischung gemessen.When using a pressure measuring system, as a measure of the foam level h s and / or a negative time gradient of the foam level (ie s / dt) of a liquid-air mixture in the tub, preferably a hydrostatic pressure p and a negative time gradient of the hydrostatic pressure ( dp / dt) of a liquid-air mixture in the tub.
In einer bevorzugten Ausführungsform der Erfindung beträgt die kontinuierlich zulaufende Wassermenge 0,5 bis 1,5 l / min. In einer bevorzugten alternativen Ausführungsform beträgt die diskontinuierlich zulaufende Wassermenge jeweils 0,2 bis 2 l.In a preferred embodiment of the invention, the continuous amount of water is 0.5 to 1.5 l / min. In a preferred alternative embodiment, the discontinuously tapered amount of water is 0.2 to 2 l in each case.
In einer ganz besonders bevorzugten Ausführungsform ist die Erfindung ein Verfahren zum Beseitigen von erkanntem Schaum in einer Trommelwaschmaschine mit einer Programmsteuerung zur Steuerung eines Programmablaufs, einer in einem Laugenbehälter drehbar gelagerten Trommel, einem Wasserzulaufsystem, einem am Boden des Laugenbehälters angeordneten Laugenablaufsystem mit einer Laugenpumpe, einem Antriebsmotor für die Trommel, einer Heizeinrichtung und einem Sensor zur Bestimmung eines hydrostatischen Drucks p und/oder eines negativen zeitlichen Gradienten des hydrostatischen Drucks (dp/dt) einer im Laugenbehälter befindlichen Flüssigkeit-Luft-Mischung, wobei die folgenden Schritte A) bis F) durchgeführt werden:
- A) Bei Stillstand oder langsamem Drehen der Trommel, vorzugsweise bei Stillstand der Trommel, Abpumpen der Flüssigkeit-Luft-Mischung und nach einer vorgegebenen Zeit Δt1 Messen des hydrostatischen Drucks p und/oder des negativen zeitlichen Gradienten des hydrostatischen Drucks (-dp/dt);
- B) Vergleich des in Schritt A) gemessenen hydrostatischen Drucks p mit einem vorgegebenen Schwellenwert p1 für den hydrostatischen Druck p und/oder Vergleich des in Schritt A) gemessenen negativen zeitlichen Gradienten des hydrostatischen Drucks (-dp/dt) mit einem vorgegebenen Schwellenwert (-dp/dt)1 für den negativen zeitlichen Gradienten des hydrostatischen Drucks (-dp/dt), und
- C) bei Vorliegen der Bedingungen (-dp/dt) < (-dp/dt)1 und p > p1 Durchführen der folgenden Schritte C1) bis C3),
- C1) Zugabe einer vorgegebenen kleinen Wassermenge ΔVi,
- C2) Drehen der Trommel mit einer vorgegebenen niedrigen Drehzahl U1, vorzugsweise in abwechselnden Richtungen, ggf. unterbrochen von einem Stillstehen der Trommel,
- C3) Abpumpen der Flüssigkeit-Luft-Mischung, Messen des hydrostatischen Drucks p und Wiederholen von Schritt B),
- D) bei Vorliegen der Bedingung (-dp/dt) > (-dp/dt)1 oder p < p1 Durchführen der folgenden Schritte D1) bis D4)
- D1) bei einem Druck p, der größer als ein vorgegebener Druck p2 ist, wobei p2 < p < p1 gilt, Zugabe einer vorgegebenen kleinen Wassermenge ΔVj und Drehen der Trommel bei eingeschalteter Pumpe mit einer Drehzahl U2 > U1, wobei nach einem vorgegebenen Zeitintervall Δt2 der hydrostatische Druck p gemessen wird und in Abhängigkeit von einer Änderung des hydrostatischen Drucks p nach Ablauf des Zeitintervalls Δt2 einer der folgenden Schritte D2) bis D4) durchgeführt wird;
- D2) bei einem Ansteigen des hydrostatischen Drucks p Zugabe einer vorgegebenen kleinen Wassermenge AVj, Herabsetzen der Drehzahl U1 um einen Betrag ΔUi und Drehen der Trommel mit der Drehzahl U1-AUi;
- D3) bei einem Gleichbleiben des hydrostatischen Drucks p Zugabe einer vorgegebenen kleinen Wassermenge ΔVj und Drehen der Trommel mit unveränderter Drehzahl U1;
- D4) bei einer Abnahme des hydrostatischen Drucks p Zugabe einer vorgegebenen kleinen Wassermenge ΔVj, Erhöhen der Drehzahl U1 um einen Betrag ΔUj und Drehen der Trommel mit der Drehzahl U1-ΔUj;
- D5) Messen des hydrostatischen Drucks p nach Ablauf eines Zeitintervalls Δt2, und für den Fall, dass p > p1 ist und eine Summe Σ ΔVi,j der zugegebenen Wassermengen ΔVi,j kleiner als eine vorgegebene maximal zulässige Wassermenge Wz ist, Durchführung eines der Schritte D2) bis D4) in Abhängigkeit von der nach dem Zeitintervall Δt2 eingetretenen Änderung des Drucks;
- E) für den Fall ΣΔVi,j > Wz Wiederholen der Schritte A) bis D5);
- F) bei einem Druck p < p2 Erhöhung der Drehzahl U der Trommel bis zum Erreichen einer vorgegebenen maximalen Drehzahl Umax.
- A) At standstill or slow rotation of the drum, preferably at standstill of the drum, pumping the liquid-air mixture and after a given time .DELTA.t 1 measuring the hydrostatic pressure p and / or the negative temporal gradient of the hydrostatic pressure (-dp / dt );
- B) Comparison of the hydrostatic pressure p measured in step A) with a predetermined threshold value p 1 for the hydrostatic pressure p and / or comparison of the negative temporal gradient of the hydrostatic pressure (-dp / dt) measured in step A) with a predefined threshold value ( -dp / dt) 1 for the negative time gradient of the hydrostatic pressure (-dp / dt), and
- C) in the presence of the conditions (-dp / dt) <(-dp / dt) 1 and p> p 1 performing the following steps C1) to C3),
- C1) adding a predetermined small amount of water ΔV i ,
- C2) rotating the drum at a predetermined low speed U 1 , preferably in alternating directions, possibly interrupted by a standstill of the drum,
- C3) pumping out the liquid-air mixture, measuring the hydrostatic pressure p and repeating step B),
- D) in the presence of the condition (-dp / dt)> (-dp / dt) 1 or p <p 1 performing the following steps D1) to D4)
- D1) at a pressure p which is greater than a predetermined pressure p 2 , where p 2 <p <p 1 , adding a predetermined small amount of water ΔV j and rotating the drum with the pump switched on at a speed U 2 > U 1 , wherein after a predetermined time interval .DELTA.t 2, the hydrostatic pressure p is measured and in response to a change in the hydrostatic pressure p after the expiration of the time interval .DELTA.t 2 one of the following steps D2) to D4) is performed;
- D2) with an increase in the hydrostatic pressure p adding a predetermined small amount of water AV j , reducing the speed U 1 by an amount ΔU i and rotating the drum at the speed U 1 -AU i ;
- D3) at a constant hydrostatic pressure p addition of a predetermined small amount of water .DELTA.V j and rotating the drum with unchanged speed U 1 ;
- D4) with a decrease in the hydrostatic pressure p adding a predetermined small amount of water ΔV j , increasing the speed U 1 by an amount ΔU j and rotating the drum at the speed U 1 -ΔU j ;
- D5) measuring the hydrostatic pressure p after a time interval Δt 2 , and in the event that p> p is 1 and a sum Σ ΔV i, j of the added amounts of water .DELTA.V i, j is less than a predetermined maximum allowable amount of water W z Performing one of the steps D2) to D4) as a function of the change in pressure which has occurred after the time interval Δt 2 ;
- E) for the case ΣΔV i, j > W z repeating steps A) to D5);
- F) at a pressure p <p 2 increase the speed U of the drum until reaching a predetermined maximum speed U max .
Im vorgenannten Schritt A) erfolgt das langsame Drehen der Trommel vorzugsweise mit einer Drehzahl im Bereich von 10 bis 40 Umdrehungen pro Minute, beispielsweise mit 35 Umdrehungen pro Minute. Außerdem wird im Schritt A) vorteilhaft der negative zeitliche Gradient des hydrostatischen Drucks (-dp/dt) gemessen. Das Vorhandensein einer Flüssigkeit-Luft-Mischung (Schaum) zeigt sich im Allgemeinen in einer Auftragung von hydrostatischem Druck p gegen die Zeit t während eines Abpumpens durch einen mehr oder weniger ausgeprägten Knick, der eine Abnahme des negativen zeitlichen Gradienten des hydrostatischen Drucks (-dp/dt) anzeigt.In the aforementioned step A), the slow rotation of the drum is preferably carried out at a speed in the range of 10 to 40 revolutions per minute, for example, at 35 revolutions per minute. In addition, the negative temporal gradient of the hydrostatic pressure (-dp / dt) is advantageously measured in step A). The presence of a liquid-air mixture (foam) generally manifests itself in a plot of hydrostatic pressure p versus time t during pump down by a more or less pronounced kink which indicates a decrease in the negative time gradient of hydrostatic pressure (-dp / dt).
In einer bevorzugten Ausführungsform des erfindungsgemäßen Verfahrens ist die vorgegebene Wassermenge ΔVi und / oder ΔVj an eine Beladung der Trommel mit Wäsche angepasst.In a preferred embodiment of the inventive method, the predetermined amount of water .DELTA.V i and / or .DELTA.V j is adapted to a loading of the drum with laundry.
Im Allgemeinen beträgt die vorgegebene Wassermenge ΔVi und / oder ΔVj 0,5 bis 2 Liter. Die Wassermengen ΔVi und ΔVj können gleich oder unterschiedlich sein. Vorzugsweise werden die Wassermengen ΔVi und ΔVj so eingestellt, dass beide gleich sind.In general, the predetermined amount of water ΔV i and / or ΔV j is 0.5 to 2 liters. The amounts of water ΔV i and ΔV j may be the same or different. Preferably, the amounts of water ΔV i and ΔV j are set so that both are equal.
Erfindungsgemäß liegt die niedrige Drehzahl U1 vorzugsweise im Bereich von 15 bis 45 Umdrehungen pro Minute. Vorzugsweise beträgt die Drehzahl U2 mindestens 100 Umdrehungen pro Minute.According to the invention, the low speed U 1 is preferably in the range of 15 to 45 revolutions per minute. Preferably, the speed U 2 is at least 100 revolutions per minute.
Bei dem vorgenannten bevorzugten Verfahren werden vorzugsweise die Schritte C2) und C3) gleichzeitig durchgeführt.In the aforementioned preferred method, steps C2) and C3) are preferably carried out simultaneously.
Im Schritt F) wird bei einem Druck p < p2 die Drehzahl U der Trommel bis zum Erreichen einer vorgegebenen maximalen Drehzahl Umax, die vorzugsweise im Bereich von 900 bis 1100 Umdrehungen pro Minute liegt, erhöht. Die Erhöhung der Drehzahl kann allmählich oder in einer oder mehreren Stufen erfolgen.In step F), at a pressure p <p 2, the rotational speed U of the drum is increased until reaching a predetermined maximum rotational speed U max , which is preferably in the range from 900 to 1100 revolutions per minute. The increase in speed can be gradual or in one or more stages.
Die Zeitintervalle Δt1 und Δt2 können gleich oder verschieden sein. Vorzugsweise sind sie gleich.The time intervals Δt 1 and Δt 2 may be the same or different. Preferably, they are the same.
Vor Durchführung des erfindungsgemäßen Verfahrens kann eine Schaumdetektion durchgeführt werden.Before carrying out the process according to the invention, a foam detection can be carried out.
Üblicherweise wird die Anwesenheit von Schaum (Flüssigkeit-Luft-Gemisch) über einen Druckaufbau beim Waschen oder Schleudern oder über eine stark verlangsamte Druckabnahme beim Abpumpen detektiert.Usually, the presence of foam (liquid-air mixture) is detected by a build-up of pressure during washing or spinning or by a greatly reduced pressure decrease during pumping.
Die Schaumdetektion kann auch Ober eine Leitwertmessung mit zwei Elektroden im unteren Bereich des Laugenbehälters erfolgen. Darüber hinaus ist eine Schaumdetektion beim Schleudern mittels einer Auswertung der Soll/Ist-Drehzahldifferenz möglich. Bei der Schaumdetektion mittels Auswertung der Soll/lst-Drehzahldifferenz wird der Umstand ausgenutzt, dass der Schaum eine sich drehende Trommel bremsen kann, wodurch es zu einem Unterschied zwischen der Soll- und der Ist-Drehzahl kommt. Hierbei ist die Zuordnung zwischen einer bestimmten Schaumkonzentration und der Soll/ist-Differenz im Allgemeinen in einem Datenspeicher der Trommelwaschmaschine hinterlegt.Foam detection can also be carried out by means of a conductivity measurement with two electrodes in the lower region of the tub. In addition, a foam detection during spinning by means of an evaluation of the target / actual speed difference is possible. In the foam detection by evaluation of the target / lst speed difference, the fact is exploited that the foam can brake a rotating drum, whereby there is a difference between the target and the actual speed. In this case, the association between a specific foam concentration and the target / difference is generally stored in a data memory of the drum washing machine.
Bei einer Detektion von Schaum während des Schleuderns wird das Schleudern abgebrochen und das erfindungsgemäße Verfahren durchgeführt.Upon detection of foam during spinning, spinning is stopped and the process of the invention is carried out.
Die Erfindung betrifft außerdem eine Trommelwaschmaschine mit einer Programmsteuerung zur Steuerung eines Programmablaufs, einer in einem Laugenbehälter drehbar gelagerten Trommel, einem Wasserzulaufsystem, einem am Boden des Laugenbehälters angeordneten Laugenablaufsystem mit einer Laugenpumpe, einem Antriebsmotor für die Trommel, einem Sensor zur Bestimmung eines Schaumniveaus hs und/oder eines negativen zeitlichen Gradienten (dhs/dt) einer im Laugenbehälter befindlichen Flüssigkeit-Luft-Mischung, sowie Schaltmitteln zum Drehen, Beschleunigen, Abbremsen und/oder Anhalten der Trommel, wobei die Schaltmittel das oben beschriebene erfindungsgemäße Verfahren durchführen können. Vorzugsweise weist die erfindungsgemäße Trommelwaschmaschine überdies eine Heizeinrichtung auf.The invention also relates to a drum washing machine with a program control for controlling a program sequence, a drum rotatably mounted in a tub, a water supply system, a liquor drain system arranged at the bottom of the tub with a drain pump, a drive motor for the drum, a sensor for determining a foam level h s and / or a negative temporal Gradients (ie, s / dt) of a liquid-air mixture in the tub, and switching means for rotating, accelerating, decelerating and / or stopping the drum, wherein the switching means can perform the method of the invention described above. The drum washing machine according to the invention preferably also has a heating device.
Das Verfahren und die Trommelwaschmaschine der vorliegenden Erfindung ermöglichen eine schnelle und effiziente Schaumbeseitigung. Im Allgemeinen wird einmal ausgeschleuderter Schaum nicht wieder auf die Wäsche aufgetragen. Die Erfindung ermöglicht bei Einsatz reduzierter Wassermengen die Vermeidung von restlichem Schaum auf Wäsche und Manschette. Die Erfindung ermöglicht hierbei eine automatische Anpassung der Schaumbeseitigungsmaßnahme an die tatsächlich erfolgte Bildung von Schaum.The method and drum washing machine of the present invention enable rapid and efficient foam removal. Generally, any foam that has been ejected is not applied to the laundry again. When using reduced amounts of water, the invention makes it possible to avoid residual foam on the laundry and the cuff. In this case, the invention makes possible an automatic adaptation of the foam removal measure to the actual formation of foam.
Die Erfindung wird im Folgenden anhand der
Die Trommelwaschmaschine der in
Die Trommelwaschmaschine weist zudem ein Laugenzulaufsystem auf, das eine Wasseranschlussarmatur für das Hauswassernetz 8, ein elektrisch steuerbares Ventil 9 und eine Zuleitung 10 zum Laugenbehälter 1 umfasst, die gegebenenfalls auch über eine Waschmitteleinspüleinrichtung ("Einspülschale") 11 geführt sein kann, aus der das Zulaufwasser Waschmittelportionen in den Laugenbehälter transportieren kann. Außerdem befindet sich im Laugenbehälter 1 eine Heizeinrichtung 13. Das Ventil 9 wie auch die Heizeinrichtung 13 können durch eine Steuereinrichtung ("Programmsteuerung") 12 in Abhängigkeit von einem Programmablaufplan gesteuert werden, der an ein Zeitprogramm und/oder an das Erreichen von gewissen Messwerten von Parametern wie Laugenniveau, Laugentemperatur, Drehzahl der Trommel usw. innerhalb der Trommelwaschmaschine gebunden sein kann. 15 bedeutet einen Sensor für die Messung des hydrostatischen Druckes bzw. seines negativen zeitlichen Gradienten im Laugenbehälter 1.16 bedeutet eine Laugenpumpe zum Abpumpen der Waschlauge.The drum washing machine also has a liquor inlet system comprising a water connection fitting for the
Claims (12)
- Method of eliminating foam in a drum washing machine with a program control (12) for control of a program sequence, a drum (2) rotatably mounted in a solution container (1), a water feed system (8, 9, 10), a solution drain system, which is arranged at the base of the solution container (1), with a solution pump (16), a drive motor (14) for the drum (2) and a sensor (15) for determining the level hs of foam and/or a negative time gradient (dhs/dt) of the foam level of a liquid/air mixture in the solution container (1), characterised in that when foam is recognised by the sensor (15) during spinning run-up of the drum (2), i.e. a continuous or discontinuous increase in the rotational speed of the drum (2), with the solution pump (16) switched on continuously or discontinuously a small quantity of water is added continuously or discontinuously, wherein the level hs of foam is monitored by means of the sensor (15) during spinning and a rotational speed of the drum (2) is controlled in dependence on the level hs of foam so that in a case of increase in the level hs of foam the rotational speed is reduced, in a case of maintenance of the level hs of foam the rotational speed is maintained and/or in a case of a reduction in the level hs of foam the rotational speed is increased, and a maximum feed quantity of water is adapted during the spinning run-up to the amount of laundry present in the drum (2).
- Method according to claim 1, characterised in that in the case of exceeding a maximum level hsmax of foam the rotational speed is reduced to standstill of the drum (2).
- Method according to claim 2, characterised in that the maximum level hsmax of foam is adapted to the amount of laundry present in the drum (2).
- Method according to any one of claims 1 to 3, characterised in that the sensor (15) is an optical measuring system.
- Method according to any one of claims 1 to 3, characterised in that the sensor (15) is a conductometric measuring system.
- Method according to any one of claims 1 to 3, characterised in that the sensor (15) is a capacitive measuring system.
- Method according to any one of claims 1 to 3, characterised in that the sensor (15) is a pressure measuring system.
- Method according to claim 7, characterised in that the pressure measuring system is additionally used for regulating a water state during a washing and/or rinsing process.
- Method according to any one of claims 1 to 8, characterised in that the continuously fed water quantity is 0.5 to 1.5 l/min.
- Method according to any one of claims 1 to 8, characterised in that the discontinuously fed water quantity is in each instance 0.2 to 2 l.
- Method according to any one of claims 1 to 10, characterised in that the following steps A) to F) are carried out:A) in the case of standstill or slow rotation of the drum, pumping away of the liquid/air mixture and after a predetermined time Δt1 measuring the hydrostatic pressure p and/or the negative time gradient (-dp/dt) of the hydrostatic pressure;B) comparing the hydrostatic pressure p measured in step A) with a predetermined threshold value p1 for the hydrostatic pressure p and/or comparing the negative time gradient (-dp/dt), which is measured in step A), of the hydrostatic pressure with a predetermined threshold value (-dp/dt)1 for the negative time gradient (-dp/dt) of the hydrostatic pressure andC) performing the following steps C1) to C3) if the conditions (-dp/dt) < (-dp/dt)1 and p > p1 are present:C1) adding a predetermined small water quantity ΔVi;C2) rotating the drum at a predetermined low rotational speed U1;C3) pumping away the liquid/air mixture, measuring the hydrostatic pressure p and repeating step B);D) performing the following steps D1) to D4) if the condition (-dp/dt) > (-dp/dt)1 or p < p1 is present:D1) in the case of pressure p greater than a predetermined pressure p2, wherein p2 < p < p1, adding a predetermined small water quantity ΔVj and rotating the drum at a rotational speed U2 > U1 with the pump switched on, wherein after a predetermined time interval Δt2 the hydrostatic pressure p is measured and depending on a change in the hydrostatic pressure p after expiry of the time interval Δt2 one of the following steps D2) to D4) is performed:D2) in the case of a rise in the hydrostatic pressure p adding a predetermined small water quantity ΔVj, reducing the rotational speed U1 by an amount ΔUi and rotating the drum at the rotational speed U1 - AUi;D3) in the case of the hydrostatic pressure p remaining the same adding a predetermined small water quantity ΔVj and rotating the drum at unchanged rotational speed U1;D4) in the case of reduction in the hydrostatic pressure p adding a predetermined small water quantity ΔVj, increasing the rotational speed U1 by an amount ΔUj androtating the drum at the rotational speed U1 - ΔUj;D5) measuring the hydrostatic pressure p after expiry of a time interval Δt2 and if p > p1 and a sum ∑ΔVi,j of the added water quantities ΔVi,j is smaller than a predetermined maximum permissible water quantity Wz carrying out one of the steps D2) to D4) in dependence on the change in pressure occurring after the time internal Δt2;E) repeating the steps A) to D5) if ∑ΔVi,j > Wz; andF) in the case of a pressure p < p2 increasing the rotational speed U of the drum until reaching a predetermined maximum rotational speed Umax.
- Drum washing machine with a program control (12) for control of a program sequence, a drum (2) rotatably mounted in solution container (1), a water feed system (8, 9, 10), a solution drain system, which is arranged at the base of the solution container (1), with a solution pump (16), a drive motor (14) for the drum (2) and a sensor (15) for determining the level hs of foam and/or a negative time gradient (dhs/dt) [of the foam level] of a liquid/air mixture in the solution container (1), as well as switching means (9, 12, 14) for rotating, accelerating, braking and/or stopping the drum, characterised in that the switching means (9, 12, 14) are arranged for eliminating foam in the drum washing machine in that when foam is recognised by the sensor (15) during spinning run-up of the drum (2) with the solution pump (16) switched on continuously or discontinuously a small quantity of water is added continuously or discontinuously, wherein the level hs of foam is monitored by means of the sensor (15) during spinning and a rotational speed of the drum (2) is controlled in dependence on the level hs of foam so that in a case of increase in the level hs of foam the rotational speed is reduced, in a case of maintenance of the level hs of foam the rotational speed is maintained and/or in a case of a reduction in the level hs of foam the rotational speed is increased, and a maximum feed quantity of water is adapted during the spinning run-up to the amount of laundry present in the drum (2).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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PL08774906T PL2185763T3 (en) | 2007-08-01 | 2008-07-09 | Method for eliminating foam in a drum washing machine and drum washing machine suitable therefor |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE102007036041A DE102007036041A1 (en) | 2007-08-01 | 2007-08-01 | Method for removing foam in a drum washing machine and drum washing machine suitable for this purpose |
PCT/EP2008/058900 WO2009016009A1 (en) | 2007-08-01 | 2008-07-09 | Method for eliminating foam in a drum washing machine and drum washing machine suitable therefor |
Publications (2)
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EP2185763A1 EP2185763A1 (en) | 2010-05-19 |
EP2185763B1 true EP2185763B1 (en) | 2012-11-28 |
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EP08774906A Active EP2185763B1 (en) | 2007-08-01 | 2008-07-09 | Method for eliminating foam in a drum washing machine and drum washing machine suitable therefor |
Country Status (7)
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US (1) | US8510887B2 (en) |
EP (1) | EP2185763B1 (en) |
CN (1) | CN101772600B (en) |
DE (1) | DE102007036041A1 (en) |
EA (1) | EA017259B1 (en) |
PL (1) | PL2185763T3 (en) |
WO (1) | WO2009016009A1 (en) |
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ES2367639T3 (en) * | 2009-07-09 | 2011-11-07 | MIELE & CIE. KG | WASHER WITH A DEVICE TO AVOID FOAM OUTPUT. |
DE102009045433B4 (en) | 2009-10-07 | 2011-09-15 | BSH Bosch und Siemens Hausgeräte GmbH | Process for treating foam, correspondingly programmed control device and corresponding laundry treatment machine |
TR201101412A2 (en) | 2011-02-15 | 2011-09-21 | Vestel Beyaz Eşya Sanayi̇ Ve Ti̇caret Anoni̇m Şi̇rketi̇@ | Foam detection and removal method for washing machines. |
JP5903649B2 (en) * | 2011-06-29 | 2016-04-13 | パナソニックIpマネジメント株式会社 | Drum washing machine |
CN103649399B (en) * | 2011-06-29 | 2016-06-01 | 松下电器产业株式会社 | Tumbling-box washing machine |
JP5787777B2 (en) * | 2012-01-18 | 2015-09-30 | シャープ株式会社 | Washing and drying machine |
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DE102013216743A1 (en) * | 2013-08-23 | 2015-02-26 | BSH Bosch und Siemens Hausgeräte GmbH | Laundry care device |
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EP3235939B1 (en) * | 2016-04-21 | 2021-06-09 | Electrolux Appliances Aktiebolag | Method for the detection of foam in a laundry washing machine |
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-
2007
- 2007-08-01 DE DE102007036041A patent/DE102007036041A1/en not_active Withdrawn
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2008
- 2008-07-09 US US12/671,045 patent/US8510887B2/en not_active Expired - Fee Related
- 2008-07-09 EP EP08774906A patent/EP2185763B1/en active Active
- 2008-07-09 EA EA201070210A patent/EA017259B1/en not_active IP Right Cessation
- 2008-07-09 PL PL08774906T patent/PL2185763T3/en unknown
- 2008-07-09 WO PCT/EP2008/058900 patent/WO2009016009A1/en active Application Filing
- 2008-07-09 CN CN2008801013285A patent/CN101772600B/en active Active
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US8510887B2 (en) | 2013-08-20 |
WO2009016009A1 (en) | 2009-02-05 |
EA017259B1 (en) | 2012-11-30 |
PL2185763T3 (en) | 2013-04-30 |
CN101772600A (en) | 2010-07-07 |
CN101772600B (en) | 2012-05-30 |
EP2185763A1 (en) | 2010-05-19 |
EA201070210A1 (en) | 2010-08-30 |
DE102007036041A1 (en) | 2009-02-05 |
US20100199440A1 (en) | 2010-08-12 |
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