EP2176438B1 - Combined annealing and galvanisation line and method for converting a continuous annealing line into such combined line - Google Patents

Combined annealing and galvanisation line and method for converting a continuous annealing line into such combined line Download PDF

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Publication number
EP2176438B1
EP2176438B1 EP08831213A EP08831213A EP2176438B1 EP 2176438 B1 EP2176438 B1 EP 2176438B1 EP 08831213 A EP08831213 A EP 08831213A EP 08831213 A EP08831213 A EP 08831213A EP 2176438 B1 EP2176438 B1 EP 2176438B1
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Prior art keywords
section
annealing
line
galvanisation
bath
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German (de)
French (fr)
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EP2176438A1 (en
Inventor
Pierre-Jérôme BORREL
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Clecim SAS
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Siemens VAI Metals Technologies SAS
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C21D9/54Furnaces for treating strips or wire
    • C21D9/56Continuous furnaces for strip or wire
    • C21D9/562Details
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/003Apparatus
    • C23C2/0034Details related to elements immersed in bath
    • C23C2/00342Moving elements, e.g. pumps or mixers
    • C23C2/00344Means for moving substrates, e.g. immersed rollers or immersed bearings
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/003Apparatus
    • C23C2/0035Means for continuously moving substrate through, into or out of the bath
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/003Apparatus
    • C23C2/0038Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
    • C23C2/004Snouts
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26After-treatment
    • C23C2/28Thermal after-treatment, e.g. treatment in oil bath
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26After-treatment
    • C23C2/28Thermal after-treatment, e.g. treatment in oil bath
    • C23C2/29Cooling or quenching
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36Elongated material
    • C23C2/40Plates; Strips

Definitions

  • the invention relates to a combined annealing and galvanizing line of a metal strip and also covers a method of converting an existing annealing line into such a combined line.
  • the cold rolling of a steel strip causes hardening, by hardening, of the metal which causes a fragility making it more difficult and may even prohibit the subsequent use of the rolled strips.
  • the entire annealing installation forms a furnace generally placed under a controlled atmosphere in a closed enclosure, and wherein the strip travels along a zig-zag path defined by a plurality of deflection rollers and which successively provides the heating of the band in section 21, its maintenance at the annealing temperature in section 22, a first cooling in section 23, fast enough to avoid oxidation, a complement of overaging treatment, in English "overaging" in the section 24, which usually comprises several successive units and a slow cooling in the section 25 which ends, usually, by quenching the strip in a final cooling liquid bath to room temperature.
  • the annealing installation 2 successively performs the metallurgical annealing and correct temperature-setting functions of the strip before it enters the metal bath 41. It therefore comprises a preheating section 21, a retention section 22 at the annealing temperature, a rapid cooling section 23 and a section 26 of galvanizing temperature in which can also be carried out an activation of the surface to be galvanized by surface chemical migrations.
  • Complete annealing lines of the type shown on the figure 1 are therefore normally provided for steel grades which justify a large tonnage and are equipped with all the equipment necessary to adapt to a new grade after modification of the adjustment parameters, in particular temperatures and the duration of the heat treatments.
  • the tonnages required in each grade are relatively small and require rapid changes in setting parameters, sometimes without stopping scrolling, the tail of a coil at the end of unwinding can be welded to the head of a next coil, of different quality and requiring other treatments.
  • the document EP-A-0254633 for example, describes such a combined line comprising successively, between a reel and a winder, a horizontal annealing furnace, a temperature control section and a conventional type of galvanizing installation. There is also a coating coating installation. According to the invention, to allow a passage from one treatment to another, without increasing the complexity and the cost of such an installation, the treated metal flow must be at most 7 tons / hour, at a speed of passage at most equal to 12 meters per minute. The production capacity of such an installation, designed some twenty years ago, would have been very limited.
  • the object of the invention is to solve such problems by means of a particular arrangement of the different equipment necessary, on the one hand for annealing and on the other hand for galvanization, making it possible to produce a combined line capable of performing either annealing alone, or an annealing followed by galvanization, without unduly increasing the congestion in length of the line.
  • this particular arrangement of the equipment makes it possible, according to the invention, to quite simply convert an existing continuous annealing installation to add galvanizing means without excessive modification of the existing installation and remaining in the floor area of the floor. it.
  • the invention makes it possible to continue a profitable exploitation of certain existing continuous annealing installations that are no longer adapted to the requirements of the market, by transforming them into a combined line capable of handling a very wide variety of products.
  • the invention therefore relates to a combined annealing and galvanizing line of a metal strip comprising means for controlling the movement of the strip in a continuous line, between an input device and an output device of the line, successively in a annealing apparatus and a galvanizing plant, the annealing apparatus having a section for heating and holding the band at an annealing temperature, a first annealing section after annealing, an overaging section and a second cooling section up to ambient temperature, and the galvanizing plant having an inlet section of the strip in a galvanizing metal bath, an outlet section of the metal bath of the strip covered on both sides with a layer coating, a cooling section of the coating and a final coolant bath.
  • the galvanizing plant is incorporated inside the annealing plant, between the overaging section and the second cooling section, and at the outlet of the overaging section, the band is directed by selective guiding means, either to the galvanizing plant and then, at the outlet of the final cooling bath, directly to the output device of the line, or directly to the second cooling section and then to the output device of the line.
  • the overfill section and the second cooling section of the annealing plant are each placed in a sealed enclosure filled with a protective gas and the inlet section in the galvanizing metal bath is placed in a sealed duct having an inlet connected to the outlet of the overflow section and two outlets, respectively a first outlet immersed in the metal bath and a second outlet on which is releasably connected a leaktight trough with the second section cooling and annealing installation, said second outlet being provided with removable sealing means.
  • the combined line according to the invention comprises a plurality of deflection rollers defining two paths of the strip at the exit of the overaging section, respectively a first galvanization path comprising an inlet section in the metal bath. passing through the first outlet of the sealed conduit, an outlet section of the metal bath, a cooling section of the coating prior to entry into the final cooling bath, and an exit section of said cooling bath passing above or below the enclosure in which is placed the second cooling section, so as to connect directly to the output device of the line, and a second annealing path alone, passing through the removable connection channel between the second outlet of the sealed conduit and the enclosure of the second cooling section.
  • the combined line comprises two liquid final cooling baths of the strip, respectively a first bath placed at the outlet of the galvanizing installation, and a second bath placed at the outlet of the second cooling section, the strip being directed towards the outlet device of the line after final cooling carried out, either in the first bath after galvanization, or in the second bath after an annealing treatment alone, without galvanizing.
  • the first cooling bath is placed above the metal bath and offset to the inlet side thereof to reduce the bulk of the galvanizing plant.
  • the over-age section has a reduced length compared to the length usually required in a continuous annealing line. and the running speed of the web is adapted to this reduced length in order to obtain the necessary processing time.
  • the invention also covers a process for converting into a combined annealing and galvanizing line, an existing continuous annealing line of a metal strip comprising successively, in a running direction of the product, an input device in the line, a preheating section, an annealing section, a first rapid cooling section after annealing, a supercooling section, a slow cooling section under a protective atmosphere and a line output device.
  • part of the overaging section is removed leaving the other sections in place and a galvanizing installation is placed inside the annealing line, in the space thus released between the remaining part of the overfill section and the second slow cooling section, and connected to the scroll control means so as to achieve a combined annealing and galvanizing line without increasing the overall length of the annealing line.
  • the running speed of the web between the input device and the output device of the line is adapted either to the annealing process alone or to the galvanizing process.
  • the installation of The galvanization replaces only a part of the overaging section and the running speed of the band is adjusted, if necessary, so as to carry out a survival treatment in the remaining part of the corresponding section.
  • the temperature in the annealing section is maintained at the desired level for annealing, taking into account the nature of the strip and the speed of travel and, between the exit of the overaging section and the inlet in the galvanizing bath, the installation comprises combined means of heating and cooling, for adjusting the temperature of the strip to a level suitable for the galvanizing process.
  • the galvanizing installation comprises means for controlling the running of the strip between a galvanizing metal bath and a quenching bath, along a continuous scrolling path passing over a plurality of deflection rollers. and having at least four portions, respectively a first connection portion between the quench section and the inlet to the metal bath, a second exit portion of the metal bath with coating thickness control, a third cooling portion coating before entering the quench bath and a fourth quenching bath outlet portion, connecting directly to the exit section of the annealing line, without passing through the slow cooling section.
  • the quenching bath is placed above the metal bath and shifted towards the inlet side of the the line, so that in the third cooling part, the strip returns to the rear and, in the fourth quenching bath outlet portion, passes over the metal bath and then above or below the slow cooling section to connect directly to the output device of the line.
  • the figure 1 represents, schematically, the conventional arrangement of a continuous annealing line comprising, between an input device 1 and an output device 3, an oven 2 in which the strip travels along a zig-zag path, between two series baffle rollers, respectively upper and lower, and consisting of successive sections respectively heating the band M in section 21, maintaining it at the annealing temperature in section 22, rapid cooling in section 23, a complement of so-called over-aging or "over” treatment aging "in section 24 with several successive units and slow cooling to a moderate temperature, in section 25.
  • the figure 3 is a diagram showing two examples of continuous annealing cycles shown, respectively, by curve 5 for a direct flame furnace and by the 5 'curve for heating without direct flame, for example by reverberation.
  • the heating has no particular metallurgical impact up to 600 ° C and the rate of rise in temperature (51, 51 ') can be more or less rapid depending on the heating technology used. Beyond 600 ° C and up to the maximum temperature, heating is continued at a lower speed (52, 52 ') in order to improve the control of the temperature.
  • the annealing temperature (53, 53 ') depends on the metallurgical quality targeted. It is generally between 650 and 700 ° C for tinplate and 700 to 850 ° C for a thin strip for galvanizing.
  • the holding time (53, 53 ') generally close to 15 to 30 seconds, makes it possible to stabilize the annealed structure.
  • This holding phase (53, 53 ') is followed by a controlled cooling (54, 54') at a slow speed, generally below 10 ° C./s up to a temperature of 600 to 700 ° C. to ensure the precipitation of Fe 3 C carbides.
  • a cooling is carried out to a temperature of about 350 to 450 ° C., which is rapidly conducted (55, 55 '), the cooling rate being greater than 100 ° C./s and up to 200 ° C / s to maintain carbon in solution.
  • the treatment then continues, in section 24, by maintaining the temperature for a period of one to several minutes (56, 56 '), in order to produce the precipitation of the interstitial carbon in a so-called overaging phase. .
  • the cycle ends with cooling (57, 57) to a moderate temperature, for example about 60.degree. possibly up to room temperature.
  • the figure 4 is a diagram showing a typical cycle of annealing in a galvanizing line of the type shown in FIG. figure 2 .
  • the curve 5a which shows the evolution of the temperature as a function of time is analogous to the curves 5, 5 'described previously and therefore comprises the same portions (51a, 52a) of temperature rise, (53a) of maintenance at the temperature of annealing, (54a) controlled cooling at low speed, then (55a) rapid cooling.
  • the galvanizing line of the type shown on the figure 2 also comprises a thermal control section 26 for performing, first of all over-aging (56a) and then, by cooling (57a) or possibly heating, to bring the strip to the temperature (58a) desirable for the entering the galvanizing bath.
  • the thermal cycle 5a in the galvanizing line is therefore similar to the cycle 5 in an annealing line of the type shown in FIG. figure 1 , the differences coming essentially from the speed of movement imposed by the galvanizing process which must not exceed, normally, 200 m / min in order to be able to control the thickness of the coating deposited at the exit of the metal bath whereas the usual speeds of Continuous annealing lines for thin sheets are in the range of 300 to 500 m / min.
  • the invention is based on the idea that, even for conventional and relatively complex annealing treatments, it should be possible to reduce the length of the overaging section, as compared to the usual length, and that the removal of certain chambers of overaging would provide a space in which a galvanizing plant could be incorporated, without increasing the overall size of the annealing line, to achieve a combined line to perform either an annealing treatment alone or a treatment of galvanization preceded by annealing.
  • the output of the overaging section opens into a selective guiding device 80 for directing the band M, either directly to the slow cooling section 25, for an annealing treatment alone, or to the input T1 of the In this case, at the outlet of the final cooling bath 45, the strip is directed directly towards the outlet device 3 of the line, by short-circuiting the cooling section 25.
  • the space left by the removal of a portion of the overaging section must have a relatively small length, less than the normal footprint of a conventional galvanizing plant.
  • one of the ideas of the invention consists in modifying the usual architecture of the continuous galvanizing lines by organizing in a new way the unwinding of the strip at the outlet of the zinc bath, as shown schematically on the figure 5 and more in detail on the figure 6 .
  • the strip has been brought to the desired temperature for galvanizing, as shown in the diagram of FIG. figure 4 .
  • the band leaving the section 26 passes over a deflector roll D1 which directs it to the galvanizing metal bath 41 formed in a tank and in which is immersed a deflection roll D2.
  • the band M therefore follows a downward path T1 between the output roller D1 and the immersed roll D2 on which it bears by its upper face A.
  • the strip M then comes out of the bath 41 in an upward path T2 to an upper roll D3, passing in front of a wiper device 42 of known type for controlling the thickness of the coating.
  • the band M bears on the upper roll D3 by the same side A passing on the immersed roll D2 and, therefore, instead of being directed towards the outside of the tank containing the metal bath 41, the band M returns back to the entrance side in the tray, that is to say the left side on the figures 5 and 6 .
  • the strip returns to an upper roll D'3 and descends, by a downward path T3, to a deflector roll D4 immersed in the quenching bath 45.
  • the strip then exits from this bath 45 along a rising path T4 to a pair of upper deflector rollers D5, 5 spaced apart from each other, so as to pass over the entire installation.
  • galvanizing 41 and the slow cooling section 25, then descends, by a downward path T5, to a lower roller D6 to be directed to the accumulator 31 of the output device 3.
  • the quenching bath 45 can be placed above the tank containing the galvanizing metal bath 41.
  • the footprint of the galvanizing plant 4 is reduced by compared to the classic layout of the figure 2 since it covers substantially the same length as the galvanizing bath 41.
  • this arrangement requires the construction, above the metal bath 41, of a floor to support the quench tank 45 but this increase in height of the installation does not constitute a real disadvantage, particularly for the transformation of an existing installation.
  • the return towards the rear of the strip from the upper roller D3 makes it possible to incorporate the entire galvanizing installation into the existing reduced space between the remaining part of the overaging section. and the slow cooling section 25.
  • Such an arrangement is also particularly compact since, at each change of direction, the band passes on a single roll returning, as before, to the rear.
  • This arrangement also makes it possible to distribute cooling means 44, 44 'not only along the upward path T2 but also along the downward path T3 so as to provide sufficient cooling of the coating.
  • the face A 'of the strip opposite the face A passing on the immersed roll D2 comes into contact with the lower roll D6 after the upward path T2 and the descending path T3 and, thus, not likely to be deteriorated before curing the coating.
  • Such an arrangement is particularly advantageous in applications where an outer face of the sheet, called “exposed face” must have excellent surface quality, for example for the automobile body.
  • the cooling cells and, where appropriate, the alloying furnace 43 may advantageously be staggered on the ascending strand T2 and the descending arm T3 which, in the case of the figure 6 , are separated only by a single deflection roll D3, which further reduces the footprint of the assembly.
  • the outlet section 26 of the oven 2 allows, by adjusting the speed of travel at a moderate level, for example 200 m / min, to perform a survival treatment adapted to the nature of the metal, then to ensure the implementation at the appropriate temperature of the strip before entering the zinc bath 41.
  • the figure 7 shows a complete annealing cycle for a "TRIP" type steel which requires, after annealing, isothermal retention in the bainitic transformation zone, that is to say around 290 ° C.
  • the outlet section 26 of the furnace must raise the temperature of the strip to a level compatible with the temperature of the zinc bath, for example 470 ° C.
  • the figure 8 corresponds to the case of a common steel requiring overaging, for example at 560 ° C. In this case, the temperature must be lowered to the temperature of the zinc bath.
  • the temperature control section 26 will therefore be equipped with heating means, preferably by induction and cooling, preferably by neutral gas jet.
  • the galvanizing installation 4 placed, according to the invention, between the outlet section 26 of the oven 2 and the slow cooling section 25, is provided, at its output, with a quenching bath 45 at the output of which the strip is at a temperature close to ambient. Therefore, it is not necessary to pass the strip in the slow cooling section 25, the quenching bath 45 being connected directly to the output accumulator 31.
  • a combined line has thus been realized to ensure, as the case may be, the continuous annealing line functions in the oven 2 and the final cooling section 25 and galvanizing continuous line in the furnace 2 and the galvanizing plant 4 which ends with the quench bath 45.
  • the figure 9 schematically shows the layout of an installation to easily switch from one mode of operation to another.
  • the annealing to be carried out in a controlled atmosphere the entire annealing furnace 2, with the overaging section 26, is placed in a closed enclosure 8 provided at its base with a conduit 80 which forms a branch with two outlets , respectively a first outlet 81 which plunges inside the metal bath 41 to ensure sealing, and a second outlet 82 which can be removably closed by a door 83.
  • the slow cooling section 25 also placed under a controlled atmosphere, is disposed in a sealed enclosure 8 'whose inlet 81' can be connected to the second outlet 82 of the duct 80 via a connecting chute 84 which can be moved, for example by pivoting, between the position shown on the figure 9 for which the chute 84 is tightly connected to the second outlet 82 of the duct 80 and a spaced apart position allowing the passage of the strip M along the path T2, at the outlet of the metal bath 41.
  • This mobile chute 84 thus forms a bypass tunnel allowing, when it is put in place and the door 83 open, to ensure the passage of the band M between the deflector roll D1 placed at the outlet of the oven and the section cooling 25, sealing between the two closed enclosures 8 and 8 'in which is formed a neutral atmosphere, for example a mixture of nitrogen and hydrogen.
  • the figure 10 is a schematic diagram of the operation of such a combined line.
  • the band M successively passes through the various sections of the annealing furnace 2 and, after being put into temperature in the outlet section 26, passes through the first outlet 81 of the duct 80 to open into the zinc bath 41.
  • the strip M guided by the deflecting rollers D5, D5, D7 passes below or, optionally, above the slow cooling section 25 to be directed directly to the 3 output device of the line.
  • the connecting trough 84 is put in place and the door 83 is opened. From the deflector roll D1, the band M passes into the connecting chute 84, then into the slow cooling section 25 which preferably terminates in a quenching tank 27 and is then directed by the drive rollers D8 to the output device 3 of the line.
  • the installation is equipped, on the other hand, with means not represented on the figure 9 , making it possible to cut the strip, either at a point 85, at the inlet into the connecting chute 84, or at a point 86, at the outlet of the cooling zone 25, upstream of the driving rollers D8.
  • the strip is cut at these two points 85 and 86, the mobile tunnel 84 is raised vertically and held against the front wall of the enclosure 8 'containing the cooling section 25. A band portion remains engaged in the tunnel 84 and section 25. It will serve as a "pull tape” to put the line in annealing configuration in another campaign.
  • the strip is cut at two points, respectively 87 at the exit of the zinc bath 41 and 88 after the exit of the quenching bath 45.
  • the hanging strands of the strip are attached to the frame members carrying the galvanizing plant 4 '. A portion of band remains engaged in this area and will serve as a draw tape to put the line in galvanizing configuration, in another campaign.
  • the invention thus makes it possible to carry out either an annealing alone or a galvanization after annealing in a combined line of the type shown in FIG. figure 5 , the overall overall length of which is of the same order as that of a conventional continuous annealing line, insofar as the galvanizing installation, in particular if it is carried out in the particularly compact manner described above, can incorporated within the annealing line, between the overaging section and the slow cooling section.
  • the invention will find a particularly interesting application for the transformation of existing continuous annealing lines whose profitability is no longer assured due to the variety of qualities of sheet required and the resulting tonnage decline.
  • the invention has further advantages and is not limited to the details of the embodiments which have been described as mere examples.
  • the band could pass over the cooling section 25 for descend directly into the quench bath 27 placed at the outlet thereof.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Coating With Molten Metal (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

The invention relates to a combined annealing and galvanisation line of a metal strip (1), that successively comprises an annealing station (2) with an annealing section (22), a quenching section (23), an over-ageing section (26) and a second slow-cooling section (25), and a galvanisation station (4) ending in a tempering bath. According to the invention, the galvanisation station (4) is integrated inside the annealing station (2) between the over-ageing section (26) and the second cooling section (25) and, at the output of the over-ageing section (26), the strip is directed by selective guiding means (80) either to the galvanisation station (4) and directly to the line output device (3), or directly to the second cooling section (25) and the line output device (3). The invention also relates to a particularly simple and economical method for converting an existing continuous annealing line into a combined annealing and/or galvanisation line.

Description

L'invention a pour objet une ligne combinée de recuit et de galvanisation d'une bande métallique et couvre également un procédé de transformation d'une ligne existante de recuit en une telle ligne combinée.The invention relates to a combined annealing and galvanizing line of a metal strip and also covers a method of converting an existing annealing line into such a combined line.

Le laminage à froid d'une bande d'acier provoque un durcissement, par écrouissage, du métal qui entraîne une fragilité rendant plus difficile et pouvant même interdire la mise en oeuvre ultérieure des bandes laminées.The cold rolling of a steel strip causes hardening, by hardening, of the metal which causes a fragility making it more difficult and may even prohibit the subsequent use of the rolled strips.

Afin de restaurer la ductilité d'une bande laminée, on pratique habituellement un traitement thermique dit « de recuit de recristallisation ». Un tel traitement peut être réalisé de façon statique dans des fours cloches (patch annealing) sur la bande enroulée en bobine. Cependant, depuis un certain temps, pour éviter le déroulement et l'enroulement des bobines et leur transport d'une installation à la suivante, on a proposé de réaliser le traitement de ces bandes en défilement continu sur des lignes spécialisées.In order to restore the ductility of a rolled strip, a so-called "recrystallization annealing" heat treatment is usually used. Such treatment can be performed statically in patch-annealing ovens on the coil-wound web. However, for some time, to prevent unwinding and winding of the coils and their transport from one facility to the next, it has been proposed to perform the treatment of these strips in continuous scrolling on specialized lines.

La figure 1 montre schématiquement, à titre d'exemple, la disposition habituelle d'une telle ligne de recuit en continu qui comporte successivement, dans le sens de défilement de la bande :

  • Un dispositif d'entrée 1 comportant une ou deux dérouleuses de bande 11, une cisaille 12, par exemple à guillotine, une soudeuse de raboutage 13 permettant de raccorder la queue d'une bande issue d'une première dérouleuse à la tête de la bande suivante issue de la seconde dérouleuse afin d'assurer un fonctionnement continu de la ligne, et un accumulateur de bande 14 permettant, lorsque le déroulement est stoppé en amont, pour réaliser la soudure de raboutage, de délivrer à sa sortie, une certaine longueur de bande préalablement accumulée afin de poursuivre le défilement en continu de celle-ci dans les appareillages placés en aval.
  • Une installation de recuit 2 comportant une section de préchauffage 21, une section 22 de chauffage et de maintien à la température de recuit pendant le temps nécessaire, une section de refroidissement rapide 23, une section de survieillissement 24 et une seconde section 25 de refroidissement lent.
  • Un dispositif de sortie 3 comportant un accumulateur de bande 31, éventuellement un laminoir de skin-pass 32, une cisaille 33 et une ou deux enrouleuses 34 travaillant alternativement.
The figure 1 schematically shows, by way of example, the usual arrangement of such a continuous annealing line which comprises successively, in the running direction of the strip:
  • An input device 1 comprising one or two belt unrollers 11, a shear 12, for example a guillotine, a splicing welder 13 for connecting the tail of a strip from a first unwinder to the head of the strip next from the second unwinder to ensure continuous operation of the line, and a strip accumulator 14 allowing, when the flow is stopped upstream, to perform the solder splicing, to deliver at its output, a certain length of previously accumulated tape in order to continue the continuous scrolling thereof in downstream equipment.
  • An annealing plant 2 having a preheating section 21, a section 22 for heating and maintaining the annealing temperature for the necessary time, a section of rapid cooling 23, a supernatant section 24 and a second slow cooling section.
  • An output device 3 comprising a tape accumulator 31, possibly a skin-pass rolling mill 32, a shear 33 and one or two winders 34 working alternately.

L'ensemble de l'installation de recuit forme un four généralement placé sous une atmosphère contrôlée dans une enceinte fermée, et dans lequel la bande circule en suivant un trajet en zig-zag défini par une pluralité de rouleaux déflecteurs et qui assure successivement le chauffage de la bande dans la section 21, son maintien à la température de recuit dans la section 22, un premier refroidissement dans la section 23, suffisamment rapide pour éviter l'oxydation, un complément de traitement de survieillissement, en anglais « overaging » dans la section 24, qui comporte habituellement plusieurs unités successives et un refroidissement lent dans la section 25 qui se termine, habituellement, par la trempe de la bande dans un bain liquide de refroidissement final jusqu'à la température ambiante.The entire annealing installation forms a furnace generally placed under a controlled atmosphere in a closed enclosure, and wherein the strip travels along a zig-zag path defined by a plurality of deflection rollers and which successively provides the heating of the band in section 21, its maintenance at the annealing temperature in section 22, a first cooling in section 23, fast enough to avoid oxidation, a complement of overaging treatment, in English "overaging" in the section 24, which usually comprises several successive units and a slow cooling in the section 25 which ends, usually, by quenching the strip in a final cooling liquid bath to room temperature.

Par ailleurs, afin d'améliorer la résistance à la corrosion des tôles métalliques utilisées en particulier, dans certaines applications comme le bâtiment, l'automobile ou l'électroménager, il est courant de déposer à la surface de ces tôles une couche de revêtement en zinc ou en un alliage à base de zinc. Pour cela, habituellement, on fait passer la bande sur un rouleau immergé dans un bain de métal liquide. Il faut donc que la bande, avant son entrée dans le bain, soit portée à la température voulue. Dans la mesure où, habituellement, la bande a subi un traitement de recuit, on peut réaliser des lignes continues de recuit et de galvanisation du type représenté schématiquement sur la figure 2, comprenant successivement, dans le sens le défilement du produit :

  • un dispositif d'entrée 1 du type décrit précédemment, comprenant une dérouleuse 11, une cisaille 12, une soudeuse de raboutage 13 et un accumulateur 14,
  • une installation de recuit 2,
  • une installation de galvanisation 4 comprenant un bain de métal liquide 41, un dispositif d'essorage 42, un circuit de sortie avec par exemple, un four d'alliation 43 et un équipement de refroidissement 44 et un bac de tempe 45,
  • un dispositif 3 de sortie de la ligne comportant par exemple un laminoir skin-pass 32, une section de passivation 35, un accumulateur de sortie 31, une cisaille 33 et une ou deux enrouleuses 34 travaillant alternativement.
Furthermore, in order to improve the corrosion resistance of the metal sheets used in particular, in certain applications such as the building, the automobile or household appliances, it is common practice to deposit on the surface of these sheets a layer of cladding. zinc or a zinc-based alloy. For this, usually, the tape is passed over a roll immersed in a bath of liquid metal. It is therefore necessary that the band, before entering the bath, be brought to the desired temperature. Since, usually, the strip has undergone annealing treatment, it is possible to produce continuous annealing and galvanizing lines of the type shown schematically on the strip. figure 2 , comprising successively, in the direction of scrolling the product:
  • an input device 1 of the type described above, comprising a unwinder 11, a shear 12, a splicing welder 13 and an accumulator 14,
  • an annealing installation 2,
  • a galvanizing installation 4 comprising a bath of liquid metal 41, a dewatering device 42, an output circuit with, for example, an alloying oven 43 and a cooling equipment 44 and a tundish 45,
  • a device 3 for output of the line comprising for example a skin-pass 32, a passivation section 35, an output accumulator 31, a shear 33 and one or two winders 34 working alternately.

Dans une telle ligne de galvanisation en continu, l'installation de recuit 2 assure successivement les fonctions de recuit métallurgique et de mise à la température correcte de la bande avant son entrée dans le bain métallique 41. Elle comporte donc une section de préchauffage 21, une section 22 de maintien à la température de recuit, une section de refroidissement rapide 23 et une section 26 de mise à la température de galvanisation dans laquelle peut aussi s'effectuer une activation de la surface à galvaniser par migrations chimiques superficielles.In such a continuous galvanizing line, the annealing installation 2 successively performs the metallurgical annealing and correct temperature-setting functions of the strip before it enters the metal bath 41. It therefore comprises a preheating section 21, a retention section 22 at the annealing temperature, a rapid cooling section 23 and a section 26 of galvanizing temperature in which can also be carried out an activation of the surface to be galvanized by surface chemical migrations.

D'une façon générale, de telles lignes de traitement continu constituent un équipement lourd ayant un coût très élevé et qui exige, pour être rentable, une production importante. Une modification des paramètres de réglage en fonction de la nuance du métal à traiter et des qualités à obtenir entraîne en effet, un arrêt de la ligne avec une perte de productivité et la production de rebuts.In general, such lines of continuous processing constitute a heavy equipment with a very high cost and which requires, in order to be profitable, a large production. A modification of the adjustment parameters depending on the grade of the metal to be treated and the qualities to be obtained in fact leads to a stopping of the line with a loss of productivity and the production of waste.

Les lignes complètes de recuit du type représenté sur la figure 1 sont donc prévues, normalement, pour des nuances d'acier justifiant un tonnage important et sont munies de tous les équipements nécessaires pour s'adapter à une nouvelle nuance après modification des paramètres de réglage, notamment des températures et les durées des traitements thermiques.Complete annealing lines of the type shown on the figure 1 are therefore normally provided for steel grades which justify a large tonnage and are equipped with all the equipment necessary to adapt to a new grade after modification of the adjustment parameters, in particular temperatures and the duration of the heat treatments.

Cependant, l'évolution du marché, en particulier pour l'industrie automobile, conduit à une plus grande variété des nuances d'acier et de leur métallurgie ainsi qu'à une plus forte demande en bandes galvanisées.However, market developments, especially for the automotive industry, are leading to a greater variety of steel grades and their metallurgy as well as a higher demand for galvanized strips.

De plus, les tonnages demandés dans chaque qualité sont relativement faibles et nécessitent des changements rapides des paramètres de réglage, parfois sans arrêt du défilement, la queue d'une bobine en fin de déroulement pouvant être soudée à la tête d'une bobine suivante, de qualité différente et demandant d'autres traitements.In addition, the tonnages required in each grade are relatively small and require rapid changes in setting parameters, sometimes without stopping scrolling, the tail of a coil at the end of unwinding can be welded to the head of a next coil, of different quality and requiring other treatments.

Il en résulte qu'un certain nombre d'installations de recuit en ligne continue, prévues pour des tonnages importants, ne deviennent plus rentables en raison de l'évolution du marché et de la diminution des tonnages demandés. En revanche, la demande en tôle galvanisée augmente et il est donc intéressant de réaliser des lignes continues permettant de répondre de façon souple à la demande. On est donc amené à réaliser de nouvelles lignes combinées permettant de réaliser en continu soit un traitement de recuit seul, soit un recuit suivi d'une galvanisation.As a result, a number of continuous line annealing facilities, planned for large tonnages, no longer become profitable due to market developments and decreasing tonnages demanded. On the other hand, the demand for galvanized sheet is increasing and it is therefore interesting to produce continuous lines that allow the demand to be met flexibly. It is therefore necessary to achieve new combined lines to continuously perform either an annealing treatment alone, or annealing followed by galvanization.

Le document EP-A-0254633 , par exemple, décrit une telle ligne combinée comportant successivement, entre une dérouleuse et une enrouleuse, un fourde recuit de type horizontal, une section de régulation des températures et une installation de galvanisation de type classique. Il est également prévu une installation de revêtement par enduction. Selon l'invention, pour permettre un passage d'un traitement à l'autre, sans augmenter la complexité et le coût d'une telle installation, le débit de métal traité doit être au plus de 7 tonnes/heure, à une vitesse de passage au plus égale à 12 mètres par minute. Les capacités de production d'une telle installation, conçue il y a une vingtaine d'années, auraient, donc été très limitées.The document EP-A-0254633 for example, describes such a combined line comprising successively, between a reel and a winder, a horizontal annealing furnace, a temperature control section and a conventional type of galvanizing installation. There is also a coating coating installation. According to the invention, to allow a passage from one treatment to another, without increasing the complexity and the cost of such an installation, the treated metal flow must be at most 7 tons / hour, at a speed of passage at most equal to 12 meters per minute. The production capacity of such an installation, designed some twenty years ago, would have been very limited.

On a aussi proposé, dans le document WO-002/22894 , de placer une installation de galvanisation en aval d'une installation de recuit, entre la section de refroidissement sous atmosphère contrôlée et un bac de refroidissement final jusqu'à la température ambiante. L'installation de galvanisation s'ajoute donc à l'installation de recuit et augmente l'encombrement de l'ensemble.It was also proposed in the document WO-002/22894 placing a galvanizing plant downstream of an annealing plant between the controlled atmosphere cooling section and a final cooling tank to ambient temperature. The galvanizing installation is therefore added to the annealing installation and increases the bulk of the assembly.

L'invention a pour objet de résoudre de tels problèmes grâce à un arrangement particulier des différents équipements nécessaires, d'une part au recuit et d'autre part à la galvanisation, permettant de réaliser une ligne combinée capable d'effectuer, soit un recuit seul, soit un recuit suivi de galvanisation, sans augmenter exagérément l'encombrement en longueur de la ligne.The object of the invention is to solve such problems by means of a particular arrangement of the different equipment necessary, on the one hand for annealing and on the other hand for galvanization, making it possible to produce a combined line capable of performing either annealing alone, or an annealing followed by galvanization, without unduly increasing the congestion in length of the line.

En outre, cet arrangement particulier des équipements permet, selon l'invention, de transformer assez simplement une installation existante de recuit continu pour y ajouter des moyens de galvanisation sans modification excessive de l'installation existante et en restant dans l'emprise au sol de celle-ci.In addition, this particular arrangement of the equipment makes it possible, according to the invention, to quite simply convert an existing continuous annealing installation to add galvanizing means without excessive modification of the existing installation and remaining in the floor area of the floor. it.

Ainsi, l'invention permet de poursuivre une exploitation rentable de certaines installations existantes de recuit continu qui ne sont plus adaptées aux exigences du marché, en les transformant en une ligne combinée capable de traiter une très grande variété de produits.Thus, the invention makes it possible to continue a profitable exploitation of certain existing continuous annealing installations that are no longer adapted to the requirements of the market, by transforming them into a combined line capable of handling a very wide variety of products.

L'invention concerne donc une ligne combinée de recuit et de galvanisation d'une bande métallique comportant des moyens de commande du défilement de la bande en ligne continue, entre un dispositif d'entrée et un dispositif de sortie de la ligne, successivement dans une installation de recuit et une installation de galvanisation, l'installation de recuit comportant une section de chauffage et de maintien de la bande à une température de recuit, une première section de refroidissement rapide après recuit, une section de survieillissement et une seconde section de refroidissement jusqu'à la température ambiante, et l'installation de galvanisation comportant une section d'entrée de la bande dans un bain métallique de galvanisation, une section de sortie du bain métallique de la bande recouverte, sur ses deux faces, d'une couche de revêtement, une section de refroidissement du revêtement et un bain liquide de refroidissement final.The invention therefore relates to a combined annealing and galvanizing line of a metal strip comprising means for controlling the movement of the strip in a continuous line, between an input device and an output device of the line, successively in a annealing apparatus and a galvanizing plant, the annealing apparatus having a section for heating and holding the band at an annealing temperature, a first annealing section after annealing, an overaging section and a second cooling section up to ambient temperature, and the galvanizing plant having an inlet section of the strip in a galvanizing metal bath, an outlet section of the metal bath of the strip covered on both sides with a layer coating, a cooling section of the coating and a final coolant bath.

Conformément à l'invention, l'installation de galvanisation est incorporée à l'intérieur de l'installation de recuit, entre la section de survieillissement et la seconde section de refroidissement et, à la sortie de la section de survieillissement, la bande est dirigée par des moyens de guidage sélectif, soit vers l'installation de galvanisation puis, à la sortie du bain de refroidissement final, directement vers le dispositif de sortie de la ligne, soit, directement vers la seconde section de refroidissement puis le dispositif de sortie de la ligne.According to the invention, the galvanizing plant is incorporated inside the annealing plant, between the overaging section and the second cooling section, and at the outlet of the overaging section, the band is directed by selective guiding means, either to the galvanizing plant and then, at the outlet of the final cooling bath, directly to the output device of the line, or directly to the second cooling section and then to the output device of the line.

Dans un mode de réalisation préférentiel, la section de survieillissement et la seconde section de refroidissement de l'installation de recuit sont placées chacune dans une enceinte étanche remplie d'un gaz protecteur et la section d'entrée dans le bain métallique de galvanisation est placée dans un conduit étanche ayant une entrée branchée sur la sortie de la section de survieillissement et deux sorties, respectivement une première sortie plongeant dans le bain métallique et une seconde sortie sur laquelle vient se brancher de façon amovible une goulotte de liaison étanche avec la seconde section de refroidissement et l'installation de recuit, ladite seconde sortie étant munie de moyens amovibles de fermeture étanche.In a preferred embodiment, the overfill section and the second cooling section of the annealing plant are each placed in a sealed enclosure filled with a protective gas and the inlet section in the galvanizing metal bath is placed in a sealed duct having an inlet connected to the outlet of the overflow section and two outlets, respectively a first outlet immersed in the metal bath and a second outlet on which is releasably connected a leaktight trough with the second section cooling and annealing installation, said second outlet being provided with removable sealing means.

Selon une autre caractéristique préférentielle, la ligne combinée selon l'invention comporte une pluralité de rouleaux déflecteurs définissant deux trajets de la bande à la sortie de la section de survieillissement, respectivement un premier trajet de galvanisation comportant une section d'entrée dans le bain métallique passant par la première sortie du conduit étanche, une section de sortie du bain métallique, une section de refroidissement du revêtement avant l'entrée dans le bain de refroidissement final et une section de sortie dudit bain de refroidissement passant au-dessus ou en dessous de l'enceinte dans laquelle est placée la seconde section de refroidissement, de façon à se raccorder directement au dispositif de sortie de la ligne, et un second trajet de recuit seul, passant dans la goulotte de liaison amovible entre la seconde sortie du conduit étanche et l'enceinte de la seconde section de refroidissement.According to another preferred feature, the combined line according to the invention comprises a plurality of deflection rollers defining two paths of the strip at the exit of the overaging section, respectively a first galvanization path comprising an inlet section in the metal bath. passing through the first outlet of the sealed conduit, an outlet section of the metal bath, a cooling section of the coating prior to entry into the final cooling bath, and an exit section of said cooling bath passing above or below the enclosure in which is placed the second cooling section, so as to connect directly to the output device of the line, and a second annealing path alone, passing through the removable connection channel between the second outlet of the sealed conduit and the enclosure of the second cooling section.

De façon particulièrement avantageuse, la ligne combinée comporte deux bains liquides de refroidissement final de la bande, respectivement un premier bain placé à la sortie de l'installation de galvanisation, et un second bain placé à la sortie de la seconde section de refroidissement, la bande étant dirigée vers le dispositif de sortie de la ligne après un refroidissement final effectué, soit dans le premier bain après galvanisation, soit dans le second bain après un traitement de recuit seul, sans galvanisation.Particularly advantageously, the combined line comprises two liquid final cooling baths of the strip, respectively a first bath placed at the outlet of the galvanizing installation, and a second bath placed at the outlet of the second cooling section, the strip being directed towards the outlet device of the line after final cooling carried out, either in the first bath after galvanization, or in the second bath after an annealing treatment alone, without galvanizing.

De préférence, le premier bain de refroidissement est placé au-dessus du bain métallique et décalé vers le côté d'entrée de celui-ci afin de réduire l'encombrement de l'installation de galvanisation.Preferably, the first cooling bath is placed above the metal bath and offset to the inlet side thereof to reduce the bulk of the galvanizing plant.

Pour permettre l'incorporation de l'installation de galvanisation à l'intérieur de l'installation de recuit sans augmenter la longueur de la ligne, la section de survieillissement présente une longueur réduite par rapport à la longueur habituellement nécessaire dans une ligne de recuit continu et la vitesse de défilement de la bande est adaptée à cette longueur réduite afin d'obtenir le temps de traitement nécessaire.To allow the incorporation of the galvanizing plant into the annealing installation without increasing the length of the line, the over-age section has a reduced length compared to the length usually required in a continuous annealing line. and the running speed of the web is adapted to this reduced length in order to obtain the necessary processing time.

L'invention couvre également un procédé de transformation en une ligne combinée de recuit et de galvanisation, d'une ligne existante de recuit continu d'une bande métallique comportant successivement, dans un sens de défilement du produit, un dispositif d'entrée dans la ligne, une section de préchauffage, une section de recuit, une première section de refroidissement rapide après recuit, une section de survieillissement, une section de refroidissement lent sous atmosphère protectrice et un dispositif de sortie de la ligne.The invention also covers a process for converting into a combined annealing and galvanizing line, an existing continuous annealing line of a metal strip comprising successively, in a running direction of the product, an input device in the line, a preheating section, an annealing section, a first rapid cooling section after annealing, a supercooling section, a slow cooling section under a protective atmosphere and a line output device.

Selon l'invention, une partie de la section de survieillissement est supprimée en laissant en place les autres sections et une installation de galvanisation est disposée à l'intérieur de la ligne de recuit, dans l'espace ainsi libéré entre la partie restante de la section de survieillissement et la seconde section de refroidissement lent, et reliée aux moyens de commande du défilement de façon à réaliser une ligne combinée de recuit et de galvanisation sans augmentation de la longueur globale de la ligne de recuit.According to the invention, part of the overaging section is removed leaving the other sections in place and a galvanizing installation is placed inside the annealing line, in the space thus released between the remaining part of the overfill section and the second slow cooling section, and connected to the scroll control means so as to achieve a combined annealing and galvanizing line without increasing the overall length of the annealing line.

Selon une autre caractéristique de l'invention, la vitesse de défilement de la bande entre le dispositif d'entrée et le dispositif de sortie de la ligne est adaptée, soit au processus de recuit seul, soit au processus de galvanisation.According to another characteristic of the invention, the running speed of the web between the input device and the output device of the line is adapted either to the annealing process alone or to the galvanizing process.

Selon une autre caractéristique avantageuse, l'installation de galvanisation remplace une partie seulement de la section de survieillissement et la vitesse de défilement de la brande est réglée, en cas de besoin, de façon à effectuer un traitement de survieillissement dans la partie restante de la section correspondante.According to another advantageous characteristic, the installation of The galvanization replaces only a part of the overaging section and the running speed of the band is adjusted, if necessary, so as to carry out a survival treatment in the remaining part of the corresponding section.

Selon une autre caractéristique préférentielle, la température dans la section de recuit est maintenue au niveau souhaité pour le recuit, compte tenu de la nature de la bande et de la vitesse de défilement et, entre la sortie de la section de survieillissement et l'entrée dans le bain de galvanisation, l'installation comporte des moyens combinés de chauffage et de refroidissement, pour le réglage de la température de la bande à un niveau adapté au processus de galvanisation.According to another preferred characteristic, the temperature in the annealing section is maintained at the desired level for annealing, taking into account the nature of the strip and the speed of travel and, between the exit of the overaging section and the inlet in the galvanizing bath, the installation comprises combined means of heating and cooling, for adjusting the temperature of the strip to a level suitable for the galvanizing process.

Dans un mode de réalisation préférentiel, l'installation de galvanisation comporte des moyens de commande du défilement de la bande entre un bain métallique de galvanisation et un bain de trempe, le long d'un trajet continu de défilement passant sur une pluralité de rouleaux déflecteurs et comportant au moins quatre parties, respectivement une première partie de liaison entre la section de refroidissement rapide et l'entrée dans le bain métallique, une seconde partie de sortie du bain métallique avec contrôle de l'épaisseur du revêtement, une troisième partie de refroidissement du revêtement avant d'entrer dans le bain de trempe et une quatrième partie de sortie du bain de trempe, se raccordant directement à la section de sortie de la ligne de recuit, sans passer par la section de refroidissement lent.In a preferred embodiment, the galvanizing installation comprises means for controlling the running of the strip between a galvanizing metal bath and a quenching bath, along a continuous scrolling path passing over a plurality of deflection rollers. and having at least four portions, respectively a first connection portion between the quench section and the inlet to the metal bath, a second exit portion of the metal bath with coating thickness control, a third cooling portion coating before entering the quench bath and a fourth quenching bath outlet portion, connecting directly to the exit section of the annealing line, without passing through the slow cooling section.

Par ailleurs, pour adapter l'encombrement global de l'installation de galvanisation à la longueur de l'espace libéré dans la ligne de recuit, le bain de trempe est placé au-dessus du bain métallique et décalé vers le côté d'entrée de la ligne, de telle sorte que, dans la troisième partie de refroidissement, la bande revient vers l'arrière et, dans la quatrième partie de sortie du bain de trempe, passe au-dessus du bain métallique puis au dessus ou au dessous de la section de refroidissement lent afin de se raccorder directement au dispositif de sortie de la ligne.Furthermore, to adapt the overall size of the galvanizing installation to the length of the space released in the annealing line, the quenching bath is placed above the metal bath and shifted towards the inlet side of the the line, so that in the third cooling part, the strip returns to the rear and, in the fourth quenching bath outlet portion, passes over the metal bath and then above or below the slow cooling section to connect directly to the output device of the line.

D'autres caractéristiques avantageuses de l'invention apparaîtront dans la description qui va suivre de certains modes de réalisation particuliers, donnés à titre de simples exemples en se référant aux dessins annexés.

  • La figure 1 montre schématiquement la disposition classique d'une ligne continue de recuit, suivie d'une section de finissage.
  • La figure 2 montre schématiquement la disposition connue d'une ligne continue de galvanisation après recuit.
  • La figure 3 est un diagramme représentant deux exemples de cycles thermiques de recuit continu.
  • La figure 4 montre un cycle typique de recuit dans une ligne de galvanisation en continu.
  • La figure 5 montre schématiquement la disposition, selon l'invention, d'une ligne combinée de recuit et de galvanisation.
  • La figure 6 montre schématiquement, à échelle agrandie, la disposition selon l'invention d'une installation de galvanisation.
  • La figure 7 et la figure 8 sont deux diagrammes indiquant, à titre d'exemple deux cycles complets de recuit dans une ligne combinée selon l'invention.
  • La figure 9 montre schématiquement la disposition, selon l'invention, d'une installation de galvanisation à l'intérieur d'une ligne de recuit continu.
  • La figure 10 montre de façon synthétique, les fonctions propres au recuit continu et à la galvanisation ainsi que celles communes aux deux traitements.
Other advantageous features of the invention will appear in the following description of certain particular embodiments, given by way of simple examples with reference to the accompanying drawings.
  • The figure 1 schematically shows the conventional layout of a continuous annealing line, followed by a finishing section.
  • The figure 2 shows schematically the known arrangement of a continuous line of galvanization after annealing.
  • The figure 3 is a diagram showing two examples of continuous annealing thermal cycles.
  • The figure 4 shows a typical annealing cycle in a continuous galvanizing line.
  • The figure 5 shows schematically the arrangement according to the invention of a combined annealing and galvanizing line.
  • The figure 6 schematically shows, on an enlarged scale, the arrangement according to the invention of a galvanizing installation.
  • The figure 7 and the figure 8 are two diagrams indicating, by way of example, two complete cycles of annealing in a combined line according to the invention.
  • The figure 9 schematically shows the arrangement, according to the invention, of a galvanizing installation inside a continuous annealing line.
  • The figure 10 shows in a synthetic way, the functions of continuous annealing and galvanization as well as those common to both treatments.

Comme indiqué plus haut, la figure 1 représente, schématiquement, la disposition classique d'une ligne de recuit continu comprenant, entre un dispositif d'entrée 1 et un dispositif de sortie 3, un four 2 dans lequel la bande circule en suivant un trajet en zig-zag, entre deux séries de rouleaux déflecteurs, respectivement supérieur et inférieur, et constitué de sections successives assurant respectivement le chauffage de la bande M dans la section 21, son maintien à la température de recuit dans la section 22, un refroidissement rapide dans la section 23, un complément de traitement dit de survieillissement ou « over aging » dans la section 24 comportant plusieurs unités successives et un refroidissement lent jusqu'à une température modérée, dans la section 25.As mentioned above, the figure 1 represents, schematically, the conventional arrangement of a continuous annealing line comprising, between an input device 1 and an output device 3, an oven 2 in which the strip travels along a zig-zag path, between two series baffle rollers, respectively upper and lower, and consisting of successive sections respectively heating the band M in section 21, maintaining it at the annealing temperature in section 22, rapid cooling in section 23, a complement of so-called over-aging or "over" treatment aging "in section 24 with several successive units and slow cooling to a moderate temperature, in section 25.

La figure 3 est un diagramme montrant deux exemples de cycles de recuit continu représentés, respectivement, par la courbe 5 pour un four à flamme directe et par la courbe 5' pour un chauffage sans flamme directe, par exemple par réverbération.The figure 3 is a diagram showing two examples of continuous annealing cycles shown, respectively, by curve 5 for a direct flame furnace and by the 5 'curve for heating without direct flame, for example by reverberation.

Le chauffage n'a pas d'impact métallurgique particulier jusque vers 600°C et l'allure de la montée en température (51, 51') peut être plus ou moins rapide en fonction de la technologie de chauffage utilisée. Au-delà de 600°C et jusqu'à la température maximale, le chauffage est poursuivi à vitesse plus réduite (52, 52') afin d'améliorer le contrôle de la température.The heating has no particular metallurgical impact up to 600 ° C and the rate of rise in temperature (51, 51 ') can be more or less rapid depending on the heating technology used. Beyond 600 ° C and up to the maximum temperature, heating is continued at a lower speed (52, 52 ') in order to improve the control of the temperature.

La température de recuit (53, 53') dépend de la qualité métallurgique visée. Elle est généralement comprise entre 650 et 700°C pour du fer blanc et 700 à 850°C pour une bande mince destinée à la galvanisation. Le temps de maintien (53, 53') généralement voisin de 15 à 30 secondes, permet de stabiliser la structure recuite.The annealing temperature (53, 53 ') depends on the metallurgical quality targeted. It is generally between 650 and 700 ° C for tinplate and 700 to 850 ° C for a thin strip for galvanizing. The holding time (53, 53 ') generally close to 15 to 30 seconds, makes it possible to stabilize the annealed structure.

Cette phase de maintien (53, 53') est suivie d'un refroidissement contrôlé (54, 54') à une vitesse lente, généralement inférieure à 10°C/s jusqu'à une température de 600 à 700°C environ, afin d'assurer la précipitation des carbures Fe3C.This holding phase (53, 53 ') is followed by a controlled cooling (54, 54') at a slow speed, generally below 10 ° C./s up to a temperature of 600 to 700 ° C. to ensure the precipitation of Fe 3 C carbides.

On réalise alors, dans la section 23 du four, un refroidissement jusqu'à une température de 350 à 450°C environ, qui est conduit rapidement (55, 55'), la vitesse de refroidissement étant supérieure à 100°C/s et pouvant atteindre 200°C/s afin de maintenir le carbone en solution.Then, in the section 23 of the furnace, a cooling is carried out to a temperature of about 350 to 450 ° C., which is rapidly conducted (55, 55 '), the cooling rate being greater than 100 ° C./s and up to 200 ° C / s to maintain carbon in solution.

Le traitement se poursuit ensuite, dans la section 24, par un maintien en température pendant un temps de une à plusieurs minutes (56, 56'), afin de produire la précipitation du carbone interstitiel dans une phase dite de survieillissement ou « over aging ».The treatment then continues, in section 24, by maintaining the temperature for a period of one to several minutes (56, 56 '), in order to produce the precipitation of the interstitial carbon in a so-called overaging phase. .

Le cycle se termine par un refroidissement (57, 57)' jusqu'à une température modérée, par exemple environ 60°C, éventuellement jusqu'à la température ambiante.The cycle ends with cooling (57, 57) to a moderate temperature, for example about 60.degree. possibly up to room temperature.

La figure 4 est un diagramme montrant un cycle typique de recuit dans une ligne de galvanisation du type représenté sur la figure 2. La courbe 5a qui montre l'évolution de la température en fonction du temps est analogue aux courbes 5, 5' décrites précédemment et comporte donc les mêmes parties (51a, 52a) de montée en température, (53a) de maintien à la température de recuit, (54a) de refroidissement contrôlé à vitesse lente, puis (55a) de refroidissement rapide.The figure 4 is a diagram showing a typical cycle of annealing in a galvanizing line of the type shown in FIG. figure 2 . The curve 5a which shows the evolution of the temperature as a function of time is analogous to the curves 5, 5 'described previously and therefore comprises the same portions (51a, 52a) of temperature rise, (53a) of maintenance at the temperature of annealing, (54a) controlled cooling at low speed, then (55a) rapid cooling.

Comme indiqué plus haut, la ligne de galvanisation du type représenté sur la figure 2 comporte également une section 26 de régulation thermique permettant d'effectuer, tout d'abord un survieillissement (56a) puis, par un refroidissement (57a) ou, éventuellement un chauffage, d'amener la bande à la température (58a) souhaitable pour l'entrée dans le bain métallique de galvanisation.As indicated above, the galvanizing line of the type shown on the figure 2 also comprises a thermal control section 26 for performing, first of all over-aging (56a) and then, by cooling (57a) or possibly heating, to bring the strip to the temperature (58a) desirable for the entering the galvanizing bath.

Le cycle thermique 5a dans la ligne de galvanisation est donc analogue au cycle 5 dans une ligne de recuit du type représenté sur la figure 1, les différences venant essentiellement de la vitesse de défilement imposée par le processus de galvanisation qui ne doit pas dépasser, normalement, 200 m/mn afin de pouvoir contrôler l'épaisseur du revêtement déposé à la sortie du bain métallique alors que les vitesses habituelles des lignes de recuit continu pour tôles minces sont de l'ordre de 300 à 500 m/mn.The thermal cycle 5a in the galvanizing line is therefore similar to the cycle 5 in an annealing line of the type shown in FIG. figure 1 , the differences coming essentially from the speed of movement imposed by the galvanizing process which must not exceed, normally, 200 m / min in order to be able to control the thickness of the coating deposited at the exit of the metal bath whereas the usual speeds of Continuous annealing lines for thin sheets are in the range of 300 to 500 m / min.

De telles vitesses sont nécessaires pour obtenir la productivité souhaitée dans une ligne de recuit continu classique qui doit être capable de traiter des aciers de différents types pour lesquels le traitement thermique, en particulier de survieillissement, peut être plus ou moins complexe et nécessite l'utilisation de plusieurs unités de traitement successives.Such speeds are necessary to obtain the desired productivity in a conventional continuous annealing line which must be capable of treating steels of different types for which the heat treatment, in particular of over-aging, can be more or less complex and requires the use several successive processing units.

L'invention repose sur l'idée que, même pour réaliser des traitements de recuit classiques et relativement complexes, il devrait être possible de réduire la longueur de la section de survieillissement, par rapport à la longueur habituelle et que la suppression de certaines chambres de survieillissement permettrait de dégager un espace dans lequel une installation de galvanisation pourrait être incorporée, sans augmentation de l'encombrement global de la ligne de recuit, afin de réaliser une ligne combinée permettant d'effectuer, soit un traitement de recuit seul, soit un traitement de galvanisation précédé d'un recuit.The invention is based on the idea that, even for conventional and relatively complex annealing treatments, it should be possible to reduce the length of the overaging section, as compared to the usual length, and that the removal of certain chambers of overaging would provide a space in which a galvanizing plant could be incorporated, without increasing the overall size of the annealing line, to achieve a combined line to perform either an annealing treatment alone or a treatment of galvanization preceded by annealing.

Par exemple, si l'on supprimée le tiers des passes dans la section de survieillissement d'un four de recuit continu pour tôles minces dont les équipements sont dimensionnés, pour un format de produit donné, afin de permettre une vitesse de l'ordre de 300 m/mn, il suffit de réduire la vitesse de défilement à 200 m/mn pour réaliser le même traitement sur une section réduite d'un tiers, en conservant le même temps de maintien en température. Or, cette vitesse de 200 m/mn est voisine de la vitesse de défilement imposée habituellement pour le processus de galvanisation et convient donc à une ligne combinée.For example, if one-third of the passes in the overfill section of a continuous annealing furnace for thin sheets with equipment sizes are removed, for a given product format, to allow a speed of the order of 300 m / min, it is enough to reduce the running speed to 200 m / min to achieve the same treatment on a reduced section of a third, while maintaining the same temperature maintenance time. However, this speed of 200 m / min is close to the scroll speed usually imposed for the galvanizing process and is therefore suitable for a combined line.

On réalise ainsi une installation du type représenté schématiquement sur la figure 5 comportant, comme dans le cas de la figure 2, un dispositif d'entrée 1, un four de recuit 2, une installation de galvanisation 4 et un dispositif de sortie 3, mais dans laquelle la section 26 de mise à la température de galvanisation correspond à une partie seulement 24' de la section de survieillissement 24 du four de recuit 2 représenté sur la figure 1. L'installation de galvanisation 4' est donc incorporée à l'intérieur de la ligne de recuit puisqu'elle est placée entre la section réduite de survieillissement 26 et la section 25 de refroidissement lent sous atmosphère contrôlée.This produces an installation of the type shown schematically on the figure 5 including, as in the case of figure 2 , an inlet device 1, an annealing furnace 2, a galvanizing plant 4 and an outlet device 3, but in which the galvanizing temperature setting section 26 corresponds to a part only 24 'of the over-aging 24 of the annealing furnace 2 shown in FIG. figure 1 . The galvanizing plant 4 'is therefore incorporated inside the annealing line since it is placed between the reduced overaging section 26 and the slow cooling section under a controlled atmosphere.

De plus, la sortie de la section de survieillissement débouche dans un dispositif 80 de guidage sélectif permettant de diriger la bande M, soit directement vers la section de refroidissement lent 25, pour un traitement de recuit seul, soit vers l'entrée T1 de l'installation de galvanisation 4. Dans ce cas, à la sortie du bain de refroidissement final 45, la bande est dirigée directement vers le dispositif 3 de sortie de la ligne, en court-circuitant la section de refroidissement 25.In addition, the output of the overaging section opens into a selective guiding device 80 for directing the band M, either directly to the slow cooling section 25, for an annealing treatment alone, or to the input T1 of the In this case, at the outlet of the final cooling bath 45, the strip is directed directly towards the outlet device 3 of the line, by short-circuiting the cooling section 25.

Cependant, si l'on souhaite ne pas augmenter la longueur globale de la ligne de recuit, la place dégagée par la suppression d'une partie de la section de survieillissement doit présenter une longueur relativement faible, inférieure à l'emprise normale d'une installation classique de galvanisation.However, if one wishes not to increase the length In the overall annealing line, the space left by the removal of a portion of the overaging section must have a relatively small length, less than the normal footprint of a conventional galvanizing plant.

Il est donc intéressant de réaliser une installation de galvanisation particulièrement compacte.It is therefore interesting to realize a particularly compact galvanizing installation.

Pour cela, l'une des idées de l'invention consiste à modifier l'architecture habituelle des lignes continues de galvanisation en organisant de façon nouvelle le déroulement de la bande à la sortie du bain de zinc, de la façon représentée schématiquement sur la figure 5 et plus en détail sur la figure 6.For this, one of the ideas of the invention consists in modifying the usual architecture of the continuous galvanizing lines by organizing in a new way the unwinding of the strip at the outlet of the zinc bath, as shown schematically on the figure 5 and more in detail on the figure 6 .

A la sortie de la section de survieillissement 26, la bande a été portée à la température souhaitable pour la galvanisation, de la façon indiquée sur le diagramme de la figure 4. La bande sortant de la section 26 passe sur un rouleau déflecteur D1 qui la dirige vers le bain métallique de galvanisation 41 ménagé dans une cuve et dans lequel est immergé un rouleau déflecteur D2. La bande M suit donc un trajet descendant T1 entre le rouleau de sortie D1 et le rouleau immergé D2 sur lequel elle prend appui par sa face supérieure A.At the exit of the overaging section 26, the strip has been brought to the desired temperature for galvanizing, as shown in the diagram of FIG. figure 4 . The band leaving the section 26 passes over a deflector roll D1 which directs it to the galvanizing metal bath 41 formed in a tank and in which is immersed a deflection roll D2. The band M therefore follows a downward path T1 between the output roller D1 and the immersed roll D2 on which it bears by its upper face A.

La bande M ressort alors du bain 41 suivant un trajet ascendant T2 jusqu'à un rouleau supérieur D3, en passant devant un dispositif d'essorage 42 de type connu permettant de contrôler l'épaisseur du revêtement.The strip M then comes out of the bath 41 in an upward path T2 to an upper roll D3, passing in front of a wiper device 42 of known type for controlling the thickness of the coating.

Toutes ces dispositions sont classiques et correspondent à celles représentées schématiquement sur la figure 2.All these provisions are classic and correspond to those shown schematically on the figure 2 .

Dans l'invention, cependant, la bande M prend appui sur le rouleau supérieur D3 par la même face A passant sur le rouleau immergé D2 et, de ce fait, au lieu d'être dirigée vers l'extérieur du bac contenant le bain métallique 41, la bande M revient en arrière vers le côté d'entrée dans le bac, c'est-à-dire le côté gauche sur les figures 5 et 6.In the invention, however, the band M bears on the upper roll D3 by the same side A passing on the immersed roll D2 and, therefore, instead of being directed towards the outside of the tank containing the metal bath 41, the band M returns back to the entrance side in the tray, that is to say the left side on the figures 5 and 6 .

Dans le cas de la figure 5, la bande repasse sur un rouleau supérieur D'3 et redescend, par un trajet descendant T3, jusqu'à un rouleau déflecteur D4 immergé dans le bain de trempe 45. La bande ressort alors de ce bain 45 suivant un trajet montant T4 jusqu'à une paire de rouleaux déflecteurs supérieurs D5, D'5 écartés l'un de l'autre, de façon à passer au-dessus de l'ensemble de l'installation de galvanisation 41 et de la section de refroidissement lent 25, puis redescend, par un trajet descendant T5, jusqu'à un rouleau inférieur D6 afin d'être dirigée vers l'accumulateur 31 du dispositif de sortie 3.In the case of figure 5 , the strip returns to an upper roll D'3 and descends, by a downward path T3, to a deflector roll D4 immersed in the quenching bath 45. The The strip then exits from this bath 45 along a rising path T4 to a pair of upper deflector rollers D5, 5 spaced apart from each other, so as to pass over the entire installation. galvanizing 41 and the slow cooling section 25, then descends, by a downward path T5, to a lower roller D6 to be directed to the accumulator 31 of the output device 3.

Il résulte de cet arrangement du trajet de la bande que le bain de trempe 45 peut être placé au-dessus de la cuve contenant le bain métallique de galvanisation 41. Ainsi, l'emprise au sol de l'installation de galvanisation 4 est diminuée par rapport à la disposition classique de la figure 2 puisqu'elle couvre sensiblement la même longueur que le bain de galvanisation 41.As a result of this arrangement of the path of the strip, the quenching bath 45 can be placed above the tank containing the galvanizing metal bath 41. Thus, the footprint of the galvanizing plant 4 is reduced by compared to the classic layout of the figure 2 since it covers substantially the same length as the galvanizing bath 41.

Certes, cette disposition nécessite la construction, au-dessus du bain métallique 41, d'un plancher pour supporter la cuve de trempe 45 mais cette augmentation de hauteur de l'installation ne constitue pas un véritable inconvénient, en particulier pour la transformation d'une installation existante. En revanche, le retour vers l'arrière de la bande à partir du rouleau supérieur D3 permet d'incorporer l'ensemble de l'installation de galvanisation dans l'espace de longueur réduite existant, entre la partie restante de la section de survieillissement 26 et la section de refroidissement lent 25.Admittedly, this arrangement requires the construction, above the metal bath 41, of a floor to support the quench tank 45 but this increase in height of the installation does not constitute a real disadvantage, particularly for the transformation of an existing installation. On the other hand, the return towards the rear of the strip from the upper roller D3 makes it possible to incorporate the entire galvanizing installation into the existing reduced space between the remaining part of the overaging section. and the slow cooling section 25.

De façon connue, il est possible de réaliser un traitement thermique dit d'alliation qui assure la diffusion du fer provenant de la bande vers le revêtement de zinc afin de créer un véritable alliage fer/zinc. A cet effet, il est possible de placer un four d'alliation 43 au-dessus du dispositif d'essorage 42. Ce four d'alliation peut être suivi de cellules de refroidissement 44a, 44b qui peuvent être placées non seulement sur le trajet ascendant T2, en amont du rouleau supérieur D3, mais également sur le trajet descendant T3, avant l'entrée dans le bain de trempe 45.In known manner, it is possible to perform a so-called alloy heat treatment which ensures the diffusion of iron from the band to the zinc coating to create a real iron / zinc alloy. For this purpose, it is possible to place an alloy oven 43 above the wiper device 42. This alloying oven can be followed by cooling cells 44a, 44b which can be placed not only on the upward path T2, upstream of the upper roller D3, but also on the descending path T3, before entering the quench bath 45.

Pour réaliser un refroidissement suffisant de la bande avant la trempe, sans augmenter exagérément la hauteur de l'installation, il est également possible de réaliser l'arrangement représenté schématiquement sur la figure 6 dans lequel, après son passage sur le rouleau supérieur D3, la bande redescend jusqu'à un rouleau inférieur D6, puis remonte jusqu'à un rouleau supérieur D'6 afin de redescendre dans le bac de trempe 45 en passant sur le rouleau immergé D4.To achieve sufficient cooling of the strip before quenching, without unduly increasing the height of the installation, it is also possible to make the arrangement schematically represented on the figure 6 in which, after passing over the upper roll D3, the strip descends to a lower roll D6, then back to an upper roller D'6 to descend into the quenching tank 45 by passing on the submerged roll D4 .

Une telle disposition est également particulièrement compacte puisque, à chaque changement de direction, la bande passe sur un seul rouleau en revenant, comme précédemment, vers l'arrière.Such an arrangement is also particularly compact since, at each change of direction, the band passes on a single roll returning, as before, to the rear.

Cette disposition permet également de répartir des moyens de refroidissement 44, 44' non seulement le long du trajet ascendant T2 mais également le long du trajet descendant T3 de façon à réaliser un refroidissement suffisant du revêtement.This arrangement also makes it possible to distribute cooling means 44, 44 'not only along the upward path T2 but also along the downward path T3 so as to provide sufficient cooling of the coating.

Il est à noter que, grâce à cette disposition, la face A' de la bande opposée à la face A passant sur le rouleau immergé D2, ne vient au contact du rouleau inférieur D6 qu'après le trajet ascendant T2 et le trajet descendant T3 et, ainsi, ne risque pas d'être détériorée avant le durcissement du revêtement. Une telle disposition est particulièrement intéressante dans les applications où une face externe de la tôle, dite « face exposée », doit avoir une excellente qualité de surface, par exemple pour la carrosserie automobile.It should be noted that, thanks to this arrangement, the face A 'of the strip opposite the face A passing on the immersed roll D2, comes into contact with the lower roll D6 after the upward path T2 and the descending path T3 and, thus, not likely to be deteriorated before curing the coating. Such an arrangement is particularly advantageous in applications where an outer face of the sheet, called "exposed face" must have excellent surface quality, for example for the automobile body.

Comme le montre la figure 6, les cellules de refroidissement et, le cas échéant, le four d'alliation 43, peuvent avantageusement être implantés en quinconce sur le brin ascendant T2 et le bras descendant T3 qui, dans le cas de la figure 6, ne sont séparés que par un seul rouleau déflecteur D3, ce qui diminue encore l'emprise au sol de l'ensemble.As shown in figure 6 , the cooling cells and, where appropriate, the alloying furnace 43, may advantageously be staggered on the ascending strand T2 and the descending arm T3 which, in the case of the figure 6 , are separated only by a single deflection roll D3, which further reduces the footprint of the assembly.

De plus, une telle disposition permet de répartir les cellules de refroidissement 44a, 44b sur une plus grande longueur de bande et d'avoir ainsi un soufflage moins violent, ce qui diminue les risques de vibration de la bande pouvant avoir un impact sur la qualité du revêtement, en particulier la régulation de son épaisseur.In addition, such an arrangement makes it possible to distribute the cooling cells 44a, 44b over a greater length of strip and thus to have a less violent blowing, which reduces the risks of vibration of the strip which may have an impact on the quality. coating, in particular the regulation of its thickness.

Comme indiqué plus haut, même si sa longueur est réduite par rapport à la disposition habituelle des fours de recuit représentés sur la figure 1, la section 26 de sortie du four 2 permet, en réglant la vitesse de défilement à un niveau modéré, par exemple de 200 m/mn, d'effectuer un traitement de survieillissement adapté à la nature du métal, puis d'assurer la mise en température adéquate de la bande avant son entrée dans le bain de zinc 41.As mentioned above, even if its length is reduced compared to the usual arrangement of annealing furnaces shown on the figure 1 , the outlet section 26 of the oven 2 allows, by adjusting the speed of travel at a moderate level, for example 200 m / min, to perform a survival treatment adapted to the nature of the metal, then to ensure the implementation at the appropriate temperature of the strip before entering the zinc bath 41.

Il est à noter, en particulier, que l'évolution actuelle du marché conduit à réaliser des aciers pour lesquels le survieillissement, après recuit, s'effectue à une température relativement basse.It should be noted, in particular, that the current evolution of the market leads to making steels for which the aging, after annealing, is carried out at a relatively low temperature.

La figure 7, par exemple, montre un cycle complet de recuit pour un acier de type « TRIP » qui nécessite, après recuit, un maintien isotherme dans la zone de transformation Bainitique, c'est-à-dire vers 290°C. Dans ce cas, la section 26 de sortie du four doit remonter la température de la bande jusqu'à un niveau compatible avec la température du bain de zinc, par exemple 470°C.The figure 7 , for example, shows a complete annealing cycle for a "TRIP" type steel which requires, after annealing, isothermal retention in the bainitic transformation zone, that is to say around 290 ° C. In this case, the outlet section 26 of the furnace must raise the temperature of the strip to a level compatible with the temperature of the zinc bath, for example 470 ° C.

La figure 8, en revanche, correspond au cas d'un acier courant nécessitant un survieillissement, par exemple à 560°C. Dans ce cas, la température doit être abaissée jusqu'à la température du bain de zinc.The figure 8 on the other hand, corresponds to the case of a common steel requiring overaging, for example at 560 ° C. In this case, the temperature must be lowered to the temperature of the zinc bath.

La section 26 de régulation en température sera donc équipée de moyens de chauffage, de préférence par induction et de refroidissement, de préférence par jet de gaz neutre.The temperature control section 26 will therefore be equipped with heating means, preferably by induction and cooling, preferably by neutral gas jet.

Il est à noter, d'autre part, que l'installation de galvanisation 4 placée, selon l'invention, entre la section 26 de sortie du four 2 et la section 25 de refroidissement lent, est munie, à sa sortie, d'un bain de trempe 45 à la sortie duquel la bande se trouve à une température proche de l'ambiante. De ce fait, il n'est pas nécessaire de faire passer la bande dans la section de refroidissement lent 25, le bain de trempe 45 étant relié directement à l'accumulateur de sortie 31.It should be noted, on the other hand, that the galvanizing installation 4 placed, according to the invention, between the outlet section 26 of the oven 2 and the slow cooling section 25, is provided, at its output, with a quenching bath 45 at the output of which the strip is at a temperature close to ambient. Therefore, it is not necessary to pass the strip in the slow cooling section 25, the quenching bath 45 being connected directly to the output accumulator 31.

On a ainsi réalisé une ligne combinée permettant d'assurer, selon les cas, les fonctions de ligne de recuit continu dans le four 2 et la section de refroidissement final 25 et de ligne continue de galvanisation dans le four 2 et l'installation de galvanisation 4 qui se termine par le bain de trempe 45.A combined line has thus been realized to ensure, as the case may be, the continuous annealing line functions in the oven 2 and the final cooling section 25 and galvanizing continuous line in the furnace 2 and the galvanizing plant 4 which ends with the quench bath 45.

La figure 9 montre schématiquement la disposition d'une installation permettant de passer facilement d'un mode de fonctionnement à l'autre.The figure 9 schematically shows the layout of an installation to easily switch from one mode of operation to another.

Le recuit devant s'effectuer dans une atmosphère contrôlée, l'ensemble du four de recuit 2, avec la section de survieillissement 26, est placé dans une enceinte fermée 8 munie à sa base d'un conduit 80 qui forme un embranchement avec deux sorties, respectivement une première sortie 81 qui plonge à l'intérieur du bain métallique 41 afin d'assurer l'étanchéité, et une seconde sortie 82 qui peut être fermée de façon amovible par une porte 83.The annealing to be carried out in a controlled atmosphere, the entire annealing furnace 2, with the overaging section 26, is placed in a closed enclosure 8 provided at its base with a conduit 80 which forms a branch with two outlets , respectively a first outlet 81 which plunges inside the metal bath 41 to ensure sealing, and a second outlet 82 which can be removably closed by a door 83.

D'autre part, la section de refroidissement lent 25, également placée sous atmosphère contrôlée, est disposée dans une enceinte étanche 8' dont l'entrée 81' peut être reliée avec la seconde sortie 82 du conduit 80, par une goulotte de liaison 84 qui peut être déplacée, par exemple par pivotement, entre la position représentée sur la figure 9 pour laquelle la goulotte 84 être branchée de façon étanche sur la seconde sortie 82 du conduit 80 et une position écartée permettant le passage de la bande M suivant le trajet T2, à la sortie du bain métallique 41.On the other hand, the slow cooling section 25, also placed under a controlled atmosphere, is disposed in a sealed enclosure 8 'whose inlet 81' can be connected to the second outlet 82 of the duct 80 via a connecting chute 84 which can be moved, for example by pivoting, between the position shown on the figure 9 for which the chute 84 is tightly connected to the second outlet 82 of the duct 80 and a spaced apart position allowing the passage of the strip M along the path T2, at the outlet of the metal bath 41.

Cette goulotte mobile 84 forme donc un tunnel de by-pass permettant, lorsqu'elle est mise en place et la porte 83 ouverte, d'assurer le passage de la bande M entre le rouleau déflecteur D1 placé à la sortie du four et la section de refroidissement 25, en assurant l'étanchéité entre les deux enceintes fermées 8 et 8' dans lesquelles est ménagée une atmosphère neutre, par exemple un mélange d'azote et d'hydrogène.This mobile chute 84 thus forms a bypass tunnel allowing, when it is put in place and the door 83 open, to ensure the passage of the band M between the deflector roll D1 placed at the outlet of the oven and the section cooling 25, sealing between the two closed enclosures 8 and 8 'in which is formed a neutral atmosphere, for example a mixture of nitrogen and hydrogen.

La figure 10 est un schéma de principe du fonctionnement d'une telle ligne combinée.The figure 10 is a schematic diagram of the operation of such a combined line.

Pour effectuer une galvanisation après recuit, la bande M passe successivement dans les différentes sections du four de recuit 2 et, après mise à température dans la section de sortie 26, passe par la première sortie 81 du conduit 80 pour déboucher dans le bain de zinc 41. Comme le montre la figure 9, à la sortie du bain de trempe 45, la bande M guidée par les rouleaux déflecteurs D5, D'5, D7, passe au-dessous ou, éventuellement, au-dessus de la section de refroidissement lent 25 pour être dirigée directement vers le dispositif 3 de sortie de la ligne.To carry out a galvanization after annealing, the band M successively passes through the various sections of the annealing furnace 2 and, after being put into temperature in the outlet section 26, passes through the first outlet 81 of the duct 80 to open into the zinc bath 41. As shown in figure 9 at the outlet of the quenching bath 45, the strip M guided by the deflecting rollers D5, D5, D7, passes below or, optionally, above the slow cooling section 25 to be directed directly to the 3 output device of the line.

Pour effectuer un recuit seul, la goulotte de liaison 84 est mise en place et la porte 83 est ouverte. A partir du rouleau déflecteur D1, la bande M passe dans la goulotte de liaison 84, puis dans la section de refroidissement lent 25 qui, de préférence, se termine par un bac de trempe 27, puis elle est dirigée, par les rouleaux entraîneurs D8, vers le dispositif 3 de sortie de la ligne.To perform annealing alone, the connecting trough 84 is put in place and the door 83 is opened. From the deflector roll D1, the band M passes into the connecting chute 84, then into the slow cooling section 25 which preferably terminates in a quenching tank 27 and is then directed by the drive rollers D8 to the output device 3 of the line.

L'installation est munie, d'autre part, de moyens non représentés sur la figure 9, permettant de couper la bande, soit en un point 85, à l'entrée dans la goulotte de liaison 84, soit en un point 86, à la sortie de la zone de refroidissement 25, en amont des rouleaux entraîneurs D8.The installation is equipped, on the other hand, with means not represented on the figure 9 , making it possible to cut the strip, either at a point 85, at the inlet into the connecting chute 84, or at a point 86, at the outlet of the cooling zone 25, upstream of the driving rollers D8.

A l'arrêt d'une campagne de recuit continu, la bande est coupée en ces deux points 85 et 86, le tunnel mobile 84 est relevé verticalement et maintenu contre la paroi avant de l'enceinte 8' contenant la section de refroidissement 25. Une portion de bande reste donc engagée dans le tunnel 84 et la section 25. Elle servira de « bande de tirage » pour remettre la ligne en configuration de recuit lors d'une autre campagne.At the end of a continuous annealing campaign, the strip is cut at these two points 85 and 86, the mobile tunnel 84 is raised vertically and held against the front wall of the enclosure 8 'containing the cooling section 25. A band portion remains engaged in the tunnel 84 and section 25. It will serve as a "pull tape" to put the line in annealing configuration in another campaign.

De la même façon, à l'arrêt d'une campagne de galvanisation, la bande est coupée en deux points, respectivement 87 à la sortie du bain de zinc 41 et 88 après la sortie du bain de trempe 45. Les brins pendants de la bande sont fixés aux éléments de charpente portant l'installation de galvanisation 4'. Une portion de bande reste donc engagée dans cette zone et servira de bande de tirage pour remettre la ligne en configuration de galvanisation, lors d'une autre campagne.Similarly, at the end of a galvanizing campaign, the strip is cut at two points, respectively 87 at the exit of the zinc bath 41 and 88 after the exit of the quenching bath 45. The hanging strands of the strip are attached to the frame members carrying the galvanizing plant 4 '. A portion of band remains engaged in this area and will serve as a draw tape to put the line in galvanizing configuration, in another campaign.

Pour passer d'une configuration à l'autre, il suffit donc de souder ou d'agrafer la portion concernée de « bande de tirage » au bout de la nouvelle bande, au niveau du rouleau déflecteur D1, dans le conduit 80 de sortie de la zone de survieillissement 26, puis de faire avancer cette bande de tirage jusqu'à la cisaille 33, à la sortie de la ligne, pour l'éliminer.To pass from one configuration to another, it suffices to weld or staple the relevant portion of "pulling strip" at the end of the new strip, at the level of the deflector roll D1, in the outlet duct 80 of the overaging zone 26, then to advance this pulling strip to the shear 33, at the exit of the line, to eliminate it.

L'invention permet ainsi de réaliser, soit un recuit seul, soit une galvanisation après recuit, dans une ligne combinée du type représenté sur la figure 5, dont l'encombrement global, en longueur, est du même ordre que celui d'une ligne de recuit continu classique, dans la mesure où l'installation de galvanisation, en particulier si elle est réalisée de la façon particulièrement compacte décrite précédemment, peut être incorporée à l'intérieur de la ligne de recuit, entre la section de survieillissement et la section de refroidissement lent.The invention thus makes it possible to carry out either an annealing alone or a galvanization after annealing in a combined line of the type shown in FIG. figure 5 , the overall overall length of which is of the same order as that of a conventional continuous annealing line, insofar as the galvanizing installation, in particular if it is carried out in the particularly compact manner described above, can incorporated within the annealing line, between the overaging section and the slow cooling section.

De ce fait, l'invention trouvera une application particulièrement intéressante pour la transformation de lignes de recuit continu existantes dont la rentabilité n'est plus assurée en raison de la variété des qualités de tôles demandées et de la baisse de tonnage qui en résulte.Therefore, the invention will find a particularly interesting application for the transformation of existing continuous annealing lines whose profitability is no longer assured due to the variety of qualities of sheet required and the resulting tonnage decline.

En effet, du fait que les tonnages demandés sont plus faibles, Il sera possible de réduire la vitesse de défilement et de supprimer certaines unités de la section de survieillissement, la partie restante de cette section étant suffisante pour réaliser les traitements thermiques nécessaires pour la plupart des qualités d'acier demandés actuellement, l'espace ainsi dégagé permettant de loger une installation de galvanisation de type compact telle que décrite précédemment.Indeed, because the tonnages requested are lower, It will be possible to reduce the speed of scrolling and remove some units of the overaging section, the remaining portion of this section being sufficient to achieve the heat treatments necessary for most steel qualities currently required, the space thus cleared to accommodate a compact type galvanizing installation as described above.

Il est à noter, par ailleurs, qu'un certain nombre des équipements utilisés dans la partie supprimée de la section de survieillissement, en particulier les cellules de refroidissement par jet de gaz et les organes annexes pourront être utilisés dans l'installation de galvanisation.It should be noted, moreover, that a number of the equipment used in the deleted part of the over-aging section, in particular the gas jet cooling cells and the auxiliary members may be used in the galvanizing plant.

L'invention présente encore d'autres avantages et ne se limite pas aux détails des modes de réalisation qui ont été décrits à titre de simples exemples. Par exemple, après un refroidissement suffisant par les cellules 44a, 44b placées sur le trajet de la bande à la sortie du bain de galvanisation 41, la bande pourrait passer au-dessus de la section de refroidissement 25 pour descendre directement dans le bain de trempe 27 placé à la sortie de celle-ci. Cependant, l'utilisation, selon le mode de réalisation préférentiel de la figure 9, de deux bacs de trempe séparées, respectivement 45 à la sortie de l'installation de galvanisation 4 et 27 à la sortie de la zone de refroidissement 25, permet d'éviter la pollution par les poussières de zinc du bac de refroidissement 27 dans lequel passent les bandes recuites non revêtues, en cas de fonctionnement en recuit seul.The invention has further advantages and is not limited to the details of the embodiments which have been described as mere examples. For example, after sufficient cooling by the cells 44a, 44b placed in the path of the strip at the exit of the galvanizing bath 41, the band could pass over the cooling section 25 for descend directly into the quench bath 27 placed at the outlet thereof. However, the use, according to the preferred embodiment of the figure 9 , two separate quench tanks, respectively 45 at the exit of the galvanizing plant 4 and 27 at the outlet of the cooling zone 25, avoids the pollution by zinc dust cooling tank 27 in which pass the uncoated annealed strips, in case of annealing operation alone.

Claims (12)

  1. Combined annealing and galvanisation line for a metal strip (1) having means to control the movement of the strip along a continuous line, between an input device (1) and an output device (3) of the line, successively in an annealing installation (2) and a galvanisation installation (4), the annealing installation (2) having a heating section (21), a section (22) for keeping the strip (M) at an annealing temperature, a first section (23) for rapid quenching following annealing, an over-ageing section (24) and a second slow quenching section (25), and the galvanisation installation (4) having a strip input section (T1) in a metal galvanisation bath (41), an output section (T2) from the metal bath of the strip covered, on both faces, with a coating, a section (T3) for quenching the coating and a final quenching liquid bath (45), characterised in that the galvanisation installation (4) is built inside the annealing installation, between the over-ageing section (24, 26), and the second quenching section (25) and that, at the output of the over-ageing section (24, 26), the strip is directed by selective guiding means (80), either towards the galvanisation installation (4) then, at the output of the final quenching bath (45), directly towards the line output device (3), or directly towards the second quenching section (25) and the line output device (3).
  2. Combined line according to claim 1, characterised in that the over-ageing section (26) and the second quenching section (25) of the annealing installation (2) are each placed in a sealed enclosure (8, 8') filled with a protective gas and that the input section in the metal galvanisation bath (41) is placed in a sealed conduit (80) forming a junction with an input connected to the output of the enclosure (6) of the over-ageing section (26) and two outputs, respectively a first output (81) dropping into the metal bath (41) and a second output (82) to which is connected a detachable chute (84) making a sealed connection with the enclosure (81) of the second quenching section (25) of the annealing installation, said second output (82) being provided with detachable sealing means (83).
  3. Combined line according to claim 2, characterised in that it has a plurality of deflector rolls defining two strip routes at the output of the over-ageing section (16), respectively a first galvanisation route having an input section (T1) in the metal bath passing via a first output (81) of the sealed conduit (80), an output section (T2) from the metal bath (41), a coating quenching section (T3) before input in the final quenching bath (45) and an output section (T4, T5) from said quenching bath (45), passing above or below the enclosure (8') in which is placed the second quenching section (25), such as to connect directly to the line output device (3), and a second annealing-only route, passing through a detachable linking chute (84) between the second output (82) of the sealed conduit (80) and the enclosure (81) of the second quenching section (25).
  4. Combined line according to one of claims 1, 2, 3, characterised in that it has two final quenching liquid baths for the strip, respectively a first bath (45) placed at the output of the galvanisation installation (4), and a second bath (27) placed at the output of the second quenching section (25), the strip (M) being directed towards the line output device (3) once final quenching is complete, either in the first bath (45) after galvanisation, or in the second bath (27) after annealing-only treatment, without galvanisation.
  5. Combined line according to one of the preceding claims, characterised in that the final quenching bath (45) of the galvanisation installation (4), is placed above the metal bath (41) and offset towards it in order to reduce the footprint of the galvanisation installation (4).
  6. Combined line according to one of the preceding claims, characterised in that the length of the over-ageing section (26) is shorter than the length normally required in a continuous annealing line and that the strip movement speed is adjusted to this reduced length in order to achieve the required thermal treatment time.
  7. Method for transforming a continuous annealing line for a metal strip in a combined annealing and galvanisation line, said annealing line (2) having means for controlling the continuous movement of the strip, successively, in an input device (1), a preheating section (21), an annealing section (22) with a temperature maintained at the level required depending on the type of strip, a first post-annealing quenching section (23), an over-ageing section (24), a second slow quenching section (25) in a protective atmosphere and an output device (3), characterised in that a part of the over-ageing section (24) is removed leaving the other sections in place and that a galvanisation installation (4) is placed inside the annealing line (2), in the space thus created between the remaining part (26) of the over-ageing section (24) and the second slow-quenching section (25), and connected to the movement control means such as to create a combined annealing and galvanisation line without increasing the overall length of the annealing line (2).
  8. Method according to claim 7 for transforming an annealing line into a combined annealing and galvanisation line, characterised in that the strip movement speed between the input device (1) and the output device (3) of the strip is adapted to the galvanisation process.
  9. Method according to claim 8, characterised in that the galvanisation installation (4) replaces just one part (26) of the over-ageing section (24) and that the movement speed of the strip (M) is adjusted, if necessary, such as to perform an over-ageing treatment in the remaining part (26) of the corresponding section (24).
  10. Method according to claim 7, characterised in that the temperature in the annealing section is maintained at the level required for annealing, in consideration of the type of strip and the movement speed and that, between the output of the quick quenching section (21) and the input in the galvanisation bath (41), the remaining part (26) of the over-ageing section (24) has combined heating and quenching means for adjusting the temperature of the strip to the level required for the galvanisation process.
  11. Method according to one of claims 7 to 10 for transforming a continuous annealing line (1, 2, 3) into a combined annealing and galvanisation line, characterised in that the galvanisation installation (4) has means to control the movement of the strip between a metal galvanisation bath (41) and a quench bath (45), along a continuous movement route defined by a plurality of deflector rolls (D1 ... D6) and comprising at least four parts, respectively a first part (T1) linking the quick quenching section (23) and the input in the metal bath (41), a second output part (T2) from the metal bath (41) with coating thickness check, a third part (T3) for quenching the coating before entry in the quench bath (45) and a fourth output part (T4, T5) from the quench bath (45), connected directly to the output section of the annealing line, without passing via the slow quenching section (25).
  12. Method according to claim 11, characterised in that, to adapt the overall footprint of the galvanisation installation (4) to the length of the space created in the annealing line (2), the quench bath (45) is placed above the metal bath (41) and offset towards the line input side, such that, in the third quenching part (T3), the strip (M) turns backwards and, in the fourth output part (T4) from the quench bath (45), it passes above or below the metal bath (41) then the slow quenching section (25), in order to connect directly to the line output device (3).
EP08831213A 2007-08-10 2008-07-03 Combined annealing and galvanisation line and method for converting a continuous annealing line into such combined line Active EP2176438B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0757023A FR2919876B1 (en) 2007-08-10 2007-08-10 COMBINED LINE OF ANNEALING AND GALVANIZING AND PROCESS FOR TRANSFORMING A CONTINUOUS ANNEALING LINE INTO SUCH A COMBINED LINE
PCT/FR2008/000968 WO2009034243A1 (en) 2007-08-10 2008-07-03 Combined annealing and galvanisation line and method for converting a continuous annealing line into such combined line

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EP2176438A1 EP2176438A1 (en) 2010-04-21
EP2176438B1 true EP2176438B1 (en) 2011-01-12

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AT (1) ATE495277T1 (en)
DE (1) DE602008004544D1 (en)
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CN102298361B (en) * 2010-06-25 2012-12-19 鞍钢股份有限公司 Emergency stop system of continuous annealing production line and control method
WO2016001701A1 (en) * 2014-07-03 2016-01-07 Arcelormittal Polyvalent processing line for heat treating and hot dip coating a steel strip
FR3095452A1 (en) * 2019-04-29 2020-10-30 Fives Stein Dual Purpose Metal Strip Continuous Processing Line
CN110079658A (en) * 2019-06-10 2019-08-02 苏州新凌电炉有限公司 A kind of environment-friendly type steel wire thermal treatment production line
CN112281079B (en) * 2020-09-25 2021-11-19 河钢股份有限公司承德分公司 Hot-base galvanized steel coil and preparation method thereof

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JP2824345B2 (en) * 1991-05-10 1998-11-11 三菱重工業株式会社 Hot dip galvanized steel sheet alloying equipment
JPH05195176A (en) * 1992-01-22 1993-08-03 Kawasaki Steel Corp Continuous hot-dip metal coating equipment for steel strip

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WO2009034243A1 (en) 2009-03-19
EP2176438A1 (en) 2010-04-21
DE602008004544D1 (en) 2011-02-24
FR2919876A1 (en) 2009-02-13
FR2919876B1 (en) 2009-10-09
ATE495277T1 (en) 2011-01-15

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