EP2162023B1 - Smoking article with controlled flavor release - Google Patents
Smoking article with controlled flavor release Download PDFInfo
- Publication number
- EP2162023B1 EP2162023B1 EP08807184.0A EP08807184A EP2162023B1 EP 2162023 B1 EP2162023 B1 EP 2162023B1 EP 08807184 A EP08807184 A EP 08807184A EP 2162023 B1 EP2162023 B1 EP 2162023B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- time
- flavorant
- release
- smoking article
- controlled flavor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000796 flavoring agent Substances 0.000 title claims description 162
- 235000019634 flavors Nutrition 0.000 title claims description 162
- 230000000391 smoking effect Effects 0.000 title claims description 53
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 12
- 238000009472 formulation Methods 0.000 claims description 11
- 239000007934 lip balm Substances 0.000 claims description 11
- 239000003094 microcapsule Substances 0.000 claims description 11
- 230000007246 mechanism Effects 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 claims description 5
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 241000167854 Bourreria succulenta Species 0.000 claims description 3
- 244000061176 Nicotiana tabacum Species 0.000 claims description 3
- 235000019618 chemesthesis Nutrition 0.000 claims description 3
- 235000019693 cherries Nutrition 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 230000001960 triggered effect Effects 0.000 claims description 3
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims description 2
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims description 2
- 244000223760 Cinnamomum zeylanicum Species 0.000 claims description 2
- 241000207199 Citrus Species 0.000 claims description 2
- 240000004670 Glycyrrhiza echinata Species 0.000 claims description 2
- 235000001453 Glycyrrhiza echinata Nutrition 0.000 claims description 2
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 claims description 2
- 235000017382 Glycyrrhiza lepidota Nutrition 0.000 claims description 2
- 235000019501 Lemon oil Nutrition 0.000 claims description 2
- 235000006679 Mentha X verticillata Nutrition 0.000 claims description 2
- 235000002899 Mentha suaveolens Nutrition 0.000 claims description 2
- 235000001636 Mentha x rotundifolia Nutrition 0.000 claims description 2
- 244000299461 Theobroma cacao Species 0.000 claims description 2
- 235000009499 Vanilla fragrans Nutrition 0.000 claims description 2
- 235000012036 Vanilla tahitensis Nutrition 0.000 claims description 2
- 235000019219 chocolate Nutrition 0.000 claims description 2
- 235000017803 cinnamon Nutrition 0.000 claims description 2
- 239000001926 citrus aurantium l. subsp. bergamia wright et arn. oil Substances 0.000 claims description 2
- 235000020971 citrus fruits Nutrition 0.000 claims description 2
- 239000008369 fruit flavor Substances 0.000 claims description 2
- 239000010648 geranium oil Substances 0.000 claims description 2
- 235000019717 geranium oil Nutrition 0.000 claims description 2
- 239000010649 ginger oil Substances 0.000 claims description 2
- 239000010501 lemon oil Substances 0.000 claims description 2
- 229940010454 licorice Drugs 0.000 claims description 2
- 229930007744 linalool Natural products 0.000 claims description 2
- 229960001047 methyl salicylate Drugs 0.000 claims description 2
- 235000013599 spices Nutrition 0.000 claims description 2
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical compound CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 claims 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims 1
- 239000001730 (5R)-5-butyloxolan-2-one Substances 0.000 claims 1
- 241000675108 Citrus tangerina Species 0.000 claims 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims 1
- 244000263375 Vanilla tahitensis Species 0.000 claims 1
- 239000008376 breath freshener Substances 0.000 claims 1
- 229940073505 ethyl vanillin Drugs 0.000 claims 1
- IPBFYZQJXZJBFQ-UHFFFAOYSA-N gamma-octalactone Chemical compound CCCCC1CCC(=O)O1 IPBFYZQJXZJBFQ-UHFFFAOYSA-N 0.000 claims 1
- 238000009499 grossing Methods 0.000 claims 1
- 229940041616 menthol Drugs 0.000 claims 1
- 241000208125 Nicotiana Species 0.000 description 36
- 235000019504 cigarettes Nutrition 0.000 description 14
- 238000001914 filtration Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000011144 upstream manufacturing Methods 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000013270 controlled release Methods 0.000 description 3
- 230000035807 sensation Effects 0.000 description 3
- 235000019615 sensations Nutrition 0.000 description 3
- 239000002594 sorbent Substances 0.000 description 3
- 235000019505 tobacco product Nutrition 0.000 description 3
- XPCTZQVDEJYUGT-UHFFFAOYSA-N 3-hydroxy-2-methyl-4-pyrone Chemical compound CC=1OC=CC(=O)C=1O XPCTZQVDEJYUGT-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- LOUPRKONTZGTKE-WZBLMQSHSA-N Quinine Chemical compound C([C@H]([C@H](C1)C=C)C2)C[N@@]1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OC)C=C21 LOUPRKONTZGTKE-WZBLMQSHSA-N 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 description 2
- 235000019506 cigar Nutrition 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000007888 film coating Substances 0.000 description 2
- 238000009501 film coating Methods 0.000 description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002077 nanosphere Substances 0.000 description 2
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N pentanal Chemical compound CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- WTOYNNBCKUYIKC-JMSVASOKSA-N (+)-nootkatone Chemical compound C1C[C@@H](C(C)=C)C[C@@]2(C)[C@H](C)CC(=O)C=C21 WTOYNNBCKUYIKC-JMSVASOKSA-N 0.000 description 1
- 229940098795 (3z)- 3-hexenyl acetate Drugs 0.000 description 1
- WLJVXDMOQOGPHL-PPJXEINESA-N 2-phenylacetic acid Chemical compound O[14C](=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-PPJXEINESA-N 0.000 description 1
- JDLKFOPOAOFWQN-VIFPVBQESA-N Allicin Natural products C=CCS[S@](=O)CC=C JDLKFOPOAOFWQN-VIFPVBQESA-N 0.000 description 1
- 235000001258 Cinchona calisaya Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241001640034 Heteropterys Species 0.000 description 1
- HYMLWHLQFGRFIY-UHFFFAOYSA-N Maltol Natural products CC1OC=CC(=O)C1=O HYMLWHLQFGRFIY-UHFFFAOYSA-N 0.000 description 1
- YKVWPZJHENXDAJ-VOTSOKGWSA-N Megastigmatrienone Chemical compound CC1=CC(=O)CC(C)(C)C1\C=C\C=C YKVWPZJHENXDAJ-VOTSOKGWSA-N 0.000 description 1
- 244000024873 Mentha crispa Species 0.000 description 1
- 235000014749 Mentha crispa Nutrition 0.000 description 1
- 244000246386 Mentha pulegium Species 0.000 description 1
- 235000016257 Mentha pulegium Nutrition 0.000 description 1
- 235000004357 Mentha x piperita Nutrition 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- 244000290333 Vanilla fragrans Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- JDLKFOPOAOFWQN-UHFFFAOYSA-N allicin Chemical compound C=CCSS(=O)CC=C JDLKFOPOAOFWQN-UHFFFAOYSA-N 0.000 description 1
- 235000010081 allicin Nutrition 0.000 description 1
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 description 1
- 235000019568 aromas Nutrition 0.000 description 1
- 239000000227 bioadhesive Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 235000017663 capsaicin Nutrition 0.000 description 1
- 229960002504 capsaicin Drugs 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- LOUPRKONTZGTKE-UHFFFAOYSA-N cinchonine Natural products C1C(C(C2)C=C)CCN2C1C(O)C1=CC=NC2=CC=C(OC)C=C21 LOUPRKONTZGTKE-UHFFFAOYSA-N 0.000 description 1
- 239000010630 cinnamon oil Substances 0.000 description 1
- NPFVOOAXDOBMCE-PLNGDYQASA-N cis-3-Hexenyl acetate Natural products CC\C=C/CCOC(C)=O NPFVOOAXDOBMCE-PLNGDYQASA-N 0.000 description 1
- RRGOKSYVAZDNKR-ARJAWSKDSA-M cis-3-hexenylacetate Chemical compound CC\C=C/CCCC([O-])=O RRGOKSYVAZDNKR-ARJAWSKDSA-M 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- WTOYNNBCKUYIKC-UHFFFAOYSA-N dl-nootkatone Natural products C1CC(C(C)=C)CC2(C)C(C)CC(=O)C=C21 WTOYNNBCKUYIKC-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 235000001050 hortel pimenta Nutrition 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940043353 maltol Drugs 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000008164 mustard oil Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229960000948 quinine Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229930004725 sesquiterpene Natural products 0.000 description 1
- 150000004354 sesquiterpene derivatives Chemical class 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- PQDRXUSSKFWCFA-CFNZNRNTSA-N solanone Chemical compound CC(=O)CC[C@@H](C(C)C)\C=C\C(C)=C PQDRXUSSKFWCFA-CFNZNRNTSA-N 0.000 description 1
- PQDRXUSSKFWCFA-UHFFFAOYSA-N solanone Natural products CC(=O)CCC(C(C)C)C=CC(C)=C PQDRXUSSKFWCFA-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- NPFVOOAXDOBMCE-UHFFFAOYSA-N trans-3-hexenyl acetate Natural products CCC=CCCOC(C)=O NPFVOOAXDOBMCE-UHFFFAOYSA-N 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 239000008371 vanilla flavor Substances 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 239000009637 wintergreen oil Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- -1 zeolites Chemical compound 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
- A24B15/282—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by indirect addition of the chemical substances, e.g. in the wrapper, in the case
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
- A24B15/283—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
- A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
- A24C5/56—Making tipping materials, e.g. sheet cork for mouthpieces of cigars or cigarettes, by mechanical means
- A24C5/565—Making tipping materials, e.g. sheet cork for mouthpieces of cigars or cigarettes, by mechanical means by treating the tipping material with a liquid or viscous solution, e.g. paraffine
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/002—Cigars; Cigarettes with additives, e.g. for flavouring
Definitions
- Flavorants are frequently added to tobacco products, including smoking articles or smokeless, oral tobacco products, to achieve desirable organoleptic sensations. Typically, the flavors are added to the tobacco material or filter component.
- Document WO2007/036814 for example discloses a cigarette withe filtering system having encapsulated flavorants.
- smoking articles include a controlled flavor release product that provides prolonged and varied organoleptic sensation.
- a controlled flavor release product including at least a first time-release flavorant and a second time-release flavorant. Additional time-release flavorants may also be included.
- the first time-release flavorant and the second time-release flavorant contain different flavorants, but they may contain the same flavorants.
- the first time-release flavorant and the second time-release flavorant contain the same flavorant.
- the first time-release flavorant and the second time-release flavorant are released at different times during smoking to provide continuous enjoyment and a variety of flavors.
- the time release of the second time-released flavorant overlaps release of the first time-released flavorant.
- the first time-release flavorant and the second time-release flavorant are incorporated into controlled release microcapsules.
- the microcapsules may be embedded in a format to create a controlled flavor release product.
- Each microcapsule can contain the first time-release flavorant, the second time-release flavorant or both.
- the microcapsules form the controlled flavor release product that can be used in a smoking article.
- the controlled flavor release product includes at least a first time-release flavorant and a second time-release flavorant.
- Suitable microcapsules for controlled release of flavorants are those developed by Salvona LLC of Dayton, New Jersey. ( e.g . MultiSalTM and NanoSalTM).
- MultiSalTM is a free flowing powder matrix with high concentrations of functional ingredients encapsulated in nanospheres.
- NanoSalTM is a liquid formula encapsulated in solid, hydrophobic nanospheres.
- Each microcapsule can incorporate different oil based flavors for controlled delivery over time.
- the microcapsules provide enhanced bioadhesive properties such that the flavorants bind to mucous in the mouth cavity to prolong flavor enjoyment.
- the microcapsules may also be designed to target specific areas of the mouth.
- the controlled flavor release product has controlled diffusion mechanisms.
- the first time-release flavorant and the second time-release flavorant may be released by the same or different mechanisms. Additional time-release flavorants may be used, and may be triggered by different methods at different times.
- the first time-release flavorant and the second time-release flavorant are released by exposure to moisture from the lips or mouth.
- heat from igniting the smoking article or from the user's mouth may cause the release of the first time-release flavorant and the second time-release flavorant.
- the first time-release flavorant and the second time-release flavorant are released by a change in pH. The change in pH may occur when the controlled flavor release product is placed in an environment such as a human's mouth. Alternatively, a substance may be added to a microcapsule that changes the pH and causes the release of another microcapsule.
- the first time-release flavorant and the second time-release flavorant are embedded in a format to create a controlled flavor release product.
- the controlled flavor release product is in the form of a lip balm type formulation.
- the lip balm type formulation may be made of a wax with the first time-release flavorant and the second time-release flavorant embedded therein.
- the controlled flavor release product is in the form of a film having a first time-release flavorant and a second time-release flavorant embedded therein.
- the films can be formed by conventional means known in the art, and may be dissolvable and/or disintegrable.
- the film is adhered to the downstream end of the smoking article.
- the first time-release flavorant may include a different flavorant than the second time-release flavorant so that the user is provided with at least two flavors during the smoking experience. Also, since the first time-release flavorant and the second time-release flavorant are released at separate times, the organoleptic sensations are prolonged thereby providing the user with more flavor over a longer period of time.
- Suitable flavorants for use in the controlled flavor release product include, without limitation, mint, such as peppermint and spearmint, vanillin, chocolate, licorice, citrus and other fruit flavors, spice flavors, such as cinnamon, methyl salicylate, linalool, bergamot oil, geranium oil, lemon oil, ginger oil, tobacco flavors and other agents commonly used to impart flavor and aroma to tobacco products.
- suitable flavors and aromas may include flavor compounds selected from the group consisting of an acid, an alcohol, an ester, an aldehyde, a ketone, a pyrazine, combinations or blends thereof and the like.
- Suitable flavor compounds may be selected, for example, from the group consisting of phenylacetic acid, solanone, megastigmatrienone, 2-heptanone, benzylalcohol, cis-3-hexenyl acetate, valeric acid, valeric aldehyde, ester, terpene, sesquiterpene, nootkatone, maltol, combinations thereof and the like.
- the first and second flavorants may contain a cooling agent.
- chemesthesis agents may also be included in the controlled release flavor product.
- Suitable chemesthesis agents include, without limitation, capsaicin, tannins, mustard oil, wintergreen oil, cinnamon oil, allicin, quinine, citric acid, and salt.
- complimentary flavors may be chosen for the first time-release flavorant and the second time release flavorant to provide a combined flavor.
- a cherry vanilla flavor may be provided by choosing a cherry flavorant for the first time-release flavorant and a vanilla flavorant for the second time-release flavorant.
- the release of the first time-release flavorant and the second time-release flavorant can overlap so that the complimentary flavorants can be enjoyed together.
- smoking article includes cigarettes, pipes, cigars, and cigarillos.
- Non-traditional cigarettes such as cigarettes using electrical smoking systems are also included in the definition of smoking articles or cigarettes generally.
- a traditional cigarette typically contains two sections, a tobacco-containing portion sometimes referred to as the tobacco rod, and a filter portion which may be referred to as a filtration zone.
- Tipping paper typically surrounds the filter, which forms the mouth end of the cigarette. The tipping paper overlaps with the tobacco rod in order to hold the filter and tobacco rod together.
- the tobacco rod includes a paper wrapper in which the tobacco is wrapped and an adhesive holding the seams of the paper wrapper together.
- the tobacco rod has a first end which is integrally attached to the filter and a second end which is lit or heated for smoking the tobacco. When the tobacco rod is lit or heated for smoking, the smoke travels from the lit end downstream to the filter end of the tobacco rod and further downstream through the filter.
- upstream and downstream relative positions between filter segments and other features are described in relation to the direction of mainstream smoke as it is drawn from a tobacco rod and through a multi-component filter during a puff.
- the smoking article is a cigarette.
- the cigarette may contain tobacco material, a filter, and a controlled flavor release product.
- the cigarette may also contain at least one sorbent.
- sorbent refers to an adsorbent, an absorbent, or a substance that can function as both an adsorbent and an absorbent.
- Preferred sorbents include various forms of activated carbon, molecular sieves, such as zeolites, and mixtures thereof.
- suitable types of tobacco materials include, but are not limited to, flue-cured tobacco, Burley tobacco, Maryland tobacco, Oriental tobacco, rare tobacco, specialty tobacco, blends thereof and the like.
- the tobacco material may be provided in any suitable form, including, but not limited to, tobacco lamina, processed tobacco materials, such as volume expanded or puffed tobacco, processed tobacco stems, such as cut-rolled or cut-puffed stems, reconstituted tobacco materials, blends thereof, and the like. Tobacco substitutes may also be used.
- the tobacco material can include at least one humectant, such as glycerin, at least one sweetener or at least one non-tobacco flavorant, or combinations thereof, dispersed throughout the tobacco material.
- at least one humectant such as glycerin, at least one sweetener or at least one non-tobacco flavorant, or combinations thereof, dispersed throughout the tobacco material.
- a smoking article 10 has an upstream end 12 and a downstream end 14.
- the smoking article 10 includes a filtration zone 40 that lies at the downstream end 14.
- the filtration zone 40 includes a filter 42 surrounded by a portion of tipping paper 18.
- the filtration zone 40 is attached to a tobacco rod 20.
- the filter 42 is made of cellulose acetate fibers.
- the smoking article 10 preferably includes a controlled flavor release product 16.
- the controlled flavor release product 16 includes a first time-release flavorant 24 and a second time-release flavorant 26.
- the controlled flavor release product 16 coats the tipping paper 18 that surrounds the filter 42 at the downstream end 14 of the smoking article 10.
- the controlled flavor release product 16 is in the form of a lip balm type formulation 15.
- the lip balm type formulation 15 may be made of a wax with the first time-release flavorant 24 and the second time-release flavorant 26 embedded therein.
- the controlled flavor release product 16 is in the form of a lip balm type formulation 15 that coats the end 22 of the filter 42 of the smoking article 10.
- the lip balm type formulation 15 is transferred to a user's mouth upon contact with the downstream portion 14.
- the smoking article 10 has an upstream end 12, a downstream end 14, a tobacco rod 20, a filtration zone 40, including a filter 42 covered with tipping paper 18, and a controlled flavor release product 16.
- the controlled flavor release product 16 is in the form of a film 30.
- the film 30 is formed by conventional means known in the art.
- the film 30 is dissolvable or disintegrable.
- a first time-release flavorant 24 and a second time-release flavorant 26 are embedded in the film 30.
- the film 30 is wrapped around the tipping paper 18 and adhered thereto.
- the smoking article 10 has an upstream end 12, a downstream end 14, a tobacco rod 20, a filtration zone 40 including a filter 42 covered with tipping paper 18, and a controlled flavor release product 16.
- the controlled flavor release product 16 is in the form of a film 30 that is affixed to the end 22 of the filter 42.
- the film 30 is adhered to the tipping paper 18 or the end 22 of the filter 42 by any known adhesive.
- the film 30 may be glued onto the tipping paper 18.
- the smoking article 10 does not include a filtration zone.
- the smoking article 10 may be a cigar without a filtration zone or a filterless cigarette.
- the controlled flavor release product 16 may coat the downstream end 14 of the wrapper 100 or the end 200 of the smoking article 10.
- the controlled flavor release product 16 may be a film that is wrapped around the downstream end 14 of the smoking article 10.
- the method for manufacturing includes contacting a wrapper with a controlled flavor release product, surrounding tobacco with the wrapper, and sealing the wrapper to form a smoking article.
- the method may also include sealing a filter to the rod and then cutting the rod to a specified length.
- the method for manufacturing a smoking article having a controlled flavor release product includes coating a tipping paper with the controlled flavor release product and wrapping a filter with the tipping paper.
- the coating may take place by dipping or brushing on the controlled flavor release product.
- the method may also include the step of fitting the filter to a tobacco rod to form a cigarette.
- the method includes coating the end of a filter with a lip balm type formulation having an embedded first time-release flavorant and a second time-release flavorant.
- the filter may be made by conventional methods known in the art and attached to a tobacco rod to form a cigarette.
- the end of the filter is then coated by dipping, spraying, or otherwise applying the lip balm type formulation to the end of the cigarette.
- the method includes adhering a film having an embedded first time-release flavorant and a second time-release flavorant to the end of a filter of a smoking article.
- the film is cut to an appropriate size and adhered to the end of the filter.
- the method includes adhering a film having an embedded first time-release flavorant and a second time-release flavorant to the tipping paper of a smoking article.
- the film is formed or cut to about the size of the tipping paper and adhered thereto.
- the method includes adhering a film having an embedded first time-release flavorant and a second time-release flavorant to the wrapper of a smoking article.
Landscapes
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Manufacture Of Tobacco Products (AREA)
- Fats And Perfumes (AREA)
Description
- Flavorants are frequently added to tobacco products, including smoking articles or smokeless, oral tobacco products, to achieve desirable organoleptic sensations. Typically, the flavors are added to the tobacco material or filter component. Document
WO2007/036814 for example discloses a cigarette withe filtering system having encapsulated flavorants. - As described herein, smoking articles include a controlled flavor release product that provides prolonged and varied organoleptic sensation.
- Provided is a controlled flavor release product including at least a first time-release flavorant and a second time-release flavorant. Additional time-release flavorants may also be included.
- Preferably, the first time-release flavorant and the second time-release flavorant contain different flavorants, but they may contain the same flavorants. In an embodiment, the first time-release flavorant and the second time-release flavorant contain the same flavorant. According to the invention, the first time-release flavorant and the second time-release flavorant are released at different times during smoking to provide continuous enjoyment and a variety of flavors. Also preferably, the time release of the second time-released flavorant overlaps release of the first time-released flavorant.
- In a preferred embodiment, the first time-release flavorant and the second time-release flavorant are incorporated into controlled release microcapsules. The microcapsules may be embedded in a format to create a controlled flavor release product. Each microcapsule can contain the first time-release flavorant, the second time-release flavorant or both.
- In another embodiment, the microcapsules form the controlled flavor release product that can be used in a smoking article. Preferably, the controlled flavor release product includes at least a first time-release flavorant and a second time-release flavorant.
- Suitable microcapsules for controlled release of flavorants are those developed by Salvona LLC of Dayton, New Jersey. (e.g. MultiSal™ and NanoSal™).
- MultiSal™ is a free flowing powder matrix with high concentrations of functional ingredients encapsulated in nanospheres. NanoSal™ is a liquid formula encapsulated in solid, hydrophobic nanospheres. Each microcapsule can incorporate different oil based flavors for controlled delivery over time. The microcapsules provide enhanced bioadhesive properties such that the flavorants bind to mucous in the mouth cavity to prolong flavor enjoyment. The microcapsules may also be designed to target specific areas of the mouth.
- In a preferred embodiment, the controlled flavor release product has controlled diffusion mechanisms. The first time-release flavorant and the second time-release flavorant may be released by the same or different mechanisms. Additional time-release flavorants may be used, and may be triggered by different methods at different times.
- In one embodiment, the first time-release flavorant and the second time-release flavorant are released by exposure to moisture from the lips or mouth. In another embodiment, heat from igniting the smoking article or from the user's mouth may cause the release of the first time-release flavorant and the second time-release flavorant. In yet another embodiment, the first time-release flavorant and the second time-release flavorant are released by a change in pH. The change in pH may occur when the controlled flavor release product is placed in an environment such as a human's mouth. Alternatively, a substance may be added to a microcapsule that changes the pH and causes the release of another microcapsule.
- Preferably, the first time-release flavorant and the second time-release flavorant are embedded in a format to create a controlled flavor release product. In a preferred embodiment, the controlled flavor release product is in the form of a lip balm type formulation. The lip balm type formulation may be made of a wax with the first time-release flavorant and the second time-release flavorant embedded therein. In another embodiment, the controlled flavor release product is in the form of a film having a first time-release flavorant and a second time-release flavorant embedded therein. The films can be formed by conventional means known in the art, and may be dissolvable and/or disintegrable. Preferably the film is adhered to the downstream end of the smoking article.
- In an embodiment, the first time-release flavorant may include a different flavorant than the second time-release flavorant so that the user is provided with at least two flavors during the smoking experience. Also, since the first time-release flavorant and the second time-release flavorant are released at separate times, the organoleptic sensations are prolonged thereby providing the user with more flavor over a longer period of time.
- Suitable flavorants for use in the controlled flavor release product include, without limitation, mint, such as peppermint and spearmint, vanillin, chocolate, licorice, citrus and other fruit flavors, spice flavors, such as cinnamon, methyl salicylate, linalool, bergamot oil, geranium oil, lemon oil, ginger oil, tobacco flavors and other agents commonly used to impart flavor and aroma to tobacco products.
- Other suitable flavors and aromas may include flavor compounds selected from the group consisting of an acid, an alcohol, an ester, an aldehyde, a ketone, a pyrazine, combinations or blends thereof and the like. Suitable flavor compounds may be selected, for example, from the group consisting of phenylacetic acid, solanone, megastigmatrienone, 2-heptanone, benzylalcohol, cis-3-hexenyl acetate, valeric acid, valeric aldehyde, ester, terpene, sesquiterpene, nootkatone, maltol, combinations thereof and the like. The first and second flavorants may contain a cooling agent.
- Additives such as chemesthesis agents may also be included in the controlled release flavor product. Suitable chemesthesis agents include, without limitation, capsaicin, tannins, mustard oil, wintergreen oil, cinnamon oil, allicin, quinine, citric acid, and salt.
- In one embodiment, complimentary flavors may be chosen for the first time-release flavorant and the second time release flavorant to provide a combined flavor. For instance, a cherry vanilla flavor may be provided by choosing a cherry flavorant for the first time-release flavorant and a vanilla flavorant for the second time-release flavorant. In an embodiment, the release of the first time-release flavorant and the second time-release flavorant can overlap so that the complimentary flavorants can be enjoyed together.
- The term "smoking article" includes cigarettes, pipes, cigars, and cigarillos. Non-traditional cigarettes such as cigarettes using electrical smoking systems are also included in the definition of smoking articles or cigarettes generally.
- A traditional cigarette typically contains two sections, a tobacco-containing portion sometimes referred to as the tobacco rod, and a filter portion which may be referred to as a filtration zone. Tipping paper typically surrounds the filter, which forms the mouth end of the cigarette. The tipping paper overlaps with the tobacco rod in order to hold the filter and tobacco rod together. The tobacco rod includes a paper wrapper in which the tobacco is wrapped and an adhesive holding the seams of the paper wrapper together. The tobacco rod has a first end which is integrally attached to the filter and a second end which is lit or heated for smoking the tobacco. When the tobacco rod is lit or heated for smoking, the smoke travels from the lit end downstream to the filter end of the tobacco rod and further downstream through the filter.
- The "upstream" and "downstream" relative positions between filter segments and other features are described in relation to the direction of mainstream smoke as it is drawn from a tobacco rod and through a multi-component filter during a puff.
- In a preferred embodiment, the smoking article is a cigarette. The cigarette may contain tobacco material, a filter, and a controlled flavor release product. In an embodiment, the cigarette may also contain at least one sorbent.
- The term "sorbent" as used herein refers to an adsorbent, an absorbent, or a substance that can function as both an adsorbent and an absorbent. Preferred sorbents include various forms of activated carbon, molecular sieves, such as zeolites, and mixtures thereof.
- Examples of suitable types of tobacco materials that may be used include, but are not limited to, flue-cured tobacco, Burley tobacco, Maryland tobacco, Oriental tobacco, rare tobacco, specialty tobacco, blends thereof and the like. The tobacco material may be provided in any suitable form, including, but not limited to, tobacco lamina, processed tobacco materials, such as volume expanded or puffed tobacco, processed tobacco stems, such as cut-rolled or cut-puffed stems, reconstituted tobacco materials, blends thereof, and the like. Tobacco substitutes may also be used.
- In an embodiment, the tobacco material can include at least one humectant, such as glycerin, at least one sweetener or at least one non-tobacco flavorant, or combinations thereof, dispersed throughout the tobacco material.
-
-
Figure 1 is an illustration of a smoking article including a controlled flavor release product in the form of a lip balm type formulation coating the tipping paper. -
Figure 2 is an illustration of a smoking article including a controlled flavor release product in the form of a lip balm type formulation coating the end of the smoking article. -
Figure 3 is an illustration of a smoking article including a controlled flavor release product in the form of a film coating the tipping paper. -
Figure 4 is an illustration of a smoking article including a controlled flavor release product in the form of a film coating the end of the smoking article. -
Figure 5 is an illustration of a filterless smoking article including a controlled flavor release product. - - As illustrated in
Figure 1 , asmoking article 10 has anupstream end 12 and adownstream end 14. Thesmoking article 10 includes afiltration zone 40 that lies at thedownstream end 14. Thefiltration zone 40 includes afilter 42 surrounded by a portion of tippingpaper 18. Thefiltration zone 40 is attached to atobacco rod 20. In one embodiment, thefilter 42 is made of cellulose acetate fibers. Thesmoking article 10 preferably includes a controlledflavor release product 16. In one embodiment, the controlledflavor release product 16 includes a first time-release flavorant 24 and a second time-release flavorant 26. - Preferably, the controlled
flavor release product 16 coats the tippingpaper 18 that surrounds thefilter 42 at thedownstream end 14 of thesmoking article 10. Also preferably, the controlledflavor release product 16 is in the form of a lipbalm type formulation 15. The lipbalm type formulation 15 may be made of a wax with the first time-release flavorant 24 and the second time-release flavorant 26 embedded therein. - In another embodiment, as seen in
Figure 2 , the controlledflavor release product 16 is in the form of a lipbalm type formulation 15 that coats theend 22 of thefilter 42 of thesmoking article 10. The lipbalm type formulation 15 is transferred to a user's mouth upon contact with thedownstream portion 14. - In one embodiment, as illustrated in
Figure 3 , thesmoking article 10 has anupstream end 12, adownstream end 14, atobacco rod 20, afiltration zone 40, including afilter 42 covered with tippingpaper 18, and a controlledflavor release product 16. - Preferably, the controlled
flavor release product 16 is in the form of afilm 30. Thefilm 30 is formed by conventional means known in the art. In a preferred embodiment, thefilm 30 is dissolvable or disintegrable. Preferably, a first time-release flavorant 24 and a second time-release flavorant 26 are embedded in thefilm 30. Thefilm 30 is wrapped around the tippingpaper 18 and adhered thereto. - In another embodiment, as shown in
Figure 4 , thesmoking article 10 has anupstream end 12, adownstream end 14, atobacco rod 20, afiltration zone 40 including afilter 42 covered with tippingpaper 18, and a controlledflavor release product 16. Preferably, the controlledflavor release product 16 is in the form of afilm 30 that is affixed to theend 22 of thefilter 42. - In a preferred embodiment; the
film 30 is adhered to the tippingpaper 18 or theend 22 of thefilter 42 by any known adhesive. For instance, thefilm 30 may be glued onto the tippingpaper 18. - In one embodiment, the
smoking article 10 does not include a filtration zone. As seen inFigure 5 , thesmoking article 10 may be a cigar without a filtration zone or a filterless cigarette. The controlledflavor release product 16 may coat thedownstream end 14 of thewrapper 100 or theend 200 of thesmoking article 10. In an embodiment, the controlledflavor release product 16 may be a film that is wrapped around thedownstream end 14 of thesmoking article 10. - Also provided is a method for manufacturing a smoking article including a controlled flavor release product.
- In a preferred embodiment, the method for manufacturing includes contacting a wrapper with a controlled flavor release product, surrounding tobacco with the wrapper, and sealing the wrapper to form a smoking article. The method may also include sealing a filter to the rod and then cutting the rod to a specified length.
- In another embodiment, the method for manufacturing a smoking article having a controlled flavor release product includes coating a tipping paper with the controlled flavor release product and wrapping a filter with the tipping paper. The coating may take place by dipping or brushing on the controlled flavor release product. The method may also include the step of fitting the filter to a tobacco rod to form a cigarette.
- In yet another embodiment, the method includes coating the end of a filter with a lip balm type formulation having an embedded first time-release flavorant and a second time-release flavorant. The filter may be made by conventional methods known in the art and attached to a tobacco rod to form a cigarette. The end of the filter is then coated by dipping, spraying, or otherwise applying the lip balm type formulation to the end of the cigarette.
- In a preferred embodiment, the method includes adhering a film having an embedded first time-release flavorant and a second time-release flavorant to the end of a filter of a smoking article. The film is cut to an appropriate size and adhered to the end of the filter.
- In another embodiment, the method includes adhering a film having an embedded first time-release flavorant and a second time-release flavorant to the tipping paper of a smoking article. The film is formed or cut to about the size of the tipping paper and adhered thereto.
- In another embodiment, the method includes adhering a film having an embedded first time-release flavorant and a second time-release flavorant to the wrapper of a smoking article.
- Variations and modifications of the foregoing will be apparent to those skilled in the art. Such variations and modifications are to be considered within the purview and scope of the claims appended hereto.
Claims (13)
- A controlled flavor release smoking article (10) comprising:a tobacco rod (20);a downstream end (14); anda controlled flavor release product (16) including:wherein the controlled flavor release product (16) contacts the downstream end (14) of said smoking article (10).a first time-released flavorant (24) delivered at a first time and triggered by a first mechanism; anda second time-released flavorant (26) delivered at a second time and triggered by a second mechanism, wherein the second time is different to the first time,
- The controlled flavor release smoking article of Claim 1, wherein said first time-release flavorant (24), and said second time-release flavorant (26) are released by a first mechanism and a second mechanism selected from the group consisting of the addition of moisture, a change of pH. a temperature increase, and combinations thereof.
- The controlled flavor release smoking article of Claim 1, wherein said first time-release flavorant and said second time-release flavorant are incorporated into at least one microcapsule.
- The controlled flavor release smoking article of Claim 1, wherein said controlled flavor release product (16) is a film (30).
- The controlled flavor release smoking article of Claim 4, wherein said film (30) is dissolvable, disintegrable or both.
- The controlled flavor release smoking article of Claim 1, wherein said controlled flavor release product (16) is a lip balm type formulation (15).
- The controlled flavor release smoking article of Claim 1. wherein, said controlled flavor release product is applied to an outside surface of said downstream end (14) of said smoking article (10).
- The controlled flavor release smoking article of Claim 1, wherein said first time-release flavorant (24) and said second time-release flavorant (26) are selected from the group consisting of menthol, mint, chocolate, licorice, fruit flavors, tangerine, citrus, cherry, gamma octalactone, vanilla, ethyl vanillin, breath freshener flavors, spice flavors, cinnamon, methyl salicylate, linalool, bergamot oil, geranium oil, lemon oil, ginger oil, tobacco flavors, smoothing or refreshing active compounds, bitter agents, and combinations thereof.
- The controlled flavor release smoking article of Claim 1, wherein said first time-released ftavorant (24) and said second time-released flavorant (26) each include the same flavorant.
- The controlled flavor release smoking article of Claim 1, wherein said first time-released flavorant (24) and said second time-released flavorant (26) each include different flavorants.
- The controlled flavor release smoking article of Claim 1, wherein said first time-released flavorant (24) and said second time-released flavorant (26) include a chemesthesis agent.
- A method of making a controlled flavor release smoking article (10) according to claim 1, said method comprising contacting a downstream end (14) of a smoking article (10) with a controlled flavor release product (16), wherein said controlled flavor release product (16) contains a first time-release flavorant (24) and a second time-release flavorant (26).
- The method of Claim 12, wherein said first time-release flavorant (24) includes different flavorant or flavorants to said second time-release flavorant (26).
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SI200831013T SI2162023T1 (en) | 2007-06-08 | 2008-06-06 | Smoking article with controlled flavor release |
PL08807184T PL2162023T3 (en) | 2007-06-08 | 2008-06-06 | Smoking article with controlled flavor release |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US92901007P | 2007-06-08 | 2007-06-08 | |
PCT/IB2008/002544 WO2008152526A2 (en) | 2007-06-08 | 2008-06-06 | Smoking article with controlled flavor release |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2162023A2 EP2162023A2 (en) | 2010-03-17 |
EP2162023B1 true EP2162023B1 (en) | 2013-07-31 |
Family
ID=40094724
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08807184.0A Active EP2162023B1 (en) | 2007-06-08 | 2008-06-06 | Smoking article with controlled flavor release |
Country Status (20)
Country | Link |
---|---|
US (1) | US20080302376A1 (en) |
EP (1) | EP2162023B1 (en) |
JP (1) | JP5415409B2 (en) |
KR (1) | KR101533123B1 (en) |
CN (1) | CN101808541A (en) |
AU (1) | AU2008263505B2 (en) |
BR (1) | BRPI0812921B1 (en) |
CO (1) | CO6270191A2 (en) |
DK (1) | DK2162023T3 (en) |
EA (1) | EA018725B1 (en) |
ES (1) | ES2432409T3 (en) |
MX (1) | MX2009012970A (en) |
MY (1) | MY180445A (en) |
NZ (1) | NZ580976A (en) |
PL (1) | PL2162023T3 (en) |
PT (1) | PT2162023E (en) |
RS (1) | RS52952B (en) |
SI (1) | SI2162023T1 (en) |
UA (1) | UA97986C2 (en) |
WO (1) | WO2008152526A2 (en) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ZA200901679B (en) | 2009-03-09 | 2015-08-26 | Tobacco Res And Development Institute (Pty) Ltd | Apparatus for introducing objects into filter rod material |
EP2429321A4 (en) | 2009-05-11 | 2013-03-06 | Us Smokeless Tobacco Co | Method and device for flavoring smokeless tobacco |
AT508818B1 (en) * | 2009-09-30 | 2011-10-15 | Tannpapier Gmbh | MOUTHPIECE OR FILTER CASE OF A CIGARETTE |
US8361236B2 (en) * | 2009-10-09 | 2013-01-29 | Philip Morris Usa Inc. | Supramolecular complex flavor immobilizing for controlled release of flavor in smoking articles |
US10051884B2 (en) | 2010-03-26 | 2018-08-21 | Philip Morris Usa Inc. | Controlled release mentholated tobacco beads |
ZA201008663B (en) | 2010-12-01 | 2014-08-27 | Tobacco Res And Dev Inst (Pty) Ltd | Feed mechanism |
GB2490739A (en) * | 2011-05-13 | 2012-11-14 | British American Tobacco Co | Additive release component for use with a smoking article |
CN102423129A (en) * | 2011-08-26 | 2012-04-25 | 湖北中烟工业有限责任公司 | Method for preparing hollow fiber cigarette filter tip |
GB2495925A (en) * | 2011-10-25 | 2013-05-01 | British American Tobacco Co | Flavoured liquid for application to a smoking article |
US9282772B2 (en) * | 2012-01-31 | 2016-03-15 | Altria Client Services Llc | Electronic vaping device |
LT2879528T (en) | 2012-08-06 | 2018-06-11 | Philip Morris Products S.A. | Method of forming smoking articles with mouth end cavities |
CN103054180B (en) * | 2012-12-27 | 2014-10-22 | 广东中烟工业有限责任公司 | Aromatized composite particle filter stick and production method thereof |
CN103478902B (en) * | 2013-09-13 | 2016-08-24 | 湖南中烟工业有限责任公司 | A kind of composite cigarette filter stick and preparation method thereof |
CN103666764B (en) * | 2013-12-30 | 2016-01-20 | 湖南中烟工业有限责任公司 | A kind of cold taste essence for peppermint type cigarette composition |
RU2670522C2 (en) | 2014-02-26 | 2018-10-23 | Филип Моррис Продактс С.А. | Smoking article with tactile liquid release component |
KR102367689B1 (en) * | 2014-02-26 | 2022-02-25 | 필립모리스 프로덕츠 에스.에이. | Smoking article with liquid release component having frangible shell |
KR101659652B1 (en) * | 2014-06-11 | 2016-09-23 | 주식회사 케이티앤지 | Flavor controlling cigarette |
US20160044955A1 (en) * | 2014-08-13 | 2016-02-18 | R.J. Reynolds Tobacco Company | Smokeless tobacco products |
CN104382233A (en) * | 2014-11-12 | 2015-03-04 | 广西中烟工业有限责任公司 | Filter stick containing natural herbaceous plant fruit grains and application of filter stick |
JP6736579B2 (en) | 2015-04-30 | 2020-08-05 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Aerosol-generating article with a high suction-resistant detachable freshener delivery element |
TWI693031B (en) * | 2015-04-30 | 2020-05-11 | 瑞士商菲利浦莫里斯製品股份有限公司 | Aerosol-generating article comprising a detachable freshener delivery element with high degree of ventilation |
TW201700019A (en) * | 2015-06-30 | 2017-01-01 | 菲利浦莫里斯製品股份有限公司 | Smoking article with improved extinguishment |
CN105505580B (en) * | 2015-12-14 | 2019-07-30 | 长江大学 | A kind of microcapsules and preparation method thereof |
ITUA20162010A1 (en) * | 2016-03-24 | 2017-09-24 | Gd Spa | Smoking item and method for its realization. |
HUE063356T2 (en) | 2016-05-13 | 2024-01-28 | Nicoventures Trading Ltd | Apparatus arranged to heat smokable material and method of forming a heater |
CN106190562A (en) * | 2016-08-11 | 2016-12-07 | 无锡华海香料有限公司 | A kind of preparation method of tobacco aromatics using |
GB201618365D0 (en) * | 2016-10-31 | 2016-12-14 | British American Tobacco Investments Ltd | Tobacco industry product |
CN107418730B (en) * | 2017-04-27 | 2021-01-08 | 河南中烟工业有限责任公司 | Kumquat flavor essence for bead blasting of cigarettes and application of kumquat flavor essence in cigarettes |
CN107418729A (en) * | 2017-04-27 | 2017-12-01 | 河南中烟工业有限责任公司 | A kind of cigarette quick-fried pearl tendril-leaved fritillary bulb essence and its application in cigarette |
CN107259637A (en) * | 2017-07-28 | 2017-10-20 | 四川三联新材料有限公司 | A kind of multi-flavor smoking article and its manufacture method |
GB201808526D0 (en) * | 2018-05-24 | 2018-07-11 | Nicoventures Trading Ltd | Aerosol Generation |
CN110373265A (en) * | 2019-06-27 | 2019-10-25 | 广东中烟工业有限责任公司 | A kind of sustained release fragrance and its application in Chinese style taste tobacco product |
WO2022013222A1 (en) * | 2020-07-14 | 2022-01-20 | Jt International Sa | Stick equity – use of beeswax for tobacco products |
JP1714443S (en) | 2020-10-30 | 2022-05-10 | Smoking aerosol generator | |
JP1714442S (en) | 2020-10-30 | 2022-05-10 | Smoking aerosol generator | |
JP1715888S (en) | 2020-10-30 | 2022-05-25 | Smoking aerosol generator | |
JP1714440S (en) | 2020-10-30 | 2022-05-10 | Smoking aerosol generator | |
USD990765S1 (en) | 2020-10-30 | 2023-06-27 | Nicoventures Trading Limited | Aerosol generator |
JP1714441S (en) | 2020-10-30 | 2022-05-10 | Smoking aerosol generator | |
USD989384S1 (en) | 2021-04-30 | 2023-06-13 | Nicoventures Trading Limited | Aerosol generator |
Family Cites Families (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1507925A (en) * | 1923-01-10 | 1924-09-09 | Jr Henry Hall Marshall | Cigarette |
US2886440A (en) * | 1956-07-03 | 1959-05-12 | Gen Foods Corp | Chewing gum and method of producing |
US2886446A (en) * | 1958-12-08 | 1959-05-12 | Gen Foods Corp | Process for making chewing gum and product |
US2886445A (en) * | 1958-12-08 | 1959-05-12 | Gen Foods Corp | Process for making chewing gum and product |
US2886449A (en) * | 1959-03-10 | 1959-05-12 | Gen Foods Corp | Method of making chewing gum and the resulting product |
US3339558A (en) * | 1966-10-28 | 1967-09-05 | Haskett Barry F | Smoking article and filter therefor containing vitamin a |
US4253473A (en) * | 1979-07-13 | 1981-03-03 | International Flavors & Fragrances Inc. | Process for augmenting or enhancing the aroma or taste of smoking tobacco or a smoking tobacco article by adding thereto a suspended flavoring composition |
US4259355A (en) * | 1979-03-05 | 1981-03-31 | International Flavors & Fragrances Inc. | Chewing gum containing flavor composition and flavor composition therefor |
US4515769A (en) * | 1981-12-01 | 1985-05-07 | Borden, Inc. | Encapsulated flavorant material, method for its preparation, and food and other compositions incorporating same |
US4643205A (en) * | 1984-02-02 | 1987-02-17 | R. J. Reynolds Tobacco Company | Smoking product |
US4717017A (en) * | 1987-03-23 | 1988-01-05 | Philip Morris Incorporated | Package with means for releasing aromatic substance on opening |
US4975270A (en) * | 1987-04-21 | 1990-12-04 | Nabisco Brands, Inc. | Elastomer encased active ingredients |
KR910000142B1 (en) * | 1987-05-29 | 1991-01-21 | 니혼 다바고 상교오 가부시기가이샤 | Filter for cigarette |
US5154927A (en) * | 1989-01-19 | 1992-10-13 | Wm. Wrigley Jr. Company | Gum composition containing dispersed porous beads containing active chewing gum ingredients and method |
US5069231A (en) * | 1989-07-12 | 1991-12-03 | International Flavors & Fragrances Inc. | Method for imparting functional ingredients, functional ingredient-imparting articles and methods for preparation and use thereof |
JPH0396410U (en) * | 1990-01-24 | 1991-10-02 | ||
US5077051A (en) * | 1990-04-10 | 1991-12-31 | Warner-Lambert Company | Sustained release of active agents from bioadhesive microcapsules |
US5417229A (en) * | 1993-07-20 | 1995-05-23 | Summers; John K. | Organoleptic bite composition for human consumption |
US5752529A (en) * | 1996-08-21 | 1998-05-19 | V. Mane Fils S.A. | Tobacco products containing coolant compositions |
JP3096410B2 (en) | 1995-09-19 | 2000-10-10 | 象印マホービン株式会社 | Liquid ejection device |
US8828432B2 (en) * | 1996-10-28 | 2014-09-09 | General Mills, Inc. | Embedding and encapsulation of sensitive components into a matrix to obtain discrete controlled release particles |
US5989535A (en) * | 1997-08-15 | 1999-11-23 | Soma Technologies | Polymeric bioadhesive emulsions and suspensions and methods of treatment |
US6042792A (en) * | 1997-09-18 | 2000-03-28 | International Flavors & Fragrances Inc. | Apparatus for preparing a solid phase microparticulate composition |
US6053175A (en) * | 1998-03-03 | 2000-04-25 | D'angelo; Carmen A. | Method for treating smoking article |
MY138902A (en) * | 2000-04-20 | 2009-08-28 | Philip Morris Prod | "cigarette filters of shaped micro cavity fibers impregnated with flavorant materials" |
US6541030B2 (en) * | 2000-09-27 | 2003-04-01 | Verion Inc. | Instant water dissolvable encapsulate and process |
US6565873B1 (en) * | 2000-10-25 | 2003-05-20 | Salvona Llc | Biodegradable bioadhesive controlled release system of nano-particles for oral care products |
US6887493B2 (en) * | 2000-10-25 | 2005-05-03 | Adi Shefer | Multi component controlled release system for oral care, food products, nutraceutical, and beverages |
US6589562B1 (en) * | 2000-10-25 | 2003-07-08 | Salvona L.L.C. | Multicomponent biodegradable bioadhesive controlled release system for oral care products |
HU230306B1 (en) * | 2001-02-22 | 2015-12-28 | Philip Morris Products Inc | Cigarette and filter with downstream flavor addition |
KR20030009800A (en) * | 2001-07-24 | 2003-02-05 | 김진희 | Taste changeable tobacco |
AU2002340407A1 (en) * | 2001-11-09 | 2003-05-26 | Vector Tobacco Inc. | Method and composition for mentholation of charcoal filtered cigarettes |
US7067152B2 (en) * | 2002-04-17 | 2006-06-27 | Salvona Llc | Multi component moisture triggered controlled release system that imparts long lasting cooling sensation on the target site and/or provides high impact fragrance or flavor burst |
US7115282B2 (en) * | 2002-04-17 | 2006-10-03 | Salvona Ip Llc | Multi component controlled release system for anhydrous cosmetic compositions |
PL203915B1 (en) * | 2002-10-31 | 2009-11-30 | Philip Morris Prod | Electrically heated cigarette including controlled-release flavoring |
US20050172976A1 (en) * | 2002-10-31 | 2005-08-11 | Newman Deborah J. | Electrically heated cigarette including controlled-release flavoring |
JP3096410U (en) * | 2003-03-12 | 2003-09-19 | 彦三 片山 | Aqua filter |
US7856990B2 (en) * | 2003-09-30 | 2010-12-28 | R. J. Reynolds Tobacco Company | Filtered cigarette incorporating an adsorbent material |
AU2004289248B2 (en) * | 2003-11-07 | 2012-05-03 | U.S. Smokeless Tobacco Company Llc | Tobacco compositions |
GB0328644D0 (en) * | 2003-12-11 | 2004-01-14 | Souza Cruz Sa | Smoking article |
WO2005105045A1 (en) * | 2004-04-30 | 2005-11-10 | Astellas Pharma Inc. | Time-limited release type granular pharmaceutical composition for oral administration and intraoral rapid disintegration tablet containing the composition |
US10285431B2 (en) * | 2004-12-30 | 2019-05-14 | Philip Morris Usa Inc. | Encapsulated flavorant designed for thermal release and cigarette bearing the same |
EP1754419A1 (en) * | 2005-08-15 | 2007-02-21 | Philip Morris Products S.A. | Liquid release device for a smoking article |
WO2007036814A2 (en) * | 2005-09-30 | 2007-04-05 | Philip Morris Products S.A. | Flavoured cigarette |
US8157918B2 (en) * | 2005-09-30 | 2012-04-17 | Philip Morris Usa Inc. | Menthol cigarette |
PL1942753T3 (en) * | 2005-11-01 | 2009-10-30 | Philip Morris Products Sa | Smoking article with manually releasable odorant |
EP1891866A1 (en) * | 2006-08-25 | 2008-02-27 | Philip Morris Products S.A. | Smoking article with encapsulated flavourant |
-
2008
- 2008-06-05 US US12/155,548 patent/US20080302376A1/en not_active Abandoned
- 2008-06-06 EA EA200971126A patent/EA018725B1/en not_active IP Right Cessation
- 2008-06-06 SI SI200831013T patent/SI2162023T1/en unknown
- 2008-06-06 DK DK08807184.0T patent/DK2162023T3/en active
- 2008-06-06 RS RS20130399A patent/RS52952B/en unknown
- 2008-06-06 PT PT88071840T patent/PT2162023E/en unknown
- 2008-06-06 AU AU2008263505A patent/AU2008263505B2/en not_active Ceased
- 2008-06-06 MY MYPI20094749A patent/MY180445A/en unknown
- 2008-06-06 KR KR1020097027320A patent/KR101533123B1/en active IP Right Grant
- 2008-06-06 EP EP08807184.0A patent/EP2162023B1/en active Active
- 2008-06-06 UA UAA201000078A patent/UA97986C2/en unknown
- 2008-06-06 MX MX2009012970A patent/MX2009012970A/en active IP Right Grant
- 2008-06-06 WO PCT/IB2008/002544 patent/WO2008152526A2/en active Application Filing
- 2008-06-06 NZ NZ580976A patent/NZ580976A/en not_active IP Right Cessation
- 2008-06-06 JP JP2010510914A patent/JP5415409B2/en active Active
- 2008-06-06 ES ES08807184T patent/ES2432409T3/en active Active
- 2008-06-06 BR BRPI0812921-5A patent/BRPI0812921B1/en active IP Right Grant
- 2008-06-06 CN CN200880019326A patent/CN101808541A/en active Pending
- 2008-06-06 PL PL08807184T patent/PL2162023T3/en unknown
-
2010
- 2010-01-07 CO CO10001473A patent/CO6270191A2/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
CN101808541A (en) | 2010-08-18 |
PT2162023E (en) | 2013-09-17 |
AU2008263505B2 (en) | 2013-03-07 |
JP5415409B2 (en) | 2014-02-12 |
MX2009012970A (en) | 2010-01-14 |
AU2008263505A1 (en) | 2008-12-18 |
KR20100032394A (en) | 2010-03-25 |
EA200971126A1 (en) | 2010-04-30 |
EA018725B1 (en) | 2013-10-30 |
PL2162023T3 (en) | 2014-01-31 |
SI2162023T1 (en) | 2013-10-30 |
EP2162023A2 (en) | 2010-03-17 |
US20080302376A1 (en) | 2008-12-11 |
KR101533123B1 (en) | 2015-07-01 |
WO2008152526A3 (en) | 2009-04-02 |
BRPI0812921B1 (en) | 2017-07-18 |
CO6270191A2 (en) | 2011-04-20 |
MY180445A (en) | 2020-11-28 |
ES2432409T3 (en) | 2013-12-03 |
JP2010528650A (en) | 2010-08-26 |
NZ580976A (en) | 2012-12-21 |
WO2008152526A2 (en) | 2008-12-18 |
DK2162023T3 (en) | 2013-09-30 |
WO2008152526A8 (en) | 2009-06-04 |
RS52952B (en) | 2014-02-28 |
UA97986C2 (en) | 2012-04-10 |
BRPI0812921A2 (en) | 2014-12-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2162023B1 (en) | Smoking article with controlled flavor release | |
US11517041B2 (en) | Application of a flavorant particle in a filter of a smoking article for delivering flavor | |
JP5854560B2 (en) | Coil packaging for smokeless tobacco | |
JP7205029B2 (en) | Smoking articles to which Triple Care cigarette odor reduction technology is applied | |
KR20200030371A (en) | An aerosol generating rod comprising a capsule filter segment consisting of a hard capsule | |
CA3042363A1 (en) | Tobacco industry product | |
CN112543597B (en) | Filter for smoking article adapted to hand odor and halitosis reducing technology and smoking article comprising the same | |
JP7562689B2 (en) | Delivery system and method for making same - Patents.com | |
JPWO2021215490A5 (en) | ||
CN111918563A (en) | Smoking article | |
CN107205468B (en) | Sleeve for smoking articles and corresponding smoking article, kit and container | |
TWI856438B (en) | Filter for a smoking article with reduced cigarette odor by applying additives fragrances to reduce cigarette smell-inducing substances, and a smoking article including the same | |
JP7272554B2 (en) | Filters for smoking articles containing solid flavorants and methods of making same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20091221 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL BA MK RS |
|
RAX | Requested extension states of the european patent have changed |
Extension state: RS Payment date: 20091221 |
|
17Q | First examination report despatched |
Effective date: 20120207 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: KARLES, GEORGIOS, D. Inventor name: ALLEN, JEFF Inventor name: ZHUANG, SHUZHONG Inventor name: JUPE, RICHARD Inventor name: NEPOMUCENO, JOSE |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: RS |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: NV Representative=s name: BOVARD AG, CH Ref country code: AT Ref legal event code: REF Ref document number: 624094 Country of ref document: AT Kind code of ref document: T Effective date: 20130815 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: PT Ref legal event code: SC4A Free format text: AVAILABILITY OF NATIONAL TRANSLATION Effective date: 20130910 |
|
REG | Reference to a national code |
Ref country code: RO Ref legal event code: EPE |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602008026472 Country of ref document: DE Effective date: 20130926 |
|
REG | Reference to a national code |
Ref country code: DK Ref legal event code: T3 Effective date: 20130927 Ref country code: DK Ref legal event code: T3 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: T3 |
|
REG | Reference to a national code |
Ref country code: NO Ref legal event code: T2 Effective date: 20130731 |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
REG | Reference to a national code |
Ref country code: GR Ref legal event code: EP Ref document number: 20130401967 Country of ref document: GR Effective date: 20131015 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 624094 Country of ref document: AT Kind code of ref document: T Effective date: 20130731 |
|
REG | Reference to a national code |
Ref country code: EE Ref legal event code: FG4A Ref document number: E008354 Country of ref document: EE Effective date: 20131031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20131130 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130821 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130731 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130731 |
|
REG | Reference to a national code |
Ref country code: PL Ref legal event code: T3 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130731 |
|
REG | Reference to a national code |
Ref country code: SK Ref legal event code: T3 Ref document number: E 15260 Country of ref document: SK |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130731 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20140502 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602008026472 Country of ref document: DE Effective date: 20140502 |
|
REG | Reference to a national code |
Ref country code: HU Ref legal event code: AG4A Ref document number: E020013 Country of ref document: HU |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130731 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20140606 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130731 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130731 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 9 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 10 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 11 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DK Payment date: 20190621 Year of fee payment: 12 Ref country code: LU Payment date: 20190619 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: EE Payment date: 20190625 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CZ Payment date: 20200529 Year of fee payment: 13 Ref country code: TR Payment date: 20200604 Year of fee payment: 13 Ref country code: GR Payment date: 20200622 Year of fee payment: 13 Ref country code: RO Payment date: 20200528 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20200625 Year of fee payment: 13 Ref country code: PL Payment date: 20200529 Year of fee payment: 13 Ref country code: SE Payment date: 20200625 Year of fee payment: 13 Ref country code: SI Payment date: 20200528 Year of fee payment: 13 Ref country code: SK Payment date: 20200605 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20200824 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: HU Payment date: 20200718 Year of fee payment: 13 |
|
REG | Reference to a national code |
Ref country code: EE Ref legal event code: MM4A Ref document number: E008354 Country of ref document: EE Effective date: 20200630 |
|
REG | Reference to a national code |
Ref country code: DK Ref legal event code: EBP Effective date: 20200630 Ref country code: NO Ref legal event code: MMEP |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201207 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MM4D Effective date: 20200606 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200606 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200606 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NO Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200630 Ref country code: LT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200606 Ref country code: PT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210111 Ref country code: EE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200630 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200630 |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: EUG |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CZ Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210606 Ref country code: RO Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210606 |
|
REG | Reference to a national code |
Ref country code: SK Ref legal event code: MM4A Ref document number: E 15260 Country of ref document: SK Effective date: 20210606 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210607 |
|
REG | Reference to a national code |
Ref country code: SI Ref legal event code: KO00 Effective date: 20220128 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20210630 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210607 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210606 Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210607 Ref country code: GR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20220105 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210630 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20220805 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210607 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210606 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230529 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20230620 Year of fee payment: 16 Ref country code: FR Payment date: 20230627 Year of fee payment: 16 Ref country code: DE Payment date: 20230620 Year of fee payment: 16 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20230621 Year of fee payment: 16 Ref country code: CH Payment date: 20230702 Year of fee payment: 16 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20240620 Year of fee payment: 17 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210606 |