EP2109664B1 - Mittel zur behandlung harter oberflächen - Google Patents
Mittel zur behandlung harter oberflächen Download PDFInfo
- Publication number
- EP2109664B1 EP2109664B1 EP07847714A EP07847714A EP2109664B1 EP 2109664 B1 EP2109664 B1 EP 2109664B1 EP 07847714 A EP07847714 A EP 07847714A EP 07847714 A EP07847714 A EP 07847714A EP 2109664 B1 EP2109664 B1 EP 2109664B1
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- EP
- European Patent Office
- Prior art keywords
- radical
- agent according
- carbon atoms
- water
- integer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229940068041 phytic acid Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001522 polyglycol ester Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000007686 potassium Nutrition 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- 239000004224 potassium gluconate Substances 0.000 description 1
- 235000013926 potassium gluconate Nutrition 0.000 description 1
- 229960003189 potassium gluconate Drugs 0.000 description 1
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 1
- 235000019828 potassium polyphosphate Nutrition 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000002797 proteolythic effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 239000008237 rinsing water Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 230000035040 seed growth Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 125000005372 silanol group Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Inorganic materials [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 235000015393 sodium molybdate Nutrition 0.000 description 1
- 239000011684 sodium molybdate Substances 0.000 description 1
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical class [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229940083982 sodium phytate Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- UGTZMIPZNRIWHX-UHFFFAOYSA-K sodium trimetaphosphate Chemical compound [Na+].[Na+].[Na+].[O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 UGTZMIPZNRIWHX-UHFFFAOYSA-K 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000008223 sterile water Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
- 150000003900 succinic acid esters Chemical class 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000003075 superhydrophobic effect Effects 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 150000005621 tetraalkylammonium salts Chemical class 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- KWXLCDNSEHTOCB-UHFFFAOYSA-J tetrasodium;1,1-diphosphonatoethanol Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P(=O)([O-])C(O)(C)P([O-])([O-])=O KWXLCDNSEHTOCB-UHFFFAOYSA-J 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- AVYKQOAMZCAHRG-UHFFFAOYSA-N triethoxy(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane Chemical compound CCO[Si](OCC)(OCC)CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F AVYKQOAMZCAHRG-UHFFFAOYSA-N 0.000 description 1
- HPEPIADELDNCED-UHFFFAOYSA-N triethoxysilylmethanol Chemical compound CCO[Si](CO)(OCC)OCC HPEPIADELDNCED-UHFFFAOYSA-N 0.000 description 1
- UZIAQVMNAXPCJQ-UHFFFAOYSA-N triethoxysilylmethyl 2-methylprop-2-enoate Chemical compound CCO[Si](OCC)(OCC)COC(=O)C(C)=C UZIAQVMNAXPCJQ-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- PZJJKWKADRNWSW-UHFFFAOYSA-N trimethoxysilicon Chemical group CO[Si](OC)OC PZJJKWKADRNWSW-UHFFFAOYSA-N 0.000 description 1
- FYZXEMANQYHCFX-UHFFFAOYSA-K tripotassium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate Chemical compound [K+].[K+].[K+].OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O FYZXEMANQYHCFX-UHFFFAOYSA-K 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940117565 trisodium dicarboxymethyl alaninate Drugs 0.000 description 1
- 229940048198 trisodium hedta Drugs 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- WHNXAQZPEBNFBC-UHFFFAOYSA-K trisodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O WHNXAQZPEBNFBC-UHFFFAOYSA-K 0.000 description 1
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3738—Alkoxylated silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3742—Nitrogen containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/16—Metals
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/24—Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes
Definitions
- toilet cleaners for better lime solution are often after application for a long time, often several hours or even overnight, left to act on the ceramic.
- the formulations are usually thickened to improve the adhesion to the ceramic. When prolonged exposure then forms on the surface of a film that is usually colored due to the product coloring and after drying is difficult to remove.
- silyl-polyalkoxylate-containing agents are particularly suitable to protect a surface treated therewith from contamination and / or to facilitate the removal of contaminants from the surface.
- silyl polyalkoxylates of the formula (I) as additives in surfactant-containing cleaning agents makes it possible not only to clean one surface in a single work step, but at the same time provides it with protection against dirt. In this way, for example, a calcification, an adhesion of protein or fat-containing dirt and the growth of bacteria is prevented. The treated surfaces stay clean longer and, moreover, the subsequent cleaning is greatly facilitated. This means that you need to clean the surfaces less often without sacrificing cleanliness, and their subsequent cleaning is associated with less effort insofar as it can be done in a time-saving manner and / or requires milder detergents. So it is possible in favorable cases, for a certain time alone with the help of water a sufficient To achieve cleaning effect, ie without the need for the use of a conventional cleaning agent.
- R 1 and R 2 independently of one another are methyl or ethyl, and r is 2 or 3.
- radicals -Si (OR 1 ) r (R 2 ) 3-r are dimethylethoxysilyl, dimethylmethoxysilyl, diisopropylethoxysilyl, methyldimethoxysilyl
- trimethoxysilyl and triethoxysilyl radicals are most preferred.
- agent according to the invention contains a thickener, it is generally present in amounts of from 0.01 to 30% by weight, in particular from 0.2 to 15% by weight.
- Compositions according to the invention may furthermore comprise one or more antimicrobial active ingredients, preferably in an amount of from 0.01 to 1% by weight, in particular from 0.05 to 0.5% by weight, particularly preferably from 0.1 to 0.3 wt .-%.
- antimicrobial agents from the groups of alcohols, aldehydes, antimicrobial acids or their salts, carboxylic acid esters, acid amides, phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, oxygen, nitrogen acetals and formals, benzamidines, isothiazoles and their derivatives such as isothiazolines and isothiazolinones, phthalimide derivatives, pyridine derivatives, antimicrobial surface active compounds, guanidines, antimicrobial amphoteric compounds, quinolines, 1,2-dibromo-2,4-dicyanobutane, iodo-2-propynyl-butylcarbamate
- Preferred antimicrobial agents are preferably selected from the group comprising ethanol, n-propanol, i-propanol, 1,3-butanediol, phenoxyethanol, 1,2-propylene glycol, glycerol, undecylenic acid, citric acid, lactic acid, benzoic acid, salicylic acid, thymol, 2- Benzyl 4-chlorophenol, 2,2'-methylenebis (6-bromo-4-chlorophenol), 2,4,4'-trichloro-2'-hydroxydiphenyl ether, N- (4-chlorophenyl) -N- ( 3,4-dichlorophenyl) urea, N, N '- (1,10-decanediyldi-1-pyridinyl-4-ylidene) bis (1-octan-amine) dihydrochloride, N, N'-bis ( 4-chlorophenyl) -3,12-diimino-2,4,11,
- the agent according to the invention may also contain enzymes, preferably proteases, lipases, amylases, hydrolases and / or cellulases. They may be added to the composition in any form established in the art. In the case of liquid or gel-containing compositions, these include, in particular, solutions of the enzymes, advantageously as concentrated as possible, sparing in water and / or added with stabilizers. Alternatively, the enzymes can be encapsulated, for example by spray drying or extrusion of the enzyme solution together with a, preferably natural, polymer or in the form of capsules, for example those in which the enzymes are entrapped as in a solidified gel or in core-shelled form.
- enzymes preferably proteases, lipases, amylases, hydrolases and / or cellulases.
- stabilizers for example the combination of polyols, boric acid and / or borax, the combination of boric acid or borate, reducing salts and succinic acid or other dicarboxylic acids or the combination of boric acid or borate with polyols or polyamino compounds and with reducing salts.
- the inventive method is used to treat a surface of ceramic, glass, stainless steel or plastic.
- the treatment of a surface with the agents according to the invention makes this surface hydrophilic.
- This facilitates wetting and the removal of dirt and at the same time causes the surface to be easily "dewaxed" by a film of water, thereby avoiding the formation of water droplets and thus the retention of residual soiling.
- This feature is particularly useful where surfaces are particularly prone to lime and dirt and biofilm deposits, such as, typically, toilet bowls, sinks, baths and shower stalls.
- Another benefit of this feature is that water drains from treated surfaces faster, allowing them to dry faster.
- a rinse with pure water is usually required after treating the surface with detergent. It is desirable that the surfaces after this rinse quickly dry again, for example, because a fast-drying surface in a consumer enhances the impression of cleanliness.
- Voranol CP 1421 from DOW Chemicals was dried in vacuo with stirring for 1 h at 80 ° C.
- To 2.04 g (0.41 mmol) of the dried polyether polyol was slowly added 317 mg (1.0 equivalents) of (3-isocyanatopropyl) triethoxysilane.
- the reaction mixture was further stirred under inert gas at 100 ° C for 2 days until the vibration band of the NCO group disappeared upon IR measurement.
- the product was obtained, which in each case has a triethoxylsilyl group at the free ends of the polymer arms of the polyether polyol and represents a mixture of a 3-armed and an 8-armed polyalkoxylate in a ratio of about 20/80, as a colorless viscous liquid.
- Shoe polish dirt was made as follows: A mixture of black shoe polish (6.5% by weight), Mazola oil (3.5% by weight), gravy (26% by weight) and tap water (64% by weight) became 100 ° C cooked for 2 min. Subsequent stirring for 20 minutes and cooling to room temperature gave the shoe cream stain. The test surfaces were dipped in the shoe cream soil for 2 minutes. After removal, the test surfaces were dried at room temperature for 1 min and then rinsed with running water. The amount and distribution of residual debris left on the surfaces (white fat layer) were used as criteria for the easy-to-clean effect.
- the first specimen was taken in the morning on the first day, after there were no or few rinses.
- the second withdrawal took place in the afternoon after the rinses, overnight the reactor was filled with medium without rinsing.
- the specimens were dried after removal from the reactor at room temperature and then stained with 6 ml of 0.01% safranine solution for 15 minutes. Thereafter, the dyeing solution was sucked off, then the dyeing solution was sucked off, and the test pieces rinsed to remove the unbound dye from the test specimens. After drying, the dyed test specimens were scanned and evaluated with Corel Draw Paint 9. In order to be able to deduct the background value caused by the surfaces of the substrates used from the measured value, untreated surfaces were additionally scanned.
- Formulation F1 Another formulation (Formulation F2) was prepared in an analogous manner but additionally containing tetraethoxysilane (on a weight basis double the amount of silyl polyalkoxylate). Coverslips (20mm x 20mm) were dipped in the respective formulation for 1 min, followed by rinsing with running water. The reference was an untreated cover glass. The results showed that both inventive formulations against both test organisms used (Staphylococcus aureus and Pseudomonas aeruginosa) compared to the uncoated control a comparably strong and compared to the reference a significant adhesion reduction on glass caused.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL07847714T PL2109664T3 (pl) | 2006-12-05 | 2007-12-04 | Środek do obróbki twardych powierzchni |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006057632 | 2006-12-05 | ||
DE102007039652A DE102007039652A1 (de) | 2006-12-05 | 2007-08-22 | Mittel zur Behandlung harter Oberflächen |
PCT/EP2007/063204 WO2008068236A1 (de) | 2006-12-05 | 2007-12-04 | Mittel zur behandlung harter oberflächen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2109664A1 EP2109664A1 (de) | 2009-10-21 |
EP2109664B1 true EP2109664B1 (de) | 2010-10-27 |
Family
ID=39059363
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07847714A Not-in-force EP2109664B1 (de) | 2006-12-05 | 2007-12-04 | Mittel zur behandlung harter oberflächen |
Country Status (8)
Country | Link |
---|---|
US (1) | US7998919B2 (ko) |
EP (1) | EP2109664B1 (ko) |
JP (1) | JP2010511763A (ko) |
KR (1) | KR20090087905A (ko) |
AT (1) | ATE486120T1 (ko) |
DE (2) | DE102007039652A1 (ko) |
PL (1) | PL2109664T3 (ko) |
WO (1) | WO2008068236A1 (ko) |
Families Citing this family (30)
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DE102009029060A1 (de) * | 2009-09-01 | 2011-03-03 | Henkel Ag & Co. Kgaa | Mittel zur Behandlung harter Oberflächen |
WO2011051385A2 (de) * | 2009-10-30 | 2011-05-05 | Henkel Ag & Co. Kgaa | Zeitmodifiziert feuchtigkeitsaushärtende formulierungen |
DE102010032780A1 (de) | 2010-07-26 | 2012-01-26 | Helfried Haufe | Hydrophile Schicht und Beschichtungszusammensetzung zur Herstellung der Schicht sowie Verfahren zur Herstellung der Beschichtungszusammensetzung |
US11292919B2 (en) | 2010-10-08 | 2022-04-05 | Ut-Battelle, Llc | Anti-fingerprint coatings |
DE102011002809A1 (de) | 2011-01-18 | 2012-07-19 | Henkel Ag & Co. Kgaa | 2K-PU-Zusammensetzung mit verzögerter Vernetzung |
US20120189485A1 (en) * | 2011-01-21 | 2012-07-26 | Ppg Idustries Ohio, I Nc. | Methods of removing rust from a ferrous metal-containing surface |
FI20115276A0 (fi) * | 2011-03-22 | 2011-03-22 | 3S Cosmetics Oy | Kynsilakanpoistokoostumus ja sen käyttö |
DE102011007504A1 (de) | 2011-04-15 | 2012-10-18 | Henkel Ag & Co. Kgaa | PU-Zusammensetzungen mit komplexierten Katalysatoren |
US8852357B2 (en) | 2011-09-30 | 2014-10-07 | Ppg Industries Ohio, Inc | Rheology modified pretreatment compositions and associated methods of use |
KR101358448B1 (ko) * | 2011-11-23 | 2014-02-06 | 극동제연공업 주식회사 | 음이온성 계면활성제 및 주석산을 포함하는 자동차 유리 세정액 조성물 |
US20130216631A1 (en) | 2012-02-17 | 2013-08-22 | The Clorox Company | Targeted performance of hypohalite compositions thereof |
US9771656B2 (en) | 2012-08-28 | 2017-09-26 | Ut-Battelle, Llc | Superhydrophobic films and methods for making superhydrophobic films |
AU2013308540A1 (en) | 2012-08-31 | 2015-03-19 | 3M Innovative Properties Company | Multi-functional compositions and methods of use |
US20150239773A1 (en) | 2014-02-21 | 2015-08-27 | Ut-Battelle, Llc | Transparent omniphobic thin film articles |
US10030216B2 (en) | 2015-06-12 | 2018-07-24 | Crossford International, Llc | Systems and methods for cooling tower fill cleaning with a chemical gel |
US9404069B1 (en) | 2015-06-12 | 2016-08-02 | Crossford International, Llc | Systems and methods for cooling tower fill cleaning with a chemical gel |
KR102508822B1 (ko) * | 2016-04-28 | 2023-03-10 | (주)덕산테코피아 | 포토레지스트 박리액 조성물 |
KR101789251B1 (ko) * | 2017-03-17 | 2017-10-26 | 영창케미칼 주식회사 | 화학적 기계적 연마 후 세정용 조성물 |
MX2020007163A (es) | 2017-09-26 | 2020-08-17 | Ecolab Usa Inc | Composiciones de acidos/anionicos antimicrobianos y viricidas y usos de estas. |
US11541105B2 (en) | 2018-06-01 | 2023-01-03 | The Research Foundation For The State University Of New York | Compositions and methods for disrupting biofilm formation and maintenance |
JP7075657B2 (ja) * | 2018-06-29 | 2022-05-26 | エフエーティシステム株式会社 | うろこ状皮膜の除去方法 |
CA3136356A1 (en) | 2019-04-12 | 2020-10-15 | Ecolab Usa Inc. | Antimicrobial multi-purpose cleaner and methods of making and using the same |
CN114652898A (zh) * | 2022-03-25 | 2022-06-24 | 华南理工大学 | 一种用于慢性肾病修复的亲水负电多孔纳米薄膜及其制备方法与应用 |
GR20220100628A (el) * | 2022-08-01 | 2024-03-12 | Παπαδοπουλος Νικολαος-Ξαφακης Σωτηριος Ομορρυθμη Εταιρεια, | Μεθοδος αναπτυξης ανθεκτικων αντιρρυπαντικων νανοεπικαλυπτικων συστηματων με επιπροσθετη ισχυρη αντιμικροβιακη δραση |
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DE19642623A1 (de) * | 1996-10-16 | 1998-04-23 | Wella Ag | Haarreinigungsmittel mit Festigungseigenschaften |
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EP0983332A4 (en) * | 1997-12-12 | 2002-10-23 | Church & Dwight Co Inc | COMPOSITION FOR CLEANING HARD SURFACES |
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FR2779641B1 (fr) * | 1998-06-16 | 2000-07-21 | Oreal | Compositions cosmetiques detergentes et utilisation |
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US6528070B1 (en) * | 2000-09-15 | 2003-03-04 | Stepan Company | Emulsion comprising a ternary surfactant blend of cationic, anionic, and bridging surfactants, oil and water, and methods of preparing same |
EP1245667B1 (en) * | 2001-03-26 | 2005-10-26 | The Procter & Gamble Company | Process for cleaning hard surfaces with a liquid cleaning composition comprising a bleach |
DE10204523A1 (de) * | 2002-02-05 | 2003-08-07 | Bayer Ag | Alkoxysilan- und OH-Endgruppen aufweisende Polyurethanprepolymere mit erniedrigter Funktionalität, ein Verfahren zu ihrer Herstellung sowie ihre Verwendung |
US20050202178A1 (en) * | 2002-05-02 | 2005-09-15 | Hussmann Corporation | Merchandisers having anti-fog coatings and methods for making the same |
US20040033924A1 (en) * | 2002-08-14 | 2004-02-19 | Murphy Dennis Stephen | Methods for conferring fabric care benefits during laundering |
TW200407172A (en) * | 2002-10-17 | 2004-05-16 | Unilever Nv | Scalp treatment |
KR20040040782A (ko) * | 2002-11-08 | 2004-05-13 | 선바이오(주) | 신규한 헥사-암 폴리에틸렌글리콜과 유도체 및 그의합성방법 |
DE10357232B3 (de) | 2003-12-09 | 2005-06-30 | Henkel Kgaa | Artifizielle Fäkalanschmutzung |
WO2006005358A1 (en) | 2004-07-10 | 2006-01-19 | Henkel Kommanditgesellschaft Auf Aktien | Copolymer-containing cleaning compositions |
DE102005057857A1 (de) * | 2005-12-03 | 2010-02-25 | Evonik Goldschmidt Gmbh | Polyethermodifizierte Polysiloxane mit Blockcharakter und deren Verwendung zur Herstellung von kosmetischen Formulierungen |
US20070277697A1 (en) * | 2006-06-06 | 2007-12-06 | Keri Diamond | Product for treating vehicle surfaces |
-
2007
- 2007-08-22 DE DE102007039652A patent/DE102007039652A1/de not_active Withdrawn
- 2007-12-04 KR KR1020097011579A patent/KR20090087905A/ko active IP Right Grant
- 2007-12-04 JP JP2009539726A patent/JP2010511763A/ja active Pending
- 2007-12-04 DE DE502007005503T patent/DE502007005503D1/de active Active
- 2007-12-04 PL PL07847714T patent/PL2109664T3/pl unknown
- 2007-12-04 US US12/517,374 patent/US7998919B2/en not_active Expired - Fee Related
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- 2007-12-04 EP EP07847714A patent/EP2109664B1/de not_active Not-in-force
- 2007-12-04 WO PCT/EP2007/063204 patent/WO2008068236A1/de active Application Filing
Also Published As
Publication number | Publication date |
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JP2010511763A (ja) | 2010-04-15 |
WO2008068236A1 (de) | 2008-06-12 |
KR20090087905A (ko) | 2009-08-18 |
US7998919B2 (en) | 2011-08-16 |
DE502007005503D1 (de) | 2010-12-09 |
DE102007039652A1 (de) | 2008-06-12 |
ATE486120T1 (de) | 2010-11-15 |
EP2109664A1 (de) | 2009-10-21 |
US20100056415A1 (en) | 2010-03-04 |
PL2109664T3 (pl) | 2011-04-29 |
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