EP2069468B1 - Perfume dispensing system - Google Patents
Perfume dispensing system Download PDFInfo
- Publication number
- EP2069468B1 EP2069468B1 EP07820183A EP07820183A EP2069468B1 EP 2069468 B1 EP2069468 B1 EP 2069468B1 EP 07820183 A EP07820183 A EP 07820183A EP 07820183 A EP07820183 A EP 07820183A EP 2069468 B1 EP2069468 B1 EP 2069468B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- oder
- shaped article
- perfume
- shaped
- und
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
- 239000002304 perfume Substances 0.000 title claims description 51
- 239000003205 fragrance Substances 0.000 claims description 79
- 229920000642 polymer Polymers 0.000 claims description 55
- 238000000034 method Methods 0.000 claims description 30
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- 239000000126 substance Substances 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 13
- 239000002243 precursor Substances 0.000 claims description 12
- 239000004753 textile Substances 0.000 claims description 12
- 238000009835 boiling Methods 0.000 claims description 10
- 230000007062 hydrolysis Effects 0.000 claims description 8
- 238000006460 hydrolysis reaction Methods 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 6
- 238000000926 separation method Methods 0.000 claims description 3
- 230000003014 reinforcing effect Effects 0.000 claims 2
- 239000010408 film Substances 0.000 description 97
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- 235000019645 odor Nutrition 0.000 description 61
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- 239000000463 material Substances 0.000 description 25
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- 238000004519 manufacturing process Methods 0.000 description 15
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- 239000012362 glacial acetic acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- JHHZQADGLDKIPM-UHFFFAOYSA-N hept-3-en-2-one Chemical class CCCC=CC(C)=O JHHZQADGLDKIPM-UHFFFAOYSA-N 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- XOYYHTTVCNEROD-UHFFFAOYSA-N hex-1-enyl 2-hydroxybenzoate Chemical compound CCCCC=COC(=O)C1=CC=CC=C1O XOYYHTTVCNEROD-UHFFFAOYSA-N 0.000 description 1
- YDZCHDQXPLJVBG-UHFFFAOYSA-N hex-1-enyl acetate Chemical compound CCCCC=COC(C)=O YDZCHDQXPLJVBG-UHFFFAOYSA-N 0.000 description 1
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- 229940117955 isoamyl acetate Drugs 0.000 description 1
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- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- SVURIXNDRWRAFU-UHFFFAOYSA-N juniperanol Natural products C1C23C(C)CCC3C(C)(C)C1C(O)(C)CC2 SVURIXNDRWRAFU-UHFFFAOYSA-N 0.000 description 1
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- 239000002502 liposome Substances 0.000 description 1
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- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- GEWDNTWNSAZUDX-KWKBKKAHSA-N methyl (+)-7-isojasmonate Chemical compound CC\C=C/C[C@H]1[C@@H](CC(=O)OC)CCC1=O GEWDNTWNSAZUDX-KWKBKKAHSA-N 0.000 description 1
- KVWWIYGFBYDJQC-MNOVXSKESA-N methyl 2-[(1r,2s)-3-oxo-2-pentylcyclopentyl]acetate Chemical compound CCCCC[C@H]1[C@@H](CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-MNOVXSKESA-N 0.000 description 1
- BFBPISPWJZMWJN-UHFFFAOYSA-N methyl 2-[(7-hydroxy-3,7-dimethyloctylidene)amino]benzoate Chemical compound COC(=O)C1=CC=CC=C1N=CCC(C)CCCC(C)(C)O BFBPISPWJZMWJN-UHFFFAOYSA-N 0.000 description 1
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 229960001047 methyl salicylate Drugs 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- ZLQJVGSVJRBUNL-UHFFFAOYSA-N methylumbelliferone Natural products C1=C(O)C=C2OC(=O)C(C)=CC2=C1 ZLQJVGSVJRBUNL-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
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- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 229940067137 musk ketone Drugs 0.000 description 1
- YRDNVESFWXDNSI-UHFFFAOYSA-N n-(2,4,4-trimethylpentan-2-yl)prop-2-enamide Chemical compound CC(C)(C)CC(C)(C)NC(=O)C=C YRDNVESFWXDNSI-UHFFFAOYSA-N 0.000 description 1
- XFHJDMUEHUHAJW-UHFFFAOYSA-N n-tert-butylprop-2-enamide Chemical compound CC(C)(C)NC(=O)C=C XFHJDMUEHUHAJW-UHFFFAOYSA-N 0.000 description 1
- KPSSIOMAKSHJJG-UHFFFAOYSA-N neopentyl alcohol Chemical compound CC(C)(C)CO KPSSIOMAKSHJJG-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229940078552 o-xylene Drugs 0.000 description 1
- IWPOSDLLFZKGOW-UHFFFAOYSA-N oct-3-enoic acid Chemical compound CCCCC=CCC(O)=O IWPOSDLLFZKGOW-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- TZMFJUDUGYTVRY-UHFFFAOYSA-N pentane-2,3-dione Chemical compound CCC(=O)C(C)=O TZMFJUDUGYTVRY-UHFFFAOYSA-N 0.000 description 1
- QDRJCWZGTMRXCL-ZHACJKMWSA-N pentyl (e)-3-phenylprop-2-enoate Chemical compound CCCCCOC(=O)\C=C\C1=CC=CC=C1 QDRJCWZGTMRXCL-ZHACJKMWSA-N 0.000 description 1
- QKNZNUNCDJZTCH-UHFFFAOYSA-N pentyl benzoate Chemical compound CCCCCOC(=O)C1=CC=CC=C1 QKNZNUNCDJZTCH-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- GKSCDAAEBDVKTF-UHFFFAOYSA-N phenyl 2-ethylbenzoate Chemical compound CCC1=CC=CC=C1C(=O)OC1=CC=CC=C1 GKSCDAAEBDVKTF-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- 230000026731 phosphorylation Effects 0.000 description 1
- 238000006366 phosphorylation reaction Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229930006968 piperitone Natural products 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
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- 230000002035 prolonged effect Effects 0.000 description 1
- FJWSMXKFXFFEPV-UHFFFAOYSA-N prop-2-enamide;hydrochloride Chemical compound Cl.NC(=O)C=C FJWSMXKFXFFEPV-UHFFFAOYSA-N 0.000 description 1
- HPCIWDZYMSZAEZ-UHFFFAOYSA-N prop-2-enyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC=C HPCIWDZYMSZAEZ-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 150000003220 pyrenes Chemical class 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
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- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
- 229940081974 saccharin Drugs 0.000 description 1
- 235000019204 saccharin Nutrition 0.000 description 1
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229930002224 sesquiphellandrene Natural products 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
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- 239000000377 silicon dioxide Substances 0.000 description 1
- XJKVPKYVPCWHFO-UHFFFAOYSA-N silicon;hydrate Chemical class O.[Si] XJKVPKYVPCWHFO-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- LFSYLMRHJKGLDV-UHFFFAOYSA-N tetradecanolide Natural products O=C1CCCCCCCCCCCCCO1 LFSYLMRHJKGLDV-UHFFFAOYSA-N 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 238000002560 therapeutic procedure Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000001585 thymus vulgaris Substances 0.000 description 1
- CZCBTSFUTPZVKJ-UHFFFAOYSA-N trans-Rosenoxid Natural products CC1CCOC(C=C(C)C)C1 CZCBTSFUTPZVKJ-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KXSDPILWMGFJMM-UHFFFAOYSA-N trans-sabinene hydrate Natural products CC1(O)CCC2(C(C)C)C1C2 KXSDPILWMGFJMM-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- OEIXGLMQZVLOQX-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCNC(=O)C=C OEIXGLMQZVLOQX-UHFFFAOYSA-N 0.000 description 1
- KMPQYAYAQWNLME-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
- YHQGMYUVUMAZJR-UHFFFAOYSA-N α-terpinene Chemical compound CC(C)C1=CC=C(C)CC1 YHQGMYUVUMAZJR-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
Definitions
- the invention relates to a fragrance medium delivery system comprising a perfumed, polymer-containing shaped article which is provided in a removal container.
- the invention further relates to the use of the fragrance medium dispensing system for dispensing fragrance and to a process for scenting aqueous systems.
- fragrances to create fragrances has been an important element of human culture for a long time. For example, fragrances were used very early for sacred or ritual purposes. An example of this is the burning of frankincense. As a rule, fragrances are intended to mask other, perceived as unpleasant odors or produce pleasant, attractive odors. The use of fragrances also often has the purpose of giving the impression of cleanliness.
- EP 16 14 743 A1 describes a method for the prolonged scenting of textiles with water-soluble, perfume-containing films of polysaccharides or cellulose polymers.
- the object of the invention was to enable the consumer to individually perfume aqueous systems. This object is solved by the subject matter of the invention.
- the subject matter of the invention is a fragrance medium delivery system comprising a perfumed, water-soluble or water-dispersible, shaped body which contains at least 20% by weight of polymer (s) and at least 10% by weight of fragrances,% by weight, based in each case on the entire shaped body, wherein the shaped body is provided in a dispensing container, and wherein the shaped body is a foamed sheet, and wherein the perfume contained in the shaped body is at least 5 wt .-% in encapsulated form.
- a fragrance medium is a medium which carries fragrances, in the present case it is a perfumed shaped body.
- AWmediumabgsbesystem Is an object that allows the, preferably metered or portioned, delivery of the fragrance medium, so the perfumed molding to the consumer.
- the polymer content of the molded article may, in a preferred embodiment, also be well above 20% by weight, e.g. at a value of at least 25% by weight. 30 wt%, 35 wt%, 40 wt%, 45 wt%, 50 wt%, 55 wt%, 60 wt%. 65% by weight. 70 wt .-% or at least 75 wt .-% or even at least 80 wt .-%, wherein wt .-% based on the total molding is.
- Possible upper limits for the polymer portion of the molded article may e.g.
- the polymer content of the molded article may therefore be e.g. in the range of from 35% to 70% by weight, or e.g. Ranging from 40% to 80% by weight, etc.
- the perfumed shaped body is a strip-shaped, sheet-shaped, disk-shaped, or web-shaped, preferably flexible, film.
- a foil is a thin, flat material.
- films are more or less flexible, their flexibility being dependent both on the thickness of the film web and on the type of raw material used. In the case of very stiff products, in general parlance, one often no longer speaks of films, but rather of plates. According to the invention, plates are also included.
- the thicknesses of the films may preferably be between about 1 and 500 microns. There are also thinner films possible, which are then called membranes. These too are encompassed by the invention. There are also thicker films with thicknesses> 500 microns possible. These too are encompassed by the invention.
- Preferred film thicknesses are e.g. at values ⁇ 400 ⁇ m, ⁇ 300 ⁇ m, ⁇ 200 ⁇ m or even smaller ⁇ 100 ⁇ m. Thicknesses of e.g. ⁇ 80 ⁇ m, ⁇ 60 ⁇ m or ⁇ 40 ⁇ m possible.
- Possible minimum thicknesses may be, for example, values such as e.g. 2, 3, 4, 5, 6, 7, 8, 9 or 10 microns are. There are also minimum thicknesses of e.g. 15, 20, 25, 30, 35, 40, 45 or 50 microns possible, even values of at least 60, 70, 80, 90, 100, 150 or 200 microns are possible.
- a film according to the invention may accordingly have, for example, a thickness of from 3 to ⁇ 200 ⁇ m or, for example, from 20 to ⁇ 80 ⁇ m, to name only two examples.
- the minimum length of the film can also be 5, 6, 7 or 8 cm.
- the minimum width of the film can also be 5, 6, 7 or 8 cm.
- a film of the invention may have any shape, for example, square, rectangular, triangular, oval, circular. There are also special forms possible, such as heart shape, number form or letter form.
- the films of the invention may be transparent or opaque. It can be e.g. to act solo or composite foils.
- solofilms consist only of a uniform film material, which of course may comprise a mixture of different substances, in particular a polymer mixture. Both solo and composite films are encompassed by the invention.
- films consist of two layers of the same material, they are called double films.
- a major reason for the production of double films may be the generation of larger film thicknesses.
- a variant here is the coextrusion of two layers of a thermoplastic as an alternative to a single thicker layer. Double foils are also included in the invention.
- the films according to the invention are multilayered.
- the shaped articles according to the invention may comprise a single polymer or a blend of different polymers.
- the shaped body comprises one or more materials from the group (optionally acetalized) polyvinyl alcohol (PVAL) and / or PVAL copolymers, polyvinylpyrrolidone, polyethylene oxide, polyethylene glycol, gelatin, cellulose and derivatives thereof; in particular MC, HEC, HPC, HPMC and / or CMC, and / or copolymers and mixtures thereof.
- PVAL polyvinyl alcohol
- PVAL copolymers polyvinylpyrrolidone
- polyethylene oxide polyethylene glycol
- gelatin cellulose and derivatives thereof
- MC MC
- HEC highC
- HPMC HPMC
- CMC / or copolymers and mixtures thereof.
- copolymers and mixtures thereof Possibly. can the moldings known to the expert Softener to increase the flexibility of the material or other auxiliaries or additives mixed.
- polyvinyl alcohols are very particularly preferred as water-soluble polymers.
- Polyvinyl alcohols (abbreviated PVAL, occasionally PVOH) is the name for polymers of the general structure in small proportions (about 2%) also structural units of the type contain.
- polyvinyl alcohols which are available as white-yellowish powders or granules with degrees of polymerization in the range of about 100 to 2500 (molar masses of about 4000 to 100,000 g / mol), have degrees of hydrolysis of 98-99 or 87-89 mol%. , so still contain a residual content of acetyl groups.
- the polyvinyl alcohols are characterized by the manufacturer by indicating the degree of polymerization of the starting polymer, the degree of hydrolysis, the saponification number or the solution viscosity.
- polyvinyl alcohols are soluble in water and a few highly polar organic solvents (formamide, dimethylformamide, dimethyl sulfoxide); They are not attacked by (chlorinated) hydrocarbons, esters, fats and oils.
- Polyvinyl alcohols are classified as toxicologically safe and are biologically at least partially degradable. The water solubility can be reduced by aftertreatment with aldehydes (acetalization), by complexation with Ni or Cu salts or by treatment with dichromates, boric acid or borax.
- Polyvinyl alcohol is largely impermeable to gases such as oxygen, nitrogen, helium, hydrogen, carbon dioxide, but allows water vapor to pass through.
- Moldings which are preferred in the context of the present invention are characterized in that they comprise polyvinyl alcohols and / or PVAL copolymers whose degree of hydrolysis is 70 to 100 mol%, preferably 80 to 90 mol%, particularly preferably 81 to 89 mol% and in particular 82 to 88 mol%.
- the degree of polymerization of such preferred polyvinyl alcohols is between about 200 to about 2100, preferably between about 220 to about 1890, more preferably between about 240 to about 1680, and most preferably between about 260 to about 1500.
- Shaped bodies preferred according to the invention are characterized in that the shaped body comprises polyvinyl alcohols and / or PVAL copolymers whose average degree of polymerization is between 80 and 700, preferably between 150 and 400, more preferably between 180 and 300 and / or their molecular weight ratio MW (50%). to MG (90%) is between 0.3 and 1, preferably between 0.4 and 0.8 and in particular between 0.45 and 0.6.
- polyvinyl alcohols described above are widely available commercially, for example under the trade name Mowiol ® (Clariant).
- Mowiol ® Commercially, for example under the trade name Mowiol ® (Clariant).
- particularly suitable polyvinyl alcohols are, for example, Mowiol ® 3-83, Mowiol ® 4-88, Mowiol ® 5-88 and Mowiol ® 8-88.
- polyvinyl alcohols ® ELVANOL 51-05, 52-22, 50-42, 85-82, 75-15, T-25, T-66, 90-50 (trademark of Du Pont)
- ALCOTEX ® 72.5, 78, B72, F80 / 40, F88 / 4, F88 / 26, F88 / 40, F88 / 47 (trademark of Harlow Chemical Co.)
- Gohsenol ® NK-05, A-300, AH-22, C -500, GH-20, GL-03, GM-14L, KA-20, KA-500, KH-20, KP-06, N-300, NH-26, NM11Q, KZ-06 (Trademark of Nippon Gohsei KK ).
- ERKOL types from Wacker.
- a further preferred group of water-soluble polymers which may be present in the moldings according to the invention are the polyvinylpyrrolidones. These are marketed under the name Luviskol ® (BASF). Polyvinylpyrrolidones [poly (1-vinyl-2-pyrrolidinones)], abbreviation PVP, are polymers of the general formula (I) which are prepared by free-radical polymerization of 1-vinylpyrrolidone by the method of solution or suspension polymerization using free-radical initiators (peroxides, azo compounds) as initiators. The ionic polymerization of the monomer provides only low molecular weight products.
- polyvinylpyrrolidones have molar masses in the range of about 2500-750000 g / mol, which are characterized by the specification of the K values and - depending on K value - have glass transition temperatures of 130-175 °. They are offered as white, hygroscopic powders or as aqueous solutions. Polyvinylpyrrolidones are readily soluble in water and a variety of organic solvents (alcohols, ketones, glacial acetic acid, chlorinated hydrocarbons, phenols, etc.).
- copolymers of vinylpyrrolidone with other monomers in particular vinylpyrrolidone / Vinylester copolymers, such as for example, under the trade name Luviskol ® (BASF).
- Luviskol ® VA 64 and Luviskol ® VA 73, each vinylpyrrolidone / vinyl acetate copolymers are particularly preferred non-ionic polymers.
- the vinyl ester polymers are vinyl ester-accessible polymers having the moiety of the formula (II) as a characteristic building block of the macromolecules.
- the vinyl acetate polymers (R CH 3 ) with polyvinyl acetates as by far the most important representatives of the greatest technical importance.
- the polymerization of the vinyl esters is carried out free-radically by different processes (solution polymerization, suspension polymerization, emulsion polymerization, bulk polymerization).
- Copolymers of vinyl acetate with vinylpyrrolidone contain monomer units of the formulas (I) and (II).
- PEG polyethylene glycols
- PEG polyethylene oxides
- n can take values between 5 and> 100,000.
- PEGs are prepared industrially by anionic ring-opening polymerization of ethylene oxide (oxirane), usually in the presence of small amounts of water. Depending on the reaction procedure, they have molar masses in the range of about 200-5,000,000 g / mol, corresponding to degrees of polymerization of about 5 to> 100,000.
- PEG polyethylene glycols
- PEOX polyethylene oxides
- gelatin is a polypeptide (molecular weight: about 15,000 to> 250,000 g / mol), which is obtained primarily by hydrolysis of the collagen contained in the skin and bones of animals under acidic or alkaline conditions.
- the amino acid composition of gelatin largely corresponds to that of the collagen from which it was obtained and varies depending on its prevalence.
- the use of gelatin as water-soluble coating material is extremely widespread, especially in pharmacy in the form of hard or soft gelatin capsules. In the form of films, gelatin generally has little use because of its high price compared to the polymers mentioned above.
- Preferred shaped bodies according to the invention are characterized in that they comprise hydroxypropylmethylcellulose (HPMC) which has a degree of substitution (average number of methoxy groups per anhydroglucose unit of the cellulose) of from 1.0 to 2.0, preferably from 1.4 to 1.9, and a molar substitution (average number of hydroxypropoxyl groups per anhydroglucose unit of cellulose) of from 0.1 to 0.3, preferably from 0.15 to 0.25.
- HPMC hydroxypropylmethylcellulose
- polymers which are suitable according to the invention are water-soluble amphopolymers.
- Amphoteric polymers ie polymers which contain both free amino groups and free -COOH or SO 3 H groups in the molecule and are capable of forming internal salts, are zwitterionic polymers which contain quaternary ammonium groups in the molecule. COO - - or -SO 3 - groups, and summarized those polymers containing -COOH or SO 3 H groups and quaternary ammonium groups.
- amphopolymer suitable is the acrylic resin commercially available as Amphomer ® is a copolymer of tert-butylaminoethyl methacrylate, N- (1,1,3,3-tetramethylbutyl) -acrylamide and two or more monomers from the group of acrylic acid, Represents methacrylic acid and its simple esters.
- preferred amphopolymers are composed of unsaturated carboxylic acids (eg, acrylic and methacrylic acid), cationically derivatized unsaturated carboxylic acids (eg, acrylamidopropyltrimethylammonium chloride), and optionally further ionic or nonionogenic monomers together.
- Terpolymers of acrylic acid, methyl acrylate and methacrylamidopropyltrimonium as they are commercially available under the name Merquat ® 2001 N are inventively particularly preferred amphopolymers.
- Other suitable amphoteric polymers are for example sold under the names Amphomer ® and Amphomer ® LV-71 (DELFT NATIONAL) available octylacrylamide / methyl methacrylate / tert-butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers.
- Such grafted polymers of vinyl esters, esters of acrylic acid or methacrylic acid alone or in admixture with other copolymerizable compounds on polyalkylene glycols are obtained by homogeneous-phase polymerization by reacting the polyalkylene glycols in the monomers of vinyl esters, esters of acrylic acid or methacrylic acid, in The presence of free radical initiator stirs.
- Suitable vinyl esters are, for example, vinyl acetate, vinyl propionate, vinyl butyrate, vinyl benzoate and as esters of acrylic acid or methacrylic acid those with aliphatic alcohols of low molecular weight, ie in particular ethanol, propanol, isopropanol, 1-butanol, 2-butanol, 2-methyl 1-propanol, 2-methyl-2-propanol, 1-pentanol, 2-pentanol, 3-pentanol, 2,2-dimethyl-1-propanol, 3-methyl-1-butanol; 3-methyl-2-butanol, 2-methyl-2-butanol, 2-methyl-1-butanol, 1-hexanol, are proven.
- the polyethylene glycol used has a molecular weight between 200 and several million, preferably between 300 and 30,000.
- the nonionic monomers may be of very different types and of these preferred are: vinyl acetate, vinyl stearate, vinyl laurate, vinyl propionate, allyl stearate, allylaurate, diethyl maleate, allyl acetate, methyl methacrylate, cetyl vinyl ether, stearyl vinyl ether and 1-hexene.
- the non-ionic monomers may equally be of very different types, among which particularly preferably crotonic acid, allyloxyacetic acid, vinylacetic acid, maleic acid, acrylic acid and methacrylic acid are contained in the grafting polymers.
- crosslinkers used are preferably ethylene glycol dimethacrylate, diallyl phthalate, ortho-, meta- and para-divinylbenzene, tetraallyloxyethane and polyallyl sucrose having 2 to 5 allyl groups per molecule of saccharin.
- cationic polymers which can be used according to the invention are cationic polymers.
- the permanent cationic polymers are preferred.
- "permanently cationic” refers to those polymers which have a cationic group independently of the pH. These are usually polymers containing a quaternary nitrogen atom, for example in the form of an ammonium group.
- Cationic polymers preferred according to the invention are quaternized cellulose derivatives and polymeric dimethyldiallylammonium salts and their copolymers.
- Cationic cellulose derivatives, in particular the vialsptodukt Polymer ® JR 400, are very particularly preferred cationic polymers.
- the use of cationic polymers can help to further improve the scent effect of the film in use.
- the odor of a scented aqueous system can be further improved so that the fragrance lasts longer and is preferably more intense, with the same amount of fragrance used.
- the Aufzieh the Fragrances on substrates treated in / with the perfumed aqueous system, such as textiles can be improved by the use of cationic polymers, so that the fragrance of the substrate lasts longer and is preferably more intense.
- cationic polymers are particularly effective when preferably> 2 wt .-%, preferably> 4 wt .-%, in particular> 6 wt .-% of cationic polymers are contained in the molding, wt .-% based on the total molding , Upper limits may e.g. at 30, 20 or 10 wt .-% cationic polymer, based on the total molding.
- the film paint material may contain further ingredients which in particular improve the processability of the starting materials for the film.
- plasticizers and release agents should be mentioned here.
- dyes and optical brighteners can be incorporated into the film to achieve aesthetic effects there.
- Suitable release agents which may preferably be applied to the finished, dried films are e.g. Talc, starch or (physically, chemically and / or enzymatically) modified starch. Suitable chemical modifications are e.g. Crosslinking, acetylation, esterification, hydroxyethylation, hydroxypropylation, phosphorylation.
- the preferably hydrophobic release agent adheres in particular externally to the film.
- hydrophilic, high-boiling liquids can be used as the plasticizer, solids which may also be solid at room temperature being used as the solution. Dispersion or melt can be used.
- Particularly preferred plasticizers are selected from the group glycol, di-, tri-, tetra-, penta-, hexa-, hepta-, octa-, nona-, deca-, undeca-, dodecaethylene glycol, glycerol, neopentyl glycol, trimethylolpropane, pentaerythritol, mono -, di-, triglycerides, surfactants, in particular nonionic surfactants, and mixtures thereof.
- Plasticizers are preferably used in amounts of from 1 to 50% by weight, preferably from 2 to 40% by weight, in particular from 5 to 30% by weight. Upper limits may also be, for example, at 20 or 10% by weight of plasticizer, based on the total molding.
- Surfactants in particular nonionic surfactants, are also suitable as further plasticizers.
- plasticizers may be glycerol carbonate, propylene glycol and propylene carbonate.
- additional additives which are preferably in solid form at room temperature.
- pyrogenic silicas such as the commercially available Aerosil ® or precipitated silicas offer.
- Particularly preferred processes according to the invention are characterized in that as further additives one or more materials from the group (preferably finely divided) silica, dispersion powder, high molecular weight polyglycols, stearic acid and / or stearic acid salts, and / or from the group of inorganic salts such as sodium sulfate, calcium chloride and / or from the group of Inclusiontruckner such as urea, cyclodextrin and / or from the group of superabsorbents such as (preferably crosslinked) polyacrylic acid and / or their salts such as Cabloc 5066 / CTF and mixtures thereof, is / are used.
- Moldings preferred according to the invention may contain dyes.
- Suitable dyes preferably have a high storage stability and insensitivity to the other ingredients of the compositions and to light and no pronounced substantivity to the at least indirectly coming into contact with the dye-containing agents substrates such as textiles, glass, ceramics or plastic dishes, so as not to stain them.
- the colorants have a high storage stability and insensitivity to light.
- water-insoluble colorants are more stable to oxidation than water-soluble colorants.
- concentration of the colorant in the moldings varies.
- dyeing concentrations in the range of a few 10 -2 to 10 -3 % by weight, based on the total molding are typically selected.
- the suitable concentration of the dyestuff is typically about 10 -3 to 10 -4 % by weight, based on the total molding
- colorants which can be oxidatively destroyed in a washing process and mixtures thereof with suitable blue dyes, so-called blue toners. It has proven to be advantageous to use colorants which are soluble in water or at room temperature in liquid organic substances. Suitable are, for example, anionic colorants, e.g. anionic nitrosofibres.
- the films according to the invention are not a packaging material for liquids or solids, e.g. Washing or cleaning agents, so are no film material of detergent pouches or the like.
- the films of the invention can be prepared by any known method, but the casting method is to be regarded as very advantageous.
- thermoplastic processing by calendering or extrusion is very preferred. In particular, coextrusion is preferred.
- the blown film process and the flat film process according to the invention are very preferred processes for film production.
- blown films The production of blown films is known. For example, mixing of polymeric material, such as e.g. PVOH powder with additives and stabilizers in the solid state. This mixture is melted in the heated extruder.
- the fragrances required according to the invention may e.g. be added to the melt. This is followed by the blowing of the melt, the cooling and preferably the winding of the film.
- Blown films are generally less expensive to produce than cast films, but the film thickness distribution can be slightly more slender and it may possibly lead to more air bubbles, but this can also be a desired effect.
- blown films are something harder and have less recovery properties than cast films, whereas these can be soft, flexible, almost rubbery and can also have high
- the polymer solutions can be prepared according to the invention by use of solvents, which is preferred, or by chemical conversion of insoluble macromolecules into soluble derivatives.
- the fragrances required according to the invention may e.g. be added to the polymer solution.
- wet-casting For example, in cellophane production, a high-viscosity cellulose solution is forced through a slot die into a strong acid precipitation bath.
- the solvent evaporates and thereby the polymer is recovered as a film, so it is called dry casting, for the implementation of particular belt or drum casters can be used.
- the polymer solution which contains odoriferous substances according to the invention, is poured from a storage container preferably through a nozzle onto a generally endless, preferably highly polished, metal strip.
- the belt speeds depend strongly on the material used and on the desired film thickness. They can preferably be between 2 and 60 meters per minute.
- the film can be stripped off after evaporation of most of the solvents. For winding, it is preferably passed through a dryer with hot air or hot rollers. Resulting film thicknesses can be 15 to 300 microns in this process, for example.
- the polymer solution prefferably be forced over a filter prior to being cast onto the metal strip to retain any undissolved particles that might otherwise result in so-called speckling. It is likewise possible and preferred to at least partially free the polymer solution from air that is contained in a degassing container before it is poured onto the metal plate.
- the optional degassing is advantageously carried out before the addition of fragrance.
- the PVOH powder / granules and plasticizers eg PEG and / or glycerol
- water eg in a batch tank.
- the solution is fed to a reservoir.
- the solution is then heated to, for example, about 80 ° C and then fed via a slot die to a rolled strip.
- the drying process air heating channel
- the solution is expressed as a film.
- perfume oils may be added to the PVOH mixture in the batch tank according to the invention.
- Trommelg machineclar Similar to the strip casting method is the Trommelg foolclar.
- heated drums are used at the location of the metal strip, such as those with a diameter of 2-3 m and widths of about 2 m.
- films are usually obtained which generally show uniform, uniform film thickness distribution and little air inclusions, although the process is expensive because of the energy-intensive drying.
- the cast process can produce thinner foils than the blown process.
- High levels of water can also be adjusted, e.g. 5-8 wt .-% water based on the entire film.
- the cast method is preferably applied to those which are not meltable or decompose only with decomposition, e.g. Cellulose or polyimides.
- the casting process is also preferably used.
- Rolling or sintering processes are in principle also possible for film production, but only in exceptional cases makes sense, e.g. for the production of tetrafluoroethylene films and polyimide films.
- a method for producing a film wherein first by dissolving or dispersing one or more polymers in a liquid carrier medium, a rollable preparation is prepared and this is then brought by means of rolling in the form of a film by means of a rolling device.
- the liquid carrier medium can be evaporated.
- a liquid carrier medium preferably comprises solvents or dispersants such as water, alcohols, ethers or hydrocarbons or mixtures of two or more of the substances mentioned, wherein the substances or mixtures of substances are liquid at room temperature (20 ° C.).
- Suitable alcohols are e.g. the monohydric or polyhydric alcohols having 1 to 5 carbon atoms, e.g. Ethanol, isopropanol, ethylene glycol, glycerol and propylene glycols.
- the content of the liquid carrier medium may be e.g. in the range of 20 to 90 wt .-% or 30 to 70 wt .-% are.
- a suitable rollable formulation may e.g. semi-solid or dough-like consistency, or it may be a viscous liquid with which a suitable carrier is coated and the desired film thickness is produced by rolling with a rolling device.
- the finished film is then removed from the carrier after drying.
- suitable carrier materials for example, from the group of silicone, metal, metallized polymers, polytetrafluoroethylene, polyether / polyamide block copolymers, polyurethanes, polyvinyl chloride, nylon, alkylene / styrene copolymers, polystyrene, polyester or other, redetachable materials can be selected suitable carrier materials.
- Suitable rolling devices are, for example, the known, with at least two equal or opposite rollers or rollers provided so-called forward roll or reverse roll coater, with a reverse roll method is preferred.
- the resulting (by all possible methods) films can be further processed, for example, by vapor deposition, coating, printing or flocking. It is also possible that the perfuming of the film takes place only after the actual film production, e.g. by spraying, brushing or dipping the film into a perfume-containing preparation. However, it is more preferred if the perfuming of the film takes place in the course of the film production. A coupled process is also possible, in which perfuming takes place both in the course of film production and the finished film is then perfumed once again, e.g. by spraying.
- the films according to the invention are foamed films.
- gas bubbles of a suitable gas e.g. Air included.
- Such films with trapped gas bubbles are characterized by a particularly good feel. Furthermore, they can show improved water solubility.
- Preferred foamed films have a density of ⁇ 1 kg / m 3 .
- a blowing or blowing agent can be used. It can e.g. foaming can be achieved by mechanical stirring of the still liquid or viscous carrier mass. It can e.g. to provoke a gas-producing chemical reaction. It can e.g. a volatile solvent may be used, which is evaporated at elevated temperatures. It can e.g. an introduction of a gas or a liquefied gas into the still viscous carrier mass.
- blowing agents are substances that decompose on heating with evolution of gas, so that e.g. Nitrogen or carbon dioxide to be released.
- confetti form means that it is a variety of Foflenschnipseln or foil shreds.
- the term "confetti” is generally known for small, colorful scraps of paper. Confetti-shaped foils do not necessarily have to be as small as that well-known paper confetti, which is thrown in the air especially during carnival parades, but also at other celebrations, such as children's birthday parties or weddings.
- the confetti shape can be regular or irregular, it can be, for example, circular foil shreds, it can be, for example, bug-shaped foil snippets. Any conceivable shape is possible and obtainable, for example, by punching out the foil confetti from a larger mother foil.
- the use of films according to the invention in confetti form can be advantageous, for example, in hand-textile washing, if a certain amount of the films in confetti form is scattered in the textile treatment bath.
- the removal container may be any container which is particularly suitable for at least partially enveloping and / or holding together a film-shaped molding.
- the container may be made of e.g. be formed of a flexible, semi-rigid or dimensionally stable material.
- a dimensionally stable container has the advantage, in particular to protect fragile film-shaped moldings from mechanical influences and to prevent corresponding damage.
- the container is preferably made water vapor-tight.
- the container is preferably odor-proof.
- means for child-safe opening are provided on the container, to prevent inadvertent contact of children with the film-shaped moldings.
- metering and removal aids for the film-shaped moldings are provided on the container according to the invention.
- a flexible container it may be e.g. to act a packaging bag, such as a flat bag, sealed edge bag, bottom bag, double bag, bag or bag, e.g. a pouch made of a multilayer, sheet-like and flexible composite material, the pouch preferably having a tear-open aid, such as e.g. has a tear strip or Anreiflaussparung.
- a packaging bag such as a flat bag, sealed edge bag, bottom bag, double bag, bag or bag, e.g. a pouch made of a multilayer, sheet-like and flexible composite material
- the pouch preferably having a tear-open aid, such as e.g. has a tear strip or Anreiflaussparung.
- roller-shaped moldings individually or in a plurality in a flexible container.
- the film-shaped moldings packaged in one or more flexible containers may be intended for use in tape or sheet dispensers. Ribbon or sheet dispensers can also be used for unpacked film-shaped moldings.
- the extraction container may also comprise or consist of a roll.
- the preferably strip-shaped, sheet-shaped, Schelbenförmige or web-shaped, flexible shaped body can therefore be wound on a roll, wherein the shaped body is preferably provided with separation points for portionwise removal.
- Such removal containers are known for example from the field of adhesive tape scooters. Adhesive tape scooters fall under the generic term of tape dispensers. All tape dispensers may be suitable as a removal container.
- the Ent Spotify itris thus comprises a roller, preferably a tape dispenser, wherein the shaped body is provided in particular with separation points for portion removal, so is a preferred embodiment.
- tape dispensers For the production of pieces of tape also devices, so-called tape dispensers, are useful, with which the tape is unwound from a roll and passed over a cutting element. When the free end of the band has reached the desired length, it is cut off with the cutting element.
- the length of the tape to be cut off is determined by the user by unwinding the tape in the desired length and then cutting it off. For cutting, it must lead the end of the tape over the cutting element, typically a saw-toothed cutting blade made of either metal or plastic, that this cutting can act on the tape.
- Such or similar tape dispensers can be advantageously used according to the invention.
- Refillable tape dispensers are particularly preferred for repeatably receiving a tape roll.
- Particularly suitable are e.g. also such tape dispensers as are known in the field of correction tape dispensers (film transfer rollers). If the removal container according to the invention is a film transfer roller, this is a preferred embodiment.
- sheet dispensers are devices that contain a stack of sheets, strips or foils, etc., and include a dispensing aid for the sheets, strips or foils.
- this stack is arranged so that upon removal of the uppermost sheet, the underlying sheet is aligned so that it is then removed without difficulty.
- the following sheet already tracked so far that it protrudes from the removal slot and can be easily removed afterwards.
- it is a block of films each having a layer of a flexible polymeric material which may be provided at a second end region with a coating of repositionable pressure-sensitive adhesive material, while remaining free of adhesive along a visually recognizable first end region in a stack with the adjacent ends of the sheets aligned and the first and second ends of successive sheets disposed adjacent one another.
- the stack may be disposed in a chamber which is partially bounded in the top wall by a slot through which the first end portion of the topmost sheet projects.
- the fragrance medium delivery system of the present invention is configured to allow removal of at least 3, 4, 5, or more different perfume tablets.
- This may be, for example, a system comprising 3, 4 or 5 rolls of different perfume films. This can then also be described as a set of 3, 4 or 5 sets.
- the perfume tablets differ in their perfuming, so that the consumer can set the total perfume rating by the dosage of the individual perfume body. There are no limits to the creativity of the consumer.
- the different perfuming can advantageously be indicated by different colors.
- the shaped bodies of a corresponding set configuration advantageously contain different fragrances, which can preferably be distinguished according to specific notes.
- dosing dispensers for moldings.
- Such dosing dispensers usually consist of a housing with a storage chamber whose bottom is e.g. an outlet opening which opens into a guide for a slide with pressure plate and with return spring, wherein the slide has a channel located in its rest position below the outlet opening, the discharge opening is covered in the rest position by a cover.
- Such dosing dispensers may contain perfumed shaped bodies, so that one can speak in such a case of a fragrance medium delivery system.
- the dimensions of corresponding metering dispensers are of course adapted to the dimensions of the molding in question.
- Such dosing dispensers may be preferred according to the invention.
- the consumer can e.g. Create dishwashing water with a banana-like odor, bath water with a vanilla-like odor or, for example, window rinse water with a honey-like odor. He can also create completely new odor images by combining different moldings.
- fragrances of essential oils can be used. Typical examples are chamomile, rosemary, thyme, jasmine, peppermint and sandalwood.
- fragrances e.g.
- Typical examples are chamomile, rosemary, thyme, jasmine, peppermint and sandalwood.
- the consumer can thus influence the subjective sense of well-being by selecting fragrances, and e.g. Psychosomatically concomitant complaints such as nervousness or stress accompany with the use of perfumed moldings.
- appropriate moldings can be used to support the subjective well-being. However, this is not a therapeutic process in the true sense, but an odor-cosmetic process.
- the set configuration already described is also suitable, for example, for designing a scent carousel.
- Carousel configurations are known in particular from the field of spice carousel. These are usually rotatable structures, which comprise at least 4 or more, for example up to 12 individual, removable containers which are arranged in a round shape on a stand or a holding device. Such a perfume carousel with e.g. 12 containers, which comprise different fragrance tablets, may even be referred to as a so-called fragrance organ, with which the consumer can compose an individual fragrance.
- the molded article according to the invention contains at least 12% by weight of perfume, preferably at least 15% by weight of perfume, in particular at least 20% by weight of perfume, based on the total molding.
- the molded article may also contain larger amounts of perfume, e.g. at least 25, 30, 35, 40, 45 or even at least 60% by weight of perfume.
- Useful upper limits of perfume may e.g. at 80 wt%, 75 wt%, 70 wt%, 65 wt%, 60 wt%, 55 wt%. 50 wt%, 45 wt%, 40 wt%, 35 wt%, 30 wt%. 25 wt .-%, 20 wt .-%, 15 wt .-% or 10 wt .-% are.
- the perfume contained at least 5, 10 or 15 wt .-% of fragrances having a boiling point above 250 ° C and a logP value of ⁇ 3.0, so is a preferred embodiment. It has been found that moldings according to the invention which contain such minimum amounts of fragrances having a boiling point above 250 ° C. and a logP value of ⁇ 3.0 have particularly advantageous scent properties. For example, a longer-lasting fragrance impression can be achieved when using the shaped bodies in aqueous systems. Likewise, the Aufzieh the fragrances on substrates which are treated in / with the perfumed aqueous system, further improved, so that dia substrates, especially textiles longer and more intense smell.
- the octanol / water partition coefficient of a perfume ingredient is the ratio between its equilibrium concentration in octanol and in water. Since the distribution coefficients of the perfume ingredients are often high, e.g. 1000 or higher, they are more conveniently given in the form of their base 10 logarithm, one speaks of the so-called log P value.
- Preferred fragrances of this invention have a logP of ⁇ 3.0 or higher, e.g. From ⁇ 3.1. preferably ⁇ 3.2, in particular ⁇ 3.3.
- the logP value of numerous fragrances is documented; For example, the Pomona92 database, available from Daylight Chemical Information Systems, Inc., (Daylight CIS), Irvine, California, contains numerous logP values, along with citations to the original literature. However, the logP values are most conveniently calculated by the "CLOGP” program, which is also available from Daylight CIS. This program also lists the experimental logP values if they are available in the Pomona92 database. The "calculated logP" (ClogP value) is determined by the fragment approximation according to Harsch and Leo.
- Table 1 below lists several fragrances that fulfill the criteria boiling point> 250 ° C and ClogP ⁇ 3. Such fragrances which fulfill these criteria are also referred to as persistent fragrances in the further course. Table 1: Examples of persistent fragrances Perfume ingredients Approximately boiling point (° C) ClogP Boiling point> 250 ° C and ClogP ⁇ 3.0 Allylcylclohexanpropionat 267 3,935 ambrettolide 300 6.261 amyl benzoate 262 3,417 Amylcinnamat 310 3,771 amyl cinnamic aldehyde 285 4,324 Amylzimtaldehyddimethylacetal 300 4,033 iso-amyl salicylate 277 4,601 aurantiol 450 4,216 benzophenone 306 3,120 benzyl 300 4,383 para-tert-butylcyclohexyl acetate +250 4,019 iso-butylquinoline 252 4,193 beta-caryophyl
- the shaped articles of the present invention preferably contain at least 3 different resistant fragrances, more preferably at least 4 different resistant fragrances, and even more preferably at least 5 different resistant fragrances.
- the shaped bodies preferably contain ⁇ 20% by weight, ⁇ 25% by weight, ⁇ 30% by weight, ⁇ 35% by weight, ⁇ 40% by weight, ⁇ 45% by weight. %, ⁇ 50 wt%, ⁇ 55 wt%, ⁇ 60 wt%, ⁇ 65 wt%, ⁇ 75 wt%, ⁇ 80 wt%, ⁇ 85 wt% , ⁇ 90 wt .-% or even ⁇ 95 wt .-% of resistant fragrances, wt .-% based on the total amount of the fragrances contained in the molding.
- non-odor or very low odor materials are used as perfume diluents or extenders.
- these materials are dipropylene glycol, diethyl phthalate, triethyl citrate, isopropyl myristate and benzyl benzoate. These materials are e.g. used to dilute and stabilize some other perfume ingredients. These materials are not included in the calculation of the total amount of fragrances contained in the molding.
- Non-resistant fragrances in the context of this invention are those fragrances which have a boiling point of less than about 250 ° C or a ClogP of less than about 3.0, or both a boiling point of less than about 250 ° C and a ClogP of less than about 3.0.
- non-resistant fragrances are preferably minimized in the shaped bodies of the present invention, ie the shaped bodies preferably contain ⁇ 60% by weight, ⁇ 55% by weight, ⁇ 50% by weight, ⁇ 45% by weight.
- non-resistant fragrances are used at least in small amounts, namely to improve the odor of the molded article as such.
- the shaped bodies of the present invention therefore preferably contain ⁇ 1% by weight, preferably ⁇ 5% by weight, more preferably ⁇ 10% by weight, even more preferably ⁇ 15% by weight, in particular even ⁇ 20, ⁇ 25 or even ⁇ 30 wt .-%, of non-resistant fragrances, wt .-% based on the total amount of fragrances contained in the molding.
- the perfume contained in the molding is at least 5% by weight in an encapsulated form.
- the proportion of the contained perfume in encapsulated form may be even greater, e.g. at values of at least 10, 15, 20, 25, 30, 35, 40 or 45 wt .-% are.
- Wt .-% refers to the total amount of the perfume contained in the molding.
- the encapsulated perfume particles are activated by moisture.
- perfume particles are known. They may be, for example, cyclodextrin / perfume inclusion complexes or perfume microcapsules, e.g. act with a polysaccharin binder. The encapsulation of the perfume minimizes premature volatilization of the fragrances even further. The verkapseit perfume is only then released. when the materials are moistened.
- the perfume capsules may have a diameter of 100 nm to e.g. 1 mm. It is also possible. To use perfume capsules that are larger than 1 mm in diameter
- Preferred perfume microcapsules have e.g. a diameter of 0.5 .mu.m to 300 .mu.m, preferably 1 .mu.m to 200 .mu.m, in particular 2 .mu.m to 100 .mu.m.
- the Kapsei twistmesser is of course to vote on the film thickness.
- the maximum capsule diameter may e.g. even at values ⁇ 90 ⁇ m, ⁇ 80 ⁇ m, ⁇ 70 ⁇ m, ⁇ 60 ⁇ m, ⁇ 50 ⁇ m or ⁇ 40 ⁇ m.
- Particularly useful methods of encapsulation include coacervation, liposome formation. Granulation. Coating, emulsification, atomization and spray cooling.
- the capsules can be incorporated into a preferably water-soluble film.
- the capsules are preferably immiscible with the film.
- the capsules are hydrophobic in nature to prevent their diffusion into the hydrophilic film.
- the capsules may preferably be prepared in situ in the film as part of the film casting process.
- the preferably hydrophobic ingredient for the capsules is especially selected from the group consisting of paraffin, wax, oil, vaseline, a hydrophobic polymer, and mixtures thereof.
- the e.g. hydrophobic continuous phase and then mixed with either an oil-soluble benefit agent (such as perfume) or a discontinuous phase or blender.
- the resulting solution or emulsion or dispersion is mixed with a solution of a water-soluble film in water (for example, ratio of film to water 1: 4).
- the mixture is preferably prepared at a relatively low temperature to protect sensitive benefit components, if present (eg, 30-45 ° C).
- the result is an emulsion in the water-soluble film.
- the emulsion is poured and e.g. sintered in an oven to form a film with capsules.
- the molding according to the invention contains perfume precursors, which preferably release fragrances by hydrolysis only in the presence of H 2 O.
- the perfume precursors may advantageously be selected from ⁇ -aminoketone scavenger precursors, aldehyde- or ketone-releasing perfume precursors, alcohol-releasing perfume precursors, preferably silicic acid esters, and orthocarbonate and ortho ester perfume extenders.
- the fragrance precursors are selected from acetals, ketals, orthoesters, orthocarbonates, and mixtures thereof.
- a particularly preferred fragrance precursor is of the formula in which R is hydrogen, linear C 1 -C 8 -alkyl, branched C 3 -C 20 -alkyl, cyclic C 3 -C 20 -alkyl, branched cyclic C 6 -C 20 -alkyl, ilmenes C 6 -C 20 -alkenyl, branched C 6 -C 20 alkenyl, cyclic C 0 -C 20 alkenyl, branched cyclic C 6 -C 20 alkenyl, substituted or unsubstituted C 6 -C 20 aryl, and mixtures thereof;
- R 1 , R 22 and R 3 independently of one another are linear, branched or substituted C 1 -C 20 -alkyl, linear, branched or substituted C 2 -C 20 -alkenyl, substituted or unsubstituted, cyclic C 3 -C 20 -alkyl , substituted or unsubstit
- the fragrance precursor is an acetal or a ketal of the formula contain, in which R is linear C 1 -C 20 -alkyl, branched C 3 -C 20 -alkyl, cyclic C 6 -C 20 -alkyl, branched cyclic C 6 -C 20 -alkyl, linear C 2 -C 20 -alkenyl, branched C 3 -C 20 alkenyl, C 6 -C 20 cyclic alkenyl, branched cyclic C 6 -C C 6 -C 20 alkenyl, substituted or unsubstituted 20 aryl, and mixtures thereof; R 1 is hydrogen or R; R 2 and R 3 are each independently selected from the group consisting of linear C 1 -C 20 alkyl, branched C 3 -C 20 alkyl, cyclic C 3 -C 20 alkyl, branched cyclic C 6 -C 20 Alkyl, linear C 6 -C
- a fragrance precursor having the formula: wherein R 1 , R 2 , R 3 and R 4 are independently linear, branched or substituted C 1 -C 20 alkyl, linear, branched or substituted C 2 -C 20 alkenyl, substituted or unsubstituted, cyclic C 5 -C 20 -Alkyl, substituted or unsubstituted C 6 -C 20 -aryl, substituted or unsubstituted C 2 -C 40 -alkyleneoxy, substituted or unsubstituted C 3 -C 40 -alkyleneoxyalkyl, substituted or unsubstituted C 6 -C 40 -alkylene-aryl, substituted or unsubstituted C 6 -C 32 aryloxy, substituted or unsubstituted C 6 -C 40 alkyleneoxyaryl, C 6 -C 40 oxyalkylene aryl, and mixtures thereof.
- fragrance precursors leads to shaped articles having an outstanding odor behavior in aqueous systems, in particular as regards the length and duration of the resulting fragrance impression, also on treated substrates, in particular textile.
- the combination of perfume precursors with the above-mentioned persistent fragrances and / or cationic polymer leads to films with excellent odor behavior.
- a shaped article according to the invention may preferably comprise fragrances selected from the group bergamot oil, tangerine oil, dimethyl anthranilate, dihydromyrcenol (2-methyl-6-methylene-2-octanol), Tetrahydrolinalool, isobomylacetate, ethyllinalool, limonene, orange oil, isobornylacetate, eucalyptus oil (globulus), aldehyde C 10, styrolylacetate, citronitrile ((Z, E) -methyl-5-phenyl-2-pentenitrile), undecavertol (4-methylbenzene) 3-decene-5-ol), styrolyl acetate, tartalide (acetyl hexamethyl tetralin).
- fragrances selected from the group bergamot oil, tangerine oil, dimethyl anthranilate, dihydromyrcenol (2-methyl-6-methylene-2
- a molded article of the invention may preferably comprise fragrances selected from the group consisting of aldehyde C 14, decalactone gamma, cyclamen aldehyde, troenan (5-methyl-5-propyl-2- (1-methylbutyl) -1,3-dioxane), canthoxal (2 Methyl 3- (para-methoxy-phenyl) -propanal), citronellol, geraniol, musk, phenylethyl alcohol, phenatez (2-phenylethyl 2-methylpropanoate), phenylethyl isobutyrate, jasmelia (2H-pyran-4-ol, 3-butyltetrahydro-5- methyl acetate), hexyl cinnamic aldehyde (alpha), ylang, cyclohexyl salicylate, hexenyl salicylate (cis-3), Sandelice, guaiacolite
- the shaped body according to the invention is substantially free of constituents other than perfume and polymer material. Accordingly, a shaped article according to the invention is accordingly ⁇ 65 wt%, ⁇ 70 wt%, ⁇ 75 wt%, ⁇ 80 wt%, ⁇ 85 wt%, ⁇ 90 wt%, ⁇ 95 wt .-% or even to ⁇ 98 wt .-% of the components polymer and perfume.
- Possible other constituents which may be present in the moldings according to the invention are advantageously selected from the group of surfactants, builders, bleaches, bleach activators, enzymes, electrolytes, non-aqueous solvents, pH adjusters, fluorescers, dyes, skincare agents, hydrotopes, softeners, foam inhibitors , Silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, corrosion inhibitors, antistatic agents, ironing aids, repellents and impregnating agents, swelling and anti-slip agents and UV absorbers.
- surfactants builders, bleaches, bleach activators, enzymes, electrolytes, non-aqueous solvents, pH adjusters, fluorescers, dyes, skincare agents, hydrotopes, softeners, foam inhibitors , Silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-s
- a further subject matter is a process for scenting or scent-enhancing an aqueous system, preferably a washing, cleaning or rinsing liquor, wherein at least one portion of the perfumed, water-soluble or water-dispersible, shaped body is removed from the scent medium delivery system according to the invention and these are removed from the aqueous system, in particular the wash liquor , admits.
- the scenting in connection with the machine textile washing the molding according to the invention can be placed directly in the washing drum or in the Waschmitielschublade.
- a further subject matter is a method for applying fragrances to textile goods in a washing machine by adding molded bodies according to the invention which have been taken from the fragrance medium dispensing system according to the invention, wherein the shaped bodies are added to the wet laundry in the washing or rinsing cycle of a machine washing process.
- a further subject matter is a method for applying fragrances to textile material in an automatic laundry drier by addition of shaped bodies according to the invention which have been taken from the fragrance medium dispensing system according to the invention, wherein the shaped articles are added to the wet laundry to be dried in the drier.
- a further subject of the present invention is the use of a shaped body removed from the fragrance medium delivery system according to the invention for scenting or Odor enhancement of an aqueous system, advantageously a textile washing liquor, a dishwashing wash liquor, bathing water or a cleaning liquid for cleaning hard surfaces, such as preferably floors or windows.
- scenting of a toilet porcelain standard sink is possible. To do this, place the molded body in the water of the siphon, where it then unfolds pleasant odors, for example, to cover already existing unpleasant odors.
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Description
Die Erfindung betrifft ein Duftmediumabgabesystem, welches einen parfümierten, polymerhaltigen Formkörper umfasst der in einem Entnahmebehältnis bereitgestellt ist.The invention relates to a fragrance medium delivery system comprising a perfumed, polymer-containing shaped article which is provided in a removal container.
Die Erfindung betrifft ferner die Verwendung des Duftmediumabgabesystems zur Dosierung von Duftmittel sowie ein Verfahren zur Beduftung wässriger Systeme.The invention further relates to the use of the fragrance medium dispensing system for dispensing fragrance and to a process for scenting aqueous systems.
Der Einsatz von Riechstoffen zur Erzeugung von Wohlgerüchen ist seit langer Zelt ein wichtiger Bestandtell menschlicher Kultur. Riechstoffe wurden beispielsweise sehr früh für sakrale oder kultische Zwecke eingesetzt. Ein Beispiel hierfür Ist die Verbrennung von Weihrauch. In der Regel sollen Riechstoffe dazu dienen, andere, als unangenehm empfundene Gerüche zu überdecken beziehungsweise angenehme, anziehende Gerüche hervorzubringen. Der Einsatz von Riechstoffen hat auch oft den Zweck, den Eindruck von Sauberkeit zu vermitteln.The use of fragrances to create fragrances has been an important element of human culture for a long time. For example, fragrances were used very early for sacred or ritual purposes. An example of this is the burning of frankincense. As a rule, fragrances are intended to mask other, perceived as unpleasant odors or produce pleasant, attractive odors. The use of fragrances also often has the purpose of giving the impression of cleanliness.
Auch die meisten Wasch- und Reinigungsprodukte enthalten Riechstoffe. Diese überdecken den originären Produktgeruch und sorgen für ein angenehmes Geruchsbild.Most washing and cleaning products also contain fragrances. These cover the original product smell and provide a pleasant smell.
Wie sich gezeigt hat, entfaltet der Verbraucher ein Bedürfnis nach immer neuen Düften, und entsprechend werden im Handel fortwährend neu beduftete Produkte angeboten.As has been shown, the consumer is developing a need for ever-new fragrances, and accordingly, new fragranced products are continually being offered in the trade.
Ein gewisser Mangel liegt jedoch darin, dass die im Handel angebotenen Produkte sehr einheitlich beduftet sind, was die Duftintensität anbetrifft. Die Duftintensität ist dabei abgestimmt auf die Bedürfnisse eines durchschnittlichen Verbrauchers. Entsprechend leiden Verbraucher, welche einen sehr ausgeprägten oder aber einen verminderten Wohlgeruchsbedarf haben, an der einheitlichen Produktbeduftung. Dies betrifft Insbesondere jene Produkte, wie Wasch- oder Reintgungsmiltel, welche Im Zusammenhang mit wässrigen Systemen angewendet werden.However, there is a certain shortcoming in the fact that the products offered on the market are very uniformly scented, as far as the intensity of the scent is concerned. The fragrance intensity is tailored to the needs of an average consumer. Accordingly, consumers who have a very pronounced or a reduced fragrance need to uniform product scenting. This particularly concerns those products, such as washing or cleaning agents, which are used in connection with aqueous systems.
Vor diesem Hintergrund lag die an die Erfindung gestellte Aufgabe darin, dem Verbraucher die individuelle Parfümierung wässriger Systeme zu ermöglichen. Diese Aufgabe wird vom Gegenstand der Erfindung gelöst.Against this background, the object of the invention was to enable the consumer to individually perfume aqueous systems. This object is solved by the subject matter of the invention.
Der Gegenstand der Erfindung ist ein Duftmediumabgabesystem, umfassend einen parfümierten, wasserlöslichen oder wasserdispergierbaren, Formkörper, welcher zumindest 20 Gew.-% Polymer(e) sowie zumindest 10 Gew.-% Riechstoffe enthält, Gew.-% jeweils bezogen auf den gesamten Formkörper, wobei der Formkörper in einem Entnahmebehältnis bereitgestellt ist, und wobei der Formkörper eine geschäumte Folie ist und wobei das im Formkörper enthaltene Parfüm zumindest zu 5 Gew.-% in verkapselter Form vorliegt.The subject matter of the invention is a fragrance medium delivery system comprising a perfumed, water-soluble or water-dispersible, shaped body which contains at least 20% by weight of polymer (s) and at least 10% by weight of fragrances,% by weight, based in each case on the entire shaped body, wherein the shaped body is provided in a dispensing container, and wherein the shaped body is a foamed sheet, and wherein the perfume contained in the shaped body is at least 5 wt .-% in encapsulated form.
Ein Duftmedium ist ein Medium, welches Riechstoffe trägt, im vorliegenden Fall handelt es sich um einen parfümierten Formkörper. Ein Duftmediumabgsbesystem Ist ein Gegenstand, der die, vorzugsweise dosierte bzw. portionierte, Abgabe des Duftmediums, also des parfümierten Formkörpers an den Verbraucher ermöglicht.A fragrance medium is a medium which carries fragrances, in the present case it is a perfumed shaped body. A Duftmediumabgsbesystem Is an object that allows the, preferably metered or portioned, delivery of the fragrance medium, so the perfumed molding to the consumer.
Der Polymeranteil des Formkörpers kann nach einer bevorzugten Ausführungsform auch deutlich über 20 Gew.-% liegen, z.B. bei einem Wert von zumindest 25 Gew.-%. 30 Gew.-%, 35 Gew.-%, 40 Gew.-%, 45 Gew.-%, 50 Gew.-%, 55 Gew.-%, 60 Gew.-%. 65 Gew.-%. 70 Gew.-% oder auch zumindest 75 Gew.-% oder sogar zumindest 80 Gew.-%, wobei Gew.-% auf den gesamten Formkörper bezogen Ist. Mögliche Obergrenzen für den Polymeranteil des Formkörpers können z.B. bei einem Wert von maximal 95 Gew.-%, 90 Gew.-%, 85 Gew.%, 80 Gew.-%, 75 Gew.-%, 70 Gew.-%, 65 Gew.-%, 60 Gew.-%. 55 Gew.-%, 50 Gew.-%, 45 Gew.-%, 40 Gew.%, 35 Gew.-% oder maximal 30 Gew.-% liegen.The polymer content of the molded article may, in a preferred embodiment, also be well above 20% by weight, e.g. at a value of at least 25% by weight. 30 wt%, 35 wt%, 40 wt%, 45 wt%, 50 wt%, 55 wt%, 60 wt%. 65% by weight. 70 wt .-% or at least 75 wt .-% or even at least 80 wt .-%, wherein wt .-% based on the total molding is. Possible upper limits for the polymer portion of the molded article may e.g. at a maximum value of 95% by weight, 90% by weight, 85% by weight, 80% by weight, 75% by weight, 70% by weight, 65% by weight, 60% by weight. %. 55 wt .-%, 50 wt .-%, 45 wt .-%, 40 wt.%, 35 wt .-% or at most 30 wt .-% are.
Der Polymeranteil des Formkörpers kann also z.B. im Bereich von 35 Gew.-% bis 70 Gew.-% liegen oder z.B. Im Bereich von 40 Gew.-% bis 80 Gew.-%, usw.The polymer content of the molded article may therefore be e.g. in the range of from 35% to 70% by weight, or e.g. Ranging from 40% to 80% by weight, etc.
Nach einer erheblich bevorzugten Ausführungsform ist der parfümierte Formkörper eine streifenförmige, blattförmige, scheibenförmige, oder bahnförmige, vorzugsweise flexible, Folie.According to a considerably preferred embodiment, the perfumed shaped body is a strip-shaped, sheet-shaped, disk-shaped, or web-shaped, preferably flexible, film.
Eine Folie ist ein dünnes, flächiges Material. In der Regel sind Folien mehr oder weniger flexibel, wobei ihre Flexibilität sowohl von der Dicke der Folienbahn als auch von der Art des eingesetzten Rohstoffs abhängig ist. Bei sehr steifen Produkten spricht man im allgemeinen Sprachgebrauch oft nicht mehr von Folien, sondern eher von Platten. Erfindungsgemäß sind auch Platten umfasst. Die Dicken der Folien können vorzugsweise zwischen etwa 1 und 500 µm liegen. Es sind auch noch dünnere Folien möglich, welche man dann als Membranen bezeichnet. Auch diese sind von der Erfindung umfasst. Es sind auch noch dickere Folien mit Dicken > 500 µm möglich. Auch diese sind von der Erfindung umfasst.A foil is a thin, flat material. As a rule, films are more or less flexible, their flexibility being dependent both on the thickness of the film web and on the type of raw material used. In the case of very stiff products, in general parlance, one often no longer speaks of films, but rather of plates. According to the invention, plates are also included. The thicknesses of the films may preferably be between about 1 and 500 microns. There are also thinner films possible, which are then called membranes. These too are encompassed by the invention. There are also thicker films with thicknesses> 500 microns possible. These too are encompassed by the invention.
Bevorzugte Foliendicken liegen z.B. bei Werten < 400 µm, < 300 µm, < 200 µm oder auch kleiner < 100 µm. Es sind auch Dicken von z.B. < 80 µm, < 60 µm oder < 40 µm möglich.Preferred film thicknesses are e.g. at values <400 μm, <300 μm, <200 μm or even smaller <100 μm. Thicknesses of e.g. <80 μm, <60 μm or <40 μm possible.
Mögliche Mindestdicken können beispielsweise bei Werten wie z.B. 2, 3, 4, 5, 6, 7, 8, 9 oder 10 µm liegen. Es sind auch Mindestdicken von z.B. 15, 20, 25, 30, 35, 40, 45 oder 50 µm möglich, sogar Werte von wenigstens 60, 70, 80, 90, 100, 150 oder 200 µm sind möglich.Possible minimum thicknesses may be, for example, values such as e.g. 2, 3, 4, 5, 6, 7, 8, 9 or 10 microns are. There are also minimum thicknesses of e.g. 15, 20, 25, 30, 35, 40, 45 or 50 microns possible, even values of at least 60, 70, 80, 90, 100, 150 or 200 microns are possible.
Eine erfindungsgemäße Folie kann demnach z.B. eine Dicke von 3 bis < 200 µm oder z.B. von 20 bis < 80 µm aufweisen, um nur 2 Beispiele zu nennen.Accordingly, a film according to the invention may accordingly have, for example, a thickness of from 3 to <200 μm or, for example, from 20 to <80 μm, to name only two examples.
Die Länge-Breite-Abmessungen einer bevorzugten streifenförmigen, blattförmigen, scheibenförmigen oder bahnförmigen Folie, können (unabhängig voneinander) betragen:
- (a) in der Länge vorzugsweise 1cm bis 30 cm, vorteilhafterweise 2cm bis 20 cm, in weiter vorteilhafter Weise 3 cm bis 15 cm, insbesondere 4 cm bis 10 cm,
- (b) in der Breite vorzugsweise 1 cm bis 25 cm, vortellhafterweise 2 cm bis 20 cm, in weiter vorteilhafter Weise 3 cm bis 15 cm, insbesondere 4 cm bis 10 cm.
- (a) preferably 1 cm to 30 cm in length, advantageously 2 cm to 20 cm, more preferably 3 cm to 15 cm, in particular 4 cm to 10 cm,
- (b) preferably 1 cm to 25 cm in width, preferably 2 cm to 20 cm in width, more preferably 3 cm to 15 cm, in particular 4 cm to 10 cm.
Die Mindestlänge der Folie kann auch bei 5, 6, 7 oder 8 cm liegen. Die Mindeslbreite der Folie kann ebenfalls bei 5, 6, 7 oder 8 cm liegen.The minimum length of the film can also be 5, 6, 7 or 8 cm. The minimum width of the film can also be 5, 6, 7 or 8 cm.
Eine erfindungsgemäße Folie kann jede Form haben, beispielsweise quadratisch, rechteckig, dreieckig, oval, kreisförmig. Es sind auch Sonderformen möglich, beispielsweise Herzform, Zahlenform oder Buchstabenform.A film of the invention may have any shape, for example, square, rectangular, triangular, oval, circular. There are also special forms possible, such as heart shape, number form or letter form.
Die erfindungsgemäßen Folien, können transparent oder undurchsichtig sein. Es kann sich z.B. um Solo- oder Verbundfolien handeln.The films of the invention may be transparent or opaque. It can be e.g. to act solo or composite foils.
Während so genannte Verbundfolien, z.B. PA/PE-Folien, mehrere Schichten verschiedener Materialien aufweisen, z.B. eine PA- und eine PE-Schicht, bestehen Solofolien nur aus einem einheitlichen Folienmaterial, das natürlich eine Mischung verschiedener Stoffe, insbesondere eine Polymermischung, umfassen kann. Sowohl Solo- wie Verbundfolien sind von der Erfindung umfasst.While so-called composite films, e.g. PA / PE films, multiple layers of different materials, e.g. a PA and a PE layer, solofilms consist only of a uniform film material, which of course may comprise a mixture of different substances, in particular a polymer mixture. Both solo and composite films are encompassed by the invention.
Wenn Folien aus zwei Schichten des gleichen Materials bestehen, werden sie als Doppelfolien bezeichnet. Ein wesentlicher Grund für die Herstellung von Doppelfolien kann die Erzeugung größerer Foliendicken sein. Eine Variante hierbei ist die Coextrusion von zwei Schichten eines Thermoplasten als Alternative zu einer einzigen dickeren Schicht. Auch Doppelfolien sind von der Erfindung umfasst.If films consist of two layers of the same material, they are called double films. A major reason for the production of double films may be the generation of larger film thicknesses. A variant here is the coextrusion of two layers of a thermoplastic as an alternative to a single thicker layer. Double foils are also included in the invention.
Nach einer bevorzugten Ausführungsform der Erfindung sind die erfindungsgemäßen Folien mehrschichtig ausgebildet.According to a preferred embodiment of the invention, the films according to the invention are multilayered.
Die erfindungsgemäßen Formkörper können ein einzelnes Polymer oder einen Blend verschiedener Polymere umfassen. In bevorzugten Fällen umfasst der Formkörper ein oder mehrere Materialien aus der Gruppe (gegebenenfalls acetalisierter) Polyvinylalkohol (PVAL) und/oder PVAL-Copolymere, Polyvinylpyrrolidon, Polyethylenoxid, Polyethylenglykol, Gelatine, Cellulose und deren Derivate; insbesondere MC, HEC, HPC, HPMC und/oder CMC, und/oder Copolymere sowie deren Mischungen. Ggf. können den Formkörpern dem Fachmann bekannte Weichmacher zur Erhöhung der Flexibilität des Materials oder andere Hilfs- oder Zusatzstoffe beigemischt sein.The shaped articles according to the invention may comprise a single polymer or a blend of different polymers. In preferred cases, the shaped body comprises one or more materials from the group (optionally acetalized) polyvinyl alcohol (PVAL) and / or PVAL copolymers, polyvinylpyrrolidone, polyethylene oxide, polyethylene glycol, gelatin, cellulose and derivatives thereof; in particular MC, HEC, HPC, HPMC and / or CMC, and / or copolymers and mixtures thereof. Possibly. can the moldings known to the expert Softener to increase the flexibility of the material or other auxiliaries or additives mixed.
Im Rahmen der vorliegenden Erfindung sind Polyvinylalkohole als wasserlösliche Polymere ganz besonders bevorzugt. "Polyvinylalkohole" (Kurzzeichen PVAL, gelegentlich auch PVOH) ist dabei die Bezeichnung für Polymere der allgemeinen Struktur
Handelsübliche Polyvinylalkohole, die als weiß-gelbliche Pulver oder Granulate mit Polymerisationsgraden im Bereich von ca. 100 bis 2500 (Molmassen von ca. 4000 bis 100.000 g/mol) angeboten werden, haben Hydrolysegrade von 98-99 bzw. 87-89 Mol-%, enthalten also noch einen Restgehalt an Acetyl-Gruppen. Charakterisiert werden die Polyvinylalkohole von Seiten der Hersteller durch Angabe des Polymerisationsgrades des Ausgangspolymeren, des Hydrolysegrades, der Verseifungszahl bzw. der Lösungsviskosität.Commercially available polyvinyl alcohols, which are available as white-yellowish powders or granules with degrees of polymerization in the range of about 100 to 2500 (molar masses of about 4000 to 100,000 g / mol), have degrees of hydrolysis of 98-99 or 87-89 mol%. , so still contain a residual content of acetyl groups. The polyvinyl alcohols are characterized by the manufacturer by indicating the degree of polymerization of the starting polymer, the degree of hydrolysis, the saponification number or the solution viscosity.
Polyvinylalkohole sind abhängig vom Hydrolysegrad löslich in Wasser und wenigen stark polaren organischen Lösungsmitteln (Formamid, Dimethylformamid, Dimethylsulfoxid); von (chlorierten) Kohlenwasserstoffen, Estern, Fetten und Ölen werden sie nicht angegriffen. Polyvinylalkohole werden als toxikologisch unbedenklich eingestuft und sind biologisch zumindest teilweise abbaubar. Die Wasserlöslichkeit kann man durch Nachbehandlung mit Aldehyden (Acetalisierung), durch Komplexierung mit Ni- oder Cu-Salzen oder durch Behandlung mit Dichromaten, Borsäure od. Borax verringern. Polyvinylalkohol ist weitgehend undurchdringlich für Gase wie Sauerstoff, Stickstoff, Helium, Wasserstoff, Kohlendioxid, lässt jedoch Wasserdampf hindurchtreten.Depending on the degree of hydrolysis, polyvinyl alcohols are soluble in water and a few highly polar organic solvents (formamide, dimethylformamide, dimethyl sulfoxide); They are not attacked by (chlorinated) hydrocarbons, esters, fats and oils. Polyvinyl alcohols are classified as toxicologically safe and are biologically at least partially degradable. The water solubility can be reduced by aftertreatment with aldehydes (acetalization), by complexation with Ni or Cu salts or by treatment with dichromates, boric acid or borax. Polyvinyl alcohol is largely impermeable to gases such as oxygen, nitrogen, helium, hydrogen, carbon dioxide, but allows water vapor to pass through.
Im Rahmen der vorliegenden Erfindung bevorzugte Formkörper sind dadurch gekennzeichnet, dass sie Polyvinylalkohole und/oder PVAL-Copolymere umfassen, deren Hydrolysegrad 70 bis 100 Mol-%, vorzugsweise 80 bis 90 Mol-%, besonders bevorzugt 81 bis 89 Mol-% und insbesondere 82 bis 88 Mol-% beträgt.Moldings which are preferred in the context of the present invention are characterized in that they comprise polyvinyl alcohols and / or PVAL copolymers whose degree of hydrolysis is 70 to 100 mol%, preferably 80 to 90 mol%, particularly preferably 81 to 89 mol% and in particular 82 to 88 mol%.
Vorzugsweise werden Polyvinylalkohole eines bestimmten Molekulargewichtsbereichs eingesetzt, wobei erfindungsgemäße Verfahren bevorzugt sind, bei denen der Formkörper Polyvinylalkohole und/oder PVAL-Copolymere umfasst, deren Molekulargewicht im Bereich von 3.500 bis 100.000 gmol-1, vorzugsweise von 10.000 bis 90.000 gmol-1, besonders bevorzugt von 12.000 bis 80.000 gmol-1 und insbesondere von 13.000 bis 70.000 gmol-1 liegt.Preference is given to using polyvinyl alcohols having a specific molecular weight range, preference being given to processes according to the invention in which the molded body comprises polyvinyl alcohols and / or PVAL copolymers whose molecular weight is in the range from 3,500 to 100,000 gmol -1 , preferably from 10,000 to 90,000 gmol -1 , more preferably from 12,000 to 80,000 gmol -1 and in particular from 13,000 to 70,000 gmol -1 .
Der Polymerisationsgrad solcher bevorzugten Polyvinylalkohole liegt zwischen ungefähr 200 bis ungefähr 2100, vorzugsweise zwischen ungefähr 220 bis ungefähr 1890, besonders bevorzugt zwischen ungefähr 240 bis ungefähr 1680 und insbesondere zwischen ungefähr 260 bis ungefähr 1500.The degree of polymerization of such preferred polyvinyl alcohols is between about 200 to about 2100, preferably between about 220 to about 1890, more preferably between about 240 to about 1680, and most preferably between about 260 to about 1500.
Erfindungsgemäß bevorzugte Formkörper sind dadurch gekennzeichnet, dass der Formkörper Polyvinylalkohole und/oder PVAL-Copolymere umfasst, deren durchschnittlicher Polymerisationsgrad zwischen 80 und 700, vorzugsweise zwischen 150 und 400, besonders bevorzugt zwischen 180 bis 300 liegt und/oder deren Molekulargewichtsverhältnis MG(50%) zu MG(90%) zwischen 0,3 und 1, vorzugsweise zwischen 0,4 und 0,8 und insbesondere zwischen 0,45 und 0,6 liegt.Shaped bodies preferred according to the invention are characterized in that the shaped body comprises polyvinyl alcohols and / or PVAL copolymers whose average degree of polymerization is between 80 and 700, preferably between 150 and 400, more preferably between 180 and 300 and / or their molecular weight ratio MW (50%). to MG (90%) is between 0.3 and 1, preferably between 0.4 and 0.8 and in particular between 0.45 and 0.6.
Die vorstehend beschriebenen Polyvinylalkohole sind kommerziell breit verfügbar, beispielsweise unter dem Warenzeichen Mowiol® (Clariant). Im Rahmen der vorliegenden Erfindung besonders geeignete Polyvinylalkohole sind beispielsweise Mowiol® 3-83, Mowiol® 4-88, Mowiol® 5-88 sowie Mowiol® 8-88.The polyvinyl alcohols described above are widely available commercially, for example under the trade name Mowiol ® (Clariant). In the present invention, particularly suitable polyvinyl alcohols are, for example, Mowiol ® 3-83, Mowiol ® 4-88, Mowiol ® 5-88 and Mowiol ® 8-88.
Weitere als Material für die Formkörper besonders geeignete Polyvinylalkohole sind der nachstehenden Tabelle zu entnehmen:
Weitere als Material für die Formkörper geeignete Polyvinylalkohole sind ELVANOL® 51-05, 52-22, 50-42, 85-82, 75-15, T-25, T-66, 90-50 (Warenzeichen der Du Pont), ALCOTEX® 72.5, 78, B72, F80/40, F88/4, F88/26, F88/40, F88/47 (Warenzeichen der Harlow Chemical Co.), Gohsenol® NK-05, A-300, AH-22, C-500, GH-20, GL-03, GM-14L, KA-20, KA-500, KH-20, KP-06, N-300, NH-26, NM11Q, KZ-06 (Warenzeichen der Nippon Gohsei K.K.). Auch geeignet sind ERKOL-Typen von Wacker.Other suitable as a material for the shaped bodies are polyvinyl alcohols ® ELVANOL 51-05, 52-22, 50-42, 85-82, 75-15, T-25, T-66, 90-50 (trademark of Du Pont), ALCOTEX ® 72.5, 78, B72, F80 / 40, F88 / 4, F88 / 26, F88 / 40, F88 / 47 (trademark of Harlow Chemical Co.), Gohsenol ® NK-05, A-300, AH-22, C -500, GH-20, GL-03, GM-14L, KA-20, KA-500, KH-20, KP-06, N-300, NH-26, NM11Q, KZ-06 (Trademark of Nippon Gohsei KK ). Also suitable are ERKOL types from Wacker.
Eine weiter bevorzugte Gruppe wasserlöslicher Polymere, die erfindungsgemäß in den Formkörpern enthalten sein können, sind die Polyvinylpyrrolidone. Diese werden beispielsweise unter der Bezeichnung Luviskol® (BASF) vertrieben. Polyvinylpyrrolidone [Poly(1-vinyl-2-pyrrolidinone)], Kurzzeichen PVP, sind Polymere der allg. Formel (I)
Geeignet sind auch Copolymere des Vinylpyrrolidons mit anderen Monomeren, insbesondere Vinylpyrrolidon/Vinylester-Copolymere, wie sie beispielsweise unter dem Warenzeichen Luviskol® (BASF) vertrieben werden. Luviskol® VA 64 und Luviskol® VA 73, jeweils Vinylpyrrolidon/Vinylacetat-Copolymere, sind besonders bevorzugte nichtionische Polymere.Also suitable are copolymers of vinylpyrrolidone with other monomers, in particular vinylpyrrolidone / Vinylester copolymers, such as for example, under the trade name Luviskol ® (BASF). Luviskol ® VA 64 and Luviskol ® VA 73, each vinylpyrrolidone / vinyl acetate copolymers, are particularly preferred non-ionic polymers.
Die Vinylester-Polymere sind aus Vinylestern zugängliche Polymere mit der Gruppierung der Formel (II)
Die Polymerisation der Vinylester erfolgt radikalisch nach unterschiedlichen Verfahren (Lösungspolymerisation, Suspensionspolymerisation, Emulsionspolymerisation, Substanzpolymerisation). Copolymere von Vinylacetat mit Vinylpyrrolidon enthalten Monomereinheiten der Formeln (I) und (II).The polymerization of the vinyl esters is carried out free-radically by different processes (solution polymerization, suspension polymerization, emulsion polymerization, bulk polymerization). Copolymers of vinyl acetate with vinylpyrrolidone contain monomer units of the formulas (I) and (II).
Weitere geeignete wasserlösliche Polymere sind die Polyethylenglykole (Polyethylenoxide), die kurz als PEG bezeichnet werden. PEG sind Polymere des Ethylenglycols, die der allgemeinen Formel (III)
H-(O-CH2-CH2)n-OH (III)
genügen, wobei n Werte zwischen 5 und > 100.000 annehmen kann.Further suitable water-soluble polymers are the polyethylene glycols (polyethylene oxides), which are referred to as PEG for short. PEG are polymers of ethylene glycol which are of the general formula (III)
H- (O-CH 2 -CH 2 ) n -OH (III)
satisfy, where n can take values between 5 and> 100,000.
PEGs werden technisch hergestellt durch anionische Ringöffnungspolymerisation von Ethylenoxid (Oxiran) meist in Gegenwart geringer Mengen Wasser. Sie haben je nach Reaktionsführung Molmassen im Bereich von ca. 200-5 000 000 g/mol, entsprechend Polymerisationsgraden von ca. 5 bis > 100 000.PEGs are prepared industrially by anionic ring-opening polymerization of ethylene oxide (oxirane), usually in the presence of small amounts of water. Depending on the reaction procedure, they have molar masses in the range of about 200-5,000,000 g / mol, corresponding to degrees of polymerization of about 5 to> 100,000.
Die Produkte mit Molmassen < ca. 25 000 g/mol sind bei Raumtemperatur flüssig wund werden als eigentliche Polyethylenglycole, Kurzzeichen PEG, bezeichnet. Diese kurzkettigen PEGs können insbesondere anderen wasserlöslichen Polymeren, z.B. Polyvinvlalkoholen oder Celluloseethern als Weichmacher zugesetzt werden. Die erfindungsgemäß einsetzbaren, bei Raumtemperatur festen Polyethylenglycole werden als Polyethylenoxide, Kurzzeichen PEOX, bezeichnet. Hochmolekulare Polyethylenoxide besitzen eine äußerst niedrige Konzentration an reaktiven Hydroxy-Endgruppen und zeigen daher nur noch schwache Glykol-Eigenschaften.The products with molecular weights <about 25 000 g / mol are liquid sore at room temperature are referred to as actual polyethylene glycols, abbreviated PEG. These short-chain PEGs can be used in particular other water-soluble polymers, e.g. Polyvinvlalkoholen or cellulose ethers are added as plasticizer. The polyethyleneglycols which can be used according to the invention and which are solid at room temperature are termed polyethylene oxides, abbreviated PEOX. High molecular weight polyethylene oxides have an extremely low concentration of reactive hydroxy end groups and therefore show only weak glycol properties.
Weiter als Material für den Formkörper geeignet ist erfindungsgemäß auch Gelatine, wobei diese vorzugsweise mit anderen Polymeren zusammen eingesetzt wird. Gelatine ist ein Polypeptid (Molmasse: ca. 15.000 bis >250.000 g/mol), das vornehmlich durch Hydrolyse des in Haut und Knochen von Tieren enthaltenen Kollagens unter sauren oder alkalischen Bedingungen gewonnen wird. Die Aminosäuren-Zusammensetzung der Gelatine entspricht weitgehend der des Kollagens, aus dem sie gewonnen wurde und variiert in Abhängigkeit von dessen Prövenienz. Die Verwendung von Gelatine als wasserlösliches Hüllmaterial ist insbesondere in der Pharmazie in Form von Hart- oder Weichgelatinekapseln äußerst weit verbreitet. In Form von Folien findet Gelatine wegen ihres im Vergleich zu den vorstehend genannten Polymeren hohen Preises im allgemeinen nur geringe Verwendung.Further suitable as a material for the molding according to the invention is also gelatin, which is preferably used together with other polymers. Gelatin is a polypeptide (molecular weight: about 15,000 to> 250,000 g / mol), which is obtained primarily by hydrolysis of the collagen contained in the skin and bones of animals under acidic or alkaline conditions. The amino acid composition of gelatin largely corresponds to that of the collagen from which it was obtained and varies depending on its prevalence. The use of gelatin as water-soluble coating material is extremely widespread, especially in pharmacy in the form of hard or soft gelatin capsules. In the form of films, gelatin generally has little use because of its high price compared to the polymers mentioned above.
Weitere erfindungsgemäß geeignete wasserlösliche Polymere werden nachstehend beschrieben:
- Celluloseether, wie Hydroxypropylcellulose, Hydroxyethylcellulose und Methylhydroxypropylcellulose, wie sie beispielsweise unter den Warenzeichen Culminal® und Benecel® (AQUALON) vertrieben werden.
Celluloseether lassen sich durch die allgemeine Formel (IV) beschreiben,
- Cellulose ethers, such as hydroxypropylcellulose, hydroxyethylcellulose and methylhydroxypropylcellulose, as sold, for example, under the trademarks Culminal ® and Benecel ® (AQUALON).
Cellulose ethers can be described by the general formula (IV)
Bevorzugte erfindungsgemäße Formkörper sind dadurch gekennzeichnet, dass sie Hydroxypropylmethylcellulose (HPMC) umfassen, die einen Substitutionsgrad (durchschnittliche Anzahl von Methoxygruppen pro Anhydroglucose-Einheit der Cellulose) von 1,0 bis 2,0, vorzugsweise von 1,4 bis 1,9, und eine molare Substitution (durchschnittliche Anzahl von Hydroxypropoxylgruppen pro Anhydroglucose-Einheit der Cellulose) von 0,1 bis 0,3, vorzugsweise von 0,15 bis 0,25, aufweist.Preferred shaped bodies according to the invention are characterized in that they comprise hydroxypropylmethylcellulose (HPMC) which has a degree of substitution (average number of methoxy groups per anhydroglucose unit of the cellulose) of from 1.0 to 2.0, preferably from 1.4 to 1.9, and a molar substitution (average number of hydroxypropoxyl groups per anhydroglucose unit of cellulose) of from 0.1 to 0.3, preferably from 0.15 to 0.25.
Weitere erfindungsgemäß geeignete Polymere sind wasserlösliche Amphopolymere. Unter dem Oberbegriff Ampho-Polymere sind amphotere Polymere, d.h. Polymere, die im Molekül sowohl freie Aminogruppen als auch freie -COOH- oder SO3H-Gruppen enthalten und zur Ausbildung innerer Salze befähigt sind, zwitterionische Polymere, die im Molekül quartäre Ammoniumgruppen und -COO-- oder -SO3 --Gruppen enthalten, und solche Polymere zusammengefasst, die -COOH- oder SO3H-Gruppen und quartäre Ammoniumgruppen enthalten. Ein Beispiel für ein erfindungsgemäß einsetzbares Amphopolymer ist das unter der Bezeichnung Amphomer® erhältliche Acrylharz, das ein Copolymer aus tert.-Butylaminoethylmethacrylat, N-(1,1,3,3-Tetramethylbutyl)acrylamid sowie zwei oder mehr Monomeren aus der Gruppe Acrylsäure, Methacrylsäure und deren einfachen Estern darstellt. Ebenfalls bevorzugte Amphopolymere setzen sich aus ungesättigten Carbonsäuren (z.B. Acryl- und Methacrylsäure), kationisch derivatisierten ungesättigten Carbonsäuren (z.B. Acrylamidopropyl-trimethyl-ammoniumchlorid) und gegebenenfalls weiteren ionischen oder nichtionogenen Monomeren zusammen. Terpolymere von Acrylsäure, Methylacrylat und Methacrylamidopropyltrimoniumchlorid, wie sie unter der Bezeichnung Merquat®2001 N im Handel erhältlich sind, sind erfindungsgemäß besonders bevorzugte Ampho-Polymere. Weitere geeignete amphotere Polymere sind beispielsweise die unter den Bezeichnungen Amphomer® und Amphomer® LV-71 (DELFT NATIONAL) erhältlichen Octylacrylamid/Methylmethacrylat/tert.-Butylaminoethylmethacrylat/2-Hydroxypropylmethacrylat-Copolymere.Further polymers which are suitable according to the invention are water-soluble amphopolymers. Amphoteric polymers, ie polymers which contain both free amino groups and free -COOH or SO 3 H groups in the molecule and are capable of forming internal salts, are zwitterionic polymers which contain quaternary ammonium groups in the molecule. COO - - or -SO 3 - groups, and summarized those polymers containing -COOH or SO 3 H groups and quaternary ammonium groups. An example of the present invention amphopolymer suitable is the acrylic resin commercially available as Amphomer ® is a copolymer of tert-butylaminoethyl methacrylate, N- (1,1,3,3-tetramethylbutyl) -acrylamide and two or more monomers from the group of acrylic acid, Represents methacrylic acid and its simple esters. Likewise preferred amphopolymers are composed of unsaturated carboxylic acids (eg, acrylic and methacrylic acid), cationically derivatized unsaturated carboxylic acids (eg, acrylamidopropyltrimethylammonium chloride), and optionally further ionic or nonionogenic monomers together. Terpolymers of acrylic acid, methyl acrylate and methacrylamidopropyltrimonium as they are commercially available under the name Merquat ® 2001 N, are inventively particularly preferred amphopolymers. Other suitable amphoteric polymers are for example sold under the names Amphomer ® and Amphomer ® LV-71 (DELFT NATIONAL) available octylacrylamide / methyl methacrylate / tert-butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers.
Erfindungsgemäß geeignete wasserlösliche anionische Polymere sind u. a.:
- Vinylacetat/Crotonsäure-Copolymere, wie sie beispielsweise unter den Bezeichnungen Resyn® (NATIONAL STARCH), Luviset® (BASF) und Gafset® (GAF) im Handel sind.
Diese Polymere weisen neben Monomereinheiten der vorstehend genannten Formel (II) auch Monomereinheiten der allgemeinen Formel (V) auf:
[-CH(CH3)-CH(COOH)-]n (V)
- VinylpyrrolidonNinylacrylat-Copolymere, erhältlich beispielsweise unter dem Warenzeichen Luviflex® (BASF). Ein bevorzugtes Polymer ist das unter der Bezeichnung Luviflex® VBM-35 (BASF) erhältliche Vinylpyrrolidon/Acrylat-Terpolymere.
- Acrylsäure/Ethylacrylat/N-tert.Butylacrylamid-Terpolymere, die beispielsweise unter der Bezeichnung Ultrahold® strong (BASF) vertrieben werden.
- Pfropfpolymere aus Vinylestern, Estern von Acrylsäure oder Methacrylsäure allein oder im Gemisch, copolymerisiert mit Crotonsäure, Acrylsäure oder Methacrylsäure mit Polyalkylenoxiden und/oder Polykalkylenglycolen.
- Vinyl acetate / crotonic acid copolymers, such as those sold under the names Resyn ® (National Starch), Luviset ® (BASF) and Gafset ® (GAF) are commercially available.
These polymers also have monomer units of the formula (II) above
[-CH (CH 3 ) -CH (COOH) -] n (V)
- Vinyl pyrrolidone copolymers, available, for example under the trade name Luviflex ® (BASF). A preferred polymer is the VBM-35 (BASF) under the name Luviflex ® available vinylpyrrolidone / acrylate terpolymers.
- Acrylic acid / ethyl acrylate / N-tert.butyl acrylamide terpolymers, for example, under the name Ultrahold ® strong (BASF).
- Graft polymers of vinyl esters, esters of acrylic acid or methacrylic acid, alone or in admixture, copolymerized with crotonic acid, acrylic acid or methacrylic acid with polyalkylene oxides and / or polyalkylene glycols.
Solche gepfropften Polymere von Vinylestern, Estern von Acrylsäure oder Methacrylsäure allein oder im Gemisch mit anderen copolymerisierbaren Verbindungen auf Polyalkylenglycolen werden durch Polymerisation in der Hitze in homogener Phase dadurch erhalten, dass man die Polyalkylenglycole in die Monomeren der Vinylester, Ester von Acrylsäure oder Methacrylsäure, in Gegenwart von Radikalbildner einrührt.Such grafted polymers of vinyl esters, esters of acrylic acid or methacrylic acid alone or in admixture with other copolymerizable compounds on polyalkylene glycols are obtained by homogeneous-phase polymerization by reacting the polyalkylene glycols in the monomers of vinyl esters, esters of acrylic acid or methacrylic acid, in The presence of free radical initiator stirs.
Als geeignete Vinylester haben sich beispielsweise Vinylacetat, Vinylpropionat, Vinylbutyrat, Vinylbenzoat und als Ester von Acrylsäure oder Methacrylsäure diejenigen, die mit aliphatischen Alkoholen mit niedrigem Molekulargewicht, also insbesondere Ethanol, Propanol, Isopropanol, 1-Butanol, 2-Butanol, 2-Methy-1-Propanol, 2-Methyl-2-Propanol, 1-Pentanol, 2-Pentanol, 3-Pentanol, 2,2-Dimethyl-1-Propanol, 3-Methyl-1-butanol; 3-Methyl-2-butanol, 2-Methyl-2-butanol, 2-Methyl-1-Butanol, 1-Hexanol, erhältlich sind, bewährt.Suitable vinyl esters are, for example, vinyl acetate, vinyl propionate, vinyl butyrate, vinyl benzoate and as esters of acrylic acid or methacrylic acid those with aliphatic alcohols of low molecular weight, ie in particular ethanol, propanol, isopropanol, 1-butanol, 2-butanol, 2-methyl 1-propanol, 2-methyl-2-propanol, 1-pentanol, 2-pentanol, 3-pentanol, 2,2-dimethyl-1-propanol, 3-methyl-1-butanol; 3-methyl-2-butanol, 2-methyl-2-butanol, 2-methyl-1-butanol, 1-hexanol, are proven.
Polypropylenglycole (Kurzzeichen PPG) sind Polymere des Propylenglycols, die der allgemeinen Formel (VI)
Insbesondere können die auf Polyethylenglycole gepfropften Vinylacetatcopolymeren und die auf Polyethylenglycole gepfropften Polymeren von Vinylacetat und Crotonsäure eingesetzt werden.
- gepfropfte und vernetzte Copolymere aus der Copolymerisation von
- i) mindesten einem Monomeren vom nicht-ionischen Typ,
- ii) mindestens einem Monomeren vom ionischen Typ,
- iii) von Polyethylenglycol und
- iv) einem Vernetzer
- grafted and crosslinked copolymers from the copolymerization of
- i) at least one nonionic type monomer,
- ii) at least one ionic-type monomer,
- iii) of polyethylene glycol and
- iv) a crosslinker
Das verwendete Polyethylenglycol weist ein Molekulargewicht zwischen 200 und mehreren Millionen, vorzugsweise zwischen 300 und 30.000, auf.The polyethylene glycol used has a molecular weight between 200 and several million, preferably between 300 and 30,000.
Die nicht-ionischen Monomeren können von sehr unterschiedlichem Typ sein und unter diesen sind folgende bevorzugt: Vinylacetat, Vinylstearat, Vinyllaurat, Vinylpropionat, Allylstearat, Allyllaurat, Diethylmaleat, Allylacetat, Methylmethacrylat, Cetylvinylether, Stearylvinylether und 1-Hexen.The nonionic monomers may be of very different types and of these preferred are: vinyl acetate, vinyl stearate, vinyl laurate, vinyl propionate, allyl stearate, allylaurate, diethyl maleate, allyl acetate, methyl methacrylate, cetyl vinyl ether, stearyl vinyl ether and 1-hexene.
Die nicht-ionischen Monomeren können gleichermaßen von sehr unterschiedlichen Typen sein, wobei unter diesen besonders bevorzugt Crotonsäure, Allyloxyessigsäure, Vinylessigsäure, Maleinsäure, Acrylsäure und Methacrylsäure in den Pfropfpolameren enthalten sind.The non-ionic monomers may equally be of very different types, among which particularly preferably crotonic acid, allyloxyacetic acid, vinylacetic acid, maleic acid, acrylic acid and methacrylic acid are contained in the grafting polymers.
Als Vernetzer werden vorzugsweise Ethylenglycoldimethacrylat, Diallylphthalat, ortho-, meta- und para-Divinylbenzol, Tetraallyloxyethan und Polyallylsaccharosen mit 2 bis 5. Allylgruppen pro Molekül Saccharin eingesetzt.The crosslinkers used are preferably ethylene glycol dimethacrylate, diallyl phthalate, ortho-, meta- and para-divinylbenzene, tetraallyloxyethane and polyallyl sucrose having 2 to 5 allyl groups per molecule of saccharin.
Die vorstehend beschriebenen gepfropften und vernetzten Copolymere werden vorzugsweise gebildet aus:
- i) 5 bis 85 Gew.-% mindesten eine Monomeren vom nicht-ionischen Typ,
- ii) 3 bis 80 Gew.-% mindestens eines Monomeren vom ionischen Typ,
- iii) 2 bis 50 Gew.-%, vorzugsweise 5 bis 30 Gew.-% Polyethylenglycol und
- iv) 0,1 bis 8 Gew.-% eines Vernetzers, wobei der Prozentsatz des Vernetzers durch das Verhältnis der Gesamtgewichte von i), ii) und iii) ausgebildet ist.
- durch Copolymerisation mindestens eines Monomeren jeder der drei folgenden Gruppen erhaltene Copolymere:
- i) Ester ungesättigter Alkohole und kurzkettiger gesättigter Carbonsäuren und/oder Ester kurzkettiger gesättigter Alkohole und ungesättigter Carbonsäuren,
- ii) ungesättigte Carbonsäuren,
- iii) Ester langkettiger Carbonsäuren und ungesättigter Alkohole und/oder Ester aus den Carbonsäuren der Gruppe ii) mit gesättigten oder ungesättigten, geradkettigen oder verzweigten C8-18-Alkohols
- Terpolymere aus Crotonsäure, Vinylacetat und einem Allyl- oder Methallylester
Diese Terpolymere enthalten Monomereinheiten der allgemeinen Formeln (II) und (IV) (siehe oben) sowie Monomereinheiten aus einem oder mehreren Allyl- oder Methallyestern der Formel (VII):
- durch Copolymerisation mindestens eines Monomeren jeder der drei folgenden Gruppen erhaltene Copolymere:
- i) from 5 to 85% by weight of at least one nonionic type monomer,
- ii) from 3 to 80% by weight of at least one ionic-type monomer,
- iii) 2 to 50 wt .-%, preferably 5 to 30 wt .-% polyethylene glycol and
- iv) 0.1 to 8 wt% of a crosslinker, wherein the percentage of crosslinker is formed by the ratio of the total weights of i), ii) and iii).
- Copolymers obtained by copolymerization of at least one monomer of each of the following three groups:
- i) esters of unsaturated alcohols and short-chain saturated carboxylic acids and / or esters of short-chain saturated alcohols and unsaturated carboxylic acids,
- ii) unsaturated carboxylic acids,
- iii) esters of long-chain carboxylic acids and unsaturated alcohols and / or esters of the carboxylic acids of group ii) with saturated or unsaturated, straight-chain or branched C 8-18 -alcohols
- Terpolymers of crotonic acid, vinyl acetate and an allyl or methallyl ester
These terpolymers comprise monomer units of the general formulas (II) and (IV) (see above) and monomer units of one or more allyl or methallyl esters of the formula (VII):
- Copolymers obtained by copolymerization of at least one monomer of each of the following three groups:
Die vorstehend genannten Terpolymeren resultieren vorzugsweise aus der Copolymerisation von 7 bis 12 Gew.-% Crotonsäure, 65 bis 86 Gew.-%, vorzugsweise 71 bis 83 Gew.-% Vinylacetat und 8 bis 20 Gew.-%, vorzugsweise 10 bis 17 Gew.-% Allyl- oder Methallyletsre der Formel (VII).
- Tetra- und Pentapolymere aus
- i) Crotonsäure oder Allyloxyessigsäure
- ii) Vinylacetat oder Vinylpropionat
- iii) verzweigten Allyl- oder Methallylestern
- iv)Vinylethern, Vinylesterrn oder geradkettigen Allyl- oder Methallylestern
- Crotonsäure-Copolymere mit einem oder mehreren Monomeren aus der Gruppe Ethylen, Vinylben zol, Vinymethylether, Acrylamid und deren wasserlöslicher Salze
- Terpolymere aus Vinylacetat, Crotonsäure und Vinylestern einer gesättigten aliphatischen verzweig ten Monocarbonsäure.
- Tetra and pentapolymers from
- i) crotonic acid or allyloxyacetic acid
- ii) vinyl acetate or vinyl propionate
- iii) branched allyl or methallyl esters
- iv) vinyl ethers, Vinylesterrn or straight-chain allyl or methallyl esters
- Crotonic acid copolymers with one or more monomers from the group consisting of ethylene, vinylbenzene, vinyl methyl ether, acrylamide and their water-soluble salts
- Terpolymers of vinyl acetate, crotonic acid and vinyl esters of a saturated aliphatic branched th monocarboxylic acid.
Weitere erfindungsgemäß einsetzbare Polymere sind kationische Polymere. Unter den kationischen Polymeren sind dabei die permanent kationischen Polymere bevorzugt. Als "permanent kationisch" werden erfindungsgemäß solche Polymere bezeichnet, die unabhängig vom pH-Wert eine kationische Gruppe aufweisen. Dies sind in der Regel Polymere, die ein quartäres Stickstoffatom, beispielsweise in Form einer Ammoniumgruppe, enthalten.Further polymers which can be used according to the invention are cationic polymers. Among the cationic polymers, the permanent cationic polymers are preferred. According to the invention, "permanently cationic" refers to those polymers which have a cationic group independently of the pH. These are usually polymers containing a quaternary nitrogen atom, for example in the form of an ammonium group.
Bevorzugte kationische Polymere sind beispielsweise
- quaternisierte Callurose-Derivale, wie sie unter den Bezeichnungen Celquat® und Polymer JR® im Handel erhältlich sind, Die Verbindungen Celquat® H 100, Celquat® L 200 und Polymer JR®400 sind bevorzugte quaternierte Cellulose-Derivate.
- Polyslloxane mit quaternären Gruppen, wie beispielsweise die im Handel erhältlichen Produkte Q2-7224 (Hersteller: Dow Corning; ein stabilisiertes Trimethylsilylamodimethicon), Dow Corning® 929 Emulsion (enthaltend ein hydroxyl-amino-modifiziertes Silicon, das auch als Amodimethicone bezeichnet wird), SM-2059 (Hersteller: General Electric), SLM-55067 (Hersteller: Wacker) sowie Abil®-Quat 3270 und 3272 (Hersteller: Th. Goldschmidt: diquaternäre Polydime- thylsiloxane, Quaternium-80),
- Kationische Guar-Derivate, wie insbesondere die unter den Handelsnamen Cosmedia®)Guar und Jaguar® vertriebenen Produkte.
- Polymere Dimethyldiallylammonlumsalze und deren Copolymere mit Estern und Amiden von Acrylsäure und Methacrylsäure. Die unter den Bezeichnungen Merquat®100 (Poly(dimethyldiallylammoniumchlorid)) und Merquat®550 (Dimethyldiallylammoniumchlorid-Acrylamid-Copolymer) im Handel erhältlichen Produkte sind Beispiele für solche kationischen Polymere.
- Copolymere des Vinylpyrrolidons mit quaternierten Derivaten des Dialkylaminoacrylats und - methacrylats, wie beispielsweise mit Diethylsulfat quaternierte Vinylpyrrolidon-Dimethylaminomethacrylat-Copolymere. Solche Verbindungen sind unter den Bezeichnungen Gafquat®734 und Gafquat®755 Im Handel erhältlich.
- vinylpyrrolidon-Methoimidazoliniumchlorid-Copolymere, wie sie unter der Bezeichnung Luviquat® angeboten werden.
- quaternierter Polyvinylalkohol
- Polyquaternium 2,
- Polyquaternium 17,
- Polyquaternium 18 und
- Polyquaternium 27
- quaternized Callurose-Derivale, as are obtainable under the names of Celquat ® and Polymer JR ® commercially, The compounds Celquat ® H 100, Celquat L 200 and Polymer JR ® ® 400 are preferred quaternized cellulose derivatives.
- Polyslloxanes with quaternary groups, such as the commercially available products Q2-7224 (manufactured by Dow Corning, a stabilized trimethylsilylamodimethicone), Dow Corning® 929 emulsion (containing a hydroxylamino-modified silicone, also referred to as amodimethicones), SM -2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ® quat 3270 and 3272 (manufacturer: Th Goldschmidt. diquaternary Polydime- thylsiloxane, quaternium-80)
- Cationic guar derivatives, in particular the products sold under the trade name Cosmedia ®) and Guar Jaguar ®.
- Polymers Dimethyldiallylammonlumsalze and their copolymers with esters and amides of acrylic acid and methacrylic acid. Under the names Merquat ® 100 (Poly (dimethyldiallylammonium chloride)) and Merquat ® 550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of such cationic polymers.
- Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoacrylate and - methacrylate, such as diethyl sulfate quaternized vinylpyrrolidone-dimethylaminomethacrylate copolymers. Such compounds are sold under the names Gafquat ® 734 and Gafquat ® 755 commercially.
- vinylpyrrolidone methoimidazolinium chloride copolymers, as offered under the name Luviquat.RTM ®.
- quaternized polyvinyl alcohol
- Polyquaternium 2,
- Polyquaternium 17,
- Polyquaternium 18 and
- Polyquaternium 27
Erfindungsgemäß bevorzugte kationische Polymere sind quaternisierte Cellulose-Derivate sowie polymere Dimethyldiallylammoniumsalze und deren Copolymere. Kationische Cellulose-Derivate, insbesondere das Händelsptodukt Polymer®JR 400, sind ganz besonders bevorzugte kationische Polymere. Der Einsatz kationischer Polymere kann dazu beitragen, dass die Duftwirkung der Folie bei der Anwendung weiter verbessert wird. Insbesondere kann der Geruch eines bedufteten wässrigen Systems weiter verbessert werden, so dass der Duft länger vorhält und vorzugweise intensiver ist, bei gleicher eingesetzter Riechstoffmenge. Auch das Aufziehverhalten der Riechstoffe auf in/mit dem parfümierten wässrigen System behandelte Substrate, wie z.B. Textil, kann durch den Einsatz kationischer Polymere verbessert werden, so dass der Wohlgeruch des Substrates länger vorhält und vorzugsweise intensiver ist.Cationic polymers preferred according to the invention are quaternized cellulose derivatives and polymeric dimethyldiallylammonium salts and their copolymers. Cationic cellulose derivatives, in particular the Händelsptodukt Polymer ® JR 400, are very particularly preferred cationic polymers. The use of cationic polymers can help to further improve the scent effect of the film in use. In particular, the odor of a scented aqueous system can be further improved so that the fragrance lasts longer and is preferably more intense, with the same amount of fragrance used. Also the Aufziehverhalten the Fragrances on substrates treated in / with the perfumed aqueous system, such as textiles, can be improved by the use of cationic polymers, so that the fragrance of the substrate lasts longer and is preferably more intense.
Der Einsatz kationischer Polymere ist dann besonders wirkungsvoll, wenn vorzugsweise > 2 Gew.-%, vorleilhafterweise > 4 Gew.-%, insbesondere > 6 Gew.-% kationischer Polymere in dem Formkörper enthalten sind, Gew.-% bezogen auf den gesamten Formkörper. Obergrenzen können z.B. bei 30, 20 oder 10 Gew.-% kationischem Polymer, bezogen auf den gesamten Formkörper, liegen.The use of cationic polymers is particularly effective when preferably> 2 wt .-%, preferably> 4 wt .-%, in particular> 6 wt .-% of cationic polymers are contained in the molding, wt .-% based on the total molding , Upper limits may e.g. at 30, 20 or 10 wt .-% cationic polymer, based on the total molding.
Das Folienmalerial kann neben dem vorzugsweise wasserlöslichen Polymer bzw. dem wasserdispergierbaren Polymer weitere Inhaltsstoffe enthalten, welche insbesondere die Verarbeitbarkeit der Ausgangsmaterialien zur Folie verbessern. Hier sind insbesondere Weichmacher und Trennmittel zu nennen. Darüber hinaus können Farbstoffe sowie optische Aufheller in die Folie inkorporiert werden, um dort ästhetische Effekte zu erzielen.In addition to the preferably water-soluble polymer or the water-dispersible polymer, the film paint material may contain further ingredients which in particular improve the processability of the starting materials for the film. In particular, plasticizers and release agents should be mentioned here. In addition, dyes and optical brighteners can be incorporated into the film to achieve aesthetic effects there.
Geeignete Trennmittel, welche vorzugsweise auf die fertigen, getrockneten Folien aufgebracht werden können, sind z.B. Talkum, Stärke oder (physikalisch, chemisch und/oder enzymatisch) modifizierte Stärke sein. Geeignete chemische Modifikationen sind z.B. Vernetzung, Acetylierung, Veresterung, Hydroxyethylierung, Hydroxypropylierung, Phosphorylierung. Das vorzugsweise hydrophobe Trennmittel haftet insbesondere äußerlich an der Folie.Suitable release agents which may preferably be applied to the finished, dried films are e.g. Talc, starch or (physically, chemically and / or enzymatically) modified starch. Suitable chemical modifications are e.g. Crosslinking, acetylation, esterification, hydroxyethylation, hydroxypropylation, phosphorylation. The preferably hydrophobic release agent adheres in particular externally to the film.
Durch die Behandlung der Folien mit einem pulverförmigen Trennmittel kann ein mögliches Verkleben der Folien, z.B. als Folge von Lagerung oder hoher Luftfeuchtigkeit, wirkungsvoll verhindert werden.By treating the films with a powdery release agent, possible adhesion of the films, e.g. as a result of storage or high humidity, be effectively prevented.
Als Weichmacher lassen sich erfindungsgemäß insbesondere hydrophile, hochsiedende Flüssigkeiten einsetzen, wobei gegebenenfalls auch bei Raumtemperatur feste Stoffe als Lösung. Dispersion oder Schmelze eingesetzt werden können. Besonders bevorzugte Weichmacher stammen aus der Gruppe Glykol, Di-, Tri-, Tetra-, Penta-, Hexa-, Hepta-, Octa-, Nona-, Deca-, Undeca-, Dodecaethylenglycol, Glycerin, Neopentylglycol, Trimethylolpropan, Pentaerythrit, Mono-, Di-, Triglyceride, Tenside, insbesondere Niotenside, sowie deren Mischungen. Weichmacher werden vorzugsweise in Mengen von 1 bis 50 Gew.-%, vorzugsweise 2 bis 40 Gew.-%, Insbesondere 5 bis 30 Gew.-% eingesetzt. Obergrenzen können z.B. auch bei 20 oder 10 Gew.-% Weichmacher, bezogen auf den gesamten Formkörper, liegen.According to the invention, hydrophilic, high-boiling liquids can be used as the plasticizer, solids which may also be solid at room temperature being used as the solution. Dispersion or melt can be used. Particularly preferred plasticizers are selected from the group glycol, di-, tri-, tetra-, penta-, hexa-, hepta-, octa-, nona-, deca-, undeca-, dodecaethylene glycol, glycerol, neopentyl glycol, trimethylolpropane, pentaerythritol, mono -, di-, triglycerides, surfactants, in particular nonionic surfactants, and mixtures thereof. Plasticizers are preferably used in amounts of from 1 to 50% by weight, preferably from 2 to 40% by weight, in particular from 5 to 30% by weight. Upper limits may also be, for example, at 20 or 10% by weight of plasticizer, based on the total molding.
Als weitere Weichmacher kommen auch Tenside, insbesondere Niotenside, In Betracht.Surfactants, in particular nonionic surfactants, are also suitable as further plasticizers.
Weitere bevorzugt als Weichmacher einzusetzende Substanzen können Glycerincarbonat, Propylenglycol und Propylencarbonat sein.Further preferred substances to be used as plasticizers may be glycerol carbonate, propylene glycol and propylene carbonate.
Als zusätzliche Additive, die vorzugsweise in bei Raumtemperatur fester Form vorliegen, sind insbesondere hochdisperse Kieselsäuren geeignet. Hier bieten sich pyrogene Kieselsäuren wie das handelsüblich Aerosil® oder Fällungskieselsäuren an. Besonders bevorzugte erfinddungsgemäße Verfahren sind dadurch gekennzeichnet, dass als weitere Additive ein oder mehrere Materialien aus der Gruppe (vorzugsweise hochdisperse) Kieselsäure, Dispersionspulver, hochmolekulare Polyglycole, Stearinsäure und/oder Stearinsäuresalze, und/oder aus der Gruppe der anorganischen Salze wie Natriumsulfat, Calciumchlorid und/oder aus der Gruppe der Inclusionsbildner wie Urea, Cyclodextrin und/oder aus der Gruppe der Superabsorber wie (vorzugsweise vernetzte) Polyacrylsäure und/oder deren Salze wie Cabloc 5066/CTF sowie deren Mischungen, eingesetzt wird/werden.As additional additives, which are preferably in solid form at room temperature, especially highly disperse silicas are suitable. Here, pyrogenic silicas such as the commercially available Aerosil ® or precipitated silicas offer. Particularly preferred processes according to the invention are characterized in that as further additives one or more materials from the group (preferably finely divided) silica, dispersion powder, high molecular weight polyglycols, stearic acid and / or stearic acid salts, and / or from the group of inorganic salts such as sodium sulfate, calcium chloride and / or from the group of Inclusionbildner such as urea, cyclodextrin and / or from the group of superabsorbents such as (preferably crosslinked) polyacrylic acid and / or their salts such as Cabloc 5066 / CTF and mixtures thereof, is / are used.
Erfindungsgemäß bevorzugte Formkörper können Farbstoffe enthalten. Geeignete Farbstoffe, besitzen vorzugsweise eine hohe Lagerstabilität und Unempfindlichkeit gegenüber den übrigen Inhaltsstoffen der Mittel und gegen Licht sowie keine ausgeprägte Substantivität gegenüber den mit den farbstofhaltigen Mitteln zumindest mittelbar in Kontakt tretenden Substraten wie beispielsweise Textilien, Glas, Keramik oder Kunststoffgeschirr, um diese nicht anzufärben.Moldings preferred according to the invention may contain dyes. Suitable dyes preferably have a high storage stability and insensitivity to the other ingredients of the compositions and to light and no pronounced substantivity to the at least indirectly coming into contact with the dye-containing agents substrates such as textiles, glass, ceramics or plastic dishes, so as not to stain them.
Bei der Wahl des Färbemittels solite beachtet werden, dass die Färbemittel eine hohe Lagerstabilität und Unempfindlichkeit gegenüber Licht aufweisen. Gleichzeitig ist auch bei der Wahl geeigneter Färbemittel zu berücksichtigen, dass Färbemittel unterschiedliche Stabilitäten gegenüber Oxidation aufweisen. Im Allgemeinen gilt, dass wasserunlösliche Färbemittel gegen Oxidation stabiler sind als wasserlösliche Färbemittel. Abhängig von der Löslichkeit und damit auch von der Oxidationsempfindlichkeit variiert die Konzentration des Färbemittels in den Formkörpern. Bei gut wasserlöslichen Färbemitteln werden typischerweise Färbemiltel-Konzentrationen im Bereich von einigen 10-2 bis 10-3 Gew.-% gewählt, bezogen auf den gesamten Formkörper. Bei den auf Grund ihrer Brillanz insbesondere bevorzugten, allerdings weniger gut wasserlöslichen Pigmentfarbstoffen liegt die geeignete Konzentration des Färbemittels dagegen typischerweise bei einigen 10-3 bis 10-4 Gew.-%, bezogen auf den gesamten FormkörperWhen choosing the colorant it should be noted that the colorants have a high storage stability and insensitivity to light. At the same time, it should also be taken into account when choosing suitable colorants that colorants have different stabilities to oxidation. In general, water-insoluble colorants are more stable to oxidation than water-soluble colorants. Depending on the solubility and thus also on the sensitivity to oxidation, the concentration of the colorant in the moldings varies. In the case of readily water-soluble colorants, dyeing concentrations in the range of a few 10 -2 to 10 -3 % by weight, based on the total molding, are typically selected. In the preferred because of their brilliance, but less water-soluble On the other hand, for pigment dyestuffs, the suitable concentration of the dyestuff is typically about 10 -3 to 10 -4 % by weight, based on the total molding
Es werden vorzugsweise solche Färbemittel bevorzugt, die in einem Waschprozess oxidativ zerstört werden können sowie Mischungen derselben mit geeigneten blauen Farbstoffen, sog. Blautönern. Es hat sich als vorteilhaft erwiesen, Färbemittel einzusetzen, die in Wasser oder bei Raumtemperatur in flüssigen organischen Substanzen löslich sind. Geeignet sind beispielsweise anionische Färbemittel, z.B. anionische Nitrosoferbsloffe.Preference is given to those colorants which can be oxidatively destroyed in a washing process and mixtures thereof with suitable blue dyes, so-called blue toners. It has proven to be advantageous to use colorants which are soluble in water or at room temperature in liquid organic substances. Suitable are, for example, anionic colorants, e.g. anionic nitrosofibres.
Als optische Aufheller, welche vorzugsweise im erfindungsgemäßen Formkörper enthalten sein können, eignen sich beispielsweise 1,3,5-Triazinyl-Derivate von 4,4'-Diamino-2,2'-stilbendisulfonsäure (Flavonsäure), 4,4'-Distyrylbiphenylen, Hymecromon (Methylumbelliferon), Cumarin, Dihydrochinolinon, 1,3-Diarylpyrazolin, Naphthalsäureimid, über CH=CH-Bindungen verknüpfte Benzoxazol-Systeme, Benzisoxazol- und Benzimidazol-Systeme und durch Heterocyclen substituierte Pyren-Derivate.Suitable optical brighteners, which may preferably be present in the molding according to the invention, are, for example, 1,3,5-triazinyl derivatives of 4,4'-diamino-2,2'-stilbenedisulfonic acid (flavonic acid), 4,4'-distyrylbiphenylene, Hymecromon (methylumbelliferone), coumarin, dihydroquinolinone, 1,3-diarylpyrazoline, naphthalimide, benzoxazole systems linked via CH = CH bonds, benzisoxazole and benzimidazole systems, and heterocyclic substituted pyrene derivatives.
Nach einer bevorzugten Ausführungsform der Erfindung sind die erfindungsgemäßen Folien kein Verpackungsmaterial für Flüssigkeiten oder Feststoffe wie z.B. Wasch- oder Reinigungsmittel, sind also kein Folienmaterial von Waschmittelpouches oder ähnliches.According to a preferred embodiment of the invention, the films according to the invention are not a packaging material for liquids or solids, e.g. Washing or cleaning agents, so are no film material of detergent pouches or the like.
Die erfindungsgemäßen Folien können über alle bekannten Verfahren hergestellt werden, wobei aber das Gießverfahren als sehr vorteilhaft anzusehen ist.The films of the invention can be prepared by any known method, but the casting method is to be regarded as very advantageous.
Die Fullenherstellung über thermoplastische Verarbeitung durch Kalandrieren oder Extrudieren ist sehr bevorzugt. Insbesondere die Coextrusion ist bevorzugt.Fulling via thermoplastic processing by calendering or extrusion is very preferred. In particular, coextrusion is preferred.
Das Blasfolienverfahren und das Flachfolienverfahren sind erfindungsgemäß sehr bevorzugte Verfahren zur Folienherstellung.The blown film process and the flat film process according to the invention are very preferred processes for film production.
Die Herstellung von Blasfolien ist bekannt. Beispielsweise erfolgt zuerst ein Mischen von Polymermaterial wie z.B. PVOH-Pulver mit Additiven und Stabilisatoren im festen Zustand. Diese Mischung wird im beheizten Extruder aufgeschmolzen. Die erfindungsgemäß erforderlichen Riechstoffe können z.B. zur Schmelze zugesetzt werden. Danach folgt das Aufblasen der Schmelze, das Kühlen und vorzugsweise das Aufwickeln der Folie.The production of blown films is known. For example, mixing of polymeric material, such as e.g. PVOH powder with additives and stabilizers in the solid state. This mixture is melted in the heated extruder. The fragrances required according to the invention may e.g. be added to the melt. This is followed by the blowing of the melt, the cooling and preferably the winding of the film.
Blasfolien sind im allgemeinen preiswerter herstellbar als Cast-Folien, jedoch kann die Foliendickenverteilung etwas stärker schlanken und es kann ggf. zu mehr Lufteinschlüssen kommen, was aber auch ein erwünschter Effekt sein kann. In der Regel sind Blasfolien etwas härter und haben weniger Rückstelleigenschaften als Castfolien, wohingegen diese weich, flexibel, fast schon gummiartig sein können und auch hohe Rückstellneigung aufweisen können.Blown films are generally less expensive to produce than cast films, but the film thickness distribution can be slightly more slender and it may possibly lead to more air bubbles, but this can also be a desired effect. As a rule, blown films are something harder and have less recovery properties than cast films, whereas these can be soft, flexible, almost rubbery and can also have high Rückstellungsneigung.
Wenn Folien aus Lösungen von Polymeren hergestellt werden, spricht man vom Gießverfahren. Die Polymer-Lösungen können erfindungsgemäß durch Einsatz von Lösungsmitteln, was bevorzugt ist, oder durch chemische Umwandlung unlöslicher Makromoleküle in lösliche Derivate hergestellt werden. Die erfindungsgemäß erforderlichen Riechstoffe können z.B. der Polymerklösung zugesetzt werden. Zur Überführung der Polymerlösungen in Folien gibt es mehrere Methoden. Wenn die Polymerlösung in einem Bad ausgefällt wird, so spricht man vom Naßgießverfahren. Beispielsweise wird bei der Cellophanherstellung eine hochviskose Celluloselösung durch ein Breitschlitzdüse in ein starksaures Fällbad gedrückt.When films are made from solutions of polymers, this is called the casting process. The polymer solutions can be prepared according to the invention by use of solvents, which is preferred, or by chemical conversion of insoluble macromolecules into soluble derivatives. The fragrances required according to the invention may e.g. be added to the polymer solution. There are several methods for converting the polymer solutions into films. When the polymer solution is precipitated in a bath, it is called wet-casting. For example, in cellophane production, a high-viscosity cellulose solution is forced through a slot die into a strong acid precipitation bath.
Wenn das Lösungsmittel verdampft und dadurch das Polymer als Folie gewonnen wird, so spricht man vom Trockengießverfahren, zu dessen Durchführung vor allem Band- oder Trommelgießmaschinen verwendet werden können.If the solvent evaporates and thereby the polymer is recovered as a film, so it is called dry casting, for the implementation of particular belt or drum casters can be used.
Beim Bandgießverfahren (auch Cast-Verfahren oder Chillroll-Verfahren genannt), welches erfindungsgemäß bevorzugt einsetzbar ist, wird die Polymerlösung, welche erfindungsgemäß Riechstoffe enthält, aus einem Vorratsbehälter vorzugsweise durch eine Düse auf ein in der Regel endloses, vorzugsweise hoch poliertes, Metallband gegossen. Die Bandgeschwindigkeiten hängen stark vom eingesetzten Material und von der angestrebten Foliendicke ab. Sie können vorzugsweise zwischen 2 und 60 Meter pro Minute liegen. Die Folie kann nach dem Verdampfen des größten Teils der Lösungsmittel abgezogen werden. Zur Aufwicklung wird sie vorzugsweise durch einen Trockner mit heißer Umluft oder über Heizwalzen geführt. Resultierende Foliendicken können bei diesem Verfahren beispielsweise 15 bis 300 µm betragen. Es ist möglich und bevorzugt, dass die Polymerlösung, bevor sie auf das Metallband gegossen wird, zuvor über einen Filter gedrückt wird, um ungelöste Teilchen zurückzuhalten, die sonst zur so genannten Stippenbildung führen könnten. Ebenfalls ist es möglich und bevorzugt, die Polymerlösung vor dem Vergießen auf die Metallplatte in einem Entgasungsbehälter zumindest teilweise von enthaltener Luft zu befreien. Die optionale Entgasung erfolgt vorteilhafterweise vor der Duftstoffzugabe.In the strip casting method (also called cast method or chill roll method), which is preferably used according to the invention, the polymer solution, which contains odoriferous substances according to the invention, is poured from a storage container preferably through a nozzle onto a generally endless, preferably highly polished, metal strip. The belt speeds depend strongly on the material used and on the desired film thickness. They can preferably be between 2 and 60 meters per minute. The film can be stripped off after evaporation of most of the solvents. For winding, it is preferably passed through a dryer with hot air or hot rollers. Resulting film thicknesses can be 15 to 300 microns in this process, for example. It is possible, and preferred, for the polymer solution to be forced over a filter prior to being cast onto the metal strip to retain any undissolved particles that might otherwise result in so-called speckling. It is likewise possible and preferred to at least partially free the polymer solution from air that is contained in a degassing container before it is poured onto the metal plate. The optional degassing is advantageously carried out before the addition of fragrance.
Zur Herstellung von Folien wie z.B. PVOH-Folien nach dem Castverfahren wird also z.B. in einem Ansatzbehälter das PVOH-Pulver/Granulat und Weichmacher (z.B. PEG und oder Glycerin) in Wasser aufgelöst. Anschließend wird die Lösung einem Vorratsbehälter zugeführt. Die Lösung wird dann auf z.B. ca. 80°C erhitzt und anschließend über eine Schlitzdüse einem Walzband zugeführt. Im Trocknungsprozeß (Luft-Heizkanal) wird die Lösung als Folie ausgeprägt. Dabei können z.B. im Ansatzbehälter erfindungsgemäß zu dem PVOH-Gemenge Parfümöle zugegeben werden.For the production of films such as PVOH films by the casting process, the PVOH powder / granules and plasticizers (eg PEG and / or glycerol) are dissolved in water eg in a batch tank. Subsequently, the solution is fed to a reservoir. The solution is then heated to, for example, about 80 ° C and then fed via a slot die to a rolled strip. In the drying process (air heating channel), the solution is expressed as a film. For example, perfume oils may be added to the PVOH mixture in the batch tank according to the invention.
Ähnlich dem Bandgießverfahren ist das Trommelgießverfahren. Bei diesem werden an der Stelle des Metallbandes beheizte Trommeln verwendet, etwa solche mit 2-3 m Durchmesser und Breiten von etwa 2 m.Similar to the strip casting method is the Trommelgießverfahren. In this case, heated drums are used at the location of the metal strip, such as those with a diameter of 2-3 m and widths of about 2 m.
Man erhält beim Cast(Gieß)-Verfahren Folien, die gewöhnlich eine durchgehend gleichmäßige Foliendickenverteilung und wenig Lufteinschlüsse zeigen, allerdings ist das Verfahren wegen der energieintensiven Trocknung teuer. Mit dem Cast-Verfahren können dünnere Folien als beim Blasverfahren hergestellt werden. Es können auch hohe Wassergehalte eingestellt werden, z.B. 5-8 Gew.-% Wasser bezogen auf die gesamte Folie.In the casting process, films are usually obtained which generally show uniform, uniform film thickness distribution and little air inclusions, although the process is expensive because of the energy-intensive drying. The cast process can produce thinner foils than the blown process. High levels of water can also be adjusted, e.g. 5-8 wt .-% water based on the entire film.
Das Cast(Gieß)-Verfahren wird vorzugsweise bei solchen Stoffen angewendet, die nicht oder nur unter Zersetzung schmelzbar sind, wie z.B. Cellulose oder Polyimide. Zur Herstellung von sehr dünnen Folien ist das Castverfahren ebenfalls bevorzugt einsetzbar.The cast method is preferably applied to those which are not meltable or decompose only with decomposition, e.g. Cellulose or polyimides. For the production of very thin films, the casting process is also preferably used.
Walz- oder Sinterverfahren sind prinzipiell auch zur Folienherstellung möglich, jedoch nur in Ausnahmefällen sinnvoll, z.B. zur Herstellung von Tetrafluorethylenfolien und Polyimidfolien.Rolling or sintering processes are in principle also possible for film production, but only in exceptional cases makes sense, e.g. for the production of tetrafluoroethylene films and polyimide films.
Möglich ist beispielsweise auch ein Verfahren zur Herstellung einer Folie, wobei zuerst durch Lösen oder Dispergieren eines oder mehrerer Polymere in einem flüssigen Trägermedium eine walzfähige Zubereitung hergestellt wird und diese anschließend mit Hilfe einer Walzvorrichtung durch Walzen in die Form einer Folie gebracht wird. Dabei kann gleichzeitig oder anschließend das flüssige Trägermedium verdampft werden.It is also possible, for example, a method for producing a film, wherein first by dissolving or dispersing one or more polymers in a liquid carrier medium, a rollable preparation is prepared and this is then brought by means of rolling in the form of a film by means of a rolling device. In this case, simultaneously or subsequently, the liquid carrier medium can be evaporated.
Ein flüssiges Trägermedium umfasst vorzugsweise Löse- oder Dispergiermittel wie Wasser, Alkohole, Ether oder Kohlenwasserstoffe oder Gemische aus zwei oder mehreren der genannten Stoffe, wobei die Stoffe oder Stoffgemische bei Raumtemperatur (20°C) flüssig sind. Geeignete Alkohole sind z.B. die ein- oder mehrwertigen Alkohole mit 1 bis 5 C-Atomen wie z.B. Ethanol, Isopropanol, Ethylenglykol, Glycerin und Propylenglykole.A liquid carrier medium preferably comprises solvents or dispersants such as water, alcohols, ethers or hydrocarbons or mixtures of two or more of the substances mentioned, wherein the substances or mixtures of substances are liquid at room temperature (20 ° C.). Suitable alcohols are e.g. the monohydric or polyhydric alcohols having 1 to 5 carbon atoms, e.g. Ethanol, isopropanol, ethylene glycol, glycerol and propylene glycols.
In der walzfähigen Zubereitung kann der Gehalt des flüssigen Trägermediums z.B. im Bereich von 20 bis 90 Gew.-% oder 30 bis 70 Gew.-% liegen.In the rollable preparation, the content of the liquid carrier medium may be e.g. in the range of 20 to 90 wt .-% or 30 to 70 wt .-% are.
Eine geeignete walzfähige Zubereitung kann z.B. halbfeste oder teigartige Konsistenz haben oder es kann sich um eine viskose Flüssigkeit handeln, mit welcher ein geeigneter Träger beschichtet wird und durch Walzen mit einer Walzvorrichtung die gewünschte Foliendicke erzeugt wird.A suitable rollable formulation may e.g. semi-solid or dough-like consistency, or it may be a viscous liquid with which a suitable carrier is coated and the desired film thickness is produced by rolling with a rolling device.
Die fertige Folie wird dann nach dem Trocknen vom Träger entfernt. Z.B. aus der Gruppe Silikon, Metall, metallisierten Polymeren, Polytetrafluorethylen, Polyether/Polyamid Blockcopolymeren, Polyurethanen, Polyvinylchlorid, Nylon, Alkylen/Styrol Copolymeren, Polysthylen, Polyester oder anderen, wiederablösbaren Materialien kann man geeignete Trägermaterialien auswählen. Geeignete Walzvorrichtungen sind z.B. die bekannten, mit mindestens zwei gleich- oder gegenläufigen Walzen oder Rollen versehenen so genannten Forward-Roll- oder Reverse-Roll-Coater, wobei ein Reverse-Roll Verfahren bevorzugt ist.The finished film is then removed from the carrier after drying. For example, from the group of silicone, metal, metallized polymers, polytetrafluoroethylene, polyether / polyamide block copolymers, polyurethanes, polyvinyl chloride, nylon, alkylene / styrene copolymers, polystyrene, polyester or other, redetachable materials can be selected suitable carrier materials. Suitable rolling devices are, for example, the known, with at least two equal or opposite rollers or rollers provided so-called forward roll or reverse roll coater, with a reverse roll method is preferred.
Die (nach allen möglichen Verfahren) resultierenden Folien können nachfolgend weiterverarbeitet werden, beispielsweise durch Bedampfen, Beschichten, Bedrucken oder Beflocken. Es ist auch möglich, dass die Parfümierung der Folie erst nach der eigentlichen Folienherstellung erfolgt, z.B. durch Besprühen, Bestreichen oder Eintauchen der Folie in eine parfümhaltige Zubereitung. Es ist aber mehr bevorzugt, wenn die Parfümierung der Folie im Verlaufe der Folienherstellung erfolgt. Möglich ist auch ein gekoppeltes Verfahren, bei dem also sowohl im Verlaufe der Folienherstellung eine Parfümierung erfolgt als auch die fertige Folie anschließend noch einmal parfümiert wird, z.B. durch Besprühen.The resulting (by all possible methods) films can be further processed, for example, by vapor deposition, coating, printing or flocking. It is also possible that the perfuming of the film takes place only after the actual film production, e.g. by spraying, brushing or dipping the film into a perfume-containing preparation. However, it is more preferred if the perfuming of the film takes place in the course of the film production. A coupled process is also possible, in which perfuming takes place both in the course of film production and the finished film is then perfumed once again, e.g. by spraying.
Bei den erfindungsgemäßen Folien handelt es sich um geschäumte Folien. Um geschäumte Folien zu erhalten, werden in die Folien Gasblasen eines geeigneten Gases wie z.B. Luft eingeschlossen.The films according to the invention are foamed films. To obtain foamed films, gas bubbles of a suitable gas, e.g. Air included.
Solche Folien mit eingeschlossenen Gasblasen zeichnen sich durch eine besonders gute Haptik aus. Ferner können sie eine verbesserte Wasserlösllchkeit zeigen.Such films with trapped gas bubbles are characterized by a particularly good feel. Furthermore, they can show improved water solubility.
Bevorzugte geschäumte Folien weisen eine Dichte von < 1 kg/m3 auf.Preferred foamed films have a density of <1 kg / m 3 .
Zum Einbringen der Gasblasen stehen verschiedene Möglichkeiten zur Verfügung. So kann z.B. ein Bläh- oder Treibmittel verwendet werden. Es kann z.B. ein Aufschäumen durch mechanisches Rühren der noch flüssigen oder zähflüssigen Trägermasse erzielt werden. Es kann z.B. eine ein Gas erzeugende chemische Reaktion provoziert werden. Es kann z.B. ein leichtflüchtiges Lösungsmittel verwendet werden, welches bei erhöhten Temperaturen verdampft wird. Es kann z.B. eine Einleitung eines Gases oder eines verflüssigten Gases in die noch zähflüssige Trägermasse erfolgen.There are various options for introducing the gas bubbles. Thus, e.g. a blowing or blowing agent can be used. It can e.g. foaming can be achieved by mechanical stirring of the still liquid or viscous carrier mass. It can e.g. to provoke a gas-producing chemical reaction. It can e.g. a volatile solvent may be used, which is evaporated at elevated temperatures. It can e.g. an introduction of a gas or a liquefied gas into the still viscous carrier mass.
Es kann aber bevorzugt sein, Blähmittel zu verwenden. Dies sind Substanzen, die sich beim Erwärmen unter Gasentwicklung zersetzen, so dass z.B. Stickstoff oder Kohlendioxid, freigegeben werden.However, it may be preferable to use blowing agents. These are substances that decompose on heating with evolution of gas, so that e.g. Nitrogen or carbon dioxide to be released.
Carbonate, Hydrogencarbonate, Borhydride, Siliziumoxyhydride usw, sind Beispiele für geeignete anorganische Blähmittel. Bevorzugt einsetzbar sind aber auch alle organischen Blähmittel, wie sie bekanntermaßen bei der Herstellung poröser bzw. blasenhaltiger Kunststoffe eingesetzt werden. Erfindungsgemäße Folien, wie vorzugsweise geschäumte Folien, können auch in Konfetti-Form vorliegen. Konfetti-Form bedeutet, dass es sich um eine Vielzahl von Foflenschnipseln oder Folienfetzen handelt. Der Begriff "Konfetti" ist im allegemeinen Sprachbebrauch bekannt für kleine, bunte Papierschnipsel. Folien in Konfetti-Form müssen nicht unbedingt so klein sein, wie das bekannte Papierkonfetti, welches vor allem bei Fastnachtsumzügen, aber auch bei anderen Feierlichkeiten, wie Kindergeburtstagen oder Hochzeiten, in die Luft geworfen wird. Die Konfetti-Form kann regelmäßig oder unregelmäßig sein, es kann sich beispielsweise um kreisrunde Folienschnipsel handeln, es kann sich beispielsweise um hetzförmige Folienschnipsel handeln. Jede denkbare Form ist möglich und erhältlich beispielsweise durch Ausstanzen des Folienkonfetti aus einer größeren Mutterfolie. Der Einsatz von erfindungsgemäßen Folien in Konfetti-Form kann z.B. bei der Handtextilwäsche vorteilhaft sein, wenn man eine bestimmte Menge der Folien in Konfetti-Form in das Textilbehandlungsbad streut.Carbonates, bicarbonates, borohydrides, silicon oxyhydrides, etc. are examples of suitable inorganic blowing agents. However, it is also possible to use all organic blowing agents which are known to be used in the production of porous or bubble-containing plastics. Films according to the invention, such as preferably foamed films, can also be present in confetti form. Confetti form means that it is a variety of Foflenschnipseln or foil shreds. The term "confetti" is generally known for small, colorful scraps of paper. Confetti-shaped foils do not necessarily have to be as small as that well-known paper confetti, which is thrown in the air especially during carnival parades, but also at other celebrations, such as children's birthday parties or weddings. The confetti shape can be regular or irregular, it can be, for example, circular foil shreds, it can be, for example, bug-shaped foil snippets. Any conceivable shape is possible and obtainable, for example, by punching out the foil confetti from a larger mother foil. The use of films according to the invention in confetti form can be advantageous, for example, in hand-textile washing, if a certain amount of the films in confetti form is scattered in the textile treatment bath.
Das Entnahmebehältnis kann ein beliebiges Behältnis sein, welches insbesondere geeignet ist, einen folienförmigen Formkörper zumindest teilweise zu umhüllen und/oder zusammenzuhalten.The removal container may be any container which is particularly suitable for at least partially enveloping and / or holding together a film-shaped molding.
Das Behältnis kann aus z.B. einem flexiblen, halbstarren oder formstabilen Material gebildet sein.The container may be made of e.g. be formed of a flexible, semi-rigid or dimensionally stable material.
Ein formstabiles Behältnis hat den Vorteil, insbesondere fragile folienförmige Formkörper vor mechanischen Einflüssen zu schützen und entsprechende Beschädigungen zu verhindern.A dimensionally stable container has the advantage, in particular to protect fragile film-shaped moldings from mechanical influences and to prevent corresponding damage.
Um ein Aufquellen oder unbeabsichtigte Aktivierung der folienförmigen Formkörper zu verhindern, ist das Behältnis bevorzugt wasserdampfdicht ausgeführt.In order to prevent swelling or unintentional activation of the film-shaped moldings, the container is preferably made water vapor-tight.
Um eine unbeabsichtigte Emission von Substanzen, wie etwas Duftstoffen, aus den folienförmigen Formkörpern zu verhindern, ist das Behältnis bevorzugt riechstoffdicht ausgebildet.In order to prevent inadvertent emission of substances, such as fragrances, from the film-shaped moldings, the container is preferably odor-proof.
In einer weiteren, bevorzugten Ausführungsform der Erfindung sind an dem Behältnis Mittel zum kindersicheren Öffnen vorgesehen, um einen unbeabsichtigten Kontakt von Kindern mit den folienförmigen Formkörpern zu verhindern.In a further preferred embodiment of the invention means for child-safe opening are provided on the container, to prevent inadvertent contact of children with the film-shaped moldings.
Insbesondere sind an dem erfindungsgemäßen Behälter Dosler- und Entnahmehilfen für die folienförmigen Formkörper vorgesehen.In particular, metering and removal aids for the film-shaped moldings are provided on the container according to the invention.
Bei einem flexiblen Behälter kann es sich z.B. um einen Verpackungsbeutel, wie beispielsweise ein Flachbeutel, Siegelrandbeutel, Bodenbeutel, Doppelbeutel, Raumbeutel oder Schlauchbeutel handeln, z.B. ein Beutel aus einem mehrschichtigen, folienförmigen und flexiblen Verbundmaterial, wobei der Beutel vorzugsweise eine Aufreißhilfe, wie z.B. einen Aufreißstreifen oder eine Anreiflaussparung aufweist.For a flexible container, it may be e.g. to act a packaging bag, such as a flat bag, sealed edge bag, bottom bag, double bag, bag or bag, e.g. a pouch made of a multilayer, sheet-like and flexible composite material, the pouch preferably having a tear-open aid, such as e.g. has a tear strip or Anreiflaussparung.
Es ist denkbar die rollenförmigen Formkörper einzeln oder in Mehrzahl in einem flexiblen Behälter anzuordnen.It is conceivable to arrange the roller-shaped moldings individually or in a plurality in a flexible container.
Die in einem oder mehreren flexiblen Behältern verpackten folienförmigen Formkörper können zur Verwendung in Band- oder Blattspendern vorgesehen sein. Band- oder Blattspendern können auch für unverpackte folienförmigen Formkörper verwendet werden.The film-shaped moldings packaged in one or more flexible containers may be intended for use in tape or sheet dispensers. Ribbon or sheet dispensers can also be used for unpacked film-shaped moldings.
Das Entnahmebehältnis kann auch eine Rolle umfassen oder aus dieser bestehen. Der vorzugsweise streifenförmige, blattförmige, schelbenförmige oder bahnförmige, flexible Formkörper kann also auf einer Rolle aufgewickelt sein, wobei der Formkörper vorzugsweise mit Trennstellen zur portionsweisen Entnahme versehen ist. Solche Entnahmebehältnisse sind beispielsweise aus dem Bereich der Klebebandroller bekannt. Klebebandroller fallen unter den Oberbegriff der Bandspender. Alle Bandspender können als Entnahmebehältnis geeignet sein.The extraction container may also comprise or consist of a roll. The preferably strip-shaped, sheet-shaped, Schelbenförmige or web-shaped, flexible shaped body can therefore be wound on a roll, wherein the shaped body is preferably provided with separation points for portionwise removal. Such removal containers are known for example from the field of adhesive tape scooters. Adhesive tape scooters fall under the generic term of tape dispensers. All tape dispensers may be suitable as a removal container.
Wenn das Entnahmebehältrtis also eine Rolle umfasst, vorzugsweise ein Bandspender ist, wobei der Formkörper insbesondere mit Trennstellen zur portionsweisen Entnahme versehen ist, so liegt eine bevorzugte Ausführungsform vor.If the Entnahmebehältris thus comprises a roller, preferably a tape dispenser, wherein the shaped body is provided in particular with separation points for portion removal, so is a preferred embodiment.
Zum Erzeugen von Bandstücken sind auch Vorrichtungen, so genannte Band-Abroller, dienlich, mit denen das Band von einer Rolle abgewickelt und über ein Schneideelement geführt wird. Wenn das freie Ende des Bandes die gewünschte Länge erreicht hat, wird es mit dem Schneideelement abgeschnitten. Bei diesen Vorrichtungen wird die Länge des abzuschneidenden Bandes durch den Benutzer bestimmt, indem er das Band in gewünschter Länge abwickelt und dann abschneidet. Zum Abschneiden muss er das Bandende so über das Schneideelement, typischerweise eine sägeartig gezahnte Schneidklinge entweder aus Metall oder Kunststoff, führen, dass dieses schneidend auf das Band einwirken kann. Solche oder ähnliche Bandspender sind erfindungsgemäß mit Vorteil einsetzbar.For the production of pieces of tape also devices, so-called tape dispensers, are useful, with which the tape is unwound from a roll and passed over a cutting element. When the free end of the band has reached the desired length, it is cut off with the cutting element. In these devices, the length of the tape to be cut off is determined by the user by unwinding the tape in the desired length and then cutting it off. For cutting, it must lead the end of the tape over the cutting element, typically a saw-toothed cutting blade made of either metal or plastic, that this cutting can act on the tape. Such or similar tape dispensers can be advantageously used according to the invention.
Besonders bevorzugt sind nachfüllbare Bandspender zur wiederholbaren Aufnahme einer Bandrolle.Refillable tape dispensers are particularly preferred for repeatably receiving a tape roll.
Besonders geeignet sind z.B. auch solche Bandspender, wie sie aus dem Bereich der Korrekturbandspender (Filmübertragungsroller) bekannt sind. Ist das erfindungsgemäße Entnahmebehältnis ein Filmübertragungsroller, so handelt es sich um eine bevorzugte Ausführungsform.Particularly suitable are e.g. also such tape dispensers as are known in the field of correction tape dispensers (film transfer rollers). If the removal container according to the invention is a film transfer roller, this is a preferred embodiment.
Ebenfalls dienlich sind Behältnisse zur Ausgabe von Blättern oder Streifen, so genannte Blattspender. Dies sind Vorrichtungen, die einen Stapel von Blättern, Streifen oder Folien usw. enthalten und eine Dosier- bzw. Entnahmehilfe für die Blätter, Streifen oder Folien umfassen.Also useful are containers for dispensing sheets or strips, so-called sheet dispensers. These are devices that contain a stack of sheets, strips or foils, etc., and include a dispensing aid for the sheets, strips or foils.
Bevorzugt ist dieser Stapel so angeordnet ist, dass bei Entnahme des obersten Blattes das darunter liegende Blatt so ausgerichtet wird, dass es danach ohne Schwierigkeiten entnehmbar ist. Z.B. wird bei solchen Vorrichtungen mit Entnahmeschlitz bei der Entnahme des obersten Blattes das folgende Blatt schon soweit nachgeführt, dass es hernach schon aus dem Entnahmeschlitz ragt und leicht entnommen werden kann.Preferably, this stack is arranged so that upon removal of the uppermost sheet, the underlying sheet is aligned so that it is then removed without difficulty. For example, In such devices with removal slot in the removal of the top sheet, the following sheet already tracked so far that it protrudes from the removal slot and can be easily removed afterwards.
Es handelt sich z.B. um einen Block von Folien, die jeweils eine Schicht aus einem flexiblen Polymermaterial aufweisen, welche an einem zweiten Endbereich mit einer Beschichtung aus repositionierbarem Selbstklebematerial versehen sein kann, während sie entlang einem visuell erkennbaren ersten Endbereich in einem Stapel jedenfalls frei von Kleber sind, wobei die benachbarten Enden der Blätter aufeinander ausgerichtet sind und das erste und das zweite Ende aufeinanderfolgender Blätter benachbart angeordnet sind. Der Stapel kann in einer Kammer angeordnet sein, die teilweise in der oberen Wand mit einem Schlitz begrenzt ist, durch welchen der erste Endbereich des obersten Blattes ragt. Durch Relativbewegung zwischen der oberen Wand und dem obersten Blatt wird beim Herausziehen des obersten Blattes durch den Schlitz die Ausrichtung des Schlitzes mit nachfolgenden Bereichen des Blattes bis zu dessen zweitem Ende erreicht, während diese aufeinanderfolgenden Bereiche von dem Stapel abgezogen werden. Der Endbereich des darunterliegenden Blattes wird mit dem Endbereich des obersten Blattes durch den Schlitz bewegt, um so den ersten Endbereich des darunterliegenden Blattes aus dem Schlitz ragen zu lassen, wenn das oberste Blatt entfernt ist. Solche oder ähnliche Blattabgabesysteme sind erfindungsgemäß bevorzugt.For example, it is a block of films each having a layer of a flexible polymeric material which may be provided at a second end region with a coating of repositionable pressure-sensitive adhesive material, while remaining free of adhesive along a visually recognizable first end region in a stack with the adjacent ends of the sheets aligned and the first and second ends of successive sheets disposed adjacent one another. The stack may be disposed in a chamber which is partially bounded in the top wall by a slot through which the first end portion of the topmost sheet projects. By relative movement between the top wall and the topmost sheet, as the topmost sheet is withdrawn through the slot, alignment of the slot with subsequent portions of the sheet is achieved to its second end as these successive portions are withdrawn from the stack. Of the End portion of the underlying sheet is moved with the end portion of the uppermost sheet through the slot so as to leave the first end portion of the underlying sheet from the slit when the uppermost sheet is removed. Such or similar sheet dispensing systems are preferred according to the invention.
Nach einer bevorzugten Ausführungsform ist das erfindungsgemäße Duftmedium-abgabesystem so konfiguriert, dass es die Entnahme von zumindest 3, 4, 5 oder mehr unterschiedlichen Parfümformkörpem ermöglicht. Dies kann beispielsweise ein System sein, welches 3, 4 oder 5 Rollen unterschiedlicher Parfümfilme umfasst. Dies kann man dann auch als 3er, 4er oder 5er-Set bezeichnen. Die Parfümformkörper unterscheiden sich dabei durch ihre Parfümierung, so dass der Verbraucher durch die Dosierung der einzelnen Parfümkörper selbst die Gesamtparfümnote festlegen kann. Der Kreativität des Verbrauchers sind dabei keine Grenzen gesetze. Die unterschiedliche Parfümierung kann vorteilhafterweise durch unterschiedliche Farbgebung angezeigt werden.In a preferred embodiment, the fragrance medium delivery system of the present invention is configured to allow removal of at least 3, 4, 5, or more different perfume tablets. This may be, for example, a system comprising 3, 4 or 5 rolls of different perfume films. This can then also be described as a set of 3, 4 or 5 sets. The perfume tablets differ in their perfuming, so that the consumer can set the total perfume rating by the dosage of the individual perfume body. There are no limits to the creativity of the consumer. The different perfuming can advantageously be indicated by different colors.
Die Formkörper einer entsprechenden Set-Konfiguration enthalten dabei vorteilhafterweise unterschiedliche Riechstoffe, die vorzugsweise nach bestimmten Noten unterschieden werden können.The shaped bodies of a corresponding set configuration advantageously contain different fragrances, which can preferably be distinguished according to specific notes.
Ein weiteres Entnahmebehältnis sind Dosierspender für Formkörper. Solche Dosierspender bestehen gewöhnlich aus einem Gehäuse mit Vorratskammer, deren Boden z.B. eine Auslaßöffnung aufweist, welche in eine Führung für einen Schieber mit Druckplatte und mit Rückstellfeder öffnet, wobei der Schieber einen in seiner Ruhestellung unterhalb der Auslaßöffnung befindlichen Kanal aufweist, dessen Auswurföffnung in Ruhestellung durch eine Abdeckung abgedeckt ist.Another removal container are dosing dispensers for moldings. Such dosing dispensers usually consist of a housing with a storage chamber whose bottom is e.g. an outlet opening which opens into a guide for a slide with pressure plate and with return spring, wherein the slide has a channel located in its rest position below the outlet opening, the discharge opening is covered in the rest position by a cover.
Solche Dosierspenden können parfümierte Formkörper enthalten, so dass man in solchem Falle von einem Duftmediumabgabesystem sprechen kann. Die Dimensionen entsprechender Dosierspender sind selbstverständlich an die Dimensionen das betreffenden Formkörpers angepasst. Solche Dosierspender können erfindungsgemäß bevorzugt sein.Such dosing dispensers may contain perfumed shaped bodies, so that one can speak in such a case of a fragrance medium delivery system. The dimensions of corresponding metering dispensers are of course adapted to the dimensions of the molding in question. Such dosing dispensers may be preferred according to the invention.
Die vorliegende Erfindung ermöglicht dem Fachmann einen erheblichen Handlungsspielraum bei der Beduftung wässriger Systemen, wodurch er in die Lage versetzt wird, wässrige Systeme mit ganz individuellen, verfeinerten Duftnoten hervorzubringen. Zu diesem Zwecke können die erfindungsgemäßen Folien, nach einer bevorzugten Ausführungsform auch insbesondere Riechstoffe mit
- (a) mandelartigem Geruch, wie vorzugsweise Benzaldehyd, Pentanal, Heptenal, 6-Methylfurfural, Methylbutanal, Furfural und/oder Acetophenon oder
- (b) apfelartigem Geruch, wie vorzugsweise (S)-(+)-Ethyl-2-methylbutanoat, Diethylmalonat, Ethylbutyrat, Geranylbulyral, Geranylisopentanoat, Isobutylacetat, Linalylisopentanoat, (E)-β-Damascone, Heptyl-2-methylbutyrat, Methyl-3-methylbulanoat, 2-Hexenal-pentylmethylbutyrat, Ethylmethylbutyrate und/oder Methyl-2-Methylbutanoat oder
- (c) apfelschalenartigem Geruch, wie vorzugsweise Ethylhexanoat, Hexylbutanoat und/oder Hexylhexanoat oder
- (d) aprikosenartigem Geruch wie vorzugsweise γ-Undecalacton oder
- (e) bananenartigem Geruch, wie vorzugsweise Isobutylacetat, Isoamylacetat, Hexenylacelat und/oder Pentylbutanoat oder
- (f) bittermandelartigem Geruch wie vorzugsweise 4-Acetyltoluol oder
- (g) schwarze Johannisbeere-artigem Geruch wie vorzugsweise Mercaptomethylpentanon und/oder Methoxymethylbutanethiol oder
- (h) zitrusartigem Geruch wie vorzugsweise Linalylpentanoat, Heptanal, Linalylisopenlanoat dodecanal, Linalylformiat, α-p-Dimethylstyrol, p-Cymenol, Nonanal, β-Cubebene, (Z)-Limonenoxid, cis-6-Ethenyltetrahydro-2,2,6-trimethylpyren-3-ol, cis-pyranoidlinalcoloxid, Dihydrolinalool, 6(10)-Dihydromyrcenol, Dihydromyrcenol, β-Farnesen, (Z)-β-Farnesen, (Z)-Ocimen, (E)-Limonenoxid, Dihydroterpinylacetat, (+)-Limonen, (Epoxymethylbutyl)-methylfuran und/oder p-Cymen oder
- (i) kakaoartigem Geruch wie vorzugsweise Dimethylpyrazin, Butylmethylbutyrat und/oder Methylbutanal oder
- (j) kokusnußartigem Geruch, wie vorzugsweise γ-Octalacton, γ-Nonalacton, Methyllaurat, Tetradecanol, Methylnonanoat, (35,3aS,7aR)-3a,4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2(3H)-on, 5-Butyldihydro-4-methyl-2(3H)-Furanon, Ethylundecanoat und/oder δ-Decalacton oder
- (k) sahneartigem Geruch wie vorzugsweise Diethylacetal, 3-Hydroxy-2-butanon, 2,3-Pentadion und/oder 4-Heptenal oder
- (l) blumenartigem Geruch wie vorzugsweise Benzylalcohol, Phenylessigsäure, Tridecanal, p-Anisylalcohol, Hexanol, (E,E)-Farnesylaceton, Methylgeranat, trans-Crotonaldehyd, Tetradecylaldehyd, Methylanthranilat, Linalooloxid, Epoxylinalool, Phytol, 10-epi-γ-Eudesmol, Neroloxid, Ethyldihydrocinnamat, γ-Dodecalacton, Hexadecanol, 4-Mercapto-4-methyl-2-pentanol, (Z)-Ocimene, Cetylalcohol, Nerolidol, Ethyl-(E)-cinnamat, Elemicin, Pinocarveol, α-Bisabolol, (2R,4R)-Tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2H-pyran, (E)-Isoelemicin, Methyl-2-methylpropanoat, Trimethylphenylbutenon, 2-Methylanisol, β-Farnesol, (E)-Isoeugenol, Nitro-phenylethan, Ethylvanillat, 6-Methoxyeugenol, Linalool, β-Ionon, Trimethylphenylbutenon, Ethylbenzoat, Phenylethylbenzoat, Isoeugenol und/oder Acetophenone oder
- (m) Frische-Geruch wie vorzugsweise Methylhexanoat, Undecanon, (Z)-limonenoxid, Benzylacetat, Ethylhydroxyhexanoat, Isopropylhexanoat, Pentadecanal, β-Elemene, α-Zingiberene, (E)-Limonenoxid, (E)-p-Mentha-2,8-dien-1-ol, Menthon, Piperiton, (E)-3-Hexenol und/oder Carveol oder
- (n) Frucht-Geruch wie verzugsweise Ethylphenylacetat, Geranylvalerat, γ-Heptalacton, Ethylpropionat, Diethylacetal, Geranylbutyrat, Ethylheptylat, Ethyloctanoat, Methylhexanoat, Dimethylheptenal, Pentanon, Ethyl-3-methylbutanoat, Geranylisovalerat, lobutylacetat, Ehoxypropanol, Mthyl-2-butenal, Methylnonanedion, Linalylacetat, Mthylgeranat, Lmonenoxid, Hdrocinnamicalcohol, Dethylsuccinat, Ehylhexanoat, Ehylmethylpyrazin, β-Cbebene, Nryletat, Ctronellylbutyrat, Heylacetat, Nonylacetat, Butylmethylbutyrat, Pentenal, Isopentyldimethylpyrazin, p-menth-1-en-9-ol, Hexadecanon, Octylacetat, γ-Dodecalacton, Epoxy-β-ionon, Ethyloctenoat, Ethylisohexanoat, Isobornylpropionat, Cedrenol, p-menth-1-en-9-yl acetat, Cadinadien, (Z)-3-Hexenylhexanoat, Ethylcyclohexanoat, 4-Methylthio-2-butanon, 3,5-Octadienon, Methylcyclohexancarboxylat, 2-pentylthiophen, α-Ocimene, Butandiol, Ethylvalerat, Pentanol, Isopiperiton, Butyloctanoat, Ethylvanillat, Methylbutanoat, 2-Mmethylbutylacetat, Propylhexanoat, Butylhexanoat, Isopropylbutanoat, Spathulenol, Butanol, 6-Dodecalacton, Methylquinoxalin, Sesquiphellandren, 2-Hexenol, Ethylbenzoate, Isopropylbenzoat, Ethyllactat und/oder Citronellylisobutyrat oder
- (o) Geranium-artigen Geruch, wie vorzugsweise Geraniol, (E,Z)-2,4-Nonadienal, Octadienon und/oder o-Xylen oder
- (p) weintraubenartigem Geruch wie vorzugsweise Ethyldecanoat und/oder Hexanon oder
- (q) grapefruitartigem Geruch wie vorzugsweise (+)-5,6-Dimethyl-8-isopropenylbicyclo[4.4.0]dec-1-en-3-on und/oder p-Menthenethiol oder
- (r) grasartigem Geruch wie vorzugsweise 2-Ethylpyridin, 2,6-Dimethylnaphthalen, Hexanal und/oder (Z)-3-Hexenol oder
- (s) grüner Note, vorzugsweise 2-Ethylhexanol, 6-Decenal, Dimethylheptenal, Hexanol, Heptanol, Methyl-2-butenal, Hexyloctanoate, Nonansäure, Undecanon, Methylgeranat, Isobornylformiate, Butanal, Octanal, Nonanal, Epoxy-2-decenal, cis-Linalool, Pyranoxid, Nonanol, alpha,γ-dimethylallylalcohol, (Z)-2-penten-1-ol, (Z)-3-hexenylbutanoat, Isobutylthiazol, (E)-2-nonenal, 2-dodecenal, (Z)-4-decenal, 2-octenal, 2-hepten-1-al, Bicyclogermacrene, 2-Octenal, α-Thujene, (Z)-β-Farnesene, (-)-γ-Elemene, 2,4-Octadienal, Fucoserraten, Hexenylacetat, Geranylaceton, Valencene, β-Eudesmol, 1-Hexenol, (E)-2-Undecenal, Artemisia keton, Viridiflorol, 2,6-Nonadienal, Trimethylphenylbutenon, 2,4-Nonadienal, Butylisothiocyanat, 2-Pentanol, Elemol, 2-Hexenal, 3-Hexenal, (+)-(E)-Limonen-oxid, cis-Isocitral, Dimethyloctadienal, Bornylformiat, Bornylisovalerat, Isobutyraldehyd, 2,4-Hexadienal, Trimethylphenylbutenon, Nonanon, (E)-2-Hexenal, (+)-cis-Rosenoxide, Menthone, Coumarin, (Epoxymethylbutyl)-methylfuran, 2-Hexenol, (E)-2-hexenol und/oder Carvylacetat oder
- (t) Grüner Tee-artigem Geruch, vorzugsweise (-)-Cubenol oder
- (u) kräuterartigem Geruch, vorzugsweise Octanon, Hexyloctanoat, Caryophyllenoxide, Methylbutenol, Safranal, Benzylbenzoat, Bornylbutyrat, Hexylacetat, β-Bisabolol, Piperitol, β-Selinene, α-Cubebene, p-Menth-1-en-9-ol, 1,5,9,9-Tetramethyl-12-oxabicyclododeca-4,7-dien, T-muurolol, (-)-Cubenol, Levomenol, Ocimene, α-Thujene, p-Menth-1-en-9-yl acetat, Dehydrocarveol, Artemisia alcohol, γ-Muurolene, Hydroxypentanon, (Z)-Ocimene, β-Elemene, δ-Cadinol, (E)-β-Ocimene, (Z)-Dihydrocarvone, α-Cadinol, Calamenen, (Z)-Piperitol. Lavandulol, β-Bourbonene, (Z)-3-Hexenyl-2-methylbutanoat, 4-(1-Methylethyl-benzenemethanol, Artemisia keton, Methyl-2-butenol, Heptanol, (E)-Dihydrocarvon, p-2-Menthen-1-ol, α-Curcumene, Spathulenol, Sesquiphellandren, Citronellylvalerat, Bornylisovalerat, 1,5-Octadien-3-ol, Methylbenzoat, 2,3,4,5-Tetrahydroanisol und/oder Hydroxycalamenen oder
- (v) honigartigem Geruch, vorzugsweise Ethylcinnamate, β-Phenethylacetat, Phenylessigsäure, Phenylethanal, Methylanthranilat, Zimtsäure, β-Damascenone, Ethyl-(E)-cinnamat, 2-Phenylethylalcohol, Citronellylvalerate, Phenylethylbenzoate und/oder Eugenol oder
- (w) Hyazinthen-artigem Geruch, vorzugsweise Hotrienol oder
- (x) jasminartigem Geruch, vorzugsweise Methyljasmonate, Methyldihydroepijasmonat und/oder Methylepijasmonat oder
- (y) lavendelartigem Geruch, vorzugsweise Linalylvalerate und/oder Linalool oder
- (z) zitronenartigem Geruch, vorzugsweise Neral, Octanal, δ-3-Carene, Limonen, Geranial, 4-mercapto-4-methyl-2-pentanol, Citral, 2,3-Dehydro-1,8-cineol und/oder α-Terpinen oder
- (aa) lilienartigem Geruch, vorzugsweise Dodecanal oder
- (bb) magnolienartigem Geruch, vorzugsweise Geranylaceton oder
- (cc) mandarinenartigem Geruch, vorzugsweise Undecanol oder
- (dd) melonenartigem Geruch, vorzugsweise Dimethylheptenal oder
- (ee) Minze-artigem Geruch, vorzugsweise Menthone, Ethylsalicylat, p-Anisaldehyd, 2,4,5,7a-tetra-hydro-3,6-dimethyl-benzofuran, Epoxy-p-menthene, Geranial, (Methylbutenyl)-methylfuran, Dihydrocarvylacetat, β-Cyclocitral, 1,8-Cineol, β-Phellandrene, Methylpentanon, (+)-Limonen, Dihydrocarveol (-)-Carvon, (E)-p-Mentha-2,8-dien-1-ol, Isopulegylacetat, Piperiton, 2,3-Dehydro-1,8-cineol, α-Terpineol, DL-carvon und/oder α-Phellandrene oder
- (ff) nußartigem Geruch, vorzugsweise 5-methyl-(E)-2-hepten-4-on, γ-Heptalacton, 2-Acetylpyrrol, 3-Octen-2-on, Dihydromethylcyclopentapyrazin, Acetylthiazol, 2-Octenal, 2,4-Heptadienal, 3-Octenon, Hydroxypentanon, Octanol, Dimethylpyrazin, Methylquinoxalin und/oder Acetylpyrrolin oder
- (gg) orangenartigem Geruch, vorzugsweise Methyloctanoat, Undecanon, Decylalcohol, Limonen und/oder 2-Decenal oder
- (hh) Orangenschalen-artigem Geruch, vorzugsweise Decanal und/oder β-Carene oder
- (ii) pfirsichartigem Geruch, vorzugsweise γ-Nonalacton, (Z)-6-Dodecene-γ-lacton, δ-Decalacton, R-δ-Decenolacton, Hexylhexanoat, 5-Octanolid, γ-Decalacton und/oder δ-Undecalacton oder
- (jj) Pfefferminze-artigem Geruch, vorzugsweise Methylsalicylat und/oder I-Menthol oder
- (kk) Kiefer-artigem Geruch, vorzugsweise α-p-Dimethylstyrol, β-Pinene, Bornylbenzoat, δ-Terpinen, Dihydroterpinylacetat und/oder α-Pinen oder
- (II) ananasartigem Geruch, vorzugsweise Propylbutyrat, Propylpropanoat und/oder Ethylacetat oder
- (mm)pflaumenartigem Geruch, vorzugsweise Benzylbutanoat, oder
- (nn) himbeerartigem Geruch, vorzugsweise β-Ionone oder
- (oo) Rose-artigem Geruch, vorzugsweise β-Phenethylacetat, 2-Ethylhexanol, Geranylvalerat, Geranylacetat, Citronellol, Geraniol, Geranylbutyrat, Geranylisovalerat, Citronellylbutyrat, Citronellylacetat, Isogeraniol, Tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2,5-cis-2H-pyran, Isogeraniol, 2-Phenylethylalcohol, Citronellylvalerat und/oder Citronellylisobutyrat, oder
- (pp) Grüne Minze-artigem Geruch, vorzugsweise Carvylacetate und/oder Carveol, oder
- (qq) erdbeerenartigem Geruch, vorzugsweise Hexylmethylbutyrat, Methylcinnamat, Pentenal, Methylcinnamate oder
- (rr) süßlichem Geruch, vorzugsweise Benzylalcohol, Ethylphenylacetat, Tridecanal, Nerol, Methylhexanoat, Linalylisovalerat, Undecanaldehyd, Caryophyllenoxid, Linalylacetat, Safranal, Uncineol, Phenylethanal, p-Anisaldehyd, Eudesmol, Ethylmethylpyrazin, Citronellylbutyrat, 4-Methyl-3-penten-2-on, Nonylacetat, 10-Epi-γ-eudesmol, β-Bisabolol, (Z)-6-Dodecen-γ-lacton, β-Famesene, 2-Dodecenal, γ-Dodecalacton, Epoxy-β-ionon, 2-Undecenal, Styrenglycol, Methylfuraneol, (-)-cis-Rosenoxid, (E)-β-Ocimene, Dimethylmethoxyfuranon, 1,8-Cineole, Ethylbenzaldehyd, 2-Pentylthiophen, α-Farnesene, Methionol, 7-Methoxycoumarin, (Z)-3-Hexenyl-2-methylbutanoat, o-Aminoacetophenon, Viridiflorol, Isopiperitone, β-Sinensal, Ethylvanillat, Methylbutanoat, p-Methoxystyrol, 6-Methoxyeugenol, 4-Hexanolid, δ-Dodecalacton, Sesquiphellandren, Diethylmalat, Linalylbutyrat, Guaiacol, Coumarin, Methylbenzoat, Isopropylbenzoat, Safrole, Durene, γ-Butyrolacton, Ethylisobutyrat und/oder Furfural oder
- (ss) Vanille-artigem Geruch, vorzugsweise Vanillin, Methylvanillat, Acetovanillon und/oder Ethylvanillat oder
- (tt) wassermelonenartigem Geruch, vorzugsweise 2,4-Nonadienal oder
- (uu) holzartigem Geruch, vorzugsweise α-Muurolene, Cadina-1,4-dien-3-ol, Isocaryophyllene, Eudesmol, α-Ionon, Bornylbutyrat, (E)-α-Bergamoten, Linalooloxid, Ethylpyrazin, 10-epi-γ-Eudesmol, Germacrene B, trans-Sabinenhydrat, Dihydrolinalool, Isodihydrocarveol, β-Famesene, β-Sesquiphellandren, δ-elemente, α-Calacorene, Epoxy-β-ionon, Germacrene D, Bicyclogermacrene, Alloaromadendrene, α-Thujene, oxo-β-Ionon, (-)-γ-Elemene. γ-Muurolene, Sabinene, α-Guaiene, α-Copaene, γ-Cadinene, Nerolidol, β-Eudesmol, α-Cadinol, δ-Cadinene, 4,5-Dimethoxy-6-(2-propenyl)-1,3-benzodioxol, [1ar-(1aalpha,4aalpha,7alpha,7abeta,7balpha)]-decahydro-1,1,7-trimethyl-4-methylene-1H-cycloprop[e]azulen, α-Gurjunen, Guaiol, α-Farnesene, γ-Selinene, 4-(1-Methylethyl)-benzenemethanol, Perillen, Elemol, α-Humulene, β-Caryophyllene und/oder β-Guaiene oder
- (vv) Mischungen aus vorgenannten
- (a) almond-like odor, such as preferably benzaldehyde, pentanal, heptenal, 6-methylfurfural, methylbutanal, furfural and / or acetophenone or
- (b) apple-like odor, preferably (S) - (+) - ethyl-2-methylbutanoate, diethyl malonate, ethyl butyrate, geranylbulyral, geranylisopentanoate, isobutyl acetate, linalyl isopentanoate, (E) -β-damascone, heptyl-2-methyl butyrate, methyl 3-methylbulanoate, 2-hexenalpentylmethyl butyrate, ethylmethyl butyrate and / or methyl 2-methylbutanoate or
- (c) apple peel-like odor, such as preferably ethylhexanoate, hexylbutanoate and / or hexylhexanoate or
- (d) apricot-like odor, preferably γ-undecalactone, or
- (e) banana-like odor, such as preferably isobutyl acetate, isoamyl acetate, hexenyl acelate and / or pentyl butanoate or
- (f) bitter almond-like odor such as preferably 4-acetyltoluene or
- (g) blackcurrant-like odor, such as preferably mercaptomethylpentanone and / or methoxymethylbutanethiol or
- (c) citrus-like odor such as preferably linalyl pentanoate, heptanal, linalyl isopenlanoate dodecanal, linalyl formate, α-p-dimethylstyrene, p-cymenol, nonanal, β-cubebene, (Z) -liminene oxide, cis-6-ethenyl-tetrahydro-2,2,6- trimethylpyrene-3-ol, cis-pyranoidinalcoloxide, dihydrolinalool, 6 (10) -dihydromyrcenol, dihydromyrcenol, β-farnesene, (Z) -β-farnesene, (Z) -cimene, (E) -Limone oxide, Dihydroterpinylacetat, (+) - limonene, (Epoxymethylbutyl) -methylfuran and / or p-cymene or
- (i) cocoa like odor, preferably dimethylpyrazine, butylmethyl butyrate and / or methylbutanal or
- (j) coconut-like odor, preferably γ-octalactone, γ-nonalactone, methyl laurate, tetradecanol, methyl nonanoate, (35,3aS, 7aR) -3a, 4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2 (3H) -on, 5-butyldihydro-4-methyl-2 (3H) -furanone, ethyl undecanoate and / or δ-decalactone or
- (k) creamy odor such as preferably diethyl acetal, 3-hydroxy-2-butanone, 2,3-pentadione and / or 4-heptenal, or
- (l) flower-like odor such as preferably benzyl alcohol, phenylacetic acid, tridecanal, p-anisyl alcohol, hexanol, (E, E) -farnesylacetone, methyl geranate, trans-crotonaldehyde, tetradecylaldehyde, methyl anthranilate, linalooloxide, epoxylinalool, phytol, 10-epi-γ-eudesmol , Nerol oxide, ethyldihydrocinnamate, γ-dodecalactone, hexadecanol, 4-mercapto-4-methyl-2-pentanol, (Z) -oximes, cetyl alcohol, nerolidol, ethyl (E) -cinnamate, elemicin, pinocarveol, α-bisabolol, ( 2R, 4R) -Tetrahydro-4-methyl-2- (2-methyl-1-propenyl) -2H-pyran, (E) -Isoelemicin, methyl 2-methylpropanoate, trimethylphenylbutenone, 2-methylanisole, β-farnesol, ( E) isoeugenol, nitro-phenylethane, ethyl vanillate, 6-methoxyeugenol, linalool, β-ionone, trimethylphenylbutenone, ethyl benzoate, phenylethyl benzoate, isoeugenol and / or acetophenones or
- (m) freshness odor, preferably methylhexanoate, undecanone, (Z) -limonoxide, benzylacetate, ethylhydroxyhexanoate, isopropylhexanoate, pentadecanal, β-elemene, α-zingiberene, (E) -liminic oxide, (E) -p-mentha-2, 8-dien-1-ol, menthone, piperone, (E) -3-hexenol and / or carveol or
- (n) Fruit odor, such as ethylphenylacetate, geranylvalerate, γ-heptalactone, ethylpropionate, diethylacetal, geranylbutyrate, ethylheptylate, ethyloctanoate, methylhexanoate, dimethylheptenal, pentanone, ethyl-3-methylbutanoate, geranylisovalerate, lobutylacetate, ethoxypropanol, methyl-2-butenal, Methylnonanedione, linalyl acetate, methyl geranate, lmone oxide, hdrocinnamiccohol, ethylsuccinate, ethylhexanoate, ethylmethylpyrazine, β-cbene, nylate, ctronellylbutyrate, heylacetate, nonylacetate, butylmethylbutyrate, pentenal, isopentyldimethylpyrazine, p-menth-1-en-9-ol, hexadecanone, octylacetate, γ-dodecalactone, epoxy β-ionone, ethyloctenoate, ethylisohexanoate, isobornyl propionate, cedrenol, p-menth-1-en-9-yl acetate, cadinadiene, (Z) -3-hexenylhexanoate, ethylcyclohexanoate, 4-methylthio-2-butanone , 3,5-octadienone, methylcyclohexanecarboxylate, 2-pentylthiophene, α-ocimene, butanediol, ethylvalerate, pentanol, isopiperiton, butyl octanoate, ethyl vanillate, methyl butanoate, 2-methylbutyl acetate, propyl hexanoate, Butyl hexanoate, isopropyl butanoate, spathulenol, butanol, 6-dodecalactone, methylquinoxaline, sesquiphenilene, 2-hexenol, ethyl benzoate, isopropyl benzoate, ethyl lactate and / or citronellyl isobutyrate or
- (o) Geranium-like odor, such as preferably geraniol, (E, Z) -2,4-nonadienal, octadienone and / or o-xylene or
- (p) grape-like odor such as preferably ethyl decanoate and / or hexanone or
- (q) grapefruit-like odor such as preferably (+) - 5,6-dimethyl-8-isopropenylbicyclo [4.4.0] dec-1-en-3-one and / or p-menthenethiol or
- (R) grassy odor such as preferably 2-ethylpyridine, 2,6-dimethylnaphthalene, hexanal and / or (Z) -3-hexenol or
- (s) green note, preferably 2-ethylhexanol, 6-decenal, dimethylheptenal, hexanol, heptanol, methyl-2-butenal, hexyloctanoates, nonanoic acid, undecanone, methyl geranate, isobornylformiate, butanal, octanal, nonanal, epoxy-2-decenal, cis -Linalool, pyranoxide, nonanol, alpha, γ-dimethylallylalcohol, (Z) -2-penten-1-ol, (Z) -3-hexenylbutanoate, isobutylthiazole, (E) -2-nonenal, 2-dodecenal, (Z) 4-decenal, 2-octenal, 2-hepten-1-al, bicyclo mermose, 2-octenal, α-thujene, (Z) -β-farnesene, (-) - γ-elemene, 2,4-octadienal, fucoserrate , Hexenylacetate, geranylacetone, valencene, β-eudesmol, 1-hexenol, (E) -2-undecenal, artemisia ketone, viridiflorol, 2,6-nonadienal, trimethylphenylbutenone, 2,4-nonadienal, butylisothiocyanate, 2-pentanol, elemole, 2-hexenal, 3-hexenal, (+) - (E) -lone oxide, cis-isocitral, dimethyloctadienal, bornyl formate, bornyl isovalerate, isobutyraldehyde, 2,4-hexadienal, trimethylphenylbutenone, nonanone, (E) -2-hexenal, (+) - cis-Rosenoxide, Menthone, Coumarin, (Epoxymethylbutyl) -methylfur on, 2-hexenol, (E) -2-hexenol and / or carvyl acetate or
- (t) Green Tea-like odor, preferably (-) - Cubenol or
- (u) herbaceous odor, preferably octanone, hexyloctanoate, caryophyllene oxides, methylbutenol, safranal, benzyl benzoate, bornyl butyrate, hexyl acetate, β-bisabolol, piperitol, β-selenene, α-cubebene, p-menth-1-en-9-ol, 1 , 5,9,9-tetramethyl-12-oxabicyclododeca-4,7-diene, T-muurolol, (-) - cubenol, levomenol, ocimene, α-thujene, p-menth-1-en-9-yl acetate, Dehydrocarveol, Artemisia alcohol, γ-Muurolene, hydroxypentanone, (Z) -Ocimene, β-elemene, δ-cadinol, (E) -β-Ocimene, (Z) -dihydrocarvone, α-cadinol, calamenene, (Z) -piperitol , Lavandulol, β-bourbonene, (Z) -3-hexenyl-2-methylbutanoate, 4- (1-methylethylbenzenemethanol, artemisia ketone, methyl-2-butenol, heptanol, (E) -dihydrocarvone, p-2-menthene 1-ol, α-Curcumene, Spathulenol, Sesquiphellandren, Citronellylvalerat, Bornylisovalerat, 1,5-octadien-3-ol, methyl benzoate, 2,3,4,5-tetrahydroanisole and / or Hydroxycalamenen or
- (v) honey-like odor, preferably ethyl cinnamate, β-phenethyl acetate, phenylacetic acid, phenylethanal, methyl anthranilate, cinnamic acid, β-damascenone, ethyl (E) -cinnamate, 2-phenylethylalcohol, citronellyl valerate, phenylethyl benzoate and / or eugenol or
- (w) Hyacinth-like odor, preferably Hotrienol or
- (x) jasmine-like odor, preferably methyl jasmonate, methyldihydroepijasmonate and / or methylepijasmonate or
- (y) lavender-like odor, preferably linalyl valerate and / or linalool or
- (z) lemon-like odor, preferably, neral, octanal, δ-3-carene, limonene, geranial, 4-mercapto-4-methyl-2-pentanol, citral, 2,3-dehydro-1,8-cineol and / or α -Terpines or
- (aa) lily-like odor, preferably dodecanal or
- (bb) magnolia-like odor, preferably geranylacetone or
- (cc) mandarin-like odor, preferably undecanol or
- (dd) melon-like odor, preferably dimethylheptenal or
- (ee) minty odor, preferably menthone, ethyl salicylate, p-anisaldehyde, 2,4,5,7a-tetra-hydro-3,6-dimethylbenzofuran, epoxy-p-menthene, geranial, (methylbutenyl) -methylfuran , Dihydrocarvyl acetate, β-cyclocitral, 1,8-cineole, β-phellandrene, methylpentanone, (+) - limonene, dihydrocarveol (-) - carvone, (E) -p-mentha-2,8-dien-1-ol, Isopulegyl acetate, piperitone, 2,3-dehydro-1,8-cineol, α-terpineol, DL-carvone and / or α-phellandrene or
- (ff) Nutty odor, preferably 5-methyl- (E) -2-hepten-4-one, γ-heptalactone, 2-acetylpyrrole, 3-octen-2-one, dihydromethylcyclopentapyrazine, acetylthiazole, 2-octenal, 2,4 Heptadienal, 3-octenone, hydroxypentanone, octanol, dimethylpyrazine, methylquinoxaline and / or acetylpyrroline or
- (gg) orange-like odor, preferably methyloctanoate, undecanone, decyl alcohol, limonene and / or 2-decenal or
- (hh) orange peel-like odor, preferably decanal and / or beta-carene or
- (ii) peach-like odor, preferably γ-nonalactone, (Z) -6-dodecene-γ-lactone, δ-decalactone, R-δ-decenolactone, hexylhexanoate, 5-octanolide, γ-decalactone and / or δ-undecalactone or
- (jj) peppermint-like odor, preferably methyl salicylate and / or I-menthol or
- (kk) pine-like odor, preferably α-p-dimethylstyrene, β-pinene, bornyl benzoate, δ-terpinene, dihydroterpinyl acetate and / or α-pinene or
- (II) pineapple-like odor, preferably propyl butyrate, propyl propanoate and / or ethyl acetate or
- (mm) plum-like odor, preferably benzyl butanoate, or
- (nn) raspberry-like odor, preferably β-ionone or
- (oo) Rose-like odor, preferably β-phenethyl acetate, 2-ethylhexanol, geranyl valerate, geranyl acetate, citronellol, geraniol, geranyl butyrate, geranyl isovalerate, citronellyl butyrate, citronellyl acetate, isogeraniol, tetrahydro-4-methyl-2- (2-methyl-1) propenyl) -2,5-cis-2H-pyran, isogeraniol, 2-phenylethyl alcohol, citronellyl valerate and / or citronellyl isobutyrate, or
- (pp) spearmint-like odor, preferably carvylacetate and / or carveol, or
- (qq) strawberry-like odor, preferably hexylmethyl butyrate, methyl cinnamate, pentenal, methyl cinnamate or
- (rr) sweet odor, preferably benzyl alcohol, ethyl phenylacetate, tridecanal, nerol, methylhexanoate, linalyl isovalerate, undecanedehyde, caryophyllene oxide, linalyl acetate, safranal, uncinol, phenylethanal, p-anisaldehyde, eudesmol, ethylmethylpyrazine, citronellylbutyrate, 4-methyl-3-pentene-2 -on, nonyl acetate, 10-epi-γ-eudesmol, β-bisabolol, (Z) -6-dodecene-γ-lactone, β-famesenes, 2-dodecenal, γ-dodecalactone, epoxy-β-ionone, 2-undecenal , Styrene glycol, methylfuraneol, (-) - cis-rose oxide, (E) -β-ocimene, dimethylmethoxyfuranone, 1,8-cineole, ethylbenzaldehyde, 2-pentylthiophene, α-farnesene, Methionol, 7-methoxycoumarin, (Z) -3-hexenyl-2-methylbutanoate, o-aminoacetophenone, viridiflorol, isopiperitones, β-sinensal, ethyl vanillate, methyl butanoate, p-methoxystyrene, 6-methoxyeugenol, 4-hexanolide, δ-dodecalactone, Sesquiphellandrene, diethyl malate, linalyl butyrate, guaiacol, coumarin, methyl benzoate, isopropyl benzoate, safroles, durene, γ-butyrolactone, ethyl isobutyrate and / or furfural or
- (ss) vanilla-like odor, preferably vanillin, methyl vanillate, acetovanillon and / or ethyl vanillate or
- (tt) watermelon-like odor, preferably 2,4-nonadienal or
- (uu) woody odor, preferably α-muurolene, cadina-1,4-dien-3-ol, isocaryophyllene, eudesmol, α-ionone, bornyl butyrate, (E) -α-bergamotene, linalooloxide, ethylpyrazine, 10-epi-γ Eudesmol, germacrene B, trans-sabine hydrate, dihydrolinalool, isodihydrocarveol, β-feamenes, β-sesquiphellandrene, δ-elements, α-calacorene, epoxy-β-ionone, germacrene D, bicyclogermacrene, alloaromadendrene, α-thujene, oxo-β Ionone, (-) - γ-elemene. γ-Muurolene, Sabinene, α-Guaiene, α-Copaene, γ-Cadinene, Nerolidol, β-Eudesmol, α-Cadinol, δ-Cadinene, 4,5-Dimethoxy-6- (2-propenyl) -1,3- benzodioxole, [1ar- (1aalpha, 4aalpha, 7alpha, 7abeta, 7balpha)] - decahydro-1,1,7-trimethyl-4-methylene-1H-cycloprop [e] azulen, α-gurjunen, guaiol, α-farnesene, γ-seleneins, 4- (1-methylethyl) -benzenemethanol, Perillen, Elemol, α-Humulenes, β-Caryophyllene and / or β-Guaiene or
- (vv) mixtures of the above
So kann der Verbraucher z.B. Geschirrspülwasser mit bananenartigem Geruch erzeugen, Badewasser mit vanilleartigem Geruch oder beispielsweise Fensterspülwasser mit honigartigem Geruch. Er kann durch Kombination unterschiedlicher Formkörper auch völlig neue Geruchsbilder erzeugen.So the consumer can e.g. Create dishwashing water with a banana-like odor, bath water with a vanilla-like odor or, for example, window rinse water with a honey-like odor. He can also create completely new odor images by combining different moldings.
Bei entsprechenden Anwendungen kann sich auch ein so genannter aromatherapeutischer Zusatznutzen für den Verbraucher einstellen. Beispielsweise können auch natürliche Duftstoffe etherischer Öle eingesetzt werden. Typische Beispiele sind Kamille, Rosmarin, Thymian, Jasmin, Pfefferminze und Sandelholz. Der Verbraucher kann so durch die Auswahl von Duftstoffen Einfluss auf sein subjektives Wohlgefühl nehmen, und z.B. psychosomatisch mitverursachten Beschwerden wie beispielsweise Nervosität oder Stress mit dem Einsatz entsprechend parfümierter Formkörper begleiten. Auch als begleitende Mittel bei Erkältungskrankheiten oder nervösen Magen-Darm-Störungen können entsprechende Formkörper eingesetzt werden, um das subjektive Wohlgefühl zu unterstützen. Es handelt sich hier allerdings nicht um ein therapeutisches Verfahren im eigentlichen Sinne, sondern um ein geruchskosmetisches Verfahren.With appropriate applications, a so-called aromatherapeutischer added benefit for the consumer can be adjusted. For example, natural fragrances of essential oils can be used. Typical examples are chamomile, rosemary, thyme, jasmine, peppermint and sandalwood. The consumer can thus influence the subjective sense of well-being by selecting fragrances, and e.g. Psychosomatically concomitant complaints such as nervousness or stress accompany with the use of perfumed moldings. Also as an adjunctive remedy for colds or nervous gastrointestinal disorders appropriate moldings can be used to support the subjective well-being. However, this is not a therapeutic process in the true sense, but an odor-cosmetic process.
Die bereits beschriebene Set-Konfiguration eignet sich beispielsweise auch zur Gestaltung eines Duftkarussels.The set configuration already described is also suitable, for example, for designing a scent carousel.
Karussellkonfiguationen sind insbesondere aus dem Bereich der Gewürzkarussells bekannt. Das sind In der Regel drehbare Gebilde, welche zumindest 4 oder mehr, belspielsweise bis zu 12 einzelne, entnehmbaren Behälter umfassen, die rundförmig auf einem Ständer oder einer Haltveorrichtung angeordnet sind. Ein solches Duftkarussell mit z.B. 12 Behältern, welche unterschiedliche Duftformkörper umfassen, kann sogar schon als so genannte Duftorgel bezeichnet werden, mit welcher der Verbraucher einen Individualduft komponieren kann.Carousel configurations are known in particular from the field of spice carousel. These are usually rotatable structures, which comprise at least 4 or more, for example up to 12 individual, removable containers which are arranged in a round shape on a stand or a holding device. Such a perfume carousel with e.g. 12 containers, which comprise different fragrance tablets, may even be referred to as a so-called fragrance organ, with which the consumer can compose an individual fragrance.
Nach einer bevorzugten Ausführungsform enthält der erfindungsgemäße Formköper zumindest 12 Gew.-% Parfüm, vorzugsweise zumindest 15 Gew.-% Parfüm, insbesondere zumindest 20 Gew.-% Parfüm, bezogen auf den gesamten Formkörper. Ebenso kann der Formkörper auch noch größere Mengen an Parfüm enthalten, z.B. zumindest 25, 30. 35, 40, 45 oder gar zumindest 60 Gew.-% Parfüm. Sinnvolle Obergrenzen an Parfüm können z.B. bei 80 Gew.-%, 75 Gew.-%, 70 Gew.-%, 65 Gew.-%, 60 Gew.-%, 55 Gew.-%. 50 Gew.-%, 45 Gew.-%, 40 Gew.-%, 35 Gew.-%, 30 Gew.-%. 25 Gew.-%, 20 Gew.-%, 15 Gew.-% oder auch 10 Gew.-% liegen.According to a preferred embodiment, the molded article according to the invention contains at least 12% by weight of perfume, preferably at least 15% by weight of perfume, in particular at least 20% by weight of perfume, based on the total molding. Likewise, the molded article may also contain larger amounts of perfume, e.g. at least 25, 30, 35, 40, 45 or even at least 60% by weight of perfume. Useful upper limits of perfume may e.g. at 80 wt%, 75 wt%, 70 wt%, 65 wt%, 60 wt%, 55 wt%. 50 wt%, 45 wt%, 40 wt%, 35 wt%, 30 wt%. 25 wt .-%, 20 wt .-%, 15 wt .-% or 10 wt .-% are.
Wenn das enthaltene Parfüm zu mindestens 5, 10 oder 15 Gew.-% aus Riechstoffen mit einem Siedepunkt über 250°C und einem logP-Wert von ≥ 3,0 besteht, so liegt eine bevorzugte Ausführungsform vor. Es hat sich gezeigt, dass erfindungsgemäße Formkörper, weiche solche Mindestmengen an Riechstoffen mit einem Siedepunkt über 250°C und einem logP-Wert von ≥ 3,0 enthalten, besonders vorteilhafte Dufteigenschaften aufweisen. Beispielsweise kann bei der Verwendung der Formkörper in wässrigen Systemen ein länger anhaltender Dufteindruck erzielt werden. Ebenso kann das Aufziehverhalten der Riechstoffe auf Substrate, welche in/mit dem parfümierten wässrigen System behandelt werden, weiter verbessert werden, so dass dia Substrate, insbesondere Textilien länger und intensiver riechen.If the perfume contained at least 5, 10 or 15 wt .-% of fragrances having a boiling point above 250 ° C and a logP value of ≥ 3.0, so is a preferred embodiment. It has been found that moldings according to the invention which contain such minimum amounts of fragrances having a boiling point above 250 ° C. and a logP value of ≥ 3.0 have particularly advantageous scent properties. For example, a longer-lasting fragrance impression can be achieved when using the shaped bodies in aqueous systems. Likewise, the Aufziehverhalten the fragrances on substrates which are treated in / with the perfumed aqueous system, further improved, so that dia substrates, especially textiles longer and more intense smell.
Der Octanol/Wasser-Verteilungskoeffizient eines Duftstoff-Bestandteils ist das Verhältnis zwischen seiner Gleichgewichlskonzentration in Octanol und in Wasser. Da die Verteilungskoeffizienten der Duftstoffbestandteile oft hohe Werte haben, z.B. 1000 oder höher, werden sie zweckmäßiger in der Form ihres Logarithmus zur Basis 10 angegeben, man spricht dann vom so genannten log-P-Wert. Bevorzugte Riechstoffe dieser Erfindung weisen einen logP von ≥ 3,0 oder höher auf, z. B. von ≥ 3.1. vorzugsweise ≥ 3.2, insbesondere ≥ 3,3.The octanol / water partition coefficient of a perfume ingredient is the ratio between its equilibrium concentration in octanol and in water. Since the distribution coefficients of the perfume ingredients are often high, e.g. 1000 or higher, they are more conveniently given in the form of their base 10 logarithm, one speaks of the so-called log P value. Preferred fragrances of this invention have a logP of ≥ 3.0 or higher, e.g. From ≥ 3.1. preferably ≥ 3.2, in particular ≥ 3.3.
Der logP-Wert zahlreicher Riechstoffe ist dokumentiert; zum Beispiel enthält die Pomona92-Datenbank, verfügbar von Daylight Chemical information Systems, Inc., (Daylight CIS), Irvine, Kalifornien, zahlreiche logP-Werte, zusammen mit Zitaten zur Originalliteratur. Jedoch werden die logP-Werte am zweckmäßigsten durch das "CLOGP"-Programm, das auch von Daylight CIS verfügbar ist, berechnet. Dieses Programm führt auch die experimentellen logP-Werte auf, wenn sie in der Pomona92-Datenbank verfügbar sind. Der "errechnete logP" (ClogP-Wert) wird durch die Fragmentannäherung nach Harsch und Leo bestimmt.The logP value of numerous fragrances is documented; For example, the Pomona92 database, available from Daylight Chemical Information Systems, Inc., (Daylight CIS), Irvine, California, contains numerous logP values, along with citations to the original literature. However, the logP values are most conveniently calculated by the "CLOGP" program, which is also available from Daylight CIS. This program also lists the experimental logP values if they are available in the Pomona92 database. The "calculated logP" (ClogP value) is determined by the fragment approximation according to Harsch and Leo.
Im folgenden werden in Tabelle 1 etliche Riechstoffe aufgeführt, welche die Kriterien Siedepunkt > 250°C und ClogP ≥ 3 erfüllen. Solche Riechstoffe, welche diese Kriterien erfüllen, werden im weiteren Verlauf auch als beständige Riechstoffe bezeichnet.
Diese Tabelle gibt eine hinreichende Anzahl nichteinschränkender Beispiele für beständige Riechstoffe, welche im Rahmen dieser Erfindung bevorzugt einsetzbar sind. Die Formkörper der vorliegenden Erfindung enthalten vorzugsweise mindestens 3 unterschiedliche beständige Riechstoffe, stärker bevorzugt mindestens 4 unterschiedliche beständige Riechstoffe, und noch weiter bevorzugt mindestens 5 unterschiedliche beständige Riechstoffe.This table gives a sufficient number of non-limiting examples of persistent fragrances which are preferred for use in this invention. The shaped articles of the present invention preferably contain at least 3 different resistant fragrances, more preferably at least 4 different resistant fragrances, and even more preferably at least 5 different resistant fragrances.
Gemäß einer bevorzugten Ausführungsform der Erfindung enthalten die Formkörper vorzugsweise ≥ 20 Gew.-%, ≥ 25 Gew.-%, ≥ 30 Gew.-%, ≥ 35 Gew.-%, ≥ 40 Gew.-%, ≥ 45 Gew.-%, ≥ 50 Gew.-%, ≥ 55 Gew.-%, ≥ 60 Gew.-%, ≥ 65 Gew.-%, ≥ 75 Gew.-%, ≥ 80 Gew.-%, ≥ 85 Gew.-%, ≥ 90 Gew.-% oder sogar ≥ 95 Gew.-% an beständigen Riechstoffen, Gew.-% bezogen auf die Gesamtmenge der im Formkörper enthaltenen Riechstoffe.According to a preferred embodiment of the invention, the shaped bodies preferably contain ≥20% by weight, ≥25% by weight, ≥30% by weight, ≥35% by weight, ≥40% by weight, ≥45% by weight. %, ≥50 wt%, ≥55 wt%, ≥60 wt%, ≥65 wt%, ≥75 wt%, ≥80 wt%, ≥85 wt% , ≥ 90 wt .-% or even ≥ 95 wt .-% of resistant fragrances, wt .-% based on the total amount of the fragrances contained in the molding.
Im Duftstofffachbereich werden einige Materialien ohne Geruch oder mit sehr schwachem Geruch als Verdünnungsmittel oder Streckmittel für Parfüms verwendet. Nichteinschränkende Beispiele dieser Materialien sind Dipropylenglykol, Diethylphthalat, Triethylcitrat, Isopropylmyristat und Benzylbenzoat. Diese Materialien werden z.B. zum Verdünnen und Stabilisieren einiger anderer Duftstoffbestandteile verwendet. Diese Materialien werden bei der Berechnung der Gesamtmenge der im Formkörper enthaltenen Riechstoffe nicht mitgerechnet.In the perfume compartment, some non-odor or very low odor materials are used as perfume diluents or extenders. Nonlimiting examples of these materials are dipropylene glycol, diethyl phthalate, triethyl citrate, isopropyl myristate and benzyl benzoate. These materials are e.g. used to dilute and stabilize some other perfume ingredients. These materials are not included in the calculation of the total amount of fragrances contained in the molding.
Nicht-beständige Riechstoffe sind im Rahmen dieser Erfindung solche Riechstoffe, welche einen Siedepunkt von niedriger als etwa 250°C oder einen ClogP von weniger als etwa 3,0 oder sowohl einen Siedepunkt von weniger als etwa 250°C und einen ClogP von weniger als etwa 3,0 aufweisen. Nach einer bevorzugten Ausführungsform werden nicht-beständige Riechstoffe vorzugsweise in den Formkörpern der vorliegenden Erfindung minimiert , d.h. die Formkörper enthalten vorzugsweise ≤ 60 Gew.-%, ≤ 55 Gew.-%, ≤ 50 Gew.-%, ≤ 45 Gew.-%, ≤ 40 Gew.-%, ≤ 35 Gew.-%, ≤ 30 Gew.-%, ≤25 Gew.-%, ≤ 20 Gew.-%, ≤ 15 Gew.%, ≤ 10 Gew.-%, ≤ 5 Gew.-%, ≥ 3 Ges.-%, ≥ 2 Gew.-% oder sogar ≥ 1 Gew.-% an nichtbeständigen Riechstoffen, Gew.-% bezogen auf die Gesamtmenge der im Formkörper enthaltenen Riechstoffe.Non-resistant fragrances in the context of this invention are those fragrances which have a boiling point of less than about 250 ° C or a ClogP of less than about 3.0, or both a boiling point of less than about 250 ° C and a ClogP of less than about 3.0. According to a preferred embodiment, non-resistant fragrances are preferably minimized in the shaped bodies of the present invention, ie the shaped bodies preferably contain ≦ 60% by weight, ≦ 55% by weight, ≦ 50% by weight, ≦ 45% by weight. , ≤ 40 wt%, ≤ 35 wt%, ≤ 30 wt%, ≤ 25 wt%, ≤ 20 wt%, ≤ 15 wt%, ≤ 10 wt%, ≤ 5 wt .-%, ≥ 3 Ges .-%, ≥ 2 wt .-% or even ≥ 1 wt .-% of non-resistant fragrances, wt .-% based on the total amount of fragrances contained in the molding.
Es kann aber vorteilhaft sein, wenn nicht beständige Riechstoffe zumindest in kleinen Mengen verwendet werden, nämlich zur Verbesserung des Formkörpergeruchs als solchem. Vorzugsweise enthallen die Formkörper der vorliegenden Erfindung daher ≥ 1 Gew.-%, vorzugsweise ≥ 5 Gew.-%, stärker bevorzugt ≥ 10 Gew.-%, noch stärker bevorzugt ≥ 15 Gew.-%, insbesondere sogar ≥ 20. ≥ 25 oder sogar ≥ 30 Gew.-%, an nicht beständigen Riechstoffen, Gew.-% bezogen auf die Gesamtmenge der Im Formkörper enthaltenen Riechstoffe.However, it may be advantageous if non-resistant fragrances are used at least in small amounts, namely to improve the odor of the molded article as such. The shaped bodies of the present invention therefore preferably contain ≥1% by weight, preferably ≥5% by weight, more preferably ≥10% by weight, even more preferably ≥15% by weight, in particular even ≥20, ≥25 or even ≥ 30 wt .-%, of non-resistant fragrances, wt .-% based on the total amount of fragrances contained in the molding.
Das im Formkörper enthaltene Parfüm liegt zumindest zu 5 Gew.% in verkopselter Form vor. Der Anteil des enthaltenen Parfüms in verkapselter Form kann auch noch größer sein, z.B. bei Werten von zumindest 10, 15, 20, 25, 30, 35, 40 oder 45 Gew.-% liegen. Gew.-% bezieht sich dabei auf die Gesamtmenge des im Formkörper enthaltenen Parfüms.The perfume contained in the molding is at least 5% by weight in an encapsulated form. The proportion of the contained perfume in encapsulated form may be even greater, e.g. at values of at least 10, 15, 20, 25, 30, 35, 40 or 45 wt .-% are. Wt .-% refers to the total amount of the perfume contained in the molding.
Vorzugsweise sind die verkapselten Parfümteilchen durch Feuchtigkeit aktivierbar. Solche Parfümteilchen sind bekannt. Es kann sich beispielsweise um Cyclodextrin/Parfüm-Einschlußkomplexe oder um Parfüm-Mikrokapseln, z.B. mit einem Polysaccharin-Bindemittel handeln. Das Verkapseln des Parfüms minimiert eine vorzeitige Verflüchtigung der Riechstoffe noch weiter. Das verkapseite Parfüm wird erst dann freigeseizt. wenn die Materialien befeuchtet werden.Preferably, the encapsulated perfume particles are activated by moisture. Such perfume particles are known. They may be, for example, cyclodextrin / perfume inclusion complexes or perfume microcapsules, e.g. act with a polysaccharin binder. The encapsulation of the perfume minimizes premature volatilization of the fragrances even further. The verkapseit perfume is only then released. when the materials are moistened.
Die Parfümkapseln können beispielsweise einen Durchmesser von 100 nm bis z.B. 1 mm aufweisen. Es ist auch möglich. Parfümkapseln zu verwenden, die einen Durchmesser über 1 mm aufweisenFor example, the perfume capsules may have a diameter of 100 nm to e.g. 1 mm. It is also possible. To use perfume capsules that are larger than 1 mm in diameter
Bevorzugte Parfüm-Mikrokapseln haben z.B. einen Durchmesser von 0,5 µm bis 300 µm, vorzugsweise 1 µm bis 200 µm, insbesondere 2 µm bis 100µm. Der Kapseidurchmesser ist selbstverständlich auf die Foliendicke abzustimmen. Der maximale Kapseldurchmesser kann z.B. auch bei Werten < 90 µm, < 80 µm, < 70 µm, < 60 µm, < 50 µm oder < 40 µm liegen.Preferred perfume microcapsules have e.g. a diameter of 0.5 .mu.m to 300 .mu.m, preferably 1 .mu.m to 200 .mu.m, in particular 2 .mu.m to 100 .mu.m. The Kapseidurchmesser is of course to vote on the film thickness. The maximum capsule diameter may e.g. even at values <90 μm, <80 μm, <70 μm, <60 μm, <50 μm or <40 μm.
Besonders brauchbare Verfahren der Einkapselung schließen Coacervation, Liposomenbildung. Granulierung. Beschichtung, Emulgierung, Zerstäubung und Sprühkühlen ein.Particularly useful methods of encapsulation include coacervation, liposome formation. Granulation. Coating, emulsification, atomization and spray cooling.
Gemäß der vorliegenden Erfindung können die Kapseln in eine vorzugsweise in Wasser lösliche Folie eingearbeitet werden. Die Kapseln sind mit der Folie vorzugsweise nicht mischbar. Vorteilhafterweise sind die Kapseln in der Beschaffenheit hydrophob, um ihre Diffusion in die hydrophile Folie zu verhindern. Beispielsweise können die Kapseln vorzugsweise in situ in der Folie als Teil des Foliengießverfahrens hergestellt werden.According to the present invention, the capsules can be incorporated into a preferably water-soluble film. The capsules are preferably immiscible with the film. Advantageously, the capsules are hydrophobic in nature to prevent their diffusion into the hydrophilic film. For example, the capsules may preferably be prepared in situ in the film as part of the film casting process.
Der vorzugsweise hydrophobe Bestandteil für die Kapseln ist insbesondere ausgewählt aus der Gruppe, bestehend aus Paraffin, Wachs, Öl, Vaseline, einem hydrophoben Polymer und Gemischen davon.The preferably hydrophobic ingredient for the capsules is especially selected from the group consisting of paraffin, wax, oil, vaseline, a hydrophobic polymer, and mixtures thereof.
Bei der in-situ-Hersteltung wird die z.B. hydrophobe kontinuierliche Phase geschmolzen und kann dann mit entweder einem In Öl löslichen Vorteilsmittel (wie z.B. Parfüm) oder einer diskontinuierlichen Phase oder beldem vermischt wurden. Die erhaltene Lösung oder Emulsion oder Dispersion wird mit einer Lösung einer in Wasser löslichen Folie in Wasser (beispielsweise Verhältnis von Folie zu Wasser 1:4) vermischt. Das Gemisch wird vorzugsweise bei einer relativ niedrigen Temperatur hergestellt, um empfindliche Vorteilsbestandteile, falls vorliegend (beispielsweise 30-45°C), zu schützen. Das Ergebnis ist eine Emulsion In der In Wasser löslichen Folie. Die Emulsion wird gegossen und z.B. in einem Ofen gesintert, unter Bildung einer Folie mit Kapseln.In in-situ production, the e.g. hydrophobic continuous phase and then mixed with either an oil-soluble benefit agent (such as perfume) or a discontinuous phase or blender. The resulting solution or emulsion or dispersion is mixed with a solution of a water-soluble film in water (for example, ratio of film to water 1: 4). The mixture is preferably prepared at a relatively low temperature to protect sensitive benefit components, if present (eg, 30-45 ° C). The result is an emulsion in the water-soluble film. The emulsion is poured and e.g. sintered in an oven to form a film with capsules.
Nach einer bevorzugten Ausführungsform enthält der erfindungsgemäße Formkörper Riechstoffvorläufer, welche vorzugsweise erst bei Gegenwart von H2O Riechstoffe durch Hydrolyse freisetzen. Die Riechstoffvorläufer können vorteilhafterweise ausgewählt sein aus β-Aminoketon-Riechsloffvorläufern, Aldehyd- oder Keton-freisetzenden Riechstoffvorläufem, Alkoholfreisetzenden Riechstoffvorläufern, vorzugsweise Kieselsäureestern sowie Orthocarbonat- und Orthoester-Riechstoffverläufern.According to a preferred embodiment, the molding according to the invention contains perfume precursors, which preferably release fragrances by hydrolysis only in the presence of H 2 O. The perfume precursors may advantageously be selected from β-aminoketone scavenger precursors, aldehyde- or ketone-releasing perfume precursors, alcohol-releasing perfume precursors, preferably silicic acid esters, and orthocarbonate and ortho ester perfume extenders.
Vortailhafterweise sind die Riechstoffvorläufer ausgewählt aus Acetalen, Ketalen, Orthoestern, Orthocarbonaten und Mischungen hiervon.Advantageously, the fragrance precursors are selected from acetals, ketals, orthoesters, orthocarbonates, and mixtures thereof.
Ein besonders bevorzugter Riechstoffvorläufer gehorcht der Formel
Nach einer bevorzugten Ausführungsform ist als Riechstoffvorläufer ein Acetal oder ein Ketal der Formel
worin R lineares C1-C20-Alkyl, verzweigtes C3-C20-Alkyl, cyclisches C6-C20-Alkyl, verzweigtes cyclisches C6-C20-Alkyl, lineares C2-C20-Alkenyl, verzweigtes C3-C20-Alkenyl, cyclisches C6-C20-Alkenyl, verzweigtes cyclisches C6-C20-Alkenyl, substituiertes oder unsubstituiertes C6-C20-Aryl und Mischungen hiervon ist; R1 ist Wasserstoff oder R;
R2 und R3 sind jeweils unabhängig voneinander gewählt aus der Gruppe, bestehend aus lineares C1-C20-Alkyl, verzweigtes C3-C20-Alkyl, cyclisches C3-C20-Alkyl, verzweigtes cyclisches C6-C20-Alkyl, lineares C6-C20-Alkenyl, verzweigtes C6-C20-Alkenyl, cyclisches C6-C20-Alkenyl, verzweigtes cyclisches C6-C20-Alkenyl, C6-C20-Aryl, substituiertes C7-C20-Aryl und Mischungen hiervon.According to a preferred embodiment, the fragrance precursor is an acetal or a ketal of the formula
in which R is linear C 1 -C 20 -alkyl, branched C 3 -C 20 -alkyl, cyclic C 6 -C 20 -alkyl, branched cyclic C 6 -C 20 -alkyl, linear C 2 -C 20 -alkenyl, branched C 3 -C 20 alkenyl, C 6 -C 20 cyclic alkenyl, branched cyclic C 6 -C C 6 -C 20 alkenyl, substituted or unsubstituted 20 aryl, and mixtures thereof; R 1 is hydrogen or R;
R 2 and R 3 are each independently selected from the group consisting of linear C 1 -C 20 alkyl, branched C 3 -C 20 alkyl, cyclic C 3 -C 20 alkyl, branched cyclic C 6 -C 20 Alkyl, linear C 6 -C 20 alkenyl, branched C 6 -C 20 alkenyl, cyclic C 6 -C 20 alkenyl, branched cyclic C 6 -C 20 alkenyl, C 6 -C 20 aryl, substituted C 7 -C 20 aryl and mixtures thereof.
Nach einer bevorzugten Ausführungsform ist ein Riechstoffvorläufer mit folgender Formel enthalten:
Der Einsatz entsprechender Riechstoffvorläufer führt zu Formkörpern mit einem hervorragendem Duftverhalten in wässrigen Systemen, insbesondere was Länge und Dauer des resultierenden Dufteindrucks, auch auf behandelten Substraten, wie insbesondere Textil, anbetrifft. Vor allem die Kombination von Riechstoffvorläufern mit den oben erwähnten beständigen Riechstoffen und/oder kationischem Polymer führt zu Folien mit excellentem Duftverhalten.The use of corresponding fragrance precursors leads to shaped articles having an outstanding odor behavior in aqueous systems, in particular as regards the length and duration of the resulting fragrance impression, also on treated substrates, in particular textile. Above all, the combination of perfume precursors with the above-mentioned persistent fragrances and / or cationic polymer leads to films with excellent odor behavior.
Ein erfindungsgemäßer Formkörper kann vorzugsweise Riechstoffe umfassen, die aus der Gruppe Bergamotteöl, Tangerineöl, Dimethylanthranilat, Dihydromyrcenol (2-Methyl-6-methylene-2-octanol), Tetrahydrolinalool, Isobomylacetat, Ethyllinalool, Limonen, Orangenöl, Isobornylacetat, Eucalyptusoel (globulus), Aldehyd C 10, Styrolylacetat, Citronitril ((Z,E)-Methyl-5-phenyl-2-penten-nitril), Undecavertol (4-Methyl-3-decen-5-ol), Styrolylacetat, Tonalid (Acetyl hexamethyl tetralin) ausgewählt sind. Diese Riechstoffe können einen besonders guten Frische-Eindruck erwecken, sowohl was den Formkörper selbst betrifft als auch bei dessen Anwendung in wässrigen Systemen.A shaped article according to the invention may preferably comprise fragrances selected from the group bergamot oil, tangerine oil, dimethyl anthranilate, dihydromyrcenol (2-methyl-6-methylene-2-octanol), Tetrahydrolinalool, isobomylacetate, ethyllinalool, limonene, orange oil, isobornylacetate, eucalyptus oil (globulus), aldehyde C 10, styrolylacetate, citronitrile ((Z, E) -methyl-5-phenyl-2-pentenitrile), undecavertol (4-methylbenzene) 3-decene-5-ol), styrolyl acetate, tartalide (acetyl hexamethyl tetralin). These fragrances can give a particularly good freshness impression, both as regards the molding itself and in its use in aqueous systems.
Ein erfindungegemäßen Formkörper kann vorzugsweise Riechstoffe umfassen, die aus der Gruppe Aldehyd C 14, Decalacton gamma, Cyclamenaldehyd, Troenan (5-Methyl-5-propyl-2-(1-methylbutyl)-1,3-dioxane), Canthoxal (2-Methyl-3-(para-methoxy phenyl)-propanal), Citronellol, Geraniol, Moschus, Phenylethylalkohol, Phenirat ( 2-Phenylethyl 2-Methylpropanoat), Phenylethylisobutyrat, Jasmelia (2H-pyran-4-ol, 3-butyltetrahydro-5-methyl-acetat), Hexylzimtaldehyd (alpha), Ylang, Cyclohexylsalicylat, Hexenylsalicylat (cis-3), Sandelice, Guajakholzoel, Iso E Super ( 7-Acetyl, 1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethyl naphthalen), Norlimbanol, Ambroxan (3aR-(3aalpha,5abeta,9aalpha,9bbeta))-Dodecahydro-3a,6,6,9a-tetramethyl naphtho(2,1-b)furan), Zimtalkohol, Cyclopentadecanolide, Nirvanol ( (S)-(+)-5-Ethyl-5-phenylhydantoin), Javanol ( 1-Methyl-2-((1,2,2-trimethyl bicyclo(3.1.0)hex-3-yl)methyl)cyclopropane methanol), Habanolide (Oxacyclohexadecen-2-one), Maltol, Benzylaceton, Cumarin, Benzylsalicylat, Melonal (2,6-Dimethyl-5-Heptenal), Galbanum(öl), Ethylvanillin, Koavone (3-Hepten-2-one,3,4,5,6,6-pentamethyl), Methylpalmitat, Methyloleat und/oder Methylmyristat ausgewählt sind. Diese Riechstoffe können einen besonders guten Pflege-Eindruck erwecken, sowohl was den Formkörper selbst betrifft als auch bei dessen Anwendung in wässrigen Systemen.A molded article of the invention may preferably comprise fragrances selected from the group consisting of aldehyde C 14, decalactone gamma, cyclamen aldehyde, troenan (5-methyl-5-propyl-2- (1-methylbutyl) -1,3-dioxane), canthoxal (2 Methyl 3- (para-methoxy-phenyl) -propanal), citronellol, geraniol, musk, phenylethyl alcohol, phenatez (2-phenylethyl 2-methylpropanoate), phenylethyl isobutyrate, jasmelia (2H-pyran-4-ol, 3-butyltetrahydro-5- methyl acetate), hexyl cinnamic aldehyde (alpha), ylang, cyclohexyl salicylate, hexenyl salicylate (cis-3), Sandelice, guaiacolite, Iso E Super (7-acetyl, 1,2,3,4,5,6,7,8-octahydro -1,1,6,7-tetramethylnaphthalene), norlimbanol, ambroxan (3aR- (3aalpha, 5abeta, 9aalpha, 9bbeta)) - dodecahydro-3a, 6,6,9a-tetramethylnaphtho (2,1-b) furan Cinnamyl alcohol, cyclopentadecanolides, nirvanol ((S) - (+) - 5-ethyl-5-phenylhydantoin), Javanol (1-methyl-2 - ((1,2,2-trimethyl bicyclo (3.1.0) hex) 3-yl) methyl) cyclopropane methanol), habanolides (oxacyclohexadecene-2-ones), maltol, benzylacetone, coumarin, benzylsalicycl lat, melonal (2,6-dimethyl-5-heptenal), galbanum (oil), ethylvanillin, koavones (3-hepten-2-ones, 3,4,5,6,6-pentamethyl), methyl palmitate, methyl oleate and / or methyl myristate. These fragrances can give a particularly good care impression, both as regards the molding itself and when used in aqueous systems.
Nach einer bevorzugten Ausführungsform ist der erfindungsgemäße Formkörper im wesentlichen frei von anderen Bestandteilen als Parfüm und Polymermaterial. Vorzugsweise besteht ein erfindungsgemäßer Formkörper dementsprechend zu ≥65 Gew.-%, ≥ 70 Gew.-%, ≥75 Gew.-%, ≥ 80 Gew.-%, ≥ 85 Gew.-%, ≥ 90 Gew.-%, ≥95 Gew.-% oder sogar zu ≥ 98 Gew.-% aus den Bestandteilen Polymer und Parfüm.According to a preferred embodiment, the shaped body according to the invention is substantially free of constituents other than perfume and polymer material. Accordingly, a shaped article according to the invention is accordingly ≥65 wt%, ≥70 wt%, ≥75 wt%, ≥80 wt%, ≥85 wt%, ≥90 wt%, ≥ 95 wt .-% or even to ≥ 98 wt .-% of the components polymer and perfume.
Mögliche andere Bestandteile, welche in den erfindungsgemäßen Formkörpern enthalten sein können, sind vorteilhafterweise ausgewählt aus der Gruppe der Tenside, Gerüststoffe, Bleichmittel, Bleichaktivatoren, Enzyme, Elektrolyte, nichtwässrigen Lösungsmittel, pH-Stellmittel, Fluoreszenzmittel, Farbstoffe, Hautpflegemittel, Hydrotope, Avivagemittel, Schauminhibitoren, Silikonöle, Antiredepositionsmittel, optischen Aufheller, Vergrauungsinhibitoren, Einlaufverhinderer, Knitterschutzmittel, Farbübertragungsinhibitoren, antimikrobiellen Wirkstoffe, Germizide, Fungizide, Antioxidantien, Korrosionsinhibitoren, Antistatika, Bügelhilfsmittel, Phobier- und Imprägniermittel, Quell- und Schiebefestmittel sowie UV-Absorber.Possible other constituents which may be present in the moldings according to the invention are advantageously selected from the group of surfactants, builders, bleaches, bleach activators, enzymes, electrolytes, non-aqueous solvents, pH adjusters, fluorescers, dyes, skincare agents, hydrotopes, softeners, foam inhibitors , Silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, corrosion inhibitors, antistatic agents, ironing aids, repellents and impregnating agents, swelling and anti-slip agents and UV absorbers.
Ein weiterer Gegenstand ist ein Verfahren zur Beduftung oder Duftverstärkung eines wässrigen Systems, vorzugsweise einer Wasch-, Reinigungs- oder Spülflotte, wobei man dem erfindungsgemäßen Duftmediumabgabesystem zumindest eine Portion des parfümierten, wasserlöslichen oder wasserdispergierbaren, Formkörpers entnimmt und diese dem wässrigen System, insbesondere der Waschflotte, zugibt. Bei der Beduftung im Zusammenhang mit der maschinellen Textilwäsche kann der erfindungsgemäße Formkörper direkt in die Waschtrommel oder aber in die Waschmitielschublade gelegt werden.A further subject matter is a process for scenting or scent-enhancing an aqueous system, preferably a washing, cleaning or rinsing liquor, wherein at least one portion of the perfumed, water-soluble or water-dispersible, shaped body is removed from the scent medium delivery system according to the invention and these are removed from the aqueous system, in particular the wash liquor , admits. In the scenting in connection with the machine textile washing the molding according to the invention can be placed directly in the washing drum or in the Waschmitielschublade.
Ein weiterer Gegenstand ist ein Verfahren zum Aufbringen von Duftstoffen auf Textilgut in einer Waschmaschine durch Zugabe erfindungsgemäßer Formkörper, die dem afindungsgemäßen Duftmediumabgabesystem entnommen wurden, wobei die Formkörper Im Wasch- oder Spülgang eines maschinellen Waschverfahrens zur nassen Wäsche zugegeben werden.A further subject matter is a method for applying fragrances to textile goods in a washing machine by adding molded bodies according to the invention which have been taken from the fragrance medium dispensing system according to the invention, wherein the shaped bodies are added to the wet laundry in the washing or rinsing cycle of a machine washing process.
Ein weiterer Gegenstand ist ein Verfahren zum Aufbringen von Duftstoffen auf Textilgut In einem automatischen Wäschetrockner durch Zugabe erfindungsgemäßer Formkörper, die dem erfindungsgemäßen Duftmediumabgabesystem entnommen wurden, wobei die Formkörper zu der zu trocknenden feuchten Wäsche in den Trockner gegeben werden.A further subject matter is a method for applying fragrances to textile material in an automatic laundry drier by addition of shaped bodies according to the invention which have been taken from the fragrance medium dispensing system according to the invention, wherein the shaped articles are added to the wet laundry to be dried in the drier.
Ein weiterer Gegenstand der vorliegenden Erfindung Ist die Verwendung eines aus dem erfindungsgemäßen Duftmediumabgabesystem entnommenen Formkörpers zur Beduftung oder Duftverstärkung eines wässrigen Systems, vorteilhafterweise einer Textilwaschflotte, einer Geschirrspülwaschflotte, Badewassers oder einer Reinigungsflüssigkeit zur Säuberung von harten Flächen, wie vorzugsweise Fußböden oder Fenstern. Ebenfalls ist die Beduftung eines WC-Porzellanstandardbeckens (so genanntes Sitzklo) möglich. Dazu gibt man den Formkörper in das Wasser des Syphons, wo dieser dann angenehme Gerüche entfaltet, beispielsweise um bereits vorhandene unangenehme Gerüche zu überdecken.A further subject of the present invention is the use of a shaped body removed from the fragrance medium delivery system according to the invention for scenting or Odor enhancement of an aqueous system, advantageously a textile washing liquor, a dishwashing wash liquor, bathing water or a cleaning liquid for cleaning hard surfaces, such as preferably floors or windows. Also the scenting of a toilet porcelain standard sink (so-called Sitzklo) is possible. To do this, place the molded body in the water of the siphon, where it then unfolds pleasant odors, for example, to cover already existing unpleasant odors.
Claims (8)
- Fragrant medium dispensing system that includes a water-soluble or water-dispersible perfumed shaped article that comprises at least 20 wt.% polymer(s) as well as at least 10 wt.% odoriferous substances, each wt.% being based on the total shaped article, wherein the shaped article is supplied in a withdrawal receptacle, and wherein the shaped article is a foamed film and wherein the perfume comprised in the shaped article is present in at least 5 wt.% in encapsulated form.
- System according to claim 1, characterized in that the withdrawal receptacle comprises a flexible or inflexible, advantageously reclosable receptacle, preferably a box, that surrounds the shaped article and is advantageously a storage reservoir with a dosing device, in particular a dosing dispenser.
- System according to one of claims 1 or 2, characterized in that the withdrawal receptacle comprises a roll, on which a strip-shaped, a sheet-shaped, a disk-shaped or a web-shaped, flexible shaped article, is wound, wherein the shaped article is preferably provided with separation points for single portion withdrawal.
- System according to one of claims 1-3, characterized in that the shaped article comprises at least 12 wt.% perfume, preferably at least 15 wt.% perfume, especially at least 20 wt.% perfume, based on the total shaped article.
- System according to one of claims 1-4, characterized in that the comprised perfume consists of at least 5 wt.% of odoriferous substances having a boiling point above 250°C and a ClogP value of ≥ 3.0.
- System according to one of claims 1-5, characterized in that the shaped article comprises precursors of odoriferous substances that preferable once in the presence of H2O release odoriferous substances by hydrolysis.
- Method for perfuming or reinforcing the fragrance of an aqueous system, preferably a laundry liquor, characterized in that at least a portion of the perfumed, preferably water-soluble or water-dispersible shaped article is taken out of the fragrant medium dispenser system according to one of claims 1-6 and added to the aqueous system, especially to the laundry liquor.
- Use of a shaped article taken out of the fragrant medium dispensing system according to one of claims 1-6 for perfuming or reinforcing the fragrance of an aqueous system, advantageously a laundry liquor for textiles, a dishwasher liquor, bath water or a cleaning liquid for cleaning hard surfaces, such as preferably floors or windows.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006047230A DE102006047230A1 (en) | 2006-10-04 | 2006-10-04 | Fragrant medium dispensing system |
PCT/EP2007/059635 WO2008040620A1 (en) | 2006-10-04 | 2007-09-13 | Aromatic agent dispensing system |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2069468A1 EP2069468A1 (en) | 2009-06-17 |
EP2069468B1 true EP2069468B1 (en) | 2012-12-26 |
Family
ID=38857915
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07820183A Not-in-force EP2069468B1 (en) | 2006-10-04 | 2007-09-13 | Perfume dispensing system |
Country Status (4)
Country | Link |
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US (1) | US9181516B2 (en) |
EP (1) | EP2069468B1 (en) |
DE (1) | DE102006047230A1 (en) |
WO (1) | WO2008040620A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7786027B2 (en) | 2006-05-05 | 2010-08-31 | The Procter & Gamble Company | Functionalized substrates comprising perfume microcapsules |
DE102008031212A1 (en) * | 2008-07-03 | 2010-01-07 | Henkel Ag & Co. Kgaa | Detergent and detergent additive in particulate form |
JP6175449B2 (en) | 2012-01-11 | 2017-08-02 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンHenkel AG & Co. KGaA | Scented water soluble package |
DE102012212842A1 (en) * | 2012-07-23 | 2014-01-23 | Henkel Ag & Co. Kgaa | Water-soluble packaging and process for its preparation |
US11441106B2 (en) | 2017-06-27 | 2022-09-13 | Henkel Ag & Co. Kgaa | Particulate fragrance enhancers |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB899100A (en) * | 1958-09-24 | 1962-06-20 | Robert John Anderson | Detergent films |
TW399096B (en) * | 1996-07-03 | 2000-07-21 | Kao Corp | The sheet-like article for laundry |
US20030104969A1 (en) * | 2000-05-11 | 2003-06-05 | Caswell Debra Sue | Laundry system having unitized dosing |
ATE349229T1 (en) * | 2002-07-11 | 2007-01-15 | Firmenich & Cie | COMPOSITION FOR THE CONTROLLED RELEASE OF PERFUME AND FLAVORS |
EP1614743A1 (en) * | 2004-07-05 | 2006-01-11 | Givaudan SA | Washing method |
JP5198257B2 (en) * | 2005-05-13 | 2013-05-15 | ザ プロクター アンド ギャンブル カンパニー | Bleaching products |
GB2432843A (en) * | 2005-12-02 | 2007-06-06 | Unilever Plc | Perfume carrying polymeric particle |
ATE468967T1 (en) * | 2006-05-05 | 2010-06-15 | Procter & Gamble | FILMS WITH MICRO CAPSULES |
-
2006
- 2006-10-04 DE DE102006047230A patent/DE102006047230A1/en not_active Withdrawn
-
2007
- 2007-09-13 WO PCT/EP2007/059635 patent/WO2008040620A1/en active Application Filing
- 2007-09-13 EP EP07820183A patent/EP2069468B1/en not_active Not-in-force
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2009
- 2009-04-02 US US12/417,178 patent/US9181516B2/en not_active Expired - Fee Related
Also Published As
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US20090247446A1 (en) | 2009-10-01 |
EP2069468A1 (en) | 2009-06-17 |
US9181516B2 (en) | 2015-11-10 |
DE102006047230A1 (en) | 2008-04-10 |
WO2008040620A1 (en) | 2008-04-10 |
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