GB899100A - Detergent films - Google Patents
Detergent filmsInfo
- Publication number
- GB899100A GB899100A GB32386/59A GB3238659A GB899100A GB 899100 A GB899100 A GB 899100A GB 32386/59 A GB32386/59 A GB 32386/59A GB 3238659 A GB3238659 A GB 3238659A GB 899100 A GB899100 A GB 899100A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight
- amounts
- parts
- glycerol
- films
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/044—Solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
Abstract
Flexible, self-supporting detergent films of substantially uniform thickness comprise (a) a water-soluble hydroxyethylcellulose or an alkali metal (e.g. sodium or potassium) or ammonium salt of carboxymethylcellulose, preferably in amounts of 33-67 parts by weight of the composition, (b) a saturated acyclic alcohol, preferably in amounts of 15-30 parts by weight as plasticizer, and (c) an organic detergent, preferably in amounts of 25-55 parts by weight, and having a pH of 7-10. For ingredient (a), sodium carboxymethylcellulose having a degree of substitution of 0,65-0,95 is preferred. (b) may suitably comprise glycerol; di-glycerol; glycerol a -monomethyl ether or chlorhydrin; 1:2:6-hexanetriol; ethylene, propylene or 2:3-butylene glycol; 2-nitro-2-methyl-1:3-propanediol; 2:2-dihydroxydiethylamine; or 2-hydroxyethylamine. Suitable detergents (c) are soap, sulphonated long chain amide derivatives, alkyl sulphates and sulphonates, and alkylaryl sulphonates; non-ionic detergents and cationic detergents such as cetyltrimethylammonium bromide or p-tert.-octylphenoxyethenoxyethyldimethylbenzyl ammonium chloride may be used but are less preferred. The compositions may also include an additional non-ionic surfaceactive agent, suitably a polyoxyalkylene ether of a mono-ester of a polyhydric alcohol having a viscosity of 200-500 cs. Other materials which may be included are clays such as bentonite, kieselguhr, diatomaceous earth, and talc, hydrated aluminium or magnesium silicate, alkali metal carbonates and pyrophosphates, and borax. The films are made by dissolving first (a), then (b) and (c) and any optional ingredients in 2-10 times the weight of water at 70 DEG -100 DEG F., ethanol, isopropanol or tert.-butanol being added if required to prevent sudsing. The solution is then spread continously or batchwise into a layer 0,002 to 0,08 inches thick on a surface which suitably consists of a glass or metal coated surface which is itself coated with polytetrafluorethylene, and which is heated to 130 DEG -300 DEG F., preferably 150 DEG to 200 DEG F. The film having a thickness of 0,001-0,008 inches is stripped off the surface when the water content has fallen to 5-10% by weight, and may then be cut to the required dimensions for binding into booklets or for use in dispensing devices. Specification 645,752 is referred to.ALSO:Flexible, self-supporting detergent films of substantially uniform thickness comprise (a) a water-soluble hydroxyethyl cellulose or an alkali-metal (e.g. sodium or potassium) or ammonium salt of carboxymethylcellulose, preferably in amounts of 33-67 parts by weight of the composition, (b) a saturated acyclic alcohol, preferably in amounts of 15-30 parts by weight as plasticizer, and (c) an organic detergent, preferably in amounts of 25-55 parts by weight, and having a pH of 7-10. For component (a), sodium carboxymethylcellulose having a degree of substitution of 0,65-0,95 is preferred. Component (b) may be glycerol; diglycerol; glycerol-a -monomethyl ether or chlorhydrin; 1:2:6-hexanetriol; ethylene, propylene or 2:3-butylene glycol; 2-nitro-2-methyl-1:3-propanediol; 2:2-dihydroxydiethylamine; or 2-hydroxyethylamine. Suitable detergents (c) are soap, sulphonated long-chain amide derivatives, alkyl sulphates and sulphonates, and alkyl aryl sulphonates; non-ionic and cationic detergents, such as cetyltrimethylammonium bromide or p-tert.-octylphenoxyethenoxyethyldimethylbenzyl ammonium chloride, may be used but are less preferred. The compositions may also include an additional non-ionic surfaceactive agent, suitably a polyoxyalkylene ether of a mono-ester of a polyhydric alcohol having a viscosity of 200-500 cs. Other materials which may be included are clays such as bentonite, kieselguhr diatomaceous earth and talc, hydrated aluminium or magnesium silicate, alkali metal carbonates and pyrophosphates, and borax. The films are made by dissolving first (a), then (b) and (c) and any optional ingredients in 2-10 times the weight of water at 70 DEG -100 DEG F., ethanol, isopropanol or tert.-butanol being added if required to prevent sudsing. The solution is then spread continuously or batchwise into a layer 0,002 to 0,08 inches thick on a surface which suitably consists of a glass- or metal-coated surface which is itself coated with polytetrafluorethylene, and which is heated to 130 DEG -300 DEG F., preferably 150 DEG -200 DEG F. The film having a thickness of 0,001-0,008 inches is stripped off the surface when the water content has fallen to 5-10% by weight, and may then be cut to the required dimensions for binding into booklets or for use in dispensing devices. Specification 645,752 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US76293858A | 1958-09-24 | 1958-09-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB899100A true GB899100A (en) | 1962-06-20 |
Family
ID=25066459
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB32386/59A Expired GB899100A (en) | 1958-09-24 | 1959-09-23 | Detergent films |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR1243045A (en) |
GB (1) | GB899100A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004016724A1 (en) * | 2002-08-14 | 2004-02-26 | Colgate-Palmolive Company | Unit dose detergent film |
WO2004087857A1 (en) * | 2003-04-03 | 2004-10-14 | Reg Macquarrie | Film-form compositions for delivery of soaps and detergents |
WO2007034471A3 (en) * | 2005-09-26 | 2007-05-31 | Samuel Icht | Detergent printed film |
WO2008040619A1 (en) * | 2006-10-04 | 2008-04-10 | Henkel Ag & Co. Kgaa | Detergent or cleaning material dispensing system |
WO2008040620A1 (en) * | 2006-10-04 | 2008-04-10 | Henkel Ag & Co. Kgaa | Aromatic agent dispensing system |
WO2016102395A1 (en) * | 2014-12-22 | 2016-06-30 | L'oreal | Quick dissolving film for washing keratin materials |
-
1959
- 1959-09-23 GB GB32386/59A patent/GB899100A/en not_active Expired
- 1959-09-24 FR FR805907A patent/FR1243045A/en not_active Expired
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004016724A1 (en) * | 2002-08-14 | 2004-02-26 | Colgate-Palmolive Company | Unit dose detergent film |
WO2004087857A1 (en) * | 2003-04-03 | 2004-10-14 | Reg Macquarrie | Film-form compositions for delivery of soaps and detergents |
WO2007034471A3 (en) * | 2005-09-26 | 2007-05-31 | Samuel Icht | Detergent printed film |
WO2008040619A1 (en) * | 2006-10-04 | 2008-04-10 | Henkel Ag & Co. Kgaa | Detergent or cleaning material dispensing system |
WO2008040620A1 (en) * | 2006-10-04 | 2008-04-10 | Henkel Ag & Co. Kgaa | Aromatic agent dispensing system |
US9181516B2 (en) | 2006-10-04 | 2015-11-10 | Henkel Ag & Co. Kgaa | Fragrant medium dispensing system |
WO2016102395A1 (en) * | 2014-12-22 | 2016-06-30 | L'oreal | Quick dissolving film for washing keratin materials |
Also Published As
Publication number | Publication date |
---|---|
FR1243045A (en) | 1960-10-07 |
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