EP1973667B1 - Vorrichtung zur zuführung von gas-flüssigkeits-gemischen - Google Patents

Vorrichtung zur zuführung von gas-flüssigkeits-gemischen Download PDF

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Publication number
EP1973667B1
EP1973667B1 EP07700024A EP07700024A EP1973667B1 EP 1973667 B1 EP1973667 B1 EP 1973667B1 EP 07700024 A EP07700024 A EP 07700024A EP 07700024 A EP07700024 A EP 07700024A EP 1973667 B1 EP1973667 B1 EP 1973667B1
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EP
European Patent Office
Prior art keywords
liquid
mixing chamber
chamber
gas
tank
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP07700024A
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English (en)
French (fr)
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EP1973667A1 (de
Inventor
Stefano Santagiuliana
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Taplast SRL
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Taplast SRL
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Publication date
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Publication of EP1973667A1 publication Critical patent/EP1973667A1/de
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Publication of EP1973667B1 publication Critical patent/EP1973667B1/de
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/10Spray pistols; Apparatus for discharge producing a swirling discharge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/10Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
    • B05B11/1042Components or details
    • B05B11/1073Springs
    • B05B11/1074Springs located outside pump chambers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/10Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
    • B05B11/1087Combination of liquid and air pumps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B1/00Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
    • B05B1/34Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl
    • B05B1/3405Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl
    • B05B1/341Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet
    • B05B1/3421Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber
    • B05B1/3431Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber the channels being formed at the interface of cooperating elements, e.g. by means of grooves
    • B05B1/3436Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber the channels being formed at the interface of cooperating elements, e.g. by means of grooves the interface being a plane perpendicular to the outlet axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/10Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
    • B05B11/1001Piston pumps
    • B05B11/1023Piston pumps having an outlet valve opened by deformation or displacement of the piston relative to its actuating stem
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/0018Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam
    • B05B7/0025Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply
    • B05B7/0031Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply with disturbing means promoting mixing, e.g. balls, crowns
    • B05B7/0037Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply with disturbing means promoting mixing, e.g. balls, crowns including sieves, porous members or the like

Definitions

  • This invention relates to a device for the delivery of gas-liquid mixtures, particularly in association with a container for containing a liquid product for delivery in the form of a foam or nebulized spray.
  • Such manually-operated devices collect the product from the container and mix it with a gas (usually air) under a positive pressure, thereby generating a foam during the delivery stage.
  • a gas usually air
  • Such devices basically comprise first means for collecting the product from the container and conveying it to a mixing chamber, said first means being operated by means of an actuator in coordination with second means for conveying air entrained from the environment and suitably pressurized to the same mixing chamber.
  • Said first means essentially comprise a hollow body serving as the product suction/compression chamber, in which a first mobile piston is slidingly engaged.
  • the second means comprise a second piston slidingly engaged in an airtight manner inside a hollow body serving as a gas compression chamber, which communicates with the mixing chamber by means of an air intake pipe.
  • Means for facilitating the formation of the foam comprising a filter or porous septum through which the air-product mixture is forced to flow, are installed downstream from the mixing chamber and upstream of the device's outlet.
  • the user takes action on the actuator to load the elastic means and thereby pushes the air under pressure and the product first towards the mixing chamber and then towards the device's outlet.
  • the air and product are first mixed together in the mixing chamber, forming a mixture that increases in volume as it is forced through the filter or porous septum, giving rise to the required foam.
  • the user By releasing the actuator, the user enables the elastic means to restore the device to the initial resting position, ready for a subsequent delivery action.
  • the first drawback of the known devices lies in that the residual liquid component contained in the foam and in the air-liquid mixture that does not reach the device's outlet tends to drop back into the air compression chamber through the air intake pipe.
  • a further correlated drawback lies in that the volume of the residual liquid reaching the air compression chamber progressively shrinks, thus altering both the product-to-air ratio and the performance of the device with each delivery action.
  • the known state of the art has proposed devices with a one-way valve element inserted inside the air intake pipe to prevent the residual fluid product flowing back into the air compression chamber and to enable the passage of the air.
  • Form Document EP126696 A1 a device is known which comprises collection means adapted to collect residual liquid, said collection means comprising a duct formed in the stem of said device.
  • valve element gives rise to a delay in the flow of pressurized air into the mixing chamber due to the valve's inertia.
  • a further drawback consists in that said valve element makes the device less reliable.
  • the purpose of the present invention is to overcome the above drawbacks.
  • a particular object of the invention is to realize a device for the delivery of gas-liquid mixtures, even in the form of a foam or nebulized spray, that presents no variations in the ratio of air to liquid each time the product is delivered.
  • Another object is to realize a device with minimal overall dimensions by comparison with devices of the known state of the art used in comparable working conditions.
  • a further object is to realize a device that comprises a smaller number of components than comparable devices of known type.
  • Another object is to realize a device that is easier to assemble than comparable devices of known type.
  • a further object is to realize a device that can also be assembled using automated production lines.
  • Another object is to realize a device that is more compact than comparable devices of known type.
  • Another, not necessarily last object is to realize a device that is reliable and can also be completely recycled, even without any prior dismantling or other operations.
  • a device for the delivery of gas-liquid mixtures that can be used in association with a container for a liquid in accordance with the content of the main claim.
  • the proposed solution advantageously enables the above-mentioned drawbacks to be overcome without using valve elements, thereby reducing both the cost of the device and its complexity, while increasing its reliability and the simplicity of the assembly operations involved, be they undertaken manually or using automatic equipment.
  • Another advantage of the proposed solution lies in that it enables the realization of a device with minimal overall dimensions, thereby also minimizing the space occupied for the storage of the device-container system and maximizing the amount of product that can be stored inside the container.
  • Position indicators mentioned in the single embodiments are logically transferable to new positions in the event of any change of position.
  • the embodiment of the invention described below refers to devices for the delivery of liquid detergents.
  • the proposed solution is clearly also applicable, however, to devices for the delivery of perfumes or foodstuffs, or any other fluid in general, that has to be collected from a container and conveyed towards a delivery point after mixing with a gas, preferably in the form of a foam.
  • FIG. 1 An embodiment of the device for the delivery of gas-liquid mixtures and/or fluids forming the object of the present invention, attached to a container C containing a fluid L for delivery in the form of foam, is illustrated in figure 1 , where it is globally identified by the numeral 1.
  • first means indicated globally by the numeral 2, suitable for being moved from a first position at rest, illustrated in figures 1 and 2 , to a second position, illustrated in figure 3 , where they suck the fluid L (consisting of a liquid detergent in this case) from the container C and carry it first to a mixing chamber 3 and then to the outlet 4 of the device 1 through a delivery pipe 4a.
  • the device 1. also comprises second means, indicated globally by the numeral 5, suitable for compressing a gas A (consisting of air in this case) and carrying it to the mixing chamber 3, when the first means 2 are moved from the first position to the second position.
  • second means indicated globally by the numeral 5, suitable for compressing a gas A (consisting of air in this case) and carrying it to the mixing chamber 3, when the first means 2 are moved from the first position to the second position.
  • the device also comprises collection means, indicated globally by the numeral 6, suitable for collecting at least a part of the portion of liquid of any air-liquid mixture that is not delivered, but remains in said mixing chamber 3 and/or downstream therefrom, and particularly between said chamber 3 and said outlet 4, after the device 1 has been operated.
  • collection means indicated globally by the numeral 6, suitable for collecting at least a part of the portion of liquid of any air-liquid mixture that is not delivered, but remains in said mixing chamber 3 and/or downstream therefrom, and particularly between said chamber 3 and said outlet 4, after the device 1 has been operated.
  • the collection means 6 are also suitable for being emptied, at least partially, during the operation of the device 1, and particularly when the first means 2 are moved from the first position to the second position.
  • the first means comprise a first hollow body 7 in which a first piston 8 is slidingly engaged.
  • the first hollow body 7 defines a first chamber 9 for the liquid L, also called the suction/compression chamber for the liquid L, which communicates with the inside of the container C by means of a liquid suction pipe 10, and with the mixing chamber 3 by means of at least one liquid intake pipe 11.
  • the first piston 8 is connected by means of a stem 12 to an actuator 13, also called an actuator cap or button and comprising a spout, whereon the user exerts a pressure to operate the device 1.
  • an actuator 13 also called an actuator cap or button and comprising a spout, whereon the user exerts a pressure to operate the device 1.
  • the inside of the stem 12 is provided with said liquid intake pipe 11, which communicates with the first chamber 9 and with the mixing chamber 3.
  • the first piston 8 comprises a supporting element 8a, to which a plunger 8b (also called a membrane) cooperating in an airtight manner with the walls of the first chamber 9, is slidingly engaged.
  • a plunger 8b also called a membrane
  • the first valve means 14 comprise a first ball 14a made of a nonmetallic material and housed inside a corresponding seat 14b, while the second valve means 15 comprise sealing edges, or lips 15a on the plunger 8b.
  • the second means 5 comprise at least one second chamber 60 suitable for containing the aforesaid gas A so that when the suction means 2 are moved from the first position to the second position, the gas A is compressed and conveyed to the mixing chamber 3 through an air intake pipe 16.
  • the second chamber 60 consists of a second hollow body 17, communicating with the mixing chamber 3 by means of the aforesaid air intake pipe 16, in which a second piston 18 comprising a second plunger 18a is slidingly engaged.
  • Third valve means globally indicated by the numeral 19, regulate the replenishment of the air in the second chamber 60, after each delivery action.
  • said third valve means 19 comprise a ball 19a made of a nonmetallic material and housed in a seat 19b.
  • Said means 20 comprise a filter or a porous septum 20a and a diaphragm 20b with a plurality of through holes 21. There is a gap between the porous septum 20a and diaphragm 20b, that together constitute an expansion chamber 22 that facilitates the mixing of the liquid L with the air A, and the formation of a foam.
  • the collection means 6 comprise a collection tank 25 coming between the second means 5 and the mixing chamber; to be more precise, said collection means are situated inside the pressurized gas intake pipe 16 that, as mentioned earlier, places the second means 5 in communication with the mixing chamber 3.
  • the top of the tank 25 communicates with the second air compression chamber 60 through a first stretch of the pressurized air intake pipe 16, while at the bottom it is complete with at least one opening 26 communicating, through a second stretch of the pressurized air intake pipe, with the mixing chamber 3.
  • the tank 25 is in the shape of a ring arranged coaxially both to the stem 12 of the first piston 8 and to the plunger 18a of the second piston 18. To be more precise, the tank 25 is contained between two cylindrical walls 25a and 25b forming part of the second plunger 18a.
  • the capacity of the tank 25 is equal to or greater than the volume of the residual liquid obtained after the mixture contained inside the mixing chamber 3 and/or the expansion chamber 22 and/or the outlet pipe 4a has dissolved, said quantity of liquid depending on the air to liquid ratio of the mixture.
  • the capacity of the tank 25 is equal to or greater than the volume of the outlet pipe extending downstream from the mixing chamber to the device's outlet.
  • the capacity of the tank is equal to or greater than the sum of the volumes of the mixing chamber 3, the expansion chamber 22 and the outlet pipe 4a.
  • the collection means 6 are situated outside the second chamber 60. This advantageously enables the useful volume of the air compression chamber 60 to remain the same, optimizing the overall dimensions of the device. This solution also enables a reduction in the volume of the outlet pipe and a consequent reduction in the amount of residual liquid that can remain inside said pipe after each delivery action.
  • the opening 26 may not be in the bottom of the container.
  • the device 1 also comprises elastic means, indicated globally by the numeral 28, suitable for ensuring the return of the means 2 and 5 to the first position after a delivery action.
  • these elastic means 28 comprise a helical spring 28a situated inside the second chamber 60 for the compression of the gas A.
  • said helical spring 28a has one end coming to bear on the second piston and the other end coming to bear on the bottom wall of the second chamber 60.
  • the device 1 also comprises means for locking/releasing the device 1, indicated globally by the numeral 29 and visible in figure 4 .
  • Said means 29 are suitable for preventing or enabling the operation of the device 1 and can be operated by selectively rotating the actuator element 13 around a longitudinal axis, from a first predefined locking position, shown in figure 4 , to a second predefined operating position, shown in figures 1 , 2 and 3 .
  • first opposing element consisting of a first projecting part 29a solidly attached to the stem 12, shown in figure 4 , suitable for selectively interfering with a second opposing element 31 belonging to the supporting element 32 and solidly attached to the first hollow body 7.
  • this second opposing element 31 comprises a horizontal striker plane 31a that interferes with the element 29a, thereby preventing the axial movement of the plunger-stem-actuator assembly.
  • the horizontal striker plane 31a is interrupted by a vertical groove 34, not shown in figure 2 , obtained in the ring-shaped element 32, whereon the projecting element 29a can slide under the pressure exerted by the user to enable the movement of the pistons 28, 8 when the actuator 13 is brought into the releasing position.
  • Another embodiment of the invention is distinguishable from the previous embodiment in that the third valve means 19 comprise a ring-shaped lip 38 made of a nonmetallic material and belonging to a membrane 18b that forms part of the plunger of the first piston 18.
  • a further embodiment of the invention is distinguishable from the previous embodiment in that the ring-shaped lip 38a consists of a separate element associated with the membrane 18b on the plunger of the first piston 18.
  • Another embodiment of the device according to the invention is distinguishable from the previous embodiment in that the second chamber 60 is collapsible and, to be more specific, consists of bellows 39.
  • said embodiment is also distinguishable from the previous embodiments in that, in addition to forming at least a part of the air compression chamber 60, said bellows 39 are elastic bellows that also serve as elastic means 28 for enabling the device to return to the resting position after each delivery action.
  • the first chamber 9 may also be collapsible and the elastic means 28 may also be situated inside the first chamber 9.
  • the device also comprises means suitable for varying the allowable stroke of the first means 2.
  • These means comprise an opposing element suitable for selectively engaging in grooves of various length provided, for instance, in the supporting element 31.
  • the user turns the actuator 13 into the position corresponding to the quantity of fluid to deliver, which is suitably indicated on the cap.
  • Another embodiment of the invention is distinguishable from the previous embodiments in that the device delivers the liquid product in nebulized form.
  • the means 20 are suitable for contributing to the nebulization of the product and in this case comprise a nozzle 65, illustrated in detail in figure 9 .
  • Said nozzle 65 is complete with three lines 66, which carry the air-product mixture towards the outlet 65b of the nozzle 65, generating a turbulence that determines the nebulization of the mixture.
  • FIG. 1 Another embodiment of the invention, indicated globally with the numeral 104 in figure 16 , is distinguishable from the previous embodiments in that the collection means 6 consist of a stretch 70 of the air intake pipe 16 and, to be more precise, of a stretch wherein said pipe has a wider cross-section.
  • valve means in the device as described hitherto may be substituted by any other equivalent valve means of known type, and the same applies to the locking and stroke-limiting systems of the suction means.
  • the user takes preliminary action on the actuator 13, rotating it in order to configure the device 1 in the required operating mode.
  • the user can lock the device 1 by rotating the spout or cap 13 around its axis 30 so as to bring it into the position shown in detail in figure 4 : in this position, the first opposing elements 29a face the striker planes 31 a, thus preventing any axial movement of the first and second means 2 and 5.
  • the user rotates the actuator 13 around its axis 30 in order to bring it into the position shown in figure 1 : in this position, the former opposing elements 29a face the groove 34, along which they are able to slide freely, thus enabling the pistons 8 and 18 to move axially under the pressure P exerted by the user on the actuator 13.
  • the user loads the elastic means 28 and compresses both the product L contained in the first chamber 9 and the air contained in the second chamber 60.
  • the rise in the pressure in the first chamber moves the plunger 8b on the supporting element 8a, thus enabling the liquid L contained in the chamber 9 to flow out, first into the liquid intake pipe 11 and then into the mixing chamber 3, along the path indicated by the numeral 50 in figure 10 .
  • the increase in the pressure in the second chamber 60 forces the pressurized air first into the air intake pipe 16 and then into the mixing chamber 3, along the path indicated with the numeral 51.
  • the mixture that forms inside the mixing chamber 3 then moves to the outlet 4, passing through the means 20.
  • the liquid-air mixture passes first through the holes 21 in the diaphragm 20b, giving rise to a turbulence that facilitates the creation of air bubbles in the mixture, which subsequently expands in the expansion chamber 22 and passes through the filter 20a, where it becomes finer, ultimately reaching the outlet 4 through the pipe 4a in the form of a foam F, as shown in figures 3 and 11 .
  • This elastic return generates a negative pressure inside the chambers 9 and 60.
  • This negative pressure prompts the intervention of the first and second valve means 14 and 15 and makes the liquid L flow into the first chamber 9, making the device ready for subsequent reuse.
  • the negative pressure retains the first plunger 8b which slides along the supporting element 8a and thus closes the liquid intake pipe 11, as illustrated in detail in figure 12 .
  • the negative pressure generated in the second chamber 60 prompts the intervention of the third valve means 19, which consequently enable air to flow from the outside E into the first chamber 5, preparing the device 1 for subsequent reuse.
  • the residual liquid L thus collects temporarily in the tank 25, advantageously avoiding it reaching the second chamber 60.
  • the proposed solution means that, when the device is subsequently reused, the tank 25 is emptied and all or most of the liquid it contained is carried into the mixing chamber 3. This advantageously enables the recovery of the liquid L in the tank 25, returning it to the mixing chamber 3 and consequently to the device's outlet 4, thereby substantially avoiding any loss of liquid.
  • a subsequent operation of the device determines a flow of pressurized air into the tank 25 through the first stretch of the air intake pipe 16.
  • the proposed solution advantageously enables a device to be obtained that contains a smaller number of valve elements than comparable devices of the known state of the art.
  • the proposed device can advantageously and preferably also be made entirely of plastic or synthetic material. This gives rise to a device that can be completely recycled without any prior action being needed to separate any parts made of metal or other incompatible materials.
  • Another advantage lies in that, by preventing the liquid from reaching the chamber, the proposed solution enables the spring to be advantageously installed inside said compression chamber, a solution that would otherwise not be advisable because of the oxidation phenomena that would be bound to occur therein as a result of contact between the metal, the liquid and the air, leading to a discoloring of the liquid being delivered.

Landscapes

  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Nozzles (AREA)
  • Gas Separation By Absorption (AREA)
  • Accessories For Mixers (AREA)

Claims (21)

  1. Vorrichtung (1, 100, 101, 102, 103) zur Abgabe von Gas-Flüssigkeits-Gemischen in Verbindung mit einem Behälter (C) für eine Flüssigkeit (L), umfassend:
    - erste Mittel (2), die dazu geeignet sind, von zumindest einer ersten Ruhestellung in zumindest eine zweite Stellung bewegt zu werden, um die Flüssigkeit (L) anzusaugen und zu zumindest einer Mischkammer (3) zu befördern;
    - zweite Mittel (5), die dazu geeignet sind, ein Gas (A) zu verdichten und dieses in die zumindest eine Mischkammer (3) zu befördern, wenn die ersten Mittel (2) von der zumindest einen ersten Stellung in die zumindest eine zweite Stellung bewegt werden;
    - wobei die Vorrichtung Sammelmittel (6) umfasst, die dazu geeignet sind, zumindest einen Teil des Anteils an Flüssigkeit (L) im Luft-FlüssigkeitsGemisch, der nach dem Betätigen der Vorrichtung nicht abgegeben ist und im Inneren der Mischkammer (3) und/oder stromabwärts dieser verbleibt, zu sammeln, wobei die Sammelmittel (6) mit der zumindest einen Mischkammer (3) und mit den zweiten Mitteln kommunizieren, um dazu geeignet zu sein, während einer nachfolgenden Betätigung der Vorrichtung zumindest teilweise entleert zu werden, wenn die ersten Mittel (2) von der zumindest einen ersten Stellung in die zumindest eine zweite Stellung bewegt werden, sodass während des Entleerens der Sammelmittel die darin enthaltene Flüssigkeit zumindest teilweise in die Mischkammer befördert wird;
    dadurch gekennzeichnet, dass die Sammelmittel (6) ein Reservoir (25) von der Form eines Rings umfassen, das von zwei zylindrischen Wänden (25a, 25b) definiert ist, die Teil eines Stößels (18a) bilden, der zu den zweiten Mitteln (5) gehört und dazu geeignet ist, das Gas (A) zu verdichten, um es in die zumindest eine Mischkammer (3) zu befördern.
  2. Vorrichtung nach Anspruch 1), dadurch gekennzeichnet, dass das Reservoir (25) zumindest einen Abschnitt (70) einer Lufteinlassröhre (16) umfasst, die die zweiten Mittel in Kommunikation mit der zumindest einen Mischkammer (3) versetzt.
  3. Vorrichtung nach Anspruch 2), dadurch gekennzeichnet, dass der zumindest eine Abschnitt einen breiteren Querschnitt als der Rest der Lufteinlassröhre (16) aufweist.
  4. Vorrichtung nach einem der Ansprüche 1) bis 3), dadurch gekennzeichnet, dass das Reservoir (25) mit den zweiten Mitteln kommuniziert und mit zumindest einer Öffnung, die mit der Mischkammer kommuniziert, ausgestattet ist.
  5. Vorrichtung nach Anspruch 4), dadurch gekennzeichnet, dass die zumindest eine Öffnung im Wesentlichen am Boden des Reservoirs bereitgestellt ist.
  6. Vorrichtung nach Anspruch 4) oder 5), dadurch gekennzeichnet, dass das Reservoir mittels einer Gaseinlassröhre, die im oberen Abschnitt des Reservoirs, oberhalb der Oberfläche der sich im Reservoir ansammelnden Flüssigkeit (L), angeordnet ist, mit den zweiten Mitteln kommuniziert.
  7. Vorrichtung nach einem der vorangegangenen Ansprüche, dadurch gekennzeichnet, dass die Kapazität des Reservoirs (25) gleich groß oder größer als das Volumen der Restflüssigkeit ist, die erhalten wird, nachdem sich das Gemisch in der Mischkammer (3) und/oder in einer Expansionskammer (22) und/oder in einer Auslassröhre (4a) aufgelöst hat.
  8. Vorrichtung nach einem der vorangegangenen Ansprüche, dadurch gekennzeichnet, dass die ersten Mittel (2) einen ersten hohlen Körper (7), der eine Kammer (9) für die zu mischende Flüssigkeit bildet, die mittels einer Saugröhre (10) mit dem Behälter kommuniziert, sowie einen ersten Kolben (8), der im ersten hohlen Körper gleitend in Eingriff ist, umfassen.
  9. Vorrichtung nach einem der Ansprüche 1) bis 8), dadurch gekennzeichnet, dass die ersten Mittel (2) eine erste zusammenlegbare Kammer für die zu mischende Flüssigkeit umfassen, die mittels einer Saugröhre (10) mit dem Behälter kommuniziert.
  10. Vorrichtung nach einem der Ansprüche 8) oder 9), dadurch gekennzeichnet, dass die Vorrichtung ferner erste und zweite Ventilmittel (14, 15) umfasst, die dazu geeignet sind, den Fluss der Flüssigkeit vom Behälter zur Kammer (9) und ihren Fluss von dieser in die zumindest eine Mischkammer (3) zu regulieren.
  11. Vorrichtung nach Anspruch 10), dadurch gekennzeichnet, dass die ersten und/oder zweiten Ventilmittel (14, 15) .eine Kugel (14a) und/oder Dichtränder oder -lippen (15a) umfassen.
  12. Vorrichtung nach einem der vorangegangenen Ansprüche, dadurch gekennzeichnet, dass die zweiten Mittel (5) zumindest einen zweiten hohlen Körper (17) umfassen, der dazu geeignet ist, eine zweite Kammer (60) für das zu mischende Gas zu definieren, die mittels zumindest einer Gaseinlassröhre (16) mit der zumindest einen Mischkammer (3) kommuniziert, wobei ein zweiter Kolben (18) im zweiten hohlen Körper (17) gleitend in Eingriff ist.
  13. Vorrichtung nach einen der Ansprüche 1) bis 9), dadurch gekennzeichnet, dass die zweiten Mittel (5) zumindest eine zweite zusammenlegbare Kammer umfassen, die mittels zumindest einer Gaseinlassröhre (16) mit der zumindest einen Mischkammer (3) kommuniziert.
  14. Vorrichtung nach Anspruch 12) oder 13), dadurch gekennzeichnet, dass die Vorrichtung ferner dritte Ventilmittel (19) umfasst, die dazu geeignet sind, den Strom des Gases in die zumindest eine zweite Kammer (60) und seinen Strom von dieser in die zumindest eine Mischkammer (3) zu regulieren.
  15. Vorrichtung nach Anspruch 14), dadurch gekennzeichnet, dass die dritten Ventilmittel (19) eine zweite Kugel (19a) und/oder Dichtlippen (38, 38a) umfassen.
  16. Vorrichtung nach einem der vorangegangenen Ansprüche, dadurch gekennzeichnet, dass die Vorrichtung ferner elastische Mittel (28) umfasst, die dazu geeignet sind, die Rückkehr der ersten Mittel (2) und/oder der zweiten Mittel (5) nach einem Abgabevorgang in die erste Stellung sicherzustellen.
  17. Vorrichtung nach Anspruch 16), dadurch gekennzeichnet, dass die elastischen Mittel zumindest ein elastisches Faltenbalgelement (39) oder zumindest eine Spiralfeder (28a) umfassen.
  18. Vorrichtung nach einem der vorangegangenen Ansprüche, dadurch gekennzeichnet, dass die Vorrichtung ferner Mittel zum Sperren/Freigeben (29) der ersten Mittel (2) und/oder zweiten Mittel (5) umfasst, um die Betätigung der Vorrichtung zu verhindern oder zuzulassen, wobei die Mittel zum Sperren/Freigeben der ersten und/oder zweiten Mittel vorzugsweise vom Benutzer durch selektives Drehen eines Aktuators (13), der einstückig mit einem Stiel (12) des ersten Kolbens (8) ausgebildet ist, betätigt werden können.
  19. Vorrichtung nach Anspruch 18), dadurch gekennzeichnet, dass die Mittel zum Sperren/Freigeben ein erstes Element (29a) umfassen, das vom Stiel (12) vorsteht, um selektiv mit einem zweiten Gegenelement (31a) zusammenzuwirken oder gleitend in eine oder mehrere Rillen (34) einzugreifen.
  20. Vorrichtung nach einem der vorangegangenen Ansprüche, dadurch gekennzeichnet, dass die Vorrichtung ferner Mittel (20) umfasst, die dazu geeignet sind, zur Bildung von Schaum (F) beizutragen und stromabwärts der zumindest einen Mischkammer (3) und stromaufwärts eines Auslasses (4) der Vorrichtung angeordnet sind, oder Mittel (20) umfasst, die dazu geeignet sind, zur Zerstäubung des Gemischs beizutragen und stromabwärts der zumindest einen Mischkammer (3) und stromaufwärts eines Auslasses (4) der Vorrichtung angeordnet sind.
  21. System zur Abgabe von Gas-Flüssigkeits-Gemischen, umfassend einen Behälter für eine Flüssigkeit und eine Abgabevorrichtung, dadurch gekennzeichnet, dass die Abgabevorrichtung nach einem der vorangegangenen Ansprüche ausgeführt ist.
EP07700024A 2006-01-17 2007-01-04 Vorrichtung zur zuführung von gas-flüssigkeits-gemischen Not-in-force EP1973667B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT000019A ITVI20060019A1 (it) 2006-01-17 2006-01-17 Dispositivo per l'erogazione di miscele gas-liquido
PCT/IB2007/000066 WO2007083206A1 (en) 2006-01-17 2007-01-04 Device for the delivery of gas-liquid mixtures

Publications (2)

Publication Number Publication Date
EP1973667A1 EP1973667A1 (de) 2008-10-01
EP1973667B1 true EP1973667B1 (de) 2009-12-02

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CN (1) CN101370594A (de)
AT (1) ATE450318T1 (de)
BR (1) BRPI0707141A2 (de)
DE (1) DE602007003557D1 (de)
ES (1) ES2337412T3 (de)
IT (1) ITVI20060019A1 (de)
RU (1) RU2388549C1 (de)
WO (1) WO2007083206A1 (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2910449B1 (fr) * 2006-12-22 2009-03-06 Rexam Dispensing Systems Sas Pompe compacte a capacite de rotulage du gicleur par rapport au piston.
DE102010001375A1 (de) 2010-01-29 2011-08-04 Henkel AG & Co. KGaA, 40589 Schaumförmige Färbemittel II
IT1404092B1 (it) * 2011-01-31 2013-11-08 Taplast Srl Dispositivo per l'erogazione di fluidi o miscele.
US9101952B2 (en) * 2011-06-06 2015-08-11 Gojo Industries, Inc. Modular pump
DE102011079922A1 (de) 2011-07-27 2013-01-31 Henkel Ag & Co. Kgaa Aufhellverfahren mit Blondiermousse
ITVI20120100A1 (it) * 2012-04-26 2013-10-27 Taplast Srl Dispositivo per l'erogazione di una miscela, preferibilmente schiuma.
FR2998198B1 (fr) * 2012-11-22 2015-05-29 Aptar France Sas Organe de distribution de produit fluide.
JP6118659B2 (ja) * 2013-06-28 2017-04-19 株式会社吉野工業所 フォーマポンプ
DE102013225585A1 (de) 2013-12-11 2015-06-11 Henkel Ag & Co. Kgaa Schaumförmige Färbemittel mit verbesserten Applikationseigenschaften
CN104210745B (zh) * 2014-07-29 2016-07-06 余姚市特力喷雾器有限公司 泡沫泵
DE102014226752A1 (de) 2014-12-22 2016-06-23 Henkel Ag & Co. Kgaa Schaumförmige direktziehende Färbemittel
NL2015724B1 (en) 2015-11-04 2017-05-24 Gab Eng & Dev B V Storage holder for a dispenser.
NL2016644B1 (en) 2016-04-20 2017-11-07 Gab Eng & Development B V Storage holder for a dispenser
DE102017206087A1 (de) 2017-04-10 2018-10-11 Henkel Ag & Co. Kgaa Verfahren und Kit zum Färben von Haaren mit Säurefarbstoffen
CN109290087A (zh) * 2018-10-19 2019-02-01 上海睿琦包装科技有限公司 一种全塑可回收环保喷头
RU2753861C1 (ru) * 2020-09-11 2021-08-24 Акционерное общество "Эридан" Устройство для очистки оптических поверхностей
IT202000022504A1 (it) * 2020-09-24 2022-03-24 Coster Tecnologie Speciali Spa Dispositivo di erogazione di una sostanza fluida

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3911510A1 (de) * 1989-04-08 1990-10-11 Pfeiffer Erich Gmbh & Co Kg Austragvorrichtung fuer medien
JPH0669161U (ja) * 1993-03-05 1994-09-27 大和製罐株式会社 ポンプ式泡出し容器
NL1001366C2 (nl) * 1995-10-06 1997-04-08 Airspray Int Bv Inrichting voor het afgeven van een luchtvloeistofmengsel, in het bijzonder schuim en daarvoor bestemde bedieningseenheid.
EP1266696A1 (de) * 2001-06-13 2002-12-18 Taplast S.p.A. Balgpumpe zur Abgabe von Gasflüssigkeitmischungen

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ITVI20060019A1 (it) 2007-07-18
WO2007083206A1 (en) 2007-07-26
RU2008133414A (ru) 2010-02-27
DE602007003557D1 (de) 2010-01-14
ES2337412T3 (es) 2010-04-23
BRPI0707141A2 (pt) 2011-04-19
ATE450318T1 (de) 2009-12-15
CN101370594A (zh) 2009-02-18
EP1973667A1 (de) 2008-10-01
RU2388549C1 (ru) 2010-05-10

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