EP1966548A2 - Paroi de transfert de chaleur a sorption et element de transfert de chaleur a sorption - Google Patents

Paroi de transfert de chaleur a sorption et element de transfert de chaleur a sorption

Info

Publication number
EP1966548A2
EP1966548A2 EP06829464A EP06829464A EP1966548A2 EP 1966548 A2 EP1966548 A2 EP 1966548A2 EP 06829464 A EP06829464 A EP 06829464A EP 06829464 A EP06829464 A EP 06829464A EP 1966548 A2 EP1966548 A2 EP 1966548A2
Authority
EP
European Patent Office
Prior art keywords
sorptionswärmeübertragerwand
heat
sorption
sorbent
thermally conductive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06829464A
Other languages
German (de)
English (en)
Inventor
Roland Burk
Markus Watzlawski
Eberhard Zwittig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mahle Behr GmbH and Co KG
Original Assignee
Behr GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Behr GmbH and Co KG filed Critical Behr GmbH and Co KG
Priority to EP10159027A priority Critical patent/EP2211126A1/fr
Publication of EP1966548A2 publication Critical patent/EP1966548A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B35/00—Boiler-absorbers, i.e. boilers usable for absorption or adsorption
    • F25B35/04—Boiler-absorbers, i.e. boilers usable for absorption or adsorption using a solid as sorbent
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/003—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using thermochemical reactions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00—Adapting or protecting infrastructure or their operation
    • Y02A30/27—Relating to heating, ventilation or air conditioning [HVAC] technologies
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/62—Absorption based systems
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14—Thermal energy storage

Definitions

  • the invention relates to a Sorptionsebenntontragerwand with an acted upon by a heat donating or receiving fluid fluid side, which is bounded by a fluid wall, and a sorption, which has a sorbent bed with a sorbent, which releases a sorbent under heat or absorption or attaches.
  • European Patent Application EP 1 175 583 B1 discloses an absorber heat exchanger in which polar gas is repeatedly absorbed and desorbed on a complex compound.
  • the known heat exchanger has between at least a portion of the heat exchanger surfaces a space containing a sorbent / substrate composition comprising a fibrous substrate material that is inert to the polar gas or hydrogen.
  • the fibrous substrate material comprises woven or nonwoven strands or fibers or combinations of woven and nonwoven strands or fibers.
  • the absorbent is embedded in the fibrous subscribe material.
  • the object of the invention is to provide a mechanically stable Sorptionskorauertragerwand according to the preamble of claim 1, which has good heat and mass transfer properties.
  • the object is for a Sorptionskorauertragerwand with acted upon by a heat donating or receiving fluid fluid side, which is bounded by a fluid wall, and a sorption, which has a sorbent bed with a sorbent, the absorption or release of heat Sorptiv dissipates or accumulates, thereby achieved that the sorption comprises a good heat conducting support structure for the sorbent, which is thermally conductively connected to the fluid wall.
  • the present invention preferably relates to adsorption, ie the reversible addition of gases or solutes to the surface of solid bodies.
  • the Sorptions ses awaittragerwand is preferably part of a Sorptions ses awaittragers, which is also referred to as a sorption reactor and can be developed into a closed sorption tube.
  • the basis of a Sorptions ses awaittragers is the reversible binding or attachment of a gaseous working fluid (Sorptivs) to a solid (sorbent) with release or absorption of heat.
  • the solid For low-loss supply and removal of the material streams in the adsorption or desorption of the associated working fluid into the solid or out of the solid, the solid should offer the gas space as large a surface as possible with short diffusion paths. Furthermore, the resulting heat outputs must be as good as possible from the solid or can be supplied.
  • a high mechanical strength can be achieved, and on the other hand a large macroscopic heat contact surface can be provided for the usually poorly heat-conducting sorbent.
  • the structure according to the invention provides a good compromise between heat transport, mass transport, adsorption capacity and ratio of active to passive masses. In this case, even with the thermal stresses and vibrations occurring during operation, in particular in mobile applications, a sufficient mechanical fatigue strength is ensured.
  • the inventive heat-conducting support structure is inexpensive and largely automated to produce.
  • a preferred embodiment of the Sorptionsebenntontragerwand is characterized in that the heat-conducting support structure, a heat- includes conductive macro support structure.
  • the macro support structure is preferably designed and arranged such that the entire space of the sorption bed is penetrated. This macro support structure forms a coarse network for heat conduction from the fluid wall into the adsorber structure. This allows large adsorbent masses to be thermally connected to the fluid wall.
  • the macro support structure comprises an expanded metal mesh, a wire mesh and / or a perforated or unperforated metal foil. It is essential that the macro support structure has a very good heat-conducting metallic skeleton structure.
  • the macro support structure comprises an expanded grid with diamond-shaped or hexagonal meshes. It is particularly preferable to use a flat-rolled ultrafine expanded metal mesh.
  • Another preferred exemplary embodiment of the sorption heat exchanger wall is characterized in that the meshes have a web width of less than 1 mm, in particular less than 0.5 mm. According to one aspect of the invention, the web width is chosen as small as possible.
  • the expanded metal mesh is formed of a strip material having a thickness of less than 0.5 mm, preferably less than 0.2 mm, more preferably less than 0.1 mm , having.
  • the aim of the invention is to use the smallest possible strip thickness in order to keep the passive masses as small as possible with sufficient heat conduction and mechanical reinforcing effect.
  • a further preferred embodiment of the Sorptionsebenntontragerwand is characterized in that the strip material contains at least one copper and / or aluminum alloy. These materials provide the advantage that they are good heat-conducting.
  • a further preferred exemplary embodiment is characterized in that the sorption heat exchanger wall is formed from a pleated sandwich structure, which consists essentially of two heat-conducting films and adsorber structure arranged therebetween.
  • the intermediate adsorber structure may optionally have regions that promote axial vapor transport due to a more permeable structure.
  • the highly thermally conductive cover films can also have breakthroughs for additional vapor transport.
  • a further preferred exemplary embodiment is characterized in that the adsorber structure is formed from a metallic planar carrier structure provided on both sides with a sorbent layer, which is shaped into a pleated structure and at least one side is thermally conductively connected to the fluid wall.
  • the pleated structure is also heat-related connected to an opposite fluid wall of a sorption reactor or sorption tube.
  • a soldering, welding or adhesive process is used for this purpose.
  • the sorbent layer in the region of the contact surface is preferably removed from the metallic support structure so that it comes into direct metallic and therefore heat-conducting contact with the fluid walls, which is also a prerequisite for a subsequent soldering or welding process.
  • the sorbent layers resting against the metal foil on both sides have grooves or grooves running transversely to the rolling or production direction, which form steam channels in pleated form, which shorten the mass transfer by diffusion to the sorption-active particles.
  • the heat-conducting support structure comprises a thermally conductive meso-structure.
  • This meso structure forms a second plane of a heat-conducting structure, which, starting from a macrostructure, leads the heat flow more finely distributed in the direct vicinity of the adsorbent particles.
  • the heat conduction paths are again significantly shortened by this finer structure and thus the thermal connection of each sorbent particle to the fluid wall is improved.
  • the thermally conductive meso structure is part of the manufacturing process of the sorbent structure and is introduced together with this in the overall structure.
  • the thermally conductive meso structure contains carbon.
  • the use of carbon-based adsorbents provides the advantage that the meso-thermal conduction structure form the sorption-active structures at the same time with a suitable not too great activation, for example by using preferably used partially activated carbon fibers (AKF), AKF felts or AKF fabrics.
  • a further preferred exemplary embodiment of the sorption heat exchanger wall is characterized in that conventionally granulated activated carbon together with carbon particles, carbon platelets and / or carbon fibers is combined with a binder to form a coherent adsorber block penetrating the macrostructure.
  • the mesostructure is formed by the designed for good thermal conductivity carbon particles.
  • the carbon particles may be admixed in the form of so-called "multiwalled carbon nanotubes" to the sorption-active particles.
  • a further preferred exemplary embodiment of the sorption heat exchanger wall is characterized in that the heat-conducting meso- Support structure contains activated carbon fibers (AKF).
  • the activated carbon fibers are preferably in the form of felts or fabrics.
  • thermally conductive meso support structure is formed by admixed thin, thermally conductive metal fibers which are mixed with granulated activated carbon mixed with a binder to form a coherent adsorber block penetrating the macrostructure.
  • the sorption heat exchanger wall has a sorbent structure or channel structure.
  • the channel structure serves to transport the matter and is preferably of a fractal design similar to the bronchial system of a lung. Due to the fractal design of the mass transfer path of the active substance molecules to the sorption-active centers of the adsorption bed, the mass transport is optimized. In combination with one of the described likewise fractally approximated heat transport systems, the total kinetics of the sorption heat exchanger thus formed is optimized.
  • two independent fractal or fractal-approximate transport systems penetrate analogously to, for example, the lung, in which also two independent fractal transport systems penetrate each other.
  • the sorbent structure passes through a network of flow channels.
  • the flow channels optimize the transport and distribution of sorbent.
  • the invention also relates to a sorption heat exchanger having at least one sorption heat exchanger wall described above.
  • FIG. 1 shows the view of a section through a Sorptions Weübertra- gerwand according to a first embodiment
  • Figure 2 is a perspective view of a heat-conducting support structure
  • FIG. 3 shows an adsorption tube with a heat exchanger wall according to the invention in longitudinal section;
  • FIG. 4 shows the adsorption tube from FIG. 3 in a further longitudinal section;
  • FIG. 5 shows an enlarged detail V from FIG. 4;
  • FIG. 6 shows the view of a section along the line VI-VI in FIG. 3;
  • Figure 7 is a sectional view taken along the line VII-VII in Figure 4;
  • Figure 8 is an enlarged view of Figure 7; 9 shows the view of a section through a heat exchanger wall according to a further embodiment;
  • FIG. 10 shows the view of a further section through the heat exchanger wall from FIG. 9;
  • Figure 11 is a similar view as in Figure 9 according to another embodiment.
  • Fluid wall is connected, in section
  • Figure 13 is a schematic representation of a wound sorbent bed
  • Figure 14 is a perspective view of a clamping device for a sorption bed
  • FIG. 15 shows a sandwich structure formed of heat transfer foils with interposed adsorbent and areas of increased vapor permeability to form a sorption bed
  • FIG. 16 shows a pleated sandwich structure for forming an alternative sorption heat exchanger wall
  • 17 shows a section through a sorption tube with a pressed, pleated sandwich structure
  • FIG. 18 shows a 5-layer sandwich structure which is characterized by an additional porous intermediate layer for increasing the axial vapor permeability and through openings in the heat-conducting cover films;
  • Fig. 19 is a schematic diagram showing a structure and a preferable production method of a laminated tape for producing an adsorber structure;
  • Figures 20 are side views of an adsorbent structure made from the laminated tape by pleating and plating and doctoring and
  • FIGS. 22 are partial sectional views of a sorption tube with preferred and 23 th adsorber structures.
  • a heat exchanger wall 1 which is also referred to as a heat transfer wall, shown in section.
  • the heat transfer wall 1 is part of an adsorption reactor with a fluid side 2, which is bounded by a fluid wall 4.
  • a fluid such as water or air, flows past the fluid side 2 and releases heat to the fluid wall 4.
  • the fluid wall 4 is preferably formed from sheet metal.
  • the metal sheet is, for example, aluminum sheet.
  • the side facing away from the fluid side 2 5 of the heat exchanger wall 1 is referred to as sorption.
  • a sorption bed 6 On the sorption 5 of the heat exchanger wall 1, a sorption bed 6 is formed.
  • the sorption bed 6 contains a sorbent 7, which is attached to a heat-conducting support structure 10.
  • the thermally conductive support structure 10 has, viewed in section, a substantially castellated structure.
  • the support structure 10 is integrally connected to the fluid wall 4 at a plurality of connection points 11, 12, 13, 14. At the connection points 11 to 14, the support structure 10 is, for example, soldered, welded or glued to the fluid wall 4.
  • the thermally conductive support structure 10 is also referred to as a macro-thermal conduction structure, and includes, for example, an expanded metal mesh, a wire mesh, a perforated sheet, a sheet, and is preferably formed of a copper or aluminum alloy.
  • the sorbent 7 is provided with a sorbent structure 15 comprising a plurality of flow channels 17-20.
  • the flow channels 17 to 20 have the shape of blind holes, which are arranged perpendicular to the fluid wall 4 and tapering.
  • the sorbent structure 15 is also referred to as an adorber structure and includes, for example, carbon fiber felt, carbon fiber fabric, or a bonded char bed.
  • a heat-conductive support structure 21 is shown in perspective.
  • the heat-conducting support structure 21 is formed by a zig-zag-shaped metal grating 22, which has a plurality of longitudinal webs 23 to 25, which are interconnected by transverse webs 26 to 28.
  • the grid 22 has a pleating height 29 and a pleating density 30.
  • the heat-conducting support structure 21 is formed from a good heat-conducting alloy, preferably a copper or aluminum alloy, and constitutes a heat-conducting reinforcing structure for an adsorption bed to be applied in a subsequent process.
  • the adsorption bed (not shown) is in the form of a highly viscous or pasty mass a bed so introduced into the primary reinforcing structure, that the cavities between the metal webs 23 to 28 are almost completely filled and they are surrounded by the adsorber composite. This composite mass or bed is then cured or bonded to a solid.
  • the adsorbent composite preferably comprises adsorber particles (eg, activated carbon, zeolite, silica gel, metal hydride), a binder, and optionally a good heat-conductive filler such as carbon fibers, graphite particles (flakes), metal fibers, or the like.
  • adsorber particles eg, activated carbon, zeolite, silica gel, metal hydride
  • a binder e.g., activated carbon fibers, zeolite, silica gel, metal hydride
  • a good heat-conductive filler such as carbon fibers, graphite particles (flakes), metal fibers, or the like.
  • the adsorber composite in the nature of a fractal model has a mesoporous structure that facilitates mass transfer to deeper layers of the structure by still mixing gas or voids between the layers Contains particles.
  • the structure may have additional macrostructures, such as slots, gaps or blind holes, which are applied prior to curing of the entire structure by displacement or shaping measures
  • a hierarchical (fractal) pore system is generated, ranging from large cross-sections (longitudinal channels, blind holes, slots) to ever smaller cross-sections (spaces between sorbent particles) to the inner particulate macro- and finally to the sorption-active meso- and micropores branched.
  • the geometric dimensioning of the individual structures depends, on the one hand, on the choice of the substance pair, in particular the substance data of the working medium used (vapor pressure, density, viscosity, diffusion coefficients) and, on the other, on the heat conduction properties of the structures used.
  • the optimal geometric parameter combination for the overall structure can be determined for the structures used at the macro, meso and micro level by means of a detailed replacement model for heat and mass transfer.
  • an adsorption tube 31 constructed from half-shells and hermetically sealed on all sides is shown in different views.
  • the adsorption tube 31 comprises an adsorption bed 32 with an adsorber structure.
  • the adsorber structure is, for example, a bound bed of granular activated carbon.
  • the adsorber structure comprises, as shown in FIG. 5, a main flow passage 33 from which a plurality of bypass flow passages 34, 35 branch off.
  • the secondary flow channels 34, 35 are arranged perpendicular to the main flow channel 33. Towards the outside, the secondary flow channels 34, 35 taper sharply.
  • the adsorber structure is applied to a support structure 36.
  • the sorption tube 31 further comprises capillary structures 37, 38 which serve to receive condensed liquid. During heating, gas is expelled from the sorption bed 32, which condenses on or in the capillary structures 37, 38.
  • the sorption tube 31 from two half-shells 41, 42 is formed, which are integrally connected to one another at the connection points. In the vicinity of the connection points, the half-shells 41, 42 further main flow channels 39, 40 with a triangular cross-section.
  • FIGS. 9 and 10 show a sorption heat transfer wall according to a further exemplary embodiment in different views.
  • Grid webs 45, 46 extend vertically upwards from a fluid wall 44.
  • the grid bars 45, 46 form a macro support structure to which a plurality of fibers 47 to 50 are attached.
  • the fibers 47 to 50 form a thermally conductive meso-support structure, which in turn are connected to a bonded bed of a plurality of balls 51, 52 of sorbent.
  • FIG. 10 shows that the webs (45, 46 in FIG. 9) belong to an expanded metal grid 55. With the expanded grid 55 more fibers 56 to 59 are connected. The further fibers 56 to 59 in turn serve for connection to further graphite balls 60, 61.
  • a heat exchanger wall according to another embodiment is shown in section. From a fluid wall 64, a multiplicity of heat-conducting webs 65, 66 of a heat-conducting supporting structure extend. Between the cherriesleitstegen 65, 66 fabrics 68, 69 are disposed of activated carbon fibers.
  • FIG. 12 shows that the heat-conducting webs (65, 66 in FIG. 11) are heat-conducting gratings 55, as shown in FIG.
  • the heat-conducting webs are heat-conducting gratings 55, as shown in FIG.
  • four webs 71 to 74 each form a rhombus 75.
  • the adsorber structure is thus formed in this case by an alternating stack of heat conducting screens and activated carbon fiber webs, which is connected to the heat-conducting wall of the sorption heat exchanger at the end side.
  • bale 79 it is also possible to wind up metal stretch grids 67 with a surface-applied adsorber structure, for example in the form of a woven fabric of activated carbon fibers, onto a bale 79.
  • a surface-applied adsorber structure for example in the form of a woven fabric of activated carbon fibers.
  • bale 79 can then be connected to the front side with a fluid wall.
  • FIG. 15 shows the structure of a sandwich structure with two heat-conductive cover layers in the form of metal foils and an adsorbent layer arranged therebetween.
  • the adsorbent layer may have areas with increased vapor permeability. When using activated carbon fabric, this can be effected, for example, by appropriate adaptation of the type of binding.
  • FIG. 16 It can be seen from FIG. 16 how a folded adsorber structure is formed from the sandwich structure by pleating.
  • the areas of increased porosity to improve the mass transfer are spaced so that in each fold a corresponding flow channel is formed with reduced transport losses.
  • FIG. 17 shows an example of how this folded adsorber structure can still be compacted within a sorption tube, for example, in order to achieve a higher packing density of adsorbent material.
  • a type of piston rod is provided, with which a certain pressure on the adsorber can be exercised.
  • This bar can then be fixed by gluing, soldering, welding or other joining techniques. Due to the areas of increased vapor permeability, additional flow channels can be dispensed with so that the entire cross section of the sorption tube can be filled with the structure.
  • FIG. 18 shows a 5-layer sandwich structure which comprises an intermediate layer which further improves the axial vapor transport.
  • the lying between the planteleitfolien adsorbent mass is formed in this case by 3 layers, of which the two outer z. B. can be formed from a very dense charcoal fabric with high absorption capacity and the middle layer of an axially very permeable fabric, which essentially causes the mass transfer into the depth of the pleated structure formed therefrom.
  • FIG. 19 shows an alternative construction and an associated possible production method of a laminated strip 121, from which a particularly preferred adsorber structure can be produced with relatively simple means.
  • the laminate strip 121 is produced by laminating two preferably extruded pasty adsorber layers 122, 123 onto a flat, heat-conductive metal structure 124.
  • the doughy adsorber masses consist of a suitable mixture of adsorbent particles and binders.
  • thermally conductive particles for forming a thermally conductive meso structure, as well as possibly further unspecified additives may be included.
  • the middle metal strip can have openings and / or tulips, via which the two pasty adsorber masses can connect to one another during the lamination process and to the flat metal support structure. This improves the mutual adhesion of the three layers to one another.
  • the extruded adsorber layers 122, 123 each have a thickness of about 1 mm.
  • the metal structure 124 is preferably of a copper foil formed, which has a thickness of 0.05 mm.
  • the copper foil is tinned and optionally perforated.
  • the lamination process takes place, for example, by means of two laminating rollers 125, 126.
  • the laminating rollers 125, 126 preferably have displacer webs 127, 128 which are oriented transversely to the rolling direction on the surface and press transverse grooves or grooves 129 through 132 into the still soft sorbent layers. A portion of the grooves 129, 120, 131, 132 may serve as predetermined bending points for the subsequent pleating process.
  • Figures 20 and 21 are side views of an adsorbent structure made with the laminate tape 121.
  • a meander-shaped compact structure 133 is produced by pleating the strip 121.
  • the transverse grooves 129, 132 incorporated by displacement in the compacted structure lead to vapor channels which function as a macrostructure or mesostructure for mass transfer. In this way not recognizable, this structure can also have bronchial branches in order to make the transport of material as low-pressure as possible.
  • the crests of the meanders are freed from the sorbent layer on both sides, for example by doctoring.
  • the compacted adsorber structures 133 can be finally cut to length and cured.
  • FIGS. 22 and 23 show sectional partial views of a sorption or reaction tube 136 which is equipped with the correspondingly produced adsorber structure between fluid walls 137, 138.
  • FIGS. 22 and 23 show two exemplary courses of branched meso-channel structures with a main channel 140 and secondary channels 141, 142, 143 for mass transfer. Due to the alternating position of planes for the channel structures and the metallic macro-heat conducting layers also embedded in the adsorbent material, the lossy transport paths for the heat and material flow are short and can be easily optimized by adapting easily variable design parameters.
  • soldering or welding methods are also suitable.
  • a particularly preferred method is a low-flux soldering method which is not specified here, in which a low-melting solder layer applied on the inside of the fluid wall 137, 138 and / or on the metallic carrier layer 144 is melted and firmly bonded to the solder partner.
  • seal welding in particular laser welding, is indicated.
  • planar structure-forming adsorbent layers can be formed from any desired mixtures of adsorbent material and additional materials.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Sorption Type Refrigeration Machines (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Abstract

L'invention concerne une paroi de transfert de chaleur à sorption présentant un côté fluide (2) sollicité par un fluide dégageant ou absorbant de la chaleur, ce côté fluide (2) étant limité par une paroi pour fluide (4), ainsi qu'un côté sorption (5) qui présente un lit de sorption (6) pourvu d'un agent de sorption (7) fixant un sorbant par addition lors de l'absorption ou du dégagement de chaleur. L'objectif de l'invention est de créer une paroi à sorption mécaniquement stable qui présente de bonnes propriétés de transport de chaleur et de matières. A cet effet, le lit de sorption (6) comprend une structure support (10, 21) pour l'agent de sorption (7) qui présente une bonne conduction thermique et qui est reliée à la paroi pour fluide (4) de façon à permettre une conduction de chaleur, ainsi qu'un système hiérarchique de cavités.
EP06829464A 2005-12-19 2006-12-08 Paroi de transfert de chaleur a sorption et element de transfert de chaleur a sorption Withdrawn EP1966548A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP10159027A EP2211126A1 (fr) 2005-12-19 2006-12-08 Paroi de transmission thermique par sorption et échangeur de chaleur à sorption

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102005060623 2005-12-19
DE102006020794 2006-05-03
PCT/EP2006/011872 WO2007073849A2 (fr) 2005-12-19 2006-12-08 Paroi de transfert de chaleur a sorption et element de transfert de chaleur a sorption

Publications (1)

Publication Number Publication Date
EP1966548A2 true EP1966548A2 (fr) 2008-09-10

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Family Applications (2)

Application Number Title Priority Date Filing Date
EP10159027A Withdrawn EP2211126A1 (fr) 2005-12-19 2006-12-08 Paroi de transmission thermique par sorption et échangeur de chaleur à sorption
EP06829464A Withdrawn EP1966548A2 (fr) 2005-12-19 2006-12-08 Paroi de transfert de chaleur a sorption et element de transfert de chaleur a sorption

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EP10159027A Withdrawn EP2211126A1 (fr) 2005-12-19 2006-12-08 Paroi de transmission thermique par sorption et échangeur de chaleur à sorption

Country Status (4)

Country Link
US (1) US7981199B2 (fr)
EP (2) EP2211126A1 (fr)
JP (1) JP2009520173A (fr)
WO (1) WO2007073849A2 (fr)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005058624A1 (de) * 2005-03-15 2006-09-21 Sortech Ag Verfahren zur Herstellung eines Adsorberwärmetauschers
EP1887303A3 (fr) * 2006-08-08 2013-04-10 Behr GmbH & Co. KG Echangeur thermique et son procédé de fabrication
WO2010112433A2 (fr) * 2009-03-31 2010-10-07 Behr Gmbh & Co. Kg Accumulateur de fluide de travail, échangeur de chaleur et pompe à chaleur
JP5418401B2 (ja) * 2010-05-18 2014-02-19 富士通株式会社 吸着剤ブロックの製造方法
EP2644679B1 (fr) * 2011-02-10 2018-11-07 Kabushiki Kaisha Toyota Chuo Kenkyusho Accumulateur de chaleur chimique et procédé pour sa production
WO2013001390A1 (fr) * 2011-06-30 2013-01-03 International Business Machines Corporation Dispositifs d'échange thermique à adsorption
US9097821B2 (en) * 2012-01-10 2015-08-04 Chevron U.S.A. Inc. Integrated workflow or method for petrophysical rock typing in carbonates
JP6150686B2 (ja) * 2013-09-04 2017-06-21 日立造船株式会社 熱交換器および熱交換器の製造方法
JP2015087082A (ja) * 2013-11-01 2015-05-07 株式会社豊田自動織機 化学蓄熱装置
JP2015090242A (ja) * 2013-11-06 2015-05-11 住友電気工業株式会社 金属管、伝熱管、熱交換装置及び金属管の製造方法
DE102013226732A1 (de) 2013-12-19 2015-06-25 MAHLE Behr GmbH & Co. KG Adsorberstruktur
US9694310B2 (en) 2014-08-11 2017-07-04 Stant Usa Corp. Fuel vapor recovery canister
US10527362B2 (en) 2015-09-21 2020-01-07 Lockheed Martin Corporation Integrated multi-chamber heat exchanger
US10371462B2 (en) 2015-09-21 2019-08-06 Lockheed Martin Corporation Integrated multi-chamber heat exchanger
DE102016224338A1 (de) * 2016-12-07 2018-06-07 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Wärmeübertrager und Verfahren zu dessen Verwendung
US11441586B2 (en) * 2018-05-25 2022-09-13 Divergent Technologies, Inc. Apparatus for injecting fluids in node based connections
DE102019001810A1 (de) * 2019-03-14 2020-09-17 Steinbeis Transferzentren GmbH an der Hochschule Karlsruhe Adsorptiver Wärme- und Stoffübertrager

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3335550A (en) * 1964-04-24 1967-08-15 Union Carbide Corp Cryosorption apparatus
US3664095A (en) * 1968-10-21 1972-05-23 Gunnar C F Asker Exchange packing element
US3713281A (en) * 1971-11-02 1973-01-30 G Asker Heat and moisture exchange packing
US3727384A (en) * 1972-04-24 1973-04-17 E Feidman Contact element
JPS5270471A (en) * 1975-12-09 1977-06-11 Sumitomo Electric Ind Ltd Heat exchanger
DE3813563C2 (de) * 1988-04-22 2002-01-17 Mhb Filtration Gmbh & Co Kg Adsorptionsfilter mit hoher Luftdurchlässigkeit
DE58904918D1 (de) * 1989-02-28 1993-08-19 Leybold Ag Mit einem zweistufigen refrigerator betriebene kryopumpe.
US5441716A (en) 1989-03-08 1995-08-15 Rocky Research Method and apparatus for achieving high reaction rates
CA2049022C (fr) * 1989-03-08 2000-08-29 Uwe Rockenfeller Methode et dispositif pour l'obtention de reactions rapides dans un reacteur a reactifs solide et gazeux
JPH0387059U (fr) * 1989-12-11 1991-09-04
US5458784A (en) * 1990-10-23 1995-10-17 Catalytic Materials Limited Removal of contaminants from aqueous and gaseous streams using graphic filaments
JPH0538414A (ja) * 1991-08-06 1993-02-19 Mitsui Petrochem Ind Ltd 脱臭フイルター
JPH0682116A (ja) * 1992-09-02 1994-03-22 Kajima Corp 吸着式ヒートポンプ
DE4405669A1 (de) 1994-02-23 1995-08-24 Zeolith Tech Adsorptionsmittelbeschichtung auf Metallen und Verfahren zur Herstellung
DE9404126U1 (de) 1994-03-11 1994-06-30 Färber, Wilfried, 77704 Oberkirch Vorrichtung zur Kälteerzeugung und Wärmespeicherung über Feststoffadsorption mittels Wasserdampf und heißen Gasen
DE19539106A1 (de) 1995-10-20 1997-04-24 Webasto Thermosysteme Gmbh Wärmeübertrager mit durch Sorptionsmaterial gefüllten Zwischenräumen
US6015041A (en) * 1996-04-01 2000-01-18 Westinghouse Savannah River Company Apparatus and methods for storing and releasing hydrogen
DE19811302C2 (de) 1997-08-13 1999-12-09 Ufe Solar Gmbh Sorptionsspeicher, Anordnung und Verfahren zur Speicherung von Wärme
DE19805011B4 (de) 1998-02-07 2007-12-13 Behr Gmbh & Co. Kg Desorbierbares Sorptionsfilter, insbesondere zur Behandlung der einem Fahrzeuginnenraum zuführbaren Luft
JP4158270B2 (ja) 1999-03-19 2008-10-01 株式会社デンソー 吸着剤及び車両用空調装置
FR2793167B1 (fr) 1999-05-03 2007-01-19 Zecools Zeolite Cooling System Reacteur a adsorption reversible solide/gaz et resistance de regeneration de l'adsorbant d'un tel reacteur
US6224842B1 (en) * 1999-05-04 2001-05-01 Rocky Research Heat and mass transfer apparatus and method for solid-vapor sorption systems
DE19929718A1 (de) 1999-06-24 2000-12-28 Helmut Stach Wärmespeichermatte
DE19949638A1 (de) 1999-10-08 2001-04-12 Helmut Stach Wickelkörper
DE10028030A1 (de) * 2000-06-09 2001-12-13 Zeolith Tech Sorptionsvorrichtung zum Heizen und Kühlen von Gasströmen
DE10039885B4 (de) 2000-08-16 2009-07-02 Behr Gmbh & Co. Kg Desorbierbares Sorptionsfilter, insbesondere zur Behandlung der einem Fahrzeuginnenraum zuführbaren Luft, und Verfahren zur Herstellung eines solchen Sorptionsfilters
AT410716B (de) 2001-02-23 2003-07-25 Vaillant Gmbh Adsorber/desorber für ein zeolith-heizgerät
DE10141524C2 (de) 2001-08-24 2003-10-30 Zae Bayern Bayerisches Zentrum Fuer Angewandte Energieforschung Ev Stoff- und Wärmeaustauscherfläche
CN100402936C (zh) * 2002-07-22 2008-07-16 大金工业株式会社 除湿单元以及该除湿单元采用的吸附用元件
JP4220762B2 (ja) * 2002-11-15 2009-02-04 株式会社豊田自動織機 固体充填タンク
JP3987496B2 (ja) * 2004-01-20 2007-10-10 株式会社山岸工業 熱交換器及び脱臭殺菌装置

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2007073849A2 *

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US7981199B2 (en) 2011-07-19
EP2211126A1 (fr) 2010-07-28
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US20080257530A1 (en) 2008-10-23
WO2007073849A2 (fr) 2007-07-05
JP2009520173A (ja) 2009-05-21

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