EP1954785A1 - Selektive naphtha-hydrodesulfurierung mit mercaptanzersetzung bei hoher temperatur - Google Patents

Selektive naphtha-hydrodesulfurierung mit mercaptanzersetzung bei hoher temperatur

Info

Publication number
EP1954785A1
EP1954785A1 EP06827807A EP06827807A EP1954785A1 EP 1954785 A1 EP1954785 A1 EP 1954785A1 EP 06827807 A EP06827807 A EP 06827807A EP 06827807 A EP06827807 A EP 06827807A EP 1954785 A1 EP1954785 A1 EP 1954785A1
Authority
EP
European Patent Office
Prior art keywords
mercaptan
effluent stream
hydrodesulfurization
sulfur content
stream
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06827807A
Other languages
English (en)
French (fr)
Other versions
EP1954785A4 (de
Inventor
John Peter Greeley
Edward Stanley Ellis
Thomas Risher Halbert
William Joseph Tracy, Iii
Jeffrey M. Dysard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Publication of EP1954785A1 publication Critical patent/EP1954785A1/de
Publication of EP1954785A4 publication Critical patent/EP1954785A4/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/805—Water
    • C10G2300/807—Steam

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
EP06827807A 2005-11-23 2006-11-14 Selektive naphtha-hydrodesulfurierung mit mercaptanzersetzung bei hoher temperatur Withdrawn EP1954785A4 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/286,580 US20070114156A1 (en) 2005-11-23 2005-11-23 Selective naphtha hydrodesulfurization with high temperature mercaptan decomposition
PCT/US2006/044231 WO2007061701A1 (en) 2005-11-23 2006-11-14 Selective naphtha hydrodesulfurization with high temperature mercaptan decomposition

Publications (2)

Publication Number Publication Date
EP1954785A1 true EP1954785A1 (de) 2008-08-13
EP1954785A4 EP1954785A4 (de) 2011-06-22

Family

ID=38052405

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06827807A Withdrawn EP1954785A4 (de) 2005-11-23 2006-11-14 Selektive naphtha-hydrodesulfurierung mit mercaptanzersetzung bei hoher temperatur

Country Status (7)

Country Link
US (1) US20070114156A1 (de)
EP (1) EP1954785A4 (de)
JP (1) JP5396084B2 (de)
CN (1) CN101313053B (de)
BR (1) BRPI0618818A2 (de)
CA (1) CA2630340C (de)
WO (1) WO2007061701A1 (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0601787B1 (pt) * 2006-05-17 2016-06-07 Petroleo Brasileiro Sa processo de hidrodessulfurização seletiva de nafta
US8753504B2 (en) 2011-04-28 2014-06-17 Battelle Memorial Institute Systems and processes for removing elemental sulfur compounds from desulfurized fuels
US8828218B2 (en) * 2011-10-31 2014-09-09 Exxonmobil Research And Engineering Company Pretreatment of FCC naphthas and selective hydrotreating
FR3020376B1 (fr) * 2014-04-28 2017-10-20 Ifp Energies Now Procede de production d'une essence a basse temperature en soufre et en marcaptans.
EP2816094B1 (de) 2013-06-19 2020-04-29 IFP Energies nouvelles Herstellungsverfahren einer essenz mit niedrigem schwefel- und mercaptangehalt
FR3007416B1 (fr) * 2013-06-19 2018-03-23 IFP Energies Nouvelles Procede de production d'une essence a basse teneur en soufre et en mercaptans
JP6600912B2 (ja) * 2013-10-11 2019-11-06 コスモ石油株式会社 重質炭化水素油の水素化処理触媒及び重質炭化水素油の水素化処理触媒の製造方法
US10144883B2 (en) 2013-11-14 2018-12-04 Uop Llc Apparatuses and methods for desulfurization of naphtha
US9850435B2 (en) 2014-08-26 2017-12-26 Exxonmobil Research And Engineering Company Hydroprocessing with drum blanketing gas compositional control
CN105602618B (zh) * 2014-11-19 2017-08-25 中国海洋石油总公司 一种汽油选择性加氢脱硫的方法
CN105363481A (zh) * 2015-11-20 2016-03-02 洛阳金达石化有限责任公司 一种超低芳烃白油加氢精制催化剂的制备方法
FR3049955B1 (fr) 2016-04-08 2018-04-06 IFP Energies Nouvelles Procede de traitement d'une essence
FR3057578B1 (fr) 2016-10-19 2018-11-16 IFP Energies Nouvelles Procede d'hydrodesulfuration d'une essence olefinique.
SG11201906393TA (en) 2017-02-21 2019-09-27 Exxonmobil Res & Eng Co Desulfurization of a naphtha boiling range feed
FR3099175B1 (fr) 2019-07-23 2021-07-16 Ifp Energies Now Procédé de production d'une essence a basse teneur en soufre et en mercaptans
FR3099172B1 (fr) 2019-07-23 2021-07-16 Ifp Energies Now Procede de traitement d'une essence par separation en trois coupes
FR3099173B1 (fr) 2019-07-23 2021-07-09 Ifp Energies Now Procédé de production d'une essence a basse teneur en soufre et en mercaptans
FR3099174B1 (fr) 2019-07-23 2021-11-12 Ifp Energies Now Procédé de production d'une essence a basse teneur en soufre et en mercaptans
FR3104602A1 (fr) 2019-12-17 2021-06-18 IFP Energies Nouvelles Procédé d’hydrodésulfuration de finition en présence d’un catalyseur obtenu par la voie sels fondus
FR3108333B1 (fr) 2020-03-20 2022-03-11 Ifp Energies Now Procédé de production d'une essence a basse teneur en soufre et en mercaptans
FR3130834A1 (fr) 2021-12-20 2023-06-23 IFP Energies Nouvelles Procédé de traitement d'une essence contenant des composés soufrés
FR3130831A1 (fr) 2021-12-20 2023-06-23 IFP Energies Nouvelles Procédé de production d'une coupe essence légère à basse teneur en soufre

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3349027A (en) * 1965-02-08 1967-10-24 Gulf Research Development Co Multi-stage hydrodesulfurization process
US4132632A (en) * 1978-03-31 1979-01-02 Standard Oil Company (Indiana) Selective hydrodesulfurization of cracked naphtha
EP0755995A1 (de) * 1995-07-26 1997-01-29 Mitsubishi Oil Co., Ltd. Verfahren zur Entschwefelung von Benzin von katalytischen Kracken
US5846406A (en) * 1996-03-22 1998-12-08 Texaco Inc Selective hydrodesulfurization of cracked naphtha using novel manganese oxide octahedral molecular sieve supported catalysts
WO2001079391A1 (en) * 2000-04-18 2001-10-25 Exxonmobil Research And Engineering Company Selective hydroprocessing and mercaptan removal
WO2005033930A2 (en) * 2003-10-02 2005-04-14 Exxonmobil Research And Engineering Company Process for upgrading naphtha
US20050252831A1 (en) * 2004-05-14 2005-11-17 Dysard Jeffrey M Process for removing sulfur from naphtha

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5597476A (en) * 1995-08-28 1997-01-28 Chemical Research & Licensing Company Gasoline desulfurization process
US6231753B1 (en) * 1996-02-02 2001-05-15 Exxon Research And Engineering Company Two stage deep naphtha desulfurization with reduced mercaptan formation
US6387249B1 (en) * 1999-12-22 2002-05-14 Exxonmobil Research And Engineering Company High temperature depressurization for naphtha mercaptan removal
JP4681794B2 (ja) * 1999-12-22 2011-05-11 エクソンモービル リサーチ アンド エンジニアリング カンパニー ナフサメルカプタン除去のための高温減圧
US6495030B1 (en) * 2000-10-03 2002-12-17 Catalytic Distillation Technologies Process for the desulfurization of FCC naphtha
US6913688B2 (en) * 2001-11-30 2005-07-05 Exxonmobil Research And Engineering Company Multi-stage hydrodesulfurization of cracked naphtha streams with interstage fractionation
US7297251B2 (en) * 2002-05-21 2007-11-20 Exxonmobil Research And Engineering Company Multi-stage hydrodesulfurization of cracked naphtha streams with a stacked bed reactor

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3349027A (en) * 1965-02-08 1967-10-24 Gulf Research Development Co Multi-stage hydrodesulfurization process
US4132632A (en) * 1978-03-31 1979-01-02 Standard Oil Company (Indiana) Selective hydrodesulfurization of cracked naphtha
EP0755995A1 (de) * 1995-07-26 1997-01-29 Mitsubishi Oil Co., Ltd. Verfahren zur Entschwefelung von Benzin von katalytischen Kracken
US5906730A (en) * 1995-07-26 1999-05-25 Mitsubishi Oil Co., Ltd. Process for desulfurizing catalytically cracked gasoline
US5846406A (en) * 1996-03-22 1998-12-08 Texaco Inc Selective hydrodesulfurization of cracked naphtha using novel manganese oxide octahedral molecular sieve supported catalysts
WO2001079391A1 (en) * 2000-04-18 2001-10-25 Exxonmobil Research And Engineering Company Selective hydroprocessing and mercaptan removal
WO2005033930A2 (en) * 2003-10-02 2005-04-14 Exxonmobil Research And Engineering Company Process for upgrading naphtha
US20050252831A1 (en) * 2004-05-14 2005-11-17 Dysard Jeffrey M Process for removing sulfur from naphtha

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2007061701A1 *

Also Published As

Publication number Publication date
WO2007061701A1 (en) 2007-05-31
CA2630340A1 (en) 2007-05-31
BRPI0618818A2 (pt) 2016-09-13
JP2009517499A (ja) 2009-04-30
JP5396084B2 (ja) 2014-01-22
US20070114156A1 (en) 2007-05-24
CN101313053A (zh) 2008-11-26
EP1954785A4 (de) 2011-06-22
CA2630340C (en) 2015-12-22
CN101313053B (zh) 2012-01-25

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