EP1917502A1 - HEIßFILMLUFTMASSENMESSER MIT STRÖMUNGSABLÖSUNGSELEMENT - Google Patents

HEIßFILMLUFTMASSENMESSER MIT STRÖMUNGSABLÖSUNGSELEMENT

Info

Publication number
EP1917502A1
EP1917502A1 EP06777326A EP06777326A EP1917502A1 EP 1917502 A1 EP1917502 A1 EP 1917502A1 EP 06777326 A EP06777326 A EP 06777326A EP 06777326 A EP06777326 A EP 06777326A EP 1917502 A1 EP1917502 A1 EP 1917502A1
Authority
EP
European Patent Office
Prior art keywords
sensor chip
flow
air mass
separation element
film air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06777326A
Other languages
German (de)
English (en)
French (fr)
Inventor
Hans Hecht
Bernhard Opitz
Klaus Reymann
Ulrich Wagner
Christoph Gmelin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Robert Bosch GmbH
Original Assignee
Robert Bosch GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Robert Bosch GmbH filed Critical Robert Bosch GmbH
Publication of EP1917502A1 publication Critical patent/EP1917502A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01FMEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
    • G01F1/00Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow
    • G01F1/68Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow by using thermal effects
    • G01F1/684Structural arrangements; Mounting of elements, e.g. in relation to fluid flow
    • G01F1/6845Micromachined devices
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01FMEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
    • G01F1/00Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow
    • G01F1/68Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow by using thermal effects
    • G01F1/684Structural arrangements; Mounting of elements, e.g. in relation to fluid flow
    • G01F1/6842Structural arrangements; Mounting of elements, e.g. in relation to fluid flow with means for influencing the fluid flow
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01FMEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
    • G01F1/00Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow
    • G01F1/68Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow by using thermal effects
    • G01F1/684Structural arrangements; Mounting of elements, e.g. in relation to fluid flow
    • G01F1/688Structural arrangements; Mounting of elements, e.g. in relation to fluid flow using a particular type of heating, cooling or sensing element
    • G01F1/69Structural arrangements; Mounting of elements, e.g. in relation to fluid flow using a particular type of heating, cooling or sensing element of resistive type
    • G01F1/692Thin-film arrangements

Definitions

  • the invention relates to a H preciselyfileinuftmassenmesser with a flow separation element to prevent surface contamination and caused by surface contamination signal drift.
  • Such H comprehensivefileinuftmassenmesser be used in particular for the measurement of air mass flows in the intake of internal combustion engines.
  • gas mass in particular an air mass
  • gases which take place under controlled conditions.
  • An important example is the combustion of fuel in internal combustion engines of motor vehicles, in particular with subsequent catalytic emission control.
  • Various types of sensors are used to measure the air mass flow rate.
  • HFM hot film air mass meter
  • a thin sensor membrane is usually applied to a sensor chip, for example a silicon sensor chip.
  • On the sensor membrane is typically arranged at least one heating resistor, which is surrounded by two or more temperature resistors.
  • the temperature distribution changes, which in turn can be detected by the temperature measuring resistors.
  • an air mass flow can be determined.
  • Such sensors are for example directly in Intake tract of an internal combustion engine or used in a bypass duct.
  • An embodiment in which a sensor chip is used in a bypass channel is described, for example, in DE 103 48 400 A1.
  • a problem with this type of sensor which is known for example from DE 101 11 840 C2 is that frequent contamination of the sensor chip can occur, for example due to oil.
  • the sensor chip is usually used directly in the intake tract of the internal combustion engine or in a bypass duct to the intake tract of the internal combustion engine.
  • oil may precipitate on the sensor chip and in particular on the sensor membrane. This oil precipitate can lead to an undesired measurement signal influencing of the sensor chip, in particular since an oil film acts on the surface of the sensor chip on the thermal conductivity of the surface, which leads to distortions of the measurement signals or a signal drift.
  • the proposed hot film air mass meter has a greatly reduced surface contamination and reduced signal instabilities due to surface contamination compared to hot film air mass meters known in the art.
  • the hot-film air mass meter is particularly suitable for the measurement of air mass flows in the range between zero and sixty meters per second and can be used in particular in the intake tract of an internal combustion engine.
  • the invention is based on the finding that even dirt deposits of small height, for example above about 15 ⁇ m, can have a considerable influence on the flow behavior of the air mass flow over the surface of the hot-air mass meter.
  • the impurities lead to a flow separation with delayed flow of the flow to the - A -
  • a basic idea of the present invention is thus to minimize any kind of influence by dirt deposits on the velocity profile of the flow of the air mass flow.
  • the hot-film air mass meter serves for measuring an air mass flow flowing with a main flow direction and has a sensor chip with a measuring surface.
  • the air mass flow should flow substantially parallel over a surface of the sensor chip, of which the measuring surface is a component.
  • “Substantially” is to be understood as meaning that even slight deviations from a parallel flow can be tolerated, for example deviations of less than 10.degree ..
  • the hot-film air mass meter can be used, for example, to measure air mass flows directly in the intake tract of an internal combustion engine or in a bypass. Channel of the intake tract What is meant by the term "main flow direction" is therefore dependent on the place of use.
  • the "main flow direction” should essentially be understood as the transport direction of the air mass flow in the section of the bypass channel in which the hot film air mass meter, in particular the sensor chip, is arranged under a “main flow direction” are understood in each case the main transport direction of the air mass flow at the location of the sensor chip.
  • local turbulences should be neglected.
  • the sensor chip In principle, almost all sensor chips known from the prior art can be used as the sensor chip, for example the sensor chips proposed in DE 196 01 791 A1. In principle, however, other types of H combinfileinuftmassenmesser sensor chips can be used. However, what is essential is the presence of a measuring surface on the sensor chip. This measuring surface should be distinguished by the fact that the sensor chip in the area of the measuring surface has a significantly lower transverse thermal conductivity than in the surrounding area of the sensor chip (chip mainland). The sensor chip may preferably have a transverse thermal conductivity which is at least one order of magnitude smaller in the region of the measurement surface than in the surrounding region of the sensor chip.
  • the sensor chip may have a transverse conductivity of 0.1 to 2 W / m K in the region of the measurement surface, compared to air at 0.026 W / m K and a surrounding silicon mainland of 156 W / m K.
  • This can be, for example , as in the sensor chip disclosed in DE 196 01 791 A1, by means of a silicon membrane, which, since the transverse conductivity is determined essentially by the ambient air, has a significantly lower transverse thermal conductivity compared to the surrounding silicon mainland ,
  • the measuring range of the sensor chip can be made porous, the pores effecting a reduction in the thermal conductivity.
  • At least one heating element and at least two measuring resistors may be arranged on the measuring surface of the sensor chip, which are configured, for example, as substantially parallel conductor tracks extending substantially perpendicular to the main flow direction.
  • the individual strip conductors can also be slightly tilted relative to each other, "substantially parallel” here preferably being a tilt of not more than ⁇ 3 °.
  • “4m substantially vertical” is to be understood as meaning that an angle of the strip conductors of 90 ° ° to the main flow direction is preferred, with angular tolerances of up to 5 °, preferably of up to 2 °, are still tolerable.
  • a core element of the present invention is that the measuring surface is preceded by at least one flow separation element with respect to the main flow direction.
  • This at least one flow separation element is designed such that the air mass flow is removed by the flow separation element before reaching the measurement surface in at least one separation region of the surface of the sensor chip.
  • a core idea of this flow separation element is therefore to interpret the region described above at the transition between the measurement surface and the chip mainland of the sensor chip, in particular upstream of the measurement surface, as a "dead water area" from the outset, whereby the flow separation element is designed in such a way that the at least one separation element
  • the measurement signal of the hot-film air-mass meter configured in accordance with the invention is thus considerably more stable than conventional hot-film air mass meter. Signal drifts occur only to a greatly reduced extent. Furthermore, the at least one flow separation element causes the risk that impurities are driven by the air mass flow onto the measurement surface of the sensor chip to be greatly reduced. Overall, the inventive design of the H thoroughlyfileinuftmassenmessers thus also causes a greatly reduced susceptibility to interference and increased robustness of the system according to the invention.
  • the at least one flow separation element may have at least one elevation, wherein the at least one elevation has at least one upper edge spaced from the surface of the sensor chip at right angles to the main flow direction.
  • the term "spaced apart" does not necessarily mean that the flow separation element is arranged on the surface of the sensor chip, it is preferred if the at least one flow separation element is arranged upstream of the sensor chip on the hot film air mass meter It is preferred if this upper edge projects beyond the surface of the sensor chip by at least 15 ⁇ m, preferably by at least 30 ⁇ m and particularly preferably by at least 40 ⁇ m, ie perpendicular to the main flow direction of this upper edge. surface is spaced. This dimensioning of the at least one flow separation element has proven advantageous in view of typical deposits on the sensor chip.
  • the at least one flow separation element may comprise, for example, a flowwall, a wire, an auxiliary plate, a step and / or an overhang, as well as combinations of said elements. It is particularly preferred if the at least one flow separation element extends substantially parallel to the surface of the sensor chip, so that in particular the upper edge of the elevation extends substantially parallel to the surface of the sensor chip. As with the definition of "substantially” with respect to the parallel flow of the air mass flow over the measuring surface, deviations from a parallelism of up to approximately 10 ° should also be tolerable here Extends substantially perpendicular to the main flow direction. Again, deviations of up to 10 ° can be tolerated.
  • the measurement surface can have at least one conductor track.
  • This may in particular be a conductor track of one or more temperature sensors and / or one or more heating elements.
  • the at least one flow separation element of the at least one interconnect is at least 30 ⁇ m, and preferably at least 50 ⁇ m, with respect to the main flow direction. Since, as a rule, the at least one flow separation element itself has a finite extent, these minimum values preferably refer to the above-described upper edge of the at least one flow separation element, in particular to the distance along the main flow direction between this upper edge and the foremost upstream flow or at least one part of the at least one flow separation element which is closest to the at least one conductor track, this embodiment of the invention prevents the separation area from overstressing the area I extends the at least one conductor track, in which case over the at least one conductor track no laminar flow of the air mass
  • the detachment area would then protrude beyond the at least one interconnect and falsify measurements there. However, slight overlaps of the detachment area with the at least one conductor track are still tolerable. Apart from this minimum distance to the interconnects, however, there are also other preferred arrangements of the at least one flow separation element. So it is particularly preferred if the sensor chip at the transition between the measuring surface and the chip mainland has a boundary line that the at least one flow separation element of the
  • Borderline (or the most upstream portion of this boundary line) upstream of the main flow direction by a maximum of 500 microns, preferably by a maximum of 300 microns and more preferably by a maximum of 200 microns.
  • This maximum distance to the (upstream) limit line results from the fact that, as described above, contaminants (in particular oil droplets) accumulate preferentially at the boundary line which is exposed to a high temperature gradient. If the at least one flow separation element is arranged too far upstream of this boundary line, this has the effect that the flow has already re-established itself against the chip surface when the impurities have reached the boundary line. Thus, this flow in the region of the boundary line is already influenced again by impurities at the boundary line, so that the at least one flow separation element has lost its effect.
  • the term "maximum” should be understood as including a distance between the boundary line and said top edge and / or a distance between the boundary line and the furthest from the boundary line Part of at least one flow separation element is subsumed.
  • the at least one flow separation element can furthermore be realized by recessing the sensor chip into a chip carrier.
  • the sensor chip is held in a chip carrier, with the chip carrier having a carrier surface substantially overflowed in parallel by the air mass flow (deviation tolerance again about 10 °).
  • the sensor chip with a surface recessed in relation to the carrier surface is embedded in the chip carrier, whereby at the transition between the chip carrier and sensor chip on the inflow side (ie located upstream with respect to the main flow direction) forms a step.
  • the step acts as a flow separation element and forms a separation region in the edge region of the sensor chip.
  • the surface of the sensor chip is at least 15 ⁇ m relative to the carrier surface, in particular at least 30 ⁇ m, and especially preferably recessed by at least 40 microns.
  • This embodiment is particularly (but not exclusively) advantageous if dirt deposits due to thermogradient forces are also to be expected in the vicinity of the edge of the sensor chip and not further inside the surface of the sensor chip. In particular, this is the case when the measuring surface z. B. is produced over a large area by porosification (in contrast to a membrane which is usually not generated over a large area) and extends to near the edge region of the chip surface.
  • FIG. 1 shows an exemplary division of a sensor chip of a hot-film air mass meter into a measuring surface and a chip mainland;
  • Figure 2A is a schematic representation of the influence of an air mass flow over a surface by an impurity applied to the surface;
  • FIG. 2B shows the arrangement according to FIG. 2A with a flow separation element applied before the contamination
  • FIGS. 3A to 3D show various embodiments of the embodiment of a flow separation element
  • FIG. 4 shows an embodiment of a flow separation element in the form of a sensor chip recessed into a chip carrier.
  • FIG. 1 shows a configuration of a sensor chip 110 (only hinted at) of a hot-film air-mass meter (with the exception of an inventive flow-separation element, see below).
  • the sensor chip 110 can be used, for example, in the intake tract of an internal combustion engine or in a bypass channel to the intake tract of an internal combustion engine. Such devices are known for example from DE 196 01 791 Al.
  • the sensor chip according to the embodiment in FIG. 1 has a Chip mainland with a continental surface 112 in the plane of the drawing (only partially shown). In this embodiment, it is assumed that the sensor chip 110 is a silicon sensor chip. Furthermore, the sensor chip 110 has a measuring area with a measuring surface 114 in the plane of the drawing.
  • the measuring surface 114 is configured in this embodiment in the form of a rectangle 116, which has longer sides L M 118, 120 perpendicular to a main flow direction 122 of an air mass flow.
  • the longer side 118 thus represents the furthest upstream part of the rectangle 116 and thus the boundary line of the measurement surface 114.
  • the shorter sides 1 M of the rectangle 116 are designated by the reference numerals 124, 126 and are arranged parallel to the main flow direction 122.
  • the sensor chip 110 has a thermal conductivity in the region of the measurement surface 114 which is approximately 0.1 to 2 W / m K compared to the surrounding mainland at 126 W / m K. This can be achieved by porosification of the silicon in the range the measuring surface 114 can be achieved.
  • a sensor membrane with a laterally substantially determined by the surrounding air thermal conductivity of 0.026 W / m K can be used.
  • Conductor tracks 128 of a central hot-film air mass meter circuit are arranged in the region of the measuring surface 114.
  • These printed conductors 128 are composed of a central heating element 130 and two temperature sensors 132, 134.
  • a temperature sensor 132 is arranged upstream of the central heating element 130 and a temperature sensor 134 downstream.
  • the printed conductors 128 define in their outer dimensions on the measuring surface 114 a sensor region 136.
  • This sensor region 136 is likewise configured in the form of a rectangle 138, which has the longer sides 140, 142 and shorter sides 144, 146.
  • the connection-side shorter side 144 of the rectangle lies on the connection-side shorter side 124 of the rectangle 116 of the measurement surface.
  • the side lengths of the rectangle 138 of the sensor region 136 are denoted by L 8 and l s in FIG.
  • the printed conductors 128 of the central HFM circuit extend almost to the outer rectangle 116 of the measuring surface 114.
  • the rectangle 138 of the sensor region 136 is dimensioned only insignificantly smaller, for example, L 8 is about 0.9 to 0.95 x L M and l s is about 0.7 x 1 M.
  • oil droplets 148 are thus arranged in the immediate vicinity of the printed conductors 128.
  • a slight external force for example due to the air mass flow, causes oil droplets 148 to be driven onto the printed conductors 128.
  • the accumulation of oil droplets 148 also causes a change in the thermal conductivity of the sensor chip 110 in the region of the edge of the rectangle 116 of the measuring surface 114.
  • the oil droplets 148 can increase the conductivity at the transition between the measuring surface 114 and the mainland surface 112. This has a significant influence on the temperature distribution on the measuring surface 114.
  • oil droplets 148 often form a bonding agent for dust and soot.
  • an "oilwall" with a height of about 15 to 30 microns in the region of the edge of the rectangle 116 of the measuring surface is formed, which leads to air turbulence in this area, which calmed down again after a certain distance 2A shows the effect of dirt deposits in the inflow region of a hot film air mass meter on the velocity profile of the air mass meter above the sensor chip 110 of the hot film air mass meter.
  • fouling wall 210 In addition to oil droplets 148, further impurities can also be added to this fouling wall 210 contribute, for example, dust or other flying particles.
  • FIG. 2A shows flow lines 212 of an air mass flow, which flows in parallel with the main flow direction 122 over a surface 214 of the sensor chip 110.
  • airfoils 216 which symbolize the velocity profile of the air mass flow over the surface 214.
  • the detachment area 218 As can be seen from the illustration according to FIG. 2A, behind (ie with respect to the main flow direction 122 downstream) of the soiling wall 210, a soiling condition is formed. the detachment area 218. The boundary of this contamination-related detachment area 218 is shown symbolically by the dashed line 220. While a substantially laminar flow over the surface 214 prevails outside of the contamination-related detachment region 218 in the example according to FIG. 2A, this flow is removed in the polluting detachment region 218, whereby air turbulences 222 form in this detachment region 218.
  • the soiling separation region 218 extends to the measuring surface 114 and into the range of Conductor tracks 128.
  • the contamination-related detachment area 210 has an extent parallel to the main flow direction 122 of approximately 200 to 300 ⁇ m. Since the longer side 118 of the rectangle 116 in FIG.
  • FIG. 2B shows an example in which, in a modification to FIG. 2A, the contamination wall 210 is preceded by an inventive flow separation element 224.
  • this flow separation element 224 has the shape of a wall with a rectangular cross section and an upper edge 226 which, in this exemplary embodiment, lies at a height H (reference numeral 228) of approximately 30 ⁇ m above the surface 214 of the sensor chip 110.
  • H reference numeral 2228
  • the flow separation element 224 is about twice the height of the contaminant wall 210 (about 15 ⁇ m, see above).
  • a detachment region 230 forms with a boundary 232 of the detachment region 230, which virtually completely encloses the contamination-dependent detachment region 218.
  • the detachment region 230 of the flow detachment element 224 does not depend on the height of the impurity wall 210 and is therefore constant in time.
  • this separation region 230 although this also has an extent up to the tracks 128, be taken into account in a calibration of the hot-air mass meter.
  • the effects of the contamination-related detachment region 218 are not or only slightly noticeable, so that the calibration of the hot-film air mass meter is independent of the height of the impurity wall 210.
  • An additional effect of the flow separation element 224 is that the clogging wall 210 is prevented from passing through the mass air flow is driven onto the sensor area 136 of the sensor chip 110.
  • the position of the flow separation element 224 (which does not correspond to the state of the art) is shown symbolically by the dashed line 150. It can be seen that in this preferred embodiment, the flow separation element 224 extends substantially parallel to the conductor track loops 128, that is, substantially perpendicular to the main flow direction 122 of the air mass flow. The distance between the longer side 118 of the rectangle 116 and the flow separation element 224 is denoted symbolically d in the illustration according to FIG. 1 and in this exemplary embodiment is approximately 200 ⁇ m.
  • FIG. 3A to 3D Various embodiments for realizing the flow separation element 224, which may be used as an alternative to the "wall" used in Figure 2B, are shown in Figures 3A to 3D, but it should be understood that other embodiments of the flow separation element 224 are possible 3A to 3C each show a chip carrier 310, which is flowed or overflowed by the air mass flow (symbolically represented by the flow direction 122) via a leading edge 312.
  • the chip carrier 310 is designed, for example, as an injection-molded plastic part.
  • the sensor chip 110 is embedded according to the above description, wherein the surface 214 of the sensor chip 110 is substantially flush with the support surface 314 of the chip carrier 310.
  • the embodiment of the measuring surface 114 of the sensor chip 110 entspri For example, the embodiment in FIG. 1
  • Embodiment 3A the flow separation element 224 designed as a long wire which extends parallel to the leading edge 312.
  • the flow separation element 224 is designed in the form of an adhesive bead, which can be produced for example by applying a self-curing, a UV-curing or a temperature-curing adhesive. This embodiment is technically comparatively simple and inexpensive to implement.
  • a chip is applied to the chip carrier 310 upstream of the sensor chip 110, which acts as a whole as a flow separation element 224.
  • the flow separation element 224 is designed as an overhang, which projects beyond the sensor chip 110 by approximately 100 ⁇ m.
  • This overhang can be formed, for example, as an integral part of the chip carrier 310 and, for example, already formed during the manufacture (for example injection molding) of the chip carrier 310. Alternatively or additionally, the overhang can also be applied as a separate component to the chip carrier 310.
  • FIG. 4 shows a further exemplary embodiment of a hot-air air mass meter, in which the sensor chip 110 is recessed into the chip carrier 310.
  • the sensor chip 110 is in turn configured analogously to the representation in FIG. 1 and has a chip surface 214 with a measurement surface 114 and a mainland surface 112.
  • the exemplary embodiment according to FIG. 4 is particularly advantageous for sensor chips 110, in which the measurement surface 114 approaches (eg, ⁇ 400 .mu.m) the edge of the chip surface 214, that is to say, for example, measurement surfaces 114 produced by porosification.
  • the surface 114 of the sensor chip 110 is recessed relative to the carrier surface 314 in this embodiment by approximately 60 ⁇ m, so that the edge 410 forms the flow separation element 224 and corresponds to the top edge 226 in the illustration according to FIG. 2B.
  • a detachment region 230 is formed behind the edge 410.
  • This separation region 230 comprises the contamination wall 210 and an optional contamination-related separation region 218 of the contamination wall 210.
  • the flow separation element 224 has the same effect in this embodiment as in the above described cases.
  • the sensor chip 110 is connected to the chip carrier 310 via a connection layer 412 (for example an adhesive) and firmly embedded in it. By changing the thickness of the connection layer 412, the thickness of the depression of the surface 214 of the sensor chip 110 with respect to the support surface 314, and thus the size of the detachment region 230, can be adjusted.

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  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • General Physics & Mathematics (AREA)
  • Measuring Volume Flow (AREA)
EP06777326A 2005-08-16 2006-06-14 HEIßFILMLUFTMASSENMESSER MIT STRÖMUNGSABLÖSUNGSELEMENT Withdrawn EP1917502A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005038598A DE102005038598A1 (de) 2005-08-16 2005-08-16 Heißfilmluftmassenmesser mit Strömungsablösungselement
PCT/EP2006/063191 WO2007020116A1 (de) 2005-08-16 2006-06-14 HEIßFILMLUFTMASSENMESSER MIT STRÖMUNGSABLÖSUNGSELEMENT

Publications (1)

Publication Number Publication Date
EP1917502A1 true EP1917502A1 (de) 2008-05-07

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EP06777326A Withdrawn EP1917502A1 (de) 2005-08-16 2006-06-14 HEIßFILMLUFTMASSENMESSER MIT STRÖMUNGSABLÖSUNGSELEMENT

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US (1) US8448503B2 (ja)
EP (1) EP1917502A1 (ja)
JP (1) JP5124458B2 (ja)
CN (1) CN101243307B (ja)
DE (1) DE102005038598A1 (ja)
WO (1) WO2007020116A1 (ja)

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DE102005038598A1 (de) 2007-02-22
CN101243307A (zh) 2008-08-13
WO2007020116A1 (de) 2007-02-22
JP5124458B2 (ja) 2013-01-23
CN101243307B (zh) 2010-05-26
JP2009505087A (ja) 2009-02-05
US8448503B2 (en) 2013-05-28
US20110036157A1 (en) 2011-02-17

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