EP1908133A1 - Procede pour fabriquer des dispositifs electroniques organiques sur des substrats plastiques sensibles aux solvants et/ou a la temperature - Google Patents

Procede pour fabriquer des dispositifs electroniques organiques sur des substrats plastiques sensibles aux solvants et/ou a la temperature

Info

Publication number
EP1908133A1
EP1908133A1 EP06775769A EP06775769A EP1908133A1 EP 1908133 A1 EP1908133 A1 EP 1908133A1 EP 06775769 A EP06775769 A EP 06775769A EP 06775769 A EP06775769 A EP 06775769A EP 1908133 A1 EP1908133 A1 EP 1908133A1
Authority
EP
European Patent Office
Prior art keywords
ofets
oleds
solar cells
emitting diodes
effect transistors
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP06775769A
Other languages
German (de)
English (en)
Inventor
Mario SCHRÖDNER
Karin Schultheis
Hannes Schache
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Thueringisches Institut fuer Textil und Kunststoff Forschung eV
Original Assignee
Thueringisches Institut fuer Textil und Kunststoff Forschung eV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Thueringisches Institut fuer Textil und Kunststoff Forschung eV filed Critical Thueringisches Institut fuer Textil und Kunststoff Forschung eV
Publication of EP1908133A1 publication Critical patent/EP1908133A1/fr
Ceased legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K77/00—Constructional details of devices covered by this subclass and not covered by groups H10K10/80, H10K30/80, H10K50/80 or H10K59/80
    • H10K77/10—Substrates, e.g. flexible substrates
    • H10K77/111—Flexible substrates
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
    • H10K10/40—Organic transistors
    • H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
    • H10K10/462—Insulated gate field-effect transistors [IGFETs]
    • H10K10/464—Lateral top-gate IGFETs comprising only a single gate
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
    • H10K10/40—Organic transistors
    • H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
    • H10K10/462—Insulated gate field-effect transistors [IGFETs]
    • H10K10/466—Lateral bottom-gate IGFETs comprising only a single gate
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
    • H10K10/40—Organic transistors
    • H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
    • H10K10/462—Insulated gate field-effect transistors [IGFETs]
    • H10K10/468—Insulated gate field-effect transistors [IGFETs] characterised by the gate dielectrics
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/80—Constructional details
    • H10K50/84—Passivation; Containers; Encapsulations
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/141—Organic polymers or oligomers comprising aliphatic or olefinic chains, e.g. poly N-vinylcarbazol, PVC or PTFE
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/151—Copolymers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/80—Constructional details
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/80—Constructional details
    • H10K50/84—Passivation; Containers; Encapsulations
    • H10K50/844—Encapsulations
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/80—Constructional details
    • H10K59/87—Passivation; Containers; Encapsulations
    • H10K59/873—Encapsulations
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the invention relates to the production of organic field-effect transistors (OFETs), solar cells or light-emitting diodes (OLEDs) and circuits based thereon on the surface of solvent- and / or temperature-sensitive plastics, e.g. thermoplastic injection molded bodies.
  • OFETs organic field-effect transistors
  • OLEDs light-emitting diodes
  • the invention further relates to electronic components which are produced by this method.
  • OFETs organic field-effect transistors
  • substrates such as silicon, glass, polyester film (PET, PEN) or polyimide film using simple processes ⁇ CJ Drury, CM. J. Mutsaers' CM. Hart, M. Matters and DM de Leeuw: Appl. Phys. Lett. 73 (1998), 108; F. Eder, H. Klauk, M. Halik, U. Zschieschang, G. Schmid and C. Dehm, Appl. Phys. Lett. 84 (2004), 2673; J. Ficker, A. Ullmann, W. Fix, H.
  • the maximum continuous service temperature of the carrier material is also important for process control. These requirements are largely met, for example, by polyethylene terephthalate (PET) and polyimide.
  • a gate insulator for an organic HL device in particular for a field effect transistor is described which consists of a crosslinked at temperatures between 150 0 C and 200 0 C polysiloxane compound.
  • polysilane used for electrical insulation to protect loxan für ABS, polycarbonate or Polysty- rolsubstraten not possible against harmful effects of solvents during the manufacturing process.
  • ÜS2003 / 0224621 a method for producing organic semiconductor systems on various documents such as textiles is given. This method also includes the bring a protective layer on the substrate surface below the semiconductor. However, it obviously does not serve to protect the substrate from chemical effects by solvents. Also, no information is given about the chemical composition of the protective layer.
  • injection molding materials such as ABS polymer, polycarbonate and polystyrene into consideration.
  • these injection molding materials unlike silicon, glass, polyimide, and other substrate materials, many of these injection molding materials, which often serve as electronic packaging materials, compact disks (CDs), and DVDs, are sensitive to organic solvents. In addition, they are thermally mostly low loadable.
  • the roughness of the surface of the injection molding tool used also determines the surface roughness of the substrate, so that injection molding materials are only of limited use as base materials for organic electronics.
  • the object of the invention is therefore to provide a simple and inexpensive process for producing organic field effect transistors (OFETs), solar cells or light-emitting
  • OLEDs Specify diodes
  • an organic layer is applied, for example, partially or on the entire substrate surface of an injection-molded body, which is insoluble in relation to the solvents used below and whose production does not require too high temperatures.
  • Layer thicknesses between 1 ⁇ m and 5 ⁇ m are generally sufficient to protect the surface of this plastic body from solvent attack.
  • the mostly rough surface is smoothed out.
  • Crosslinkable polymers such as acrylates, polyester or epoxy resins prove to be particularly suitable.
  • the crosslinking should be carried out at low temperatures or photochemically.
  • the application of the protective layer can also in large-scale coating method, for. B. by printing, knife coating or local dripping (microdosing) happen. Then the structure of the organic components and their circuits is then made.
  • Organic or polymeric field effect transistors in the sense of this invention comprise at least the following function-determining layers on a substrate: an organic semiconductor layer between and under at least one source and at least one drain electrode which are made of a conductive organic or inorganic material , an organic insulation layer over or below the semiconductive layer and an organic conductor layer.
  • the corresponding integrated organic or polymer electronic circuits consist of at least two organic or polymeric field-effect transistors.
  • Figures 1 and 2 show schematically and in sectional view field effect transistors according to the two embodiments, wherein in Figure 2, a variant was selected for the layer structure in which the layers are arranged inversely to the structure shown in Figure 1.
  • a gate electrode 5 is generated directly on the surface of a plastic body 1 of a conductive polymer dispersion, which does not attack the plastic surface. This may be, for example, an aqueous or alcoholic dispersion of a carbon black composite.
  • an (insulating) protective layer 6 is applied, which protects the plastic or injection-molded body 1 from solvents and at the same time serves as an insulator between the gate electrode 5 and the source or drain electrode 2, 4.
  • an organic semiconductor layer 3 and the source or drain electrode 2, 4 are then applied.
  • the order of the polymer layers can be done by printing or dripping (microdosing). The structuring of the electrodes can, if this has not already been done during printing, e.g. achieve by laser processing.
  • FIG. 1 describes a realization of the invention according to FIG. 1.
  • the networking takes place with a high-performance ÜV lamp with an exposure time of up to 3 seconds.
  • the layer thickness is about 5 microns.
  • a layer of a conductive carbon black polymer composite is also applied by doctoring.
  • the source-drain electrodes 2,4 are produced by selective removal with an excimer laser.
  • the polymer semiconductor 3 poly-3-dodecylthiophene
  • the polymer semiconductor 3 from a 0.25% solution of chloroform or toluene is applied by spin coating (4000 U / min).
  • As insulator layer 6 polyvinylphenol is spin-coated from a 20% solution at 2000 revolutions / minute.
  • the gate electrodes 5 are made by local application of a colloidal graphite.
  • Figure 3
  • Example 2 This example involves implementation of the invention as shown in Figure 2.
  • a layer of the conductive polymer Polyethylendioxythiophen (Baytron) is geräkelt. This layer is patterned by selective removal with an excimer laser, so that the gate electrodes 5 are obtained.
  • the (insulating) protective layer 6 a layer of an alcoholic polyvinylphenol solution containing a crosslinking agent is applied by spinning at 2000 rpm.
  • the Polyvinylphenol für anschlieOend is annealed for 3 hours at 70 0 C.
  • a thin gold layer (about 20 nm) is sputtered, from which in turn the source-drain electrodes 2, 4 are generated with an excimer laser.
  • the semiconductor layer 3 is applied by spin-coating a 0.25% poly-3-hexylthiophene solution in toluene.
  • the output characteristics of a field effect transistor produced in this way are shown in FIG. 4.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Thin Film Transistor (AREA)
  • Electroluminescent Light Sources (AREA)

Abstract

L'invention concerne la fabrication de transistors à effet de champ organiques (OFET), de cellules solaires organiques ou de diodes électroluminescentes organiques (OLED) et de circuits basés sur ces éléments à la surface de plastiques sensibles aux solvants et/ou à la température, par ex., des éléments thermoplastiques moulés par injection. Une couche protectrice constituée par un composé polymère comme le polyacrylate, le polyphénol, la résine mélamine ou polyester, est appliquée et séchée à partir d'une solution aqueuse alcoolique ou sans solvant sur la surface d'un substrat ou sur une des couches déterminant la fonction de l'élément semi-conducteur électronique selon un procédé à basse température, les températures étant inférieures à 100 °C. Cette couche protectrice protège le substrat d'effets involontaires de solvants et peut simultanément servir de couche de planarisation et/ou d'isolation électrique.
EP06775769A 2005-07-27 2006-07-26 Procede pour fabriquer des dispositifs electroniques organiques sur des substrats plastiques sensibles aux solvants et/ou a la temperature Ceased EP1908133A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005035696A DE102005035696A1 (de) 2005-07-27 2005-07-27 Verfahren zur Herstellung organischer Feldeffekttransistoren und darauf basierender Schaltungen auf Lösungsmittel- und temperaturempfindlichen Kunststoffoberflächen und organische Feldeffekttransistoren und organische optoelektronische Bauelemente nach diesem Verfahren
PCT/DE2006/001328 WO2007012330A1 (fr) 2005-07-27 2006-07-26 Procede pour fabriquer des dispositifs electroniques organiques sur des substrats plastiques sensibles aux solvants et/ou a la temperature

Publications (1)

Publication Number Publication Date
EP1908133A1 true EP1908133A1 (fr) 2008-04-09

Family

ID=37398573

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06775769A Ceased EP1908133A1 (fr) 2005-07-27 2006-07-26 Procede pour fabriquer des dispositifs electroniques organiques sur des substrats plastiques sensibles aux solvants et/ou a la temperature

Country Status (6)

Country Link
US (1) US20090127544A1 (fr)
EP (1) EP1908133A1 (fr)
JP (1) JP2009503824A (fr)
KR (1) KR20080052550A (fr)
DE (1) DE102005035696A1 (fr)
WO (1) WO2007012330A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2959865B1 (fr) * 2010-05-07 2013-04-05 Commissariat Energie Atomique Diminution des effets de casquettes dues a l'ablation laser d'un niveau metallique par utilisation d'une couche de polymere photo- ou thermo-reticulable non reticule
DE102010027239B4 (de) 2010-07-15 2014-06-12 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zur Beschichtung eines Substrates mit einer Schutzschicht, beschichtetes Substrat, elektronisches Bauteil sowie Verwendungszwecke
US9299956B2 (en) * 2012-06-13 2016-03-29 Aixtron, Inc. Method for deposition of high-performance coatings and encapsulated electronic devices
KR101490554B1 (ko) * 2012-07-06 2015-02-05 주식회사 포스코 유기발광 다이오드 패널과 지지소재의 접합방법 및 유기발광 다이오드 모듈
KR101473308B1 (ko) * 2012-11-23 2014-12-16 삼성디스플레이 주식회사 유기 발광 소자
US20150212240A1 (en) * 2014-01-28 2015-07-30 GE Lighting Solutions, LLC Reflective coatings and reflective coating methods
US10875957B2 (en) * 2015-11-11 2020-12-29 The Regents Of The University Of California Fluorine substitution influence on benzo[2,1,3]thiodiazole based polymers for field-effect transistor applications
FR3103734A1 (fr) * 2019-11-29 2021-06-04 Commissariat A L'energie Atomique Et Aux Energies Alternatives Circuit électronique et son procédé de fabrication

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1024952B1 (fr) * 1997-10-24 2002-06-26 Agfa-Gevaert Stratifie comportant un substrat mince de verre a base de borosilicate comme couche constitutive
US6664137B2 (en) * 2001-03-29 2003-12-16 Universal Display Corporation Methods and structures for reducing lateral diffusion through cooperative barrier layers
KR20040027940A (ko) * 2001-08-20 2004-04-01 노바-플라즈마 인크. 기체 및 증기 침투율이 낮은 코팅층
US7033959B2 (en) * 2002-05-31 2006-04-25 Nokia Corporation Method for manufacturing organic semiconductor systems
CN100594617C (zh) * 2002-07-31 2010-03-17 三菱化学株式会社 场效应晶体管
DE10255870A1 (de) * 2002-11-29 2004-06-17 Infineon Technologies Ag Verfahren zur Herstellung von organischen Feldeffektransistoren mit Top-Kontakt-Architektur aus leitfähigen Polymeren
US7011983B2 (en) * 2002-12-20 2006-03-14 General Electric Company Large organic devices and methods of fabricating large organic devices
EP1609196B1 (fr) * 2003-04-01 2010-12-22 Canon Kabushiki Kaisha Dispositif a semi-conducteur organique
US20060231829A1 (en) * 2005-04-13 2006-10-19 Xerox Corporation TFT gate dielectric with crosslinked polymer

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2007012330A1 *

Also Published As

Publication number Publication date
WO2007012330A1 (fr) 2007-02-01
US20090127544A1 (en) 2009-05-21
JP2009503824A (ja) 2009-01-29
KR20080052550A (ko) 2008-06-11
DE102005035696A1 (de) 2007-02-15

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