EP1847791B1 - Verfahren zur trocknung von schlämmen und vorrichtung zur durchführung dieses verfahrens - Google Patents

Verfahren zur trocknung von schlämmen und vorrichtung zur durchführung dieses verfahrens Download PDF

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Publication number
EP1847791B1
EP1847791B1 EP07290491A EP07290491A EP1847791B1 EP 1847791 B1 EP1847791 B1 EP 1847791B1 EP 07290491 A EP07290491 A EP 07290491A EP 07290491 A EP07290491 A EP 07290491A EP 1847791 B1 EP1847791 B1 EP 1847791B1
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EP
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Prior art keywords
sludge
chamber
drying
pressure
microwaves
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English (en)
French (fr)
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EP1847791A1 (de
Inventor
Bernard Dedieu
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BARBOSA, ARTHUR
SARL INNOPARTS
BEARN INNOVATION
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SARL INNOPARTS
BEARN INNOVATION
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Priority to PL07290491T priority Critical patent/PL1847791T3/pl
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26—DRYING
    • F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B3/00—Drying solid materials or objects by processes involving the application of heat
    • F26B3/32—Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action
    • F26B3/34—Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action by using electrical effects
    • F26B3/347—Electromagnetic heating, e.g. induction heating or heating using microwave energy
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26—DRYING
    • F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B3/00—Drying solid materials or objects by processes involving the application of heat
    • F26B3/32—Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action
    • F26B3/34—Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action by using electrical effects
    • F26B3/343—Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action by using electrical effects in combination with convection
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26—DRYING
    • F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B11/00—Machines or apparatus for drying solid materials or objects with movement which is non-progressive
    • F26B11/12—Machines or apparatus for drying solid materials or objects with movement which is non-progressive in stationary drums or other mainly-closed receptacles with moving stirring devices
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26—DRYING
    • F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B21/00—Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects
    • F26B21/06—Controlling, e.g. regulating, parameters of gas supply
    • F26B21/08—Humidity
    • F26B21/086—Humidity by condensing the moisture in the drying medium, which may be recycled, e.g. using a heat pump cycle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26—DRYING
    • F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B7/00—Drying solid materials or objects by processes using a combination of processes not covered by a single one of groups F26B3/00 and F26B5/00
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26—DRYING
    • F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B2200/00—Drying processes and machines for solid materials characterised by the specific requirements of the drying good
    • F26B2200/18—Sludges, e.g. sewage, waste, industrial processes, cooling towers

Definitions

  • the present invention relates to a sludge drying process and the device for carrying out the process, and more particularly to a method and its device for drying industrial, mixed or urban sludge.
  • Another solution is initially to dry the sludge and then put in the form of granules that can be stored.
  • the drying step is generally carried out by depositing the still wet sludge on a drying bench, the sludge then being traversed by a heated air flow. At the end of this step the sludge is transformed into granules.
  • a disadvantage of this type of treatment is that the drying of the sludge with the heated air flow is too long.
  • the patent FR 2 115 951 proposes a device, which could solve the problem of the too long drying time, allowing to dry products like animal feed or fertilizer, and allowing to sterilize these products, after putting them in the form of previously fragmented sludge.
  • This device comprises a screw conveyor in the form of a tube that will allow the transport of fragmented sludge.
  • the carrier comprises a shaft extending axially with respect to the tube and having blades arranged helically.
  • This transporter has the sole purpose of advancing the fragmented sludge towards the irradiation zone by microwaves. These microwaves have the function of sterilizing the fragments and perfect drying by allowing the release of the remaining moisture of the fragmented sludge. Plots thus dried out of the device and are collected to be packaged.
  • the object of the present invention is to propose a method and its device which make it possible to optimize the sludge drying without risk of explosion while at the same time very rapidly obtaining complete sludge drying and thereby reducing the energy consumed.
  • the sludge is mixed with the mixer to allow a better homogeneity of drying, while greatly promoting the penetration of microwaves in the material.
  • the saturation water vapor pressure is in a range between 1 bar and 3 bars.
  • the saturation water vapor pressure is 1 bar.
  • the superheated steam pressure is between 1 bar and 5 bar.
  • the superheated steam pressure is 3 bar.
  • the temperature of the chamber must be lower than the temperature of the sludge to allow evaporation.
  • the irradiation by microwaves is performed when the temperature of the sludge is between 110 ° C and 140 ° C.
  • the irradiation by microwaves is performed when the temperature of the sludge is 130 ° C.
  • Another object of the invention is to provide a device for carrying out the method.
  • the device for carrying out the method consists of an enclosure, comprising a sealed tank, resistant to pressure and communicating by at least one quartz window or any other material suitable for microwaves. waves with at least one microwave generator, the chamber communicating with a saturated steam inlet path and a sludge inlet to be dried, a mixer comprising means for injecting superheated steam disposed in the enclosure, a unloading hatch of dried materials.
  • the device comprises in its lower part facing the ground an orifice for discharging by gravity runoff controlled by a valve or regulate the internal pressure of the enclosure.
  • the enclosure comprises cooling means arranged in its lowest part so as to cool its inner wall in contact with the pressurized atmosphere, the means being arranged so as to cool only part of the 'pregnant.
  • the cooling means allow to cool between half and 3 ⁇ 4 of the enclosure.
  • the mixer is formed of a tube comprising at least one blade-type mixing element integral with its periphery, the injection means being arranged on this element.
  • the tube is connected to a superheated steam generator, the steam produced by the generator circulating in the tube to reach the mixing element and then be injected by the injection means.
  • the injection means are formed by openings formed on the mixing element.
  • all the openings of the enclosure are closable with closure means ensuring the conditions of tightness to pressure and microwaves.
  • the enclosure comprises cooling means for cooling a portion of its inner surface to promote the condensation of water evaporated by the drying treatment.
  • the device comprises at least one end closable by an automatic door ensuring the conditions of tightness to pressure and microwaves.
  • the microwave generator communicates with the drying chamber through a coupler / microwave adapter.
  • the enclosure comprises a safety valve.
  • the tank is removed from the walls of the enclosure by perforated supports to allow the streaming of the condensed water
  • the device consists of an enclosure (1), preferably cylindrical and elongated metal material with a double wall ensuring on the one hand, both good thermal insulation and pressure tightness of the steam and on the other hand, airtightness.
  • This enclosure (1) has at least one end open on the outside and closable by a door (10) or a cover (10).
  • the enclosure (1) has a closable end.
  • the door (10) for closing the openings is made so that the enclosure (1) is completely airtight, at the vapor pressure and waves such as microwaves, when the door (10) is closed again.
  • the door (10) therefore comprises a seal (102) made of "Teflon” or silicone for pressure-tightness and metal (101) for microwave-tightness.
  • a seal (102) made of "Teflon” or silicone for pressure-tightness and metal (101) for microwave-tightness.
  • the door (10) is slidable by means of a displacement system (152) having wheels (151) connected to the door. This system thus allows the door to be moved axially relative to the enclosure (1). In this embodiment the sludge is loaded by the opening formed when the door is open.
  • the enclosure (1) is generally placed on the ground, and is held in place by feet (15), the portion resting on the ground forming the lower part of the enclosure (1).
  • the enclosure (1) has inside, an additional wall in its lower part forming a spherical tank (7) in which will be loaded the sludge (5) to be dried.
  • This tank (7) has upper flanges (71) fixed to the enclosure (1) and on which small openings are formed. These openings allow evacuation to the bottom of the chamber (1) condensed water on the inner wall of the enclosure (1).
  • the material (5) to be dried is loaded into the enclosure (1) by a material inlet (8).
  • This inlet (8) is disposed on a face of the enclosure (1) at mid-height thereof.
  • the loading of the material (5) to be dried is through the tank which is disposed on a carriage (152) rolling (151) can be moved laterally, unloading is done by turning the vessel.
  • the sludge (5) concerned by the invention are sludge type sludge, slurry, waste septic tanks ... etc.
  • the enclosure (1) also comprises at least one rounded or rectangular aperture (2) constituting a window (2).
  • the enclosure (1) comprises a plurality of windows (2). These windows (2) are made of vapor-tight material but passing microwave radiation. In one embodiment, the windows (2) are made of quartz. In another embodiment the windows (2) are "Teflon", or any other material allowing electromagnetic radiation and vapor tightness. These windows (2) under pressure can emit the waves (23) to the inside of the enclosure (1) and are said windows (2) emitter. They thus allow to pass the waves (23) which will then irradiate the sludge (5) to dry. The waves (23) are brought by a waveguide (24) to at least one window (2).
  • the waveguide (24) communicates through an impedance coupler / adapter (21) and the microwave generator (22).
  • the wave generator (22) (23) thus makes it possible to irradiate the sludge (5) to be dried.
  • the windows (2) are arranged in the upper part of the enclosure (1) that is to say the part opposite to that which rests on the ground.
  • the enclosure (1) is vertical, in this case it is higher than wide.
  • the enclosure (1) has an opening at the end opposite to that resting on the ground.
  • the windows (2) are then arranged on the upper part below the opening and therefore below the lid (10).
  • the waves are, at the exit of the windows, perpendicular to the bottom of the tank and are then redirected to arrive vertically in the material (5) to dry.
  • the windows (2) are arranged on the cover (10) and thus allow a direct radiation which arrives vertically in the material (5) to be dried.
  • the tank is arranged horizontally, it is then wider than it is high.
  • the opening which is always at one end will be disposed on the opposite side to the power supply.
  • the windows (2) are then always arranged in the upper part of the enclosure (1) that is to say in the opposite part to that resting on the ground.
  • the windows (2) are rectangular, they are arranged so as to be inverted relative to one another, ie a window is arranged in the direction of the length and the one next to the direction of the height etc. as illustrated on the figure 2 .
  • the enclosure (1) is in communication with at least two pipes with at least two steam generator systems.
  • a first generator (9) generates saturating steam. This steam is injected into the entire enclosure (1) before loading the material (5) to be dried.
  • a second generator (32) generates superheated steam. This superheated steam is directly injected into the material (5) to be dried.
  • This mixer (3) is formed of a tube (31, 31 ') which passes through the enclosure (1).
  • This tube (31, 31 ') is connected to the superheated steam generator (32).
  • the tube (31, 31 ') comprises at minus one element (35, 35 ') mixer.
  • This element (35, 35 ') mixer has means (33, 33') for injecting superheated steam.
  • the injection means (33, 33 ') are formed by openings (33, 33') formed on the mixing element (35, 35 ').
  • the steam produced by the generator (32) flows in the tube to reach the mixing element (35, 35 ') and is then injected by the injection means (33, 33') into the core of the material ( 5) to dry.
  • the mixing element (35) is formed by blades fixed to the end of the tube (31) arriving at the bottom of the enclosure (1).
  • the mixer rotates thanks to a motor (34) disposed outside the enclosure (1).
  • the blades follow the spherical or elliptical shape of the bottom of the tank (7).
  • the tube is offset relative to the axis (A) of symmetry of the tank, that is to say close to the wall remote from the microwave source.
  • the mixing element (35 ') is formed by rectangular blades fixed on the periphery of the tube (31') preferably in a helical geometry and offset from each other.
  • the tube rotates with a motor (34) and behaves like a worm.
  • the material used for the blades is a microwave resistant material.
  • the material may for example be pyrex or "Teflon".
  • the blades are fixed so as not to exceed the material (5) to dry before drying and the amount of material (5) is adapted so that at the end of drying the blades do not exceed too much to avoid problems due to shocks with microwaves.
  • the role of the mixers is on the one hand to mix the sludge (5) to have a homogeneous drying and on the other hand to increase the penetration of microwaves in the sludge (5) and promote drying. Indeed without mixing the mud, a dry crust forms quickly on its surface which prevents the microwaves to penetrate properly, and thus prevents an effective drying and homogeneous.
  • the condensation water is discharged through a pipe (4) controlled by a valve (41) for evacuation and disposed in the lower part of the enclosure.
  • This evacuation valve (41) makes it possible to maintain the enclosure (1) at the desired pressure, to evacuate the pressure if it is too high and finally to put the enclosure (1) in the atmosphere a once the drying process is complete.
  • the upper part of the enclosure (1) comprises a safety valve (12) which is regulated according to the desired pressure and which will be used only in the event of an incident requiring pressure regulation other than with the valve (41). ) evacuation.
  • This valve (12) will therefore, in normal operation of the device, never used.
  • the enclosure (1) also comprises cooling means (203) in its double wall. These cooling means (203) are arranged to allow the cooling of the base portion of the chamber (1) and thus the condensation of the evaporation water.
  • the cooling means (203) are for example coils in which circulates a cooling gas.
  • These cooling means (203) define a cold zone (200) and a hot zone (300) in the enclosure.
  • the separation (202) between the two zones being approximately between half and 3 ⁇ 4 of the lower part of the enclosure.
  • the enclosure (1) has in its lower part a hatch (6) which allows to evacuate the dried material when the drying cycle is completed.
  • this hatch (6) also comprises a guide which will allow the mixer (3) to be kept straight and thus prevent its swaying during mixing.
  • the enclosure (1) comprises means (11) for measuring the temperature and the pressure in order to regulate these parameters during drying.
  • the set of openings of the enclosure (1) comprises a valve system (91, 81, 61, 41) allowing the enclosure (1) to remain hermetic and also avoiding the leakage of microwaves.
  • the enclosure (1) comprises a level detector device for the automatic opening of the valve (41).
  • the microwave generator After a while when the sludge is dried, the microwave generator is also stopped and the pressure decreased to gradually reach atmospheric pressure.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Microbiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biotechnology (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Drying Of Solid Materials (AREA)
  • Treatment Of Sludge (AREA)

Claims (22)

  1. Verfahren zum Trocknen von Schlamm (5), zum Beispiel von Klärschlamm, Jauche oder Abfall aus Klärgruben mittels Bestrahlung durch Mikrowellen, wobei das Verfahren zum Trocknen von Schlamm aufweist:
    - einen Schritt des Setzens eines dichten Behälters (1) unter einen bestimmten Druck und des Aufrechterhaltens des Drucks während einer vorbestimmten Zeit,
    - einen Schritt des Aufheizens des Schlamms (5) bis zum Kern durch das Aussenden von Mikrowellen (23), wobei das Verfahren zum Trocknen von Schlamm dadurch gekennzeichnet ist, dass der Schritt des Setzens des dichten Behälters (1) unter einen bestimmten Druck mindestens durch das Einspritzen von Sättigungswasserdampf erfolgt, wobei der Schritt des Unterdrucksetzens gefolgt wird von:
    - einem Schritt des Ladens des Schlamms in das Innere eines von den Wänden des Behälters (1) entfernten Tanks (7) mit Lademitteln, die das Aufrechterhalten des Drucks gewährleisten,
    - einem Schritt des Einspritzens von überhitztem Dampf in den Schlamm (5) mittels eines Mischers (3), der nahe der Wand des Behälters im Einsatz ist, die am Weitesten von der Quelle (22) der Mikrowellen entfernt ist, der Injektionsmittel (33) aufweist,
    - dem Schritt des Aufheizens des Schlamms (5) bis zum Kern durch das Aussenden von Mikrowellen (23) mit Frequenzen zwischen 400 und 2450 MHz in Richtung des Tanks, wobei der Schritt erfolgt, während der Schlamm (5) durchmischt wird,
    - einem Schritt des Ableitens des Wassers, das sich an den Wänden des Behälters durch Kondensation und Herunterlaufen in Richtung zu dem Boden des Behälters (1) angesammelt hat, mittels eines Ventils (41), das mit dem Äußeren kommuniziert.
  2. Trocknungsverfahren gemäß Anspruch 1, dadurch gekennzeichnet, dass der Schlamm (5) während der gesamten Trocknungsdauer mit dem Mischer (3) durchmischt wird, um eine bessere Trocknungshomogenität zu ermöglichen, wobei das Eindringen der Mikrowellen in das Material deutlich begünstigt wird.
  3. Trocknungsverfahren gemäß einem der Ansprüche 1 bis 2, dadurch gekennzeichnet, dass der Sättigungswasserdampfdruck in einem Bereich zwischen 1 bar und 3 bar liegt.
  4. Trocknungsverfahren gemäß einem der Ansprüche 1 bis 2, dadurch gekennzeichnet, dass der Sättigungswasserdampfdruck 1 bar beträgt.
  5. Trocknungsverfahren gemäß einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass der Druck des überhitzten Dampfes zwischen 1 bar und 5 bar liegt.
  6. Trocknungsverfahren gemäß Anspruch 5, dadurch gekennzeichnet, dass der Druck des überhitzten Dampfes 3 bar beträgt.
  7. Trocknungsverfahren gemäß einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass die Temperatur des Behälters geringer als die Temperatur des Schlamms (5) sein muss, um ein Verdampfen zu ermöglichen.
  8. Trocknungsverfahren gemäß einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass das Bestrahlen mit Mikrowellen erfolgt, wenn die Temperatur des Schlamms (5) zwischen 110°C und 140°C beträgt.
  9. Trocknungsverfahren gemäß einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass das Bestrahlen mit Mikrowellen erfolgt, wenn die Temperatur des Schlamms (5) 130°C beträgt.
  10. Vorrichtung, die das Durchführen des Verfahrens gemäß einem der Ansprüche 1 bis 9 ermöglicht, die aus einem dichten Behälter (1) gebildet ist, der druckbeständig ist und über mindestens ein Fenster (2) aus Quarz oder jedem anderen mikrowellentauglichen Material mit mindestens einem Mikrowellengenerator (22) kommuniziert, wobei der Behälter einen Mischer (3) und eine Klappe (6) zum Entladen des getrockneten Schlamms aufweist, dadurch gekennzeichnet, dass der Behälter einen Tank (7) aufweist, der von den Wänden des Behälters entfernt ist, wobei der Behälter (1) mit einem Sättigungsdampfgenerator (32) und einer Zuleitung (8) von zu trocknendem Schlamm (5) kommuniziert, wobei der Mischer (3) Mittel (33) zum Einspritzen von überhitztem Dampf aufweist, die in dem Tank angeordnet sind.
  11. Vorrichtung gemäß Anspruch 10, dadurch gekennzeichnet, dass sie in ihrem in Richtung zu dem Boden ausgerichteten tiefsten Teil eine Öffnung (4) aufweist, die das Ableiten von herunterlaufendem Wasser mittels Schwerkraft, gesteuert durch ein Ablaufventil (41), oder das Regulieren des Innendrucks des Behälters ermöglicht.
  12. Vorrichtung gemäß einem der Ansprüche 10 bis 11, dadurch gekennzeichnet, dass der Behälter (1) Kühlmittel (203) aufweist, die in seinem tiefsten Teil angeordnet sind, um seine Innenwand in Kontakt mit der Druckatmosphäre zu kühlen, wobei die Mittel derart angeordnet sind, dass nur ein Teil des Behälters gekühlt wird.
  13. Vorrichtung gemäß Anspruch 12, dadurch gekennzeichnet, dass die Kühlmittel (203) ein Kühlen zwischen der Hälfte und einem Dreiviertel des Behälters ermöglichen.
  14. Vorrichtung gemäß einem der Ansprüche 10 bis 13, dadurch gekennzeichnet, dass der Mischer (3) aus einem Rohr (31) gebildet ist, das mindestens ein Mischelement (35) des Schaufeltyps aufweist, das mit seinem Umfang einstückig ist, wobei die Einspritzmittel (33) an diesem Element angeordnet sind.
  15. Vorrichtung gemäß Anspruch 14, dadurch gekennzeichnet, dass das Rohr (31) mit einem Generator (32) von überhitztem Dampf verbunden ist, wobei der von dem Generator erzeugte Dampf in dem Rohr (31) zirkuliert, um bis zu dem Mischelement (35) zu gelangen und anschließend von den Einspritzmitteln (33) eingespritzt zu werden.
  16. Vorrichtung gemäß Anspruch 14 oder 15, dadurch gekennzeichnet, dass die Einspritzmittel (33) durch an dem Mischelement (35) ausgebildete Öffnungen ausgebildet sind.
  17. Vorrichtung gemäß einem der Ansprüche 10 bis 16, dadurch gekennzeichnet, dass alle Öffnungen des Behälters (1) mit Verschlussmitteln verschließbar sind, die die Bedingungen der Dichtigkeit gegenüber dem Druck und den Mikrowellen sicherstellen.
  18. Vorrichtung gemäß einem der Ansprüche 10 bis 17, dadurch gekennzeichnet, dass der Behälter (1) Kühlmittel (203) aufweist, die es ermöglichen, einen Teil seiner Innenfläche zu kühlen, um das Kondensieren des durch den Trocknungsvorgang verdampften Wassers zu begünstigen.
  19. Vorrichtung gemäß einem der Ansprüche 10 bis 18, dadurch gekennzeichnet, dass sie mindestens ein durch eine automatische Tür (10) verschließbares Ende aufweist, die die Bedingungen der Dichtigkeit gegenüber dem Druck und den Mikrowellen sicherstellt.
  20. Vorrichtung gemäß einem der Ansprüche 10 bis 19, dadurch gekennzeichnet, dass der Mikrowellengenerator (22) mit dem Trocknungsbehälter (1) über einen Mikrowellen-Koppler /-Adapter (21) kommuniziert.
  21. Vorrichtung gemäß den Ansprüchen 10 bis 20, dadurch gekennzeichnet, dass der Behälter (1) ein Sicherheitsventil (12) aufweist.
  22. Vorrichtung gemäß den Ansprüchen 10 bis 21, dadurch gekennzeichnet, dass der Tank mittels perforierten Stützen von den Wänden des Behälters entfernt ist, um das Herunterlaufen des kondensierten Wassers zu ermöglichen.
EP07290491A 2006-04-21 2007-04-20 Verfahren zur trocknung von schlämmen und vorrichtung zur durchführung dieses verfahrens Active EP1847791B1 (de)

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FR0603551A FR2900224B1 (fr) 2006-04-21 2006-04-21 Procede de sechage des boues et dispositif permettant la mise en oeuvre du procede

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EP1847791B1 true EP1847791B1 (de) 2011-09-07

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US (1) US20090229140A1 (de)
EP (1) EP1847791B1 (de)
JP (1) JP4875146B2 (de)
KR (1) KR101394623B1 (de)
CN (1) CN101454630B (de)
AT (1) ATE523746T1 (de)
AU (1) AU2007242682B2 (de)
CA (1) CA2650025C (de)
DK (1) DK1847791T3 (de)
ES (1) ES2372313T3 (de)
FR (1) FR2900224B1 (de)
MA (1) MA30417B1 (de)
MX (1) MX2008013504A (de)
NO (1) NO20084754L (de)
NZ (1) NZ572340A (de)
PL (1) PL1847791T3 (de)
PT (1) PT1847791E (de)
RU (1) RU2419049C2 (de)
UA (1) UA94747C2 (de)
WO (1) WO2007122328A1 (de)
ZA (1) ZA200809360B (de)

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SE527166C2 (sv) * 2003-08-21 2006-01-10 Kerttu Eriksson Förfarande och anordning för avfuktning
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UA94747C2 (ru) 2011-06-10
CN101454630B (zh) 2012-12-26
JP2009534623A (ja) 2009-09-24
MA30417B1 (fr) 2009-05-04
RU2008142146A (ru) 2010-05-27
FR2900224A1 (fr) 2007-10-26
FR2900224B1 (fr) 2008-07-04
ES2372313T3 (es) 2012-01-18
AU2007242682B2 (en) 2011-12-22
MX2008013504A (es) 2009-02-23
ZA200809360B (en) 2009-07-29
KR101394623B1 (ko) 2014-05-13
ATE523746T1 (de) 2011-09-15
CA2650025A1 (en) 2007-11-01
JP4875146B2 (ja) 2012-02-15
US20090229140A1 (en) 2009-09-17
KR20090007458A (ko) 2009-01-16
NO20084754L (no) 2008-12-12
CA2650025C (en) 2015-06-23
WO2007122328A1 (fr) 2007-11-01
AU2007242682A1 (en) 2007-11-01
WO2007122328A8 (fr) 2008-12-18
PT1847791E (pt) 2011-11-28
CN101454630A (zh) 2009-06-10
EP1847791A1 (de) 2007-10-24
PL1847791T3 (pl) 2012-03-30
DK1847791T3 (da) 2012-01-09
RU2419049C2 (ru) 2011-05-20

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