EP1841913A2 - Pellicule d'etancheite destinee a la protection de batiment - Google Patents

Pellicule d'etancheite destinee a la protection de batiment

Info

Publication number
EP1841913A2
EP1841913A2 EP05850219A EP05850219A EP1841913A2 EP 1841913 A2 EP1841913 A2 EP 1841913A2 EP 05850219 A EP05850219 A EP 05850219A EP 05850219 A EP05850219 A EP 05850219A EP 1841913 A2 EP1841913 A2 EP 1841913A2
Authority
EP
European Patent Office
Prior art keywords
coating
sealing film
film according
flame retardant
fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP05850219A
Other languages
German (de)
English (en)
Other versions
EP1841913B1 (fr
Inventor
Werner Welter
Karl Köhler
Udo Simonis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP1841913A2 publication Critical patent/EP1841913A2/fr
Application granted granted Critical
Publication of EP1841913B1 publication Critical patent/EP1841913B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D12/00Non-structural supports for roofing materials, e.g. battens, boards
    • E04D12/002Sheets of flexible material, e.g. roofing tile underlay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • D06N3/065PVC together with other resins except polyurethanes
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/66Sealings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers

Definitions

  • the invention relates to a waterproofing membrane for building protection, which is waterproof and has a high tensile strength and flexibility.
  • a sealing film for building protection which is used as a facade film (DE 200 23 324 U1), but is also used in the roof area, has a water and airtight thermoplastic or a composite material of plastic and aluminum foil as a central layer. Applied on both sides can be plastered outer layers of fleece, fabric, knitted fabrics, etc. These are also the substrates (substrates) that determine the tear strength and the desired elongation properties.
  • a facade foil requires a particularly high tear resistance and flexibility, because it often has to be laid with tight radii of curvature. For this purpose, it preferably has a thickness of less than 1 mm.
  • the basis weight of the base layer (s) is between 20 g / m 2 and 300 g / m 2
  • the basis weight of the plastic coating is 20 g / m 2 to 250 g / m 2 , preferably about 80 g / m 2 up to 130 g / m 2 .
  • the total basis weight is preferably about 300 g / m 2 . If it can be plastered over, as described in DE 200 20 324 U1, it must also be able to carry the cleaning weight and be able to hold the plaster adhering. Moreover, a sealing film must be able to be glued as a facade film on the masonry and / or on Novaleibache.
  • sealing foils for building protection in particular for use as a facade foil, there are currently only products of building material class B2 "normally flammable". Increasing the proportion of chemical flame retardants in such sealing films, the sealing film loses some of its flexibility, it is stiffer, the coating is more brittle. For thin, very flexible films you need additional plasticizers. These affect the flame retardancy.
  • Another known sealing film for building protection which is waterproof and has a high tensile strength and flexibility (DE 196 09 311 A1), expressly takes into account aspects of fire protection. It meets the building material class B2 of DIN 4102 with a woven, knitted or non-woven textile support material as a support layer and a one-sided or double-sided applied coating, which is used as an aqueous dispersion with a viscosity of up to
  • aqueous dispersion contains up to 30% by weight of a flame retardant.
  • Basis of this dispersion is a suitably adjusted polyurethane with up to 60 wt .-%.
  • Suitable chemical flame retardants are given in DE 196 09 311 A1. All other components are described in detail and with examples. Polyethylene, polypropylene, polyester and glass fibers are specified for the carrier material forming the base layer, which are particularly preferably processed into nonwovens having a weight per unit area of 50 to 300 g / m 2 .
  • the disclosure of DE 196 09 311 A1 may be referred to in total, the is incorporated by reference into the disclosure of the present patent application.
  • sealing film for building protection is not taken into account the specifics that are important for facade films. In particular, these are over plasterability of the sealing film and bondability to masonry and window reveals.
  • the invention is now based on the problem of specifying a sealing film which achieves the highest possible fire resistance class, in particular the building material class B1 "flame retardant" or reaches an even higher level of fire protection and nonetheless can also be used as a facade film.
  • the coating which has been applied as an aqueous dispersion to the base layer and dried thereon also forms the outer surface of the sealing film in the case of the sealing film according to the invention.
  • the coating used in the sealing film according to the invention has a considerable amount of non-combustible, solid inorganic fillers, in particular non-combustible inorganic Fibers on.
  • glass fibers It is a highly elastic, very flexible coating, which does not tear even in a larger layer thickness and the sealing film affects only slightly in their flexibility.
  • the non-combustible, solid inorganic fillers results in a significantly increased fire resistance, so that a high fire resistance class of z. B. F 60 to F 90 is achieved.
  • building material class B1 "hardly inflammable" is easily achieved for the sealing film. Possibly. even an overlying building material class of fire protection is achieved.
  • the fire resistance class which is achieved according to the invention is determined according to DIN 4102-2 also to the effect that a fire transmission over the building material for the predetermined time is prevented. In this regard, a slight foaming of the coating material under the action of heat can be helpful.
  • the non-combustible solid inorganic fillers provide a comparatively rough surface of the coating.
  • This makes it possible for this sealing foil to be plastered over like a classic facade foil and also adhesively bonded to the masonry and / or to window revealings. Plaster and adhesive find sufficient support on the rough surface.
  • plaster in the sense of the present patent application can be understood hydraulically setting mortar systems based on cement and / or lime cement, but also gypsum or anhydrite, etc., as they are common in interior and exterior plasters, Ansetzbindern.
  • the carrier material forming the base layer is either a material which is permeable to water vapor, in particular a nonwoven fabric, a woven fabric, a knitted fabric or a scrim, in particular made of synthetic fibers or glass fibers, or a material which is diffusion-tight or diffusion-inhibiting for water vapor, in particular a plastic film or a metal foil is.
  • a metal foil for example an aluminum foil, itself already corresponds to the building material class A.
  • the other materials are influenced by a conventional chemical flame retardant, which does not unduly impair their flexibility, in the direction of independent flame retardancy, so that overall the sealing film including these special support layers a high Building material class of fire protection according to DIN 4102-1 achieved.
  • this sealing film for building protection which is also determined and suitable as a facade film, results in the desired flexibility and manageability under site conditions with a structure that is similar to the structure of the sealing film of the starting point for teaching (DE 200 23 324 U1).
  • the base layer is arranged on the outside. So it brings home already the necessary over plasterability and adhesion for plaster and adhesives, which is already given at the starting point for the teaching of the present invention.
  • the building material class B1 "flame retardant" or even an even higher building material class of fire protection is achieved in that a certain composition of the occurring here as a separate film coating is selected.
  • This composition is specified in claim 9.
  • the base layer forming nonwoven fabric, woven, knitted or scrim on the basis of glass fibers and / or acrylic fibers itself is already equipped fire-retardant.
  • the outer nonwoven fabric, woven, knitted fabric or scrim even if it is formed from glass fibers and / or acrylic fibers, forms heat esters on the surface of the PVC-based film-like coating.
  • the nonwoven, woven fabric, knitted fabric or scrim if it is itself partially flamed, acts as a fire accelerator for the film-like coating based on PVC.
  • This function takes according to the invention the fleece, fabric, knitted fabric or scrim by the there already carried out by home equipment with a flame retardant, so that this fleece, fabric, knitted fabric or scrims already meets the building material class B1 "flame retardant".
  • the proportion of plasticizer based on polyaddipate is reduced and instead a chlorinated polyethylene is added.
  • This polyethylene is modified so that it also has a fire retardant effect in addition to the plasticizing effect for the PVC.
  • the flame retardant claim 11 gives a number of references. For the rest, reference is also made to DE 196 09 311 A1.
  • FIG. 2 in a section, highly schematized, the dimensions of the sake of clarity not shown to scale, an embodiment of a sealing film for building protection according to the second variant of the invention.
  • Fig. 1 shows a waterproofing membrane for building protection, which is waterproof and has a high tensile strength and flexibility. Shown is a base layer 1 of a tear-resistant and flexible carrier material. This support layer 1 is provided in the illustrated embodiment from both sides with a coating 2. This has at least one chemical flame retardant and has been applied to the base layer 1 as an aqueous dispersion and then dried to the state shown in Fig. 1. Fig. 1 indicates that the coating 2 comprises a considerable amount of non-combustible, solid inorganic fillers, in particular non-combustible inorganic fibers. In the illustrated and preferred embodiment, it is provided that the support layer 1 forming carrier material is equipped as such non-combustible or flame retardant.
  • the support material forming the base layer 1 is a material which is permeable to water vapor, namely a fleece, in particular of glass fibers.
  • this carrier material many variants of this carrier material are described in DE 196 09 311 A and DE 200 23 324 U1, which may again be explicitly referred to here as disclosure source. This is the preferred material for cladding films.
  • a water vapor diffusion-proof or diffusion-inhibiting material in particular in the form of a plastic film or a metal foil, for example an aluminum foil, or else a composite foil is also suitable.
  • the coating 2 in the coatable, wet state has a content of solid inorganic fillers of about 60% to about 80%. Depending on the application, however, it will be possible to vary the content of solid inorganic fillers within further limits, for example from about 30% to about 80%.
  • inorganic fibers namely glass fibers are provided as fillers, in addition to other solid fillers in powder form and also inorganic, non-combustible pigments.
  • the high proportion of solid inorganic fillers ensures a high elasticity despite comparatively large thickness of the coating and thus in the result also an excellent fire protection effect of the coating 2.
  • the surface of the coating 2 is not rough enough to allow a particular over-brushing application.
  • a support made of a non-flammable or flame-retardant non-woven fabric, woven, knitted or scrim especially from appropriately equipped synthetic fibers or glass fibers provided.
  • such a material which in turn is intimately bonded to the coating on the outside, creates the necessary adhesion for plaster and adhesives.
  • the associated additional effort is expediently driven only if the intended application requires this.
  • the content and type of the solid inorganic fillers are in a certain relationship to the surface shape of the coating 2 and thus also to the possibly given need to use an additional layer outside.
  • the coating 2 has a thickness between about 0.2 mm and about 1, 5 mm after drying. With these dimensions, the thickness of the coating 2 on one side of the support layer 1 is meant. Thus, as shown, double-sided coating is between about 0.4 mm and about 3.0 mm for the total thickness of the sealing film.
  • a sealing film is used as a coating for over 20 years for the fire protection of cable bundles commercially available product that is sold today by the company Cognis Germany GmbH & Co. KG (www.cognis.com) under the name KBS Coating , It is a dispersion-bound paint containing inorganic, non-combustible fillers, in particular non-combustible fibers, as well as in the viscous portion of the paint a number of flame retardant additives.
  • the viscosity of the material for processing is about 40,000 mPas, the density is about 1, 43 g / m 2 , the solids content is about 70%.
  • the consistency of the commercial product will of course be suitable for use in sealing films according to the invention.
  • FIG. 2 shows a sealing film for building protection according to the second variant of the invention.
  • the carrier material is in each case a nonwoven that is permeable to water vapor, woven, knitted or laid on the basis of glass fibers and / or acrylic fibers. If only one base layer 1 is provided, then there is inextricably linked on one side a film-like coating 2, are two base layers 1 provided, then this film-like coating 2 is located between the two base layers 1, inseparably connected to both.
  • the support material forming the respective support layer 1 is first of all already fire-retardant.
  • a nonwoven fabric, fabric, knitted fabric or Geleges based on glass fibers and / or acrylic fibers to achieve the flame resistance of the building material class B1, it can be provided that an impregnation with boron salts or, better still, an admixture of carbon fibers.
  • the film-like coating 2 which in the present case will be a self-extruded film, has the following constituents:
  • sealing film described here can also provide that the proportion of polyaddipate can be partially or completely replaced by chlorinated PE (PE-C).
  • PE-C chlorinated PE
  • Suitable flame retardants are, for example, an antimony trioxide and / or an aluminum hydroxide and / or a magnesium hydroxide and / or brominated phenols. Incidentally, it can also be pointed to the DE 196 09 311 A1, where a variety of possible flame retardants are given.
  • the sealing film according to the invention is constructed as the sealing film, which forms the starting point for the teaching of the present invention (DE 200 23 324 U1), namely with corresponding support layers 1 on both sides of the film-like coating. 2
  • the support layer 1 and the support layers 1 in the ongoing production process as long as the plastic of the film-like coating 2 is still plastic, ie at temperatures between 130 and 200 0 C, inseparably connected to the film-like coating 2.
  • the surface roughness provided by the nonwoven, woven fabric, knitted fabric or fabric on the outside of the sealing film offers the well-known good basis for overpainting and sticking to masonry and window reveals.
  • the building material class B1 of DIN 4102 "flame retardant” or even an even higher class can be achieved with this variant.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Architecture (AREA)
  • Textile Engineering (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Electromagnetism (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Building Environments (AREA)
EP05850219A 2005-01-24 2005-12-01 Pellicule d'etancheite destinee a la protection de batiment Not-in-force EP1841913B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005003295A DE102005003295A1 (de) 2005-01-24 2005-01-24 Abdichtfolie für den Bautenschutz
PCT/EP2005/012809 WO2006079383A2 (fr) 2005-01-24 2005-12-01 Pellicule d'etancheite destinee a la protection de batiment

Publications (2)

Publication Number Publication Date
EP1841913A2 true EP1841913A2 (fr) 2007-10-10
EP1841913B1 EP1841913B1 (fr) 2011-01-26

Family

ID=36263841

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05850219A Not-in-force EP1841913B1 (fr) 2005-01-24 2005-12-01 Pellicule d'etancheite destinee a la protection de batiment

Country Status (4)

Country Link
EP (1) EP1841913B1 (fr)
AT (1) ATE497053T1 (fr)
DE (2) DE102005003295A1 (fr)
WO (1) WO2006079383A2 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202007018399U1 (de) 2007-04-18 2008-06-26 Tesa Ag Folie zum Eindecken eines Untergrunds, insbesondere als Bautenschutz
DE102013005221A1 (de) 2013-03-27 2014-10-02 L'isolante K-Flex S.R.L. Thermoplastische Folie
DE102013104818A1 (de) * 2013-05-10 2014-11-27 Max Frank Gmbh & Co Kg Abdichtelement für Baukörper
DE102014101234A1 (de) * 2014-01-31 2015-08-06 Johann Borgers GmbH Schwerentflammbares und selbsterlöschendes Faserbauteil
EP4067425A1 (fr) * 2021-03-31 2022-10-05 Henkel AG & Co. KGaA Feuille d'étanchéité difficilement inflammable

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2228917B3 (fr) * 1973-05-07 1975-10-31 Gruenau Gmbh Chem Fab
DE3111899C2 (de) * 1981-03-26 1984-01-26 Marburger Tapetenfabrik J.B. Schaefer Gmbh & Co Kg, 3575 Kirchhain Belag für Außenwände von Gebäuden
DE3200824C2 (de) * 1982-01-14 1984-03-01 Hoechst Ag, 6230 Frankfurt Schwer brennbares beschichtetes textiles Flächengebilde
DE3625080C2 (de) * 1986-07-24 2001-10-11 Dsm Fine Chem Austria Gmbh Thermisch expandierbare Masse, Verfahren zu ihrer Herstellung und Verwendung
AT392078B (de) * 1988-04-07 1991-01-25 Chemie Linz Gmbh Latexgebundene brandschutzmasse
DE4124560A1 (de) * 1991-07-24 1993-01-28 Wacker Chemie Gmbh Beschichtungsmittel zur herstellung von wasserdichten, dampfdurchlaessigen und flammverzoegernden beschichtungen
DE4142903A1 (de) * 1991-12-24 1993-07-01 Gruenau Gmbh Chem Fab Brandschutzmasse und ihre verwendung
DE19609311A1 (de) * 1996-03-09 1997-09-11 Basf Ag Für die Herstellung von beschichteten Textilien geeignete wässerige Dispersionen
DE19702076A1 (de) * 1997-01-22 1998-07-23 Hoechst Trevira Gmbh & Co Kg Beschichtungsmittel zur Herstellung von wasserdichten, dampfdurchlässigen und flammverzögernden Beschichtungen
JP3054866B1 (ja) * 1998-12-14 2000-06-19 キョーワ株式会社 建設工事現場に展張するメッシュシート用難燃剤とこれを用いた建設工事現場に展張する防炎メッシュシート
DE20023324U1 (de) * 1999-11-09 2003-09-11 Henkel Kgaa Folienbahn, Fensterrahmen mit einer solchen Bahn
JP3682601B2 (ja) * 2001-01-15 2005-08-10 平岡織染株式会社 防炎性及び融着接合部の耐熱クリープ性に優れた防水複合膜材料融着接合体
US8017531B2 (en) * 2001-09-18 2011-09-13 Elkcorp Composite material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2006079383A3 *

Also Published As

Publication number Publication date
EP1841913B1 (fr) 2011-01-26
DE502005010925D1 (de) 2011-03-10
ATE497053T1 (de) 2011-02-15
WO2006079383A2 (fr) 2006-08-03
WO2006079383A3 (fr) 2006-11-16
DE102005003295A1 (de) 2006-07-27

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