EP1840196A1 - Lubricant composition - Google Patents

Lubricant composition Download PDF

Info

Publication number
EP1840196A1
EP1840196A1 EP06006957A EP06006957A EP1840196A1 EP 1840196 A1 EP1840196 A1 EP 1840196A1 EP 06006957 A EP06006957 A EP 06006957A EP 06006957 A EP06006957 A EP 06006957A EP 1840196 A1 EP1840196 A1 EP 1840196A1
Authority
EP
European Patent Office
Prior art keywords
alkyl
composition according
aqueous lubricant
lubricant composition
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06006957A
Other languages
German (de)
English (en)
French (fr)
Inventor
Melanie Vierbaum
Ben De Rijk
Hamke Meijer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Chemicals GmbH
Original Assignee
Chemische Fabrik CHEM Y GmbH
Kao Chemicals GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Fabrik CHEM Y GmbH, Kao Chemicals GmbH filed Critical Chemische Fabrik CHEM Y GmbH
Priority to EP06006957A priority Critical patent/EP1840196A1/en
Priority to US12/225,234 priority patent/US20100286009A1/en
Priority to AU2007234025A priority patent/AU2007234025B2/en
Priority to BRPI0708839-6A priority patent/BRPI0708839A2/pt
Priority to CA002645226A priority patent/CA2645226A1/en
Priority to PCT/EP2007/002772 priority patent/WO2007112917A2/en
Priority to JP2009501948A priority patent/JP5465004B2/ja
Priority to RU2008143209/04A priority patent/RU2437922C2/ru
Priority to EP07723716A priority patent/EP2024472A2/en
Publication of EP1840196A1 publication Critical patent/EP1840196A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C10M173/025Lubricating compositions containing more than 10% water not containing mineral or fatty oils for lubricating conveyor belts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/124Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms containing hydroxy groups; Ethers thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/128Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/042Metal salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/043Ammonium or amine salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/38Conveyors or chain belts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Detergent Compositions (AREA)
EP06006957A 2006-03-31 2006-03-31 Lubricant composition Withdrawn EP1840196A1 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
EP06006957A EP1840196A1 (en) 2006-03-31 2006-03-31 Lubricant composition
US12/225,234 US20100286009A1 (en) 2006-03-31 2007-03-28 Lubricant Composition
AU2007234025A AU2007234025B2 (en) 2006-03-31 2007-03-28 Lubricant composition
BRPI0708839-6A BRPI0708839A2 (pt) 2006-03-31 2007-03-28 composição lubrificante, processo para lubrificar sistemas transportadores e utilização de uma composição lubrificante.
CA002645226A CA2645226A1 (en) 2006-03-31 2007-03-28 An aqueous conveyor lubricant composition for use in the foodstuff industry
PCT/EP2007/002772 WO2007112917A2 (en) 2006-03-31 2007-03-28 Lubricant composition
JP2009501948A JP5465004B2 (ja) 2006-03-31 2007-03-28 潤滑剤組成物
RU2008143209/04A RU2437922C2 (ru) 2006-03-31 2007-03-28 Смазочная композиция
EP07723716A EP2024472A2 (en) 2006-03-31 2007-03-28 Lubricant composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP06006957A EP1840196A1 (en) 2006-03-31 2006-03-31 Lubricant composition

Publications (1)

Publication Number Publication Date
EP1840196A1 true EP1840196A1 (en) 2007-10-03

Family

ID=36873143

Family Applications (2)

Application Number Title Priority Date Filing Date
EP06006957A Withdrawn EP1840196A1 (en) 2006-03-31 2006-03-31 Lubricant composition
EP07723716A Withdrawn EP2024472A2 (en) 2006-03-31 2007-03-28 Lubricant composition

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP07723716A Withdrawn EP2024472A2 (en) 2006-03-31 2007-03-28 Lubricant composition

Country Status (8)

Country Link
US (1) US20100286009A1 (ja)
EP (2) EP1840196A1 (ja)
JP (1) JP5465004B2 (ja)
AU (1) AU2007234025B2 (ja)
BR (1) BRPI0708839A2 (ja)
CA (1) CA2645226A1 (ja)
RU (1) RU2437922C2 (ja)
WO (1) WO2007112917A2 (ja)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2042587A1 (en) * 2007-09-26 2009-04-01 KAO CHEMICALS GmbH Lubrication of conveyor systems
EP2105494A1 (en) 2008-03-25 2009-09-30 Johnson Diversey, Inc. A method of lubricating a conveyor belt
EP2105493A1 (en) 2008-03-25 2009-09-30 Johnson Diversey, Inc. Dry lubrication method employing oil-based lubricants
US9359579B2 (en) 2010-09-24 2016-06-07 Ecolab Usa Inc. Conveyor lubricants including emulsions and methods employing them
US9365798B2 (en) 2005-03-15 2016-06-14 Ecolab Usa Inc. Lubricant for conveying containers
US9562209B2 (en) 2005-03-15 2017-02-07 Ecolab Usa Inc. Dry lubricant for conveying containers
US9873853B2 (en) 2013-03-11 2018-01-23 Ecolab Usa Inc. Lubrication of transfer plates using an oil or oil in water emulsions
CN109705968A (zh) * 2018-12-20 2019-05-03 广东环凯微生物科技有限公司 一种低泡的中性水基链板润滑剂及其制备方法
CN114891553A (zh) * 2022-05-26 2022-08-12 西安建筑科技大学 一种钛合金型材挤压用玻璃润滑的制备方法及玻璃润滑剂

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8716200B2 (en) * 2006-09-13 2014-05-06 Ecolab Usa Inc. Conveyor lubricants including emulsion of a lipophilic compound and an emulsifier and/or an anionic surfactant and methods employing them
EP1932901A1 (en) * 2006-12-12 2008-06-18 JohnsonDiversey, Inc. A method of lubricating a conveyor belt
BR112012002808B1 (pt) 2009-08-07 2019-06-04 Basf Se Composição lubrificante, e, método para reduzir a corrosão de um artigo de aço
US8802606B2 (en) 2010-08-06 2014-08-12 Basf Se Lubricant composition having improved antiwear properties
RU2537294C1 (ru) * 2013-12-24 2014-12-27 Общество с Ограниченной Ответственностью Научно-Производственное Предприятие "Альфа-Сервис" (ООО НПП "Альфа-Сервис") Водорастворимый смазочный состав для обработки конвейерных лент
US9578879B1 (en) 2014-02-07 2017-02-28 Gojo Industries, Inc. Compositions and methods having improved efficacy against spores and other organisms
JP2017505324A (ja) 2014-02-07 2017-02-16 ゴジョ・インダストリーズ・インコーポレイテッド 胞子及び他の生物に対する効力を有する組成物及び方法
US9732301B2 (en) * 2014-11-05 2017-08-15 Infineum International Limited Power transmitting fluids with improved materials compatibility
PT3433344T (pt) * 2016-03-25 2021-05-25 Sopura S A Composição lubrificante aquosa
CN113430039A (zh) * 2021-07-20 2021-09-24 苏州安美润滑科技有限公司 一种抗高硬水切削液及其使用方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4895668A (en) * 1986-02-18 1990-01-23 Diversey Corporation Carboxylated surfactant-containing lubricants, production and use
US5062979A (en) * 1988-09-16 1991-11-05 Ecolab Inc. Soap free conveyor lubricant that gives clear solutions in water comprising alkoxyphosphate ester, alkyl benzene sulfonate and carboxylic acid
WO2000037591A1 (en) * 1998-12-23 2000-06-29 Rhodia Inc. Phosphate ester compositions in a weight ratio greater than 1:1 monoalkyl to dialkyl phosphate used as lubricant additives
WO2004037960A1 (en) * 2002-10-24 2004-05-06 Kao Corporation, S.A. Use of ether carboxylates as lubricants
US20040167044A1 (en) * 2002-11-14 2004-08-26 Ecolab Inc. Conveyor lubricants for use in the food and beverage industries
EP1652909A1 (de) * 2004-10-19 2006-05-03 Helmut Theunissen Korrosionsschutzmittel für funktionelle Flüssigkeiten, wassermischbares Konzentrat und dessen Verwendung

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5352376A (en) * 1993-02-19 1994-10-04 Ecolab Inc. Thermoplastic compatible conveyor lubricant
CA2330279C (en) * 1998-05-22 2003-06-10 The Procter & Gamble Company Acidic cleaning compositions with c10 alkyl sulfate detergent surfactant
JP2002275483A (ja) * 2001-03-21 2002-09-25 Daisan Kogyo Kk コンベア用潤滑剤組成物
US7718587B2 (en) * 2004-04-26 2010-05-18 Lynx Enterprises, Inc. Composition and method for lubricating conveyor track
EP1690920A1 (en) * 2005-02-11 2006-08-16 JohnsonDiversey, Inc. Lubricant concentrate containing a phosphate triester

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4895668A (en) * 1986-02-18 1990-01-23 Diversey Corporation Carboxylated surfactant-containing lubricants, production and use
US5062979A (en) * 1988-09-16 1991-11-05 Ecolab Inc. Soap free conveyor lubricant that gives clear solutions in water comprising alkoxyphosphate ester, alkyl benzene sulfonate and carboxylic acid
WO2000037591A1 (en) * 1998-12-23 2000-06-29 Rhodia Inc. Phosphate ester compositions in a weight ratio greater than 1:1 monoalkyl to dialkyl phosphate used as lubricant additives
WO2004037960A1 (en) * 2002-10-24 2004-05-06 Kao Corporation, S.A. Use of ether carboxylates as lubricants
US20040167044A1 (en) * 2002-11-14 2004-08-26 Ecolab Inc. Conveyor lubricants for use in the food and beverage industries
EP1652909A1 (de) * 2004-10-19 2006-05-03 Helmut Theunissen Korrosionsschutzmittel für funktionelle Flüssigkeiten, wassermischbares Konzentrat und dessen Verwendung

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10851325B2 (en) 2005-03-15 2020-12-01 Ecolab Usa Inc. Dry lubricant for conveying containers
US10815448B2 (en) 2005-03-15 2020-10-27 Ecolab Usa Inc. Lubricant for conveying containers
US9926511B2 (en) 2005-03-15 2018-03-27 Ecolab Usa Inc. Lubricant for conveying containers
US9562209B2 (en) 2005-03-15 2017-02-07 Ecolab Usa Inc. Dry lubricant for conveying containers
US9365798B2 (en) 2005-03-15 2016-06-14 Ecolab Usa Inc. Lubricant for conveying containers
WO2009040370A1 (en) * 2007-09-26 2009-04-02 Kao Chemicals Gmbh Lubrication of conveyor systems
EP2042587A1 (en) * 2007-09-26 2009-04-01 KAO CHEMICALS GmbH Lubrication of conveyor systems
EP2105493A1 (en) 2008-03-25 2009-09-30 Johnson Diversey, Inc. Dry lubrication method employing oil-based lubricants
EP2105494A1 (en) 2008-03-25 2009-09-30 Johnson Diversey, Inc. A method of lubricating a conveyor belt
US10793806B2 (en) 2010-09-24 2020-10-06 Ecolab Usa Inc. Conveyor lubricants including emulsions and methods employing them
US10260020B2 (en) 2010-09-24 2019-04-16 Ecolab Usa Inc. Conveyor lubricants including emulsions and methods employing them
US9359579B2 (en) 2010-09-24 2016-06-07 Ecolab Usa Inc. Conveyor lubricants including emulsions and methods employing them
US9873853B2 (en) 2013-03-11 2018-01-23 Ecolab Usa Inc. Lubrication of transfer plates using an oil or oil in water emulsions
US11788028B2 (en) 2013-03-11 2023-10-17 Ecolab Usa Inc. Lubrication of transfer plate using an oil or oil in water emulsions
US10844314B2 (en) 2013-03-11 2020-11-24 Ecolab Usa Inc. Lubrication of transfer plates using an oil or oil in water emulsions
US10316267B2 (en) 2013-03-11 2019-06-11 Ecolab Usa Inc. Lubrication of transfer plates using an oil or oil in water emulsions
US11312919B2 (en) 2013-03-11 2022-04-26 Ecolab Usa Inc. Lubrication of transfer plates using an oil or oil in water emulsions
CN109705968A (zh) * 2018-12-20 2019-05-03 广东环凯微生物科技有限公司 一种低泡的中性水基链板润滑剂及其制备方法
CN114891553A (zh) * 2022-05-26 2022-08-12 西安建筑科技大学 一种钛合金型材挤压用玻璃润滑的制备方法及玻璃润滑剂
CN114891553B (zh) * 2022-05-26 2023-01-10 西安建筑科技大学 一种钛合金型材挤压用玻璃润滑的制备方法及玻璃润滑剂

Also Published As

Publication number Publication date
WO2007112917A2 (en) 2007-10-11
JP2009531483A (ja) 2009-09-03
BRPI0708839A2 (pt) 2011-06-21
AU2007234025A1 (en) 2007-10-11
CA2645226A1 (en) 2007-10-11
JP5465004B2 (ja) 2014-04-09
WO2007112917A3 (en) 2007-11-22
EP2024472A2 (en) 2009-02-18
RU2008143209A (ru) 2010-05-10
RU2437922C2 (ru) 2011-12-27
AU2007234025B2 (en) 2012-06-28
US20100286009A1 (en) 2010-11-11

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