EP1838394B1 - Oxygen-producing respiratory protection device - Google Patents
Oxygen-producing respiratory protection device Download PDFInfo
- Publication number
- EP1838394B1 EP1838394B1 EP06722457A EP06722457A EP1838394B1 EP 1838394 B1 EP1838394 B1 EP 1838394B1 EP 06722457 A EP06722457 A EP 06722457A EP 06722457 A EP06722457 A EP 06722457A EP 1838394 B1 EP1838394 B1 EP 1838394B1
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- EP
- European Patent Office
- Prior art keywords
- air treatment
- chemical
- treatment chambers
- oxygen
- breathing apparatus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 21
- 239000001301 oxygen Substances 0.000 title claims abstract description 21
- 230000000241 respiratory effect Effects 0.000 title claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 62
- 230000029058 respiratory gaseous exchange Effects 0.000 claims abstract description 49
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000013016 damping Methods 0.000 claims abstract description 28
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims abstract description 25
- 239000008187 granular material Substances 0.000 claims abstract description 18
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 14
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 14
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract 3
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 claims abstract 3
- 229910052700 potassium Inorganic materials 0.000 claims abstract 3
- 239000011591 potassium Substances 0.000 claims abstract 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 239000010949 copper Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 229910001220 stainless steel Inorganic materials 0.000 claims description 7
- 239000010935 stainless steel Substances 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 239000010419 fine particle Substances 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- 230000035939 shock Effects 0.000 description 16
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000004744 fabric Substances 0.000 description 4
- 238000010298 pulverizing process Methods 0.000 description 4
- 239000000428 dust Substances 0.000 description 3
- 230000005923 long-lasting effect Effects 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000036387 respiratory rate Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B7/00—Respiratory apparatus
- A62B7/08—Respiratory apparatus containing chemicals producing oxygen
Definitions
- the invention relates to an oxygen-generating respirator comprising a connected to a breathing tube and a breathing bag, for generating oxygen in both directions flowed through chemical cartridge, the chemical cartridge having a plurality of air-permeable holding grid separated air treatment chambers, and a breathing bag adjacent the air treatment chamber with a carbon dioxide is filled in the other air treatment chambers, the granular chemical for oxygen generation.
- An oxygen-generating respirator of this kind is out US 4,515,156 A previously known. This is to an improved distribution and mixing of the breathing gas can be achieved by dividing the chemical cartridge in air treatment chambers. For better heat distribution and removal multicellular space lattice and for damping shock loads coil springs and perforated transverse walls are provided.
- the exhaled air of the user is passed through a chemical contained in a canister or chemical cartridge, for example, in granular form, potassium peroxide (KO 2 ).
- the carbon dioxide contained in the exhaled air and reacting with the chemical oxygen is produced in an exothermic reaction, which passes from the chemical cartridge in a breathing bag and is inhaled by the user again.
- These devices where the Exhaling in a so-called pendulum respiration on the chemical and against the resulting resistance, are in case of sudden contamination of the air as self-rescuers or escape aids for a limited period of use, for example, 20 minutes and the single use, for example, in mines determined.
- the rescue device consisting of the chemical cartridge with breathing bag and breathing tube has a small design and is carried in a stable container by the user during work in a hazardous work area, for example by attachment to the belt, for safety reasons constantly carried (passive use) to Emergency case immediately created and used actively.
- the device must still be ready for use and fully functional in an emergency. This is contrary, however, that the present for the light air passage in granular form chemical due to the multiple, possibly long lasting vibration of the device of a gradual pulverization subject.
- the powder can fall into the breathing bag or settle in the region of the bottom of the chemical cartridge and thus in the opening to the breathing bag on a the fine dust particles retentive cotton-like material and due to moisture or the heat generated due to the exothermic reaction to oxygen to bond with the Cotton or caking lead, so that unimpeded flow of breathing air and thus the functioning of the rescue device is not guaranteed.
- Hardening of the granules which would reduce abrasion and dusting, results in decreased reactivity and retarded chemical reaction with the carbon dioxide, so that in this case too little oxygen is generated.
- the multi-layered superimposed wire mesh which can also create a flat against the inner walls of the cartridge, the granules completely traversing air passageway is created so that a large part of the carbon dioxide contained in the exhaled air does not come into contact with the chemical and thus is not absorbed.
- the invention has for its object to provide an oxygen-generating respirator, in which a functionality is maintained despite full external mechanical impact unrestricted.
- this object is achieved with an oxygen-generating respirator characterized in that in the outer air treatment chambers on a frontal, apertured cover of the chemical cartridge subsequent and transverse to the flow direction planar shock damping means of a multi-layer fine wire knit and in the middle air treatment chambers each one of a multilayer , Zigzag extending and fixed to one side of a wire mesh fine wire knit existing damping element is provided with aligned in the flow direction, but offset in the adjacent air treatment chambers walls arranged to each other.
- the oxygen-generating respirator designed according to the invention as self-rescuer for persons working under robust conditions, is able to function immediately and with high respiratory physiological performance without restriction even after long years of external mechanical action in a necessary application.
- the oxygen-generating respirator comprises a chemical cartridge in which oxygen is generated for breathing with the carbon dioxide contained in the exhaled air.
- a breathing tube with mouthpiece and on the opposite side a breathing bag is connected as an air reservoir.
- the chemical cartridge is subdivided according to the invention by means of fixed holding grids in individual, successive air treatment chambers.
- the provided in adjacent air treatment chambers zigzag damping elements are not in alignment, but offset from each other, preferably mirror images, arranged.
- the present in granular form of chemicals for oxygen generation and - optionally housed in a chamber for carbon dioxide - packed tightly by shaking and pressing.
- the resilient fine wire knit fabrics of the shock absorbers have a very smooth outer surface.
- the oxygen-generating respirator According to the present invention, even after many years of non-active use, in which the device and in particular the chemical, high mechanical loads (shocks, shocks) has been exposed, in the case of active use immediately and without restriction higher Performance possible to provide the oxygen required for the user's breathing.
- the chemical granules are housed so resiliently cushioned in the cartridge, that despite long-lasting high mechanical stress hardly abrasion, that is, no functioning of the counteracting pulverization of the granules.
- the inventive design of the chemical cartridge allows the use of a very coarse-grained - inexpensive - chemical and optimal flow through the chemical cartridge with high performance data.
- preferably four air treatment chambers are provided.
- the two outer chambers are significantly smaller than the inner ones.
- the outer chamber connected to the breathing bag is filled with lithium hydroxide tablets as a carbon dioxide-binding chemical, while the other chambers contain a very coarse-grained potassium hydroxide granules for oxygen production.
- the damping means provided in the two outer chambers consist of copper and at the same time serve as additional heat exchangers for cooling the respiratory air, which is strongly heated by the exothermic reaction during the oxygen generation, so that the breathing comfort is improved.
- the damping elements in the middle air treatment chambers are made of a prefabricated as a hose fine wire mesh made of stainless steel.
- the tube is compressed and folded once in the longitudinal direction, after previously for stabilization in the middle of a copper wire knit insert was introduced. After the subsequent stitching, the fabric package is folded zigzag and connected to one of the zigzag running edges with a wire mesh.
- the substantially parallel to the inner wall extending folding edges of the fabric package are located at a distance from the inner surface of the relevant air treatment chamber in the chemical cartridge.
- the breathing apparatus for generating oxygen comprises a breathing bag 1 made of airtight material, a chemical cartridge 2 sealingly held in an opening of the breathing bag 1, and a breathing tube 3 having a mouthpiece 4 and a nose clip 5.
- the breathing tube 3 is integral with a receptacle comprising the upper portion of the chemical cartridge 2 6, via which the chemical cartridge 2 is sealingly held by means of a clamp attachment 7 in the breathing bag 1.
- the respirator is packaged during non-active use in a sturdy metal container, preferably held on the belt of the user. If the respirator wearer is in an environment with non-respirable gas or smoke, the packaging container is opened and then inhaled and exhaled via the mouthpiece 4.
- the heat exchanger 12 consists of a package of fine copper screens and an air-permeable, but very fine particle-retaining, bordered by two coarse mesh stainless steel mesh cover.
- the chemical cartridge 2 is subdivided into four air treatment chambers 15 to 18 by three holding screens 14a to 14c respectively fixed to a snap ring 13a to 13c.
- the first (upper) air treatment chamber 15 and in the fourth (lower) air treatment chamber 18 are - starting from the upper and lower cover 10, 9 - a coarse screen 19a, 19b made of stainless steel, a fine mesh 20a, 20b made of copper and a multilayer A flat elastic fine wire knit made of copper as upper and lower shock absorbing means 21a, 21b.
- the respectively subsequent second and third air treatment chamber 16 17 towards the first and fourth air treatment chamber 15 and 18 are respectively limited by the above-mentioned holding screen 14 a and 14 c.
- the fine sieves 20a, 20b are there for safety and possibly retain any fine KO 2 particles present in the chemical cartridge 2.
- the arrangement of the first, relatively shallow air treatment chamber 15 ensures the immediate function of the respirator, that is, the reaction of the carbon dioxide with the potassium peroxide to oxygen, even at very low temperatures, for example -5 ° C.
- the lithium hydroxide in the fourth air treatment chamber 18 has the task of binding the excess CO 2 , which arises at high respiratory rates.
- damping elements 24, 25 are each at a - zick- zackförmig extending edge to a wire mesh 26, 27 attached.
- the longitudinal edges 28 of the folds, that is, the fold edges of the damping elements 24, 25 extend at a distance parallel to the side walls 29 of the chemical cartridge 2.
- the fine wire mesh of the damping elements 24, 25 consists of four - formed from a folded and longitudinally once folded tube - layers made of stainless steel and a stabilizing copper wire mesh lying between the two outer layers thus formed.
- the latter are arranged in mirror image relative to one another with respect to the zigzag shape, so that their mutual walls are offset from one another, that is, they are not in alignment.
- a particularly uniform flow through the two filled with potassium hydroxide granules 22 air treatment chambers 16, 17 is achieved, so that a cost coarse granules can be used and due to the resulting optimum flow of respiratory air ultimately very good respiratory physiological performance data can be achieved.
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- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Emergency Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Pulmonology (AREA)
- General Health & Medical Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Respiratory Apparatuses And Protective Means (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- External Artificial Organs (AREA)
Abstract
Description
Die Erfindung betrifft ein Sauerstoff erzeugendes Atemschutzgerät, das eine an einen Atemschlauch und einen Atembeutel angeschlossene, zur Erzeugung von Sauerstoff in beiden Richtungen durchströmte Chemikalpatrone umfasst, wobei die Chemikalpatrone mehrere mittels luftdurchlässiger Haltegitter voneinander getrennte Luftbehandlungskammern aufweist, und eine dem Atembeutel benachbarte Luftbehandlungskammer mit einer Kohlendioxid bindenden Chemikalie gefüllt ist, während sich in den anderen Luftbehandlungskammern die als Granulat vorliegende Chemikalie zur Sauerstofferzeugung befindet.The invention relates to an oxygen-generating respirator comprising a connected to a breathing tube and a breathing bag, for generating oxygen in both directions flowed through chemical cartridge, the chemical cartridge having a plurality of air-permeable holding grid separated air treatment chambers, and a breathing bag adjacent the air treatment chamber with a carbon dioxide is filled in the other air treatment chambers, the granular chemical for oxygen generation.
Ein Sauerstoff erzeugendes Atemschutzgerät dieser Art ist aus
Bei Atemschutzgeräten dieser Art wird die ausgeatmete Luft des Benutzers über eine in einem Kanister oder einer Chemikalpatrone befindliche Chemikalie, zum Beispiel in körniger Form vorliegendes Kaliumhyperoxid (KO2), geleitet. Durch das in der Ausatemluft enthaltene und mit der Chemikalie reagierende Kohlendioxid wird in einer exothermen Reaktion Sauerstoff erzeugt, der aus der Chemikalpatrone in einen Atembeutel gelangt und vom Benutzer wieder eingeatmet wird. Diese Geräte, bei denen das Ein- und Ausatmen in einer sogenannten Pendelatmung über die Chemikalie und gegen den dadurch bedingten Widerstand erfolgt, sind im Falle einer plötzlichen Kontamination der Luft als Selbstretter oder Fluchthilfegeräte für eine begrenzte Einsatzzeit von beispielsweise 20 Minuten und den einmaligen Gebrauch, beispielsweise in Bergwerken, bestimmt. Das aus der Chemikalpatrone mit Atembeutel und Atemschlauch bestehende Rettungsgerät hat eine kleine Bauform und wird, verpackt in einen stabilen Behälter, vom Benutzer während der Tätigkeit in einem gefährdeten Arbeitsbereich, beispielsweise durch Befestigung am Gürtel, aus Sicherheitsgründen ständig mitgeführt (passive Verwendung), um im Ernstfall sofort angelegt und aktiv benutzt werden zu können. Trotz der hohen und über zumeist viele Jahre des nicht notwendigen aktiven Einsatzes lang andauernden mechanischen Belastung, beispielsweise im rauen Bergwerksbetrieb, muss das Gerät dennoch ständig einsatzbereit und bei einem Notfall voll funktionsfähig sein. Dem steht jedoch entgegen, dass die für den leichten Atemluftdurchgang in körniger Form vorliegende Chemikalie aufgrund der vielfachen, gegebenenfalls langjährigen Erschütterung des Gerätes einer allmählichen Pulverisierung unterliegt. Das Pulver kann in den Atembeutel fallen oder sich im Bereich des Bodens der Chemikalpatrone und damit im Bereich der Öffnung zum Atembeutel auf einem die feinen Staubpartikel zurückhaltenden watteartigen Material absetzen und aufgrund von Feuchte oder der aufgrund der exothermen Reaktion zu Sauerstoff erzeugten Wärme zu verklebungen mit der Watte bzw. Verbackungen führen, so dass ungehinderte Durchströmung der Atemluft und damit die Funktionsfähigkeit des Rettungsgerätes nicht gewährleistet ist.In respirators of this type, the exhaled air of the user is passed through a chemical contained in a canister or chemical cartridge, for example, in granular form, potassium peroxide (KO 2 ). The carbon dioxide contained in the exhaled air and reacting with the chemical oxygen is produced in an exothermic reaction, which passes from the chemical cartridge in a breathing bag and is inhaled by the user again. These devices, where the Exhaling in a so-called pendulum respiration on the chemical and against the resulting resistance, are in case of sudden contamination of the air as self-rescuers or escape aids for a limited period of use, for example, 20 minutes and the single use, for example, in mines determined. The rescue device consisting of the chemical cartridge with breathing bag and breathing tube has a small design and is carried in a stable container by the user during work in a hazardous work area, for example by attachment to the belt, for safety reasons constantly carried (passive use) to Emergency case immediately created and used actively. Despite the high and over many years of unnecessary active use long-lasting mechanical stress, such as in rough mining operation, the device must still be ready for use and fully functional in an emergency. This is contrary, however, that the present for the light air passage in granular form chemical due to the multiple, possibly long lasting vibration of the device of a gradual pulverization subject. The powder can fall into the breathing bag or settle in the region of the bottom of the chemical cartridge and thus in the opening to the breathing bag on a the fine dust particles retentive cotton-like material and due to moisture or the heat generated due to the exothermic reaction to oxygen to bond with the Cotton or caking lead, so that unimpeded flow of breathing air and thus the functioning of the rescue device is not guaranteed.
Einer Härtung des Granulats, die den Abrieb und die Staubbildung verringern würde, steht eine verminderte Reaktionsfähigkeit und eine verzögerte Reaktion der Chemikalie mit dem Kohlendioxid entgegen, so dass in diesem Fall zu wenig Sauerstoff erzeugt wird.Hardening of the granules, which would reduce abrasion and dusting, results in decreased reactivity and retarded chemical reaction with the carbon dioxide, so that in this case too little oxygen is generated.
Um eine gleichmäßige Durchströmung der in dem Kanister untergebrachten Chemikalie zu erreichen, ist es aus der
Des weiteren wurde bereits vorgeschlagen, in die Chemikalpatrone ein sich über deren gesamte Länge in Durchströmrichtung erstreckendes, mehrfach gefaltetes Drahtgewebe aus Edelstahl einzulegen und zusätzlich auch an den Stirnseiten ein elastisches Drahtgewebe anzuordnen und dadurch die auf das Granulat wirkenden Erschütterungen zu vermindern. Vermeiden lassen sich die Erschütterungen dadurch jedoch nicht vollständig, da die gefaltete Gewebeeinlage in sich nicht formstabil ist und sich in der Chemikalpatrone verschieben kann. Die gleichmäßige Befüllung der Patrone mit dem Granulat ist schwierig oder nicht möglich. Die atemphysiologische Leistungsfähigkeit ist ohnehin und erst recht nach einer vorangegangenen mechanischen Belastung deutlich eingeschränkt. Mit dem mehrschichtig übereinander gelegten Drahtgeflecht, das sich auch flächig an die Innenwände der Patrone anlegen kann, wird ein das Granulat vollständig durchziehender Luftdurchgangskanal geschaffen, so dass ein großer Teil des in der Ausatemluft enthaltenen Kohlendioxids nicht mit der Chemikalie in Berührung kommt und somit nicht absorbiert wird.Furthermore, it has been proposed to insert in the chemical cartridge over its entire length in the direction of flow extending, multi-folded wire mesh made of stainless steel and also to arrange on the front sides of an elastic wire mesh and thereby reduce the vibrations acting on the granules shocks. However, the shocks can not be completely avoided as the folded fabric insert is not dimensionally stable in itself and can shift in the chemical cartridge. The uniform filling of the cartridge with the granules is difficult or impossible. The respiratory physiological performance is already clearly limited and certainly after a previous mechanical load. With the multi-layered superimposed wire mesh, which can also create a flat against the inner walls of the cartridge, the granules completely traversing air passageway is created so that a large part of the carbon dioxide contained in the exhaled air does not come into contact with the chemical and thus is not absorbed.
Der Erfindung liegt die Aufgabe zugrunde, ein Sauerstoff erzeugendes Atemschutzgerät zu schaffen, bei welchem eine Funktionsfähigkeit trotz andauernder äußerer mechanischer Einwirkung uneingeschränkt erhalten bleibt.The invention has for its object to provide an oxygen-generating respirator, in which a functionality is maintained despite full external mechanical impact unrestricted.
Erfindungsgemäß wird diese Aufgabe mit einem Sauerstoff erzeugenden Atemschutzgerät dadurch gelöst, dass in den äußeren Luftbehandlungskammern ein an eine stirnseitige, mit Öffnungen versehene Abdeckung der Chemikalpatrone anschließendes und quer zur Strömungsrichtung verlaufendes ebenes Stoßdämpfungsmittel aus einem mehrlagigen Feindrahtgestrick und in den mittleren Luftbehandlungskammern jeweils ein aus einem mehrlagigen, zickzackförmig verlaufenden und an einer Seite an einem Drahtgitter fixierten Feindrahtgestrick bestehendes Dämpfungselement mit in Strömungsrichtung ausgerichteten, jedoch in den benachbarten Luftbehandlungskammern versetzt zueinander angeordneten Wänden vorgesehen ist. Das erfindungsgemäß ausgestaltete, Sauerstoff erzeugende Atemschutzgerät ist als Selbstretter für unter robusten Bedingungen tätige Personen auch nach langer, über Jahre andauernder äußerer mechanischer Einwirkung in einem notwendigen Einsatzfall sofort und mit hoher atemphysiologischer Leistung unseingeschränkt funktionsfähig.According to the invention this object is achieved with an oxygen-generating respirator characterized in that in the outer air treatment chambers on a frontal, apertured cover of the chemical cartridge subsequent and transverse to the flow direction planar shock damping means of a multi-layer fine wire knit and in the middle air treatment chambers each one of a multilayer , Zigzag extending and fixed to one side of a wire mesh fine wire knit existing damping element is provided with aligned in the flow direction, but offset in the adjacent air treatment chambers walls arranged to each other. The oxygen-generating respirator designed according to the invention, as self-rescuer for persons working under robust conditions, is able to function immediately and with high respiratory physiological performance without restriction even after long years of external mechanical action in a necessary application.
Vorteilhafte Weiterbildungen und zweckmäßige Ausgestaltungen der Erfindung sind Gegenstand der Unteransprüche. Das Sauerstoff erzeugende Atemschutzgerät umfasst eine Chemikalpatrone, in der mit dem in der Ausatemluft enthaltenen Kohlendioxid Sauerstoff für die Atmung erzeugt wird. An die Chemikalpatrone ist an einer Seite ein Atemschlauch mit Mundstück und an der gegenüberliegenden Seite ein Atembeutel als Luftreservoir angeschlossen. Die Chemikalpatrone ist gemäß der Erfindung mit Hilfe von fest angeordneten Haltegittern in einzelne, aufeinander folgende Luftbehandlungskammern unterteilt. In den beiden äußeren Luftbehandlungskammern ist - angrenzend an die jeweilige stirnseitige Abdeckung der Chemikalpatrone - ein Stoßdämpfungsmittel aus einem mehrlagigen und mithin elastischen Feindrahtgestrick angeordnet, während in den mittleren Luftbehandlungskammern ein ebenfalls aus einem mehrlagigen Feindrahtgestrick bestehendes, aber zickzackförmig gefaltetes und senkrecht auf den Haltegittern steherdes, d.h. in Strömungsrichtung ausgerichtetes Dämpfungselement, das an einer der zickzackförmig verlaufenden Kanten fixiert ist, untergebracht ist. Die in benachbarten Luftbehandlungskammern vorgesehenen zickzackförmigen Dämpfungselemente sind jedoch nicht in einer Flucht, sondern zueinander versetzt, vorzugsweise spiegelbildlich, angeordnet. In den Luftbehandlungskammern sind die im Wesentlichen in körniger Form vorliegenden Chemikalien zur Sauerstofferzeugung und - wahlweise in einer Kammer zur Kohlendioxidbindung - durch Rütteln und Pressen eng gepackt untergebracht. Die elastischen Feindrahtgestricke der Stoßdämpfungsmittel haben eine sehr glatte Außenfläche.Advantageous developments and expedient embodiments of the invention are the subject of the dependent claims. The oxygen-generating respirator comprises a chemical cartridge in which oxygen is generated for breathing with the carbon dioxide contained in the exhaled air. To the chemical cartridge on one side a breathing tube with mouthpiece and on the opposite side a breathing bag is connected as an air reservoir. The chemical cartridge is subdivided according to the invention by means of fixed holding grids in individual, successive air treatment chambers. In the two outer air treatment chambers - adjacent to the respective frontal cover of the chemical cartridge - a shock absorbing means of a multi-layer and thus elastic fine wire knitted arranged while in the middle air treatment chambers also consisting of a multi-layer fine wire knit, but zigzag folded and stanchions vertically on the holding lattices, that is aligned in the flow direction damping element, which is fixed to one of the zigzagging edges, is housed. However, the provided in adjacent air treatment chambers zigzag damping elements are not in alignment, but offset from each other, preferably mirror images, arranged. In the air treatment chambers, the present in granular form of chemicals for oxygen generation and - optionally housed in a chamber for carbon dioxide - packed tightly by shaking and pressing. The resilient fine wire knit fabrics of the shock absorbers have a very smooth outer surface.
Mit dem Sauerstoff erzeugenden Atemschutzgerät gemäß der vorliegenden Erfindung ist es selbst nach vielen Jahren des nicht aktiven Einsatzes, in denen das Gerät und insbesondere das Chemikal, hohen mechanischen Belastungen (Stößen, Erschütterungen) ausgesetzt war, im Falle der aktiven Nutzung sofort und uneingeschränkt sowie mit hoher Leistung möglich, den für die Atmung des Benutzers erforderlichen Sauerstoff zur Verfügung zu stellen. Das Chemikalgranulat ist derart elastisch abgefedert in der Patrone untergebracht, dass trotz langandauernder hoher mechanischer Belastung kaum Abrieb, das heißt, keine der Funktionsfähigkeit entgegenstehende Pulverisierung des Granulats erfolgt. Zudem erlaubt die erfindungsgemäße Ausbildung der Chemikalpatrone die Verwendung eines sehr grobkörnigen - kostengünstigen - Chemikals und eine optimale Durchströmung der Chemikalpatrone mit hohen Leistungsdaten.With the oxygen-generating respirator according to the present invention, even after many years of non-active use, in which the device and in particular the chemical, high mechanical loads (shocks, shocks) has been exposed, in the case of active use immediately and without restriction higher Performance possible to provide the oxygen required for the user's breathing. The chemical granules are housed so resiliently cushioned in the cartridge, that despite long-lasting high mechanical stress hardly abrasion, that is, no functioning of the counteracting pulverization of the granules. In addition, the inventive design of the chemical cartridge allows the use of a very coarse-grained - inexpensive - chemical and optimal flow through the chemical cartridge with high performance data.
In Ausgestaltung der Erfindung sind vorzugsweise vier Luftbehandlungskammern vorgesehen. Dabei sind die beiden äußeren Kammern deutlich kleiner als die inneren. Die an den Atembeutel angeschlossene äußere Kammer ist mit Lithiumhydroxid-Tabletten als Kohlendioxid bindendes Chemikal gefüllt, während die anderen Kammern ein sehr grobkörniges Kaliumhyperoxid-Granulat zur Sauerstofferzeugung enthalten. Durch die an den Atemschlauch anschließende kleine (erste) Luftbehandlungskammer ist auch im Minustemperaturbereich sofort eine Sauerstofferzeugung gewährleistet.In an embodiment of the invention preferably four air treatment chambers are provided. The two outer chambers are significantly smaller than the inner ones. The outer chamber connected to the breathing bag is filled with lithium hydroxide tablets as a carbon dioxide-binding chemical, while the other chambers contain a very coarse-grained potassium hydroxide granules for oxygen production. By connecting to the breathing tube small (first) air treatment chamber, an oxygen production is guaranteed even in the minus temperature range immediately.
Gemäß einem weiteren wichtigen Merkmal der Erfindung bestehen die in den beiden äußeren Kammern vorgesehenen Dämpfungsmittel aus Kupfer und dienen gleichzeitig als zusätzliche Wärmetauscher zur Abkühlung der durch die exotherme Reaktion bei der Sauerstofferzeugung stark erwärmten Atemluft, so dass der Atemkomfort verbessert wird.According to a further important feature of the invention, the damping means provided in the two outer chambers consist of copper and at the same time serve as additional heat exchangers for cooling the respiratory air, which is strongly heated by the exothermic reaction during the oxygen generation, so that the breathing comfort is improved.
Die Dämpfungselemente in den mittleren Luftbehandlungskammern sind aus einem als Schlauch vorgefertigten Feindrahtgestrick aus Edelstahl hergestellt. Der Schlauch ist zusammengedrückt und einmal in Längsrichtung gefaltet, nachdem zuvor zu Stabilisierung mittig eine Kupferdrahtgestrickeinlage eingebracht wurde. Nach dem anschließenden Zusammenheften wird das Gestrickpaket zickzackförmig gefaltet und an einer der zickzackförmig verlaufenden Kanten mit einem Drahtgitter verbunden. Die im Wesentlichen parallel zur Innenwand verlaufenden Faltkanten des Gestrickpakets befinden sich im Abstand von der Innenfläche der betreffenden Luftbehandlungskammer in der Chemikalpatrone.The damping elements in the middle air treatment chambers are made of a prefabricated as a hose fine wire mesh made of stainless steel. The tube is compressed and folded once in the longitudinal direction, after previously for stabilization in the middle of a copper wire knit insert was introduced. After the subsequent stitching, the fabric package is folded zigzag and connected to one of the zigzag running edges with a wire mesh. The substantially parallel to the inner wall extending folding edges of the fabric package are located at a distance from the inner surface of the relevant air treatment chamber in the chemical cartridge.
Ein Ausführungsbeispiel der Erfindung, aus dem sich weitere vorteilhafte Ausgestaltungen ergeben, wird anhand der Zeichnung näher erläutert. Es zeigen:
- Fig. 1
- eine Vorderansicht eines nicht verpackten Atem- schutzgerätes zur Sauerstofferzeugung mit einem teilweise weggeschnitten dargestellten Atembeu- tel und in diesen eingebundener Chemikalpatro- ne; und
- Fig. 2
- eine Vorderansicht einer teilweise im Schnitt wiedergegebenen Chemikalpatrone.
- Fig. 1
- a front view of a non-packaged respirator for oxygen generation with a partially cutaway airway and in this incorporated chemical patrons; and
- Fig. 2
- a front view of a partially cut in the chemical cartridge.
Das Atemschutzgerät zur Sauerstofferzeugung umfasst einen aus luftdichtem Material bestehenden Atembeutel 1, eine in einer Öffnung des Atembeutels 1 abdichtend gehaltene Chemikalpatrone 2 und einen Atemschlauch 3 mit Mundstück 4 und Nasenklemme 5. Der Atemschlauch 3 ist integral mit einer den oberen Bereich der Chemikalpatrone 2 umfassenden Aufnahme 6 verbunden, über die die Chemikalpatrone 2 abdichtend mittels einer Schellenbefestigung 7 in dem Atembeutel 1 gehalten ist. Das Atemschutzgerät ist während der nicht aktiven Verwendung in einem stabilen, vorzugsweise am Gürtel des Benutzer gehaltenen Blechbehälter verpackt. Wenn sich der Träger des Atemschutzgerätes in einer Umgebung mit nicht veratembarem Gas oder Rauch befindet, wird der Verpackungsbehälter geöffnet und anschließend wird über das Mundstück 4 ein- und ausgeatmet. In der Atemluft enthaltenes CO2 reagiert mit dem in der Chemikalpatrone 2 enthaltenen KO2-Granulat unter Wärmeerzeugung zu Sauerstoff, der über Öffnungen (nicht dargestellt) in der unteren Abdeckung 9 der Chemikalpatrone 2 in den Atembeutel 1 gelangt und aus diesem über die Chemikalpatrone 2, (nicht dargestellte) Öffnungen in der oberen Abdeckung 10, den Atemschlauch 3 und das Mundstück 4 eingeatmet wird. Auf der oberen Abdeckung 10 liegt ein von einer Dichtmanschette 11 eingefasster Wärmetauscher 12. Der Wärmetauscher 12 besteht aus einem Paket aus feinen Kupfersieben und einer luftdurchlässigen, aber feinste Partikel zurückhaltenden, von zwei grobmaschigen Edelstahlsieben eingefassten Abdeckung.The breathing apparatus for generating oxygen comprises a breathing bag 1 made of airtight material, a chemical cartridge 2 sealingly held in an opening of the breathing bag 1, and a
In der vorliegenden Ausführungsform ist die Chemikalpatrone 2 durch drei jeweils an einem Sprengring 13a bis 13c fixierte Haltesiebe 14a bis 14c in vier Luftbehandlungskammern 15 bis 18 unterteilt. In der ersten (oberen) Luftbehandlungskammer 15 und in der vierten (unteren) Luftbehandlungskammer 18 befinden sich - jeweils von der oberen und unteren Abdeckung 10, 9 ausgehend - ein Grobsieb 19a, 19b aus Edelstahl, ein Feinsieb 20a, 20b aus Kupfer und ein mehrlagiges, ebenes elastisches Feindrahtgestrick aus Kupfer als obere und untere Stoßdämpfungsmittel 21a, 21b. Zu der jeweils anschließenden zweiten bzw. dritten Luftbehandlungskammer 16, 17 hin werden die erste und vierte Luftbehandlungskammer 15 und 18 jeweils durch das oben erwähnte Haltesieb 14a und 14c begrenzt. In dem verbleibenden Zwischenraum befindet sich in der ersten (oberen) Luftbehandlungskammer 15 grobkörniges Kaliumhyperoxid-Granulat (KO2) 22 und in der vierten (unteren) Luftbehandlungskammer 18 sind Lithiumhydroxid-Tabletten (LiOH) 23, dass heißt, das KO2 und das LiOH sind zu der starren oberen und unteren Abdeckung 9, 10 hin elastisch gelagert, um Erschütterungen und Stöße abzufangen und eine Pulverisierung zu vermeiden. Die Feinsiebe 20a, 20b sind zur Sicherheit da und halten gegebenenfalls doch vorhandene feine KO2-Partikel in der Chemikalpatrone 2 zurück.In the present embodiment, the chemical cartridge 2 is subdivided into four air treatment chambers 15 to 18 by three holding screens 14a to 14c respectively fixed to a
Die Anordnung der ersten, relativ flachen Luftbehandlungskammer 15 gewährleistet die sofortige Funktion des Atemschutzgerätes, das heißt, die Reaktion des Kohlendioxids mit dem Kaliumhyperoxid zu Sauerstoff, bereits bei sehr niedrigen Temperaturen, zum Beispiel -5°C. Das Lithiumhydroxid in der vierten Luftbehandlungskammer 18 hat die Aufgabe, den CO2-Überschuss zu binden, der bei hohen Atemfrequenzen entsteht. Eine wichtige Funktion der aus Kupfer bestehenden Stoßdämpfungsmittel 21a, 21b besteht neben dem Dämpfungseffekt in der Wirkung als zusätzlicher Wärmetauscher, so dass die aufgrund der exothermen Reaktion vergleichsweise hohe Einatemtemperatur deutlich gesenkt werden kann.The arrangement of the first, relatively shallow air treatment chamber 15 ensures the immediate function of the respirator, that is, the reaction of the carbon dioxide with the potassium peroxide to oxygen, even at very low temperatures, for example -5 ° C. The lithium hydroxide in the fourth
In der zweiten und dritten Luftbehandlungskammer 16 und 17 befindet sich jeweils ein aus einem Feindrahtgestrick bestehendes, flächiges, aber zickzackförmig gefaltetes Dämpfungselement 24, 25. Die in Strömungsrichtung hochkant in den Luftbehandlungskammern 16, 17 angeordneten Dämpfungselemente 24, 25 sind an jeweils einer - zick-zackförmig verlaufenden Kante an einem Drahtgitter 26, 27 befestigt. Die Längskanten 28 der Falten, das heißt die Faltenkanten der Dämpfungselemente 24, 25 verlaufen im Abstand parallel zu den Seitenwänden 29 der Chemikalpatrone 2. Das Feindrahtgestrick der Dämpfungselemente 24, 25 besteht aus vier - aus einem zusammengelegten und in Längsrichtung einmal gefalteten Schlauch gebildeten - Schichten aus Edelstahl und einem zwischen den beiden so gebildeten Außenschichten liegenden, stabilisierend wirkenden Kupferdrahtgestrick. Diese fünf Schichten sind zudem zusammengeheftet, so dass in Verbindung mit der Befestigung an dem Drahtgitter 26 bzw. 27 kompakte Dämpfungselemente 24, 25 vorhanden sind, deren Wände (Falten) in sich und als Ganzes elastisch sind. Die von den elastischen Wänden des jeweiligen Dämpfungselements 24, 25 begrenzen Zwischenräume sind durch Ausüben eines Pressdruckes und Rütteln vollständig mit dem Kaliumhyperoxid-Granulat 22 gefüllt. Aufgrund der elastischen Fixierung des Granulats in mehreren mittels der Haltesiebe 14 voneinander getrennten Luftbehandlungskammern 15 bis 18 sowie mit den oberen und unteren Stoßdämpfungsmitteln 21a, 21b und den beiden zickzackförmigen Dämpfungselementen 24, 25 sind die in der Chemikalpatrone 2 untergebrachten Chemikalien 22, 23 mit Bezug auf von außen einwirkende Erschütterungen und Stöße derart elastisch fixiert, das der Abtrieb und die Staubbildung vernachlässigbar klein sind und das Atemschutzgerät auch nach vielen Jahren der passiven Benutzung bei einem aktiven Einsatz in einem Ernstfall sofort funktionsfähig ist.In the second and third
In Anbetracht der Kammerbildung und der Anordnung von zwei zickzackförmigen Dämpfungselementen 24, 25 werden Letztere in Bezug auf die Zickzackform spiegelbildlich zueinander angeordnet, so dass deren beiderseitige Wände versetzt zueinander verlaufen, das heißt nicht in einer Flucht liegen. Dadurch wird eine besonders gleichmäßige Durchströmung der beiden mit Kaliumhyperoxid-Granulat 22 gefüllten Luftbehandlungskammern 16, 17 erreicht, so dass ein kostengünstiges grobkörniges Granulat verwendet werden kann und aufgrund der dadurch bedingten optimalen Durchströmung mit Atemluft letztlich sehr gute atemphysiologische Leistungsdaten erzielt werden.In view of the chamber formation and the arrangement of two
- 11
- Atembeutelbreathing bag
- 22
- Chemikalpatronechemical cartridge
- 33
- Atemschlauchbreathing tube
- 44
- Mundstückmouthpiece
- 55
- Nasenklemmenose clip
- 66
- Elast. Aufnahme f. 2Elast. Recording f. 2
- 77
- Schellenbefestigungclamped fixing
- 88th
- --
- 99
- Untere Abdeckung v. 2Lower cover v. 2
- 1010
- Obere Abdeckung v. 2Upper cover v. 2
- 1111
- Dichtmanschettesealing sleeve
- 1212
- Wärmetauscherheat exchangers
- 1313
- Sprengringsnap ring
- 1414
- HaltesiebRetainer
- 1515
- Erste (obere) LuftbehandlungskammerFirst (upper) air treatment chamber
- 1616
- Zweite (mittlere) LuftbehandlungskammerSecond (middle) air treatment chamber
- 1717
- Dritte (mittlere) LuftbehandlungskammerThird (middle) air treatment chamber
- 1818
- Vierte (untere) LuftbehandlungskammerFourth (lower) air treatment chamber
- 1919
- Grobsieb (Edelstahl)Coarse sieve (stainless steel)
- 2020
- Feinsieb (Kupfer)Fine sieve (copper)
- 2121
- Ebene Stoßdämpfungsmittel (Kupfer)Level shock absorber (copper)
- 2222
- KaliumhyperoxidgranulatKaliumhyperoxidgranulat
- 2323
- Lithiumhydroxid-TablettenLithium hydroxide tablets
- 2424
- Zickzackförmiges DämpfungselementZigzagged damping element
- 2525
- Zickzackförmiges DämpfungselementZigzagged damping element
- 2626
- Drahtgitter v. 24Wire mesh v. 24
- 2727
- Drahtgitter v. 25Wire mesh v. 25
- 2828
- Faltkante (Längskanten) v. 24, 25Folding edge (longitudinal edges) v. 24, 25
- 2929
- Seitenwand v. 2Sidewall v. 2
Claims (12)
- An oxygen-generating breathing apparatus which comprises a chemical cartridge through which respiratory air for generating oxygen flows in both directions, which is connected to a breathing hose and a breathing bag, wherein the chemical cartridge (2) has several air treatment chambers (15 to 18) separated from each other by means of air-permeable retaining grids (14a to 14c) and an air treatment chamber (18) adjacent to the breathing bag (1) is filled with a carbon-dioxide-binding chemical (23), whereas the chemical for oxygen generation, present as granulate (22), is located in the other air treatment chambers (15 to 17), characterized in that a flat impact-damping means (21a, 21b) consisting of a multilayer fine wire mesh, which adjoins a front cover (9, 10) of the chemical cartridge (2) provided with openings and running transversely to the direction of flow is provided in the outer air treatment chambers (15, 18) and a damping element (24, 25) consisting of a multilayer fine-wire mesh which runs in a zigzag fashion and is fixed on one side to a wire grid (26, 27), having walls aligned in the direction of flow but disposed in an offset manner with respect to each other in the adjacent air treatment chambers (16, 17) is provided in the middle air treatment chambers.
- A breathing apparatus according to Claim 1, characterized in that the impact damping means (21a, 21b) consists of copper and at the same time functions as a heat exchanger for cooling the respiratory air heated in the exothermic reaction for generating oxygen.
- The breathing apparatus according to Claim 1, characterized in that a fine screen (20a, 20b) for retaining fine particles is arranged between the impact damping means (21a, 21b) and the cover (9, 10).
- The breathing apparatus according to Claim 3, characterized in that the fine screen (20a, 20b) is made of copper.
- The breathing apparatus according to Claim 1, characterized in that the multilayer impact damping element (24, 25) consists of a fine-wire mesh hose made of stainless steel which is compressed in the longitudinal direction and folded once, with a centrally inserted fine-steel mesh insert of copper and the adjacent mesh layers are stapled together.
- The breathing apparatus according to Claim 5, characterized in that the damping elements (24, 25) are folded in a zigzag fashion in such a manner that they oppose one another as a mirror image in the air treatment chambers (16, 17) adjoining each other.
- The breathing apparatus according to Claim 6, characterized in that the fold edges of the damping elements (24, 25) run parallel and at a distance from the side walls of the chemical cartridge (2).
- The breathing apparatus according to Claim 1, characterized in that the division of the chemical cartridge (2) into air treatment chambers (15 to 18) takes place with the aid of circlips (13a to 13c) and retaining screens (14a to 14c) fixed thereto.
- The breathing apparatus according to Claim 1, characterized in that the oxygen-generating chemical is potassium hyperoxide which reacts with the carbon dioxide of the respiratory air and the carbon-dioxide-binding chemical is lithium hydroxide.
- The breathing apparatus according to Claim 9, characterized in that the potassium hyperoxide is a coarse-grained granulate (22) and the lithium hydroxide is present in the form of tablets (23).
- The breathing apparatus according to Claim 1, characterized in that the chemical cartridge (2) is sealingly connected to a further heat exchanger (12) at the upper cover (10) towards the breathing hose (3).
- The breathing apparatus according to Claim 1, characterized in that a total of four air treatment chambers (15 to 18) are provided, wherein the upper first air treatment chamber (15) filled with an oxygen-generating chemical and the lower fourth air treatment chamber (18) filled with a carbon-dioxide-binding chemical are each a multiple smaller than the two centrally arranged second and third air treatment chambers (16, 16) filled with an oxygen-generating chemical.
Priority Applications (1)
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PL06722457T PL1838394T3 (en) | 2005-01-19 | 2006-01-19 | Oxygen-producing respiratory protection device |
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DE102005003176A DE102005003176B3 (en) | 2005-01-19 | 2005-01-19 | Oxygen generating breathing apparatus |
PCT/DE2006/000072 WO2006076895A1 (en) | 2005-01-19 | 2006-01-19 | Oxygen-producing respiratory protection device |
Publications (2)
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EP1838394A1 EP1838394A1 (en) | 2007-10-03 |
EP1838394B1 true EP1838394B1 (en) | 2010-06-16 |
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EP06722457A Active EP1838394B1 (en) | 2005-01-19 | 2006-01-19 | Oxygen-producing respiratory protection device |
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US (1) | US8230854B2 (en) |
EP (1) | EP1838394B1 (en) |
CN (1) | CN101107046B (en) |
AT (1) | ATE471184T1 (en) |
AU (1) | AU2006207719B2 (en) |
DE (2) | DE102005003176B3 (en) |
ES (1) | ES2347818T3 (en) |
PL (1) | PL1838394T3 (en) |
WO (1) | WO2006076895A1 (en) |
ZA (1) | ZA200705527B (en) |
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US5690099A (en) * | 1996-07-22 | 1997-11-25 | Life Support Technologies, Inc. | Method and apparatus for revitalizing exhaled air |
US20040219076A1 (en) * | 2003-05-01 | 2004-11-04 | Zettel Steven A. | Catalytic converter support system |
-
2005
- 2005-01-19 DE DE102005003176A patent/DE102005003176B3/en not_active Expired - Fee Related
-
2006
- 2006-01-19 WO PCT/DE2006/000072 patent/WO2006076895A1/en active Application Filing
- 2006-01-19 AU AU2006207719A patent/AU2006207719B2/en not_active Ceased
- 2006-01-19 PL PL06722457T patent/PL1838394T3/en unknown
- 2006-01-19 US US11/795,701 patent/US8230854B2/en active Active
- 2006-01-19 AT AT06722457T patent/ATE471184T1/en not_active IP Right Cessation
- 2006-01-19 DE DE502006007225T patent/DE502006007225D1/en active Active
- 2006-01-19 ES ES06722457T patent/ES2347818T3/en active Active
- 2006-01-19 CN CN2006800026575A patent/CN101107046B/en not_active Expired - Fee Related
- 2006-01-19 EP EP06722457A patent/EP1838394B1/en active Active
-
2007
- 2007-07-06 ZA ZA200705527A patent/ZA200705527B/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11813486B2 (en) | 2016-09-12 | 2023-11-14 | Msa Europe Gmbh | Cartridge and breathing apparatus containing the same |
Also Published As
Publication number | Publication date |
---|---|
CN101107046B (en) | 2011-08-17 |
AU2006207719A1 (en) | 2006-07-27 |
DE502006007225D1 (en) | 2010-07-29 |
US8230854B2 (en) | 2012-07-31 |
CN101107046A (en) | 2008-01-16 |
DE102005003176B3 (en) | 2006-07-20 |
ES2347818T3 (en) | 2010-11-04 |
AU2006207719B2 (en) | 2010-11-11 |
US20080276934A1 (en) | 2008-11-13 |
ATE471184T1 (en) | 2010-07-15 |
PL1838394T3 (en) | 2011-01-31 |
WO2006076895A1 (en) | 2006-07-27 |
EP1838394A1 (en) | 2007-10-03 |
ZA200705527B (en) | 2008-04-30 |
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