EP1831459A1 - Method for the production of paper, cardboard and card - Google Patents
Method for the production of paper, cardboard and cardInfo
- Publication number
- EP1831459A1 EP1831459A1 EP05817729A EP05817729A EP1831459A1 EP 1831459 A1 EP1831459 A1 EP 1831459A1 EP 05817729 A EP05817729 A EP 05817729A EP 05817729 A EP05817729 A EP 05817729A EP 1831459 A1 EP1831459 A1 EP 1831459A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- retention agent
- inorganic component
- finely divided
- divided inorganic
- center
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000123 paper Substances 0.000 title claims abstract description 59
- 238000000034 method Methods 0.000 title claims abstract description 55
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000011111 cardboard Substances 0.000 title claims abstract description 12
- 230000014759 maintenance of location Effects 0.000 claims abstract description 99
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 86
- 239000011859 microparticle Substances 0.000 claims abstract description 26
- 229920000642 polymer Polymers 0.000 claims abstract description 24
- 125000002091 cationic group Chemical group 0.000 claims description 30
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 22
- 239000000440 bentonite Substances 0.000 claims description 21
- 229910000278 bentonite Inorganic materials 0.000 claims description 21
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 claims description 20
- 229920002401 polyacrylamide Polymers 0.000 claims description 19
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 17
- 125000000129 anionic group Chemical group 0.000 claims description 15
- 229920006317 cationic polymer Polymers 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 230000007062 hydrolysis Effects 0.000 claims description 7
- 238000006460 hydrolysis reaction Methods 0.000 claims description 7
- 239000011087 paperboard Substances 0.000 claims description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 claims description 4
- 150000004760 silicates Chemical class 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 239000008119 colloidal silica Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 10
- 238000010008 shearing Methods 0.000 abstract description 7
- 235000012216 bentonite Nutrition 0.000 description 23
- 239000000178 monomer Substances 0.000 description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- 229920001131 Pulp (paper) Polymers 0.000 description 7
- -1 salts Acids Chemical class 0.000 description 7
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- 229960003563 calcium carbonate Drugs 0.000 description 5
- 235000010216 calcium carbonate Nutrition 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical group NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 229910052570 clay Inorganic materials 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 4
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 229920006158 high molecular weight polymer Polymers 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 229910052615 phyllosilicate Inorganic materials 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 2
- QENRKQYUEGJNNZ-UHFFFAOYSA-N 2-methyl-1-(prop-2-enoylamino)propane-1-sulfonic acid Chemical compound CC(C)C(S(O)(=O)=O)NC(=O)C=C QENRKQYUEGJNNZ-UHFFFAOYSA-N 0.000 description 2
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 2
- NYUTUWAFOUJLKI-UHFFFAOYSA-N 3-prop-2-enoyloxypropane-1-sulfonic acid Chemical compound OS(=O)(=O)CCCOC(=O)C=C NYUTUWAFOUJLKI-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229920006322 acrylamide copolymer Polymers 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 229920006318 anionic polymer Polymers 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- 239000000701 coagulant Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 1
- QHVBLSNVXDSMEB-UHFFFAOYSA-N 2-(diethylamino)ethyl prop-2-enoate Chemical compound CCN(CC)CCOC(=O)C=C QHVBLSNVXDSMEB-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- WROUWQQRXUBECT-UHFFFAOYSA-N 2-ethylacrylic acid Chemical compound CCC(=C)C(O)=O WROUWQQRXUBECT-UHFFFAOYSA-N 0.000 description 1
- KFNGWPXYNSJXOP-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)OCCCS(O)(=O)=O KFNGWPXYNSJXOP-UHFFFAOYSA-N 0.000 description 1
- PCUPXNDEQDWEMM-UHFFFAOYSA-N 3-(diethylamino)propyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCCOC(=O)C(C)=C PCUPXNDEQDWEMM-UHFFFAOYSA-N 0.000 description 1
- XUYDVDHTTIQNMB-UHFFFAOYSA-N 3-(diethylamino)propyl prop-2-enoate Chemical compound CCN(CC)CCCOC(=O)C=C XUYDVDHTTIQNMB-UHFFFAOYSA-N 0.000 description 1
- WWJCRUKUIQRCGP-UHFFFAOYSA-N 3-(dimethylamino)propyl 2-methylprop-2-enoate Chemical compound CN(C)CCCOC(=O)C(C)=C WWJCRUKUIQRCGP-UHFFFAOYSA-N 0.000 description 1
- UFQHFMGRRVQFNA-UHFFFAOYSA-N 3-(dimethylamino)propyl prop-2-enoate Chemical compound CN(C)CCCOC(=O)C=C UFQHFMGRRVQFNA-UHFFFAOYSA-N 0.000 description 1
- ZWAPMFBHEQZLGK-UHFFFAOYSA-N 5-(dimethylamino)-2-methylidenepentanamide Chemical compound CN(C)CCCC(=C)C(N)=O ZWAPMFBHEQZLGK-UHFFFAOYSA-N 0.000 description 1
- LVGSUQNJVOIUIW-UHFFFAOYSA-N 5-(dimethylamino)-2-methylpent-2-enamide Chemical compound CN(C)CCC=C(C)C(N)=O LVGSUQNJVOIUIW-UHFFFAOYSA-N 0.000 description 1
- FLCAEMBIQVZWIF-UHFFFAOYSA-N 6-(dimethylamino)-2-methylhex-2-enamide Chemical compound CN(C)CCCC=C(C)C(N)=O FLCAEMBIQVZWIF-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical compound OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229910052900 illite Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- RCLLINSDAJVOHP-UHFFFAOYSA-N n-ethyl-n',n'-dimethylprop-2-enehydrazide Chemical compound CCN(N(C)C)C(=O)C=C RCLLINSDAJVOHP-UHFFFAOYSA-N 0.000 description 1
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 description 1
- 229910000273 nontronite Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 229910000276 sauconite Inorganic materials 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000011856 silicon-based particle Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/10—Retention agents or drainage improvers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
- D21H17/375—Poly(meth)acrylamide
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
- D21H17/55—Polyamides; Polyaminoamides; Polyester-amides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
- D21H17/56—Polyamines; Polyimines; Polyester-imides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/04—Addition to the pulp; After-treatment of added substances in the pulp
- D21H23/06—Controlling the addition
- D21H23/14—Controlling the addition by selecting point of addition or time of contact between components
- D21H23/18—Addition at a location where shear forces are avoided before sheet-forming, e.g. after pulp beating or refining
Definitions
- the invention relates to a process for the production of paper, paperboard and cardboard by adding a microparticle system of a polymeric retention agent having a molecular weight M w of at least 2 million and a finely divided inorganic component to a pulp having a maximum density of 20 g / l and dewatering the Textilstoffs, wherein the pulp before or after the addition of the cationic retention agent is subjected to at least one shear stage.
- EP-AO 223 223 a process for the production of paper and cardboard by dehydration of a paper stock is known, wherein first bentonite is added to a paper stock having a substance concentration of 2.5 to 5 wt .-%, then diluted the paper stock, a highly cationic polymer having a charge density of at least 4 meq / g and finally adding a high molecular weight polymer based on acrylamide and dewatering the resulting pulp after thorough mixing.
- an essentially linear synthetic cationic polymer having a molecular weight of more than 500,000 in an amount of more than 0.03% by weight is initially metered into an aqueous pulp suspension. , based on dry pulp, the mixture then subjected to the action of a shear field, wherein the first formed flakes are divided into microflakes carrying a cationic charge, then dosed bentonite and dewatered the pulp thus obtained without further action of shear forces.
- EP-A-0 335 575 describes a papermaking process in which first a polymeric cationic fixing agent and then a water-soluble cationic polymer are metered into a pulp, the pulp thus obtained is then subjected to at least one shear stage and then flocculated by the addition of bentonite.
- EP-A-0 885 328 describes a process for the production of paper in which a cationic polymer is first metered into an aqueous pulp suspension, then the mixture is subjected to the action of a shear field, then an activated bentonite dispersion is added and the resulting pulp is dehydrated.
- EP-A-0 910 701 describes a process for the production of paper and board, in which the paper pulp is successively obtained as a low molecular weight or medium molecular weight cationic polymer based on polyethyleneimine or polyvinylamine and subsequently with a high molecular weight cationic polymer such as polyacrylamide, polyvinylamine or cationic starch added. After this pulp has been subjected to at least one shear stage, it is flocculated by addition of bentonite and the pulp is dewatered.
- EP-A-0 608 986 It is known from EP-A-0 608 986 that a cationic retention agent is metered into the thick stock in papermaking.
- Another method for producing paper and board is known from US-A-5,393,381, WO-A-99/66130 and WO-A-99/63159, also using a microparticle system of a cationic polymer and bentonite.
- the cationic polymer used is a water-soluble, branched polyacrylamide.
- WO-A-01/34910 describes a process for producing paper in which a polysaccharide or a synthetic, high molecular weight polymer is metered into the stock suspension. Subsequently, a mechanical shear of the pulp must take place. The reflocculation is carried out by adding an inorganic component such as silica, bentonite or clay and a water-soluble polymer.
- US-A-6,103,065 discloses a process for improving the retention and dewatering of pulps by adding to a pulp after final shearing a cationic polymer having a molecular weight of 100,000 to 2 million and a charge density greater than 4.0 meq./g, at the same time or after adding a polymer having a molecular weight of at least 2 million and a charge density of less than 4.0 meq./g and then dosed bentonite. It is not necessary in this method to shear the stock after the addition of the polymers. After addition of the polymers and the bentonite, the pulp can be dewatered without further action of shearing forces.
- DE-A-102 36 252 discloses a process for producing paper, paperboard and cardboard by shearing a paper stock, adding a microparticle system comprising a cationic polymer and a finely divided inorganic component to the paper stock after the last shear stage in front of the headbox, dewatering of the paper stock, with formation of sheets and drying of the sheets, it being known as cationic Polymers of the microparticle system cationic polyacrylamides, vinylamine units containing polymers and / or polydiallyldimethylammonium chloride having an average molecular weight M w of at least 500 000 daltons and a charge density of at most 4.0 meq./g used.
- the present invention has for its object to provide a further method for the production of paper, cardboard and paperboard using a microparticle system, which gives better retention and papers having an improved formation compared to the known methods.
- the object is achieved according to the invention by a process for the production of paper, paperboard and cardboard by adding a microparticle system of at least one polymeric retention agent having a molecular weight M w of at least 2 million and a finely divided inorganic component to a pulp having a consistency of at most 20 g / l and dewatering of the pulp, wherein the pulp before or after the addition of the retention agent is subjected to at least one shear stage, if the retention agent at least two places in the pulp and the finely divided inorganic component before or after the addition of the retention agent or between two metering for Retention agent dosed.
- the process according to the invention makes it possible to produce all paper grades, for example cardboard, single or multilayer folding boxboard, single or multilayer liners, corrugating medium, papers for newspaper printing, so-called medium-fine writing and printing papers, natural gravure papers and lightweight base papers.
- wood pulp, thermo-mechanical pulp (TMP), chemo-thermo-mechanical pulp (CTMP), pressure polish (PGW), wood pulp and sulphite and sulphate pulp can be used to produce such papers.
- the pulps can be short fiber as well as long fiber.
- fibers recovered from recovered paper alone or in admixture with other fibers for the manufacture of paper, board and cardboard Preferably, wood-free grades are produced by the process according to the invention, which yield highly white paper products.
- the papers may optionally contain up to 40 wt .-%, usually 5 to 35 wt .-% fillers.
- Suitable fillers are, for example, titanium dioxide, natural and preamplified chalk, talc, kaolin, satin white, calcium sulfate, barium sulfate, clay or aluminum oxide.
- the production of the paper products takes place continuously. Usually, one starts from a thick material having, for example, a consistency in the range of 3 to 6 wt .-%.
- the thick material is diluted to a substance density of at most 20 g / l and processed according to the invention to the respective desired paper product.
- the consistency is for example 3 to 15 g / l, preferably 5 to 12 g / l and is usually in the range of 6 to 10 g / l.
- the microparticle system according to the invention consists of at least one polymeric retention agent having a molecular weight M w of at least 2 million and a finely divided anionic component.
- the retention aid may be cationic, anionic, amphoteric or nonionic.
- the average molecular weight M w of the polymeric retention aids is at least 2 million daltons, preferably at least 3 million, and is usually in the range of, for example, 3.5 million to 15 million.
- the charge density of the polymers in question is, for example, at most 4.0 meq./g.
- cationic polyacrylamides having an average molecular weight M w of at least 5 million daltons and a charge density of 0.1 to 3.5 meq./g and polyvinylamines obtainable by hydrolysis of vinylformamide units containing polymers and having an average molecular weight of at least Have 2 million daltons.
- the polyvinylamines are preferably prepared by hydrolysis of homopolymers of N-vinylformamide, the degree of hydrolysis being, for example, up to 100%, usually 70 to 95%.
- High molecular weight copolymers of N-vinylformamide with other ethylenically unsaturated monomers such as vinyl acetate, vinyl propionate, methyl acrylate, methyl methacrylate, acrylamide, acrylonitrile and / or methacrylonitrile can also be hydrolyzed to give polymers containing vinylamine units and used according to the invention.
- all polyvinylamines having a molecular weight M w of at least 2 million can be used according to the invention, which are obtainable by hydrolysis of vinylformamide units-containing polymers, the degree of hydrolysis of the vinylformamide units being 0.5 to 100 mol%.
- the preparation of homopolymers and copolymers of N-vinylformamide is known. It is described, for example, in US Pat. No. 6,132,558, column 2, line 36 to column 5, in the Ie 25 described in detail. The statements made there are hereby incorporated by reference into the disclosure content of the present application.
- Cationic polyacrylamides are, for example, copolymers which are prepared by copolymerizing acrylamide and at least one di-cis-C 2 -alkylamino-C 2 -bisC 4 -alkyl (meth) acrylate or a basic acrylamide in the form of the free bases, the salts with organic or inorganic salts Acids or quaternier- with alkyl halides compounds are available.
- Examples of such compounds are dimethylaminoethyl methacrylate, diethylaminoethyl methacrylate, dimethylaminoethyl acrylate, diethylaminoethyl acrylate, dimethylaminopropyl methacrylate, dimethylaminopropyl acrylate, diethylaminopropyl methacrylate, diethylaminopropyl acrylate and / or dimethylaminoethylacrylamide, dimethylaminoethylmethacrylamide, dimethylaminopropylacrylamide, dimethylaminopropylmethacrylamide and / or diallyldimethylammonium chloride.
- comonomers mentioned can also be copolymerized with methacrylamide to form cationic polymethacrylamides containing, for example, from 5 to 40 mol% of at least one cationic monomer, such as dimethylaminoethyl acrylate or diallyldimethylammonium chloride, in copolymerized form.
- Cationic polymethacrylamide can also be used as a polymeric retention agent of the microparticle system.
- polymers containing cationic polyacrylamides and vinylamine units can be found in the references cited in the prior art, such as EP-A-0 910 701 and US Pat. No. 6,103,065.
- Such polymers are commercially available products.
- Branched polymers e.g. can be prepared by copolymerization of acrylamide or methacrylamide with at least one cationic monomer in the presence of small amounts of crosslinking agents, for example, in the documents cited in the prior art US Pat. No. 5,393,381, WO-A-99/66130 and WO-A-99 / 63159 described.
- polystyrene resins are poly (N-vinylformamides).
- N-vinylformamides are prepared by polymerizing N-vinylformamide into homopolymers or by copolymerizing N-vinylformamide together with at least one other ethylenically unsaturated monomer.
- the vinylformamide units of these polymers are not hydrolysed, in contrast to the preparation of polymers containing vinylamine units.
- the copolymers can be cationic, anionic or amphoteric.
- Cationic polymers are obtained, for example, by copolymerizing N-vinylformamide with at least one of the basic monomers mentioned in the copolymerization of acrylamide.
- Anionic polymers of N-vinylformamide are obtainable by copolymerizing N-vinylformamide in the presence of at least one acid monoethylenically unsaturated monomer.
- Such comonomers are, for example, monoethylenically unsaturated C 3 - to C 5 -carboxylic acids, acrylamido-2-methylpropanesulfonic acid, styrenesulfonic acid or sulfopropyl acrylate.
- the acidic monomers can also be used in completely neutralized form with alkali metal, alkaline earth metal and / or ammonium bases in the copolymerization with N-vinylformamide.
- copolymers mentioned contain units of anionic or cationic monomers, for example, in amounts of 0.5 to 50, preferably 5 to 40 mol% copolymerized.
- Copolymers of N-vinylformamide may also be amphoteric if they contain units of anionic and cationic monoethylenically unsaturated monomers in copolymerized form.
- nonionic polyacrylamides and nonionic polymethacrylamides obtainable by polymerizing acrylamide and / or methacrylamide, as well as anionic polyacrylamides and anionic polymethacrylamides.
- the anionic poly (meth) acrylamides are obtainable, for example, by polymerizing acrylamide or methacrylamide with at least one anionic monomer.
- Suitable anionic monomers are, for example, monoethylenically unsaturated C 3 - to C 5 -carboxylic acids, such as acrylic acid, methacrylic acid, crotonic acid, maleic acid, fumaric acid, vinylacetic acid or ethacrylic acid, and also vinylphosphonic acid, styrenesulfonic acid, acrylamido-2-methylpropanesulfonic acid, sulfopropyl acrylate or sulfopropyl methacrylate and the alkali metal , Alkaline earth metal and ammonium salts of the acid group-containing monomers into consideration.
- monoethylenically unsaturated C 3 - to C 5 -carboxylic acids such as acrylic acid, methacrylic acid, crotonic acid, maleic acid, fumaric acid, vinylacetic acid or ethacrylic acid, and also vinylphosphonic acid, styrenesulfonic acid, acrylamido-2-methylpropa
- the anionic copolymers contain, for example, 1 to 50 mol%, preferably 5 to 40 mol% of at least one anionic monomer in copolymerized form.
- amphoteric copolymers of acrylamide and methacrylamide can be used as a polymeric retention agent of the microparticle system.
- Such copolymers are obtainable by copolymerizing acrylamide or methacrylamide in the presence of at least one anionic and at least one cationic ethylenically unsaturated monomer.
- Suitable cationic polymeric retention aids of the microparticle system are polydiallyldimethylammonium chlorides (polyDADMAC) having an average molecular weight of at least 2 million daltons. Polymers of this type are commercial products.
- the polymeric retention aids of the microparticle system are added to the paper stock in an amount of 0.005 to 0.5% by weight, preferably in an amount of 0.01 to 0.25% by weight, based on dry paper stock.
- Benetonit, colloidal silicic acid, silicates and / or calcium carbonate may be considered as an inorganic component of the microparticle system.
- Colloidal silicic acid is to be understood as meaning products based on silicates, for example silica microgel, silical sol, polysilicates, aluminum silicates, boron silicates, polyboron silicates, clay or zeolites.
- Calcium carbonate can be used, for example, in the form of chalk, ground calcium carbonate or precipitated calcium carbonate can be used as the inorganic component of the microparticle system.
- Bentonite is generally understood to be phyllosilicates which are swellable in water.
- clay mineral montmorillonite and similar clay minerals such as nontronite, hectorite, saponite, sauconite, beidellite, allevardite, illite, halloysite, attapulgite and sepiolite.
- These phyllosilicates are preferably activated before use, ie converted into a water-swellable form in which the phyllosilicates are treated with an aqueous base such as aqueous solutions of caustic soda, potassium hydroxide, soda, potash, ammonia or amines.
- Bentonite in the form treated with sodium hydroxide or those bentonites which are already obtained in the sodium form, so-called Wyoming bentonites, are preferably used as the inorganic component of the microparticle system.
- the platelet diameter of the water-dispersed bentonite in the sodium hydroxide-treated form is, for example, at most 1 to 2 ⁇ m, the thickness of the platelets is about 1 nm.
- the bentonite has a specific surface area of 60 to 800 m 2 / g. Typical bentonites are described, for example, in EP-B-0235893.
- bentonite is added to the cellulosic suspension, typically in the form of an aqueous bentonite slurry.
- This bentonite slurry may contain up to 10% by weight of bentonite. Normally, the slurries contain about 3 to 5 wt .-% bentonite.
- colloidal silica products from the group of silicon-based particles, silica microgels, silica sols, aluminum silicates, borosilicates, polyborosilicates or zeolites can be used. These have a specific surface area of 50 to 1500 m 2 / g and an average particle size distribution of 1 to 250 nm, normally in the range 5 to 100 nm. The production of such components is described, for example, in EP-AO 041 056, EP-AO 185 068 and US-A-5,176,691.
- Clay or kaolin is a hydrous aluminum silicate with a platelet-like structure.
- the crystals have a layer structure and an aspect ratio (diameter to thickness ratio) of up to 30: 1.
- the particle size is e.g. at least 50% smaller than 2 ⁇ m.
- Carbonates used are preferably natural calcium carbonate (ground calcium carbo- nate, GCC) or precipitated calcium carbonate (PCC).
- GCC is produced, for example, by grinding and visual processes using grinding aids. It has a particle size of 40 - 95% less than 2 microns, the specific surface area is in the range of 6 - 13 m 2 / g.
- PCC is made by passing carbon dioxide into an aqueous calcium hydroxide solution. The average particle size is in the range of 0.03-0.6 ⁇ m.
- the specific surface area can be greatly influenced by the choice of precipitation conditions. It is in the range of 6 to 13 m 2 / g.
- the inorganic component of the microparticle system is added to the stock in an amount of 0.01 to 2.0% by weight, preferably in an amount of 0.1 to 1.0% by weight, based on dry stock.
- the aqueous fiber slurry is subjected to at least one shear stage. It goes through at least one cleaning, mixing and / or pumping stage.
- the shearing of the pulp (thin material) can be done for example in a pulper, classifier or in a refiner.
- the retention agent is metered into the thin material and the finely divided inorganic component at least two sites before or after the addition of the retention agent or between two metering sites for retention agent.
- the process can be carried out, for example, by adding the retention agent after the last shear stage to at least two successive points and then metering the finely divided inorganic component.
- the retention agent after the last shear stage is added to at least two points which have the same distance from the shear stage, and then dosed the finely divided inorganic component.
- the process can also be carried out by adding the retention agent before the last shear stage at at least two points, which are arranged in a plane perpendicular to the stock flow or behind one another, and by metering the finely divided inorganic component after the last shear stage.
- At least one retention agent to the thin material, to subject the system to shear, then to add at least one retention agent (which may be identical or preferably different to the first-dosed retention agent) and then to add at least one finely divided inorganic component.
- the process according to the invention it is possible first to meter 25 to 75% by weight of the total retention agent before the last shear stage and the remaining portion of the retention agent and then to add the finely divided inorganic component or to meter it first before the last Scherimpl the finely divided inorganic component and 25 to 75 wt .-% of the retention agent and after the last shear stage the remaining portion of the retention agent.
- the finely divided inorganic component is metered in each case before the last shearing stage, followed by the retention agent at least two in a plane perpendicular to the first Textilstoffstrom or at successively arranged locations.
- the flow rate of the paper pulp stream is, for example, at least 2 m / sec in most paper machines and is usually in the range of 3 to 7 m / sec.
- the dosage of the retention agent can be made for example by means of single or multi-fluid nozzles in the paper stream. This achieves a rapid distribution of the retention agent in the pulp.
- the distance between the center of the metering points of the retention agent is, for example, at least 20 cm in successive addition of retention agent.
- the distance between the center of a metering point for retention agent and the center of a metering point for the finely divided inorganic component for example, also at least 20 cm.
- the retention sites for retention aids can also be arranged in a plane perpendicular to the stock flow.
- the distance between the center of the dosing points of the retention agent is preferably at least 50 cm and the distance between the center of a dosing point for retention agent and the center of a dosing point for the finely divided inorganic component at least 50 cm.
- the distance between the center of the dosing points of the retention agent is in most cases, for example, in the range of 50 cm to 15 m, wherein the distance between the center of a dosing agent for retention agent and the center of a dosing point for the finely divided inorganic component, for. at least 50 cm.
- the arrangement of the addition points is preferably such that the distance between the center of the dosing of the retention agent 50 cm to 10 m and the distance between the center of a dosing point for retention agent and the center of a metering point for the finely divided inorganic component 50 cm to 5 m is.
- the retention agents can also be metered into the paper stock stream at 3 to 5 positions arranged one behind the other. Likewise, it is possible to meter the finely divided inorganic component of the retention agent system into the stock stream at at least two successive locations.
- the customary amounts of process chemicals customarily used in papermaking for example fixatives, dry and wet strength agents, engine sizes, biocides and / or dyes.
- the paper stock is dewatered on a sieve with formation of sheets. The leaves thus produced are dried. Dehydrating the pulp and Drying of the sheets are part of the papermaking process and are carried out continuously in the art.
- the process according to the invention gives papers having a surprisingly good formation and, compared to known microparticle processes, has an improved filler and fines retention.
- the First Pass Retention was determined by determining the ratio of the solids content in the white water to the solids content in the headbox. The information is given in percent.
- the first pass ash retention (FPAR) was determined analogously to the FPR, but only the ash content was considered.
- the formation was measured with a TECHPAP 2D Lab Formation Sensor from Tec- pap).
- the dimensionless FX value is given in the table. The lower this value is, the better the formation of the tested paper.
- Polymin® 215 linear, cationic acrylamide copolymer with an average molecular weight M w of 8 million, a charge density of 1, 7 meq / g and a solids content of 46%
- Polymin® PR 8186 branched, cationic acrylamide copolymer having an average molecular weight M w of 7 million, a charge density of 1.7 meq / g and a polymer content of 46%.
- Mikrofloc® XFB The inorganic component of the microparticle system used was Mikrofloc® XFB.
- Mikrofloc® XFB is a bentonite powder activated by treatment with aqueous caustic soda. It is usually converted on site in a 3-5% suspension.
- the following examples and comparative examples were carried out on a test paper machine with GAP Former. From a wood-free, bleached pulp was first prepared a pulp with a consistency of 8 g / l and 20% calcium carbonate as a filler, which in the examples and in the comparative examples in each case to a wood-free writing and printing paper having a basis weight of 80 g / m 2 was processed.
- the paper machine contained the following arrangement of mixing and shearing units: mixing vessel, dilution, deaerator, screen and headbox. One ton of paper was produced per hour. The addition (amount and metering point) of retention aid and finely divided inorganic component was varied as indicated in the examples and comparative examples. The results obtained in each case are given in the table.
- 650 g / t Polymin 215 (the term "650 g / t" means that 650 g Polymin® 215 were used per ton of produced paper) were added in 2 doses to 350 g / t and 300 g / t with a distance of the dosing of 300 cm in each case before screen and then 2500 g / t of Microfloc® XFB after screen fed to the paper stock described above.
- Example 1 was repeated with the sole exception that the retention agent (650 g / t Polymin 215) was metered in at a single site 400 cm before screen.
- Example 2 was repeated with the sole exception that the retention agent (450 g / t Polymin 215) was metered in at a single point.
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DE102004063005A DE102004063005A1 (en) | 2004-12-22 | 2004-12-22 | Process for the production of paper, cardboard and cardboard |
PCT/EP2005/013631 WO2006069660A1 (en) | 2004-12-22 | 2005-12-17 | Method for the production of paper, cardboard and card |
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EP (1) | EP1831459B1 (en) |
CN (1) | CN101084346B (en) |
CA (1) | CA2589653C (en) |
DE (1) | DE102004063005A1 (en) |
ES (1) | ES2572776T3 (en) |
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CN104903513B (en) * | 2013-01-11 | 2017-11-17 | 巴斯夫欧洲公司 | The method for producing paper and cardboard |
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ATE448869T1 (en) | 2001-02-21 | 2009-12-15 | Metso Paper Inc | ARRANGEMENT FOR MIXING STREAMS IN A PAPER PRODUCTION PROCESS |
DE10118508A1 (en) | 2001-04-12 | 2002-10-17 | Voith Paper Patent Gmbh | Process and plant for producing a fibrous web |
DE10236252B4 (en) | 2002-08-07 | 2005-06-30 | Basf Ag | Process for the production of paper, cardboard and cardboard |
MXPA04003942A (en) | 2003-05-05 | 2007-06-29 | German Vergara Lopez | Retention and drainage system for the manufacturing of paper, paperboard and similar cellulosic products. |
-
2004
- 2004-12-22 DE DE102004063005A patent/DE102004063005A1/en not_active Withdrawn
-
2005
- 2005-12-17 ES ES05817729.6T patent/ES2572776T3/en active Active
- 2005-12-17 EP EP05817729.6A patent/EP1831459B1/en active Active
- 2005-12-17 PT PT05817729T patent/PT1831459E/en unknown
- 2005-12-17 WO PCT/EP2005/013631 patent/WO2006069660A1/en active Application Filing
- 2005-12-17 US US11/722,468 patent/US7998314B2/en active Active
- 2005-12-17 CA CA2589653A patent/CA2589653C/en active Active
- 2005-12-17 CN CN2005800438072A patent/CN101084346B/en active Active
Non-Patent Citations (1)
Title |
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See references of WO2006069660A1 * |
Also Published As
Publication number | Publication date |
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DE102004063005A1 (en) | 2006-07-13 |
CN101084346B (en) | 2012-05-30 |
ES2572776T3 (en) | 2016-06-02 |
WO2006069660A1 (en) | 2006-07-06 |
PT1831459E (en) | 2016-06-02 |
EP1831459B1 (en) | 2016-03-23 |
CA2589653C (en) | 2014-10-07 |
CN101084346A (en) | 2007-12-05 |
US7998314B2 (en) | 2011-08-16 |
CA2589653A1 (en) | 2006-07-06 |
US20100282424A1 (en) | 2010-11-11 |
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