EP1799344A2 - Procédé de production en continu de catalyseurs dmc - Google Patents

Procédé de production en continu de catalyseurs dmc

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Publication number
EP1799344A2
EP1799344A2 EP05789181A EP05789181A EP1799344A2 EP 1799344 A2 EP1799344 A2 EP 1799344A2 EP 05789181 A EP05789181 A EP 05789181A EP 05789181 A EP05789181 A EP 05789181A EP 1799344 A2 EP1799344 A2 EP 1799344A2
Authority
EP
European Patent Office
Prior art keywords
dmc catalysts
dmc
catalysts
reactor
continuous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05789181A
Other languages
German (de)
English (en)
Inventor
Edward Bohres
Michael Triller
Bernd Bechtloff
Raimund Ruppel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP1799344A2 publication Critical patent/EP1799344A2/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00033—Continuous processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00182—Controlling or regulating processes controlling the level of reactants in the reactor vessel
    • B01J35/30—

Definitions

  • the invention relates to a process for the continuous preparation of multimetal cyanide compounds which can be used as catalysts for the addition of alkylene oxides to H-functional compounds. These compounds are often referred to as DMC compounds or DMC catalysts.
  • DMC catalysts for the preparation of polyether alcohols by addition of alkylene oxides to H-functional compounds has long been known.
  • the resulting polyether alcohols can be used as surface-active agents, as carrier oils, but mainly as starting materials for the preparation of polyurethanes.
  • DMC catalysts lead to products with a lower content of unsaturated moieties in the polyether chain.
  • the addition of the alkylene oxides takes place at a higher speed.
  • the DMC catalysts are usually prepared by combining the solutions of a metal salt and a hexacyanometalate compound and subsequent separation, purification and, if appropriate, drying of the resulting polyimide cyanide compound. Usually, the production of the DMC catalysts takes place in the presence of ligands and / or surface-active agents.
  • No. 5,891,818 discloses a process for the preparation of DMC catalysts by combining a metal salt solution with the solution of a hexacyanometallate compound, where part of the reaction mixture is taken off and returned to the reactor as a spray via a nozzle.
  • the formation of foam in the reactor is suppressed and a better mixing of the reaction mixture can be effected.
  • this procedure is still expensive and can lead to clogging of the nozzle by the catalyst particles.
  • WO 01/39883 describes a process for the preparation of DMC catalysts in which a metal salt solution is mixed with the solution of a hexacyanometallate compound. tion is combined in a mixing nozzle.
  • the disadvantage here is that it can already come in the nozzle to a particle formation, which leads to a pressure drop in the nozzle to blockages.
  • the problem could be solved by continuously metering in a continuous reactor the educts used for the preparation of the DMC catalysts and continuously removing the resulting DMC catalyst from the reactor.
  • the invention thus relates to a continuous process for the preparation of DMC catalysts, characterized in that the solutions of a metal salt and a HexacyanometallatENS and optionally organic ligands and / or organic additives are fed kontinuier ⁇ Lich in a continuous reactor and the resulting Suspension of the DMC compound is taken from the Re ⁇ actuator continuously.
  • the invention furthermore relates to the DMC catalysts prepared by the process according to the invention and to their use for the preparation of polyether alcohols.
  • tubular reactors and preferably continuous stirred tank reactors can be used.
  • the resulting DMC catalyst suspension is continuously taken from the reactor. This can, in the case of using a continuous stirred tank as Reactor, for example, by a level control, coupled with a Boden ⁇ valve, a continuous withdrawal via a pump or an overflow be ensured tet.
  • the average residence time in the reactor is preferably in the range between 1 and 180 minutes
  • the temperature in the reactor is preferably between 10.. and 8O 0 C, particularly preferably between 15 and 60 0 C, in particular between 20 and 50 0 C.
  • DMC catalysts with a high catalytic activity are obtained.
  • a device for comminuting the particles formed can follow the course of the suspension from the reactor.
  • a Nassro ⁇ tormühle be used. This leads to a more uniform distribution of the particle size in the suspension.
  • the suspension of the DMC compound is usually supplied to a wash, filtration, redispersion and optionally drying. These work-up steps can also be operated continuously. However, it is also possible to collect the suspension in intermediate containers and to deliver them batchwise to the said work-up steps.
  • the washing can be done either with water only, with an organic ligand or any mixtures of both.
  • drying of the DMC catalysts is performed, this is done preferred wise at a temperature in the range between 20 and 150 0 C, in particular be- see 30 and 10O 0 C and a pressure between 0.01 bar and 1 bar, in particular Zvi ⁇ rule 0.05 bar and 0.7 bar.
  • DMC catalysts prepared by the process according to the invention may have a different crystal structure, depending on the educts and auxiliaries used and the conditions of preparation.
  • the DMC catalysts may have a crystalline or an amorphous structure.
  • Crystalline DMC catalysts are described, for example, in WO 99/16775, amorphous DMC catalysts for example, described in EP 654 302.
  • the catalysts may also be partially crystalline, that is, they contain both crystalline and amorphous portions.
  • crystalline DMC catalysts those having a monoclinic crystal structure are particularly preferred.
  • the DMC catalysts prepared by the process according to the invention have a platelet-like form, as described, for example, in WO 00/74845.
  • the DMC catalysts prepared by the process according to the invention usually have the general formula (I)
  • M 1 is a metal ion selected from the group consisting of Zn 2+ , Fe 2+ , Fe 3+ , Co 2+ , Co 3+ , Ni 2+ , Mn 2+ , Sn 2+ , Sn 4+ , Pb 2+ , Mo 4+ , Mo 6+ , Al 3+ , V 4+ , V 5+ , Sr 2+ , W 4+ , W 6+ , Cr 2+ , Cr 3+ , Cd 2+ , Cu 2+ , La 3+ , Ce 3+ , Ce 4+ , Eu 3+ , Mg 2+ , Ti 3+ , Ti 4+ , Ag + , Rh 2+ , Ru 2+ , Ru 3+ , Pd 2+
  • M 2 is a metal ion selected from the group consisting of Fe 2+ , Fe 3+ , Co 2+ , Co 3+ , Mn 2+ , Mn 3+ , Ni 2+ V 4+ , V 5+ , Cr 2+ , Cr 3+ , Rh 3+ , Ru 2+ , Ir 3+
  • A is an anion selected from the group containing halide, hydroxide, sulfate, hydrogensulfate, carbonate, bicarbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate, nitrate, nitrosyl, phosphate, hydrogen phosphate or dihydrogen phosphate
  • X is an anion selected from the group comprising halide, hydroxide, sulfate, hydrogensulfate, carbonate, bicarbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate, nitrate or nitrite (NO 2 " ) and the uncharged species CO , H 2 O and NO,
  • L is a water-miscible ligand selected from the group comprising alcohols, aldehydes, ketones, ethers, polyethers, esters, polyesters, polycarbonate, ureas, amides, nitriles, and sulfides or mixtures thereof,
  • P is an organic additive selected from the group comprising polyethers, polyesters, polycarbonates, polyalkylene glycol sorbitan esters, polyalkylene glycol glycides polyether, polyacrylamide, poly (acrylamide-co-acrylic acid), polyacrylic acid, poly (acrylamide-co-maleic acid), polyacrylonitrile, polyalkyl acrylates, polyalkyl methacrylates, polyvinyl methyl ether, polyvinyl ethyl ether, polyvinyl acetate, polyvinyl alcohol, poly-N-vinylpyrrolidone, Poly (N-vinylpyrrolidone-co-acrylic acid), polyvinyl methyl ketone, poly (4-vinylphenol), poly (acrylic acid-co-styrene), oxazoline polymers, polyalkyleneimines, maleic acid and maleic anhydride copolymer, hydroxyethylcellulose, polyacetates, ionic surfaces and surface-active compounds,
  • a, b, d, q and n are integers or fractions greater than zero
  • c, f, e, h and k are integers or fractions greater than or equal to zero
  • a, b, c, and d, and q and n are selected so that the electroneutrality is ensured.
  • these catalysts may be crystalline or amorphous.
  • k is zero
  • crystalline double metal cyanide compounds are preferred.
  • k is greater than zero
  • both crystalline, partially crystalline, and substantially amorphous catalysts are preferred.
  • DMC catalysts of the general formula (I) prepared by the process according to the invention are those in which k is greater than zero.
  • This DMC catalyst contains at least one multimetal cyanide compound, at least one organic ligand and at least one organic additive P.
  • k is zero, optionally e is also zero, and X is exclusively carboxylate, preferably formate, acetate and propionate.
  • crystalline double metal cyanide catalysts are preferred.
  • M 1 are Zn 2+ , Fe 2+ , Co 2+ , Fe 3+ , Mn 2+ .
  • Preferred examples of M 2 are Fe 2+ , Fe 3+ , Co 2+ , Co 3+ , Ir 3+ .
  • Preferred examples of A are halide and carboxylate, especially acetate.
  • At least one surfactant may be used in the preparation of the DMC catalysts.
  • The- It is not incorporated into the catalyst and almost completely removed from the catalyst by washing the catalyst.
  • the DMC catalysts prepared in this way have an improved morphology.
  • organic sulfones of the general formula RS (O) 2 -R or sulfoxides of the general formula RS (O) -R are organic Complexing agent L used.
  • the advantages of this embodiment are short induction times and moderate exotherm in the preparation of the polyether alcohols.
  • the reaction is carried out at a pH of> 1, preferably> 4, more preferably> 7. These conditions produce crystalline DMC catalysts with a monoclinic crystal structure.
  • f, e and k are equal to zero.
  • DMC catalysts which contain a water-miscible organic ligand, preferably in amounts of from 0.5 to 30% by weight, and an organic additive, preferably in amounts of from 5 to 80% by weight.
  • organic additive preferably in amounts of from 5 to 80% by weight.
  • the catalysts can be used in a stirred tank with vigorous stirring, for example with a Turrax ®, prepared as described for example in US 5,158,922.
  • the DMC compounds prepared by the process according to the invention were ⁇ most, as described, used as catalysts for the addition of alkylene oxides to H-functional starter substances.
  • the products thus obtained can be used as surfactants, carrier oils or as polyether alcohols for the preparation of polyurethanes.
  • alkylene oxides it is possible to use all known alkylene oxides, for example ethylene oxide, propylene oxide, butylene oxide, styrene oxide.
  • alkoxide oxides used are ethylene oxide, propylene oxide and mixtures of the compounds mentioned.
  • polyether alcohols for use as raw materials for polyurethane production are used as starting substances, in particular polyfunctional alcohols and as alkylene oxides, preferably ethylene oxide and / or propylene oxide.
  • H-functional compounds are used.
  • alcohols having a functionality of 1 to 8, preferably 2 to 8, are used.
  • Alcohols having a functionality of 2 to 4, in particular 2 and 3, are preferably used as starting substances for the preparation of polyether alcohols which are employed for flexible polyurethane foams. Examples are ethylene glycol, propylene glycol, glycerol, trimethylolpropane, pentaerythritol.
  • alkylene oxides by means of DMC catalysts, it is advantageous to use together with or in place of the alcohols mentioned their reaction products with alkylene oxides, in particular propylene oxide.
  • alkylene oxides in particular propylene oxide.
  • Such compounds preferably have a molecular weight of up to 500 g / mol.
  • the addition of the alkylene oxides in the preparation of these reaction products can be carried out with any catalysts, for example with basic catalysts.
  • the polyether alcohols for the production of flexible polyurethane foams usually have a hydroxyl number in the range between 20 and 100 mg KOH / g.
  • the addition of the alkylene oxides in the preparation of the polyether alcohols used for the process according to the invention can be carried out by the known processes.
  • the polyether alcohols contain only one alkylene oxide.
  • a so-called block-wise addition in which the alkylene oxides are added one after the other in succession, or a so-called statistical addition in which the alkylene oxides are added together is possible. It is also possible to incorporate both blockwise and random sections into the polyether chain in the preparation of the polyether alcohols.
  • the mixture of starting substance and DMC catalyst can be pretreated by stripping prior to the beginning of the alkoxylation according to the teaching of WO 98/52689.
  • the polyether alcohol is usually worked up by customary processes by removing the unreacted alkylene oxides and volatile constituents, usually by distillation, steam or gas stripping and or other methods of deodorization. If necessary, filtration can also be carried out.
  • the catalyst can be separated off from the reaction mixture.
  • the preparation of the polyether alcohols can also be carried out continuously. Such a procedure is described for example in WO 98/03571 or in JP H6-16806. In this process, alkylene oxides and starting substance are continuously metered into a continuous reactor and the resulting polyether alcohol is taken off continuously.
  • polyether alcohols prepared using DMC catalysts are generally used for the production of flexible polyurethane foams by reaction with polyisocyanates.
  • the DMC catalysts prepared by the process according to the invention have no disadvantages in their properties over other catalysts prepared by the conventional batch process.
  • the expense in the production of the DMC catalysts can be significantly reduced.
  • the DMC catalysts prepared by the process according to the invention have the same properties.
  • Solution 1 consisted of an aqueous zinc acetate solution (2.6% zinc), Solution 2 of an aqueous solution of potassium hexacyanocobaltate with 0.9% cobalt.
  • Solution 1 at 7.91 kg / h and solution 2 at 10 kg / h were metered through a mixing nozzle into a 3 liter stirred tank. Both solutions contained 2 wt .-% of a surfactant (Pluronic PE6200 ® of BASF AG). After filling the stirred tank, the feed was stopped and the present DMC suspension stirred at a temperature of 20 0 C in the stirred tank and an energy input by stirring 1 W / l for 1 h. Subsequently, the catalyst was filtered off, washed with water and dried at 6O 0 C.
  • a surfactant Pluronic PE6200 ® of BASF AG
  • Solution 1 consisted of an aqueous zinc acetate solution (2.6% zinc), Solution 2 of an aqueous solution of potassium hexacyanocobaltate with 0.9% cobalt.
  • Solution 1 at 7.91 kg / h and solution 2 at 10 kg / h were metered continuously through a mixing nozzle into a 3 liter stirred tank. Both solutions contained 2 wt .-% of a surface-active agent (Pluronic ® PE6200 BASF AG).
  • the present DMC suspension was at a temperature of 20 0 C in a stirred tank and an energy input by stirring 1 W / l glallstandsge- regulates via a bottom drain valve continuously drained. The average residence time in the stirred tank was 10 min. To ensure the steady state, the experiment was carried out over 10 mean residence times. Subsequently, the catalyst was filtered off, washed with water and dried at 6O 0 C.
  • Solution 1 consisted of an aqueous zinc acetate solution (2.6% zinc), Solution 2 of an aqueous solution of potassium hexacyanocobaltate with 0.9% cobalt.
  • Solution 1 at 3.95 kg / h and solution 2 at 5 kg / h were metered continuously via inlet tubes into a 3 liter stirred vessel. Both solutions contained 2 wt .-% of a devis perenniali ⁇ ven agent (Pluronic ® PE6200 BASF AG).
  • the present DMC suspension was continuously discharged at a temperature of 35 ° C in a stirred tank and an energy input by stirring of 1 W / l Medstandsge ⁇ regulated via a bottom drain valve. The average residence time in the stirred tank was 20 min. To ensure the steady state, the experiment was carried out over 10 mean residence times. Subsequently, the catalyst was filtered off, washed with water and dried at 60 0 C.
  • Example 1 100 8 8,6bar / 165 ° C
  • Example 2 100 7 8,9bar / 175 ° C
  • Example 3 100 10 8,4bar / 169 ° C
  • the catalytic activity of the DMC catalysts prepared by the process according to the invention is comparable to that of conventional DMC catalysts.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Health & Medical Sciences (AREA)
  • Polyethers (AREA)
  • Catalysts (AREA)

Abstract

Procédé de production en continu de catalyseurs DMC, caractérisé en ce que les solutions d'un sel métallique et d'un composé hexacyanométallate, ainsi éventuellement que de ligands organiques et / ou d'additifs organiques, sont introduites en continu dans un réacteur continu et en ce que la suspension du composé DMC ainsi obtenue est prélevée en continu du réacteur.
EP05789181A 2004-10-05 2005-09-28 Procédé de production en continu de catalyseurs dmc Withdrawn EP1799344A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004048735A DE102004048735A1 (de) 2004-10-05 2004-10-05 Verfahren zur kontinuierlichen Herstellung von DMC-Katalysatoren
PCT/EP2005/010492 WO2006037541A2 (fr) 2004-10-05 2005-09-28 Procédé de production en continu de catalyseurs dmc

Publications (1)

Publication Number Publication Date
EP1799344A2 true EP1799344A2 (fr) 2007-06-27

Family

ID=35355931

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05789181A Withdrawn EP1799344A2 (fr) 2004-10-05 2005-09-28 Procédé de production en continu de catalyseurs dmc

Country Status (8)

Country Link
US (1) US20080071117A1 (fr)
EP (1) EP1799344A2 (fr)
JP (1) JP4954077B2 (fr)
KR (1) KR20070063557A (fr)
CN (1) CN101035617A (fr)
DE (1) DE102004048735A1 (fr)
MX (1) MX2007003684A (fr)
WO (1) WO2006037541A2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011047780A1 (fr) 2009-10-19 2011-04-28 Basf Se Conditionnement de catalyseurs cyanures métalliques doubles
WO2011160797A1 (fr) 2010-06-23 2011-12-29 Basf Se Catalyseurs modifiés de type double cyanure métallique (dmc), procédé de synthèse par traitement d'un catalyseur de type dmc cristallin par un acide de brønsted et leurs applications

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG177717A1 (en) 2009-08-13 2012-02-28 Basf Se Process for preparing multimetal cyanide compounds

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US3278458A (en) * 1963-02-14 1966-10-11 Gen Tire & Rubber Co Method of making a polyether using a double metal cyanide complex compound
JP2884614B2 (ja) * 1989-09-01 1999-04-19 旭硝子株式会社 複合金属シアン化物錯体触媒の製造方法
JP2570903B2 (ja) * 1990-11-27 1997-01-16 旭硝子株式会社 複合金属シアン化物錯体触媒の製造法
US5158922A (en) * 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
US5891818A (en) * 1997-07-31 1999-04-06 Arco Chemical Technology, L.P. Cyanide complex catalyst manufacturing process
US6800583B2 (en) * 1999-06-02 2004-10-05 Basf Aktiengesellschaft Suspension of multimetal cyanide compounds, their preparation and their use
DE19958355A1 (de) * 1999-12-03 2001-06-07 Bayer Ag Verfahren zur Herstellung von DMC-Katalysatoren
CA2446970C (fr) * 2001-05-10 2012-09-25 Akzo Nobel Nv Procede continu et appareil de conversion efficiente de particules solides inorganiques
DE10228254A1 (de) * 2002-06-24 2004-01-22 Basf Ag Verfahren zur Herstellung von Polyetheralkoholen
JP4556496B2 (ja) * 2003-06-04 2010-10-06 旭硝子株式会社 複合金属シアン化物錯体触媒、その製造方法およびその利用

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011047780A1 (fr) 2009-10-19 2011-04-28 Basf Se Conditionnement de catalyseurs cyanures métalliques doubles
US9114380B2 (en) 2009-10-19 2015-08-25 Basf Se Conditioning of double metal cyanide catalysts
WO2011160797A1 (fr) 2010-06-23 2011-12-29 Basf Se Catalyseurs modifiés de type double cyanure métallique (dmc), procédé de synthèse par traitement d'un catalyseur de type dmc cristallin par un acide de brønsted et leurs applications

Also Published As

Publication number Publication date
KR20070063557A (ko) 2007-06-19
MX2007003684A (es) 2007-05-21
JP2008515617A (ja) 2008-05-15
WO2006037541A3 (fr) 2006-06-15
US20080071117A1 (en) 2008-03-20
WO2006037541A2 (fr) 2006-04-13
CN101035617A (zh) 2007-09-12
JP4954077B2 (ja) 2012-06-13
DE102004048735A1 (de) 2006-04-27

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