EP1749040B1 - Wasserverdünnbare polyesterharzzusammensetzungen mit gemischter ionisch/nichtionischer stabilisierung - Google Patents

Wasserverdünnbare polyesterharzzusammensetzungen mit gemischter ionisch/nichtionischer stabilisierung Download PDF

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Publication number
EP1749040B1
EP1749040B1 EP20050749522 EP05749522A EP1749040B1 EP 1749040 B1 EP1749040 B1 EP 1749040B1 EP 20050749522 EP20050749522 EP 20050749522 EP 05749522 A EP05749522 A EP 05749522A EP 1749040 B1 EP1749040 B1 EP 1749040B1
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Prior art keywords
resin
polyester resin
weight
acid
aqueous
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EP20050749522
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English (en)
French (fr)
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EP1749040A1 (de
Inventor
Walter C. Meyer
Peter W. Uhlianuk
Robert G. Von Berge
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EIDP Inc
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EI Du Pont de Nemours and Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C09D167/025—Polyesters derived from dicarboxylic acids and dihydroxy compounds containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C08K5/19—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/50—Aqueous dispersion, e.g. containing polymers with a glass transition temperature (Tg) above 20°C
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]

Definitions

  • the present invention is directed to aqueous coating compositions comprising water reducible polyester resin, particularly water soluble or dispersible polyester resin having mixed ionic and nonionic stabilization prepared by random condensation polymerization.
  • Aqueous or waterborne coating compositions are widely used to coat automobiles and trucks as these compositions generally meet stringent environmental regulations.
  • Exemplary of prior patents disclosing such coatings are U.S. Pat. Nos. 4,403,003 and 4,539,363 , both issued to Backhouse.
  • these coatings contain a latex as the main film forming component, a crosslinking agent, additives, and pigments.
  • Other non-latex resins are also oftentimes added to improve adhesion and chip resistance of the coating. Polyester resins are especially helpful when employed for adhesion and chip properties, but can have several drawbacks.
  • Polyesters stabilized with nonionic polyalkylene glycol segments alone have also been tried.
  • the presence of nonionic constituents in a finish formed from such an aqueous coating composition containing the same tend to cause defects such as water spotting and poor resistance to humidity.
  • US 2002/0013404 A1 discloses a branched, low acid number hydroxyl-functional polyester resin comprising a reaction product of a polyalkylene glycol monoalkyl ether having a number average molecular weight of 500 to 3000, polycarboxylic acid and polyhydric alcohol. Together with organic hydrophobic polyisocyanate crosslinker the polyester resin can be used as a binder composition of an aqueous coating composition.
  • the present invention is directed to an aqueous coating composition, useful for coating a substrate, which composition comprises an aqueous carrier comprising at least 40% water and a film-forming binder, wherein said binder contains at least one water reducible polyester resin having mixed ionic and nonionic stabilization, wherein said polyester resin is the reaction product of
  • the invention claims an article coated with a dried and cured layer containing an aqueous coating composition of this invention.
  • Water reducible means the material is soluble in water or is dispersible in water after neutralization.
  • GPC weight average (Mw) or GPC number average (Mn) molecular weight means Mw and Mn molecular weights of resins obtained by using gel permeation chromatography utilizing polystyrene as the standard and tetrahydrofuran as the carrier solvent.
  • Water miscible solvents are those solvents that are completely or substantially soluble in water.
  • Low acid number is defined as an acid number in the range from 2 to 30 (mg KOH / g resin solids), as determined by typical analytical techniques.
  • Latex or “latex resin” refers to a dispersion of a water-insoluble resin which may be prepared by conventional polymerization techniques such as, for example, by emulsion polymerization.
  • Crosslinkable and crosslinking refer to the formation of new chemical bonds between existing polymer chains, and “curing” refers to the crosslinking resins after application to the substrate.
  • conventional polymerization process means any polymerization process or reaction which predominantly gives a random resin or polymer.
  • the present invention is directed to aqueous coating compositions comprising an aqueous carrier, and film-forming binder containing a low acid number mixed ionic / nonionic stabilized polyester resin.
  • the polyester resins may be successfully prepared by conventional polymerization processes. In one embodiment, a single step polymerization process is used.
  • the polyester resins are prepared by conventional condensation polymerization techniques using diols, triols and higher polyhydric alcohols known in the art with conventional polycarboxylic acids or anhydrides thereof, in various proportions.
  • polyethylene glycol monoalkyl ether is also added with the forgoing monomers.
  • the preferred approach of making the polyester resin involves simultaneously adding a polyethylene glycol monoalkyl ether with the other monomers at the beginning of the polymerization process, thus making possible a single step conventional polymerization process. Polymerization is continued until the desired acid number and molecular weight are reached. This is a simpler approach than the common two step practice where a polyester resin is prepared in a first step, followed by second reaction step with a chain extending monomer, such as trimellitic anhydride, to achieve desired molecular weight properties.
  • polycarboxylic acids examples include, but are not limited to, aromatic, aliphatic, and cycloaliphatic carboxylic acids, such as 1,4-cyclohexane dicarboxylic acid, 1,3-cyclohexane dicarboxylic acid, hexahydro-4-methylphthalic acid; tetrahydrophthalic acid, phthalic acid, isophthalic acid, terephthalic acid, trimellitic acid, adipic acid, azelaic acid, sebasic acid, succinic acid, maleic acid, glutaric acid, malonic acid, pimelic acid, suberic acid, fumaric acid, itaconic acid, and the like.
  • Anhydrides of the above acids, where they exist can also be employed and are encompassed by the term "polycarboxylic acids".
  • the diols, triols, and higher polyhydric alcohols are generally known. Examples include trimethylolpropane, trimethylolethane, tris(hydroxyethyl) isocyanurate, glycerine, and pentaerythritol, and dihydric alcohols or diols such as neopentyl glycol, dimethylol hydantoin, ethylene glycol, propylene glycol, 1,4-butylene glycol, diethylene glycol, dipropylene glycol, 1,4- cyclohexane dimethanol, Esterdiol 204 (trademark of Union Carbide), 1,3- propane diol, 1,6-hexanediol, dimethylol propionic acid, and the like.
  • dihydric alcohols or diols such as neopentyl glycol, dimethylol hydantoin, ethylene glycol, propylene glycol, 1,4-butylene glycol,
  • the polyester resin contains from 1 to 25% by weight of a polyethylene glycol monoalkyl ether component with a number average molecular weight from 300 to 800, from 40 to 65 % by weight of an acid functional monomer, or mixture of acid functional monomers, and from 35 to 60% by weight of a hydroxy functional monomer, or mixture of hydroxy functional monomers.
  • the resultant polyester resins are characterized by a number average molecular weight from 1,000 to 10,000, an acid number in the range from 2 to 30 (mg KOH / g resin solids), preferably from 3 to 20, and a hydroxyl number of 50 to 200 (mg KOH/g resin solids), preferably from 65 to 130, which after neutralizing with an amine or an inorganic base such as ammonium hydroxide or sodium hydroxide, are dispersible in water.
  • a particularly useful low acid number water dispersible polyester resin composition has a monomer content of 29.9 / 10.5 / 8.7 / 10.0 / 10.0 / 30.9 parts by weight of neopentyl glycol / trimethylol propane / methoxy polyethylene glycol (Carbowax® MethoxyPEG 550 from Dow Chemical Corp.) / isophthalic acid / phthalic anhydride / adipic acid, reduced to a resin solids of 80% in a 1:1 weight ratio of n-butanol and dipropylene glycol methyl ether solvents.
  • polyester resins are useful to produce aqueous coatings by blending with other suitable components in accordance with paint formulation techniques known to those skilled in the art. It has been found that improved aqueous or waterborne coating systems are obtained by using these polyesters in combination with other binder components, preferably a latex resin and a crosslinking resin.
  • typically available amines that can be used to fully or partially neutralize the acid functional groups include AMP (2-amino-2-methyl-1-propanol), dimethyl-AMP, amino methyl propanol, amino ethyl propanol, dimethyl ethanol amine, triethylamine and the like.
  • a preferred amine is AMP.
  • the aqueous coating compositions of this invention are preferably pigmented basecoat containing solid color pigments or metallic or pearl flake pigments or mixtures thereof over which a variety of clearcoats, such as water or organic solvent based or powder clearcoats, can be applied.
  • the coating composition depending on the presence of pigments also can be used as a primer, primer surfacer, monocoat, and/or clearcoat.
  • the coating composition can be applied with conventional spray equipment and dried at ambient or slightly elevated temperatures.
  • the resulting finish has excellent adhesion to other coating layers and chip resistance which are desirable properties for automotive finishes.
  • the resulting finish also offers a significant improvement over conventionally used aqueous automotive finishes in terms of appearance such as metallic glamour and spray solids (low solvent).
  • the aqueous coatings of the present invention contain a latex of an acrylic-based resin, otherwise known as an acrylic microgel dispersion (as described in Backhouse U.S. Patent 4,403,003 issued Sep. 6, 1983 and Backhouse U.S. Patent 4,539,363 issued Sep. 3, 1985 ).
  • acrylic lattices are commercially available from Avecia, Rohm & Haas and others, for example Neocryl® latex (Neoresins Division of Avecia, Wilmington, MA, Wilmington, DE). These lattices are stable dispersions in water, typically as a dispersed latex resin, with an average particle size diameter of 10 nm to I micron, preferably 20 to 400 nm.
  • the coating compositions contain 10-70%, more typically 15-40% by weight of binder, and 30-90%, more typically 60-85% by weight, of an aqueous carrier.
  • the carrier is at least 50% water, and in one embodiment, 75 to 95% water.
  • a curable coating composition which will crosslink under elevated baking temperatures of 60-180°C for 5-60 minutes, there may be comprised 10 to 40%, preferably 15 to 30% by weight, based on the weight of the binder, of a water-soluble or water dispersible alkylated melamine formaldehyde crosslinking resin, or mixture of resins, wherein the alkyl groups contains 1-4 carbon atoms on the alkylated group.
  • a water-soluble or water dispersible alkylated melamine formaldehyde crosslinking resin or mixture of resins, wherein the alkyl groups contains 1-4 carbon atoms on the alkylated group.
  • Monomeric or polymeric alkylated melamine formaldehyde crosslinking resin may be used.
  • a particularly useful melamine formaldehyde crosslinking resin is CYMEL® 303, a monomeric methylated melamine available from Cytec Industries.
  • the coating compositions containing alkylated melamine formaldehyde crosslinking resins preferably contain from 0.1 to 2.0%, based on the weight of binder, of a strong acid catalyst, or amine salt thereof.
  • Organic sulfonic acids, or the amine salts thereof are preferred catalysts:
  • a particularly useful catalyst is amino-methyl propanol blocked dodecyl benzyl sulfonic acid, available as NACURE® 5225 from King Industries.
  • Phosphoric acid, and salts thereof, are also effective catalysts.
  • the aqueous coatings of this invention may contain color-giving and/or effect-giving pigments and, optionally, fillers.
  • color-giving inorganic or organic pigments and fillers are titanium dioxide, micronized titanium dioxide, iron oxide pigments, carbon black, -azo pigments, phthalocyanine pigments, quinacridone pigments, pyrrolopyrrole pigments, perylene pigments.
  • filler pigments particularly useful for primers are silicon dioxide, barium sulfate, micronized mica, talcum, kaolin, chalk, layered silicates, and the like.
  • effect-giving pigments are metal pigments, for example flakes of aluminum, copper or other metals, interference pigments, such as, for example, metal-oxide-coated metal pigments, for example titanium- dioxide-coated aluminum, coated mica or pearl flakes, such as, for example, titanium-dioxide-coated mica, graphite effect pigments, plate-like iron oxide, plate-like copper phthalocyanine pigments.
  • metal pigments for example flakes of aluminum, copper or other metals
  • interference pigments such as, for example, metal-oxide-coated metal pigments, for example titanium- dioxide-coated aluminum, coated mica or pearl flakes, such as, for example, titanium-dioxide-coated mica, graphite effect pigments, plate-like iron oxide, plate-like copper phthalocyanine pigments.
  • Effect pigments are generally used in the form of a commercial aqueous or non-aqueous paste, organic solvents and additives, preferably water-dilutable organic solvents and additives, are optionally added thereto, and the whole is then mixed with aqueous binder, with shearing. Powdered effect pigments may first be processed with preferably water-dilutable organic solvents and additives to form a paste.
  • Color-giving pigments and/or fillers may be milled, for example, in a portion of the aqueous binder. Milling may preferably also take place in a special water-dilutable paste resin. Milling may be carried out in conventional units known to those skilled in the art. The remainder of the aqueous binder or of the aqueous paste resin is then added to produce the finished coloring pigment mill base.
  • the aqueous coatings of the invention may contain further additives in amounts conventionally employed in the art, for example from 0.1 to 5 wt. %, based on the weight of the binder.
  • further additives are neutralizing agents, antifoaming agents, wetting agents, adhesion- promoting substances, catalysts, flow agents such as fumed silica or sheet silicate particles, anti-pitting agents, ultraviolet light stabilizers and thickeners such as, for example, synthetic resins having groups that are ionic and/or have an associative action, such as poly(meth)acrylamide, poly(meth)acrylic acid, hydrophobically modified ethoxylated polyurethanes or polyacrylates, crosslinked or uncrosslinked polymer microparticles, alkali swellable emulsions (such as Acrysol® ASE-60 from Rohm & Haas Co., and the like), and clay materials (such as the Bentone® materials available Elementis Specialties, and the like).
  • aqueous coatings of this invention also typically contain organic solvents in the aqueous carrier to facilitate atomization and spray application, as well as coalescence of the applied paint particles.
  • suitable solvents are those which are at least partially water-miscible, such as, but not limited to, mono- or polyhydric alcohols (for example iso-propanol, n-propanol, n-butanol, hexanol, and the like) glycol ethers (for example diethylene glycol alkyl ether, dipropylene glycol alkyl ether, each having alkyl residues comprising one to six carbon atoms, ethoxypropanol, butyl glycol, and the like), N-alkylpyrrolidones (for example N-methylpyrrolidone and the like), propylene glycol ethers or esters (for example propylene glycol dimethyl ether, dipropylene glycol mono- or di-C 1 -C 6 -alkyl
  • the coating compositions of this invention can be used to provide coatings on suitable substrates such as wood and reconstituted wood products, concrete, asphalt, fiber cement, stone, marble, clay, glass, plastics (for example, polystyrene, polyethylene, ABS, polyurethane, polyethylene terphthalate, polybutylene terphthalate, polypropylene, polyphenylene, polycarbonate, polyacrylate, PVC, NORYL®, and polysulfone), paper, cardboard, and metal (ferrous as well as non-ferrous).
  • suitable substrates such as wood and reconstituted wood products, concrete, asphalt, fiber cement, stone, marble, clay, glass, plastics (for example, polystyrene, polyethylene, ABS, polyurethane, polyethylene terphthalate, polybutylene terphthalate, polypropylene, polyphenylene, polycarbonate, polyacrylate, PVC, NORYL®, and polysulfone), paper, cardboard, and metal (ferrous as well as non-ferrous).
  • Coating compositions of this invention have excellent properties when applied over variety of metallic or non-metallic substrates, either alone, or in conjunction with other coating materials.
  • the coating compositions are applied over primed substrates.
  • Other substrates include, but are not limited to, previously topcoated substrates, cold rolled steel, phosphatized steel, and steel coated with conventional primers by electrodeposition.
  • the coating compositions may be used as pigmented monocoats, as clear coats, as the pigmented base coat of a clear coat/base coat or as both the clear coat and the base coat.
  • the coating compositions of this invention are particularly useful in forming metallic glamour finishes.
  • Coating compositions of this invention can be applied by conventional techniques such as rotary bell application, pneumatic air spraying, electrostatic spraying, dipping, brushing, flowcoating and the like.
  • the preferred techniques are spraying and electrostatic spraying in one or more operations.
  • the basecoat composition is applied to form a coating 2.5-76.2 ⁇ m (0.1-3.0 mils) thick and then dried to a tack-free state, preferably flash dried for a short period before the clearcoat is applied thereon.
  • the basecoat/clearcoat finish is then typically baked at 60 - 150°C for 15 to 30 minutes.
  • the present invention is also applicable to non-baking, or low baking, refinish systems, as will be readily apparent by those skilled in the art.
  • the customary technique used to apply the clearcoat over the basecoat by means of a "wet-on-wet" application wherein the clearcoat is applied to the basecoat without curing the basecoat.
  • the coated substrate is then heated for a predetermined time period to allow simultaneous curing of the base and clearcoats.
  • Application over water-bome basecoat normally prefers some degree of dehydration of the basecoat by exposure to ambient or heated air before application of the clearcoat.
  • Dehydration according to the invention is important in order that the finished two-layer coating meets the demands made both of the technological properties, such as, for example, adhesion and resistance to the impact of stones, and of the optical properties, such as, for example, color shade, the development of special effects, and the appearance.
  • the substrate is typically flashed again and finally baked until the film is cured, or at least partially cured, at 100-150°C for 15-30 minutes to produce the coated article.
  • the basecoat and clearcoat are preferably deposited to have thicknesses of 2.5-63.5 ⁇ m (0.1-2.5 mils) and 25.4-76.2 ⁇ m (1.0-3.0 mils), respectively.
  • aqueous acrylic latex resin was prepared as illustrated in the following example. Constituents were charged into a polymerization vessel equipped with a stirrer, a heat source, a thermometer, a reflux condenser and a nitrogen inlet and polymerizing under a nitrogen atmosphere: Ingredients Parts by Weight Portion 1 Water 26.62 Ammonium Alkyphenoxy Polyethoxysulfate (RHODAPEX ® CO-436 from Rhodia Inc.) 0.21 Portion 2 Ammonium Alkyphenoxy Polyethoxysulfate 0.17 Allyl Methacrylate 0.44 Water 10.51 Methyl Methacrylate 2.43 n-Butyl Acrylate 11.72 Portion 3 Water 1.61 Ammonium Alkyphenoxy Polyethoxysulfate 0.05 Portion 4 Ammonium Alkyphenoxy Polyethoxysulfate 0.18 Allyl Methacrylate 0.36 Water 10.49 Methyl Methacrylate 6.46 n-Butyl Acrylate 5.21 Portion 5 Ammonium Alky
  • Portion I constituents were charged to the polymerization vessel, heated to 83.3°C (182°F), and held at temperature.
  • Portion 2 constituents were premixed thoroughly, and slowly added to portion 1 over a 90 minute period, while maintaining a temperature of 83.3°C (182°F). The resultant solution was then held at temperature for 20 minutes.
  • Portion 3 constituents were then premixed and added to the vessel.
  • Portion 4 constituents were then premixed for 45 minutes, fed into the polymerization vessel at a temperature of 83.3°C (182°F) over a 60 minute period, and then held at temperature for 60 minutes.
  • Portion 5 constituents were thoroughly premixed and added to the polymerization vessel at a temperature of 83.3°C (182°F) over a 60 minute period, and then held at temperature for 60 minutes.
  • Portion 6 constituents were premixed and added to the vessel to adjust pH to 8.3 to 8.7.
  • the resultant aqueous acrylic latex resin had a measured weight percent solids of 35%, and pH of 8.5.
  • a mixed ionic / nonionic stabilized polyester resin was prepared as illustrated in the following example.
  • the above resin was then cooled to 100°C, and the following solvents were added to thin the resin: Dipropylene Glycol Methyl Ether Solvent (DOWANOL ® DPM from Dow Chemical Corp.) 84.7 n-Butanol Solvent 84.7
  • the resultant polyester resin had a viscosity of Z2 on the Gardner Holdt scale, and measured weight percent solids of 80%.
  • a block copolymer used to produce pigment dispersions was prepared as illustrated in the following example.
  • 0.6 ml of a 1.0 M solution of a catalyst of tetrabutyl ammonium m-chlorobenzoate in acetonitrile were added.
  • 32.5 g of a 0,140 M solution of an initiator of 1,1-bis(trimethylsiloxy)-2-methyl propene were injected into the flask.
  • Feed 1 of 0.6 ml of a 1.0 M solution of tetrabutyl ammonium m-chlorobenzoate in acetonitrile was started and added over 200 minutes.
  • Feed U trimethylsilyl methacrylate, 265.0 g (1.67 M), butyl methacrylate, 298.0 g (2.10 M), methyl methacrylate, 140.0 g (1.40 M), and trimethylsiloxyethyl methacrylate, 141.0 g (0.70 M) was started at 0.0 minutes and added over a 45 minute period.
  • Feed III (benzyl methacrylate, 616.0 g (3.46 M), and dimethyl amino ethyl methacrylate, 154.0 g (0.980 M) was started and added over 30 minutes.
  • 150 g methanol was added to the resulting reaction mixture to quench the reaction and deblock the hydroxy and acid monomers and solvent distillation was started.
  • 400.0 g of solvent were removed.
  • 100.0 g of methanol were added and an additional 200.0 g of solvent were distilled off.
  • the resulting polymer solution had a 50% solids content and the polymer had the following composition benzyl methacrylate/dimethyl amino ethyl methacrylate//butyl methacrylate/methyl methacrylate/hydroxy ethyl methacrylate/methacrylic acid in a weight ratio of 25/15//15/101//5/12 and a number average molecular weight of 10,300.
  • a carbon black pigment dispersion was prepared by using a conventional high speed media mill to disperse the above described carbon black pigment in the above prepared block copolymer which is neutralized with AMP-95.
  • the resulting carbon black pigment dispersion had the following composition and had a solids content of 20.5%: Ingredients Parts by Weight De-ionized water 67.90 Surfactan t(SURFYNOL ® 104 from Air Products & Chem icals) 0.30 Carbon black pigment (Columbian 5000 Ultra II Powder) 10.00 Block copolymer from Example 3 0.00 2-Amino-Methyl Propanol (AMP ® -95 from Angus Chemical Co.) 1.80
  • a white pigment dispersion was prepared in the following example.
  • MMA methyl methacrylate
  • BA butyl acrylate
  • AA acrylic acid
  • 2-MERE mercapto ethanol
  • An aqueous aluminum flake slurry was prepared in the following example.
  • mineral spirits ISOPAR H solvent from Exxon-Mobil Co.
  • 14.6 parts by weight butyl cellosolve 15.8 parts by weight aluminum paste
  • SSP-572 from Silberline Mfg. Co. Inc.
  • 3.6 parts by weight of a known passivator Librizol® 2062 from Lubrizol Corp.
  • AMP- 95 2-Amino Methyl Propanol
  • aqueous basecoats examples were applied at conventional film builds (15.2-25.4 ⁇ m, 0.6 to 1.0 mils) over previously primed commercially available e-coated test panels.
  • the basecoated panels were dehydrated in a pre-bake, and then clearcoated with 45.7-55.9 pm (1.8 to 2.2 mils) of a commercially available solventborne one-component etch resistant clearcoat (DuPont Generation® IVESW).
  • the composite basecoat/clearcoat coatings were then baked for 30 minutes at 129.4°C (265°F).
  • the resultant cured basecoat/clearcoated panels were tested for such film properties as gravelometer chip resistance per test method SAE J400, 20° gloss before and after humidity exposure, DOI as measured with a Hunter Dorigon DOI meter before and after humidity exposure, and adhesion before and after humidity exposure.
  • Humidity exposure conditions were 96 hours at 37.8°C (100°F) and 100% relative humidity.
  • the dry initial adhesion (dry hatch) and wet adhesion after humidity, using the X-hatch test method, were both evaluated based upon a rating system from 0 (no adhesion) to 10 (perfect adhesion).
  • Results are summarized as follows: Test Method Coating Example 1 Black Aqueous Basecoat Coating Example 2 White Aqueous Basecoat Coating Example 3 Silver Aqueous Basecoat Chip resistance 5B 6B 5B 20° Gloss before humidity 88 89 92 after humidity 86 86 90 DOI before humidity 92 93 88 after humidity 92 94 89 X-Hatch Adhesion before humidity 10 10 10 after humidity 10 10 10 Blistering before humidity None None None after humidity None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None

Claims (8)

  1. Wäßrige Beschichtungszusammensetzung, verwendbar zum Beschichten eines Substrats, wobei die Zusammensetzung einen wäßrigen Träger mit mindestens 40% Wasser und ein filmbildendes Bindemittel aufweist, wobei das Bindemittel mindestens ein durch Wasser reduzierbares Polyesterharz mit gemischter ionischer und nichtionischer Stabilisierung enthält, wobei das Polyesterharz das Reaktionsprodukt der folgenden Komponenten ist:
    (a) 1 bis 25 Gew.-% eines Polyethylenglycolmonoalkylethers mit einem zahlengemittelten Molekulargewicht von weniger als 1200;
    (b) 40 bis 65 Gew.-% einer oder mehrerer Polycarbonsäuren;
    (c) 35 bis 60 Gew.-% einer oder mehrerer mehrwertiger Alkohole; und
    wobei das Polyesterharz eine Säurezahl von 2 bis 30 (mg KOH/g Harzfeststoffe) aufweist, und wobei das filmbildende Bindemittel ferner ein Latexharz auf Acrylbasis und ein alkyliertes Melaminformaldehyd-Harz aufweist.
  2. Wäßrige Beschichtungszusammensetzung nach Anspruch 1, wobei der Polyethylenglycolmonoalkylether des Polyesterharzes ein Polyethylenglycolmonomethylether mit einem zahlengemittelten Molekulargewicht von 300 bis 800 ist.
  3. Wäßrige Beschichtungszusammensetzung nach Anspruch 1, wobei das alkylierte Melaminformaldehyd-Harz ein monomeres methyliertes Melaminformaldehyd-Harz ist.
  4. Wäßrige Beschichtungszusammensetzung nach Anspruch 1, die ferner einen organischen Säurehärter aufweist.
  5. Wäßrige Beschichtungszusammensetzung nach Anspruch 4, wobei der Säurehärter eine organische Sulfonsäure oder ein Aminsalz davon ist.
  6. Wäßrige Beschichtungszusammensetzung nach Anspruch 5, wobei der Säurehärter ein Aminsalz von Dodecylbenzylsulfonsäure ist.
  7. Gegenstand, der mit einer getrockneten und gehärteten Schicht der Zusammensetzung nach Anspruch 1 beschichtet ist.
  8. Fertigprodukt, hergestellt aus dem beschichteten Gegenstand nach Anspruch 7.
EP20050749522 2004-05-15 2005-05-11 Wasserverdünnbare polyesterharzzusammensetzungen mit gemischter ionisch/nichtionischer stabilisierung Active EP1749040B1 (de)

Applications Claiming Priority (2)

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US10/845,701 US20050255330A1 (en) 2004-05-15 2004-05-15 Water reducible polyester resin compositions with mixed ionic / nonionic stabilization
PCT/US2005/016587 WO2005116109A1 (en) 2004-05-15 2005-05-11 Water reducible polyester resin compositions with mixed ionic/nonionic stabilization

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EP1749040A1 EP1749040A1 (de) 2007-02-07
EP1749040B1 true EP1749040B1 (de) 2010-03-31

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CA (1) CA2561371A1 (de)
DE (1) DE602005020273D1 (de)
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US20050255330A1 (en) 2005-11-17
CA2561371A1 (en) 2005-12-08
EP1749040A1 (de) 2007-02-07
JP2007538118A (ja) 2007-12-27
DE602005020273D1 (de) 2010-05-12
WO2005116109A1 (en) 2005-12-08
TW200617058A (en) 2006-06-01
BRPI0510872A (pt) 2007-12-26

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