EP1722985B1 - Papier decoratif a fibres presentant une charge electrique - Google Patents

Papier decoratif a fibres presentant une charge electrique Download PDF

Info

Publication number
EP1722985B1
EP1722985B1 EP04821683.2A EP04821683A EP1722985B1 EP 1722985 B1 EP1722985 B1 EP 1722985B1 EP 04821683 A EP04821683 A EP 04821683A EP 1722985 B1 EP1722985 B1 EP 1722985B1
Authority
EP
European Patent Office
Prior art keywords
paper
fibers
resin
abrasion resistant
resistant particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP04821683.2A
Other languages
German (de)
English (en)
Other versions
EP1722985A2 (fr
Inventor
Dieter DÖHRING
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lignum Technologies AG
Original Assignee
Kronoplus Technical AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kronoplus Technical AG filed Critical Kronoplus Technical AG
Priority to PL04821683T priority Critical patent/PL1722985T3/pl
Publication of EP1722985A2 publication Critical patent/EP1722985A2/fr
Application granted granted Critical
Publication of EP1722985B1 publication Critical patent/EP1722985B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0469—Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper
    • B44C5/0476—Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper with abrasion resistant properties
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
    • D21H27/26—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
    • D21H27/28—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures treated to obtain specific resistance properties, e.g. against wear or weather
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10—Organic non-cellulose fibres
    • D21H13/20—Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/24—Polyesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter

Definitions

  • the invention relates to a method and an apparatus for the production of a paper having an abrasion-resistant surface and to a paper produced according to the method.
  • the US 4,940,503 discloses a method in which abrasion resistant particles are optionally sprinkled onto a melamine resin impregnated overlay or onto a melamine resin impregnated decor paper. Overlay and decorative paper are then pressed together so that a decorative paper with abrasion-resistant surface results.
  • the abrasion resistance that can be achieved with such a process is relatively low compared to other processes. It must be made separately an overlay, so a paper.
  • the WO 00/44984 A1 discloses a method in which a special dispersion containing abrasion resistant particles such as corundum or silicon carbide is sprayed onto a decorative paper.
  • the decorative paper is in turn used in the manufacture of a laminate floor panel.
  • this method it is indeed possible to achieve high abrasion values.
  • the expenditure on equipment is comparatively high in comparison to the scattering of abrasion-resistant particles.
  • the abrasion-resistant particles applied to the decorative paper to protect a press are covered with an overlay, for example, to produce panels for a laminate floor or worktop with an abrasion-resistant surface.
  • the WO 00/44576 A1 discloses another method in which abrasion-resistant particles such as corundum are scattered on the impregnated decor paper. Subsequently, fibers are applied together with resin and the layer system is pressed. In this way If a separate production of decorative paper should be avoided. However, it is problematic to provide in this way a protective layer that comes close to the positive properties of an overlay paper. The above-mentioned problems are solved by the subject-matter of the independent claims of the present invention. It is an object of the invention to provide an abrasion-resistant paper with improved properties.
  • the object is achieved by a method in which abrasion-resistant particles are applied to a paper. Subsequently, fibers are electrostatically charged. When loaded, the fibers are applied to the paper. In this way, it is relatively easy to bring fibers arranged on the paper. The fibers are then completely or predominantly perpendicular to the paper. A regular distribution of the fibers can be achieved. This results in a paper in which abrasion-resistant particles are applied to the surface. Furthermore, on the side with the abrasion-resistant particles, perpendicular fibers are located on the paper surface.
  • a scattering roller In order to apply the fibers to the paper in the electrically charged state, for example, a scattering roller is provided, which is supplied with electrical charge.
  • the scattering roller has recesses on its surface into which the fibers pass.
  • the recesses preferably have an irregular shape and are distributed irregularly on the surface of the roller.
  • the fibers are brought from above onto the spreader roll.
  • the scattering roller is preferably made of electrically non-conductive material such as plastic or rubber, so as to be able to bring electric charge from the roller to the fibers, rotates the roller, so eventually the fibers fall from the roller. Below the roller, the paper with the abrasion-resistant particles is then passed over. The fibers thus fall on the paper and stand up vertically.
  • the perpendicular fibers lay over the abrasion-resistant particles.
  • the press is so reliably protected from damage.
  • such a press is used as a press in which pressing is effected by means of circulating belts or rollers.
  • the paper enters the press together with plates from one side.
  • the vertical fibers are then bent uniformly in one direction. This results in a uniform, protective surface.
  • the paper compressed with a plate is moved out of the press at a different location.
  • the paper-provided plate has an abrasion-resistant surface.
  • the product thus produced can now serve as a worktop. If necessary, the plate is sawn into individual elements having a predetermined, desired size.
  • the individual elements can now be provided laterally with coupling elements, so as to provide panels for a floor covering.
  • the paper is usually provided with a decor, for this purpose, the paper may be printed with a pattern.
  • the abrasion-resistant particles are then located on the decor, ie on the printed surface.
  • the paper is brought into the press with the plate so that the decor is visible.
  • the material of the fibers is then chosen so that this practically does not prevent the view of the decor.
  • the fibers can be made of polyester. On the one hand, it is possible to apply electrical charge to the fibers. On the other hand, a decor remains visible through these fibers.
  • polyester has the desired properties for the aforementioned purpose. Disadvantageously, this material is relatively expensive.
  • cotton linters are therefore preferably used. These are very short fibers that are produced and extracted from cotton and can not be spun. This waste product can also be electrically charged. It can be provided a transparent protective layer, so that a decor of an underlying paper remains visible.
  • the length of the fibers can be at half a millimeter. However, the fibers can be two to four millimeters long.
  • an additional roller which is provided with bristles, is provided laterally next to the spreading roller. This bristled roller also rotates, brushing the fibers out of the recesses of the spreader roller.
  • a squeegee acts on the spreader roll in an embodiment that retains excess spilled fiber. It thus reaches the predetermined amount of fibers on the paper.
  • funnels are preferably provided laterally of the paper in order to be able to collect excess fibers and to be able to feed them back to the scattering roller, etc. This recycling saves costs.
  • Paper-applied or applied electrically-charged fibers are provided in one embodiment with a resin, preferably with melamine resin, so as to provide further desired surface properties. Desirable is regularly insensitivity to staining and chemical resistance, also protects melamine resin the surface particularly good against moisture.
  • the abrasion-resistant particles are sprayed onto the paper together with resin,
  • a method is basically from the WO 00/44984 A1 known.
  • the paper is previously advantageously impregnated with a resin, in particular with a melamine resin or a mixture of a melamine resin and a urea resin so as to improve the adhesion of the abrasion-resistant particles to the paper.
  • excess resin is returned to the container in which the abrasion-resistant particles are with the resin.
  • the recycling of the resin saves on the one hand costs, but more important is that the return of the resin creates a flow in the container. This flow contributes to keeping the abrasion-resistant particles in suspension, thus ensuring an improved uniform distribution of the particles in the resin. In this way, even relatively large abrasion-resistant particles can be processed.
  • the abrasion-resistant particles have been sprayed onto the paper together with the resin, this is advantageously dried in one embodiment of the invention.
  • this By drying one molecule enlargement, namely a polycondensation is achieved, so it creates a first layer on the paper, Now if electrically charged fibers are applied to this first layer, so the fibers can not penetrate into this first layer, would the fibers in this penetrate first layer, they are so far no longer available for the desired protection of a press.
  • the pre-drying thus contributes to the fact that the fibers develop the desired protective effect.
  • abrasion-resistant particles are sprinkled on impregnated decor paper in an alternative advantageous embodiment.
  • the abrasion-resistant particles are coated with a bonding agent prior to spreading in order to achieve good abrasion values.
  • electrically charged fibers are placed on the decorative paper.
  • the paper is suitably impregnated with a resin, preferably with the aid of metering rollers.
  • the impregnation can be carried out with a doctor blade. With the help of the resin or by the impregnation abrasion-resistant particles are fixed on the paper.
  • the particles provided with the adhesion promoter are preferably dried before being sprinkled.
  • the abrasion-resistant particles are first dipped for this purpose in a liquid, the Alternatively, the abrasion-resistant particles are sprayed with the primer, this is still less expensive compared to the effort, which according to the WO 00/44984 A1 to operate, since it does not have to be paid attention to dosage and circulation. Subsequently, the particles are dried and are now particularly suitable for use.
  • the dried, provided with a primer abrasion-resistant particles are sprinkled on the paper, and in particular on a decorative paper.
  • a roller is used for the spreading, which is provided with recesses, which in particular run unevenly, the depth of the recesses, however, is substantially maintained.
  • the provided with the adhesion promoter abrasion-resistant particles are scattered from above the roller and thus get into the wells. Excess material, that is to say excess, abrasion-resistant particles provided with an adhesion promoter, is stripped off by means of a doctor blade. Subsequently, the rotating roll passes to a brush, which removes the abrasion-resistant particles provided with a bonding agent.
  • the brush is preferably a circulating roller provided with bristles so as to uniformly sweep out the particles provided with an adhesive.
  • the abrasion-resistant particles are scattered uniformly on the decor paper, preferably with an amount of 18 to 25 g / m 2 , depending on the desired abrasion class, the grain size is preferably 90 to 130 ⁇ m in diameter. If the diameter chosen smaller, so a relatively large amount of abrasion-resistant particles is consumed together with adhesion promoter. If the diameter is chosen to be larger, the abrasion-resistant particles may damage the press despite a protective layer of fibers.
  • the respective webs are passed in an advantageous embodiment, in particular by a melamine resin or a mixture containing melamine resin.
  • a melamine resin or a mixture containing melamine resin By means of the adhesion promoter it is possible to incorporate the abrasion-resistant particles, for example corundum particles or silicon carbide, into the resin matrix. Otherwise, an optically visible interface between the abrasion-resistant particles and the resin or the resin matrix may remain, resulting in graying. If no adhesion promoter is used, the abrasion-resistant particles can be torn out of the matrix, which leads to low abrasion values.
  • the surface temperature during the pressing is preferably 180 to 185 ° C.
  • pressures typically 20 to 35 bar are used.
  • the specified temperature is advantageous for the resin material to harden. Said pressure is advantageous in order to keep the water which contains the layer system in liquid form. Otherwise it would escape in gaseous form and thereby produce a rough surface.
  • the high pressure also ensures a very homogeneous surface.
  • the decorative paper has a mass of 20 to 60 g / m 2 , so as to be able to manage with small amounts of resin.
  • the decorative paper is advantageously filled with acrylate or an acrylate-containing dispersion so as to be able to further reduce the amount of relatively expensive melamine resin required for the impregnation.
  • the acrylate or the dispersion is pressed into the decorative paper, in particular from both sides, so as to ensure that it passes into the interior of the paper.
  • WO 02/079 571 A1 discloses suitable compositions and a method for bringing the acrylate or, for the purposes of the present invention, the dispersion into the interior of the paper,
  • funnels are preferably provided laterally of the paper in order to be able to absorb excess abrasion-resistant particles. This catfish succeeds in recycling the abrasion-resistant particles, as far as they have been scattered laterally in excess.
  • corundum or aluminum oxide particles to be scattered are provided with an adhesion promoter, since materials such as silicon carbide can be installed relatively easily in a resin matrix anyway.
  • Silicon carbide however, has the disadvantage over corundum or aluminum oxide that it is dark particles, which are clearly visible especially in bright decors. As a rule, silicon carbide is therefore less suitable for optical reasons.
  • melamine resin and mixed resins can be used.
  • a mixed resin may consist of 70 to 80% by weight of urea resin and 20 to 30% by weight of melamine resin so as to lower the cost of the resin
  • decorative paper is preferably impregnated with a mixed resin because it can save costs
  • the result is a decorative paper, in which corundum lies in a plane. when abrasion-resistant particles have been sprinkled on the paper. This can be determined with the microscope, In addition, the then advantageously provided adhesion promoter can be found in the finished product, which wraps the abrasion-resistant particles,
  • adhesion promoters on a silane-based because these primers are particularly well suited to adhere on the one hand on the corundum or alumina and on the other hand with the resins used to bring about the desired adhesion and thus the desired abrasion resistance,
  • Abrasion-resistant particles 1 of corundum having a diameter of 90 to 130 ⁇ m were coated with a silane coupling agent and dried, the abrasion-resistant particles 1 are now in a free-flowing condition and are scattered onto a roll 2 as the FIG. 1 clarified in cross-section.
  • the roller 2 has recesses not shown on the surface. By the slow rotation of the roller 2 in the counterclockwise direction along the arrow 3, the scattered particles reach a squeegee 4, which bears against the roller 2 with an open end. The squeegee 4 ensures that the abrasion-resistant particles 1 uniformly and completely Fill wells.
  • the abrasion-resistant particles to a fast-rotating brush 5 on transported which rotates in the example in the clockwise direction in the direction of arrow 6.
  • the abrasion-resistant particles are thus completely removed from the depressions and thus arrive dosed on the surface of a decorative paper 7.
  • the decorative paper 7 is guided by means of suitably rotating rollers 8 and 9 below the roller.
  • the decorative paper 7 was impregnated immediately before with a mixture of 25 wt .-% melamine resin and 74 wt .-% urea resin.
  • the decorative paper has a basis weight of 30 g / m 2 and inside acrylate.
  • the resin application during impregnation is 15 g per square meter of paper.
  • the abrasion-resistant particles 1 adjoin to the side with the printed decor.
  • fibers 10 which may be impregnated with a melamine resin, as previously scattered the abrasion-resistant particles 1 on the decorative paper.
  • a device that in FIG. 1 comprises components shown.
  • the components involved in this process step such as roller, brush and squeegee then consist of electrically non-conductive materials such as rubber or plastic,
  • the involved components such as roller, squeegee and / or brush are additionally charged with electrical charge, this has the consequence that When the fibers are brushed out of the waltz to be electrostatically charged, the fibers are accelerated towards the paper.
  • the repulsive effect causes the fibers to be evenly distributed on the paper. They align parallel to each other and are substantially perpendicular to the paper.
  • a relatively large amount of resin is preferably used when applying the abrasion-resistant particles in comparison to the application of the particles by spraying especially when fibers are applied that have not been provided with a resin.
  • Based on the basis weight of the paper in the dry (raw) state typically 100 to 250% by weight are applied when spraying the mixture containing the resin and the abrasion-resistant particles.
  • the amount of resin in an embodiment of the invention becomes therefore chosen so that the dry paper is provided with a layer whose weight is 2 to 2.5 times or even more,
  • the paper When the electrically charged fibers 10 have been applied to the paper, the paper is desirably dried. It is such a paper ready, which is provided on the one hand with abrasion-resistant particles and which is on the other hand prepared to be used in a press. In the FIG. 2 the basic structure is shown.
  • the decorative paper 12 thus provided with an abrasion-resistant layer is then pressed, for example at pressures of 30 bar and temperatures of 180 ° C., with a base plate 13 made of HDF and a backing paper 14.
  • the hitherto completely or predominantly substantially vertically projecting fibers lie over the abrasion-resistant particles 1.
  • a press is thus protected from damage by the abrasion-resistant particles.
  • panels of the desired size of typically 20 to 40 cm in width and a length of typically 80 cm to 160 cm are sawed out and laterally provided with coupling means such as groove 15 or spring 16.
  • coupling means such as groove 15 or spring 16.
  • tongue and groove have further locking means, not shown, which can positively connect two panels with each other so that there is a locking parallel to the surface of the panels.
  • Such locks are for example from the WO 02/079 571 A1 known.
  • the countertraction paper has in particular a low basis weight of 20 to 60 g / m 2 and is preferably provided with acrylate and impregnated with a urea resin or a mixture containing predominantly urea resin prior to compression. In this way, the cost of applying the Schmidts is minimized because comparatively little and also relatively inexpensive resin is used.
  • the countertape paper protects a panel or countertop, etc. from distortion,

Landscapes

  • Laminated Bodies (AREA)
  • Paper (AREA)
  • Floor Finish (AREA)

Claims (13)

  1. Procédé de fabrication de papier avec revêtement résistant à l'abrasion et avec des fibres qui sont appliquées sur ou contre le revêtement résistant à l'abrasion, dans lequel des particules résistantes à l'abrasion (1) sont appliquées sur un papier conjointement avec de la résine (11), caractérisé en ce que les fibres (10) sont chargées électriquement et sont appliquées sur la couche constituée de particules résistantes à l'abrasion et de la résine (11).
  2. Procédé selon la revendication précédente, dans lequel le papier muni des fibres (10) est finalement séché.
  3. Procédé selon une des deux revendications précédentes, dans lequel un mélange de résine (11) et de particules résistantes à l'abrasion est pulvérisé sur le papier, et de la résine (11) excédentaire est ramenée du papier au réservoir dans lequel se trouvent les particules résistantes à l'abrasion avec la résine, à la suite de la pulvérisation et avant l'application de fibres le papier avec la couche appliquée étant de préférence séché.
  4. Procédé selon une des revendications précédentes, dans lequel le papier est imprégné de résine (11), et les particules résistantes à l'abrasion (1) sont munies d'un agent adhésif et répandues.
  5. Dispositif pour réaliser un procédé de fabrication d'un papier à surface résistante à l'abrasion selon une des revendications précédentes, comportant des moyens qui sont caractérisés en ce qu'il permettent de charger les fibres et d'appliquer les fibres chargées sur le papier, comprenant un rouleau rotatif (2) pourvu de creux et une brosse (5) qui se trouve latéralement à côté du rouleau et qui est disposée de façon que les creux puissent être brossés, ainsi que des moyens permettant de charger électriquement le rouleau et/ou la brosse, ainsi que des rouleaux rotatifs (8, 9) permettant de faire défiler un lé de papier (7) sous le rouleau (2) pourvu de creux.
  6. Dispositif selon la revendication précédente, caractérisé par des moyens pour répandre des particules résistantes à l'abrasion sur le papier, comprenant en particulier un rouleau rotatif supplémentaire (2) pourvu de creux et une brosse supplémentaire (5) qui se trouve latéralement à côté du rouleau supplémentaire et qui est disposée de façon que les creux puissent être brossés, ainsi que des moyens (8, 9, 8', 9') permettant de faire défiler un lé de papier sous le rouleau supplémentaire.
  7. Papier avec revêtement résistant à l'abrasion, constitué de particules résistantes à l'abrasion (1) et de résine (11), et avec des fibres (10) qui sont appliquée sur ou contre le revêtement résistant à l'abrasion, réalisable selon un procédé selon une des revendications 1à 4, les fibres (10) étant disposées perpendiculairement à la surface du papier (7) dans ou sur la couche résistante à l'abrasion, caractérisé en ce que les fibres (10) sont constituées de polyester et/ou de coton, et/ou du linter de coton est mis en oeuvre comme fibres (10).
  8. Papier selon la revendication précédente, caractérisé en ce que les particules résistantes à l'abrasion (1) sont enrobées d'un agent adhésif.
  9. Papier selon une des revendications précédentes 7 à 8, caractérisé en ce que les particules résistantes à l'abrasion (1) présentent un diamètre de 50 à 200 µm, de préférence de 90 à 13 µm.
  10. Papier selon une des revendications précédentes 7 à 9, caractérisé en ce que les particules résistantes à l'abrasion (1) sont enrobées d'un agent adhésif au silane, de préférence d'un agent adhésif à l'aminosilane.
  11. Papier selon une des revendications précédentes 7 à 10, caractérisé en ce que les particules résistantes à l'abrasion (1) sont constituées d'oxyde d'aluminium, selon une préférence particulière de corindon.
  12. Papier (7) selon une des revendications précédentes 7 à 11, lequel possède un grammage de 10 à 60 g/m2, selon une préférence particulière de 20 à 40 g/m2, l'intérieur du papier (7) étant rempli de préférence d'acrylate ou d'une dispersion contenant de l'acrylate.
  13. Papier (7) selon une des revendications précédentes 7 à 12, lequel est imprégné d'un mélange de résines qui contient une résine aminée ainsi qu'une autre résine, à savoir, en particulier, une résine d'urée, et qui est muni d'un décor, le papier avec les fibres (10) étant appliqué sur une plaque, un papier de contre-traction étant disposé de préférence sous la plaque.
EP04821683.2A 2004-02-25 2004-11-19 Papier decoratif a fibres presentant une charge electrique Active EP1722985B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL04821683T PL1722985T3 (pl) 2004-02-25 2004-11-19 Papier dekoracyjny zawierający elektrycznie naładowane włókna

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE202004003061U DE202004003061U1 (de) 2004-02-25 2004-02-25 Dekorpapier mit elektrisch geladenen Fasern
PCT/EP2004/053016 WO2005080096A2 (fr) 2004-02-25 2004-11-19 Papier decoratif a fibres presentant une charge electrique

Publications (2)

Publication Number Publication Date
EP1722985A2 EP1722985A2 (fr) 2006-11-22
EP1722985B1 true EP1722985B1 (fr) 2018-02-07

Family

ID=34802053

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04821683.2A Active EP1722985B1 (fr) 2004-02-25 2004-11-19 Papier decoratif a fibres presentant une charge electrique

Country Status (7)

Country Link
US (1) US7682668B2 (fr)
EP (1) EP1722985B1 (fr)
CN (1) CN1946572B (fr)
DE (1) DE202004003061U1 (fr)
PL (1) PL1722985T3 (fr)
RU (1) RU2337836C2 (fr)
WO (1) WO2005080096A2 (fr)

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1937476B1 (fr) * 2005-10-10 2016-01-13 Kronoplus Technical AG Plaques resistant a l'usure comprenant une surface decorative
DE102007025135B3 (de) * 2007-05-30 2009-02-05 Flooring Technologies Ltd. Holzwerkstoffplatte und Verfahren zur Herstellung
EP2212071B8 (fr) 2007-11-19 2013-07-17 Välinge Innovation AB Recyclage de revêtements de sol stratifiés
US9783996B2 (en) 2007-11-19 2017-10-10 Valinge Innovation Ab Fibre based panels with a wear resistance surface
NZ586169A (en) 2007-11-19 2012-06-29 Ceraloc Innovation Belgium Fibre based building panel with a surface layer comprising three horiztonal planes ofaluminium oxide particles
EP2106903A1 (fr) 2008-02-22 2009-10-07 Hermes Schleifkörper GmbH Procédé de répartition de matières premières à friction réduite et procédé correspondant
ES2693125T3 (es) * 2008-04-07 2018-12-07 Välinge Innovation AB Método de fabricación de un tablero de suelo basado en fibra de madera
US8419877B2 (en) 2008-04-07 2013-04-16 Ceraloc Innovation Belgium Bvba Wood fibre based panels with a thin surface layer
US11235565B2 (en) 2008-04-07 2022-02-01 Valinge Innovation Ab Wood fibre based panels with a thin surface layer
CN101998896B (zh) * 2008-04-07 2014-12-10 瓦林格创新股份有限公司 具有薄的表面层的基于木质纤维的镶板
DE102008057262B4 (de) * 2008-11-13 2012-12-13 Flooring Technologies Ltd. Verfahren zum Herstellen eines Holzwerkstoff-Paneels aus einer Holzwerkstoffplatte mit einer Verschleißschicht und Holzwerkstoff-Paneel
US20100221493A1 (en) * 2008-11-21 2010-09-02 Mats Hintze Use of silane-treated particles in laminates to improve clarity
DE102009014638A1 (de) * 2009-03-24 2010-09-30 Clariant International Ltd. Laminate enthaltend harte, plattenförmige Mineralien
DK2264259T3 (da) * 2009-06-17 2013-08-26 Vaelinge Innovation Ab Panel, anvendelse af et panel, fremgangsmåde til fremstilling af et panel og et prepreg
EP2272667B1 (fr) * 2009-07-06 2020-02-26 Välinge Innovation AB Plaque en matière dérivée du bois et son procédé de fabrication
PL2272668T3 (pl) * 2009-07-09 2016-11-30 Płyta z tworzywa drzewnego z równomierną warstwą wierzchnią i sposób jej wytwarzania
WO2011087423A1 (fr) * 2010-01-15 2011-07-21 Ceraloc Innovation Belgium Bvba Panneaux à base de fibres munis d'une surface résistant à l'usure décorative
JP5840624B2 (ja) 2010-01-15 2016-01-06 ベーリンゲ、イノベイション、アクチボラグＶａｅｌｉｎｇｅ Ｉｎｎｏｖａｔｉｏｎ Ａｂ 明色表面層
WO2011087424A1 (fr) 2010-01-15 2011-07-21 Ceraloc Innovation Belgium Bvba Configuration générée par chaleur et pression
US8349234B2 (en) 2010-01-15 2013-01-08 Ceraloc Innovation Belgium Bvba Fibre based panels with a decorative wear resistance surface
FI20105048A (fi) * 2010-01-21 2011-07-22 Runtech Systems Oy Menetelmä radiaalikompressorin juoksupyörän valmistamiseksi
US10899166B2 (en) 2010-04-13 2021-01-26 Valinge Innovation Ab Digitally injected designs in powder surfaces
US8480841B2 (en) 2010-04-13 2013-07-09 Ceralog Innovation Belgium BVBA Powder overlay
US10315219B2 (en) 2010-05-31 2019-06-11 Valinge Innovation Ab Method of manufacturing a panel
DE102010051902A1 (de) * 2010-11-22 2012-05-24 Guido Schulte Verfahren zur optischen Gestaltung eines Boden-, Wand- oder Deckenpaneels sowie Boden-, Wand- oder Deckenpaneel
ES2805332T3 (es) 2011-04-12 2021-02-11 Vaelinge Innovation Ab Método de fabricación de un panel de construcción
EP2697065B1 (fr) 2011-04-12 2016-12-07 Välinge Innovation AB Mélange pulvérulent et procédé de fabrication d'un panneau de construction
CN103459165B (zh) 2011-04-12 2017-02-15 瓦林格创新股份有限公司 生产层的方法
CN103459145B (zh) 2011-04-12 2016-06-29 瓦林格创新股份有限公司 基于粉末的平衡层
CN109016042B (zh) 2011-08-26 2021-12-24 塞拉洛克创新股份有限公司 用于生产层压制品的方法
US8920876B2 (en) 2012-03-19 2014-12-30 Valinge Innovation Ab Method for producing a building panel
US8993049B2 (en) 2012-08-09 2015-03-31 Valinge Flooring Technology Ab Single layer scattering of powder surfaces
US20140199495A1 (en) 2013-01-11 2014-07-17 Floor Iptech Ab Digital printing and embossing
US9181698B2 (en) 2013-01-11 2015-11-10 Valinge Innovation Ab Method of producing a building panel and a building panel
UA118967C2 (uk) 2013-07-02 2019-04-10 Велінге Інновейшн Аб Спосіб виготовлення будівельної панелі і будівельна панель
CN105612062A (zh) 2013-10-18 2016-05-25 瓦林格创新股份有限公司 建筑镶板的制造方法
DE102013113109A1 (de) 2013-11-27 2015-06-11 Guido Schulte Fußbodendiele
DE102013113130B4 (de) 2013-11-27 2022-01-27 Välinge Innovation AB Verfahren zur Herstellung einer Fußbodendiele
DE102013113125A1 (de) 2013-11-27 2015-05-28 Guido Schulte Fußboden-, Wand- oder Deckenpaneel und Verfahren zu dessen Herstellung
WO2015105456A1 (fr) 2014-01-10 2015-07-16 Välinge Innovation AB Procédé de production d'un élément plaqué
MX2016012477A (es) 2014-03-31 2017-05-04 Ceraloc Innovation Ab Tablas y paneles compuestos.
RU2687440C2 (ru) 2014-05-12 2019-05-13 Велинге Инновейшн Аб Способ изготовления элемента, покрытого шпоном, и такой элемент, покрытый шпоном
US11313123B2 (en) 2015-06-16 2022-04-26 Valinge Innovation Ab Method of forming a building panel or surface element and such a building panel and surface element
JP6457696B2 (ja) 2015-07-23 2019-01-23 アンスティテュ・キュリＩｎｓｔｉｔｕｔ Ｃｕｒｉｅ 癌を処置するためのＤｂａｉｔ分子とＰＡＲＰインヒビターとの組合せの使用
GB201519573D0 (en) 2015-11-05 2015-12-23 King S College London Combination
EP3882021A1 (fr) 2016-04-25 2021-09-22 Välinge Innovation AB Élément plaqué et procédé de fabrication d'un tel élément plaqué
WO2018162439A1 (fr) 2017-03-08 2018-09-13 Onxeo Nouveau biomarqueur prédictif de la sensibilité à un traitement du cancer avec une molécule dbait
WO2019139523A1 (fr) 2018-01-11 2019-07-18 Välinge Innovation AB Procédé de fabrication d'un élément plaqué et élément plaqué
WO2019139522A1 (fr) 2018-01-11 2019-07-18 Välinge Innovation AB Procédé de fabrication d'un élément plaqué et élément plaqué
CN108376593A (zh) * 2018-01-23 2018-08-07 安徽天康创新科技有限公司 一种线缆护套阻燃耐磨处理工艺
CA3092779A1 (fr) 2018-03-13 2019-09-19 Onxeo Molecule dbait contre la resistance acquise dans le traitement du cancer
CN113260506A (zh) 2019-01-09 2021-08-13 瓦林格创新股份有限公司 生产单板元件的方法和单板元件
WO2021148581A1 (fr) 2020-01-22 2021-07-29 Onxeo Nouvelle molécule dbait et son utilisation

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4473613A (en) * 1983-03-15 1984-09-25 Formica Corp. Decorative laminate
CN1044965A (zh) * 1989-02-16 1990-08-29 天津市木材四厂 超薄半硬塑料贴面片
JPH0815779B2 (ja) * 1991-07-31 1996-02-21 株式会社興人 微細点描調化粧板
FR2713249B1 (fr) * 1993-12-02 1996-01-19 Arjo Wiggins Sa Feuille papetière pour stratifiés résistant à l'abrasion.
DE19508797C1 (de) * 1995-03-15 1996-08-29 Graudenz & Partner Consultatio Verfahren zur Herstellung von Dekorpapier zur Verwendung bei der Herstellung von abriebfesten Laminaten
EP0872591B1 (fr) * 1997-04-16 2005-12-14 IDI-Head OY Procédé d'enduction de feuilles cellulosiques et lignocellulosiques
FI105052B (fi) * 1998-07-08 2000-05-31 Valmet Corp Menetelmä paperin valmistamiseksi, sovitelma menetelmän toteuttamiseksi ja menetelmän avulla valmistettu paperituote
PT1270811E (pt) 1999-01-26 2004-04-30 Kronospan Tech Co Ltd Processo para impregnar papeis decorativos
WO2000044576A1 (fr) * 1999-01-26 2000-08-03 Kronospan Technical Company Ltd. Procede de realisation de recouvrements stratifie, et recouvrement stratifie
US6517674B1 (en) * 2000-02-02 2003-02-11 The Mead Corporation Process for manufacturing wear resistant paper
CN100342080C (zh) * 2001-03-30 2007-10-10 克劳诺斯潘技术有限公司 用于制造镶板的纸张及其相应的制造方法

Also Published As

Publication number Publication date
PL1722985T3 (pl) 2018-07-31
WO2005080096A3 (fr) 2005-10-06
CN1946572B (zh) 2012-01-11
WO2005080096A2 (fr) 2005-09-01
RU2006129800A (ru) 2008-03-27
US7682668B2 (en) 2010-03-23
CN1946572A (zh) 2007-04-11
DE202004003061U1 (de) 2005-07-14
EP1722985A2 (fr) 2006-11-22
US20070184244A1 (en) 2007-08-09
RU2337836C2 (ru) 2008-11-10

Similar Documents

Publication Publication Date Title
EP1722985B1 (fr) Papier decoratif a fibres presentant une charge electrique
EP1634995B1 (fr) Imprégné et procédé pour sa production
EP1068083B1 (fr) Procede de realisation de recouvrements stratifie, et recouvrement stratifie
EP0732449B1 (fr) Procédé de fabrication de papier décor pour l'usage pendant la production des laminés résistant à l'abrasion
DE69824865T2 (de) Gerät zum verteilen von teilchen auf papier und verfahren zum herstellen von papier mit teilchen
DE102005006599B4 (de) Holzwerkstoffplatte mit einer mindestens abschnittweise aufgetragenen Oberflächenbeschichtung
EP1678261B1 (fr) Papier decoratif a corindon saupoudre et enduit d'un adhesif
EP1997623A1 (fr) Plaque en bois et procédé de fabrication
EP1961556A1 (fr) Matière première composée, panneau comprenant une telle matière première composée, procédé de fabrication de telles matières premières composées et de tels panneaux
DE202005015978U1 (de) Abriebfeste Platten mit dekorativer Oberfläche
EP1274594B1 (fr) Papier decoratif et procede pour impregner un papier decoratif
DE202009018018U1 (de) Ein Substrat mit zumindest einem Dekorpapier oder Overlay
AT405265B (de) Dekorlaminat und verfahren zu seiner herstellung
EP1272707A1 (fr) Papier permettant la realisation de panneaux, et procede de production de papier
DE10161093B4 (de) Kratz- und abriebfeste Dekorfolie und Verfahren zu deren Herstellung
EP3707007B1 (fr) Procédé de fabrication d'un panneau résistant à l'usure au matériau dérivé du bois et ligne de production correspondante
DE19604907B4 (de) Verfahren zur Herstellung von hoch-abriebfesten Deckschichten
DE102008057262B4 (de) Verfahren zum Herstellen eines Holzwerkstoff-Paneels aus einer Holzwerkstoffplatte mit einer Verschleißschicht und Holzwerkstoff-Paneel
DE69807776T2 (de) Verfahren zur kontinuierlichen Herstellung von Vliesstoff enthaltende Wandbeläge und so hergestellte Wandbeläge
EP4094848B1 (fr) Procede de fabrication d'un stratifie resistant a l'abrasion
EP2331642B1 (fr) Panneau, en particulier panneau de plancher
EP3181315B1 (fr) Procede de fabrication d'un panneau osb presentant une surface lisse
DE102007010483B4 (de) Verfahren zur Herstellung eines Paneels mit Kern und Dekorpapier

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20060925

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LU MC NL PL PT RO SE SI SK TR

DAX Request for extension of the european patent (deleted)
19U Interruption of proceedings before grant

Effective date: 20071221

19W Proceedings resumed before grant after interruption of proceedings

Effective date: 20090731

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: KRONOPLUS TECHNICAL AG

17Q First examination report despatched

Effective date: 20151013

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20171108

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

REG Reference to a national code

Ref country code: DE

Ref legal event code: R081

Ref document number: 502004015645

Country of ref document: DE

Owner name: XYLO TECHNOLOGIES AG, CH

Free format text: FORMER OWNER: KRONOSPAN TECHNICAL CO. LTD., NIKOSIA, CY

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LU MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 968624

Country of ref document: AT

Kind code of ref document: T

Effective date: 20180215

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502004015645

Country of ref document: DE

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20180207

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180207

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180207

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180207

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180207

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180607

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180508

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180507

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 502004015645

Country of ref document: DE

Representative=s name: BARDEHLE PAGENBERG PARTNERSCHAFT MBB PATENTANW, DE

Ref country code: DE

Ref legal event code: R081

Ref document number: 502004015645

Country of ref document: DE

Owner name: XYLO TECHNOLOGIES AG, CH

Free format text: FORMER OWNER: KRONOPLUS TECHNICAL AG, NIEDERTEUFEN, CH

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180207

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180207

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502004015645

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180207

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180207

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180207

REG Reference to a national code

Ref country code: BE

Ref legal event code: HC

Owner name: XYLO TECHNOLOGIES AG; CH

Free format text: DETAILS ASSIGNMENT: CHANGE OF OWNER(S), CHANGEMENT DE NOM DU PROPRIETAIRE; FORMER OWNER NAME: KRONOPLUS TECHNICAL AG

Effective date: 20181029

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20181108

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180207

REG Reference to a national code

Ref country code: AT

Ref legal event code: HC

Ref document number: 968624

Country of ref document: AT

Kind code of ref document: T

Owner name: XYLO TECHNOLOGIES AG, CH

Effective date: 20190129

REG Reference to a national code

Ref country code: CH

Ref legal event code: PFA

Owner name: XYLO TECHNOLOGIES AG, CH

Free format text: FORMER OWNER: KRONOPLUS TECHNICAL AG, CH

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20181119

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180207

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20181130

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20181130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20181119

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20181130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180207

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20041119

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20231123

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: TR

Payment date: 20231117

Year of fee payment: 20

Ref country code: SE

Payment date: 20231120

Year of fee payment: 20

Ref country code: IT

Payment date: 20231124

Year of fee payment: 20

Ref country code: DE

Payment date: 20231121

Year of fee payment: 20

Ref country code: AT

Payment date: 20231121

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PL

Payment date: 20231109

Year of fee payment: 20

Ref country code: BE

Payment date: 20231120

Year of fee payment: 20